EP4680445A1 - Apparatus and method for heat treatment of wood - Google Patents
Apparatus and method for heat treatment of woodInfo
- Publication number
- EP4680445A1 EP4680445A1 EP24718278.5A EP24718278A EP4680445A1 EP 4680445 A1 EP4680445 A1 EP 4680445A1 EP 24718278 A EP24718278 A EP 24718278A EP 4680445 A1 EP4680445 A1 EP 4680445A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- thermal treatment
- wood
- air
- heating
- air circulation
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B27—WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
- B27K—PROCESSES, APPARATUS OR SELECTION OF SUBSTANCES FOR IMPREGNATING, STAINING, DYEING, BLEACHING OF WOOD OR SIMILAR MATERIALS, OR TREATING OF WOOD OR SIMILAR MATERIALS WITH PERMEANT LIQUIDS, NOT OTHERWISE PROVIDED FOR; CHEMICAL OR PHYSICAL TREATMENT OF CORK, CANE, REED, STRAW OR SIMILAR MATERIALS
- B27K5/00—Treating of wood not provided for in groups B27K1/00, B27K3/00
- B27K5/0085—Thermal treatments, i.e. involving chemical modification of wood at temperatures well over 100°C
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F26—DRYING
- F26B—DRYING SOLID MATERIALS OR OBJECTS BY REMOVING LIQUID THEREFROM
- F26B21/00—Arrangements for supplying or controlling air or other gases for drying solid materials or objects
- F26B21/20—Circulating air or gases in closed cycles, e.g. wholly within the drying enclosure
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F26—DRYING
- F26B—DRYING SOLID MATERIALS OR OBJECTS BY REMOVING LIQUID THEREFROM
- F26B21/00—Arrangements for supplying or controlling air or other gases for drying solid materials or objects
- F26B21/30—Controlling, e.g. regulating, parameters of gas supply
- F26B21/35—Temperature; Pressure
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F26—DRYING
- F26B—DRYING SOLID MATERIALS OR OBJECTS BY REMOVING LIQUID THEREFROM
- F26B21/00—Arrangements for supplying or controlling air or other gases for drying solid materials or objects
- F26B21/40—Arrangements for supplying or controlling air or other gases for drying solid materials or objects using gases other than air
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F26—DRYING
- F26B—DRYING SOLID MATERIALS OR OBJECTS BY REMOVING LIQUID THEREFROM
- F26B23/00—Heating arrangements
- F26B23/10—Heating arrangements using tubes or passages containing heated fluids, e.g. acting as radiative elements; Closed-loop systems
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F26—DRYING
- F26B—DRYING SOLID MATERIALS OR OBJECTS BY REMOVING LIQUID THEREFROM
- F26B25/00—Details of general application not covered by group F26B21/00 or F26B23/00
- F26B25/001—Handling, e.g. loading or unloading arrangements
- F26B25/003—Handling, e.g. loading or unloading arrangements for articles
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F26—DRYING
- F26B—DRYING SOLID MATERIALS OR OBJECTS BY REMOVING LIQUID THEREFROM
- F26B25/00—Details of general application not covered by group F26B21/00 or F26B23/00
- F26B25/005—Treatment of dryer exhaust gases
- F26B25/006—Separating volatiles, e.g. recovering solvents from dryer exhaust gases
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F26—DRYING
- F26B—DRYING SOLID MATERIALS OR OBJECTS BY REMOVING LIQUID THEREFROM
- F26B25/00—Details of general application not covered by group F26B21/00 or F26B23/00
- F26B25/06—Chambers, containers, or receptacles
- F26B25/14—Chambers, containers, receptacles of simple construction
- F26B25/16—Chambers, containers, receptacles of simple construction mainly closed, e.g. drum
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F26—DRYING
- F26B—DRYING SOLID MATERIALS OR OBJECTS BY REMOVING LIQUID THEREFROM
- F26B3/00—Drying solid materials or objects by processes involving the application of heat
- F26B3/02—Drying solid materials or objects by processes involving the application of heat by convection, i.e. heat being conveyed from a heat source to the materials or objects to be dried by a gas or vapour, e.g. air
- F26B3/04—Drying solid materials or objects by processes involving the application of heat by convection, i.e. heat being conveyed from a heat source to the materials or objects to be dried by a gas or vapour, e.g. air the gas or vapour circulating over or surrounding the materials or objects to be dried
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F26—DRYING
- F26B—DRYING SOLID MATERIALS OR OBJECTS BY REMOVING LIQUID THEREFROM
- F26B5/00—Drying solid materials or objects by processes not involving the application of heat
- F26B5/04—Drying solid materials or objects by processes not involving the application of heat by evaporation or sublimation of moisture under reduced pressure, e.g. in a vacuum
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F26—DRYING
- F26B—DRYING SOLID MATERIALS OR OBJECTS BY REMOVING LIQUID THEREFROM
- F26B2210/00—Drying processes and machines for solid objects characterised by the specific requirements of the drying goods
- F26B2210/16—Wood, e.g. lumber, timber
Definitions
- the present description relates to the technical field of wood thermal treatment apparatuses and methods.
- wood thermal treatment methods currently used in the industry substantially consist in performing, in sequence, the following three steps:
- European Patent EP 2535156 B1 describes certain embodiments of an apparatus comprising an autoclave cell for high-temperature wood thermal treatment.
- the apparatus described comprises:
- an autoclave in which a vacuum-tight thermal treatment chamber adapted to contain the wood is defined, provided with an airtight hatch for introducing and removing a support carriage of a stack of wood to be subjected to the thermal treatment itself into/from the thermal treatment chamber;
- thermo treatment chamber a system for heating the interior of the thermal treatment chamber, which can consist of electric batteries or finned-tube radiators for heating by means of vapor and/or diathermic oil, or of a diathermic oil jacket outside the thermal treatment chamber;
- a ventilation system comprising one or more fans adapted to transfer the thermal energy from the heating system to the wood material by circulating the gas in the thermal treatment chamber;
- a vacuum pump unit comprising a vacuum pump and possibly a condenser interposed between the vacuum pump and the thermal treatment chamber, adapted to condense any vapor and/or gas exiting the wood in order to provide for its storage in a suitable tank and its disposal;
- the wood thermal treatment apparatus comprises a heating system having electric resistors arranged inside the thermal treatment chamber, and also having an air cooling system comprising an air circulation jacket arranged about the thermal treatment chamber. Therefore, in the aforesaid configuration, the heating of the thermal treatment chamber involves a significant consumption of electricity.
- FIG. 1 shows an isometric view of a part of a wood thermal treatment apparatus according to a non-limiting embodiment of the present invention
- FIG. 2 shows a diagrammatic sectional view of the wood thermal treatment apparatus in Figure 1, in a heating operating configuration
- - Figure 3 shows a diagrammatic sectional view of the wood thermal treatment apparatus in Figure 1, in a cooling operating configuration
- FIG. 4 shows a diagrammatic sectional view of a second embodiment of a wood thermal treatment apparatus in the heating operating configuration.
- Figure 1 shows a non-limiting exemplary embodiment of a part of a wood thermal treatment apparatus 1 according to a non-limiting embodiment of the present invention.
- the thermal treatment apparatus 1 will also be more briefly referred to as the apparatus 1 or the thermal treatment apparatus 1.
- the wood thermal treatment apparatus 1 comprises a cell 2 comprising a thermal treatment chamber 3 adapted to house a wood mass 4 to be thermally treated.
- the wood mass 4 comprises a plurality of wood boards 40 arranged so as to form a stack.
- cell 2 is, or comprises, a container body 16, for example a box-shaped or cylindrical container body, extending along a mainly longitudinal extension axis X-X between two opposite end portions 2a, 2b.
- the mainly longitudinal extension axis X-X a is conveniently a horizontal axis or a substantially horizontal axis.
- the outer walls of the container body 16 are preferably made of steel, e.g., stainless steel.
- the container body 16 has a length in the range of 6 - 15 meters along the mainly longitudinal extension axis X-X. If the container body 16 is a box- shaped container body, said body 16 has, for example, a rectangular cross section the sides of which have, for example, a length in the range of 2 - 4 meters. If the container body 16 is a cylindrical container body, it has, for example, a diameter in the range of 2 meters - 4 meters.
- the wood mass 4 to be thermally treated has, for example, a volume in the range of 6 m 3 -70 m 3 . Each time a range of values is indicated in the present description, the end values of the range are intended as being included in the range.
- the vacuum-tight hatch 30 is, for example, pivotally hinged to the container body 16, preferably by means of a cylindrical hinge conveniently having a vertical, or substantially vertical, hinge axis.
- the vacuum-tight hatch 30 allows introducing the wood mass 4 to be treated into the thermal treatment chamber 3 and extracting the wood mass 4 from the thermal treatment chamber 3 after the thermal treatment.
- the vacuum-tight hatch 30 allows hermetically closing the thermal treatment chamber 3.
- the wood mass 4 rests on a support carriage 41, equipped with wheels, for example.
- the thermal treatment chamber 3 comprises an inner rail 31 for the support carriage 41 to slide.
- the apparatus 1 further comprises an outer rail 32, which is outside the thermal treatment chamber 3, on which the support carriage 41 and the wood mass 4 can be placed prior to being introduced into the thermal treatment chamber 3 and after being extracted from the thermal treatment chamber.
- the outer rail 32 is movable so as to be arranged contiguous to and aligned with the inner rail 31 to translate the support carriage 41 when inserting the carriage 41 and the wood mass 4 into the treatment chamber 3, and then to be moved in order to allow closing the vacuum-tight hatch 30. After the thermal treatment and upon cooling the wood mass 4, and also upon opening the vacuum-tight hatch, the outer rail 32 can be repositioned aligned with and contiguous to the inner rail 31 to allow the extraction of the wood mass 4 from the thermal treatment chamber 3.
- Cell 2 comprises an air circulation jacket 5 arranged outside the thermal treatment chamber 3 which is adjacent to the thermal treatment chamber 3 and is fluidly isolated from the thermal treatment chamber 3 by at least one partition wall 6. This clearly implies that air flowing in the air circulation jacket 5 does not flow in the thermal treatment chamber 3.
- Said at least one partition wall 6 is a thermally conductive wall and, for example, is made of stainless steel or aluminum or a metal alloy having high thermal conductivity.
- the air circulation jacket 5 comprises an inlet collector 7 for introducing air into the air circulation jacket 5 and an outlet collector 8 for extracting air from the air circulation jacket 5.
- cell 2 comprises a thermal insulating layer 15 covering the air circulation jacket 5 on the opposite side with respect to the thermal treatment chamber 3. Said thermal insulating layer 15 is thus arranged between the partition wall 6 and an outer wall of the container body 16.
- the air circulation jacket 5 transversely surrounds the thermal treatment chamber 3 at least in part. More advantageously, the air circulation jacket 5 transversely surrounds, e.g., circumferentially, continuously or substantially continuously, at least one longitudinal segment of the thermal treatment chamber 3, for example a longitudinal segment at least equal to 50%, or preferably at least equal to 90%, of the longitudinal extension of the thermal treatment chamber 3.
- the apparatus 1 comprises a ventilation system having one or more fans 18 arranged inside the thermal treatment chamber 3, adapted to transfer to the wood mass the thermal energy of the fluid contained inside the thermal treatment chamber 3, which can be air or an inert gas, for example.
- the wood thermal treatment apparatus 1 further comprises a system for heating and cooling the thermal treatment chamber 3, adapted to take a heating operating configuration and a cooling operating configuration.
- the heating and cooling system allows heating the thermal treatment chamber 3.
- the cooling operating configuration allows cooling the thermal treatment chamber 3.
- the heating and cooling system comprises a recirculation duct 9a, 9b, or a recirculation flow path 9a, 9b, which in the heating operating configuration is connected between the inlet collector 7 and the outlet collector 8 so that an airflow, which is introduced into and extracted from the air circulation jacket 5, passes in such a recirculation duct 9a, 9b.
- the recirculation duct 9a, 9b and the air circulation jacket 5 form a closed circuit, more precisely a closed fluid path.
- the recirculation duct 9a, 9b comprises an air delivery pipe 9a and an air return pipe 9b.
- the heating and cooling system further comprises a heating unit 10 configured to heat air flowing in the recirculation duct 9a, 9b by combustion of wood waste resulting from wood processing, i.e., utilizing thermal energy generated by the combustion of wood waste material resulting from wood processing.
- the heating unit 10 heats air flowing along a limited segment of the recirculation duct 9a, 9b and is arranged between the air return pipe 9b and the air delivery pipe 9a, for example.
- the air delivery pipe 9a is a pipe for delivering relatively hotter air
- the air return pipe 9b is a pipe for returning relatively less hot air.
- the heating and cooling system further comprises flow diverter means 11a, 11b configurable or controllable to open the aforesaid closed circuit in the cooling operating configuration of the heating and cooling system. Therefore, such flow diverter means 11a, 11b are such as to open the aforesaid closed circuit in the cooling operating configuration of the heating and cooling system.
- the flow diverter means 11a, 11b are such as to interrupt the fluid communication between the air circulation jacket 5 and the recirculation duct 9a, 9b.
- the cooling operating configuration is diagrammatically shown in Figure 3.
- the flow diverter means 11a, 11b are controlled electronically to establish and interrupt the fluid communication between the air circulation jacket 5 and the recirculation duct 9a, 9b.
- said at least one fan 12a, 12b comprises a first fan 12a arranged upstream of the inlet collector 7 and a second fan 12b placed downstream of the outlet collector 8.
- the first fan 12a is operatively interposed between the heating unit 10 and the first flow diverter valve 11a, but in an alternative embodiment, the first fan 12a could be operatively interposed between the flow diverter valve 11a and the inlet collector 7.
- the aforesaid means adapted to impose a forced air circulation in the closed circuit and in the air circulation jacket 5 allow imposing a forced air circulation in the air circulation jacket 5 in both the heating operating configuration and the cooling operating configuration.
- the heating and cooling system is such as to achieve a temperature in the range of 180°C-230°C inside the thermal treatment chamber 3.
- the modification of the wood structure of the wood mass 4 occurs in this temperature range through multiple chemical- physical reactions of the substances forming it.
- Such multiple thermal-chemical reactions cause the following macroscopic modifications of the wood features:
- HYGROSCOPICITY reduction in the hygroscopicity of the wood, i.e., the ability thereof to take or absorb the humidity in the surrounding environment, making it almost insensitive to climate changes (temperature and air humidity);
- apparatus 1 further comprises a first temperature sensor 14a adapted to measure the temperature of the airflow entering into the air circulation jacket 5, and a second temperature sensor 14b adapted to measure the temperature of air exiting from the air circulation jacket 5.
- the heating and cooling system can thus be controlled based on a difference in temperature between the temperature of the incoming airflow and the temperature of the exiting air, for example so that such a difference is less than 15°C, for example equal to 10°C or equal to about 10°C.
- the heating and cooling system can be controlled by controlling the means adapted to impose a forced air circulation in the closed circuit and in the air circulation jacket, for example the speed of fan 12a and/or fan 12b.
- the heating and cooling system can be controlled, for example, by controlling the heating unit 10 so as to decrease or increase the heating power thereof.
- the first temperature sensor 14a is arranged in the inlet collector 7 or immediately upstream thereof, and the second temperature sensor 14b is arranged in the outlet collector 8 or immediately downstream thereof.
- the thermal treatment apparatus 1 further comprises a vacuum pump 13 operatively connected, for example by means of a pipe 19, to the thermal treatment chamber 3 and configured to cause a vacuum level in the range of 70-350 mBar of absolute pressure in the thermal treatment chamber 3.
- the vacuum pump 13 allows substances released following the heating of the wood mass to be drawn from the thermal treatment chamber 3.
- These substances can be condensed by providing a condenser operatively interposed between the thermal treatment chamber 3 and the vacuum pump 13 and communicating with a storage tank of said substances.
- Such substances can thus be disposed of, minimizing the environmental impact.
- the combustion of the wood mass 4 is prevented by virtue of the combination of this vacuum level with the temperatures selected for the thermal treatment (range of 180°C-230°C), as already explained in greater detail in European Patent EP 2535156 B1.
- the thermal treatment apparatus 1 is configured to perform the dual function of vacuum dryer and thermal treatment device so as to first dry the wood with temperatures between 50-100°C and pressures between 50-350 mBar so as not to damage the wood itself while lowering the moisture thereof up to values close to zero, and then expose it to the "brutal" temperatures of the thermal- chemical modification treatment with temperatures of 180- 230°C and pressures of 70-350 mBar, again using the same thermal treatment chamber 3.
- the heating unit 10 comprises a wood hot-air generator 20, for example a heater which generates hot air from the combustion of wood.
- the heating unit 10 further comprises a storage silo 21 for wood waste resulting from wood processing, and an automated transport system 22 operatively interposed between the storage silo 21 and the wood hot-air generator 20, configured to supply the wood hot-air generator 20 with wood waste contained in the storage silo 21.
- the automated transport system 22 comprises, for example, a spiral conveyor preferably controllable in an automatic manner based on the thermal energy required in the heating operating configuration. In the heating operating configuration ( Figure 2), the hot air generator 20 is ON and is powered. In the cooling operating configuration ( Figure 3), the hot air generator 20 is OFF and is not powered.
- the thermal treatment apparatus 1 comprises an electronic control unit (not shown in the figures) operatively connected to the heating and cooling system and configured, i.e., programmed, to control the operation of the heating and cooling system.
- an electronic control unit is operatively connected: to the first sensor 14a and/or to the second sensor 14b and/or to the heating unit 10 and/or to the means adapted to impose a forced air circulation in the closed circuit and in the air circulation jacket, and to the flow diverter means 11a, 11b and/or to the ventilation system 18 and/or to one or more sensors adapted to measure the temperature and/or the pressure and/or the humidity inside the thermal treatment chamber 3.
- the electronic control unit comprises a PLC (Programmable Logic Controller), for example.
- FIG. 4 diagrammatically shows a second embodiment of the wood thermal treatment apparatus 1, which differs from the apparatus described hereto with reference to
- the heating unit 10 comprises a diathermic oil-air heat exchanger 30 or a saturated vapor- air heat exchanger 30 adapted to transfer thermal energy from diathermic oil or saturated vapor to air circulating in the recirculation duct 9a, 9b.
- the diathermic oil and saturated vapor can be generated by utilizing the thermal energy developed by the combustion of wood waste.
- a wood mass 4 to be treated in a cell 2 comprising a thermal treatment chamber 3 adapted to house said wood mass 4 to be treated, where cell 2 comprises an air circulation jacket 5 arranged outside the thermal treatment chamber 3 which is adjacent to the thermal treatment chamber 3 and is fluidly isolated from the thermal treatment chamber 3 by at least one partition wall 6;
- the method further comprises a step of cooling said wood mass by opening the recirculation duct to introduce air drawn from the external environment into the air circulation jacket 5, and progressively lowering the temperature inside the thermal treatment chamber 3.
- Step 0 Preheating wood at the absolute pressure of 300 mBar (vacuum) with constant increase in temperature from ambient temperature up to reaching the start treatment temperature equal to 180°C;
- Step 1 first pressure (for example, to bring the absolute pressure to 316 mBar) and temperature (192°C) level and waiting until the wood reaches the step-1 temperature;
- Step 2 second pressure (for example, to bring the absolute pressure to 333 mBar) and temperature (203°C) level and waiting until the wood reaches the step-2 temperature;
- Step 3 third pressure (for example, to bring the absolute pressure to 350 mBar) and temperature (215°C) level, being final treatment values, and keeping them for the time required to ensure the effectiveness of the treatment.
- step 3 the cooling step is started: this step consists in bringing the apparatus back to the configuration in Figure 3 to circulate cold ambient air in the air circulation jacket 3 in order to cool the wood to a final temperature of 40-60°C.
- the heating unit 10 comprises a valve 32 which allows activating the diathermic oil or saturated vapor flow in the exchanger 30 in the heating operating configuration, and interrupting said flow in the cooling operating configuration.
- the amount of CO2 emitted by the wood in the combustion is equal to that absorbed by the tree when it was living and therefore there is substantially no increase in CO2;
Landscapes
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- General Engineering & Computer Science (AREA)
- Life Sciences & Earth Sciences (AREA)
- Sustainable Development (AREA)
- Molecular Biology (AREA)
- Chemical & Material Sciences (AREA)
- Combustion & Propulsion (AREA)
- Health & Medical Sciences (AREA)
- Microbiology (AREA)
- Physics & Mathematics (AREA)
- Thermal Sciences (AREA)
- Wood Science & Technology (AREA)
- Forests & Forestry (AREA)
- Chemical And Physical Treatments For Wood And The Like (AREA)
- Drying Of Solid Materials (AREA)
Abstract
Description
Claims
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| IT102023000007455A IT202300007455A1 (en) | 2023-04-18 | 2023-04-18 | Apparatus and method for heat treatment of wood |
| PCT/IB2024/052887 WO2024218595A1 (en) | 2023-04-18 | 2024-03-26 | Apparatus and method for heat treatment of wood |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| EP4680445A1 true EP4680445A1 (en) | 2026-01-21 |
Family
ID=87036822
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| EP24718278.5A Pending EP4680445A1 (en) | 2023-04-18 | 2024-03-26 | Apparatus and method for heat treatment of wood |
Country Status (3)
| Country | Link |
|---|---|
| EP (1) | EP4680445A1 (en) |
| IT (1) | IT202300007455A1 (en) |
| WO (1) | WO2024218595A1 (en) |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN206176892U (en) * | 2016-10-13 | 2017-05-17 | 上海青平药业有限公司 | Ebullated dryer suitable for preparation compound magnesium trisilicate piece |
Family Cites Families (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2008118036A1 (en) * | 2007-03-28 | 2008-10-02 | Igor Aleksandrovich Danchenko | Method for wood heat treatment and a device for carrying out said method |
| ITRM20110314A1 (en) | 2011-06-16 | 2012-12-17 | Dott Ing Ernesto Pagnozzi | PROCEDURE FOR THERMAL MODIFICATION OF HIGH-TEMPERATURE TIMBER WITHIN A VACUUM D AUTOCLAVE NOW FORWARD FOR A PATENTED DENOMINATION |
| US20210302096A1 (en) * | 2019-08-15 | 2021-09-30 | Tyler Player | Drying Apparatus and Method of Drying |
-
2023
- 2023-04-18 IT IT102023000007455A patent/IT202300007455A1/en unknown
-
2024
- 2024-03-26 EP EP24718278.5A patent/EP4680445A1/en active Pending
- 2024-03-26 WO PCT/IB2024/052887 patent/WO2024218595A1/en not_active Ceased
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN206176892U (en) * | 2016-10-13 | 2017-05-17 | 上海青平药业有限公司 | Ebullated dryer suitable for preparation compound magnesium trisilicate piece |
Also Published As
| Publication number | Publication date |
|---|---|
| IT202300007455A1 (en) | 2024-10-18 |
| WO2024218595A1 (en) | 2024-10-24 |
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