EP4397786A1

EP4397786A1 - Composition de revêtement de conversion pour couches colorées sur de l'aluminium

Composition de revêtement de conversion pour couches colorées sur de l'aluminium Download PDF

Info

Publication number: EP4397786A1
Authority: EP; European Patent Office
Prior art keywords: acid; water; composition; salt; composition according
Prior art date: 2023-01-03
Legal status : Pending

Application number

EP23150086.9A

Other languages

German (de)

English (en)

Inventor

Aditi Jadhav

Niranjan Das

Priya Thakur

Current Assignee

Henkel AG and Co KGaA

Original Assignee

Henkel AG and Co KGaA

Filing date

2023-01-03

Publication date

2024-07-10

2023-01-03 Application filed by Henkel AG and Co KGaA filed Critical Henkel AG and Co KGaA

2024-07-10 Publication of EP4397786A1 publication Critical patent/EP4397786A1/fr

Status Pending legal-status Critical Current

Links

238000007739 conversion coating Methods 0.000 title claims abstract description 67
229910052782 aluminium Inorganic materials 0.000 title claims abstract description 53
239000008199 coating composition Substances 0.000 title claims abstract description 51
XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 title claims abstract description 43
239000004411 aluminium Substances 0.000 title claims abstract description 33
239000000203 mixture Substances 0.000 claims abstract description 106
239000002253 acid Substances 0.000 claims abstract description 72
150000003839 salts Chemical class 0.000 claims abstract description 37
238000011282 treatment Methods 0.000 claims abstract description 21
229910000838 Al alloy Inorganic materials 0.000 claims abstract description 20
PBYZMCDFOULPGH-UHFFFAOYSA-N tungstate Chemical class [O-][W]([O-])(=O)=O PBYZMCDFOULPGH-UHFFFAOYSA-N 0.000 claims abstract description 20
229910052500 inorganic mineral Inorganic materials 0.000 claims abstract description 18
239000011707 mineral Substances 0.000 claims abstract description 18
239000011651 chromium Substances 0.000 claims abstract description 14
VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 claims abstract description 10
229910052804 chromium Inorganic materials 0.000 claims abstract description 10
150000001875 compounds Chemical class 0.000 claims abstract description 10
229910052726 zirconium Inorganic materials 0.000 claims abstract description 10
229910052710 silicon Inorganic materials 0.000 claims abstract description 9
229910052719 titanium Inorganic materials 0.000 claims abstract description 8
229910052735 hafnium Inorganic materials 0.000 claims abstract description 6
229910052796 boron Inorganic materials 0.000 claims abstract description 5
229910052732 germanium Inorganic materials 0.000 claims abstract description 4
229910052718 tin Inorganic materials 0.000 claims abstract description 4
238000000576 coating method Methods 0.000 claims description 42
239000000758 substrate Substances 0.000 claims description 37
-1 methylene phosphonic acid Chemical compound 0.000 claims description 36
239000011248 coating agent Substances 0.000 claims description 33
239000011734 sodium Substances 0.000 claims description 29
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 25
NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 claims description 23
DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 20
229910052708 sodium Inorganic materials 0.000 claims description 20
ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 claims description 16
238000000034 method Methods 0.000 claims description 16
239000011591 potassium Substances 0.000 claims description 16
229910052700 potassium Inorganic materials 0.000 claims description 16
DBVJJBKOTRCVKF-UHFFFAOYSA-N Etidronic acid Chemical compound OP(=O)(O)C(O)(C)P(O)(O)=O DBVJJBKOTRCVKF-UHFFFAOYSA-N 0.000 claims description 12
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230000008569 process Effects 0.000 claims description 9
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XMVONEAAOPAGAO-UHFFFAOYSA-N sodium tungstate Chemical compound [Na+].[Na+].[O-][W]([O-])(=O)=O XMVONEAAOPAGAO-UHFFFAOYSA-N 0.000 claims description 8
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229910003708 H2TiF6 Inorganic materials 0.000 claims description 6
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WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 claims description 5
229910052744 lithium Inorganic materials 0.000 claims description 5
150000002823 nitrates Chemical class 0.000 claims description 5
229910003899 H2ZrF6 Inorganic materials 0.000 claims description 4
YDONNITUKPKTIG-UHFFFAOYSA-N [Nitrilotris(methylene)]trisphosphonic acid Chemical compound OP(O)(=O)CN(CP(O)(O)=O)CP(O)(O)=O YDONNITUKPKTIG-UHFFFAOYSA-N 0.000 claims description 4
NAQMVNRVTILPCV-UHFFFAOYSA-N hexane-1,6-diamine Chemical compound NCCCCCCN NAQMVNRVTILPCV-UHFFFAOYSA-N 0.000 claims description 4
239000001117 sulphuric acid Substances 0.000 claims description 4
235000011149 sulphuric acid Nutrition 0.000 claims description 4
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229910004039 HBF4 Inorganic materials 0.000 claims description 2
ZEFWRWWINDLIIV-UHFFFAOYSA-N tetrafluorosilane;dihydrofluoride Chemical compound F.F.F[Si](F)(F)F ZEFWRWWINDLIIV-UHFFFAOYSA-N 0.000 claims description 2
RPNUMPOLZDHAAY-UHFFFAOYSA-N Diethylenetriamine Chemical compound NCCNCCN RPNUMPOLZDHAAY-UHFFFAOYSA-N 0.000 claims 1
229910052751 metal Inorganic materials 0.000 description 26
239000002184 metal Substances 0.000 description 26
238000012360 testing method Methods 0.000 description 20
239000001993 wax Substances 0.000 description 20
238000005260 corrosion Methods 0.000 description 16
230000007797 corrosion Effects 0.000 description 16
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238000005507 spraying Methods 0.000 description 12
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150000002367 halogens Chemical group 0.000 description 10
229910052749 magnesium Inorganic materials 0.000 description 10
239000000463 material Substances 0.000 description 10
239000000243 solution Substances 0.000 description 9
238000006243 chemical reaction Methods 0.000 description 8
235000011007 phosphoric acid Nutrition 0.000 description 8
FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 7
230000002378 acidificating effect Effects 0.000 description 7
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239000000956 alloy Substances 0.000 description 7
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150000002739 metals Chemical class 0.000 description 7
ZCDOYSPFYFSLEW-UHFFFAOYSA-N chromate(2-) Chemical class [O-][Cr]([O-])(=O)=O ZCDOYSPFYFSLEW-UHFFFAOYSA-N 0.000 description 6
238000004140 cleaning Methods 0.000 description 6
239000010949 copper Substances 0.000 description 6
229910052736 halogen Inorganic materials 0.000 description 6
239000000843 powder Substances 0.000 description 6
238000006467 substitution reaction Methods 0.000 description 6
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238000011179 visual inspection Methods 0.000 description 6
239000011701 zinc Substances 0.000 description 6
XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 5
PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 5
239000003570 air Substances 0.000 description 5
125000000217 alkyl group Chemical group 0.000 description 5
150000001450 anions Chemical class 0.000 description 5
125000003118 aryl group Chemical group 0.000 description 5
239000002585 base Substances 0.000 description 5
238000005238 degreasing Methods 0.000 description 5
125000005842 heteroatom Chemical group 0.000 description 5
239000007788 liquid Substances 0.000 description 5
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239000010936 titanium Substances 0.000 description 5
150000003624 transition metals Chemical class 0.000 description 5
IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 4
AEMRFAOFKBGASW-UHFFFAOYSA-N Glycolic acid Chemical compound OCC(O)=O AEMRFAOFKBGASW-UHFFFAOYSA-N 0.000 description 4
239000004743 Polypropylene Substances 0.000 description 4
FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 4
QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 4
150000007513 acids Chemical class 0.000 description 4
229910052783 alkali metal Inorganic materials 0.000 description 4
125000003342 alkenyl group Chemical group 0.000 description 4
125000004429 atom Chemical group 0.000 description 4
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229920001577 copolymer Polymers 0.000 description 4
125000004122 cyclic group Chemical group 0.000 description 4
125000000753 cycloalkyl group Chemical group 0.000 description 4
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RGHNJXZEOKUKBD-UHFFFAOYSA-N D-gluconic acid Natural products OCC(O)C(O)C(O)C(O)C(O)=O RGHNJXZEOKUKBD-UHFFFAOYSA-N 0.000 description 3
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RGHNJXZEOKUKBD-SQOUGZDYSA-N Gluconic acid Natural products OC[C@@H](O)[C@@H](O)[C@H](O)[C@@H](O)C(O)=O RGHNJXZEOKUKBD-SQOUGZDYSA-N 0.000 description 3
239000004698 Polyethylene Substances 0.000 description 3
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229910000831 Steel Inorganic materials 0.000 description 3
HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 3
QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 3
125000002619 bicyclic group Chemical group 0.000 description 3
239000011575 calcium Substances 0.000 description 3
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125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 3
KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 3
239000012141 concentrate Substances 0.000 description 3
229910052802 copper Inorganic materials 0.000 description 3
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239000010410 layer Substances 0.000 description 3
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239000011572 manganese Substances 0.000 description 3
230000007935 neutral effect Effects 0.000 description 3
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125000001424 substituent group Chemical group 0.000 description 3
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229910019985 (NH4)2TiF6 Inorganic materials 0.000 description 2
URDCARMUOSMFFI-UHFFFAOYSA-N 2-[2-[bis(carboxymethyl)amino]ethyl-(2-hydroxyethyl)amino]acetic acid Chemical compound OCCN(CC(O)=O)CCN(CC(O)=O)CC(O)=O URDCARMUOSMFFI-UHFFFAOYSA-N 0.000 description 2
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125000000041 C6-C10 aryl group Chemical group 0.000 description 2
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239000011975 tartaric acid Substances 0.000 description 1
235000002906 tartaric acid Nutrition 0.000 description 1
JBQYATWDVHIOAR-UHFFFAOYSA-N tellanylidenegermanium Chemical compound [Te]=[Ge] JBQYATWDVHIOAR-UHFFFAOYSA-N 0.000 description 1
NNCGPRGCYAWTAF-UHFFFAOYSA-N tellurium hexafluoride Chemical compound F[Te](F)(F)(F)(F)F NNCGPRGCYAWTAF-UHFFFAOYSA-N 0.000 description 1
125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 1
231100000331 toxic Toxicity 0.000 description 1
230000002588 toxic effect Effects 0.000 description 1
230000002110 toxicologic effect Effects 0.000 description 1
231100000723 toxicological property Toxicity 0.000 description 1
230000009466 transformation Effects 0.000 description 1
UBOXGVDOUJQMTN-UHFFFAOYSA-N trichloroethylene Natural products ClCC(Cl)Cl UBOXGVDOUJQMTN-UHFFFAOYSA-N 0.000 description 1
GSEJCLTVZPLZKY-UHFFFAOYSA-O triethanolammonium Chemical compound OCC[NH+](CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-O 0.000 description 1
GPPXJZIENCGNKB-UHFFFAOYSA-N vanadium Chemical compound [V]#[V] GPPXJZIENCGNKB-UHFFFAOYSA-N 0.000 description 1
125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
239000002699 waste material Substances 0.000 description 1
238000003466 welding Methods 0.000 description 1
239000000080 wetting agent Substances 0.000 description 1
229910009112 xH2O Inorganic materials 0.000 description 1
GBNDTYKAOXLLID-UHFFFAOYSA-N zirconium(4+) ion Chemical compound [Zr+4] GBNDTYKAOXLLID-UHFFFAOYSA-N 0.000 description 1

EP23150086.9A 2023-01-03 Composition de revêtement de conversion pour couches colorées sur de l'aluminium Pending EP4397786A1 (fr)