ES2007314T3 - Compuestos de organopolisiloxano y amonio que contienen rodio, procedimiento para su preparacion y uso. - Google Patents

Compuestos de organopolisiloxano y amonio que contienen rodio, procedimiento para su preparacion y uso.

Info

Publication number
ES2007314T3
ES2007314T3 ES87117054T ES87117054T ES2007314T3 ES 2007314 T3 ES2007314 T3 ES 2007314T3 ES 87117054 T ES87117054 T ES 87117054T ES 87117054 T ES87117054 T ES 87117054T ES 2007314 T3 ES2007314 T3 ES 2007314T3
Authority
ES
Spain
Prior art keywords
ammonium compounds
rhodium
organopolysiloxane
procedure
preparation
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
ES87117054T
Other languages
English (en)
Other versions
ES2007314A4 (es
Inventor
Peter Dr Panster
Robert Gradl
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Evonik Operations GmbH
Original Assignee
Degussa GmbH
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Degussa GmbH filed Critical Degussa GmbH
Publication of ES2007314A4 publication Critical patent/ES2007314A4/es
Application granted granted Critical
Publication of ES2007314T3 publication Critical patent/ES2007314T3/es
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
    • C08G77/48—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule in which at least two but not all the silicon atoms are connected by linkages other than oxygen atoms
    • C08G77/58—Metal-containing linkages
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/12—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides
    • B01J31/123—Organometallic polymers, e.g. comprising C-Si bonds in the main chain or in subunits grafted to the main chain
    • B01J31/124—Silicones or siloxanes or comprising such units
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/165—Polymer immobilised coordination complexes, e.g. organometallic complexes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/20—Carbonyls
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
    • C08G77/48—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule in which at least two but not all the silicon atoms are connected by linkages other than oxygen atoms
    • C08G77/54—Nitrogen-containing linkages
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/82—Metals of the platinum group
    • B01J2531/822—Rhodium

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Silicon Polymers (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

SE PROPONEN NUEVAS COMBINACIONES DE AMONIO-ORGANOPOLISILOXAN CON CONTENIDO DE RODIO, QUE CONSTA DE UNIDADES DE LA FORMULA (1) EN LA R1, R2 Y R3 SON PARA UN GRUPO R5-SIO3/2 (2), CON LO QUE R5 ES UN GRUPO DE ALQUILES Y LAS VALENCIAS LIBRES DEL ATOMO DE OXIGENO SE SATURAN POR ATOMOS DE SILICIO DE OTROS GRUPOS (2), DADO EL CASO POR FORMACION DE REDES. R4 ES PARA HIDROGENO, UN GRUPO DE ALQUIL, CICLOALQUIL O BENZIL, XN PARA UN METALANION DEL RODIO COMPLEJO MONO O POLIVALENTE Y DADO EL CASO PARA CLORICO, BROMICO O IODICO. OTROS OBJETIVOS DEL INVENTO SON EL PROCEDIMIENTO PARA LA FABRICACION DE ESTAS COMBINACIONES DE AMONIO-ORGANOPOLISILOXAN CON CONTENIDO DE RODIO ASI COMO SU UTILIZACION COMO CATALIZADORES EN REACCIONES CON MONOXIDO DE CARBONO.
ES87117054T 1986-12-22 1987-11-19 Compuestos de organopolisiloxano y amonio que contienen rodio, procedimiento para su preparacion y uso. Expired - Lifetime ES2007314T3 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DE19863643894 DE3643894A1 (de) 1986-12-22 1986-12-22 Rhodium-haltige organopolysiloxan-ammoniumverbindungen, verfahren zu ihrer herstellung und verwendung

Publications (2)

Publication Number Publication Date
ES2007314A4 ES2007314A4 (es) 1989-06-16
ES2007314T3 true ES2007314T3 (es) 1994-09-01

Family

ID=6316874

Family Applications (1)

Application Number Title Priority Date Filing Date
ES87117054T Expired - Lifetime ES2007314T3 (es) 1986-12-22 1987-11-19 Compuestos de organopolisiloxano y amonio que contienen rodio, procedimiento para su preparacion y uso.

Country Status (6)

Country Link
US (1) US4845163A (es)
EP (1) EP0275399B1 (es)
JP (1) JPH078914B2 (es)
AT (1) ATE90706T1 (es)
DE (2) DE3643894A1 (es)
ES (1) ES2007314T3 (es)

Families Citing this family (34)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE3800564C1 (es) * 1988-01-12 1989-03-16 Degussa Ag, 6000 Frankfurt, De
JP2532124B2 (ja) * 1988-04-19 1996-09-11 東芝シリコーン株式会社 海棲生物付着防止剤
JP2603291B2 (ja) * 1988-04-19 1997-04-23 東芝シリコーン株式会社 第４級アンモニウム基含有シリコーン樹脂微粉末
DE3837418A1 (de) * 1988-11-04 1990-05-10 Degussa Organosiloxanamin-copolykondensate, verfahren zu ihrer herstellung und verwendung (i)
DE3837416A1 (de) * 1988-11-04 1990-05-10 Degussa Organosiloxanamin-copolykondensate, verfahren zu ihrer herstellung und verwendung (ii)
DE4035033C1 (es) * 1990-11-03 1992-04-02 Degussa Ag, 6000 Frankfurt, De
DE4035032C1 (es) * 1990-11-03 1992-04-30 Degussa Ag, 6000 Frankfurt, De
DE4040568A1 (de) * 1990-12-19 1992-06-25 Degussa Polymere organosiloxanammoniumsalze von oxosaeuren der elemente v, nb, ta, mo und w, verfahren zu ihrer herstellung und verwendung
US5286885A (en) * 1990-12-19 1994-02-15 Degussa Aktiengesellschaft Process for preparing glycide by epoxidation using polymeric organosiloxane ammonium salts of oxoacids of the elements V, Nb, Ta, Mo, and W
DE4110705C1 (es) * 1991-04-03 1992-10-22 Degussa Ag, 6000 Frankfurt, De
DE4110706C1 (es) * 1991-04-03 1992-12-17 Degussa Ag, 6000 Frankfurt, De
DE4130643A1 (de) * 1991-09-14 1993-03-18 Degussa Verfahren zur reinigung von alkoxysilanen
DE4142129C1 (es) * 1991-12-20 1993-07-01 Degussa Ag, 6000 Frankfurt, De
DE4223539C1 (de) * 1992-07-17 1993-11-25 Degussa Geformte Sulfonatgruppen-haltige Organopolysiloxane, Verfahren zu ihrer Herstellung und Verwendung
US5466767A (en) * 1992-08-06 1995-11-14 Degussa Aktiengesellschaft Shaped organosiloxane polycondensates, process for their preparation and use
IT1256601B (it) * 1992-10-16 1995-12-12 Eniricerche Spa Composizioni supportate a base di tungsteno o molibdeno,procedimento per il loro ottenimento e proprieta' come catalizzatori eterogenei di ossidazione
DE4409140A1 (de) * 1994-03-17 1995-09-21 Degussa Wäßrige Lösungen von Organopolysiloxan-Ammoniumverbindungen, ihre Herstellung und Verwendung
US5900505A (en) * 1997-02-04 1999-05-04 Eastman Chemical Company Heterogeneous vapor phase carbonylation process
US6159896A (en) * 1999-02-16 2000-12-12 Eastman Chemical Company Iridium catalyst for carbonylation of lower aliphatic alcohols
US6137000A (en) * 1999-02-16 2000-10-24 Eastman Chemical Company Method for carbonylation of lower aliphatic alcohols using a supported iridium and lanthanide series catalyst
US6160163A (en) * 1999-02-16 2000-12-12 Eastman Chemical Company Method for the vapor-phase carbonylation of lower aliphatic alcohols using a supported platinum catalyst and halide promoter
US6355837B1 (en) 1999-08-25 2002-03-12 Eastman Chemical Company Vapor phase carbonylation process using group 4 metal promoted iridium catalyst
US6355595B1 (en) 1999-08-25 2002-03-12 Eastman Chemical Company Group 5 metal promoted iridium carbonylation catalyst
US6353132B1 (en) 1999-08-25 2002-03-05 Eastman Chemical Company Vapor phase carbonylation process using group 5 metal promoted iridium catalyst
US6506933B1 (en) 2000-05-22 2003-01-14 Eastman Chemical Company Vapor phase carbonylation process using gold catalysts
US6441222B1 (en) 2000-05-22 2002-08-27 Eastman Chemical Company Vapor phase carbonylation process using iridium-gold co-catalysts
US6177380B1 (en) 2000-05-22 2001-01-23 Eastman Chemical Company Iridium-gold carbonylation co-catalysts
US6509293B1 (en) 2000-05-22 2003-01-21 Eastman Chemical Company Gold based heterogeneous carbonylation catalysts
US6613938B2 (en) 2001-06-19 2003-09-02 Eastman Chemical Company Method for carbonylation of lower aliphatic alcohols using tin promoted platinum catalyst
US6903045B2 (en) 2001-06-19 2005-06-07 Eastman Chemical Company Tin promoted platinum catalyst for carbonylation of lower alkyl alcohols
US6537944B1 (en) 2001-06-20 2003-03-25 Eastman Chemical Company Tungsten promoted catalyst for carbonylation of lower alkyl alcohols
US6617471B2 (en) 2001-06-20 2003-09-09 Eastman Chemical Company Method for carbonylation of lower aliphatic alcohols using tin promoted iridium catalyst
US6646154B2 (en) 2001-06-20 2003-11-11 Eastman Chemical Company Method for carbonylation of lower alkyl alcohols using tungsten promoted group VIII catalyst
US6548444B2 (en) 2001-06-20 2003-04-15 Eastman Chemical Company Tin promoted iridium catalyst for carbonylation of lower alkyl alcohols

Family Cites Families (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4302401A (en) * 1980-01-23 1981-11-24 Exxon Research & Engineering Co. Tetraalkyl phosphonium substituted phosphine and amine transition metal complexes
DE3029599C2 (de) * 1980-08-05 1985-05-15 Degussa Ag, 6000 Frankfurt Polymere Organosiloxanphosphinkomplexe des Rhodiums, Iridiums und Rutheniums, Verfahren zu ihrer Herstellung und Verwendung
DE3120195C2 (de) * 1981-05-21 1986-09-04 Degussa Ag, 6000 Frankfurt Polymere Ammoniumverbindungen mit kieselsäureartigem Grundgerüst, Verfahren zu ihrer Herstellung und Verwendung
DE3131854A1 (de) * 1981-08-12 1983-03-31 Karl-Heinz 3030 Walsrode Bohlmann Verfahren zum sichern der verschluesse abgefuellter verpackungsgefaesse gegen unbefugtes oeffnen
DE3131954C2 (de) * 1981-08-13 1984-10-31 Degussa Ag, 6000 Frankfurt Metallkomplexe von polymeren, gegebenenfalls vernetzten Organosiloxanaminen, Verfahren zu ihrer Herstellung und Verwendung
DE3404702A1 (de) * 1984-02-10 1985-09-05 Degussa Ag, 6000 Frankfurt Platin- und/oder palladium-haltige organopolysiloxan-ammoniumverbindungen, verfahren zu ihrer herstellung und verwendung
US4719286A (en) * 1985-03-14 1988-01-12 Northrop Corporation Class of conductive polymers

Also Published As

Publication number Publication date
EP0275399B1 (de) 1993-06-16
ATE90706T1 (de) 1993-07-15
JPH078914B2 (ja) 1995-02-01
US4845163A (en) 1989-07-04
ES2007314A4 (es) 1989-06-16
DE3786248D1 (de) 1993-07-22
JPS63168433A (ja) 1988-07-12
DE3643894C2 (es) 1989-06-22
EP0275399A2 (de) 1988-07-27
EP0275399A3 (en) 1990-10-03
DE3643894A1 (de) 1988-06-23

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