EP4643057A1 - Systeme de combustion apte a fonctionner avec un recyclage des fumees de combustion - Google Patents
Systeme de combustion apte a fonctionner avec un recyclage des fumees de combustionInfo
- Publication number
- EP4643057A1 EP4643057A1 EP23841513.7A EP23841513A EP4643057A1 EP 4643057 A1 EP4643057 A1 EP 4643057A1 EP 23841513 A EP23841513 A EP 23841513A EP 4643057 A1 EP4643057 A1 EP 4643057A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- combustion
- recycling
- dioxygen
- combustion system
- compressor
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23N—REGULATING OR CONTROLLING COMBUSTION
- F23N5/00—Systems for controlling combustion
- F23N5/18—Systems for controlling combustion using detectors sensitive to rate of flow of air or fuel
- F23N5/184—Systems for controlling combustion using detectors sensitive to rate of flow of air or fuel using electronic means
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23C—METHODS OR APPARATUS FOR COMBUSTION USING FLUID FUEL OR SOLID FUEL SUSPENDED IN A CARRIER GAS OR AIR
- F23C9/00—Combustion apparatus characterised by arrangements for returning combustion products or flue gases to the combustion chamber
- F23C9/08—Combustion apparatus characterised by arrangements for returning combustion products or flue gases to the combustion chamber for reducing temperature in combustion chamber, e.g. for protecting walls of combustion chamber
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23L—SUPPLYING AIR OR NON-COMBUSTIBLE LIQUIDS OR GASES TO COMBUSTION APPARATUS IN GENERAL ; VALVES OR DAMPERS SPECIALLY ADAPTED FOR CONTROLLING AIR SUPPLY OR DRAUGHT IN COMBUSTION APPARATUS; INDUCING DRAUGHT IN COMBUSTION APPARATUS; TOPS FOR CHIMNEYS OR VENTILATING SHAFTS; TERMINALS FOR FLUES
- F23L5/00—Blast-producing apparatus before the fire
- F23L5/02—Arrangements of fans or blowers
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23L—SUPPLYING AIR OR NON-COMBUSTIBLE LIQUIDS OR GASES TO COMBUSTION APPARATUS IN GENERAL ; VALVES OR DAMPERS SPECIALLY ADAPTED FOR CONTROLLING AIR SUPPLY OR DRAUGHT IN COMBUSTION APPARATUS; INDUCING DRAUGHT IN COMBUSTION APPARATUS; TOPS FOR CHIMNEYS OR VENTILATING SHAFTS; TERMINALS FOR FLUES
- F23L7/00—Supplying non-combustible liquids or gases, other than air, to the fire, e.g. oxygen, steam
- F23L7/007—Supplying oxygen or oxygen-enriched air
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23N—REGULATING OR CONTROLLING COMBUSTION
- F23N3/00—Regulating air supply or draught
- F23N3/002—Regulating air supply or draught using electronic means
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23C—METHODS OR APPARATUS FOR COMBUSTION USING FLUID FUEL OR SOLID FUEL SUSPENDED IN A CARRIER GAS OR AIR
- F23C2202/00—Fluegas recirculation
- F23C2202/30—Premixing fluegas with combustion air
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23C—METHODS OR APPARATUS FOR COMBUSTION USING FLUID FUEL OR SOLID FUEL SUSPENDED IN A CARRIER GAS OR AIR
- F23C2202/00—Fluegas recirculation
- F23C2202/50—Control of recirculation rate
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23J—REMOVAL OR TREATMENT OF COMBUSTION PRODUCTS OR COMBUSTION RESIDUES; FLUES
- F23J2215/00—Preventing emissions
- F23J2215/50—Carbon dioxide
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23L—SUPPLYING AIR OR NON-COMBUSTIBLE LIQUIDS OR GASES TO COMBUSTION APPARATUS IN GENERAL ; VALVES OR DAMPERS SPECIALLY ADAPTED FOR CONTROLLING AIR SUPPLY OR DRAUGHT IN COMBUSTION APPARATUS; INDUCING DRAUGHT IN COMBUSTION APPARATUS; TOPS FOR CHIMNEYS OR VENTILATING SHAFTS; TERMINALS FOR FLUES
- F23L2900/00—Special arrangements for supplying or treating air or oxidant for combustion; Injecting inert gas, water or steam into the combustion chamber
- F23L2900/07001—Injecting synthetic air, i.e. a combustion supporting mixture made of pure oxygen and an inert gas, e.g. nitrogen or recycled fumes
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23L—SUPPLYING AIR OR NON-COMBUSTIBLE LIQUIDS OR GASES TO COMBUSTION APPARATUS IN GENERAL ; VALVES OR DAMPERS SPECIALLY ADAPTED FOR CONTROLLING AIR SUPPLY OR DRAUGHT IN COMBUSTION APPARATUS; INDUCING DRAUGHT IN COMBUSTION APPARATUS; TOPS FOR CHIMNEYS OR VENTILATING SHAFTS; TERMINALS FOR FLUES
- F23L2900/00—Special arrangements for supplying or treating air or oxidant for combustion; Injecting inert gas, water or steam into the combustion chamber
- F23L2900/07005—Injecting pure oxygen or oxygen enriched air
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23L—SUPPLYING AIR OR NON-COMBUSTIBLE LIQUIDS OR GASES TO COMBUSTION APPARATUS IN GENERAL ; VALVES OR DAMPERS SPECIALLY ADAPTED FOR CONTROLLING AIR SUPPLY OR DRAUGHT IN COMBUSTION APPARATUS; INDUCING DRAUGHT IN COMBUSTION APPARATUS; TOPS FOR CHIMNEYS OR VENTILATING SHAFTS; TERMINALS FOR FLUES
- F23L2900/00—Special arrangements for supplying or treating air or oxidant for combustion; Injecting inert gas, water or steam into the combustion chamber
- F23L2900/07006—Control of the oxygen supply
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23L—SUPPLYING AIR OR NON-COMBUSTIBLE LIQUIDS OR GASES TO COMBUSTION APPARATUS IN GENERAL ; VALVES OR DAMPERS SPECIALLY ADAPTED FOR CONTROLLING AIR SUPPLY OR DRAUGHT IN COMBUSTION APPARATUS; INDUCING DRAUGHT IN COMBUSTION APPARATUS; TOPS FOR CHIMNEYS OR VENTILATING SHAFTS; TERMINALS FOR FLUES
- F23L2900/00—Special arrangements for supplying or treating air or oxidant for combustion; Injecting inert gas, water or steam into the combustion chamber
- F23L2900/07007—Special arrangements for supplying or treating air or oxidant for combustion; Injecting inert gas, water or steam into the combustion chamber using specific ranges of oxygen percentage
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E20/00—Combustion technologies with mitigation potential
- Y02E20/34—Indirect CO2mitigation, i.e. by acting on non CO2directly related matters of the process, e.g. pre-heating or heat recovery
Definitions
- the present invention relates to the field of combustion with recycling of at least part of the combustion fumes.
- So-called “classic” combustion consists of mixing air (oxidant) with a fuel in a combustion installation (oven, boiler, etc.) under high temperature conditions to create oxidation. The reaction is exothermic and maintains itself naturally.
- the air contains 21% oxygen (O2) and the volume of air used is controlled so that the quantity of oxygen is sufficient for combustion.
- combustion fumes include water vapor (H2O) and combustion products in the gas phase, including mainly dinitrogen (N2) in the gas phase, and carbon dioxide (CO2) in the gas phase.
- H2O water vapor
- N2 dinitrogen
- CO2 carbon dioxide
- combustion gas refers to combustion products in the gas phase which are released after combustion.
- combustion In which the air (oxidizer) is replaced by dioxygen in stoichiometric proportions, the number of oxygen atoms being equal to that necessary to oxidize all the atoms of the fuel.
- dioxygen to implement oxycombustion can for example be obtained in a known manner by cryogenics or by electrolysis of water.
- combustion fumes are produced consisting of 1/3 CO2 in the gas phase and 2/3 water vapor by volume.
- pollutants from combustion such as HCl, SOx, etc. If the fuel is not nitrogenous, advantageously the fumes will naturally not contain NOx.
- the reactions are similar, with the appearance of other compounds if the fuel contains atoms other than carbon and hydrogen.
- This improvement allows oxycombustion based on dioxygen with recycling of combustion fumes that is more easily controlled, compared to oxycombustion using only dioxygen as an oxidizer, while reducing the emission of pollutants compared to conventional combustion and facilitating where applicable, CO2 capture.
- start-up and shutdown procedures of these installations are critical and risky operating phases and can detrimentally lead to oxycombustion temperatures, with recycling of combustion fumes, which are uncontrolled and too high in the combustion chamber.
- the main objective of the invention is to propose a combustion system which can operate with recycling of at least part of the combustion fumes, but which makes it possible to overcome all or part of the above-mentioned disadvantages inherent in oxycombustion installations of the art. prior art which implements such recycling of combustion fumes.
- the subject of the invention is thus a combustion system comprising a combustion device allowing the combustion of a fuel by means of at least one oxidizing gas and comprising an outlet through which it rejects combustion fumes, a supply unit in oxidizing gas which is connected to the combustion device and makes it possible to supply the combustion device with oxidizing gas, said oxidizing gas supply unit comprising a mixer and a source of gaseous dioxygen which supplies a gas rich in dioxygen and which is connected to a first inlet of the mixer, a main evacuation circuit connected to the outlet of the combustion device and opening into the open air, recycling means which comprise a recycling loop between the main evacuation circuit and a second mixer inlet, at least one recycling fan or compressor mounted on the recycling loop and adapted to circulate a gaseous fluid in the recycling loop towards the second mixer inlet from a connection of the recycling loop with the circuit main evacuation, a bypass which is connected to the recycling loop downstream of the recycling fan or compressor (that is to say between the recycling fan or compressor and the second inlet of the mixer)
- Said bypass at least allows the mixer to be supplied with air entering the bypass.
- the control unit is adapted to control the recycling fan or compressor so as to be able to configure the combustion system in an operating mode chosen from at least two different operating modes (M1; M2) and to be able to switch from one operating mode to another: a first operating mode (M1) in which the fan or recycling compressor is stopped and the mixer is not supplied with gas rich in dioxygen from the source of gaseous dioxygen and is supplied by air entering the bypass, and a second operating mode (M2), in which the recycling fan or compressor operates, and the mixer is supplied with at least gas rich in dioxygen supplied by the source of gaseous oxygen and with at least part of the combustion fumes rejected by the combustion device.
- M1 operating mode chosen from at least two different operating modes
- M2 second operating mode
- the mixer is supplied at least with air sucked in via the bypass and all of the combustion fumes emitted by the combustion device are evacuated into the open air, possibly after having been treated, without being recycled.
- the oxidizing gas contains at least air and does not contain dioxygen coming from the source of gaseous dioxygen. Combustion in the combustion device is thus conventional combustion.
- the oxidizing gas preferably consists solely of air.
- the oxidant gas contains at least gas rich in dioxygen coming from the source of gaseous dioxygen and at least part of the combustion fumes which has been recycled and which has preferably been treated ( before recycling or in the recycling loop), in particular by preferably being at least dehumidified.
- combustion in the combustion device is oxycombustion type with recycling of at least part of the combustion fumes.
- the oxidizing gas in a particular operating phase, subsequently designated “degraded oxycombustion”, may include air, which has been sucked into the ambient air via the bypass.
- the oxidizing gas does not contain air sucked into the ambient air via the bypass.
- the combustion device may be a common combustion device on the market or a particular combustion device which has been developed in a specific manner.
- This combustion device can have air inlets at different injection points depending on the need for combustion.
- the invention can more particularly be implemented without it being necessary to make any modification to this combustion device.
- combustion system of the invention may include the following additional and optional characteristics, taken individually, or in combination with each other:
- the combustion system further comprises at least one sensor which is adapted to at least measure the flow rate or the pressure of gaseous fluid leaving in the downstream part of the main evacuation circuit located downstream of the connection of the recycling loop with the main evacuation circuit and which delivers a pressure or flow measurement signal processed by the control unit.
- the combustion system further comprises at least one sensor 60 which is adapted to at least measure the flow rate or the pressure of gaseous fluid leaving in the bypass 6, and which delivers a pressure or flow measurement signal processed by the unit control.
- the control unit is suitable for controlling the fan or recycling compressor as a function of at least the flow rate or the pressure measured by said sensor during at least one operating mode with recycling of at least part of the combustion fumes.
- the control unit is adapted to control at least the fan or recycling compressor, and where appropriate the device for controlling the flow rate of the gas rich in dioxygen, so as to be able to switch from one operating mode (M1 or M2 ) to the other (M2 or M1) without stopping combustion in the combustion device.
- the source of gaseous dioxygen is connected to said first inlet of the mixer via a device for controlling the flow rate of the gas rich in dioxygen which is controlled by the control unit, and preferably which comprises a flow control valve which is controlled by the control unit.
- the flow control valve is a progressive opening and closing valve.
- the combustion system comprises at least one sensor adapted to measure the concentration of dioxygen in the oxidizing gas and the control unit is adapted to control the device for controlling the flow rate of the gas rich in dioxygen as a function of the measured dioxygen concentration by this sensor (at least during an operating mode (M2) with recycling of at least part of the combustion fumes.
- M2 operating mode
- the combustion device comprises a fan or compressor adapted to supply the combustion device with oxidant gas with a given flow rate (GC), which is preferably variable.
- GC flow rate
- the flow rate of fuel supply to the combustion device is variable and the combustion device comprises a fan or compressor adapted to supply the combustion device with oxidizing gas with a flow rate (GC) which varies as a function of the supply flow rate of the fuel combustion device.
- the combustion system includes a combustion fume treatment device which is mounted on the main evacuation circuit.
- the combustion system includes a device for treating recycled combustion fumes which is mounted on the recycling loop preferably between the recycling fan or compressor and the connection of the recycling loop with the main evacuation circuit.
- the treatment device is suitable for dehumidifying combustion fumes.
- the treatment device includes a condenser.
- the condenser comprises at least one exchanger comprising a cooling liquid.
- the exchanger comprises a bath of cooling liquid, and injection means making it possible to pass the gaseous fluid (to be dehumidified through this bath of cooling liquid (L), and preferably the injection means make it possible to inject the gaseous fluid to be dehumidified below the surface of this coolant liquid bath.
- the treatment device is suitable for cleaning up combustion fumes and more particularly for capturing one or more pollutants chosen from the following list: fine particles, SOx, NOx, acids, heavy metals, ammonia, VOCs.
- the combustion system comprises at least one sensor adapted to measure the concentration of dioxygen in the oxidizing gas and the control unit is adapted to control the device for controlling the flow rate of the gas rich in dioxygen and the recycling fan or compressor, as a function of the measured concentration of dioxygen in the oxidant gas, and preferably so as to move from an operating mode (M2) with recycling of at least part of the combustion fumes to an operating mode (M1) without recycling of combustion fumes.
- M2 operating mode
- the combustion system comprises a carbon dioxide (CO2) capture device, which is connected to the bypass and which is adapted to capture the carbon dioxide (CO2) in at least part of the outgoing recycled combustion fumes evacuated via said diversion and/or comprising a carbon dioxide (CO2) capture device, which is connected to the downstream part of the main evacuation circuit located downstream of the connection of the recycling loop with the main evacuation circuit and which is adapted to capture carbon dioxide (CO2) in at least part of the outgoing non-recycled combustion fumes evacuated via said downstream part of the main evacuation circuit.
- CO2 carbon dioxide
- the dioxygen-rich gas supplied by the source of gaseous dioxygen contains at least 50% dioxygen, preferably at least 80% dioxygen, and even more preferably at least 90% dioxygen.
- the dioxygen-rich gas supplied by the gaseous dioxygen source is pure or almost pure dioxygen.
- the combustion system comprises a carbon dioxide injection device connected to an inlet of the mixer and adapted to inject gaseous carbon dioxide (CO2) into the mixer during a particular phase ("degraded oxycombustion") of the mode operating mode (M2) with recycling of combustion fumes.
- CO2 gaseous carbon dioxide
- FIG. 1 is a schematic representation of a first particular variant of realization of a combustion system of the invention.
- Figure 2 represents the combustion system of Figure 1 in the first in operating mode M1 (“conventional combustion”);
- Figure 3 represents the combustion system of Figure 1 in the second operating mode M2 (“oxycombustion with recycling”) and in a particular operating phase (“degraded oxycombustion”).
- FIG. 5 is a schematic representation of a second particular embodiment of a combustion system of the invention.
- Figure 6 represents the combustion system of Figure 5 in the first in operating mode M1 (“conventional combustion”);
- Figure 7 represents the combustion system of Figure 5 in the second operating mode M2 (“oxycombustion with recycling”) and in a particular operating phase (“degraded oxycombustion”).
- FIG. 8 represents the combustion system of Figure 5 in the second operating mode M2 (“oxycombustion with recycling”) and in another particular operating phase (“improved oxycombustion”).
- FIG. 9 to 13 are schematic representations of five other particular embodiments of a combustion system of the invention.
- FIG. 14 represents a particular example of a condenser that can be implemented in a combustion system of the invention.
- FIG. 1 shows schematically a first alternative embodiment of a combustion system of the invention comprising:
- a combustion device 1 which is supplied with an oxidizing gas GC coming from an oxidizing gas supply unit 3 and with a fuel C coming from a fuel source 2 and which, in operation, rejects through an outlet 1a FC combustion fumes;
- main circuit 5 for evacuating at least part of the combustion fumes emitted by the combustion device 1, which main evacuation circuit 5 is connected at one end to the outlet 1a of the combustion device 1 and opens to its end opposite to free air (at atmospheric pressure) in the ambient air; this main evacuation circuit 5 comprises more particularly an evacuation chimney 50 opening into the open air;
- - recycling means 4 which comprise a recycling loop 40 connecting the main evacuation circuit 5 to an inlet of the oxidant gas supply unit 3 GC and a recycling fan VR, which is mounted on the loop recycling 40; the recycling fan VR allows in operation to forcefully circulate a gaseous fluid in the recycling loop 40 from the connection 40a of the recycling loop 40 with the main evacuation circuit 5 and towards the unit 3 d GC oxidant gas supply;
- connection 40b to the recycling loop 40 downstream of the recycling fan VR and which opens into the open air at atmospheric pressure into the ambient air;
- At least one sensor 51 adapted to at least measure the pressure or flow rate of the outgoing gaseous fluid which is evacuated to the open air via the downstream part 5b of the main evacuation circuit 5 located downstream of the connection 40a of the recycling loop 40 with the main evacuation circuit 5.
- the sensor 51 can for example be mounted in a pipe between the connection 40a of the recycling loop 40 with the main evacuation circuit 5 and the evacuation chimney 50, as illustrated in FIG. 1, or can be mounted directly into the exhaust chimney 50.
- control unit 7 is adapted to control at least the recycling fan VR as a function of at least the flow rate or the pressure measured by said sensor 51 (detection signal S51 delivered by the sensor), as will be detailed later.
- the control unit 7 can be implemented in various forms, and can for example be produced by means of a programmable electronic control unit, for example of the programmable automaton type or a programmable electronic circuit comprising a microprocessor, a microcontroller or programmable logic circuits of the FPGA type, or can also be produced by means of a specific integrated electronic circuit of the ASIC type.
- a programmable electronic control unit for example of the programmable automaton type or a programmable electronic circuit comprising a microprocessor, a microcontroller or programmable logic circuits of the FPGA type, or can also be produced by means of a specific integrated electronic circuit of the ASIC type.
- Bypass 6 can consist of a simple pipe connected at one end to the recycling loop 40 and opening directly into the open air (at atmospheric pressure) at its other end. In its simplest version, this second branch 6 can also be a simple opening allowing the recycling loop 40 to communicate with the ambient air.
- the VR recirculation fan can be replaced with an air compressor.
- the combustion device 1 generally makes it possible to carry out combustion of the fuel C by means of said oxidant gas GC, the thermal energy resulting from this combustion being able, according to the invention, to be used in any type of application requiring a contribution thermal, and for example and in a non-limiting manner to heat a fluid in a heating installation or to supply an industrial production line with energy, in particular thermal, mechanical or electrical.
- This combustion device 1 can either, according to the invention, comprise a conventional boiler, an oven, or a combustion chamber in which a combustion process is implemented.
- the combustion device 1 usually comprises a fan (or compressor) 10 which makes it possible to pull or push the oxidizing gas GC into the combustion installation 1, with automatic adjustment or regulation of the flow rate 0GC of oxidizing gas GC entering the combustion device 1. the combustion device 1 to adapt to the flow rate of the fuel C and satisfy the thermal energy needs.
- a fan or compressor
- the combustion device 1 can be a common combustion device on the market or a particular combustion device which has been developed in a specific manner.
- the combustion reaction of fuel C using the oxidizing gas GC produces combustion fumes FC whose composition depends on the fuel C and the oxidizing gas GC.
- the fuel C can be very different from one application to another and can, depending on the case, be in solid, liquid or gaseous form.
- the source 30 of gaseous dioxygen makes it possible to provide a gas rich in dioxygen, that is to say a gas containing at least 40% (volume percentage) of dioxygen.
- the gas rich in dioxygen can advantageously, but not necessarily, consist of pure or almost pure dioxygen (volume concentration greater than 90%).
- the source 30 of gaseous dioxygen can be of any known type and can for example comprise a unit for producing gaseous dioxygen by cryogenics and/or a unit for producing gaseous dioxygen by electrolysis of water.
- the source 30 of gaseous dioxygen can also be a unit for producing a gas rich in dioxygen containing at least 40% of dioxygen obtained by suitable filtration of air using zeolites or equivalent.
- the source 30 of gaseous dioxygen may also not be designed to produce the dioxygen-rich gas in situ, but may simply include a means of storing the dioxygen-rich gas which will have been previously produced on another site.
- the flow control device 32 can simply stop or allow the gas rich in dioxygen coming from the source 30 to pass.
- this flow control device 32 makes it possible to stop the gas rich in dioxygen coming from the source 30 or to let the gas rich in dioxygen coming from the source 30 pass while allowing adjustment, by the control unit 7, of the gas flow at the inlet of the mixer 31.
- the source 30 of gaseous oxygen supplies for example the mixer 31 with a constant pressure and the device 32 for controlling the flow at the inlet of the mixer 31 comprises a valve V1, preferably one solenoid valve, which is controlled by the control unit 7.
- this valve V1 is a progressive opening and closing valve.
- the flow control device 32 at the inlet of the mixer 31 may also include a system for controlling the gas pressure at the outlet of the source 30 possibly associated with a valve which may be an on-off valve. or a valve with progressive opening and closing, the pressure control system and said valve being controlled by the control unit 7.
- the oxidant gas supply unit 3 GC also comprises at least one sensor 33, which measures the dioxygen concentration in the oxidizing gas GC entering the combustion device 1 and which delivers to the control unit 7 a signal S for measuring this concentration.
- this device 8 for treating FC combustion fumes preferably comprises a condenser, which is adapted to condense the FC combustion fumes emitted by the combustion installation 1 by cooling them.
- the condenser of the treatment device 8 can generally comprise any type of exchanger allowing, by any means, to cool the FC combustion fumes so as to produce condensation of at least part of the steam. of water contained in the combustion fumes F.
- FC' dehumidified combustion fumes FC' (rich in CO2) containing mainly the combustion products in the gas phase produced by combustion in the combustion device 1, and having an absolute humidity lower than that of the combustion fumes FC at the inlet of the treatment device 8.
- This device 8 for treating combustion fumes can also be adapted to clean up combustion fumes and preferably to capture one or more pollutants chosen from the following list: fine particles, SOx, NOx, acids, heavy metals, ammonia, VOCs.
- pollutants chosen from the following list: fine particles, SOx, NOx, acids, heavy metals, ammonia, VOCs.
- FC' rich in CO2
- the installation may be devoid of treatment device 8 or the treatment device 8 may be devoid of means of dehumidifying combustion fumes and only comprising means of depolluting combustion fumes.
- the installation preferably comprises a treatment device, which is mounted on the recycling loop 40 downstream or preferably upstream of the recycling fan or compressor VR, and which is adapted to treat the recycled combustion fumes in the recycling loop 40 in order to at least dehumidify them.
- the control unit 7 makes it possible to automatically control the fan or recycling compressor VR and the oxidizing gas supply unit 3 GC, and more particularly in this variant the flow control device 32, by means respectively of the control signals. controls C2 and C1, generally so as to control the composition of the oxidizing gas GC.
- control unit 7 makes it possible to automatically control the recycling fan or compressor VR and the oxidant gas supply unit 3 GC so as to advantageously allow the installation to operate in an operating mode chosen from among at least two different operating modes (M1 and M2) detailed below and allow switching from one operating mode (M1 or M2) to another (M2 or M1).
- M1 and M2 different operating modes
- the combustion system of Figure 1 can be configured by the control unit 7 to operate in at least two different main operating modes:
- M2 ( Figures 3 and 4): an operating mode called “oxycombustion with recycling” in which the recycling fan or compressor VR operates and is controlled by the control unit 7 and valve V1 of flow control device 32 is open (O).
- the transition from one operating mode (M1 or M2) to another (M2 or M1) can be controlled by the control unit 7 simply by appropriately controlling the recycling fan or compressor VR, and the control device. flow control 32 (more particularly valve V1).
- the transition from one mode (M1 or M2) of operation to another (M2 or M1) can advantageously be carried out without stopping the combustion, and in particular without altering the combustion in the combustion device 1, and without stopping the device combustion 1.
- the dioxygen supply valve V1 coming from source 30 has been closed (F) by the control unit 7 and the recycling fan or compressor VR is stopped.
- the fan 10 (or compressor) of the combustion device 1 operates by imposing a flow rate 0GC of oxidizing gas GC at the inlet of the combustion device 1, which can vary.
- the mixer 31 is not supplied with oxygen coming from the source 30.
- the mixer 31 is supplied only with incoming air which is sucked in via the bypass 6 and which is conveyed to the inlet of the mixer 31. conventional combustion is thus carried out in the combustion installation 1 by means of this incoming air used as oxidizing gas.
- the combustion fumes FC after having been treated (FC') passing through the treatment device 8, do not recirculate to the mixer 31 but are evacuated into the open air into the atmosphere by being pushed by the fan ( or compressor) 10 in the downstream part 5b of the main evacuation circuit 5.
- the recycling loop 40 can also be equipped with smoke stopping dampers, which are controlled by the control unit 7 in operating mode M1 and which are opened by the unit control 7 in the control mode M2 operation (recycling of at least part of the combustion fumes). These dampers can also be operated manually.
- the fan 10 (or compressor) of the combustion installation operates by imposing on the inlet of the installation 1 a given flow rate (GC) of oxidizing gas GC which can vary.
- GC flow rate
- the control unit 7 automatically controls the oxidizing gas supply unit 3 GC, and in particular the flow control device 32, as a function of the dioxygen concentration measured in the oxidizing gas GC by means of the sensor 33 ( signal S), so as to produce a gas having an appropriate level of oxygen (for example fixed by a preferably configurable setpoint) which is required or requested by combustion.
- the control unit 7 also automatically controls the start of the recycling fan or compressor VR and automatically controls this recycling fan or compressor VR, as a function of the pressure or flow rate measured by the sensor 51.
- control unit 7 automatically controls the recycling fan or compressor VR, until the flow rate or pressure measured by this sensor 51 reaches at least one predefined and preferably configurable operating setpoint, and automatically regulates the flow rate of this fan or recycling compressor VR so as to maintain said pressure or said flow rate measured by the sensor 51 at this operating setpoint or in the vicinity of this operating setpoint.
- This operating instruction is set in such a way that the flow rate of the fan or recycling compressor VR is lower than the flow rate of the combustion fumes FC at the outlet of the treatment device 8 or, in the absence of treatment device 8, at the outlet of the combustion device 1, so as to recycle to the mixer 31 at least one part FC2 of the combustion fumes, the other part FC1 being evacuated into the open air into the atmosphere via the downstream part 5b of the main evacuation circuit 5.
- This M2 operating mode has in practice two operating phases:
- the mixer 31 is also supplied with air which is sucked into the ambient air, via the bypass 6, with an incoming air flow 0AIR and which is routed to the mixer 31, via the portion of the loop of recycling 40 downstream of the connection 40a of the bypass 6 with the recycling loop 40, at the same time as the combustion fumes FC2.
- the oxidizing gas GC contains dioxygen coming from the dioxygen-rich gas supplied by source 30, the treated and recycled combustion fumes FC2 (rich in CO2) and air.
- the mixer 31 is supplied with dioxygen coming from the dioxygen-rich gas from the source 30 (valve V1 open) with a given flow rate (002) and is supplied with a flow rate 01 with the FC21 part of the combustion fumes treated and recycled FC2; the other part FC22 of the treated and recycled combustion fumes FC2 is evacuated into diversion 6 with a flow rate 02.
- the combustion system in Figure 1 can in particular, but not exclusively, operate with a fuel C producing, in the “improved oxycombustion” operating phase, combustion fumes FC which mainly contain carbon dioxide (CO2) and steam. water (H2O), and to a lesser extent oxygen (O2) and carbon monoxide (CO).
- a fuel C producing, in the “improved oxycombustion” operating phase, combustion fumes FC which mainly contain carbon dioxide (CO2) and steam. water (H2O), and to a lesser extent oxygen (O2) and carbon monoxide (CO).
- the fuel C used in the combustion system of Figure 1 can advantageously be a hydrocarbon of any type, and for example a conventional hydrocarbon derived from petroleum or natural gas or an unconventional hydrocarbon derived from shale gas or oil, shales or tar sands, coal gas, biogas, singaz, etc.
- the fuel can also be a particularly solid or liquid fuel from extraction (coal, wood, etc.) or may contain waste (plastics, recovered materials, etc.)
- the combustion system can advantageously operate without time limit in the M2 operating mode (“oxycombustion with recycling”) and in said “degraded oxycombustion” phase with partial entry of air at least via bypass 6 (and possibly via another secondary air inlet or a secondary oxidizing gas inlet connected directly to the combustion device 1), and a partial discharge into the atmosphere of part FCi of the FC combustion fumes (in the absence of a treatment device 8) or FC' (with treatment device), via the downstream part 5b of the main evacuation circuit 5.
- control unit 7 automatically regulates the flow rate 002 of oxygen (for example in this particular case by closing more or less the progressive valve V1) using the measurement signal S of the dioxygen concentration in the oxidizing gas G.
- the transition from operating mode M1 to operating mode M2 (“oxycombustion with recycling), in the “degraded oxycombustion” phase or in the “improved oxycombustion” operating phase, can be requested from the control unit 7, at the initiative of the user of the combustion system, for example by means a manual operating mode change control.
- operating mode M1 The transition from operating mode M1 to operating mode M2 can also be implemented when starting the combustion system in order to operate it in “oxycombustion with recycling” (M2).
- the control unit 7 executes this start-up procedure by initially configuring the combustion system in operating mode M1 (“conventional combustion”).
- the combustion device 1 is started, in particular by putting into operation at least the fan (or compressor 10) of the combustion device 1, either manually by the user, or in an automated manner for example by the control unit 7, which initially allows the system to operate in conventional combustion (M1).
- M1 conventional combustion
- control unit 7 controls the combustion system, so as to automatically switch to “oxycombustion with recycling” (M2), as previously described, by choosing the operating phase known as “degraded oxycombustion” or the so-called “improved oxycombustion” operating phase.
- M2 oxycombustion with recycling
- Such a startup phase is advantageously simple and secure.
- a combustion system of the prior art which is adapted to operate only in improved oxycombustion mode with recycling of combustion fumes
- the risks of untimely and uncontrolled rise in temperature are avoided during the start-up phase.
- combustion system is configured in M2 operating mode (“oxycombustion with recycling”).
- the combustion device 1 operates, the fan or recycling compressor VR operates and the fan 10 (or compressor) of the combustion installation 1 operates by imposing a given flow rate (GC) of oxidizing gas GC consisting of air to the entrance to installation 1.
- GC flow rate
- control unit 7 To move from this operating mode M2 (“oxycombustion with recycling”) to operating mode M1 (“classic combustion”), the control unit 7 simply needs to control the slowdown until the fan or compressor stops. Recycling VR, then order the closing of valve V1.
- the transition from operating mode M2 to operating mode M1 can be requested from the control unit 7, at the initiative of the user of the combustion system, for example by means of a manual control for changing the mode of operation. functioning.
- the transition from operating mode M2 to operating mode M1 can also be implemented during a procedure to stop the operation of the combustion system.
- the control unit 7 executes this stopping procedure by controlling the slowing down until the recycling fan or compressor VR stops, as previously described, then by controlling the closing of the valve V1 of the device 32 for controlling the flow of gas rich in dioxygen in order to switch from operating mode M2 to operating mode M1.
- the transition from operating mode M2 to operating mode M1 can also be implemented when the concentration of dioxygen (supplied by source 30) in the oxidizing gas GC becomes insufficient and no longer allows improved oxycombustion with recycling of the combustion gas .
- This insufficiency can have several possibly cumulative causes.
- oxygen supply decreases too much. significant, for example due to an untimely slowdown in the in situ production of gas rich in dioxygen by the source 30 or too low a pressure in the source 30.
- combustion device 1 is requested to provide more of thermal energy and to respond to this increases the flow rate GC (increase in the flow rate of the fan or compressor 10) in oxidant gas GC.
- the additional oxidant gas is automatically injected through bypass 6.
- the combustion device 1 reduces the supply of thermal energy, which results in a reduction in the need for the oxidizing gas GC, the excess oxidizing gas is discharged via the bypass 6 and the control system 7 adjusts if necessary the valve V1 to reduce the injection of oxygen into the mixer 31.
- control unit 7 is preferably designed to monitor, by means of the sensor 33, the concentration of dioxygen in the gas oxidizer GC and when the dioxygen concentration decreases, to automatically detect if this dioxygen concentration reaches a predefined and preferably configurable critical minimum threshold, and if so to automatically control the combustion system, so as to switch it (such as previously described) in complete safety in operating mode M1 (“conventional combustion”), without stopping combustion in the combustion device 1.
- the combustion system advantageously comprises a device 11 for capturing carbon dioxide (CO2) connected to branch 6 and adapted to capture carbon dioxide (CO2) in at minus a portion of the outgoing recycled combustion fumes (FC22/ Figure 4) circulating in said bypass 6.
- a device 11 for capturing carbon dioxide (CO2) connected to branch 6 and adapted to capture carbon dioxide (CO2) in at minus a portion of the outgoing recycled combustion fumes (FC22/ Figure 4) circulating in said bypass 6.
- this capture device 11 comprises a fan or compressor 110 which makes it possible to suck up a portion of the outgoing recycled combustion fumes (FC22/ Figure 4) circulating in the bypass 6 and to supply a CO2 capture unit 111 ( known per se).
- this capture device 11 and in particular the fan or compressor 110 is controlled automatically (by the control unit 7 by means of the control signal C3) or by another control unit) as a function of the pressure or of the flow rate of the outgoing combustion fumes circulating in the bypass 6, this pressure or this flow rate being measured by a sensor 60 delivering a measurement signal S ⁇ .
- connection 40a of the recycling loop 40 with the main evacuation circuit 5 is located upstream of the treatment device 8, between the outlet 1a of the combustion device 1 and the inlet of this treatment device 8, and in that an additional treatment device 8' is mounted on the recycling loop 40, preferably upstream of the recycling fan or compressor VR, that is to say between the recycling fan or compressor VR and the connection 40a of the recycling loop 40 with the main circuit of evacuation 5.
- the additional treatment device 8' can be mounted on the recycling loop 40 downstream of the recycling fan or compressor VR.
- the treatment device 8 can be adapted to depollute non-recycled combustion fumes, before their evacuation into the ambient air and preferably to capture one or more pollutants chosen from the following list: fine particles, SOx, NOx, acids, metals heavy, ammonia, VOC.
- the treatment device 8' is preferably adapted to at least dehumidify the combustion fumes recycled in the recycling loop 40 and more particularly comprises at least one condenser or several condensers in cascade.
- the oxidizing gas GC is constituted by the air sucked in by bypass 6 (the valve V1 being closed and the fan or recycling compressor VR being stopped) and the combustion fumes FC are treated in their entirety by passing through the treatment device 8 and are evacuated (FC') into the ambient air.
- the other inlet of the mixer 31 is supplied with dioxygen coming from the dioxygen-rich gas from source 30 (valve V1 open) with a given flow rate (0O 2 ).
- the combustion system of Figure 9 differs from that of Figure 1 in that a condenser 34 has been added.
- This condenser 34 is supplied at the input by the mixer 31 and is connected at the output to the combustion device 1 and supplies the combustion device 1 with the oxidant gas GC.
- the combustion fumes FC are recycled to the mixer 31 without necessarily having been dehumidified in the treatment device 8, dehumidification being carried out at least by the condenser 34.
- the condenser 34 could be mounted in bypass like the treatment device 8 of Figure 12.
- Combustion system of Figure 10 is another variant, the condenser 34 could be mounted in bypass like the treatment device 8 of Figure 12.
- the combustion system of Figure 10 differs from that of Figure 1 mainly in that the control unit 7 is adapted to control the recycling fan or compressor VR) as a function at least of the flow rate or the pressure measured at less by said sensor 60 (and no longer by the sensor 51 as in the variant of Figure 1) during at least the operating mode M2 with recycling of at least part of the combustion fumes.
- the control unit 7 is adapted to control the recycling fan or compressor VR) as a function at least of the flow rate or the pressure measured at less by said sensor 60 (and no longer by the sensor 51 as in the variant of Figure 1) during at least the operating mode M2 with recycling of at least part of the combustion fumes.
- control unit 7 automatically controls the recycling fan or compressor VR, until the flow rate or pressure measured by this sensor 60 reaches at least a predefined and preferably configurable operating setpoint, and automatically regulates the flow rate of the fan or recycling compressor VR so as to maintain said pressure or said flow rate measured at this operating setpoint or in the vicinity of this operating setpoint.
- This operating instruction is set such that the flow rate of the recycling fan or compressor VR is lower than the flow rate of the combustion fumes FC at the outlet of the treatment device 8 or, in the absence of treatment device 8, at the outlet of the combustion device 1, so as to recycle to the mixer 31 at least one part FC2 of the combustion fumes, the other part FC1 being evacuated into the open air in the atmosphere via the downstream part 5b of the main evacuation circuit 5.
- the combustion system advantageously comprises a device 11' for capturing carbon dioxide (CO2) connected to the downstream part 5b of the main evacuation circuit 5 and adapted to capture carbon dioxide (CO2) in at least part of the outgoing combustion fumes FCi.
- a device 11' for capturing carbon dioxide (CO2) connected to the downstream part 5b of the main evacuation circuit 5 and adapted to capture carbon dioxide (CO2) in at least part of the outgoing combustion fumes FCi.
- this capture device comprises a fan or compressor 110 which makes it possible to suck up a portion of FC combustion fumes circulating in the downstream part 5b of the main evacuation circuit 5 and to supply a CO2 capture unit 111 ( known per se).
- this capture device 11' and in particular the fan or compressor 110, is controlled automatically (by the control unit 7 or by another control unit) as a function of the pressure or flow rate of the combustion fumes. circulating in the downstream part 5b of the main evacuation circuit 5, said pressure or said flow rate being measured by the sensor 51.
- the combustion system of Figure 11 differs from that of Figure 10 in that, in a manner comparable to Figure 5, the connection 40a of the recycling loop 40 with the main evacuation circuit 5 is located upstream of the device treatment device 8, between the outlet 1a of the combustion device 1 and the inlet of this treatment device 8, and in that an additional treatment device 8' is mounted on the recycling loop 40, preferably upstream of the recycling fan or compressor VR, that is to say between the recycling fan or compressor VR and the connection 40a of the recycling loop 40 with the main power supply circuit 5.
- the combustion system of Figure 12 differs from that of Figure 1 in that the processing device 8 is mounted as a bypass (“by-pass”) on the main evaluation circuit.
- the treatment device 8 or 8' can also be mounted in bypass (“by-pass") Combustion system of Figure 13 - injection of CCh at start-up
- the combustion system of Figure 13 differs from that of Figure 1 in that it comprises an additional device 12 connected to an inlet of the mixer 31 and allowing gaseous carbon dioxide (CO2) to be injected into the mixer 31 during the “degraded oxycombustion” transient phase during the transition from the second operating mode M2 in the “degraded oxycombustion” phase to the second operating mode M2 in the “improved oxycombustion” phase, in order to shorten the duration of this transient phase.
- CO2 gaseous carbon dioxide
- This CO2 injection device 12 comprises for example a source 120 of gaseous CO2 under pressure associated with a valve or solenoid valve 121 controlled by the control unit 7 by means of a control signal C4.
- This CCh injection device 12 can also be added to the combustion system of Figures 5, 9, 10, 11, 12.
- This condenser comprises an exchanger 12, which comprises an enclosure 120 containing a bath 121 of cooling liquid L and injection means 123, which are adapted to introduce the gaseous fluid F to be dehumidified (i.e. combustion fumes) below the surface of the cooling liquid bath L.
- an exchanger 12 which comprises an enclosure 120 containing a bath 121 of cooling liquid L and injection means 123, which are adapted to introduce the gaseous fluid F to be dehumidified (i.e. combustion fumes) below the surface of the cooling liquid bath L.
- the cooling liquid L can simply be water or an aqueous solution.
- injection means 123 may more particularly comprise a fan or compressor 123f and an injection conduit 123a comprising an inlet opening 123b, for example in its upper part 123c.
- the lower part 123d of the injection conduit 123a is immersed in the bath 121 of cooling liquid L and has an evacuation opening 123e immersed in the bath 121 of cooling liquid L.
- the fan or compressor 123f makes it possible to suck up the gaseous fluid F to be dehumidified and introduce it into the injection conduit 123 through the inlet opening 123b.
- This gaseous fluid F escapes from the injection conduit 123 through the evacuation opening 123e, and is therefore forcibly introduced into the bath 121 of cooling liquid L, below the surface of the bath 121 of cooling liquid L, rises towards the surface of the liquid bath, escapes from the enclosure 120 through the evacuation opening 120a of the enclosure 120 after having been dehumidified in the form of a dehumidified gas F'.
- the temperature TL of the cooling liquid L is always lower than the temperature TF of the gaseous fluid F at the inlet of the exchanger 12 and is preferably lower than the dew point temperature (dew point) of the gaseous fluid F.
- the absolute humidity (g water / kg dry air ] of a gas represents the number of grams of water vapor present in a given volume of gas, relative to the mass of dry gas of this volume expressed in kilogram. Its value remains constant even if the gas temperature varies, but remains higher than the dew point of the gas.
- the gaseous fluid F undergoes condensation in contact with the cooling liquid L, so that the absolute humidity of the gas F', at the outlet of the exchanger 12 is less than the absolute humidity of the gaseous fluid F at the inlet of the exchanger 12.
- the fan or compressor 123f can be connected to the injection conduit 123 and used so as to introduce the gaseous fluid F into this injection conduit 123 by blowing them through the inlet opening 123b of this injection conduit 123.
- the exchanger 12 can more particularly be coupled to a heat pump (not shown) which makes it possible to renew the liquid L in the bath by taking calories from it so as to maintain the temperature of this liquid at a sufficiently low level.
- the invention is not limited to the implementation of an exchanger 12 of the type of that in Figure 14.
- the exchanger 12 for the condensation of the gaseous fluid F can for example be of the type described in international patent application WO201 6/071648 or in international patent application WO2020/030419 or may be an exchanger operating by spraying the cooling liquid L in contact with the gaseous fluid F.
- the invention is not limited to an exchanger operating with a cooling liquid but can be implemented with any other known type of exchanger allowing dehumidification of a gaseous fluid.
- the air flow D (D ⁇ X) at the inlet of the combustion device is defined as a function of the oxygen requirement for combustion and the management of the combustion device (for example management of the flame in the combustion chamber).
- combustion fumes contain:
- the flow rate of the combustion fumes at the outlet of the combustion device which are not recycled and which are rejected directly into the atmosphere and/or which are treated (for example for CO2 capture) before discharge into the atmosphere is advantageously lower than the aforementioned flow rate X.
- the gas rich in dioxygen is pure dioxygen
- the dioxygen-rich gas contains 90% dioxygen, it is possible in practice to recycle the combustion fumes with a significant recycling rate of up to 9/10 of low and which can be of the order of 1/10 of etc.
- the gas rich in dioxygen contains at least 40% dioxygen (below this threshold, the reduction in the flow rate of non-recycled fumes is in practice too low).
- the fraction of gaseous dioxygen in the gas rich in dioxygen is at least 80%, more preferably at least 90%. More particularly, the gas rich in dioxygen is advantageously pure or almost pure gaseous dioxygen (at least 99% O2).
Landscapes
- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Combustion & Propulsion (AREA)
- Mechanical Engineering (AREA)
- General Engineering & Computer Science (AREA)
Abstract
Description
Claims
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR2214633A FR3144645A1 (fr) | 2022-12-29 | 2022-12-29 | Systeme de combustion apte a fonctionner avec un recyclage des fumees de combustion |
| PCT/EP2023/087505 WO2024141436A1 (fr) | 2022-12-29 | 2023-12-21 | Systeme de combustion apte a fonctionner avec un recyclage des fumees de combustion |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| EP4643057A1 true EP4643057A1 (fr) | 2025-11-05 |
Family
ID=85726374
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| EP23841513.7A Pending EP4643057A1 (fr) | 2022-12-29 | 2023-12-21 | Systeme de combustion apte a fonctionner avec un recyclage des fumees de combustion |
Country Status (4)
| Country | Link |
|---|---|
| EP (1) | EP4643057A1 (fr) |
| CN (1) | CN120604080A (fr) |
| FR (1) | FR3144645A1 (fr) |
| WO (1) | WO2024141436A1 (fr) |
Family Cites Families (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR100689788B1 (ko) * | 2005-07-19 | 2007-03-09 | (주)한국환경기술 | 소각로 배기가스를 재순환하여 산소와 혼합 적용한 폐기물소각방법 및 그 장치 |
| US8453585B2 (en) * | 2008-04-14 | 2013-06-04 | Babcock & Wilcox Power Generation Group, Inc. | Oxy-combustion coal fired boiler and method of transitioning between air and oxygen firing |
| WO2011139272A1 (fr) * | 2010-05-05 | 2011-11-10 | Shell Oil Company | Procédés, compositions et systèmes brûleurs pour la réduction des émissions de dioxyde de carbone gazeux dans l'atmosphère |
| US20120125240A1 (en) * | 2010-11-22 | 2012-05-24 | Alstom Technology Ltd. | System and method of managing energy utilized in a flue gas processing system |
| CN112999829A (zh) | 2014-11-06 | 2021-06-22 | 斯塔克拉博公司 | 通过液量产生和处理气体流的装置及使用该装置的设备和方法 |
| FR3084843B1 (fr) | 2018-08-10 | 2022-11-25 | Starklab | Dispositif de mise en contact d'un flux gazeux et d'un flux de liquide |
-
2022
- 2022-12-29 FR FR2214633A patent/FR3144645A1/fr active Pending
-
2023
- 2023-12-21 CN CN202380092805.0A patent/CN120604080A/zh active Pending
- 2023-12-21 WO PCT/EP2023/087505 patent/WO2024141436A1/fr not_active Ceased
- 2023-12-21 EP EP23841513.7A patent/EP4643057A1/fr active Pending
Also Published As
| Publication number | Publication date |
|---|---|
| CN120604080A (zh) | 2025-09-05 |
| WO2024141436A1 (fr) | 2024-07-04 |
| FR3144645A1 (fr) | 2024-07-05 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| EP0012091B1 (fr) | Procédé et installation de traitement de déchets industriels | |
| FR2488678A1 (fr) | Procede et appareil de combustion pour diminuer sensiblement l'emission de composes de l'azote formes pendant la combustion | |
| EP2561295B2 (fr) | Four à flamme et procédé de régulation de la combustion dans un four à flamme | |
| FR2931204A1 (fr) | Reduction catalytique trifonctionnelle a sec des nox d'une turbine a gaz | |
| WO2007034107A2 (fr) | Procede de production de gaz de synthese a l'aide d'un gaz oxygene produit par au moins une turbine a gaz | |
| WO2024141436A1 (fr) | Systeme de combustion apte a fonctionner avec un recyclage des fumees de combustion | |
| EP4537018B1 (fr) | Systeme de combustion apte a fonctionner avec un recyclage du gaz de combustion | |
| FR3136538A1 (fr) | Systeme de combustion apte a fonctionner avec un recyclage du gaz de combustion | |
| JP4829817B2 (ja) | 廃棄物の焼却装置及び焼却方法 | |
| EP4320387A1 (fr) | Systeme de combustion utilisant comme comburant un melange de dioxygene et d'un gaz deshumidifie obtenu a partir des fumees de combustion | |
| FR2721689A1 (fr) | Procédé et incinérateur pour incinérer les déchets hospitaliers et analogues. | |
| EP2175966B1 (fr) | Procede de desoxygenation de fumees d'oxycombustion | |
| WO1996000266A1 (fr) | Procede et dispositif pour traiter a chaud des dechets hospitaliers et analogues | |
| EP1831336A1 (fr) | Procede de gazeification de matieres carbonees et dispositif pour sa mise en oeuvre | |
| EP0336087B1 (fr) | Procédé et installation pour le traitement d'un courant de gaz contenant de la poussière pyrophorique | |
| EP3796990A1 (fr) | Procede de traitement de fumees generees par une combustion de bois et dispositif pour la mise en oeuvre du procede | |
| FR2977928A1 (fr) | Incinerateur de dechets tres energetiques | |
| EP3813992B1 (fr) | Enrichissement en oxygène et combustion d'un combustible en forme de particules solides entraînées par un gaz porteur | |
| EP0837920B1 (fr) | Procede et dispositif pour traiter a chaud des dechets hospitaliers et analogues | |
| FR2916760A1 (fr) | Module, systeme et procede de traitement de biomasse a lit fixe horizontal | |
| FR2958999A1 (fr) | Procede de chauffage d'au moins un fluide | |
| EP4386298A1 (fr) | Systeme de fusion et procede de fusion de dechets d aluminium | |
| BE1012048A3 (fr) | Procede pour epurer des fumees et dispositif pour sa mise en oeuvre. | |
| EP3058278B1 (fr) | Procédé et unité de valorisation énergetique de déchets | |
| WO2025093547A1 (fr) | Procede et installation de traitement de gaz de combustion provenant notamment d'un regenerateur de procede de craquage catalytique en lit fluidise (fcc) opere en mode de combustion partielle |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| STAA | Information on the status of an ep patent application or granted ep patent |
Free format text: STATUS: UNKNOWN |
|
| STAA | Information on the status of an ep patent application or granted ep patent |
Free format text: STATUS: THE INTERNATIONAL PUBLICATION HAS BEEN MADE |
|
| PUAI | Public reference made under article 153(3) epc to a published international application that has entered the european phase |
Free format text: ORIGINAL CODE: 0009012 |
|
| STAA | Information on the status of an ep patent application or granted ep patent |
Free format text: STATUS: REQUEST FOR EXAMINATION WAS MADE |
|
| 17P | Request for examination filed |
Effective date: 20250624 |
|
| AK | Designated contracting states |
Kind code of ref document: A1 Designated state(s): AL AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HR HU IE IS IT LI LT LU LV MC ME MK MT NL NO PL PT RO RS SE SI SK SM TR |
|
| DAX | Request for extension of the european patent (deleted) | ||
| RAV | Requested validation state of the european patent: fee paid |
Extension state: MA Effective date: 20250624 |