Classifications

• • H—ELECTRICITY
  • H01—ELECTRIC ELEMENTS
  • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
  • H01M8/00—Fuel cells; Manufacture thereof
  • H01M8/24—Grouping of fuel cells, e.g. stacking of fuel cells
  • H01M8/249—Grouping of fuel cells, e.g. stacking of fuel cells comprising two or more groupings of fuel cells, e.g. modular assemblies
• • H—ELECTRICITY
  • H01—ELECTRIC ELEMENTS
  • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
  • H01M8/00—Fuel cells; Manufacture thereof
  • H01M8/04—Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids
  • H01M8/04082—Arrangements for control of reactant parameters, e.g. pressure or concentration
  • H01M8/04089—Arrangements for control of reactant parameters, e.g. pressure or concentration of gaseous reactants
• • H—ELECTRICITY
  • H01—ELECTRIC ELEMENTS
  • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
  • H01M8/00—Fuel cells; Manufacture thereof
  • H01M8/04—Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids
  • H01M8/04082—Arrangements for control of reactant parameters, e.g. pressure or concentration
  • H01M8/04201—Reactant storage and supply, e.g. means for feeding, pipes
• • H—ELECTRICITY
  • H01—ELECTRIC ELEMENTS
  • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
  • H01M8/00—Fuel cells; Manufacture thereof
  • H01M8/04—Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids
  • H01M8/04223—Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids during start-up or shut-down; Depolarisation or activation, e.g. purging; Means for short-circuiting defective fuel cells
  • H01M8/04231—Purging of the reactants
• • H—ELECTRICITY
  • H01—ELECTRIC ELEMENTS
  • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
  • H01M8/00—Fuel cells; Manufacture thereof
  • H01M8/04—Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids
  • H01M8/04298—Processes for controlling fuel cells or fuel cell systems
  • H01M8/04313—Processes for controlling fuel cells or fuel cell systems characterised by the detection or assessment of variables; characterised by the detection or assessment of failure or abnormal function
  • H01M8/0438—Pressure; Ambient pressure; Flow
  • H01M8/04425—Pressure; Ambient pressure; Flow at auxiliary devices, e.g. reformers, compressors, burners
• • H—ELECTRICITY
  • H01—ELECTRIC ELEMENTS
  • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
  • H01M8/00—Fuel cells; Manufacture thereof
  • H01M8/04—Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids
  • H01M8/04298—Processes for controlling fuel cells or fuel cell systems
  • H01M8/04694—Processes for controlling fuel cells or fuel cell systems characterised by variables to be controlled
  • H01M8/04746—Pressure; Flow
  • H01M8/04753—Pressure; Flow of fuel cell reactants
• • H—ELECTRICITY
  • H01—ELECTRIC ELEMENTS
  • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
  • H01M8/00—Fuel cells; Manufacture thereof
  • H01M8/24—Grouping of fuel cells, e.g. stacking of fuel cells
  • H01M8/2465—Details of groupings of fuel cells
  • H01M8/2484—Details of groupings of fuel cells characterised by external manifolds
• • H—ELECTRICITY
  • H01—ELECTRIC ELEMENTS
  • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
  • H01M8/00—Fuel cells; Manufacture thereof
  • H01M8/10—Fuel cells with solid electrolytes
  • H01M2008/1095—Fuel cells with polymeric electrolytes

Definitions

• the present invention relates to the field of fuel cells, in particular proton exchange membrane fuel cells (or PEMFC for Proton Exchange Membrane Fuel Cell). It can be implemented to condition or activate a PEFMC, and optimize its performance.
• PEMFC Proton Exchange Membrane Fuel Cell
• a fuel cell is formed from a stack of “unit” electrochemical cells, each comprising an anode and a cathode electrically separated from each other by an electrolyte.
• the fuel hydrogen
• the oxidant oxygen
• the electrolyte can be in the form of a membrane allowing the protons resulting from the hydrogen oxidation reaction to pass through. This is the case for proton exchange membrane fuel cells (PEMFC).
• the stack of cells is only the place of the reaction: the reagents must be there brought in, the products and non-reactive species must be evacuated, just like the heat produced.
• Generally separate fluid circuits make it possible to supply the stack of cells with fuel and oxidizer respectively, and to evacuate the products resulting from the stack.
• the fuel is hydrogen
• the fluidic circuit intended to bring the hydrogen to the anode then comprises one or more expansion stages making it possible to reduce the hydrogen pressure at the inlet of the stack of cells.
• the fluidic circuit may be more complex in the case of particular battery architectures.
• the stack is divided into several groups of cells in fluid connection with each other via their respective outputs.
• the input supply 11, 21 of the different groups 10, 20 is done alternately during certain phases of operation of the battery.
• a first group 10 is supplied at inlet 11 by the combustible fluid (hydrogen) while the supply of a second group 20 is cut off at inlet 21.
• the combustible fluid passes through the first group, which then operates nominally, and exits humidified and slightly depleted at outlet 12 of the first group 10.
• This fluid then supplies the second group 20 via outlet 22 of the second group 20.
• This direct supply to the first group and in the opposite direction to the second group makes it possible to dissipate pockets of fluid strongly depleted formed within the cells of the first group.
• the second group 20 is then supplied at inlet 21 with the combustible fluid while the supply to the first group 10 is cut off at inlet 11.
• the combustible fluid passes through the second group, which then operates nominally, and leaves humidified and slightly depleted. at outlet 22 of the second group 20.
• This fluid then supplies the first group 10 via the outlet 12 of the first group 10.
• This direct supply to the second group and in the opposite direction to the first group also makes it possible to dissipate pockets of highly depleted fluid formed within the cells of the second group during the previous cycle. This prevents cells from the second group from functioning for a prolonged period in the presence of a highly depleted stagnant fluid.
• the principle of this ping-pong architecture consists of alternately supplying the different groups of cells so as to alternate phases of nominal operation with supply phases in the opposite direction.
• the fluidic circuit 3, 4 of such an architecture thus comprises a separate supply line 100, 200 for each group 10, 20 and a switching valve 101v, 201v per supply line 100, 200.
• the fluidic circuit of such a fuel cell is relatively imposing. This increases the overall stack footprint.
• An object of the present invention is therefore to propose a fuel cell having reduced bulk, particularly in terms of the fluidic circuit.
• a fuel cell comprising:
• the fluidic circuit comprises a so-called upstream part comprising:
• a main supply conduit configured to conduct the fluid at a so-called average pressure, and connected to secondary supply lines
• the fluidic circuit comprises a so-called downstream part comprising:
• a second secondary evacuation line connected to the second outlet of the second group, to the main evacuation duct, and to the first outlet of the first group, so as to allow a supply of fluid to the first group via the first outlet, by the fluid having passed through the second group.
• the stack further includes:
• At least one expansion device located in the upstream part of the fluid circuit, configured to reduce the pressure of the fluid coming from the reservoir, from medium pressure to low pressure
• a first switching member on the first secondary supply line configured to authorize or block a flow of fluid towards the first inlet
• a second switching member on the second secondary supply line configured to authorize or block a flow of fluid towards the second inlet
• a purge member on the main evacuation conduit configured to allow or block fluid flow towards the exhaust.
• the at least one expansion member comprises a first expansion member on the main supply conduit, configured to reduce the pressure of the fluid coming from the reservoir, from high pressure to medium pressure.
• the first switching member is formed by a first injector authorizing or blocking the flow of fluid towards the first inlet, and configured to reduce the pressure of the fluid coming from the first expansion member, from medium pressure to a first low pressure .
• the second switching member is formed by a second injector authorizing or blocking the flow of fluid towards the second inlet, and configured to reduce the pressure of the fluid coming from the first expansion member, from medium pressure to a second low pressure .
• the at least one expansion member is formed by the first and second injectors.
• the first and second injectors provide both a role of expanding the fluid, from medium pressure to respectively the first and second low pressures, and both a switching role to authorize or block the flow of the fluid towards respectively the first and second entries of the first and second groups.
• the expansion of the fluid is done in practice by means of two regulators 31, 32 mounted on the main supply conduit 300 successively ensuring a first expansion from the high pressure to medium pressure, then a second expansion from medium pressure to low pressure.
• the section 300a of the main supply conduit increases at the outlet of the first regulator 31 (high pressure - medium pressure), and increases further at the outlet of the second regulator 32 (medium pressure - high pressure). ).
• This increased section 300b is then constant along the secondary supply lines 100, 200 provided with switching valves 101v, 201v.
• the injector could also provide a switching function, a function which is usually assigned to on/off valves. Therefore, instead of replacing the second regulator with an injector as a person skilled in the art could have done, it was decided to remove the second regulator and replace the switching valves on each of the secondary supply lines with injectors. Thus, the number of organs of the fluidic circuit is reduced.
• the energy consumption of the fluidic circuit is also reduced, since it is enough to electrically power a single injector out of the two, alternately, to supply combustible fluid to the fuel cell having the ping-pong architecture according to the invention.
• the classic ping-pong architecture it is necessary to permanently electrically power two organs for relaxation and switching, these functions being carried out separately.
• injectors instead of switching valves, and the elimination of second regulator, also makes it possible to shorten the total length of the circuit having a large section for the circulation of the fluid at low pressure. Indeed, only the fluidic circuit parts located respectively between the first injector and the first inlet, on the first secondary supply line, and between the second injector and the second inlet, on the second secondary supply line, actually require a large section compatible with the flow of combustible fluid at low pressure.
• the total size of the fluidic circuit is further reduced. Due to its reduced size, the injector can also be partially or completely integrated into the cell inlet, which can completely eliminate the need for low pressure pipes.
• these injectors have high operating reliability and improved responsiveness allowing easy adjustment of the set pressure.
• the fuel cell having a ping-pong architecture according to the present invention makes it possible in particular to gain in compactness, to simplify the fuel fluid supply line (hydrogen), and to reduce the energy consumption dedicated to injection of combustible fluid.
• Figure 1 represents a fuel cell having a ping-pong architecture according to the prior art.
• Figure 2A represents a fuel cell having a ping-pong architecture according to a first operating phase, according to a first embodiment of the present invention.
• Figure 2B represents a fuel cell having a ping-pong architecture according to a second operating phase, according to a first embodiment of the present invention.
• Figure 2C represents a fuel cell having a ping-pong architecture according to a third operating phase, according to a first embodiment of the present invention.
• Figure 3 represents a fuel cell having a ping-pong architecture according to a second embodiment of the present invention.
• Figure 4 represents a fuel cell having a ping-pong architecture according to a third embodiment of the present invention.
• the fuel cell system comprises:
• the fluidic circuit comprises a so-called upstream part comprising:
• a main supply conduit configured to be connected to a tank storing the fluid at a pressure P1, called high pressure, and connected to secondary supply lines,
• the fluidic circuit comprises a so-called downstream part comprising:
• the stack further includes:
• At least one expansion member located in the upstream part of the fluid circuit, configured to reduce the pressure of the fluid coming from the reservoir, from high pressure to low pressure
• a first switching member on the first secondary supply line configured to authorize or block a flow of fluid towards the first inlet
• a second switching member on the second secondary supply line configured to authorize or block a flow of fluid towards the second inlet
• a purge member on the main evacuation conduit configured to allow or block fluid flow towards the exhaust.
• the at least one expansion member comprises a first expansion member on the main supply conduit, configured to reduce the pressure of the fluid coming from the reservoir, from high pressure to medium pressure.
• the first switching member is formed by a first injector configured to reduce the pressure of the fluid coming from the first expansion member, from medium pressure to a first low pressure.
• the second switching member is formed by a second injector configured to reduce the pressure of the fluid coming from the first expansion member, from medium pressure to a second low pressure.
• the first and second injectors are pressure regulated respectively by first and second sensors located respectively on the first and second secondary supply lines.
• Each of the injectors is thus connected to its own sensor. This allows independent regulation of the injectors.
• the first and second injectors are pressure regulated by a sensor located in the downstream part of the fluid circuit, for example on the main evacuation conduit, typically between the first and second outlets and the purge member.
• the regulation of the injectors is thus done via a measurement downstream of the battery. This measurement is more representative of the actual pressures within the stack groups. The measurement is thus more reliable and the pressure control can be more precise.
• a single sensor here makes it possible to regulate the injection in the two groups. This minimizes the number of organs present on the fluidic circuit. The compactness of the stack is improved.
• the senor is positioned so that, for given constant supply conditions of the first group or the second group, the sensor measures the same constant pressure.
• the senor is positioned equidistant from the first and second outputs of the first and second groups.
• the battery further comprises a controller configured to control the first and second injectors based on a pressure measurement from the sensor and optionally on a pressure loss model established for the first and second groups of electrochemical cells. This improves the regulation of the first and second injectors.
• a controller configured to control the first and second injectors based on a pressure measurement from the sensor and optionally on a pressure loss model established for the first and second groups of electrochemical cells. This improves the regulation of the first and second injectors.
• a model can take into account parameters complementary to the charge losses, such as for example the temperature of the battery or the current density.
• the fluidic circuit further comprises in the upstream part:
• a third secondary power line in parallel with the first secondary power line, connected to the main power supply conduit and connected to the first input of the first group,
• the stack further comprises:
• a third injector on the third secondary supply line authorizing or blocking the flow of fluid towards the first inlet, and configured to reduce the pressure of the fluid coming from the main supply conduit, from medium pressure to a third low pressure
• a fourth injector on the fourth secondary supply line authorizing or blocking the flow of fluid towards the second inlet, and configured to reduce the pressure of the fluid coming from the main supply conduit, from medium pressure to a fourth low pressure.
• the first and second secondary supply lines are thus doubled or supported by the third and fourth secondary supply lines, respectively.
• the term “parallel” does not necessarily mean that these secondary power lines have parallel structures to each other.
• the term “parallel” does not mean “structurally parallel”. It means that the mounting of these secondary power lines is carried out in parallel. It also means that these secondary power lines are comparable to each other.
• a third secondary power line provided with a third injector allows hardware redundancy with the first secondary power line provided with the first injector.
• a fourth secondary power line provided with a fourth injector allows hardware redundancy with the second secondary power line provided with the second injector. This improves battery reliability. This also makes it possible to extend the range of flow rates accessible for the first and second groups of cells.
• the third and fourth secondary power lines are not necessarily identical to the first and second secondary power lines.
• the third and fourth injectors are not necessarily identical to the first and second injectors. Injectors sized differently from each other, for example a large injector and a small injector in parallel, typically allow the flow range to be swept with fewer pressure oscillations. Two identical injectors in parallel typically make it possible to double the flow range.
• the first, second, third and fourth injectors are pressure regulated by a sensor located on the downstream part of the fluidic circuit, for example on the main evacuation conduit, typically between the first and second outlets and the organ purge. This minimizes the number of organs present on the fluidic circuit. The compactness of the stack is improved.
• the battery further comprises an additional sensor intended to replace the sensor located on the downstream part of the fluidic circuit.
• the additional sensor forms a redundancy with the sensor located on the downstream part of the fluidic circuit. This improves battery reliability.
• the main supply conduit is connected to a first expansion member configured to reduce the pressure of the fluid coming from a reservoir storing the fluid at a so-called high pressure, from high pressure to medium pressure.
• the first expansion member is formed by an injector different from the first and second injectors. This improves the compactness of the fluidic circuit.
• An injector is more compact than a regulator.
• the first expansion member is a simple regulator.
• the secondary supply lines include only one or more injectors with possibly their associated sensors, without switching valves.
• the secondary power lines are directly connected to the main supply conduit and to the inputs of the groups considered.
• a fuel cell according to the present invention comprises at least two groups of electrochemical cells. Those skilled in the art will have no difficulty in implementing an embodiment comprising more than two groups of electrochemical cells.
• the term “ping-pong architecture fuel cell system” means a system comprising at least two groups of electrochemical cells distributed in one or more stacks. Each group is thus made up of a series of electrochemical cells interconnected electrically and fluidically. Cells typically appear in the form of a membrane-electrode assembly commonly referred to as AME.
• the stack here comprises at least five stacked cells, and preferably at least ten.
• the ping-pong architecture battery system typically presents different operating phases, in particular, a first phase during which a first group is supplied directly by a first injector, the second group being supplied only by the gas leaving the first group, a second phase during which the second group is supplied directly by a second injector, the first group being supplied only by the gas leaving the second group, a third phase of simultaneous operation of the first and second groups and/or a purge phase.
• the first and second phases are carried out alternately.
• the third operating phase and/or the purge phase succeeds the first and second phases.
• High pressure is strictly greater than medium pressure.
• Medium pressure is strictly higher than low pressure.
• High pressure is generally above 50 bars, or even above 100 bars.
• High pressure can reach up to 700 bars, or even more depending on conditions.
• An average pressure is generally between 5 and 40 bars, typically between 5 and 20 bars.
• Low pressure is generally less than 4 bars.
• an input or an output of a group of the stack typically each have a structural aspect and a functional aspect.
• the inlet and outlet correspond to first and second passage orifices for the combustible fluid.
• inlet and outlet refer to the admission and discharge of the combustible fluid, respectively.
• the inlet and outlet can be functionally interchanged.
• the first passage orifice can form the inlet or the outlet functionally
• the second passage orifice can form the outlet or the inlet functionally.
• the outlets of the groups are in fluid communication with each other, via the secondary evacuation lines specific to each of the groups.
• Each secondary evacuation line extends between the outlet of the group in question and a common main evacuation duct.
• Each secondary evacuation line can borrow sections of other lines, for example other secondary evacuation lines. Thus, sections of a given secondary evacuation line may be common with sections of other secondary evacuation lines.
• Branch points or branches may be physically present along the secondary evacuation line(s). Organs may also be present along these secondary evacuation lines, for example regulatory organs. All of the secondary evacuation lines can form a pile outlet collector connected to the main pile evacuation conduit.
• the operation of the battery according to the invention is based on a succession of supply and/or evacuation phases that are different from each other.
• the terms “succession” or “successive” do not necessarily imply, even if this is generally preferred, that the phases follow each other immediately, with intermediate phases or stages being able to separate them.
• a direction of circulation of the fluid in the fluid circuit is indicated by an arrow.
• the dotted lines illustrate data connections, typically between sensors and injectors, valves or regulators.
• the illustrated battery system comprises a single battery comprising two groups. It is understood that the description of this battery extends to pile system and all variations in number of piles, groups etc.
• the fuel cell is described and illustrated for a ping-pong architecture comprising two groups of substantially identical cells. It is nevertheless perfectly possible to implement more than two groups and/or groups dimensioned differently, without departing from the general principle of fluidic circuit explained below. Groups can also be distributed into different stacks fluidly connected to each other.
• the original idea implemented in the context of the development of the present invention consists in particular of replacing members ensuring relaxation and switching separately along the fluidic circuit, with a single member ensuring both relaxation and switching, in particularly by an injector. This makes it possible to gain in compactness, responsiveness and reliability.
• a hydrogen injector is typically a solenoid valve sized to obtain opening-closing cycles over very short times, of the order of a hundredth or tenth of a second up to a second.
• This device allows the injection of a pulsed flow of hydrogen at a variable flow rate and with improved reactivity, for example with respect to a regulated proportional solenoid valve. Its operation requires the application of a pressure difference of a few bars between the inlet and outlet of the injector, in particular in order to obtain a wide flow range.
• Injectors are significantly more compact than diaphragm regulators. Pressure regulation by an injector is typically done by adapting the ratio of the opening-closing cycles of the injector in operation.
• an injector has at least one pressure regulation function, in particular to relieve medium pressure towards low pressure, and at least one chopping or switching function.
• a switching valve has a single chopping or switching function.
• Figure 1 illustrates a fuel cell 1 having a ping-pong architecture according to the prior art. It is connected to a high pressure hydrogen tank 2 and comprises a fluid circuit composed of a part 3 upstream of the groups 10, 20 of electrochemical cells, and of a part 4 downstream of the groups 10, 20 of electrochemical cells .
• the upstream part 3 according to the prior art comprises a stop valve 30 at the outlet of the tank 2, a main supply conduit 300 on which a first regulator 31 and a second regulator 32 are successively mounted.
• the first regulator 31 makes it possible to reduce the pressure of the fluid coming from tank 2 from a so-called high pressure of the order of a few hundred bars to a so-called average pressure of the order of a few tens of bars.
• the section of the main supply conduit 300a increases at the outlet of the first regulator 31.
• the second regulator 32 makes it possible to reduce the pressure of the fluid coming from the first regulator 31 from medium pressure to a so-called low pressure of the order of a few bars. Consequently, the section of the main supply conduit 300b increases at the outlet of the second regulator 32.
• the upstream part 3 of the fluidic circuit also comprises a first secondary supply line 100 connecting the main supply conduit 300b to the inlet 11 of the first group 10 of electrochemical cells, and a second supply line secondary 200 connecting the main supply conduit 300b to the inlet 21 of the second group 20 of electrochemical cells.
• the first and second secondary supply lines 100, 200 respectively comprise a first switching valve 101v and a second switching valve 201v ensuring either the passage or blocking of the fluid to each of said groups 10, 20.
• the downstream part 4 of the fluidic circuit comprises a first secondary evacuation line 120 connecting the outlet 12 of the first group 10 of electrochemical cells to the main evacuation conduit 400, and a second secondary evacuation line 220 connecting the outlet 22 of the second group 20 of electrochemical cells to the main evacuation conduit 400.
• the first and second secondary evacuation lines 120, 220 typically form an outlet collector of the cell 1.
• the main evacuation conduit 400 is connected to an exhaust 41, and is provided with a purge valve 40.
• Figure 2A illustrates a first embodiment of a fuel cell with ping-pong architecture according to the invention, incorporating certain elements of the fuel cell illustrated in Figure 1.
• the groups 10, 20 of electrochemical cells and the downstream part 4 of the fluidic circuit are substantially identical to those of the prior art.
• the two groups 10, 20 of cells have the same number of cells, but they can also be different.
• Groups 10, 20 can be nested in a single stack, with alternating cells from the first group and the second group, as described in patent document FR2975227.
• the modifications with respect to the prior art are located in the upstream part 3 of the fluidic circuit.
• the upstream part 3 preferably comprises a stop valve 30 at the outlet of the tank 2, a main supply conduit 300 on which is mounted a first regulator 31, preferably only one and single first regulator 31, for example a double-stage regulator 31, possibly regulated by a pressure sensor 33, and configured to reduce the pressure of the fluid coming from the tank 2 from high pressure to medium pressure.
• the section of the main supply conduit 300a increases at the outlet of the first regulator 31.
• the upstream part 3 of the fluidic circuit according to the first embodiment of the invention also comprises a first secondary supply line 100a, 100b connecting the main supply conduit 300a to the inlet 11 of the first group 10 of electrochemical cells, and a second secondary supply line 200a, 200b connecting the main supply conduit 300a to the inlet 21 of the second group 20 of electrochemical cells.
• the first and second secondary supply lines 100, 200 respectively comprise a first injector 101 and second injector 102.
• the first and second injectors 101, 201 advantageously allow:
• Each injector 101, 201 thus fulfills the function of both a regulator and a switching valve.
• the first and second injectors 101, 201 are preferably pressure regulated respectively by sensors 102, 202 located downstream of the injectors 101, 201, respectively on the first and second secondary supply lines 100b, 200b.
• a high frequency opening/closing cycle (up to several cycles per second) can be applied to each injector 101, 201 depending on the difference between the pressure setpoint and the pressure value measured downstream by the sensors 102, 202. This makes them more responsive, flexible and precise to the desired battery conditions.
• the first and second injectors 101, 201 are substantially identical and the first low pressure is substantially equal to the second low pressure. According to another possibility, the first and second injectors 101, 201 can be dimensioned differently from each other, and the first low pressure can be different from the second low pressure.
• the section of the first secondary supply line 100a upstream of the injector 101 is substantially the same as that of the main supply conduit 300a.
• the section of the second secondary supply line 200a upstream of the injector 201 is substantially the same as that of the main supply conduit 300a.
• Only the secondary supply lines 100b, 200b downstream of the first and second injectors 101, 201 have an increased section capable of conducting a constant volume flow of fluid at low pressure. The total size of the upstream part 3 of the fluid circuit is thus reduced.
• Figure 2A illustrates a first phase of operation of the cell 1 in which only the first group 10 is supplied with combustible fluid.
• the first injector 101 is in operation while the second injector 201 is closed.
• the operation of the first injector 101 typically corresponds to a rapid alternation of openings and closings.
• the purge valve 40 is closed.
• the combustible fluid coming from the tank 2 first passes through the first regulator 31.
• the combustible fluid then has an average pressure of the order of 5 to 20 bars at the outlet of the first regulator 31. (typically 6 to 8 bars).
• the combustible fluid is then led to the inlet 11 of the first group 10 by the first secondary supply line 100a, 100b, through the first injector 101.
• the combustible fluid then has, at the outlet of the first injector 101, a first low pressure of less than 4 bars.
• the combustible fluid then passes through the first group 10 then successively takes the first secondary evacuation line 120, the second secondary evacuation line 220, and reaches the second group 20 via the outlet 22.
• Figure 2B illustrates a second phase of operation of the cell 1 in which only the second group 20 is supplied with combustible fluid.
• the first injector 101 is closed and the second injector 201 is in operation.
• the operation of the second injector 201 typically corresponds to a rapid alternation of openings and closings.
• the purge valve 40 is closed.
• the combustible fluid coming from the tank 2 first passes through the first regulator 31.
• the combustible fluid then presents at the outlet of the first regulator 31 an average pressure of the order of 5 to 20 bars (typically 6 to 8 bars).
• the combustible fluid is then led to the inlet 21 of the second group 20 by the second secondary supply line 200a, 200b, through the second injector 201.
• the combustible fluid then presents at the outlet of the second injector 201 a second low pressure less than 4 bars.
• the combustible fluid then passes through the second group 20 then successively takes the second secondary evacuation line 220, the first secondary evacuation line 120, and reaches the first group 10 via the outlet 12.
• the transition between the first and second phases can be instantaneous, or occur with a delay. If we go through a transition where the two injectors 101, 201 are closed, this transition is preferably short (of the order of a few milliseconds for example) to avoid a drop in pressure in the cell. In the same way, if the two injectors 101, 201 are in operation simultaneously during the transition, its duration is preferably short (of the order of a second) to avoid switching to a “dead-end” type operating mode. .
• Figure 2C illustrates a third phase of operation of the cell 1 in which the first and second groups 10, 20 are supplied simultaneously with combustible fluid.
• the first injector 101 is in operation and the second injector 201 is in operation.
• the purge valve 40 is either open to evacuate the fluid and reaction products to the outside, or closed to accumulate certain products or reagents, for example nitrogen.
• the combustible fluid coming from the tank 2 first passes through the first regulator 31.
• the combustible fluid then has an average pressure of the order of 5 to 20 bars at the outlet of the first regulator 31. (typically 6 to 8 bars).
• a part of the combustible fluid is then conducted to the inlet 11 of the first group 10 by the first secondary supply line 100a, 100b, through the first injector 101, and another part of the combustible fluid is conducted to the inlet 21 of the second group 20 by the second secondary supply line 200a, 200b, through the second injector 201.
• the combustible fluid then has a first low pressure of less than 4 bars at the outlet of the first injector 201.
• the combustible fluid then has a second low pressure of less than 4 bars at the outlet of the second injector 201.
• the combustible fluid then passes through the first and second groups 10, 20 respectively and then takes the first and second secondary evacuation lines 120, 220, up to the main evacuation conduit 400.
• the fuel-depleted fluid can be accumulated in the downstream part 4 of the fluid circuit if the purge valve 40 is closed, or evacuated towards the exhaust 41 if the purge valve 40 is open.
• the use of two injectors 101, 201 in place of conventional switching valves upstream of the inlets 11, 21 of each group 10, 20 advantageously makes it possible to apply different pressure instructions and/or which vary over time to the groups. 10, 20, during the different phases of operation of the battery 1. It is thus possible to apply different pressure instructions for the first injector 101 and for the second injector 201. It is also possible to gradually reduce the pressure at the end of the first operating phase (respectively at the end of the second operating phase). This makes it possible to increase the pressure difference in the fluid circuit and within groups 10, 20 between the end of the first operating phase and the start of the second operating phase following it. The fluid flow is thus increased. This makes it possible to improve the movement of the liquid phase in groups 10, 20 of cells.
• the use of two injectors 101, 201 therefore advantageously provides more responsiveness and operating flexibility for the operation of the battery 1.
• the operation of the injectors is also advantageously independent of the flow rate of fluid, which presents strong variations in a fuel cell. combustible. These flow variations can generate inaccuracies in the behavior of the regulator 31, which can be corrected by the injectors 101, 201 by controlling them.
• the injectors therefore make it possible to simplify the pressure control of the battery. This is all the more true when the regulator 31 does not have regulation by a downstream sensor 33, an element of economy and simplicity for the system.
• the main evacuation conduit 400 common to the two groups 10, 20 can be included in the stack of groups 10, 20 of cells, as described in document FR2975227. It then plays the role of phase separator and allows liquid water to be collected.
• a dedicated body can be added to improve the effectiveness of this separation, for example a porous material, one or more baffles, etc.
• Figure 3 illustrates a second embodiment of a fuel cell with ping-pong architecture according to the invention. Only the different characteristics of this second embodiment compared to the first embodiment are described below. After. The other characteristics are deemed identical to those of the first embodiment.
• the first and second injectors 101, 201 are no longer each associated with an independent pressure sensor.
• a single pressure sensor 401 mounted on the downstream part 4 of the fluid circuit at the outlet of the first and second groups 10, 20, is used for regulating the first and second injectors 101, 201. This makes it possible to limit the number of pressure sensors. pressure and therefore reduce costs and improve the compactness of the stack 1. Control of the first and second injectors 101, 201 is also simplified. In this position of the sensor 401, the pressure measurement is preferably carried out halfway between the outlet of group 10 and the outlet of group 20. If the two groups 10, 20 are identical, this makes it possible to measure the same value of pressure independently of the group supplied.
• the sensor 401 may be advantageous to introduce a pressure loss model in the two groups 10, 20 of cells, for the control of the injectors 101, 201. This improves the regulation of the injectors 101, 201.
• This pressure drop model can be established from a precise characterization of the fluidic behavior of the groups 10, 20 of cells.
• One or more injection controllers configured to control the injectors 101, 201, can typically take into account this pressure loss model for the control and control of the injectors 101, 201.
• Figure 4 illustrates a third embodiment of a fuel cell with ping-pong architecture according to the invention. Only the different characteristics of the third embodiment with respect to the first embodiment or the second embodiment are described below. The other characteristics are deemed identical to those of the first embodiment or the second embodiment.
• the first secondary supply line 100 is divided into two branches 100a, 100c respectively carrying injectors 101, 103 each supplying the inlet 11 of the first group 10.
• the second secondary supply line 200 is also divided into two branches 200a, 200c respectively carrying injectors 201, 203 each supplying the inlet 21 of the second group 20.
• the injectors 101, 103, 201, 203 can all be identical, identical in pairs, or all different depending on the needs.
• This third embodiment is illustrated here with a sensor 401 downstream of groups 10, 20, configured to regulate all of the injectors 101, 103, 201, 203, as for the second embodiment.
• a second sensor 403 is provided here for a safety issue: in the event of failure of sensor 401, sensor 403 replaces sensor 401.
• the purge valve is replaced by two valves 42, 43 mounted in parallel. This allows both redundancy and the possibility of modulating the purge flow depending on whether the opening of a single or both valves 42, 43 is controlled simultaneously.
• the valves 42, 43 may be identical or different.
• the number of injectors per secondary supply line, the number of pressure sensors and the position of these pressure sensors on the fluid circuit may vary.
• a person skilled in the art will easily be able to adapt the number of injectors and sensors and their positions to form a fluidic circuit configuration corresponding to their needs.
• the capacity of one or more injectors to ensure the expansion of a relatively high upstream pressure towards a low downstream pressure is dependent on the choice of the dimensioning of the injector and the energy that one is ready to exert. provide it in order to ensure its relaxation cycles, and can be adapted by a person skilled in the art to the specificity of its installation.
• the notion of medium pressure described for the invention could thus be greater than 50 bars, using suitable injectors.

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• 2022
  • 2022-12-14 FR FR2213294A patent/FR3143882B1/fr active Active
• 2023
  • 2023-12-13 WO PCT/EP2023/085685 patent/WO2024126614A1/fr not_active Ceased
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