EP4469716A1 - Verfahren und system zur kühlung eines kryogenen speichertanks - Google Patents

Verfahren und system zur kühlung eines kryogenen speichertanks

Info

Publication number
EP4469716A1
EP4469716A1 EP23701839.5A EP23701839A EP4469716A1 EP 4469716 A1 EP4469716 A1 EP 4469716A1 EP 23701839 A EP23701839 A EP 23701839A EP 4469716 A1 EP4469716 A1 EP 4469716A1
Authority
EP
European Patent Office
Prior art keywords
cryogenic
storage tank
flow
cryogenic fluid
subcooling heat
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
EP23701839.5A
Other languages
English (en)
French (fr)
Other versions
EP4469716C0 (de
EP4469716B1 (de
Inventor
Guillaume Pages
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Cryostar SAS
Original Assignee
Cryostar SAS
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Cryostar SAS filed Critical Cryostar SAS
Publication of EP4469716A1 publication Critical patent/EP4469716A1/de
Application granted granted Critical
Publication of EP4469716C0 publication Critical patent/EP4469716C0/de
Publication of EP4469716B1 publication Critical patent/EP4469716B1/de
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B63SHIPS OR OTHER WATERBORNE VESSELS; RELATED EQUIPMENT
    • B63BSHIPS OR OTHER WATERBORNE VESSELS; EQUIPMENT FOR SHIPPING 
    • B63B25/00Load-accommodating arrangements, e.g. stowing, trimming; Vessels characterised thereby
    • B63B25/02Load-accommodating arrangements, e.g. stowing, trimming; Vessels characterised thereby for bulk goods
    • B63B25/08Load-accommodating arrangements, e.g. stowing, trimming; Vessels characterised thereby for bulk goods fluid
    • B63B25/12Load-accommodating arrangements, e.g. stowing, trimming; Vessels characterised thereby for bulk goods fluid closed
    • B63B25/16Load-accommodating arrangements, e.g. stowing, trimming; Vessels characterised thereby for bulk goods fluid closed heat-insulated
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B63SHIPS OR OTHER WATERBORNE VESSELS; RELATED EQUIPMENT
    • B63JAUXILIARIES ON VESSELS
    • B63J2/00Arrangements of ventilation, heating, cooling, or air-conditioning
    • B63J2/12Heating; Cooling
    • B63J2/14Heating; Cooling of liquid-freight-carrying tanks
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F17STORING OR DISTRIBUTING GASES OR LIQUIDS
    • F17CVESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
    • F17C6/00Methods and apparatus for filling vessels not under pressure with liquefied or solidified gases
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25JLIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J1/00Processes or apparatus for liquefying or solidifying gases or gaseous mixtures
    • F25J1/0002Processes or apparatus for liquefying or solidifying gases or gaseous mixtures characterised by the fluid to be liquefied
    • F25J1/0022Hydrocarbons, e.g. natural gas
    • F25J1/0025Boil-off gases "BOG" from storages
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25JLIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J1/00Processes or apparatus for liquefying or solidifying gases or gaseous mixtures
    • F25J1/003Processes or apparatus for liquefying or solidifying gases or gaseous mixtures characterised by the kind of cold generation within the liquefaction unit for compensating heat leaks and liquid production
    • F25J1/0047Processes or apparatus for liquefying or solidifying gases or gaseous mixtures characterised by the kind of cold generation within the liquefaction unit for compensating heat leaks and liquid production using an "external" refrigerant stream in a closed vapor compression cycle
    • F25J1/005Processes or apparatus for liquefying or solidifying gases or gaseous mixtures characterised by the kind of cold generation within the liquefaction unit for compensating heat leaks and liquid production using an "external" refrigerant stream in a closed vapor compression cycle by expansion of a gaseous refrigerant stream with extraction of work
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25JLIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J1/00Processes or apparatus for liquefying or solidifying gases or gaseous mixtures
    • F25J1/006Processes or apparatus for liquefying or solidifying gases or gaseous mixtures characterised by the refrigerant fluid used
    • F25J1/007Primary atmospheric gases, mixtures thereof
    • F25J1/0072Nitrogen
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25JLIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J1/00Processes or apparatus for liquefying or solidifying gases or gaseous mixtures
    • F25J1/02Processes or apparatus for liquefying or solidifying gases or gaseous mixtures requiring the use of refrigeration, e.g. of helium or hydrogen ; Details and kind of the refrigeration system used; Integration with other units or processes; Controlling aspects of the process
    • F25J1/0203Processes or apparatus for liquefying or solidifying gases or gaseous mixtures requiring the use of refrigeration, e.g. of helium or hydrogen ; Details and kind of the refrigeration system used; Integration with other units or processes; Controlling aspects of the process using a single-component refrigerant [SCR] fluid in a closed vapor compression cycle
    • F25J1/0204Processes or apparatus for liquefying or solidifying gases or gaseous mixtures requiring the use of refrigeration, e.g. of helium or hydrogen ; Details and kind of the refrigeration system used; Integration with other units or processes; Controlling aspects of the process using a single-component refrigerant [SCR] fluid in a closed vapor compression cycle as a single flow SCR cycle
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25JLIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J1/00Processes or apparatus for liquefying or solidifying gases or gaseous mixtures
    • F25J1/02Processes or apparatus for liquefying or solidifying gases or gaseous mixtures requiring the use of refrigeration, e.g. of helium or hydrogen ; Details and kind of the refrigeration system used; Integration with other units or processes; Controlling aspects of the process
    • F25J1/0243Start-up or control of the process; Details of the apparatus used; Details of the refrigerant compression system used
    • F25J1/0244Operation; Control and regulation; Instrumentation
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25JLIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J1/00Processes or apparatus for liquefying or solidifying gases or gaseous mixtures
    • F25J1/02Processes or apparatus for liquefying or solidifying gases or gaseous mixtures requiring the use of refrigeration, e.g. of helium or hydrogen ; Details and kind of the refrigeration system used; Integration with other units or processes; Controlling aspects of the process
    • F25J1/0243Start-up or control of the process; Details of the apparatus used; Details of the refrigerant compression system used
    • F25J1/0244Operation; Control and regulation; Instrumentation
    • F25J1/0256Safety aspects of operation
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25JLIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J1/00Processes or apparatus for liquefying or solidifying gases or gaseous mixtures
    • F25J1/02Processes or apparatus for liquefying or solidifying gases or gaseous mixtures requiring the use of refrigeration, e.g. of helium or hydrogen ; Details and kind of the refrigeration system used; Integration with other units or processes; Controlling aspects of the process
    • F25J1/0243Start-up or control of the process; Details of the apparatus used; Details of the refrigerant compression system used
    • F25J1/0257Construction and layout of liquefaction equipments, e.g. valves, machines
    • F25J1/0275Construction and layout of liquefaction equipments, e.g. valves, machines adapted for special use of the liquefaction unit, e.g. portable or transportable devices
    • F25J1/0277Offshore use, e.g. during shipping
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F17STORING OR DISTRIBUTING GASES OR LIQUIDS
    • F17CVESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
    • F17C2201/00Vessel construction, in particular geometry, arrangement or size
    • F17C2201/01Shape
    • F17C2201/0104Shape cylindrical
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F17STORING OR DISTRIBUTING GASES OR LIQUIDS
    • F17CVESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
    • F17C2201/00Vessel construction, in particular geometry, arrangement or size
    • F17C2201/03Orientation
    • F17C2201/032Orientation with substantially vertical main axis
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F17STORING OR DISTRIBUTING GASES OR LIQUIDS
    • F17CVESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
    • F17C2201/00Vessel construction, in particular geometry, arrangement or size
    • F17C2201/05Size
    • F17C2201/052Size large (>1000 m3)
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F17STORING OR DISTRIBUTING GASES OR LIQUIDS
    • F17CVESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
    • F17C2203/00Vessel construction, in particular walls or details thereof
    • F17C2203/03Thermal insulations
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F17STORING OR DISTRIBUTING GASES OR LIQUIDS
    • F17CVESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
    • F17C2205/00Vessel construction, in particular mounting arrangements, attachments or identifications means
    • F17C2205/03Fluid connections, filters, valves, closure means or other attachments
    • F17C2205/0302Fittings, valves, filters, or components in connection with the gas storage device
    • F17C2205/0323Valves
    • F17C2205/0326Valves electrically actuated
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F17STORING OR DISTRIBUTING GASES OR LIQUIDS
    • F17CVESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
    • F17C2205/00Vessel construction, in particular mounting arrangements, attachments or identifications means
    • F17C2205/03Fluid connections, filters, valves, closure means or other attachments
    • F17C2205/0302Fittings, valves, filters, or components in connection with the gas storage device
    • F17C2205/0323Valves
    • F17C2205/0329Valves manually actuated
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F17STORING OR DISTRIBUTING GASES OR LIQUIDS
    • F17CVESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
    • F17C2221/00Handled fluid, in particular type of fluid
    • F17C2221/03Mixtures
    • F17C2221/032Hydrocarbons
    • F17C2221/033Methane, e.g. natural gas, CNG, LNG, GNL, GNC, PLNG
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F17STORING OR DISTRIBUTING GASES OR LIQUIDS
    • F17CVESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
    • F17C2223/00Handled fluid before transfer, i.e. state of fluid when stored in the vessel or before transfer from the vessel
    • F17C2223/01Handled fluid before transfer, i.e. state of fluid when stored in the vessel or before transfer from the vessel characterised by the phase
    • F17C2223/0146Two-phase
    • F17C2223/0153Liquefied gas, e.g. LPG, GPL
    • F17C2223/0161Liquefied gas, e.g. LPG, GPL cryogenic, e.g. LNG, GNL, PLNG
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F17STORING OR DISTRIBUTING GASES OR LIQUIDS
    • F17CVESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
    • F17C2223/00Handled fluid before transfer, i.e. state of fluid when stored in the vessel or before transfer from the vessel
    • F17C2223/01Handled fluid before transfer, i.e. state of fluid when stored in the vessel or before transfer from the vessel characterised by the phase
    • F17C2223/0146Two-phase
    • F17C2223/0153Liquefied gas, e.g. LPG, GPL
    • F17C2223/0169Liquefied gas, e.g. LPG, GPL subcooled
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F17STORING OR DISTRIBUTING GASES OR LIQUIDS
    • F17CVESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
    • F17C2223/00Handled fluid before transfer, i.e. state of fluid when stored in the vessel or before transfer from the vessel
    • F17C2223/03Handled fluid before transfer, i.e. state of fluid when stored in the vessel or before transfer from the vessel characterised by the pressure level
    • F17C2223/033Small pressure, e.g. for liquefied gas
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F17STORING OR DISTRIBUTING GASES OR LIQUIDS
    • F17CVESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
    • F17C2227/00Transfer of fluids, i.e. method or means for transferring the fluid; Heat exchange with the fluid
    • F17C2227/01Propulsion of the fluid
    • F17C2227/0128Propulsion of the fluid with pumps or compressors
    • F17C2227/0135Pumps
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F17STORING OR DISTRIBUTING GASES OR LIQUIDS
    • F17CVESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
    • F17C2227/00Transfer of fluids, i.e. method or means for transferring the fluid; Heat exchange with the fluid
    • F17C2227/01Propulsion of the fluid
    • F17C2227/0128Propulsion of the fluid with pumps or compressors
    • F17C2227/0157Compressors
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F17STORING OR DISTRIBUTING GASES OR LIQUIDS
    • F17CVESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
    • F17C2227/00Transfer of fluids, i.e. method or means for transferring the fluid; Heat exchange with the fluid
    • F17C2227/03Heat exchange with the fluid
    • F17C2227/0337Heat exchange with the fluid by cooling
    • F17C2227/0341Heat exchange with the fluid by cooling using another fluid
    • F17C2227/0355Heat exchange with the fluid by cooling using another fluid in a closed loop
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F17STORING OR DISTRIBUTING GASES OR LIQUIDS
    • F17CVESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
    • F17C2227/00Transfer of fluids, i.e. method or means for transferring the fluid; Heat exchange with the fluid
    • F17C2227/03Heat exchange with the fluid
    • F17C2227/0337Heat exchange with the fluid by cooling
    • F17C2227/0358Heat exchange with the fluid by cooling by expansion
    • F17C2227/0362Heat exchange with the fluid by cooling by expansion in a turbine
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F17STORING OR DISTRIBUTING GASES OR LIQUIDS
    • F17CVESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
    • F17C2227/00Transfer of fluids, i.e. method or means for transferring the fluid; Heat exchange with the fluid
    • F17C2227/03Heat exchange with the fluid
    • F17C2227/0367Localisation of heat exchange
    • F17C2227/0369Localisation of heat exchange in or on a vessel
    • F17C2227/0376Localisation of heat exchange in or on a vessel in wall contact
    • F17C2227/0383Localisation of heat exchange in or on a vessel in wall contact outside the vessel
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F17STORING OR DISTRIBUTING GASES OR LIQUIDS
    • F17CVESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
    • F17C2250/00Accessories; Control means; Indicating, measuring or monitoring of parameters
    • F17C2250/03Control means
    • F17C2250/032Control means using computers
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F17STORING OR DISTRIBUTING GASES OR LIQUIDS
    • F17CVESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
    • F17C2250/00Accessories; Control means; Indicating, measuring or monitoring of parameters
    • F17C2250/04Indicating or measuring of parameters as input values
    • F17C2250/0404Parameters indicated or measured
    • F17C2250/043Pressure
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F17STORING OR DISTRIBUTING GASES OR LIQUIDS
    • F17CVESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
    • F17C2250/00Accessories; Control means; Indicating, measuring or monitoring of parameters
    • F17C2250/04Indicating or measuring of parameters as input values
    • F17C2250/0404Parameters indicated or measured
    • F17C2250/0439Temperature
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F17STORING OR DISTRIBUTING GASES OR LIQUIDS
    • F17CVESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
    • F17C2250/00Accessories; Control means; Indicating, measuring or monitoring of parameters
    • F17C2250/06Controlling or regulating of parameters as output values
    • F17C2250/0605Parameters
    • F17C2250/0626Pressure
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F17STORING OR DISTRIBUTING GASES OR LIQUIDS
    • F17CVESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
    • F17C2250/00Accessories; Control means; Indicating, measuring or monitoring of parameters
    • F17C2250/06Controlling or regulating of parameters as output values
    • F17C2250/0605Parameters
    • F17C2250/0631Temperature
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F17STORING OR DISTRIBUTING GASES OR LIQUIDS
    • F17CVESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
    • F17C2250/00Accessories; Control means; Indicating, measuring or monitoring of parameters
    • F17C2250/07Actions triggered by measured parameters
    • F17C2250/072Action when predefined value is reached
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
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    • F17CVESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
    • F17C2260/00Purposes of gas storage and gas handling
    • F17C2260/03Dealing with losses
    • F17C2260/031Dealing with losses due to heat transfer
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F17STORING OR DISTRIBUTING GASES OR LIQUIDS
    • F17CVESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
    • F17C2260/00Purposes of gas storage and gas handling
    • F17C2260/03Dealing with losses
    • F17C2260/031Dealing with losses due to heat transfer
    • F17C2260/032Avoiding freezing or defrosting
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F17STORING OR DISTRIBUTING GASES OR LIQUIDS
    • F17CVESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
    • F17C2260/00Purposes of gas storage and gas handling
    • F17C2260/04Reducing risks and environmental impact
    • F17C2260/044Avoiding pollution or contamination
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F17STORING OR DISTRIBUTING GASES OR LIQUIDS
    • F17CVESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
    • F17C2260/00Purposes of gas storage and gas handling
    • F17C2260/04Reducing risks and environmental impact
    • F17C2260/046Enhancing energy recovery
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F17STORING OR DISTRIBUTING GASES OR LIQUIDS
    • F17CVESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
    • F17C2265/00Effects achieved by gas storage or gas handling
    • F17C2265/03Treating the boil-off
    • F17C2265/032Treating the boil-off by recovery
    • F17C2265/033Treating the boil-off by recovery with cooling
    • F17C2265/035Treating the boil-off by recovery with cooling with subcooling the liquid phase
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F17STORING OR DISTRIBUTING GASES OR LIQUIDS
    • F17CVESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
    • F17C2265/00Effects achieved by gas storage or gas handling
    • F17C2265/06Fluid distribution
    • F17C2265/066Fluid distribution for feeding engines for propulsion
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F17STORING OR DISTRIBUTING GASES OR LIQUIDS
    • F17CVESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
    • F17C2270/00Applications
    • F17C2270/01Applications for fluid transport or storage
    • F17C2270/0102Applications for fluid transport or storage on or in the water
    • F17C2270/0105Ships
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25JLIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J2290/00Other details not covered by groups F25J2200/00 - F25J2280/00
    • F25J2290/34Details about subcooling of liquids

Definitions

  • the present invention relates to a method and a system for refrigerating a cryogenic storage tank.
  • the invention also relates to the use of the method onboard a sea-going LNG carrier and to a ship comprising a system according to the invention.
  • the invention is of particular relevance for the transport of natural gas in liquid form especially in sea-going LNG carriers and is primarily described herein with reference to this application. It is, however, to be understood that it is also applicable to other cryogenic liquids or cryogenic liquid mixtures.
  • LNG is normally liquefied and transported at -162°C. Before being liquefied, the natural gas is treated to remove components that could freeze at this temperature like heavier hydrocarbon having more than six carbon atoms, benzene and aromatics, carbon dioxide, water etc...
  • a stream of dry and lean natural gas is obtained, mainly comprising the components methane, ethane, propane, butane, along with a few mole percent of nitrogen.
  • Boil-Off Gas BOG
  • This BOG flow is used as fuel for the motors of the ship.
  • the evaporation is higher than the demand from the motors, resulting in a loss of cargo as not all the BOG can be used as fuel for the motors and the BOG in excess must then be disposed by incineration.
  • Subcooling means to cool down a liquid to a temperature below its condensation point, at a given pressure
  • Subcoolers are cryogenic refrigeration systems using the compression, cooling and expansion of a refrigerant stream to create cold energy, which is then transferred to the LNG stream withdrawn from the storage tank in a cryogenic heat exchanger by indirect heat exchanger with the refrigerant stream.
  • the excessive heat ingress can be compensated by cooling, preferably subcooling, a part of the LNG. This is achieved by pumping a flow of LNG from a storage tank of the ship, (sub-) cooling the LNG stream in a so-called “subcooler”, and then re-injecting the (sub-) cooled LNG stream inside the storage tank.
  • the LNG shall be subcooled down to ca. - 175°C, a temperature level significantly colder than the -162°C usually found along the whole LNG chain.
  • the wall temperature may even reach a temperature of -178°C.
  • the LNG being only treated to avoid freezing at -162°C, there is a risk of freezing of some components of the LNG because of the significantly colder temperature inside the subcooling heat exchanger.
  • WO202 1/023428 discloses a refrigeration process in which in case of freezing, impurities are removed by decreasing the cooling power by inverting the direction of rotation of at least one of the motors of the refrigeration cycle. Because of the decrease in cooling power, the LNG stored in the storage tank could no longer be subcooled enough to balance the heat ingress, resulting in a loss of LNG due to excessive evaporation.
  • WO 2021/023457 Al discloses a refrigeration process in which in case of freezing, impurities are removed by stopping the refrigeration cycle and then no longer providing any cooling power to balance the heat ingress to the storage tank, resulting in a loss of LNG due to excessive evaporation.
  • WO 2021/023458 Al discloses a method for defrosting a cryogenic heat exchanger by opening a by-pass valve bypassing said cryogenic heat exchanger. This could lead to disturbance of the thermal load and temperature gradient inside the cryogenic heat exchanger, which could result in differential thermal dilatation between the different channels and thus a catastrophic failure of this equipment because of the thermally induced mechanical stress.
  • a method for refrigerating a first cryogenic storage tank wherein a first flow of a cryogenic fluid stored inside the first cryogenic storage tank is pumped out of the first cryogenic storage tank, subcooled inside a subcooling heat exchanger and reinjected into the first cryogenic storage tank.
  • the first cryogenic storage tank is refrigerated by the reinjection of the colder first flow of the cryogenic fluid into the storage tank.
  • the first flow of the cryogenic fluid is made colder by subcooling it inside the subcooling heat exchanger by indirect heat-transfer with a gaseous refrigerant circulating inside a closed cryogenic refrigeration loop, the closed cryogenic refrigeration loop comprising at least one expansion turbine to expand the gaseous refrigerant from a high pressure to a low pressure and the subcooling heat-exchanger to indirectly transfer heat from the first flow of the cryogenic fluid to the gaseous refrigerant, the subcooling heat exchanger being located downstream the at least one expansion turbine.
  • the gaseous refrigerant circulating inside the closed cryogenic refrigeration loop is always in gaseous state in any section of the cryogenic refrigeration loop. There is no refrigerant in liquid phase in any point of the cryogenic refrigeration loop, thus allowing to simplify operation by avoiding to control any liquid level in gas/liquid separator, which can be unreliable when on moving environment like a ship at sea.
  • the subcooling heat exchanger being located downstream the expansion turbine is with reference to the circulation of the gaseous refrigerant inside the cryogenic refrigeration loop, i.e. the gaseous refrigerant circulating inside the closed refrigeration loop is first expanded from a high pressure to a low pressure inside the expansion turbine, and then the low pressure gaseous refrigerant indirectly exchanges heat with the first flow of cryogenic fluid pumped from the first storage tank inside the subcooling heat exchanger.
  • the method further comprises the steps of:
  • Defrosting the subcooling heat exchanger by partially opening a control valve located on a bypass line bypassing a part of the gaseous refrigerant around only the at least one expansion turbine, and
  • Opening a control valve located on a bypass line bypassing a part of the gaseous refrigerant around the expansion turbine allows to decrease the amount of refrigeration performed by isentropic expansion of the gaseous refrigerant through the turbine as less gaseous refrigerant is expanded through the expansion turbine, and to isenthalpically expand the part of the gaseous refrigerant bypassed through the bypass valve.
  • increasing the first flow of the cryogenic fluid pumped from the first storage tank allows to compensate the increase of temperature of the first flow of cryogenic fluid resulting from the increase of temperature of the gaseous refrigerant because the smaller mass enthalpy drop of the first flow of the cryogenic fluid being subcooled in the subcooling heat-exchanger is compensated by a higher mass flow of the cryogenic liquid passing through the subcooling heat-exchanger. In that way there is no decrease of the refrigeration power of the closed cryogenic refrigeration loop.
  • the increase of the first flow of cryogenic fluid circulating inside the cryogenic heat exchanger also increases the pressure drop within the channels of the subcooling heat exchanger obstructed by the frozen components, thus resulting in an additional mechanical force exerted by the first flow of the cryogenic fluid on the component frozen inside the cryogenic fluid path of the subcooling heat exchanger, thus contributing to the mechanical removal of the frozen components from the heat exchanger.
  • the opening of the bypass valve is adjusted to increase the temperature of the gaseous refrigerant entering the subcooling heat-exchanger above the freezing point of the first flow of the cryogenic fluid pumped from the first cryogenic storage tank.
  • the temperature increase of the gaseous refrigerant entering the subcooling heat exchanger is within the range from 0.1 °C to 10 °C, preferably from 0.1 to 5 °C, more preferably from 0.1 to 1 °C above the freezing point of the first flow of the cryogenic fluid pumped from the first cryogenic storage tank.
  • the freezing point of the cryogenic fluid can be determined by in-situ direct determination of the composition of the cryogenic fluid, for example by chromatography of a gas sample of the cryogenic fluid, or by an indirect measurement of one or more physical parameters of the cryogenic fluid like thermal conductivity of sound celerity, which are correlated to the freezing point.
  • the increase of the first flow of the cryogenic fluid pumped from the at least one cryogenic storage tank can be adjusted to compensate the heat ingress to the at least one cryogenic storage tank
  • a second flow of the cryogenic fluid can be pumped out a second cryogenic storage tank, and mixed with the first flow of the cryogenic fluid pumped out of the first cryogenic storage tank and then subcooling both the first and the second flows of the cryogenic fluid into the subcooling heat-exchanger.
  • the occurrence of freezing of at least one component of the cryogenic fluid inside the subcooling heat exchanger is detected by measuring a pressure drop across the cryogenic fluid path of the subcooling heat exchanger.
  • the at least one expansion turbine of the closed cryogenic refrigeration loop drives at least a compressor for compressing the gaseous refrigerant of the closed cryogenic refrigeration loop through a direct mechanical connection between the at least one expansion turbine and the at least one compressor, the at least one compressor being driven only by the at least one expansion turbine.
  • the expansion turbine can be directly connected to the highest-pressure compressor. The expansion turbine being partly bypassed, the mechanical energy recovered by the turbine and transferred to the compressor is decreased, and as there is no motor connected between the compressor and the turbine, the pressure ratio of the compressor decreases accordingly.
  • the present invention relates to a system for refrigerating at a first cryogenic storage tank comprising:
  • a subcooling heat exchanger fluidically connected to the first pump immerged into the cryogenic fluid stored into the first cryogenic storage tank for subcooling the first flow of the cryogenic fluid pumped out of first cryogenic storage tank by indirect heat exchange with a gaseous refrigerant circulating inside a closed cryogenic refrigeration loop, the closed cryogenic refrigeration loop comprising at least one expansion turbine for expanding the gaseous refrigerant from a high pressure to a low pressure, the subcooling heat exchanger being located downstream of the expansion turbine;
  • a control valve located on a bypass line, the bypass line bypassing only the at least one expansion turbine
  • - Command and control computer means for opening of the control valve located on the bypass line of the at least one expansion turbine and for simultaneously increasing the first flow of the cryogenic fluid pumped out of the first cryogenic storage tank by the first pump located inside the first cryogenic storage tank if the freezing of at least one component of the first flow of the cryogenic fluid inside the subcooling heatexchanger is detected.
  • the system can optionally comprise a second pump immerged into the cryogenic fluid stored into a second cryogenic storage tank for pumping a second flow of the cryogenic fluid out of the second cryogenic storage tank, the first flow and the second flow of the cryogenic fluid being mixed together before being subcooled together inside a subcooling heatexchanger by indirect heat transfer with a gaseous refrigerant circulating inside the closed cryogenic refrigeration loop.
  • the means for detecting the occurrence of freezing of at least one component of the first flow of the cryogenic fluid pumped from the first cryogenic storage tank inside the subcooling heat exchanger comprises a differential pressure transmitter for measuring the differential pressure across the cryogenic fluid path of the subcooling heat exchanger.
  • the closed cryogenic refrigeration loop comprises at least one centrifugal compressor for compressing the gaseous refrigerant circulating inside the closed cryogenic refrigeration loop, the at least one centrifugal compressor being directly connected and only driven by the at least one expansion turbine of the closed cryogenic refrigeration loop.
  • a third aspect for which protection is sought, but which also represents an embodiment of the present invention according to the first aspect, is directed to the use of the method according to claims 1 to 7 onboard a sea-going LNG carrier.
  • a fourth aspect for which protection is sought, but which also represents an embodiment of the present invention according to the second aspect, is directed to a ship comprising a system according to any of claims 8 to 11.
  • the ship is a LNG carrier.
  • FIG. 1 schematically shows a preferred embodiment of a method and a system according to the invention. Detailed description of the drawings
  • the cryogenic fluid is LNG stored at a temperature of for example about -162°C inside a first cryogenic tank 1 of a sea-going vessel (not shown).
  • LNG is typically composed of nitrogen, methane, ethane, propane, butane with ppmv level traces of benzene, carbon dioxide and water.
  • BOG Boil-Off-Gas
  • cryogenic fluid path 10 being the channels of the subcooling heat exchanger 3 dedicated to the cryogenic fluid
  • a signal is send by the differential pressure transmitter to computing means 9 where a command signal will be send simultaneously to a bypass valve 6 located on a bypass line 7 bypassing only the expansion turbine 5 of the closed cryogenic refrigeration loop 4 and to the pump 101 immerged into the first storage tank.
  • At least one expansion turbine 5 of the closed cryogenic refrigeration loop 4 drives at least a compressor 13; 14; 15 for compressing the gaseous refrigerant of the closed cryogenic refrigeration loop 4 through a direct mechanical connection between the at least one expansion turbine 5 and the at least one compressor 13; 14; 15, the at least one compressor 13; 14; 15 being driven only by the at least one expansion turbine 5.
  • the expansion turbine 5 can be directly connected to the highest- pressure compressor 15, the highest-pressure compressor 15 being the compressor compressing the gaseous refrigerant at the highest pressure level.

Landscapes

  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • General Engineering & Computer Science (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Ocean & Marine Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Combustion & Propulsion (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Filling Or Discharging Of Gas Storage Vessels (AREA)
EP23701839.5A 2022-01-28 2023-01-23 Verfahren und system zum kühlen eines kryogenen speicherbehälters Active EP4469716B1 (de)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
EP22315026 2022-01-28
PCT/EP2023/025030 WO2023143865A1 (en) 2022-01-28 2023-01-23 Method and system for refrigerating a cryogenic storage tank

Publications (3)

Publication Number Publication Date
EP4469716A1 true EP4469716A1 (de) 2024-12-04
EP4469716C0 EP4469716C0 (de) 2026-03-04
EP4469716B1 EP4469716B1 (de) 2026-03-04

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KR (1) KR20240141171A (de)
CN (1) CN118647825A (de)
WO (1) WO2023143865A1 (de)

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CN118980045A (zh) * 2023-12-15 2024-11-19 酷泰克保温科技江苏有限公司 一种lng低温储罐罐壁保冷设备

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* Cited by examiner, † Cited by third party
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DE102013018333A1 (de) * 2013-10-31 2015-04-30 Linde Aktiengesellschaft Boil-off-Gas-Management
FR3066257B1 (fr) * 2018-01-23 2019-09-13 Gaztransport Et Technigaz Pompe a chaleur cryogenique et son utilisation pour le traitement de gaz liquefie
EP3434959A1 (de) * 2017-07-28 2019-01-30 Cryostar SAS Verfahren und vorrichtung zur lagerung von flüssiggas in einem behälter und zur entnahme von verdampftem gas aus einem behälter
FR3099817B1 (fr) 2019-08-05 2022-11-04 Air Liquide Procédé et installation de refroidissement et/ou de liquéfaction.
FR3099816B1 (fr) 2019-08-05 2022-10-21 Air Liquide Procédé, dispositif et installation de réfrigération et/ou de liquéfaction
FR3099818B1 (fr) 2019-08-05 2022-11-04 Air Liquide Dispositif de réfrigération et installation et procédé de refroidissement et/ou de liquéfaction

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EP4469716C0 (de) 2026-03-04
EP4469716B1 (de) 2026-03-04
KR20240141171A (ko) 2024-09-25
CN118647825A (zh) 2024-09-13

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