EP4495089C0 - Verfahren zur alkoxycarbonylierung von di-isobuten und einem c4- bis c7-olefin - Google Patents

Verfahren zur alkoxycarbonylierung von di-isobuten und einem c4- bis c7-olefin

Info

Publication number
EP4495089C0
EP4495089C0 EP23186733.4A EP23186733A EP4495089C0 EP 4495089 C0 EP4495089 C0 EP 4495089C0 EP 23186733 A EP23186733 A EP 23186733A EP 4495089 C0 EP4495089 C0 EP 4495089C0
Authority
EP
European Patent Office
Prior art keywords
alcoxycarbonylation
isobutene
olefin
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
EP23186733.4A
Other languages
English (en)
French (fr)
Other versions
EP4495089B1 (de
EP4495089A1 (de
Inventor
Peter Kucmierczyk
Maren Termühlen
Annika Reinhardt
Armin Matthias Rix
Robert Franke
Dirk Fridag
Anna Chiara Sale
Ana Markovic
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Evonik Operations GmbH
Original Assignee
Evonik Oxeno GmbH and Co KG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Evonik Oxeno GmbH and Co KG filed Critical Evonik Oxeno GmbH and Co KG
Priority to EP23186733.4A priority Critical patent/EP4495089B1/de
Priority to TW113126716A priority patent/TW202511240A/zh
Priority to KR1020240094129A priority patent/KR20250015936A/ko
Priority to CN202410963533.3A priority patent/CN119330827A/zh
Priority to US18/776,364 priority patent/US20250026709A1/en
Publication of EP4495089A1 publication Critical patent/EP4495089A1/de
Application granted granted Critical
Publication of EP4495089B1 publication Critical patent/EP4495089B1/de
Publication of EP4495089C0 publication Critical patent/EP4495089C0/de
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/02—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons
    • C07C2/04—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation
    • C07C2/06—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation of alkenes, i.e. acyclic hydrocarbons having only one carbon-to-carbon double bond
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
    • B01J23/44—Palladium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
    • B01J31/1845—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing phosphorus
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/36—Preparation of carboxylic acid esters by reaction with carbon monoxide or formates
    • C07C67/38—Preparation of carboxylic acid esters by reaction with carbon monoxide or formates by addition to an unsaturated carbon-to-carbon bond
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/48—Separation; Purification; Stabilisation; Use of additives
    • C07C67/52—Separation; Purification; Stabilisation; Use of additives by change in the physical state, e.g. crystallisation
    • C07C67/54—Separation; Purification; Stabilisation; Use of additives by change in the physical state, e.g. crystallisation by distillation
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C69/00—Esters of carboxylic acids; Esters of carbonic or haloformic acids
    • C07C69/02—Esters of acyclic saturated monocarboxylic acids having the carboxyl group bound to an acyclic carbon atom or to hydrogen
    • C07C69/22—Esters of acyclic saturated monocarboxylic acids having the carboxyl group bound to an acyclic carbon atom or to hydrogen having three or more carbon atoms in the acid moiety
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2523/00—Constitutive chemical elements of heterogeneous catalysts
    • B01J2523/80—Constitutive chemical elements of heterogeneous catalysts of Group VIII of the Periodic Table
    • B01J2523/82—Metals of the platinum group
    • B01J2523/824—Palladium
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/582—Recycling of unreacted starting or intermediate materials

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
EP23186733.4A 2023-07-20 2023-07-20 Verfahren zur alkoxycarbonylierung von di-isobuten und einem c4- bis c7-olefin Active EP4495089B1 (de)

Priority Applications (5)

Application Number Priority Date Filing Date Title
EP23186733.4A EP4495089B1 (de) 2023-07-20 2023-07-20 Verfahren zur alkoxycarbonylierung von di-isobuten und einem c4- bis c7-olefin
TW113126716A TW202511240A (zh) 2023-07-20 2024-07-17 二異丁烯及c4至c7烯烴烷氧基羰基化之方法
KR1020240094129A KR20250015936A (ko) 2023-07-20 2024-07-17 디이소부텐 및 c4 내지 c7 올레핀의 알콕시카르보닐화 방법
CN202410963533.3A CN119330827A (zh) 2023-07-20 2024-07-18 用于二异丁烯和c4至c7烯烃的烷氧基羰基化的方法
US18/776,364 US20250026709A1 (en) 2023-07-20 2024-07-18 Process for alkoxycarbonylation of diisobutene and a c4 to c7 olefin

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
EP23186733.4A EP4495089B1 (de) 2023-07-20 2023-07-20 Verfahren zur alkoxycarbonylierung von di-isobuten und einem c4- bis c7-olefin

Publications (3)

Publication Number Publication Date
EP4495089A1 EP4495089A1 (de) 2025-01-22
EP4495089B1 EP4495089B1 (de) 2026-03-04
EP4495089C0 true EP4495089C0 (de) 2026-03-04

Family

ID=87429563

Family Applications (1)

Application Number Title Priority Date Filing Date
EP23186733.4A Active EP4495089B1 (de) 2023-07-20 2023-07-20 Verfahren zur alkoxycarbonylierung von di-isobuten und einem c4- bis c7-olefin

Country Status (5)

Country Link
US (1) US20250026709A1 (de)
EP (1) EP4495089B1 (de)
KR (1) KR20250015936A (de)
CN (1) CN119330827A (de)
TW (1) TW202511240A (de)

Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE10113381A1 (de) 2001-02-13 2002-08-14 Oxeno Olefinchemie Gmbh Verfahren zur Herstellung von hochreinem Diisobuten
GB201401392D0 (en) 2014-01-27 2014-03-12 Imp Innovations Ltd Nanofiltration membrane
CN106397484A (zh) 2015-07-23 2017-02-15 赢创德固赛有限公司 用于烷氧基羰基化的丁基‑桥连的二膦配体
EP3272732B1 (de) * 2016-07-19 2019-09-18 Evonik Degussa GmbH Verfahren zur alkoxycarbonylierung ethylenisch ungesättigter verbindungen mit monophosphinliganden
US11365171B2 (en) * 2019-06-12 2022-06-21 Evonik Operations Gmbh Process for preparing an ester by alkoxycarbonylation

Also Published As

Publication number Publication date
CN119330827A (zh) 2025-01-21
KR20250015936A (ko) 2025-02-03
EP4495089B1 (de) 2026-03-04
TW202511240A (zh) 2025-03-16
EP4495089A1 (de) 2025-01-22
US20250026709A1 (en) 2025-01-23

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