EP4623205A1 - A method of compressing a water-containing oxygen-containing stream - Google Patents
A method of compressing a water-containing oxygen-containing streamInfo
- Publication number
- EP4623205A1 EP4623205A1 EP23810034.1A EP23810034A EP4623205A1 EP 4623205 A1 EP4623205 A1 EP 4623205A1 EP 23810034 A EP23810034 A EP 23810034A EP 4623205 A1 EP4623205 A1 EP 4623205A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- stream
- oxygen
- water
- obtaining
- ejector
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
Classifications
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F04—POSITIVE - DISPLACEMENT MACHINES FOR LIQUIDS; PUMPS FOR LIQUIDS OR ELASTIC FLUIDS
- F04F—PUMPING OF FLUID BY DIRECT CONTACT OF ANOTHER FLUID OR BY USING INERTIA OF FLUID TO BE PUMPED; SIPHONS
- F04F5/00—Jet pumps, i.e. devices in which flow is induced by pressure drop caused by velocity of another fluid flow
- F04F5/02—Jet pumps, i.e. devices in which flow is induced by pressure drop caused by velocity of another fluid flow the inducing fluid being liquid
- F04F5/04—Jet pumps, i.e. devices in which flow is induced by pressure drop caused by velocity of another fluid flow the inducing fluid being liquid displacing elastic fluids
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B1/00—Electrolytic production of inorganic compounds or non-metals
- C25B1/01—Products
- C25B1/02—Hydrogen or oxygen
- C25B1/04—Hydrogen or oxygen by electrolysis of water
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B15/00—Operating or servicing cells
- C25B15/08—Supplying or removing reactants or electrolytes; Regeneration of electrolytes
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B9/00—Cells or assemblies of cells; Constructional parts of cells; Assemblies of constructional parts, e.g. electrode-diaphragm assemblies; Process-related cell features
- C25B9/05—Pressure cells
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F04—POSITIVE - DISPLACEMENT MACHINES FOR LIQUIDS; PUMPS FOR LIQUIDS OR ELASTIC FLUIDS
- F04F—PUMPING OF FLUID BY DIRECT CONTACT OF ANOTHER FLUID OR BY USING INERTIA OF FLUID TO BE PUMPED; SIPHONS
- F04F5/00—Jet pumps, i.e. devices in which flow is induced by pressure drop caused by velocity of another fluid flow
- F04F5/02—Jet pumps, i.e. devices in which flow is induced by pressure drop caused by velocity of another fluid flow the inducing fluid being liquid
- F04F5/10—Jet pumps, i.e. devices in which flow is induced by pressure drop caused by velocity of another fluid flow the inducing fluid being liquid displacing liquids, e.g. containing solids, or liquids and elastic fluids
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F04—POSITIVE - DISPLACEMENT MACHINES FOR LIQUIDS; PUMPS FOR LIQUIDS OR ELASTIC FLUIDS
- F04F—PUMPING OF FLUID BY DIRECT CONTACT OF ANOTHER FLUID OR BY USING INERTIA OF FLUID TO BE PUMPED; SIPHONS
- F04F5/00—Jet pumps, i.e. devices in which flow is induced by pressure drop caused by velocity of another fluid flow
- F04F5/44—Component parts, details, or accessories not provided for in, or of interest apart from, groups F04F5/02 - F04F5/42
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/30—Hydrogen technology
- Y02E60/36—Hydrogen production from non-carbon containing sources, e.g. by water electrolysis
Definitions
- the present invention relates to a method of compressing a water-containing oxygen-containing stream originating from an electrolyzer, wherein the obtained compressed oxygen-containing stream is used, in 5 particular in a gasifier.
- Compression of gaseous streams is well known in the art.
- the compression of gaseous streams is achieved by positive displacement devices such as reciprocating or screw compressors which 10 reduce the volume that the gas occupies and hence increase the pressure.
- This kind of ‘dry’ compression can also be achieved by centrifugal blowers, compressors or pumps, which use impellers to accelerate the gas and then decelerate the gas 15 converting the kinetic energy of the gas to pressure.
- centrifugal blowers, compressors or pumps which use impellers to accelerate the gas and then decelerate the gas 15 converting the kinetic energy of the gas to pressure.
- multiple stages of compression and cooling between the stages is required.
- a problem of multi-stage compressors is that they 20 are typically associated with high capital costs due to associated equipment, installation and high operation costs.
- a further problem of conventional ‘dry’ compression is that it cannot be used for compressing water-saturated 25 oxygen-containing streams as for example originating from an electrolyzer.
- Conventional compressors cannot tolerate any water in an oxygen-containing stream and the use of such compressors for oxygen-containing streams originating from an electrolyzer would result in a safety risk.
- a method of compressing a water-containing oxygen- containing stream originating from an electrolyzer at least comprising the steps of: (a) providing a water-containing oxygen-containing stream; 30 (b) combining the water-containing oxygen-containing stream provided in step (a) as a suction fluid in an ejector with a water-containing stream as a motive fluid, thereby obtaining a combined stream; (c) flashing the combined stream by the ejector, thereby obtaining a two-phase fluid discharged from the ejector; (d) separating the two-phase fluid discharged from 5 the ejector into an oxygen-containing gas stream and a liquid stream; (e) pressurizing the liquid stream obtained in step (d), thereby obtaining a pressurized liquid stream; (f) using the pressurized liquid stream obtained in 10 step (e) as the motive fluid in step (b); (g) dehydrogenating the oxygen-containing gas stream obtained
- a pressurized oxygen-containing gas stream can be obtained in a surprisingly simple manner, without the safety issues as confronted in ‘dry compression’.
- a further advantage of the process according to the 30 present invention is that a static piece of equipment can be used to achieve pressure transfer. Such a static piece of equipment is reliable, simple and requires less expensive construction materials. Ejectors are considered static equipment and are generally associated with low capital and operating costs in comparison to compressors.
- the ejector converts the pressure energy available in the motive fluid to velocity energy, brings in the (lower 5 pressure) suction fluid, mixes the two fluids and discharges the mixture at an intermediate pressure without the use of rotating or moving parts.
- ejectors are known per se for decades, but have not been suggested for the 10 use of compressing a water-containing oxygen-containing streams originating from an electrolyzer, wherein the compressed oxygen-containing stream is used as a product in e.g. a gasifier.
- WO 2022/069906 A1 discloses 15 the use of an ejector for condensing in particular CO2.
- 25 JP2003105577A discloses a fuel cell hybrid system comprising a gas generating section (using electrolysis of water) for producing hydrogen and oxygen and a fuel cell section for generating electricity by using the hydrogen and/or oxygen as generated in the gas generating 30 section in the fuel cell section.
- WO 2020/035470 A1 discloses a gas power cycle for power generation where use is made of an ejector. There is no mention in WO 2020/035470 A1 that a water-containing oxygen-containing stream is originating from an electrolyzer. In step (a) of the method according to the present invention, a water-containing oxygen-containing stream is provided.
- the water-containing oxygen-containing stream provided in step (a) is not limited in any way (in terms of composition, temperature, pressure, etc.), as long as it contains oxygen (O2) and water (H2O) and as long as it is originating from an electrolyzer.
- the water-containing oxygen-containing stream provided in step (a) is a gaseous stream, and it preferably is a water-saturated stream. It may even contain some liquid water carryover (up to 1.0 vol.%).
- the water-containing oxygen-containing stream provided in step (a) comprises at least 80 mol% O 2 , preferably at least 90 mol% O 2 , more preferably at least 95 mol% O2.
- the water-containing oxygen-containing stream provided in step (a) comprises at most 99 mol.% O2, more preferably at most 98 mol% O2. Further, it is preferred that the water-containing oxygen-containing stream provided in step (a) comprises from 2.0 to 20 mol% H2O, preferably from 3.0 mol% to 10.0 mol% H2O.
- the water-containing oxygen-containing stream provided in step (a) typically also comprises hydrogen (H 2 ).
- the water-containing oxygen-containing stream provided in step (a) comprises from 0.3 to 2.0 mol% H 2 .
- the water-containing oxygen-containing stream provided in step (a) has a pressure of from 0.1 bara to 2.5 bara, preferably from 0.5 bara to 1.5 bara.
- the pressure of the water-containing oxygen-containing stream provided in step (a) may be referred to as ‘first pressure’. Further it is preferred that the water-containing oxygen-containing stream provided in step (a) has a temperature of from 20 to 90°C, preferably from 40 to 80°C. If appropriate, the water-containing oxygen- containing stream provided in step (a) may have been pre- processed to obtain the desired composition and conditions.
- step (b) of the method according to the present invention the water-containing oxygen-containing stream provided in step (a) is combined as a suction fluid in an ejector with a water-containing stream as a motive fluid, thereby obtaining a combined stream. As ejectors are known in the art, these are not further described here in detail.
- the motive fluid in step (b) comprises at least 80 mol% H2O, preferably at least 90 mol%, more preferably at least 95 mol%.
- the motive fluid in step (b) comprises at most 99 mol% H2O.
- the motive fluid in step (b) may also contain some O 2 and H 2 .
- the motive fluid contains ⁇ 0.5 mol.% O 2 .
- the pressure of the ‘motive fluid’ is higher than the pressure of the ‘suction fluid’ as used in the ejector.
- the pressure of the motive fluid is at least 10 bar higher than the suction fluid, preferably at least 20 bar higher, more preferably at least 50 bar higher, even more preferably at least 80 bar higher.
- the motive fluid in step (b) has a 5 pressure in the range of from 60 to 300 bara, preferably from 80 bara to 200 bara. Further it is preferred that the motive fluid in step (b) has a temperature of from 20 to 70°C, preferably from 30 to 50°C.
- the (water-containing 10 oxygen-containing stream to be used as the) suction fluid has a pressure of from 0.1 bara to 2.5 bara, preferably from 0.5 bara to 1.5 bara.
- step (c) of the method according to the present invention the combined stream is flashed by the ejector, 15 thereby obtaining a two-phase fluid discharged from the ejector.
- the flashing takes place in the throat of the ejector, thereby obtaining the two-phase fluid whilst leaving the ejector.
- the pressure of the 20 combined stream is reduced.
- the two-phase fluid obtained in step (c) has a pressure of from 2.0 bara to 10.0 bara, preferably from 3.0 bara to 6.0 bara.
- the pressure of the two-phase fluid obtained in step (c) may be referred to as ‘second pressure’.
- This second 25 pressure is higher than the ‘first pressure’ (of the water-containing oxygen-containing stream provided in step (a)).
- step (d) of the method according to the present invention the two-phase fluid discharged from the 30 ejector is separated into an oxygen-containing gas stream and a liquid stream. This separation in step (d) is not particularly limited and typically takes place in a conventional gas/liquid-separator.
- step (d) 5 (which is at the increased, second pressure) will be further processed (e.g. dehydrogenated, dehydrated and further compressed) and used as a product, for example in a gasifier.
- step (e) of the method according to the present 10 invention the liquid stream obtained in step (d) is pressurized, thereby obtaining a pressurized liquid stream.
- this pressurizing may be performed in many ways, e.g. by using a pump, in order to obtain the 15 desired pressure for use as the motive fluid.
- step (f) of the method according to the present invention the pressurized liquid stream obtained in step (e) is used as the motive fluid in step (b).
- step (g) of the method according to the present 20 invention the oxygen-containing gas stream obtained in step (d) is dehydrogenated, thereby obtaining a dehydrogenated oxygen-containing stream.
- the dehydrogenation can 25 be done by for example catalytic H2/O2 combustion. If such catalytic H2/O2 combustion is used, then reactor temperatures are in the range of 70 to 150°C.
- the dehydrogenated oxygen-containing stream preferably has a H 2 content of less than 1 mol%, 30 preferably less than 10 ppm, more preferably less than 5 ppm.
- step (h) of the method according to the present invention the dehydrogenated oxygen-containing stream obtained in step (g) is dehydrated, thereby obtaining a dehydrated dehydrogenated oxygen-containing stream.
- the dehydrated dehydrogenated oxygen- containing stream comprises less than 10 ppm H2O.
- step (i) of the method according to the present invention the dehydrated dehydrogenated oxygen- containing stream obtained in step (h) is compressed, 10 thereby obtaining a compressed oxygen-containing stream.
- the compressed oxygen-containing stream has a pressure in the range of 6 to 70 bara, preferably 30 to 60 bara.
- step (j) of the method according to the present 15 invention the compressed oxygen-containing stream obtained in step (i) is used, in particular in a gasifier.
- a gasifier As a person skilled in the art is familiar with a gasifier, this is not further discussed here in detail. Suitable gasifiers have for example been disclosed in WO 20 2017/102942 A1. Typically, the gasifier forms part of syngas and fossil-based hydrogen production line-ups and the like.
- the method according to the present invention may 25 comprise further steps. As an example, some cooling may be performed on the liquid stream obtained in step (d) and/or the pressurized liquid stream obtained in step (e), in order to obtain the desired temperature or the motive fluid to be used in step (b).
- the present invention provides an apparatus for compressing a water-containing, in particular a water-saturated, oxygen-containing stream originating from an electrolyzer, the apparatus at least 5 comprising: - an electrolyzer for electrolyzing a water-containing stream, thereby obtaining at least a (water-containing, in particular water-saturated) H2-containing stream and a water-containing (in particular water-saturated) oxygen- 10 containing stream; - an ejector for combining the water-containing oxygen- containing stream as a suction fluid with a water- containing stream as a motive fluid, thereby obtaining a combined stream and flashing the combined stream, thereby 15 obtaining a two-phase fluid discharged from the ejector; - a separator for separating the two-phase fluid discharged from the
- FIG. 1 schematically a flow scheme of part of the method for compressing a water-saturated oxygen- 10 containing stream originating from an electrolyzer according to the present invention
- Fig. 2 schematically a detailed view of an exemplary, non-limiting embodiment of an ejector that can be used in the method according to the present invention
- Fig. 3 schematically an alternative embodiment of part of the method according to the present invention, further containing a cooler downstream of the pump 4 in Fig. 1;
- Fig. 1 schematically a flow scheme of part of the method for compressing a water-saturated oxygen- 10 containing stream originating from an electrolyzer according to the present invention
- Fig. 2 schematically a detailed view of an exemplary, non-limiting embodiment of an ejector that can be used in the method according to the present invention
- Fig. 3 schematically an alternative embodiment of part of the method according to the present invention, further containing a cooler downstream of the pump 4 in Fig. 1;
- Fig. 1 schematic
- FIG. 4 schematically an alternative embodiment of the 20 method according to the present invention, further containing a cooler upstream of the pump 4 in Fig. 1; and Fig. 5 schematically an exemplary method according to the present invention (based on Fig. 3) also showing a dehydrogenator, a dehydrator, a compressor, and a 25 gasifier.
- Fig. 3 schematically an exemplary method according to the present invention (based on Fig. 3) also showing a dehydrogenator, a dehydrator, a compressor, and a 25 gasifier.
- same reference numbers refer to same or similar components.
- the flow scheme of Figure 1 generally referred to with reference number 1, shows an ejector 2, a 30 gas/liquid-separator 3 and a pump 4.
- one of the inlets ‘2b’ in Fig.
- a water- 5 saturated oxygen-containing stream 10 is combined as a suction fluid in the ejector 2 with a water-containing stream 20 as a motive fluid, thereby obtaining a combined stream.
- the combined stream is flashed by the ejector 2, thereby obtaining a two-phase fluid 30 discharged from 10 the ejector 2.
- FIG. 2 A more detailed view of (a non-limiting embodiment of) the ejector 2 is shown in Fig. 2 and is discussed hereafter.
- the water-saturated oxygen- containing stream 10 is combined as a suction fluid with 15 a motive fluid 20, thereby obtaining a combined stream (not shown in Fig. 1; ‘25’ in Fig. 2).
- the combined stream is flashed by the ejector 2 whilst leaving the ejector 2, thereby obtaining a two-phase fluid 30 discharged from the ejector 2.
- the two-phase fluid 30 discharged from the ejector 2 is separated in a conventional gas/liquid-separator 3 into an oxygen-containing gas stream 40 and a liquid stream 50.
- Part of the liquid stream 50 may be used as a bleed stream (not shown in Fig. 1; cf. stream 60 in Fig. 25 3).
- the oxygen-containing gas 40 (which has an increased pressure when compared to the water-saturated oxygen- containing stream 10) may be routed to further compression and purification (e.g. dehydrogenation, 30 dehydration, ...) prior to end use, e.g. in a gasifier (see also Fig. 5 hereafter).
- the liquid stream 50 coming from the gas/liquid- separator 3 is pressurized in the pump 4, thereby obtaining a pressurized liquid stream, which is used as the motive fluid 20 in the ejector 2.
- Figure 2 shows a more detailed view of an ejector that can be used as the ejector 2 in Fig. 1.
- the ejector 2 comprises an inlet 2a for the motive fluid 20, an inlet 2b for the suction fluid 10, a nozzle 2c within the ejector 2 for the motive fluid, a throat 2d with a diffuser section 2e and an outlet 2f for the fluid 30 to be discharged.
- the motive fluid 20 and suction fluid 10 are combined in the ejector 2 (just after nozzle 2c) to form a combined stream 25.
- FIG. 3 and 4 schematically show alternative embodiments of the method according to the present invention, wherein a cooler 5 is used downstream (Fig. 3) or upstream (Fig. 4) of the pump 4 in Fig. 1. It goes 20 without saying, that also a cooler may be present both downstream and upstream of the pump 4.
- the cooler 5 is in the form of an indirect heat exchanger.
- the cooler 5 cools the 25 pressurized liquid stream (referred to as ‘45’ in Fig.
- FIG. 5 provides a fuller overview of the flow scheme of the method according to the present invention (based on the embodiment of Fig. 3), also showing a dehydrogenator 6, a dehydrator 7, a compressor 8, and a 5 gasifier 9. During use of the flow scheme of Fig.
- Example 1 The flow scheme of Fig. 3 was used for illustrating the compressing of a gaseous water-saturated oxygen- containing stream originating from an electrolyzer.
- the compositions and conditions of the fluid (i.e. gas and liquid) streams in the various flow lines are provided in 25 Table 1 below.
- the pressurized oxygen- 15 containing gas stream can subsequently be used in a gasifier.
- the person skilled in the art will readily understand that many modifications may be made without departing from the scope of the invention. Further, the person 20 skilled in the art will readily understand that, while the present invention in some instances may have been illustrated making reference to a specific combination of features and measures, many of those features and measures are functionally independent from other features 25 and measures given in the respective embodiment(s) such that they can be equally or similarly applied independently in other embodiments.
Landscapes
- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Electrochemistry (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Physics & Mathematics (AREA)
- Fluid Mechanics (AREA)
- Mechanical Engineering (AREA)
- General Engineering & Computer Science (AREA)
- Inorganic Chemistry (AREA)
- Electrolytic Production Of Non-Metals, Compounds, Apparatuses Therefor (AREA)
- Jet Pumps And Other Pumps (AREA)
Abstract
Description
Claims
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP22386084 | 2022-11-24 | ||
| PCT/EP2023/082492 WO2024110436A1 (en) | 2022-11-24 | 2023-11-21 | A method of compressing a water-containing oxygen-containing stream |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| EP4623205A1 true EP4623205A1 (en) | 2025-10-01 |
Family
ID=84799926
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| EP23810034.1A Withdrawn EP4623205A1 (en) | 2022-11-24 | 2023-11-21 | A method of compressing a water-containing oxygen-containing stream |
Country Status (6)
| Country | Link |
|---|---|
| EP (1) | EP4623205A1 (en) |
| JP (1) | JP2025537387A (en) |
| KR (1) | KR20250112759A (en) |
| CN (1) | CN120265887A (en) |
| AU (1) | AU2023386585A1 (en) |
| WO (1) | WO2024110436A1 (en) |
Family Cites Families (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2003105577A (en) | 2001-09-25 | 2003-04-09 | Mitsubishi Heavy Ind Ltd | Gas generator and fuel cell hybrid system |
| CN203923390U (en) * | 2014-06-09 | 2014-11-05 | 重庆朝阳气体有限公司 | The device of a kind of brine electrolysis high purity oxygen processed |
| JP6663014B2 (en) | 2015-12-16 | 2020-03-11 | エア プロダクツ アンド ケミカルズ インコーポレイテッドAir Products And Chemicals Incorporated | Gasification systems and processes |
| WO2020035470A1 (en) | 2018-08-14 | 2020-02-20 | Shell Internationale Research Maatschappij B.V. | Gas cycle and method |
| GB202015672D0 (en) | 2020-10-02 | 2020-11-18 | Transvac Systems Ltd | Apparatus and method |
-
2023
- 2023-11-21 WO PCT/EP2023/082492 patent/WO2024110436A1/en not_active Ceased
- 2023-11-21 EP EP23810034.1A patent/EP4623205A1/en not_active Withdrawn
- 2023-11-21 KR KR1020257014937A patent/KR20250112759A/en active Pending
- 2023-11-21 CN CN202380081050.4A patent/CN120265887A/en active Pending
- 2023-11-21 JP JP2025530608A patent/JP2025537387A/en active Pending
- 2023-11-21 AU AU2023386585A patent/AU2023386585A1/en active Pending
Also Published As
| Publication number | Publication date |
|---|---|
| KR20250112759A (en) | 2025-07-24 |
| JP2025537387A (en) | 2025-11-14 |
| CN120265887A (en) | 2025-07-04 |
| AU2023386585A1 (en) | 2025-05-01 |
| WO2024110436A1 (en) | 2024-05-30 |
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