EP4665574A1 - Verbundscheibe mit elektrisch steuerbaren optischen eigenschaften - Google Patents
Verbundscheibe mit elektrisch steuerbaren optischen eigenschaftenInfo
- Publication number
- EP4665574A1 EP4665574A1 EP24701556.3A EP24701556A EP4665574A1 EP 4665574 A1 EP4665574 A1 EP 4665574A1 EP 24701556 A EP24701556 A EP 24701556A EP 4665574 A1 EP4665574 A1 EP 4665574A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- surface electrode
- functional element
- composite pane
- layer
- region
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
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- G02F1/00—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics
- G02F1/01—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour
- G02F1/13—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour based on liquid crystals, e.g. single liquid crystal display cells
- G02F1/133—Constructional arrangements; Operation of liquid crystal cells; Circuit arrangements
- G02F1/1333—Constructional arrangements; Manufacturing methods
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- G02F1/00—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics
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- G02F1/13—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour based on liquid crystals, e.g. single liquid crystal display cells
- G02F1/133—Constructional arrangements; Operation of liquid crystal cells; Circuit arrangements
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- G02F1/13452—Conductors connecting driver circuitry and terminals of panels
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- G02F1/00—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics
- G02F1/01—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour
- G02F1/15—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour based on an electrochromic effect
- G02F1/153—Constructional details
- G02F1/155—Electrodes
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Definitions
- the invention relates to a composite pane with electrically controllable optical properties and its use.
- Composite panes with electrically controllable optical properties are known as such. They are equipped with functional elements which comprise an active layer or layer sequence between two surface electrodes, whereby the optical properties of the active layer or layer sequence can be changed by an electrical voltage applied to the surface electrodes.
- functional elements include SPD functional elements (suspended particle device), which are known for example from EP 0876608 B1 and WO 2011033313 A1. The transmission of visible light through SPD functional elements can be controlled by the applied voltage.
- PDLC functional elements polymer dispersed liquid crystal
- the active layer contains liquid crystals which are embedded in a polymer matrix.
- Electrochromic functional elements are also known, for example from US 20120026573 A1, WO 2010147494 A1 and EP 1862849 A1 and WO 2012007334 A1, in which a change in transmission occurs through electrochemical processes that are induced by the applied electrical voltage.
- Such composite panes can be used, for example, as vehicle windows, the light transmission behavior of which can then be controlled electrically. They can be used, for example, as roof panes to reduce solar radiation or to reduce annoying reflections.
- roof panes are known, for example, from DE 10043141 A1 and EP 3456913 A1.
- Windshields have also been proposed in which an electrically controllable sun visor is implemented by means of a switchable functional element in order to replace the conventional mechanically folding sun visor in Motor vehicles.
- Windscreens with electrically controlled sun visors are known, for example, from DE 102013001334 A1, DE 102005049081 B3, DE 102005007427 A1 and DE 102007027296 A1.
- such composite panes can be used not only in the vehicle sector, but also, for example, in building glazing or interior window panes.
- the electrically controllable functional elements are typically provided as a multilayer film and embedded in the intermediate layer of the composite pane.
- the multilayer film is made up of two carrier films, typically based on PET, with the surface electrodes deposited on them, typically based on ITO, and the active layer or layer sequence in between.
- a contact area is typically created for each surface electrode by removing the opposite carrier film with the other surface electrode and the active layer or layer sequence, so that the said surface electrode is exposed in the contact area and can be electrically contacted via a current busbar, typically a strip of copper foil. Electrical conductors are connected to the current busbars, which lead beyond the side edge of the composite pane in order to connect the functional element to the external voltage source.
- the contact areas of the two surface electrodes are typically formed on opposite sides of the functional element, which is advantageous for the optical behavior of the functional element because it ensures more uniform and sometimes faster switching behavior.
- this fact brings with it disadvantages in terms of production. Since the process steps for electrical contacting are carried out on opposite sides of the functional element, the manufacturing effort is increased. In particular, comparatively long electrical conductors are required, which are applied, for example, as metal wires with a plotter to thermoplastic films of the intermediate layer of the composite pane, which is time-consuming.
- a composite pane with an electrically controllable functional element is known, the contacting areas of which are arranged on opposite sides of the functional element.
- the current collecting rails have an L-shape, so that the current collecting rail of the first surface electrode in a connection area starting from a first contacting area to the opposite side of the functional element. This allows the electrical conductors to be connected to the two current collecting bars on the same side of the functional element.
- the second carrier film, the second surface electrode and the active layer or layer sequence must be removed in the connection area in order to arrange the current collecting bar on the first surface electrode, and the second surface electrode then directly adjoins the connection area in which the first surface electrode is exposed, there is a risk that the second surface electrode will come into contact with the first surface electrode, the current collecting bar of the first surface electrode or their electrical contacts and cause a short circuit.
- the present invention is based on the object of providing an improved composite pane with electrically controllable optical properties, which is in particular easier to produce and in which short circuits are avoided.
- the invention is based on the approach of extending one of the busbars and leading it in a connection area to the opposite side of the functional element, where the other busbar is also positioned.
- the electrical connection of both busbars can then be made on the same side of the functional element, which reduces the manufacturing effort. Fewer long electrical conductors are then required, so that their design can be carried out more quickly, for example with a plotter.
- the composite pane according to the invention with electrically controllable optical properties comprises an outer pane and an inner pane which are connected to one another via a thermoplastic intermediate layer.
- the composite pane also comprises an electrically controllable functional element which is embedded in the intermediate layer.
- the functional element has, in the order given, a first carrier film, a first surface electrode, an active layer or layer sequence with electrically controllable optical properties, a second surface electrode and a second carrier film.
- the carrier films, the surface electrodes and the active layer/layer sequence are typically arranged substantially parallel to the surfaces of the outer pane and the inner pane.
- the functional element has a first contacting area, which is provided for the electrical connection of the first surface electrode.
- the first contacting area the second carrier film, the second surface electrode and the active layer or layer sequence are removed.
- the first carrier film and the first surface electrode remain, so that the first surface electrode is exposed and can be electrically contacted.
- the first surface electrode is electrically connected to a current collecting bar.
- the current collecting bar is arranged on the first surface electrode in the first contacting area.
- the functional element also has a second contacting area, which is provided for the electrical connection of the second surface electrode.
- the first carrier film, the first surface electrode and the active layer or layer sequence are removed.
- the second carrier film and the second surface electrode remain, so that the second surface electrode is exposed and can be electrically contacted.
- the second surface electrode is electrically connected to at least one current collecting rail.
- the at least one current collecting rail is arranged in the second contacting area on the second surface electrode.
- the first contacting area and the second contacting area are arranged on opposite sides of the functional element.
- the current busbar of the first surface electrode i.e. the current busbar which is arranged on the first surface electrode in the first contacting area, is connected to it and is electrically connected to it
- the connection area is formed exactly like the first contacting area in that the second carrier film, the second surface electrode and the active layer or layer sequence are removed.
- the contact areas preferably have a width of 3 mm to 20 mm, particularly preferably 5 mm to 10 mm.
- the connection area preferably also has a Width from 3 mm to 20 mm, particularly preferably from 5 mm to 10 mm.
- the width is the dimension perpendicular to the intended direction of extension of the busbars.
- the current busbar of the first surface electrode and the at least one current busbar of the second surface electrode are connected to a voltage source via electrical conductors.
- the electrical conductors are preferably connected on the same side of the functional element to the current busbar of the first surface electrode and the at least one current busbar of the second surface electrode.
- the contacting regions are preferably formed directly adjacent to the side edge of the functional element.
- the first contacting region and the second contacting region directly adjoin opposite sections of the side edge of the functional element.
- connection region is also designed to be directly adjacent to the side edge of the functional element. It is directly adjacent to a section of the side edge that extends between the sections of the side edge with the first and second contacting regions.
- the connection region adjoins one end of the first contacting region and runs from there to the opposite side of the functional element.
- connection area is not designed to be directly adjacent to the side edge of the functional element. It runs in a central area of the functional element, bordering on both sides on active areas of the functional element.
- the connection region adjoins a section of the first contacting region located between the ends and runs from there to the opposite side of the functional element.
- the connection region divides the second surface electrode and the second contacting region into two sections, each section being assigned to an active region of the functional element.
- the functional element is not limited to a specific shape.
- the functional element has an at least approximately square, in particular at least approximately rectangular shape (based on the top view in the direction of viewing through the composite pane).
- the functional element has four corners and four sides, with adjacent sides each being connected to one another via a corner.
- approximately is meant that the shape can deviate from the ideal geometric square or rectangle in that the sides do not have to be straight, but can, for example, be convex or concavely curved or wavy independently of one another.
- the contact areas are arranged on two opposite sides, in particular directly adjacent to the side edge or the said sides.
- the two other sides run between the sides with the contact areas, in particular essentially perpendicular to them.
- the connection area preferably runs essentially parallel to these other sides, whereby it can border one of the two or run in an area between these other sides.
- the second contacting area and the connecting area can overlap.
- a section of the functional element is cut off, namely the area of overlap in which the carrier foils with the surface electrodes located on them are removed, since the active layer or layer sequence alone is not stable.
- the second contacting area and the connecting area abut one another directly, viewed from above on the functional element or the composite pane. This is the case when the cutting line for removing the first carrier foil in the second contacting area and the cutting line for removing the second carrier foil in the connecting area are arranged in a overlapping section in alignment, viewed from above.
- the second contacting area and the connection area do not overlap.
- the second contacting area and the The connection areas do not abut one another in the sense described above. Instead, when viewed from above onto the functional element or the composite pane, there is at least one intermediate area between the second contacting area and the connection area.
- the cutting line for removing the first carrier film in the second contacting area is therefore guided to the side edge of the functional element before it reaches the connection area.
- the first carrier film, the first surface electrode and the active layer or layer sequence are not removed, but extend in particular to the side edge of the functional element on the side on which the electrical connection is made.
- the second carrier film and the second surface electrode also extend in the intermediate area to the side edge of the functional element on the side on which the electrical connection is made.
- a part of the second surface electrode which, viewed in plan view, borders the connection region is electrically insulated from the rest of the second surface electrode by at least one insulation line.
- the at least one insulation line preferably runs from the side of the functional element with the second contact region to the opposite first contact region.
- the at least one insulation line divides the second surface electrode into at least one active region, in which it actually acts as a surface electrode and applies a voltage to the active layer/layer sequence, and at least one region which is electrically insulated from it and which, viewed in plan view, borders the connection region.
- the electrical insulation of the part of the second surface electrode bordering the connection region reduces the risk of short circuits in particular.
- this part of the second surface electrode borders directly on the connection region in which the first surface electrode is exposed and in which the busbar runs, so that there is a risk that this part of the second surface electrode will come into contact with the first surface electrode, the busbar of the first surface electrode or their electrical contacts and cause a short circuit.
- the at least one insulation line for insulating the region of the second surface electrode adjacent to the connection region has, for example, a width (line width) of 5 pm to 500 pm, in particular 20 pm to 200 pm. It is preferably introduced into the second surface electrode by means of laser radiation. If the connection area borders on the side edge of the functional element, a single insulation line is sufficient, which divides the second surface electrode into an active area and an area that is electrically insulated from it and borders the connection area. If the connection area does not border on the side edge of the functional element, two insulation lines are used, which divide the second surface electrode into two active areas and two areas that are electrically insulated from it and border the connection area on one side.
- the second surface electrode (or each of its active regions if the second surface electrode is divided into two sections by a connecting region not adjacent to the side edge of the functional element and/or an area of the second surface electrode adjacent to the connecting region is insulated from at least one active region by at least one insulation line in at least one intermediate region) is designed as a continuous, uninterrupted layer. It is not divided by insulation lines into several segments that are electrically insulated from one another.
- the functional element (or its active region) can then be brought into a uniform optical state by the applied electrical voltage; there are no independently controllable switching regions.
- the second surface electrode is preferably electrically conductively connected to a single busbar in the second contact region.
- each section is preferably electrically conductively connected to a single busbar.
- the second surface electrode and the first surface electrode are electrically connected to the voltage source so that an electrical voltage can be applied between the second surface electrode on the one hand and the first surface electrode on the other hand in order to control the optical properties of the active layer/layer sequence located therebetween.
- the second surface electrode (or at least one, preferably each of its active regions, if the second surface electrode is divided into two sections by a connecting region not adjacent to the side edge of the functional element and/or by at least one insulation line in at least one intermediate region, a adjacent region of the second surface electrode is insulated from at least one active region) is divided into at least two separate electrode segments by at least one insulation line. Each electrode segment is electrically connected to a (separate or separate) current busbar.
- Each electrode segment of the second surface electrode and the first surface electrode (or its active region) are electrically connected to the voltage source, so that an electrical voltage can be applied independently of one another between each electrode segment of the second surface electrode on the one hand and the first surface electrode (or its active region) on the other hand in order to control the optical properties of the section of the active layer/layer sequence located therebetween. In this way, several independent switching regions can be realized, the optical properties of which can be electrically controlled independently of one another.
- the second surface electrode has at least two segments (electrode segments) which are separated from one another by an insulation line.
- the second surface electrode can be divided into several segments by several insulation lines.
- Each electrode segment forms a switching area of the composite disk.
- the number of electrode segments can be freely selected by the expert according to the requirements in the individual case.
- the insulation lines run essentially parallel to one another and extend from one side edge of the surface electrode to the opposite side edge.
- any other geometric shapes are also conceivable.
- the insulation lines between the segments of the second surface electrode have, for example, a width of 5 pm to 500 pm, in particular 20 pm to 200 pm. They are preferably introduced into the second surface electrode by means of laser radiation.
- the width of the segments i.e. the distance between adjacent insulation lines, can be selected by the expert in accordance with the requirements in the individual case.
- the electrode segments of the second surface electrode are electrically connected to the voltage source independently of one another, so that a second electrical potential (which is constant over time in the case of a direct voltage, and variable over time in the case of an alternating voltage) can be applied to each electrode segment (independently of the other electrode segments), which can also be referred to as a switching potential.
- the first surface electrode (or its active area) is also electrically connected to the voltage source so that a first electrical potential can be applied to the first surface electrode (or its active area), which can also be referred to as the reference potential (“ground”). If the first and second potentials are identical, there is no voltage between the electrodes in the respective switching area (switching state 0%). If the first and second potentials are different, there is a voltage between the electrodes in the respective switching area, which creates a finite switching state (switching state up to 100%, which corresponds to the maximum change in the optical properties of the active layer/layer sequence).
- the first surface electrode is preferably designed as a continuous, uninterrupted layer.
- the first surface electrode therefore has no insulation lines that would divide it into independent segments.
- a uniform electrical potential is preferably applied to the first surface electrode.
- An insulation line is generally understood to be a line-like or line-shaped area in which the material of the surface electrode is not present, so that the adjacent sections (segments) are materially separated from one another and are therefore electrically insulated from one another. This means that there is no direct electrical connection between the sections (segments), although the sections (segments) can be indirectly electrically connected to one another to a certain extent via the active layer in contact with them.
- the busbars serve to distribute the electrical contact of the respective surface electrode with the voltage source over a comparatively large contact area and to introduce or discharge the electrical current over as large a width as possible. They are also referred to as “busbars”.
- the busbars preferably have a width of 2 mm to 20 mm, particularly preferably 4 mm to 9 mm.
- the width of the busbars is preferably smaller than the width of the contact areas and the connection area, for example by about 1 mm.
- the busbars are preferably made of an electrically conductive film (in particular as a strip or section of the electrically conductive film).
- the film is particularly preferably a metal foil, in particular copper foil.
- the copper foil can be tinned.
- the metal foil has, for example, a thickness of 0.02 mm to 0.2 mm, preferably 0.05 mm to 0.1 mm.
- polymer carrier films can also be used. which are provided with an electrically conductive coating, for example a silver coating.
- the busbars can be formed independently of one another in one piece (i.e. from a single strip or section of the electrically conductive film) or in multiple pieces (i.e. from several assembled strips or sections of the electrically conductive film).
- the busbar of the second surface electrode is formed in one piece (in particular as a strip of the electrically conductive film) and the busbar of the first surface electrode is formed in one piece or in multiple pieces.
- the two sections of the busbar on the contacting area and the connecting area are preferably each formed in one piece and connected to one another, for example placed on top of one another, soldered or electrically conductively glued.
- the busbar of the first surface electrode typically has an L-like shape (if the connecting section adjoins a side edge of the functional element) or a T-like shape (if the connecting section does not adjoin a side edge of the functional element).
- a T- or L-shaped section of the electrically conductive foil can be used or a strip of the electrically conductive foil can be folded into the T- or L-like shape.
- the busbars are electrically connected to the associated surface electrode.
- the busbars can, for example, simply be placed on the surface electrode, soldered to the surface electrode or connected to the surface electrode via an electrically conductive adhesive.
- an electrical contact layer is arranged between the surface electrode and the busbar in order to improve the electrical contact.
- the contact layer can, for example, be designed as a silver-containing paste with a thickness of 0.01 mm to 0.2 mm, preferably 0.02 mm to 0.1 mm, in particular 0.02 mm to 0.05 mm.
- An electrical conductor is connected to the busbar of the first surface electrode and to the busbar of the second surface electrode or the busbars of the various segments of the second surface electrode, which extends beyond the side edge of the composite disc in order to to be connected to the external voltage source.
- the conductor can be formed in one piece or in multiple pieces. This conductor can be, for example, a metal wire, a metal foil and/or an electrical cable that extends from the respective surface electrode beyond the side edge of the composite disc.
- the said conductors comprise a ribbon conductor which extends beyond the side edge of the composite pane and to which the busbars of the surface electrodes are connected via electrical conductors.
- the composite pane then has the ribbon conductor.
- the ribbon conductor is arranged laterally at a certain distance from the functional element, in particular on the side with the second contact area, on which the electrical connection is made, and extends beyond the side edge of the composite pane.
- the busbar of the first surface electrode and the at least one busbar of the second surface electrode are connected to the ribbon conductor via electrical conductors.
- the ribbon conductor advantageously facilitates the electrical connection of the functional element. In particular, the effort of laying a plurality of separate lines for each individual busbar is eliminated.
- the ribbon cable has a plurality of electrically conductive tracks, in particular each formed from a strip of metal foil (for example copper foil). Preferably, all electrically conductive tracks are connected to a component by a polymer sheath or carrier layer.
- the first surface electrode is assigned a conductive track to which it is connected via electrical conductors.
- the second surface electrode is assigned a conductive track to which it is connected via electrical conductors, or a plurality of conductive tracks are assigned, each segment of the second surface electrode being connected to a (separate) track via electrical conductors, so that each electrode segment is connected to exactly one track and each track is connected to exactly one electrode segment.
- the ribbon cable can of course also have tracks that are not connected to any electrode or electrode segment and are not used for electrical connection (“blind tracks”).
- an electrical contact element is connected to each of the busbars.
- the busbars are each provided with an electrical contact element, whereby the Contact element is, for example, placed on the current busbar, soldered to it, or glued with a conductive adhesive.
- the electrical contact element is preferably made of an electrically conductive foil, in particular copper foil.
- the copper foil can be tinned.
- the metal foil has, for example, a thickness of 0.02 mm to 0.2 mm, preferably 0.05 mm to 0.1 mm.
- the contact element can be designed, for example, as a carrier foil with an electrically conductive coating, for example a silver coating.
- the contact element preferably has at least one section that extends from the current busbar beyond the side edge of the functional element, in particular essentially perpendicular to the direction of the current busbar. This section is preferably connected to the ribbon conductor.
- the contact element can, for example, have a strip-like or T-like shape.
- the contact element can be connected directly to the ribbon cable. Alternatively, the contact element can be connected indirectly to the ribbon cable via an electrical line.
- the electrical lines are preferably metal wires, electrical cables or printed lines.
- the contact element can also be used in cases where the electrical cables themselves extend beyond the side edge of the composite pane, i.e. where there is no common ribbon cable.
- the electrically controllable functional element is a multilayer film or functional film with the actual active layer or layer sequence and the surface electrodes between two carrier films.
- Such multilayer films can be purchased, cut to the desired size and shape and then laminated into the composite pane, whereby they are preferably connected to the outer pane and the inner pane via a thermoplastic connecting layer.
- the first and second carrier films are formed, for example, on the basis of polyethylene terephthalate (PET), polypropylene, polyvinyl chloride, fluorinated ethylene propylene, polyvinyl fluoride or ethylene tetrafluoroethylene, preferably on the basis of PET.
- PET polyethylene terephthalate
- the thickness of the carrier films is preferably from 10 pm to 200 pm.
- the side edge of the functional element can be sealed, for example by fusing the carrier films or by a (preferably polymeric) tape or a polymeric film. In this way, the active layer can be protected, in particular against components of the intermediate layer (particularly plasticizers) diffusing into the active layer, which can lead to degradation of the functional element.
- the first and second surface electrodes are preferably transparent, which in the sense of the invention means that they have a light transmission in the visible spectral range of at least 50%, preferably at least 70%, particularly preferably at least 80%.
- the surface electrodes preferably contain at least one metal, a metal alloy or a transparent conductive oxide (TCO).
- TCO transparent conductive oxide
- the surface electrodes can be based, for example, on silver, gold, copper, nickel, chromium, tungsten, indium tin oxide (ITO), gallium-doped or aluminum-doped zinc oxide and/or fluorine-doped or antimony-doped tin oxide, preferably based on silver or ITO.
- the surface electrodes preferably have a thickness of 10 nm to 2 pm, particularly preferably 20 nm to 1 pm, most preferably 30 nm to 500 nm.
- the active layer or layer sequence has the variable optical properties that can be controlled by an electrical voltage applied to the active layer via the surface electrodes.
- electrically controllable optical properties are understood to mean in particular those properties that can be controlled continuously. In principle, however, it is also conceivable that the electrically controllable optical properties can only be switched between two discrete states (or between more than two discrete states).
- the said optical properties relate in particular to the light transmission and/or the scattering behavior.
- a single active layer or an active layer sequence i.e. a plurality of different layers which together provide the variable optical properties.
- Various types of functional elements can be used, with the functional element in preferred embodiments being a functional element based on liquid crystal technology (in particular a PDLC functional element), an SPD functional element or an electrochromic functional element.
- Functional elements based on liquid crystal technology contain an active layer with liquid crystals. The liquid crystals can be aligned by applying a voltage to the surface electrodes, which is the basis for the electrical control of the optical properties.
- the following functional elements based on liquid crystal technology are common:
- PDLC functional elements polymer dispersed liquid crystal.
- the active layer contains drops of liquid crystals in a polymer matrix. If the liquid crystals are aligned in an electric field, the state is transparent and does not scatter light; if the liquid crystals are not aligned without an electric field, the state is translucent and strongly scatters light.
- PNLC functional elements polymer networked liquid crystal
- the active layer contains liquid crystals embedded in a polymer network. Without an applied voltage, the liquid crystals are aligned and the state is transparent and does not scatter light. If an electrical voltage is applied, configuration changes take place, which lead to strong scattering on the liquid crystals, so that the state is translucent and strongly scatters light.
- the active layer contains dichroic dye molecules (guest) dissolved in liquid crystals (host). In the electric field, the liquid crystals are aligned, which influences the orientation of the dye molecules, which leads to a change in the degree of transmission (tint) and a change in color.
- guest dichroic dye molecules
- host liquid crystals
- SPD functional elements (suspended particle device) have an active layer that contains suspended particles.
- the absorption of light by the active layer can be changed by applying a voltage to the surface electrodes, which leads to a change in the orientation of the suspended particles.
- Electrochromic functional elements contain an active layer sequence between the surface electrodes (electrochromic layer sequence), which comprises an ion storage layer, an electrolyte layer and an electrochromic layer arranged one above the other in the order given.
- the electrochromic layer is the actual carrier of the electrically controllable optical properties. It is an electrochemically active layer whose light transmission depends on the degree of ion storage.
- the ions for example H + -, Li + , Na + - or K + -ions
- the electrolyte layer spatially separates the electrochromic layer. from the ion storage layer and serves to migrate ions.
- ions migrate from the ion storage layer through the electrolyte layer into the electrochromic layer, whereupon the optical properties (color, light transmission) of the electrochromic layer are changed depending on the extent of the ions that have migrated.
- a direct voltage of the opposite polarity is applied to the surface electrodes, the ions migrate back from the electrochromic layer through the electrolyte layer into the ion storage layer and the optical properties of the electrochromic layer change in the opposite way. If no voltage is applied to the surface electrodes, the current state remains stable.
- Suitable electrochromic layers contain electrochromic materials, for example inorganic oxides (such as tungsten oxide or vanadium oxide), complex compounds (such as Prussian blue) or conductive polymers (such as 3,4-polyethylenedioxythiophene (PEDOT) or polyaniline).
- the electrolyte layer is typically formed as a film of organic or inorganic, electrically insulating material with high ion conductivity, for example based on lithium phosphorus oxynitride.
- the ion storage layer is either permanently transparent (pure ion storage) or has an electrochromic behavior that is opposite to that of the electrochromic layer.
- An example of a pure ion storage is layers containing a mixed oxide of titanium and cerium; examples of anodic electrochromic ion storage layers are layers containing iridium oxide or nickel oxide.
- a control unit suitable for operating the functional element is preferably used as the voltage source for the functional element.
- the control unit is suitable for applying a voltage between the first surface electrode on the one hand and the second surface electrode or the electrode segments of the second surface electrode on the other hand (in each case).
- the voltage provided by the control unit can be a direct voltage (for example in the case of electrochromic functional elements) or an alternating voltage (for example in the case of SPD functional elements or in the case of PDLC functional elements or other functional elements based on liquid crystal technology).
- the primary voltage source provides a direct voltage (as is usual in the on-board network of a vehicle, for example) while the functional element is operated with an alternating voltage
- the control unit can comprise inverters.
- the control unit can comprise rectifiers.
- the control unit is designed and suitable for controlling the optical properties of the functional element.
- the control unit is electrically connected on the one hand to the surface electrodes of the functional element and on the other hand to a primary voltage source.
- the control unit contains the necessary electrical and/or electronic components to apply the required voltage to the surface electrodes depending on a switching state.
- the switching state can be specified by the user (for example by operating a switch, a button or a rotary or slide control), determined by sensors and/or transmitted via a digital interface from the central control unit of the vehicle (if the composite pane is a vehicle pane, usually LIN bus or CAN bus).
- the switches, buttons, rotary or slide controls can, for example, be integrated into the vehicle's instruments if the composite pane is a vehicle pane.
- touch buttons can also be integrated directly into the composite pane, for example capacitive or resistive buttons.
- the functional element can also be controlled by contactless methods, for example by recognizing gestures, or depending on the state of the pupil or eyelid determined by a camera and suitable evaluation electronics.
- the control unit can, for example, comprise electronic processors, voltage converters, transistors and other components.
- the control unit can be attached to the interior side surface of the inner pane facing away from the intermediate layer or, for example, be integrated in the electrical system of the vehicle or be attached to the vehicle body if the laminated pane is a vehicle pane.
- the composite pane is typically intended to separate an interior from the outside environment in a window opening (for example a window opening of a vehicle, a building or a room).
- the inner pane refers to the pane facing the interior.
- the outer pane refers to the pane facing the outside environment.
- the outer pane and the inner pane each have an outside surface and an inside surface and a circumferential side edge surface running between them.
- the outside surface refers to the main surface which is intended to face the outside environment in the installed position.
- the inside surface refers to the main surface which is intended to to face the interior in the installed position.
- the interior-side surface of the outer pane and the exterior-side surface of the inner pane face each other and are connected to one another by the thermoplastic intermediate layer.
- the outer pane and the inner pane are preferably made or formed from glass, particularly preferably from soda-lime glass, as is usual for window panes.
- the panes can also be made from other types of glass, for example quartz glass, borosilicate glass or aluminosilicate glass, or from rigid clear plastics, for example polycarbonate or polymethyl methacrylate.
- the panes can be clear or tinted or colored.
- the thickness of the outer pane and the inner pane can vary widely and can therefore be adapted to the requirements of the individual case.
- the outer pane and the inner pane preferably have thicknesses of 0.5 mm to 5 mm, particularly preferably 1 mm to 3 mm.
- the outer pane and the inner pane can be flat or cylindrical or spherically curved. Spherically curved composite panes are particularly common in vehicle glazing, while flat composite panes are common in building glazing.
- the outer pane, the inner pane and/or the intermediate layer can have suitable coatings known per se, for example anti-reflective coatings, non-stick coatings, anti-scratch coatings, photocatalytic coatings, UV-absorbing or reflective coatings or IR-absorbing or reflective coatings such as sun protection coatings or low-E coatings.
- suitable coatings known per se, for example anti-reflective coatings, non-stick coatings, anti-scratch coatings, photocatalytic coatings, UV-absorbing or reflective coatings or IR-absorbing or reflective coatings such as sun protection coatings or low-E coatings.
- the composite pane can be provided with an opaque cover print, in particular at least in a peripheral edge area, as is common in the vehicle sector, in particular for windshields, rear windows and roof windows.
- the cover print is typically made of an enamel containing glass frits and a pigment, in particular black pigment.
- the printing ink is typically applied using a screen printing process and baked in.
- Such a cover print is applied to at least one of the pane surfaces, preferably the interior surface of the outer pane and/or the inner pane.
- the cover print preferably surrounds a central see-through area in a frame-like manner.
- the cover print forms an opaque masking area of the composite pane.
- the contact areas and the Connection areas of the functional element are preferably arranged in this masking area.
- thermoplastic intermediate layer serves to connect the two panes, as is usual with composite panes. Typically, thermoplastic films are used and the intermediate layer is formed from these.
- the functional element is arranged between two thermoplastic layers.
- the intermediate layer is formed from at least a first thermoplastic layer and a second thermoplastic layer, between which the functional element is arranged.
- the functional element is then connected to the outer pane via an area of the first thermoplastic layer and to the inner pane via an area of the second thermoplastic layer.
- the thermoplastic layers preferably protrude all the way around the functional element. Where the thermoplastic layers are in direct contact with one another and are not separated from one another by the functional element, they can fuse during lamination in such a way that the original layers may no longer be recognizable and a homogeneous intermediate layer is present instead.
- the functional element is surrounded all the way around by a third thermoplastic layer.
- the third thermoplastic layer is designed like a frame with a recess into which the functional element is inserted.
- the third thermoplastic layer can be formed by a thermoplastic film into which the recess has been cut out.
- the third thermoplastic layer can also be composed of several film sections around the functional element.
- the intermediate layer is then formed from a total of at least three thermoplastic layers arranged flat on top of one another, with the middle layer having a recess in which the functional element is arranged.
- the third thermoplastic layer is arranged between the first and second thermoplastic layers, with the side edges of all thermoplastic layers preferably being in alignment.
- the third thermoplastic layer preferably has approximately the same thickness as the functional element. This compensates for the local difference in thickness introduced by the locally limited functional element, so that glass breakage during lamination can be avoided and an improved optical appearance is created.
- the functional element can also be arranged directly on the surface of the outer pane or the inner pane facing the intermediate layer.
- the side edge of the functional element is preferably completely surrounded by the intermediate layer, so that the functional element does not extend to the side edge of the composite pane and thus has no contact with the surrounding atmosphere.
- the use of a frame-like thermoplastic layer around the functional element is possible.
- the thermoplastic layers of the intermediate layer are preferably made of the same material, but in principle they can also be made of different materials.
- the layers or films of the intermediate layer are preferably based on polyvinyl butyral (PVB), ethylene vinyl acetate (EVA), or polyurethane (PU).
- PVB polyvinyl butyral
- EVA ethylene vinyl acetate
- PU polyurethane
- the layer or film mainly contains the said material (a proportion of more than 50% by weight) and can optionally contain other components, for example plasticizers, stabilizers, UV or IR absorbers.
- the thickness of each thermoplastic layer is preferably from 0.2 mm to 2 mm, particularly preferably from 0.3 mm to 1 mm. For example, films with standard thicknesses of 0.38 mm or 0.76 mm can be used.
- the composite pane can be manufactured by stacking the individual layers in the intended order to form a layer stack and then laminating the outer pane and the inner pane together via the intermediate layer.
- Known methods can be used for this, for example autoclave methods, vacuum bag methods, vacuum ring methods, calender methods, vacuum laminators or combinations thereof.
- the outer pane and inner pane are usually joined together using heat, vacuum and/or pressure.
- the layer stack preferably comprises in the order given: the outer pane - a first thermoplastic film which forms a first thermoplastic layer of the intermediate layer,
- thermoplastic film which forms a second thermoplastic layer of the intermediate layer
- the functional element When stacking the layers, the functional element is provided with the required electrical connections, with electrical conductors extending beyond the side edge of the layer stack, to which the external voltage source can later be provided.
- the functional element is provided with the busbars, which are connected to the surface electrodes, optionally via an electrical contact layer.
- the electrical conductors are provided on the thermoplastic films and suitably positioned so that when the layer stack is created, the electrical conductors come into contact with the busbars without any further measures.
- the electrical conductors preferably comprise a ribbon conductor, which is arranged to the side of the functional element, an electrical contact element for direct connection to the busbars and electrical lines (in particular wires or cables) between each contact element and a conductor track of the ribbon conductor.
- the electrical conductors are each attached to the thermoplastic film, opposite which the surface electrode, which is to be contacted with the conductors, is exposed.
- the first surface electrode is exposed in the first contact area opposite the second thermoplastic film: in the first contact area, only the first carrier film and the first surface electrode are present, with the first surface electrode facing the second thermoplastic layer.
- the invention also includes the use of a composite pane according to the invention in buildings or in means of transport for traffic on land, in the air or on water, for example as a window pane of a vehicle, as a window pane of a building or a room (building interior) or as a component of furniture, electrical devices or furnishings.
- the composite pane is preferably the window pane of a vehicle, in particular a motor vehicle.
- the glazing unit can be used, for example, as a windshield, roof window, rear window or side window, preferably as a windshield or roof window.
- the composite pane is a windshield of a vehicle.
- the functional element is preferably used as an electrically controllable sun visor, which is arranged in an upper area of the windshield, while the majority of the windshield is not provided with the functional element.
- the composite pane is a roof pane of a vehicle.
- the functional element is preferably arranged in the entire see-through area of the composite pane.
- this see-through area comprises the entire composite pane minus a peripheral edge area that is provided with an opaque cover print on at least one of the surfaces of the panes.
- the functional element extends over the entire see-through area, with its side edges arranged in the area of the opaque cover print and thus not visible to the observer.
- the independently switchable switching areas allow the user to specify which areas of the roof pane should be transparent and which should be darkened or provided with a high level of light scattering, for example depending on the position of the sun, in order to avoid excessive heating of the vehicle interior. It is also possible for each vehicle occupant, for example the driver, the front passenger, the left and right rear occupants, to be assigned a switching area located above them.
- the invention is explained in more detail using a drawing and exemplary embodiments.
- the drawing is a schematic representation and not to scale. The drawing does not limit the invention in any way. It shows:
- Fig. 1 shows a cross section of an embodiment of the composite pane according to the invention
- Fig. 2 shows a cross section through the functional element of the composite pane from Figure 1
- Fig. 3 shows a plan view of the functional element from Figure 2
- Fig. 4 is a plan view of the functional element of a further embodiment of the composite pane according to the invention.
- Fig. 5 is a plan view of the functional element of a further embodiment of the composite pane according to the invention.
- Fig. 6 is a plan view of the functional element of a conventional composite pane.
- Figure 1 shows a cross-section of the design of the composite pane according to the invention with electrically controllable optical properties.
- the composite pane is provided, for example, as a roof pane of a passenger car, the light transmission of which can be electrically controlled.
- the composite pane comprises an outer pane 1 and an inner pane 2, which are connected to one another via an intermediate layer 3.
- the outer pane 1 and the inner pane 2 consist of soda-lime glass, which can optionally be tinted.
- the outer pane 1 has a thickness of 2.1 mm, for example, and the inner pane 2 has a thickness of 1.6 mm.
- the intermediate layer 3 comprises a total of three thermoplastic layers 3a, 3b, 3c, each of which is formed by a thermoplastic PVB film with a thickness of 0.38 mm.
- the first thermoplastic layer 3a is connected to the outer pane 1, the second thermoplastic layer 3b to the inner pane 2.
- the third thermoplastic layer 3c in between has a cutout into which a functional element 10 with electrically controllable optical properties is inserted in a substantially precise manner, i.e. approximately flush on all sides.
- the third thermoplastic layer 3c thus forms a kind of passespartout or frame for the approximately 0.4 mm thick functional element 10, which is thus encapsulated all around in thermoplastic material and thus protected.
- the composite pane has a peripheral edge area which is provided with an opaque cover print 4.
- This cover print 4 is typically made of black enamel. It is printed as a printing ink with a black pigment and glass frits using the screen printing process and burned into the pane surface. The cover print 4 is applied, for example, to the interior surface of the outer pane 1 and also to the interior surface of the inner pane 2. The side edges of the functional element 10 are covered by this cover print 4.
- FIG. 2 shows a cross-section through the functional element 10 from Figure 1 alone.
- the functional element 10 is, for example, a PDLC multilayer film that can be switched from a clear, transparent state to a cloudy, non-transparent (diffuse) state.
- the functional element 10 consists of an active layer 11 between a first surface electrode 14 and a second surface electrode 15.
- the first surface electrode 14 is applied to a first carrier film 12, the second surface electrode 15 to a second carrier film 13.
- the active layer 11 contains a polymer matrix with liquid crystals dispersed therein, which align themselves depending on the electrical voltage applied to the surface electrodes 14, 15, whereby the optical properties can be controlled.
- the carrier films 12, 13 are made of PET and have a thickness of, for example, 0.125 mm.
- the carrier foils 12, 13 are each provided with a coating of ITO facing the active layer 11 with a thickness of about 100 nm, which forms the surface electrodes 14, 15.
- the functional element 10 has a first contacting region in which the first surface electrode 14 is exposed in order to connect it to the voltage source.
- the second carrier film 13, the second surface electrode 15 and the active layer 11 are removed.
- a current collecting bar 21 is arranged on the first surface electrode 14 via an electrical contact layer 23.
- the functional element 10 has a second contacting region in which the second surface electrode 15 is exposed in order to connect it to the voltage source.
- the first carrier film 12, the first surface electrode 14 and the active layer 11 are removed.
- a current collecting bar 22 is arranged on the second surface electrode 15 via an electrical contact layer 23.
- Figure 3 shows a top view of the functional element 10 from Figure 2.
- the second carrier film 13 is facing the viewer.
- the functional element has a rectangular shape with four straight side sections and four corners.
- the first contacting area extends along the left side section and directly borders on the side edge of the functional element 10. There, the second carrier film 13 with the second surface electrode 15 and the active layer 11 are removed so that the exposed first surface electrode 14 can be seen on the first carrier layer 12 (shown in dotted lines).
- the second contacting area extends along the right side section and borders directly on the side edge of the functional element 10.
- the first carrier film 12 with the first surface electrode 14 and the active layer 11 are removed there.
- the second surface electrode 15 cannot be seen here because it is covered by the second carrier film 13 on top.
- the left boundary of the second contacting area (cutting line) is indicated by a thin dashed line.
- the current busbar 22 is arranged on the second surface electrode 15. It is shown with a dashed outline and in gray because it is behind the second carrier film 13 and can therefore only be seen when viewed through it.
- the current busbar 21 is arranged on the first surface electrode 14.
- connection region Adjacent to the lower side edge, a connection region runs from the first contacting region to the opposite right-hand side section of the functional element 10. In the connection region, as in the first contacting region, the second carrier film 13, the second surface electrode 15 and the active layer 11 are removed, so that the first surface electrode 14 is exposed.
- a section of the busbar 21 of the first surface electrode 14 is arranged in the first contacting area.
- the outline of the second contacting region shown in dashed lines corresponds to the cutting line for removing the first carrier film 12. In the plan view shown, it is below the second contacting region to the side edge of the functional element in the right-hand side section before it reaches the connection region. As a result, an intermediate region is arranged between the second contacting region and the connection region in which the first carrier film 12, the first surface electrode 14 and the active layer 11 are not removed.
- the composite pane is equipped with a ribbon conductor 27, which is arranged to the side of the functional element 10, spaced from the right-hand side section.
- the ribbon conductor 27 extends beyond the side edge of the composite pane.
- a T-shaped electrical contact element 25 is arranged on the current busbar 22 of the second surface electrode 15, which is directly connected to the ribbon conductor 27.
- the majority of the contact element 25 is again shown with a dashed outline and in gray because it is located behind the second carrier film 13 and the current busbar 22.
- a strip-like electrical contact element 24 is arranged on the current busbar 21 of the first surface electrode 14 in the connection area, which is directly connected to the ribbon conductor 27.
- Each contact element 24, 25 is connected to one of two conductor tracks of the ribbon conductor 27, which is not shown for the sake of simplicity.
- the busbars have a width of 5 mm, for example. They are made of a copper foil with a thickness of 50 pm, for example.
- the electrical contact layers 23 consist of a silver paste with a thickness of 50 pm, for example.
- the electrical contact elements 24, 25 are also made of a copper foil with a thickness of 50 pm, for example.
- a part of the second surface electrode 15 is electrically insulated from the rest of the second surface electrode 15 by an insulation line 16.
- the insulation line 16 divides the second surface electrode 15 into an active region, which serves as the actual surface electrode, and an area insulated from it, which borders the connection area. This reduces the risk of a short circuit, since the part of the second surface electrode 15 bordering the connection area can easily come into contact with the first surface electrode 14 or its busbar 21.
- the insulation line 16 is introduced into the second surface electrode 15 by laser radiation and has a line width of, for example, 100 pm.
- FIG 4 shows a top view of the functional element 10 in a further embodiment of the composite pane according to the invention.
- the functional element 10 is basically constructed in the same way as in the embodiment of Figures 2 and 3.
- the functional element 10 has three independent switching areas in which the switching state can be set independently of one another.
- the switching areas allow the driver of the vehicle (for example depending on the position of the sun) to choose to provide only one area of the composite pane with the diffuse state instead of the entire composite pane, while the other areas remain transparent.
- the second surface electrode 15 is divided into three electrode segments 15.1, 15.2, 15.3 by two insulation lines 15'.
- the insulation lines 15' are introduced into the surface electrode 15 by laser radiation and have a line width of, for example, 100 pm.
- Each electrode segment 15.1, 15.2, 15.3 is connected to the voltage source independently of the others.
- a control unit is suitable for independently applying an electrical voltage between each electrode segment 15.1, 15.2, 15.3 of the second surface electrode 15 on the one hand and the first surface electrode 14 on the other hand, so that the section of the active layer 11 located between them is subjected to the required voltage in order to achieve a desired switching state.
- Each electrode segment 15.1, 15.2, 15.3 is provided in the second contact area with a current busbar 22.1, 22.2, 22.3, which in turn is provided with an electrical contact element 25.1, 25.2, 25.3.
- the contact elements 24, 25.1, 25.2, 25.3 are not connected directly to the ribbon conductor 27, but rather via an electrical line 26 connected to it.
- the ribbon conductor 27 has at least four conductor tracks, with each current busbar 21, 22.1, 22.2, 22.3 being connected to a separate conductor track.
- the electrical lines 26 are designed, for example, as tungsten wires with a diameter of 150 pm.
- part of the second surface electrode 15 is electrically insulated from the rest of the second surface electrode 15 by an insulation line 16.
- the insulation line 16 divides the second surface electrode 15 into an active region, which acts as the actual surface electrode and is divided into three independent segments 15.1, 15.2, 15.3, and an area insulated from this, which borders the connection region. This reduces the risk of a short circuit, since the part of the second surface electrode 15 bordering the connection region can easily come into contact with the first surface electrode 14 or its busbar 21.
- the insulation line 16 is introduced into the second surface electrode 15 by laser radiation and has a line width of, for example, 100 pm. Since the functional element 10 is subjected to a laser process to produce the insulation lines 15' anyway, producing the insulation line 16 only involves a small amount of additional effort.
- Figure 5 shows a top view of the functional element 10 in a further embodiment of the composite pane according to the invention.
- the functional element 10 is basically constructed in the same way as in the embodiment of Figures 2 and 3.
- the connection area is not arranged adjacent to the lower side section, but in a central area of the functional element 10.
- the functional element is divided by the connection area into two switching areas in which the optical properties can be electrically controlled. In the switching areas, the carrier foils 12, 13, the surface electrodes 14, 15 and the active layer 11 are completely present.
- the second surface electrode 15 is divided by the connection area into two electrode segments 15.1, 15.2.
- the second The contact area is divided into two sections. Each electrode segment 15.1, 15.2 is provided with a current busbar 22.1, 22.2 in the second contact area, which in turn is connected to the ribbon conductor 27 via an electrical contact element 25.1, 25.2 and an electrical line 26 connected to it.
- the ribbon conductor 27 has at least three conductor tracks, with each current busbar 21, 22.1, 22.2 being connected to a separate conductor track.
- an intermediate region is again arranged in which the first carrier film 12, the first surface electrode 14 and the active layer 11 are not removed.
- an insulation line 16 is again arranged, which divides the respective section of the second surface electrode 15 into an active section and a section insulated from it and adjacent to the connection region, which serves to prevent short circuits in the connection region.
- Figure 6 shows a top view of the functional element 10 in a conventional design of a generic composite pane.
- the functional element 10 is divided into three independent switching areas.
- the electrical connection is made via electrical lines 26, which extend from the respective busbar over the side edge of the composite pane.
- the busbar 21 of the first surface electrode 14 is connected on the left side of the functional element 10, and the busbars 22.1, 22.2, 22.3 are connected on the right side of the functional element 10.
- the lines 26 should leave the composite pane at approximately the same point, since they are typically combined with a common plug connector in order to connect them to the voltage source, the line 26 of the busbar 21 is routed around the functional element 10. Longer lines 26 are therefore required than in the design according to the invention, and laying them takes more time.
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Abstract
Description
Claims
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP23156715 | 2023-02-15 | ||
| PCT/EP2024/051010 WO2024170192A1 (de) | 2023-02-15 | 2024-01-17 | Verbundscheibe mit elektrisch steuerbaren optischen eigenschaften |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| EP4665574A1 true EP4665574A1 (de) | 2025-12-24 |
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| EP24701556.3A Pending EP4665574A1 (de) | 2023-02-15 | 2024-01-17 | Verbundscheibe mit elektrisch steuerbaren optischen eigenschaften |
Country Status (5)
| Country | Link |
|---|---|
| EP (1) | EP4665574A1 (de) |
| JP (1) | JP2026506058A (de) |
| KR (1) | KR20250138211A (de) |
| CN (1) | CN120693252A (de) |
| WO (1) | WO2024170192A1 (de) |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE19544127C1 (de) | 1995-11-27 | 1997-03-20 | Gimsa Jan Dr | Verfahren und Vorrichtung zur Erzeugung von Resonanzerscheinungen in Partikelsuspensionen und ihre Verwendung |
| DE10043141A1 (de) | 2000-08-31 | 2002-03-21 | Webasto Vehicle Sys Int Gmbh | Fahrzeugscheiben-System mit veränderbarer Lichtdurchlässigkeit |
| DE102005007427A1 (de) | 2005-02-18 | 2006-08-31 | Volkswagen Ag | Elektrische Sonnenblende für ein Kraftfahrzeug |
| DE102005049081B3 (de) | 2005-10-13 | 2007-06-06 | Webasto Ag | Schichtanordnung zur Abdunklung einer transparenten Scheibe |
| FR2901891B1 (fr) | 2006-05-30 | 2008-09-26 | Schefenacker Vision Systems Fr | Cellule electrochrome, son utilisation dans la realisation d'une vitre ou d'un retroviseur et son procede de realisation. |
| DE102007027296A1 (de) | 2007-06-11 | 2008-12-18 | Volkswagen Ag | Automatische Sonnenblende für ein Kraftfahrzeug |
| DE102008026339A1 (de) | 2008-05-31 | 2009-12-03 | Saint-Gobain Sekurit Deutschland Gmbh & Co. Kg | Elektrisch schaltbares Sichtschutzfenster |
| PT104635A (pt) | 2009-06-16 | 2010-12-16 | Univ Nova De Lisboa | Dispositivo electrocrómico e método para a sua produção |
| GB0916379D0 (en) | 2009-09-18 | 2009-10-28 | Pilkington Group Ltd | Laminated glazing |
| FR2962818B1 (fr) | 2010-07-13 | 2013-03-08 | Saint Gobain | Dispositif electrochimique a proprietes de transmission optique et/ou energetique electrocommandables. |
| US8164818B2 (en) | 2010-11-08 | 2012-04-24 | Soladigm, Inc. | Electrochromic window fabrication methods |
| DE102013001334A1 (de) | 2013-01-26 | 2014-07-31 | Audi Ag | Verfahren zum Betreiben einer Fensterscheibe eines Kraftwagens sowie Kraftwagen mit einer solchen Fensterscheibe |
| EP3456913B1 (de) | 2017-09-19 | 2022-09-07 | Ford Global Technologies, LLC | Bionische sonnenschutzvorrichtung |
| DE202018102520U1 (de) | 2018-05-07 | 2018-05-24 | Saint-Gobain Glass France | Verbundscheibe mit einem Funktionselement |
-
2024
- 2024-01-17 EP EP24701556.3A patent/EP4665574A1/de active Pending
- 2024-01-17 WO PCT/EP2024/051010 patent/WO2024170192A1/de not_active Ceased
- 2024-01-17 JP JP2025546938A patent/JP2026506058A/ja active Pending
- 2024-01-17 KR KR1020257027029A patent/KR20250138211A/ko active Pending
- 2024-01-17 CN CN202480013115.6A patent/CN120693252A/zh active Pending
Also Published As
| Publication number | Publication date |
|---|---|
| WO2024170192A1 (de) | 2024-08-22 |
| KR20250138211A (ko) | 2025-09-19 |
| CN120693252A (zh) | 2025-09-23 |
| JP2026506058A (ja) | 2026-02-20 |
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