EP4373306A1 - Aerosol generating composition - Google Patents
Aerosol generating compositionInfo
- Publication number
- EP4373306A1 EP4373306A1 EP22754096.0A EP22754096A EP4373306A1 EP 4373306 A1 EP4373306 A1 EP 4373306A1 EP 22754096 A EP22754096 A EP 22754096A EP 4373306 A1 EP4373306 A1 EP 4373306A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- aerosol
- generating material
- generating
- slurry
- amount
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
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- VFLDPWHFBUODDF-FCXRPNKRSA-N curcumin Chemical compound C1=C(O)C(OC)=CC(\C=C\C(=O)CC(=O)\C=C\C=2C=C(OC)C(O)=CC=2)=C1 VFLDPWHFBUODDF-FCXRPNKRSA-N 0.000 description 1
- HCAJEUSONLESMK-UHFFFAOYSA-N cyclohexylsulfamic acid Chemical class OS(=O)(=O)NC1CCCCC1 HCAJEUSONLESMK-UHFFFAOYSA-N 0.000 description 1
- 230000000779 depleting effect Effects 0.000 description 1
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- 238000010586 diagram Methods 0.000 description 1
- XBDQKXXYIPTUBI-UHFFFAOYSA-N dimethylselenoniopropionate Natural products CCC(O)=O XBDQKXXYIPTUBI-UHFFFAOYSA-N 0.000 description 1
- 150000007520 diprotic acids Chemical class 0.000 description 1
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- 238000005516 engineering process Methods 0.000 description 1
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- 229940009714 erythritol Drugs 0.000 description 1
- BEFDCLMNVWHSGT-UHFFFAOYSA-N ethenylcyclopentane Chemical compound C=CC1CCCC1 BEFDCLMNVWHSGT-UHFFFAOYSA-N 0.000 description 1
- 235000008995 european elder Nutrition 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 239000012765 fibrous filler Substances 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 235000019264 food flavour enhancer Nutrition 0.000 description 1
- 235000019253 formic acid Nutrition 0.000 description 1
- 239000001530 fumaric acid Substances 0.000 description 1
- 235000011087 fumaric acid Nutrition 0.000 description 1
- 125000000524 functional group Chemical group 0.000 description 1
- 238000004817 gas chromatography Methods 0.000 description 1
- 235000013531 gin Nutrition 0.000 description 1
- 235000008397 ginger Nutrition 0.000 description 1
- 239000008103 glucose Substances 0.000 description 1
- 229960005150 glycerol Drugs 0.000 description 1
- LPLVUJXQOOQHMX-QWBHMCJMSA-N glycyrrhizinic acid Chemical compound O([C@@H]1[C@@H](O)[C@H](O)[C@H](O[C@@H]1O[C@@H]1C([C@H]2[C@]([C@@H]3[C@@]([C@@]4(CC[C@@]5(C)CC[C@@](C)(C[C@H]5C4=CC3=O)C(O)=O)C)(C)CC2)(C)CC1)(C)C)C(O)=O)[C@@H]1O[C@H](C(O)=O)[C@@H](O)[C@H](O)[C@H]1O LPLVUJXQOOQHMX-QWBHMCJMSA-N 0.000 description 1
- 229910021389 graphene Inorganic materials 0.000 description 1
- 229910002804 graphite Inorganic materials 0.000 description 1
- 239000010439 graphite Substances 0.000 description 1
- 239000011084 greaseproof paper Substances 0.000 description 1
- 235000009569 green tea Nutrition 0.000 description 1
- 229920006158 high molecular weight polymer Polymers 0.000 description 1
- 235000012907 honey Nutrition 0.000 description 1
- 230000001939 inductive effect Effects 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 238000001746 injection moulding Methods 0.000 description 1
- 239000011810 insulating material Substances 0.000 description 1
- 150000004715 keto acids Chemical class 0.000 description 1
- 239000008101 lactose Substances 0.000 description 1
- 239000001102 lavandula vera Substances 0.000 description 1
- 235000018219 lavender Nutrition 0.000 description 1
- 239000010501 lemon oil Substances 0.000 description 1
- 229940010454 licorice Drugs 0.000 description 1
- 239000004571 lime Substances 0.000 description 1
- 235000001510 limonene Nutrition 0.000 description 1
- 229940087305 limonene Drugs 0.000 description 1
- 235000011477 liquorice Nutrition 0.000 description 1
- 229910001416 lithium ion Inorganic materials 0.000 description 1
- 239000001115 mace Substances 0.000 description 1
- ZLNQQNXFFQJAID-UHFFFAOYSA-L magnesium carbonate Chemical compound [Mg+2].[O-]C([O-])=O ZLNQQNXFFQJAID-UHFFFAOYSA-L 0.000 description 1
- 239000001095 magnesium carbonate Substances 0.000 description 1
- 229910000021 magnesium carbonate Inorganic materials 0.000 description 1
- 239000000395 magnesium oxide Substances 0.000 description 1
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 1
- 229910052943 magnesium sulfate Inorganic materials 0.000 description 1
- 235000019341 magnesium sulphate Nutrition 0.000 description 1
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 description 1
- 239000001630 malic acid Substances 0.000 description 1
- 235000011090 malic acid Nutrition 0.000 description 1
- 239000000594 mannitol Substances 0.000 description 1
- 235000010355 mannitol Nutrition 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- OSWPMRLSEDHDFF-UHFFFAOYSA-N methyl salicylate Chemical compound COC(=O)C1=CC=CC=C1O OSWPMRLSEDHDFF-UHFFFAOYSA-N 0.000 description 1
- 150000007522 mineralic acids Chemical class 0.000 description 1
- 239000002808 molecular sieve Substances 0.000 description 1
- 150000007518 monoprotic acids Chemical class 0.000 description 1
- DUWWHGPELOTTOE-UHFFFAOYSA-N n-(5-chloro-2,4-dimethoxyphenyl)-3-oxobutanamide Chemical compound COC1=CC(OC)=C(NC(=O)CC(C)=O)C=C1Cl DUWWHGPELOTTOE-UHFFFAOYSA-N 0.000 description 1
- 239000000978 natural dye Substances 0.000 description 1
- 210000005036 nerve Anatomy 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- 230000006911 nucleation Effects 0.000 description 1
- 238000010899 nucleation Methods 0.000 description 1
- 239000001702 nutmeg Substances 0.000 description 1
- 229920001778 nylon Polymers 0.000 description 1
- 229940006093 opthalmologic coloring agent diagnostic Drugs 0.000 description 1
- 239000010502 orange oil Substances 0.000 description 1
- 150000007524 organic acids Chemical class 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 239000013618 particulate matter Substances 0.000 description 1
- 239000010451 perlite Substances 0.000 description 1
- 235000019362 perlite Nutrition 0.000 description 1
- 229920001721 polyimide Polymers 0.000 description 1
- 229920001282 polysaccharide Polymers 0.000 description 1
- 239000005017 polysaccharide Substances 0.000 description 1
- 150000004804 polysaccharides Chemical class 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 235000010408 potassium alginate Nutrition 0.000 description 1
- 239000000737 potassium alginate Substances 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 239000003755 preservative agent Substances 0.000 description 1
- 229940107700 pyruvic acid Drugs 0.000 description 1
- 230000005855 radiation Effects 0.000 description 1
- 230000000630 rising effect Effects 0.000 description 1
- 235000019719 rose oil Nutrition 0.000 description 1
- 239000010666 rose oil Substances 0.000 description 1
- 235000013533 rum Nutrition 0.000 description 1
- CVHZOJJKTDOEJC-UHFFFAOYSA-N saccharin Chemical compound C1=CC=C2C(=O)NS(=O)(=O)C2=C1 CVHZOJJKTDOEJC-UHFFFAOYSA-N 0.000 description 1
- 235000013974 saffron Nutrition 0.000 description 1
- 239000004248 saffron Substances 0.000 description 1
- 235000002020 sage Nutrition 0.000 description 1
- 230000001953 sensory effect Effects 0.000 description 1
- HQVNEWCFYHHQES-UHFFFAOYSA-N silicon nitride Chemical compound N12[Si]34N5[Si]62N3[Si]51N64 HQVNEWCFYHHQES-UHFFFAOYSA-N 0.000 description 1
- 239000000779 smoke Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 235000010413 sodium alginate Nutrition 0.000 description 1
- 239000000661 sodium alginate Substances 0.000 description 1
- URGAHOPLAPQHLN-UHFFFAOYSA-N sodium aluminosilicate Chemical compound [Na+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O URGAHOPLAPQHLN-UHFFFAOYSA-N 0.000 description 1
- 239000011343 solid material Substances 0.000 description 1
- 239000008247 solid mixture Substances 0.000 description 1
- 239000002594 sorbent Substances 0.000 description 1
- 239000004334 sorbic acid Substances 0.000 description 1
- 235000010199 sorbic acid Nutrition 0.000 description 1
- 229940075582 sorbic acid Drugs 0.000 description 1
- 239000000600 sorbitol Substances 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 229910001220 stainless steel Inorganic materials 0.000 description 1
- 239000010935 stainless steel Substances 0.000 description 1
- 230000000638 stimulation Effects 0.000 description 1
- 235000019408 sucralose Nutrition 0.000 description 1
- BAQAVOSOZGMPRM-QBMZZYIRSA-N sucralose Chemical compound O[C@@H]1[C@@H](O)[C@@H](Cl)[C@@H](CO)O[C@@H]1O[C@@]1(CCl)[C@@H](O)[C@H](O)[C@@H](CCl)O1 BAQAVOSOZGMPRM-QBMZZYIRSA-N 0.000 description 1
- 239000005720 sucrose Substances 0.000 description 1
- 235000000346 sugar Nutrition 0.000 description 1
- 235000021092 sugar substitutes Nutrition 0.000 description 1
- 150000008163 sugars Chemical class 0.000 description 1
- 239000001117 sulphuric acid Substances 0.000 description 1
- 235000011149 sulphuric acid Nutrition 0.000 description 1
- 230000008093 supporting effect Effects 0.000 description 1
- 230000003746 surface roughness Effects 0.000 description 1
- 239000003765 sweetening agent Substances 0.000 description 1
- 230000002195 synergetic effect Effects 0.000 description 1
- 239000000979 synthetic dye Substances 0.000 description 1
- 239000011975 tartaric acid Substances 0.000 description 1
- 235000002906 tartaric acid Nutrition 0.000 description 1
- 235000013616 tea Nutrition 0.000 description 1
- 235000013529 tequila Nutrition 0.000 description 1
- 229960000790 thymol Drugs 0.000 description 1
- 239000001585 thymus vulgaris Substances 0.000 description 1
- 231100000167 toxic agent Toxicity 0.000 description 1
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 1
- 150000003627 tricarboxylic acid derivatives Chemical class 0.000 description 1
- 235000001019 trigonella foenum-graecum Nutrition 0.000 description 1
- 150000007521 triprotic acids Chemical class 0.000 description 1
- 235000013976 turmeric Nutrition 0.000 description 1
- 238000011144 upstream manufacturing Methods 0.000 description 1
- 235000016788 valerian Nutrition 0.000 description 1
- 239000010455 vermiculite Substances 0.000 description 1
- 235000019354 vermiculite Nutrition 0.000 description 1
- 229910052902 vermiculite Inorganic materials 0.000 description 1
- 235000015041 whisky Nutrition 0.000 description 1
- 238000004804 winding Methods 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
- A24B—MANUFACTURE OR PREPARATION OF TOBACCO FOR SMOKING OR CHEWING; TOBACCO; SNUFF
- A24B15/00—Chemical features or treatment of tobacco; Tobacco substitutes, e.g. in liquid form
- A24B15/10—Chemical features of tobacco products or tobacco substitutes
- A24B15/16—Chemical features of tobacco products or tobacco substitutes of tobacco substitutes
-
- A—HUMAN NECESSITIES
- A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
- A24B—MANUFACTURE OR PREPARATION OF TOBACCO FOR SMOKING OR CHEWING; TOBACCO; SNUFF
- A24B15/00—Chemical features or treatment of tobacco; Tobacco substitutes, e.g. in liquid form
- A24B15/10—Chemical features of tobacco products or tobacco substitutes
- A24B15/12—Chemical features of tobacco products or tobacco substitutes of reconstituted tobacco
- A24B15/14—Chemical features of tobacco products or tobacco substitutes of reconstituted tobacco made of tobacco and a binding agent not derived from tobacco
-
- A—HUMAN NECESSITIES
- A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
- A24B—MANUFACTURE OR PREPARATION OF TOBACCO FOR SMOKING OR CHEWING; TOBACCO; SNUFF
- A24B15/00—Chemical features or treatment of tobacco; Tobacco substitutes, e.g. in liquid form
- A24B15/18—Treatment of tobacco products or tobacco substitutes
- A24B15/28—Treatment of tobacco products or tobacco substitutes by chemical substances
- A24B15/30—Treatment of tobacco products or tobacco substitutes by chemical substances by organic substances
- A24B15/302—Treatment of tobacco products or tobacco substitutes by chemical substances by organic substances by natural substances obtained from animals or plants
-
- A—HUMAN NECESSITIES
- A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
- A24B—MANUFACTURE OR PREPARATION OF TOBACCO FOR SMOKING OR CHEWING; TOBACCO; SNUFF
- A24B15/00—Chemical features or treatment of tobacco; Tobacco substitutes, e.g. in liquid form
- A24B15/18—Treatment of tobacco products or tobacco substitutes
- A24B15/28—Treatment of tobacco products or tobacco substitutes by chemical substances
- A24B15/30—Treatment of tobacco products or tobacco substitutes by chemical substances by organic substances
- A24B15/302—Treatment of tobacco products or tobacco substitutes by chemical substances by organic substances by natural substances obtained from animals or plants
- A24B15/303—Plant extracts other than tobacco
-
- A—HUMAN NECESSITIES
- A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
- A24B—MANUFACTURE OR PREPARATION OF TOBACCO FOR SMOKING OR CHEWING; TOBACCO; SNUFF
- A24B15/00—Chemical features or treatment of tobacco; Tobacco substitutes, e.g. in liquid form
- A24B15/18—Treatment of tobacco products or tobacco substitutes
- A24B15/28—Treatment of tobacco products or tobacco substitutes by chemical substances
- A24B15/30—Treatment of tobacco products or tobacco substitutes by chemical substances by organic substances
- A24B15/32—Treatment of tobacco products or tobacco substitutes by chemical substances by organic substances by acyclic compounds
-
- A—HUMAN NECESSITIES
- A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
- A24B—MANUFACTURE OR PREPARATION OF TOBACCO FOR SMOKING OR CHEWING; TOBACCO; SNUFF
- A24B15/00—Chemical features or treatment of tobacco; Tobacco substitutes, e.g. in liquid form
- A24B15/18—Treatment of tobacco products or tobacco substitutes
- A24B15/28—Treatment of tobacco products or tobacco substitutes by chemical substances
- A24B15/30—Treatment of tobacco products or tobacco substitutes by chemical substances by organic substances
- A24B15/34—Treatment of tobacco products or tobacco substitutes by chemical substances by organic substances containing a carbocyclic ring other than a six-membered aromatic ring
-
- A—HUMAN NECESSITIES
- A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
- A24F—SMOKERS' REQUISITES; MATCH BOXES; SIMULATED SMOKING DEVICES
- A24F40/00—Electrically operated smoking devices; Component parts thereof; Manufacture thereof; Maintenance or testing thereof; Charging means specially adapted therefor
- A24F40/40—Constructional details, e.g. connection of cartridges and battery parts
- A24F40/46—Shape or structure of electric heating means
-
- A—HUMAN NECESSITIES
- A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
- A24D—CIGARS; CIGARETTES; TOBACCO SMOKE FILTERS; MOUTHPIECES FOR CIGARS OR CIGARETTES; MANUFACTURE OF TOBACCO SMOKE FILTERS OR MOUTHPIECES
- A24D1/00—Cigars; Cigarettes
- A24D1/20—Cigarettes specially adapted for simulated smoking devices
Definitions
- the present invention relates to aerosol-generating compositions comprising an aerosol-generating material; consumables for use within a non-combustible aerosol provision system, the consumables comprising the aerosol-generating composition; and non-combustible aerosol provision systems.
- a heating device which releases compounds by heating, but not burning, a solid aerosol-generating material.
- This solid aerosol-generating material may, in some cases, contain a botanical material.
- the heating volatilises at least one component of the material, typically forming an inhalable aerosol.
- These products may be referred to as heat-not-burn devices, tobacco heating devices or tobacco heating products.
- Various different arrangements for volatilising at least one component of the solid aerosol-generating material are known.
- there are hybrid devices These contain a liquid source
- the device additionally contains a solid aerosolgenerating material (which may or may not contain a tobacco material) and components of this material are entrained in the inhalable vapour or aerosol to produce the inhaled medium.
- an aerosol-generating material for use in aerosol generation, the aerosol-generating material comprising: - an aerosol-generating agent in an amount of from about 1 to about 80 wt% of the aerosol-generating material;
- binders wherein the total amount of binder is from about 5 to about 50 wt% of the aerosol-generating material, and wherein the one or more binders include a cellulosic binder; - flavour in an amount of from about 0.1 to about 60 wt% of the aerosolgenerating material;
- an emulsifier in an amount of from about 1 to about 25 wt% of the aerosolgenerating material
- an aerosol-generating agent in an amount of from about 1 to about 80 wt% of the aerosol-generating material
- the total amount of binder is from about 10 to about 50 wt% of the aerosol-generating material, and wherein the one or more binders include a cellulosic binder;
- an aerosol-generating composition comprising the aerosol-generating material of the first aspect.
- an aerosol-generating composition comprising a first aerosol-generating material and a second aerosol-generating material, wherein the first aerosol-generating material is defined according to the first aspect, and wherein the second aerosol-generating comprises - an aerosol-generating agent in an amount of from about 1 to about 80 wt% of the aerosol-generating material;
- binders wherein the total amount of binder is from about 5 to about 50 wt% of the aerosol-generating material; - flavour in an amount of from about 0.1 to about 60 wt% of the aerosolgenerating material;
- an emulsifier in an amount of from about 1 to about 25 wt% of the aerosolgenerating material
- composition of the second aerosol-generating material is different to the composition of the first aerosol-generating material.
- an aerosol-generating agent in an amount of from about 1 to about 80 wt% of the aerosol-generating material
- binder is from about 10 to about 50 wt% of the aerosol-generating material
- flavour in an amount of from about 0.1 to about 60 wt% of the aerosolgenerating material
- emulsifier in an amount of from about 1 to about 15 wt% of the aerosolgenerating material
- a consumable for use within a non-combustible aerosol provision system comprising the aerosol-generating composition as defined herein.
- a noncombustible aerosol provision system comprising the consumable as defined herein and a non-combustible aerosol provision device, the non-combustible aerosol provision device comprising an aerosol-generation device arranged to generate aerosol from the consumable when the consumable is used with the non-combustible aerosol provision device.
- an aerosol-generating composition as defined herein in a consumable for use in a noncombustible aerosol provision device
- the non-combustible aerosol provision device comprising an aerosol-generation device arranged to generate aerosol from the consumable when the consumable is used with the non-combustible aerosol provision device.
- a method of generating an aerosol using a non-combustible aerosol provision system as described herein comprising heating the aerosol-generating material.
- the method comprises heating the aerosol-generating material to a temperature of less than or equal to 350 °C.
- the method comprises heating the aerosol-generating material to a temperature of from about 220 °C to about 280 °C.
- Figure 1 shows a section view of an example of an aerosol-generating article.
- Figure 2 shows a perspective view of the article of Figure 1.
- Figure 3 shows a sectional elevation of an example of an aerosol-generating article.
- Figure 4 shows a perspective view of the article of Figure 3.
- Figure 5 shows a perspective view of an example of an aerosol generating assembly.
- Figure 6 shows a section view of an example of an aerosol generating assembly.
- Figure 7 shows a perspective view of an example of an aerosol generating assembly.
- Figure 8 shows the menthol release profile of an alginate containing gel.
- Figure 9 shows the menthol release profile of a CMC containing gel.
- Figures 10-13 show the menthol release profile of Alginate:CMC containing gels.
- Figure 14 shows an exploded diagram of an example consumable.
- Figure 15 shows an example of a consumable comprising a plurality of discrete portions of aerosol-generating material.
- the aerosol-generating compositions described herein are compositions that are capable of generating aerosol, for example when heated, irradiated or energized in any other way.
- the aerosol-generating composition may, for example, be in the form of a solid, liquid or gel which may or may not contain nicotine.
- the aerosolgenerating composition comprises an aerosol-generating material.
- the aerosolgenerating material may be an “amorphous solid”. In some embodiments, the amorphous solid is a “monolithic solid”.
- the aerosol-generating material may be non-fibrous or fibrous. In some embodiments, the aerosol-generating material may be a dried gel.
- the aerosol-generating material may be a solid material that may retain some fluid, such as liquid, within it.
- the aerosolgenerating composition may for example comprise from about 50wt%, 60wt% or 70wt% of aerosol-generating material, to about 90wt%, 95wt% or 100wt% of aerosolgenerating material. In some cases, the aerosol-generating composition consists of aerosol-generating material.
- the invention provides an aerosol-generating material, wherein the aerosol-generating material comprises: an aerosol-generating agent in an amount of from about 1 to about 80 wt% of the aerosol-generating material; one or more binders, wherein the total amount of binder is from about 5 to about 50 wt% of the aerosol-generating material, and wherein the one or more binders include a cellulosic binder; flavour in an amount of from about 0.1 to about 60 wt% of the aerosolgenerating material; an emulsifier in an amount of from about 1 to about 25 wt% of the aerosolgenerating material; and optionally a filler.
- one or more binders including a cellulosic binder may provide an improved substrate.
- a binder which comprises a cellulosic binder such as carboxymethyl cellulose
- the ease of manufacturing may also be improved as the specific choice of binder can circumvent the requirement of a crosslinking agent which can be challenging to apply.
- the one or more binders include a cellulosic binder and a non-cellulosic binder.
- a combination of a cellulosic binder and a non-cellulosic binder may have a synergistic effect on the binding in the aerosol-generating material.
- the ability of the aerosol-generating material to release flavour during use may be improved by using a combination of a cellulosic binder and a non-cellulosic binder.
- combining a cellulosic binder with a non-cellulosic binder in particular ratios may influence the temperature at which the flavour (such as menthol) is released from the aerosol-generating material when heated and/or the point in a session of use at which point flavour (such as menthol) is released.
- the aerosol-generating material comprises about 1wt%, 5wt%, 10wt%, 12wt% or 13wt% to about 18wt%, 20wt%, 25wt%, 30wt%, 35wt%, 45wt%, 55wt%, 65wt%, 75wt% or 80wt% of an aerosol-generating agent (all calculated on a dry weight basis).
- the aerosol-generating material comprises from 5-35wt%, 5-20wt%, 5-15wt%, 10-35wt%, 10-30wt%, 12-25wt%, 13-20wt% or 13-18wt% of an aerosol-generating agent (all calculated on a dry weight basis).
- the aerosol-generating agent may comprise one or more of glycerol, propylene glycol, diethylene glycol, triethylene glycol, tetraethylene glycol, 1,3-butylene glycol, erythritol, meso-Erythritol, ethyl vanillate, ethyl laurate, a diethyl suberate, triethyl citrate, triacetin, a diacetin mixture, benzyl benzoate, benzyl phenyl acetate, tributyrin, lauryl acetate, lauric acid, myristic acid, and propylene carbonate.
- the aerosol-generating agent comprises, consists essentially of or consists of glycerol.
- the aerosol-generating material may comprise a total amount of about 5wt%, 10wt%, 12wt%, 15wt%, 17wt% or 20wt% to about 25wt%, 30wt%, 40wt%, 45wt% or 50wt% of one or more binders (all calculated on a dry weight basis).
- the aerosol-generating material comprises a total amount of 15wt%, 17wt%, 19wt% or 20wt% to about 25wt%, 27wt% or 30wt% of one or more binders.
- the aerosol-generating material may comprise a total amount of 15- 30wt%, 17-27wt%, 17-25wt% or 20-25wt% of one or more binders.
- the one or more binders include a cellulosic binder.
- cellulosic binders which may be used include, but are not limited to, hydroxymethyl cellulose, hydroxyethyl cellulose, hydroxypropyl cellulose, carboxymethylcellulose (CMC), hydroxypropyl methylcellulose (HPMC), methyl cellulose, ethyl cellulose, cellulose acetate (CA), cellulose acetate butyrate (CAB), and cellulose acetate propionate (CAP).
- the cellulosic binder is selected from hydroxyethyl cellulose, hydroxypropyl cellulose, and/or carboxymethylcellulose.
- the cellulosic binder comprises carboxymethylcellulose (CMC).
- the cellulosic binder is carboxymethylcellulose (CMC).
- the one or more binders include a cellulosic binder and a non- cellulosic binder.
- the cellulosic binder may be selected from those listed above.
- the cellulosic binder is selected from hydroxyethyl cellulose, hydroxypropyl cellulose and/or carboxymethylcellulose.
- the cellulosic binder comprises carboxymethylcellulose.
- the cellulosic binder is carboxymethylcellulose.
- the non-cellulosic binder may be selected from the group comprising alginates, pectins, starches (and derivatives), gums, silica or silicones compounds, clays, polyvinyl alcohol and combinations thereof.
- the non-cellulosic binder is selected from the group consisting of alginates, pectins, pullulan, xanthan gum, guar gum, carrageenan, agarose, acacia gum, fumed silica, PDMS, sodium silicate, kaolin and polyvinyl alcohol.
- the non-cellulosic binder comprises alginate.
- the cellulosic binder is alginate.
- the binder comprises one or more of hydroxyethyl cellulose, hydroxypropyl cellulose and/or carboxymethylcellulose, and one or more of alginates, pectins, pullulan, xanthan gum, guar gum, carrageenan, agarose, acacia gum, fumed silica, PDMS, sodium silicate, kaolin and polyvinyl alcohol.
- the binder comprises, consists essentially of or consists of carboxymethyl cellulose.
- the binder comprises, consists essentially of or consists of carboxymethyl cellulose and alginate.
- the aerosol-generating composition comprises a crosslinking agent.
- the crosslinking agent comprises calcium ions.
- the aerosol-generating composition may comprise carboxymethyl cellulose and a calcium-crosslinked alginate.
- the crosslinking agent may also be described as a setting agent.
- the aerosol-generating composition does not comprise a crosslinking agent.
- the binder comprises carboxymethyl cellulose, and the carboxymethyl cellulose is present in the aerosol-generating composition in an amount from 5-50wt%, 5-25wt%, 5-20wt%, 5-15wt%, 10-50wt%, 15-40wt%, 20- 35wt% or 20-30wt% of the aerosol-generating material (calculated on a dry weight basis).
- carboxymethyl cellulose is the only binder present in the aerosol-generating composition.
- the binder comprises carboxymethyl cellulose and at least one further non-cellulosic binder, such as alginate.
- the binder comprises a cellulosic binder and a non-cellulosic binder.
- the weight ratio of cellulosic binder to non-cellulosic binder is from 1 :4 to 4:1 , from 1 :1 to 2:1, from 2:3 to 7:3, from 2:3 to 3:2 or from 1 :1 to 3:2.
- the weight ratio of cellulosic binder to non-cellulosic binder is >1 :1. That is, in some embodiments, the cellulosic binder is present in an amount greater than the amount of non-cellulosic binder.
- the weight ratio of cellulosic binder to non-cellulosic binder is about 1 :1. In some embodiments, the weight ratio of cellulosic binder to non-cellulosic binder is about 3:2
- flavourant compounds for example menthol
- the inventors have found that by including one or more binders in the aerosolgenerating material, flavourant compounds (for example menthol) are stabilised within the binder matrix allowing controlled release of flavourant over the course of a smoking session.
- the flavouring e.g. menthol
- the flavouring is stabilised at high concentrations and the products have a good shelf life.
- the aerosol-generating material may comprise about 0.1wt%, 0.5 wt%, 1wt%, 5wt%, 10wt%, 15wt%, 20wt%, 25wt%, 30wt% or 35wt% to about 45wt%, 50wt% or
- the aerosol-generating material comprises 1 wt%, 5 wt%, 10 wt%, 20 wt%, 30wt%, or 35wt% to about 42wt%, 45wt% or 47wt% of flavour.
- the aerosolgenerating material may comprise 1-45wt%, 10-45wt%, 20-50wt%, 30-50wt%, 30-45wt% or 35-45wt% of flavour.
- the aerosol-generating material may comprise 5-25wt%, 10-25wt%, 10-20wt% or 15-20wt% of flavour.
- flavour and “flavourant” refer to materials which, where local regulations permit, may be used to create a desired taste, aroma, or other somatosensorial sensation in a product for adult consumers. They may include naturally occurring flavour materials, botanicals, extracts of botanicals, synthetically obtained materials, or combinations thereof (e.g., tobacco, cannabis, licorice (liquorice), hydrangea, eugenol, Japanese white bark magnolia leaf, chamomile, fenugreek, clove, maple, matcha, menthol, Japanese mint, aniseed (anise), cinnamon, turmeric, Indian spices, Asian spices, herb, wintergreen, cherry, berry, red berry, cranberry, peach, apple, orange, mango, clementine, lemon, lime, tropical fruit, papaya, rhubarb, grape, durian, dragon fruit, cucumber, blueberry, mulberry, citrus fruits, Drambuie, bourbon, scotch
- the flavour comprises menthol, spearmint and/or peppermint. In some embodiments, the flavour comprises, consists essentially of or consists of menthol.
- the flavour comprises flavour components of cucumber, blueberry, citrus fruits and/or redberry. In some embodiments, the flavour comprises eugenol.
- the flavour comprises flavour components extracted from tobacco. In some embodiments, the flavour comprises flavour components extracted from cannabis.
- the flavour may comprise a sensate, which is intended to achieve a somatosensorial sensation which are usually chemically induced and perceived by the stimulation of the fifth cranial nerve (trigeminal nerve), in addition to or in place of aroma or taste nerves, and these may include agents providing heating, cooling, tingling, numbing effect.
- a suitable heat effect agent may be, but is not limited to, vanillyl ethyl ether and a suitable cooling agent may be, but not limited to eucolyptol or WS-3 (/V-ethyl-2-isopropyl-5-methylcyclohexanecarboxamide).
- the aerosol-generating material may comprise about 1wt%, 3wt% or 5wt% to about 7wt%, 10wt%, 12wt%, 15wt%, 20wt% or 25wt% of emulsifier (all calculated on a dry weight basis).
- the aerosol-generating material comprises about 3wt%, 4wt% or 5wt% to about 7wt%, 8wt% or 10wt% of emulsifier.
- the aerosol-generating material may comprise 4-8wt% or 5-7wt% of emulsifier.
- the emulsifier comprises one or more compounds selected from agar, xanthan gum, gum Arabic (acacia gum), guar gum, locust bean gum, pectin, carrageenan and lecithin. In some cases, the emulsifier comprises, consists essentially of or consists of guar gum.
- the aerosol-generating material comprises less than 35wt% of a filler, such as from about 1wt%, 5wt% or 10wt% to about 20wt%, 25wt%,
- the aerosol-generating material comprises about 7wt%, 10wt% or 11wt% to about 15wt%, 20wt% or 25wt% of filler.
- the aerosolgenerating material may comprise 7-25wt%, 10-20wt%, 15-20wt%, 10-15wt% or 11-15wt% of filler.
- the aerosol-generating material comprises less than 60wt% of filler, such as from about 30wt%, 40wt% or 45wt% to about 50wt%, 55wt%, or 60wt% of filler (all calculated on a dry weight basis). In exemplary embodiments, the aerosol-generating material comprises about 40-60wt%, 40-55wt% or 45-55wt% of filler.
- the aerosol-generating material may comprise less than 20 wt%, suitably less than 10 wt% or less than 5 wt% of filler. In some cases, the aerosol-generating material comprises less than 1 wt% of filler, and in some cases the aerosol-generating material comprises no filler.
- the filler may comprise one or more inorganic filler materials, such as calcium carbonate, perlite, vermiculite, diatomaceous earth, colloidal silica, magnesium oxide, magnesium sulphate, magnesium carbonate, and suitable inorganic sorbents, such as molecular sieves.
- the filler if present, may comprise one or more organic filler materials such as wood pulp, cellulose and cellulose derivatives. In particular cases, aerosol-generating material comprises no calcium carbonate such as chalk.
- the filler is fibrous.
- the filler may be a fibrous organic filler material such as wood pulp, hemp fibre, cellulose or cellulose derivatives, such as microcrystalline cellulose (MCC) and/or nanocrystalline cellulose.
- MCC microcrystalline cellulose
- the filler comprises (or is) wood pulp and/or MCC.
- the filler comprises maltodextrin or microcrystalline cellulose
- microcrystalline cellulose may be formed by depolymerising cellulose by a chemical process (e.g. using an acid or enzyme).
- a chemical process e.g. using an acid or enzyme.
- One example method for forming microcrystalline cellulose involves acid hydrolysis of cellulose, using an acid such as HCI. The cellulose produced after this treatment is crystalline (i.e. no amorphous regions remain). Suitable methods and conditions for forming microcrystalline cellulose are well-known in the art.
- the filler has a density of less than about 2 g/cm 3 , such as less than about 0.5 g/cm 3 or less than about 0.3 g/cm 3 .
- the aerosol-generating material may have any suitable water content, such as from 1wt % to 15wt%.
- the water content of the aerosol-generating material may be from about 5wt%, 7wt% or 9wt% to about 15wt%, 13wt% or 11wt% (wet weight basis) (WWB).
- WWB wet weight basis
- the water content of the aerosol-generating material may, for example, be determined by Karl-Fischer-titration or Gas Chromatography with Thermal Conductivity Detector (GC-TCD).
- the aerosol-generating material may comprise a colourant.
- the addition of a colourant may alter the visual appearance of the aerosol-generating material.
- the presence of colourant in the aerosol-generating material may enhance the visual appearance of the aerosol-generating material and the aerosol-generating composition.
- the aerosolgenerating material may be colour-matched to other components of the aerosol- generating composition or to other components of an article comprising the aerosolgenerating material.
- the colour of aerosol-generating material may be, for example, white, green, red, purple, blue, brown or black. Other colours are also envisaged. Natural or synthetic colourants, such as natural or synthetic dyes, food- grade colourants and pharmaceutical-grade colourants may be used.
- the colourant is caramel, which may confer the aerosol-generating material with a brown appearance (e.g. similar to tobacco).
- the aerosol-generating material comprises up to 5 wt% of a colourant such as caramel, for example from about 1 to about 4 wt% (calculated on a dry weight basis).
- the colour of the aerosol-generating material may be similar to the colour of other components (such as tobacco material) in an aerosolgenerating composition comprising the aerosol-generating material.
- the addition of a colourant to the aerosol-generating material renders it visually indistinguishable from other components in the aerosol-generating composition.
- the colourant may be incorporated during the formation of the aerosolgenerating material (e.g. when forming a slurry comprising the materials that form the aerosol-generating material) or it may be applied to the aerosol-generating material after its formation (e.g. by spraying it onto the aerosol-generating material).
- the aerosol-generating composition additionally comprises an active substance.
- the aerosol-generating composition additionally comprises a tobacco material and/or nicotine.
- the aerosol-generating composition may comprise 5-60wt% (calculated on a dry weight basis) of a tobacco material and/or nicotine.
- the aerosol-generating composition may comprise from about 1wt%, 5wt%, 10wt%, 15wt%, 20wt% or 25wt% to about 70wt%, 60wt%, 50wt%, 45wt%, 40wt%, 35wt%, or 30wt% (calculated on a dry weight basis) of an active substance.
- the aerosolgenerating composition may comprise from about 1wt%, 5wt%, 10wt%, 15wt%, 20wt% or 25wt% to about 70wt%, 60wt%, 50wt%, 45wt%, 40wt%, 35wt%, or 30wt% (calculated on a dry weight basis) of a tobacco material.
- the aerosolgenerating composition may comprise 10-50wt%, 15-40wt% or 20-35wt% of a tobacco material.
- the aerosol-generating composition may comprise from about 1wt%, 2wt%, 3wt% or 4wt% to about 20wt%, 18wt%, 15wt% or 12wt% (calculated on a dry weight basis) of nicotine.
- the aerosol-generating composition may comprise 1-20wt%, 2-18wt% or 3-12wt% of nicotine.
- the aerosol-generating composition comprises an active substance such as tobacco extract.
- the aerosol-generating composition may comprise 5-60wt% (calculated on a dry weight basis) of tobacco extract.
- the aerosol-generating composition may comprise from about 5wt%, 10wt%, 15wt%, 20wt% or 25wt% to about 60wt%, 50wt%, 45wt%, 40wt%, 35wt%, or 30wt% (calculated on a dry weight basis) tobacco extract.
- the aerosol-generating composition may comprise 10-50wt%, 15-40wt% or 20- 35wt% of tobacco extract.
- the tobacco extract may contain nicotine at a concentration such that the aerosol-generating composition comprises 1wt% 1.5wt%, 2wt% or2.5wt% to about 10wt%, 8wt%, 6wt%, 5wt%, 4.5wt% or4wt% (calculated on a dry weight basis) of nicotine.
- the aerosol-generating composition may comprise 1-10 wt%, 2.5-8 wt% or 2-6wt% nicotine. In some cases, there may be no nicotine in the aerosol-generating composition other than that which results from the tobacco extract.
- the aerosol-generating composition comprises no tobacco material but does comprise nicotine.
- the aerosol-generating composition may comprise from about 1wt%, 2wt%, 3wt% or 4wt% to about 20wt%, 18wt%, 15wt% or 12wt% (calculated on a dry weight basis) of nicotine.
- the aerosol-generating composition may comprise 1-20wt%, 2-18wt% or 3-12wt% of nicotine.
- the aerosol-generating composition may comprise an acid.
- the acid may be an organic acid. In some of these embodiments, the acid may be at least one of a monoprotic acid, a diprotic acid and a triprotic acid.
- the acid may contain at least one carboxyl functional group. In some such embodiments, the acid may be at least one of an alpha-hydroxy acid, carboxylic acid, dicarboxylic acid, tricarboxylic acid and keto acid. In some such embodiments, the acid may be an alpha-keto acid.
- the acid may be at least one of succinic acid, lactic acid, benzoic acid, citric acid, tartaric acid, fumaric acid, levulinic acid, acetic acid, malic acid, formic acid, sorbic acid, benzoic acid, propanoic and pyruvic acid.
- the acid is lactic acid.
- the acid is benzoic acid.
- the acid may be an inorganic acid.
- the acid may be a mineral acid.
- the acid may be at least one of sulphuric acid, hydrochloric acid, boric acid and phosphoric acid.
- the acid is levulinic acid.
- an acid is particularly preferred in embodiments in which the aerosol-generating composition comprises nicotine.
- the presence of an acid may stabilise dissolved species in the slurry from which the aerosol-generating composition is formed.
- the presence of the acid may reduce or substantially prevent evaporation of nicotine during drying of the slurry, thereby reducing loss of nicotine during manufacturing.
- the presence of the acid may also improve the flavour of the aerosol when nicotine is present. For example, the perceived harshness of the nicotine may be reduced by the presence of the acid.
- the aerosol-generating material is substantially free from tobacco.
- substantially free from it is meant that the material comprises less than 1wt%, such as less than 0.5wt% tobacco.
- the aerosolgenerating material is free from tobacco.
- the aerosolgenerating material does not comprise tobacco fibres.
- the aerosol-generating material does not comprise fibrous material.
- the aerosol-generating composition does not comprise tobacco fibres.
- the aerosol-generating composition does not comprise fibrous material.
- the aerosol-generating composition comprises a first and a second aerosol-generating material, where the composition of the second aerosol-generating material is different from the composition of the first aerosolgenerating material.
- the first aerosol-generating material is as defined herein, and comprises - an aerosol-generating agent in an amount of from about 1 to about 80 wt% of the aerosol-generating material;
- binders wherein the total amount of binder is from about 5 to about 50 wt% of the aerosol-generating material, and wherein the one or more binders include a cellulosic binder; - flavour in an amount of from about 0.1 to about 60 wt% of the aerosolgenerating material;
- the second aerosol-generating material comprises:
- an aerosol-generating agent in an amount of from about 1 to about 80 wt% of the aerosol-generating material; - one or more binders, wherein the total amount of binder is from about 5 to about 50 wt% of the aerosol-generating material;
- the first aerosol-generating material is as defined herein, and comprises - an aerosol-generating agent in an amount of from about 1 to about 80 wt% of the aerosol-generating material;
- binders wherein the total amount of binder is from about 10 to about 50 wt% of the aerosol-generating material, and wherein the one or more binders include a cellulosic binder; - flavour in an amount of from about 0.1 to about 60 wt% of the aerosolgenerating material;
- the second aerosol-generating material comprises:
- an aerosol-generating agent in an amount of from about 1 to about 80 wt% of the aerosol-generating material
- binders wherein the total amount of binder is from about 10 to about 50 wt% of the aerosol-generating material; - flavour in an amount of from about 0.1 to about 60 wt% of the aerosolgenerating material;
- an emulsifier in an amount of from about 1 to about 15 wt% of the aerosolgenerating material
- the aerosol-generating material applies equally to both the first and the second aerosol-generating materials, apart from the fact that the second aerosol-generating material does not need to include a cellulosic binder.
- the one or more binders in the second aerosol generating composition are different to the one or more binders in the first aerosol generating composition.
- the one or more binders in the second aerosol-generating material are different to the one or more binders in the first aerosolgenerating material.
- the one or more binders in the second aerosol-generating material include a non-cellulosic binder.
- the non-cellulosic binder is alginate.
- An aerosol-generating composition comprising two different aerosolgenerating materials may allow for the release of flavour at two different temperatures, or over a temperature range. This may especially be the case when the aerosol-generating materials comprise different binders.
- the flavour e.g.
- menthol may be released from the first aerosol-generating material at a lower temperature than from the second aerosol-generating material or vice versa, allowing for the release of flavour over a wider temperature range and potentially a longer time. Without wishing to be bound by theory, it is believed that the flavour (e.g. menthol) will be released at a lower temperature when a non-cellulosic binder is used.
- the aerosol-generating article does not comprise tobacco fibres. In particular embodiments, the aerosol-generating article does not comprise fibrous material.
- the aerosolisable or aerosol-generating material may be present on or in a support to form a substrate.
- the support functions as a support on which the aerosolgenerating material layer forms, easing manufacture.
- the support may provide rigidity to the aerosol-generating material layer, easing handling.
- the support may be any suitable material which can be used to support an aerosol-generating material.
- the support may be formed from materials selected from metal foil, paper, carbon paper, greaseproof paper, ceramic, carbon allotropes such as graphite and graphene, plastic, cardboard, wood or combinations thereof.
- the support may comprise or consist of a tobacco material, such as a sheet of reconstituted tobacco.
- the support may be formed from materials selected from metal foil, paper, cardboard, wood or combinations thereof.
- the support comprises paper.
- the support itself may be a laminate structure comprising layers of materials selected from the preceding lists.
- the support may also function as a flavour support.
- the support may be impregnated with a flavourant or with tobacco extract.
- the thickness of the support layer may be in the range of about 10pm, 15pm, 17pm, 20pm, 23pm, 25pm, 50pm, 75pm or 0.1mm to about 2.5mm,
- the support may comprise more than one layer, and the thickness described herein refers to the aggregate thickness of those layers.
- the support may be magnetic. This functionality may be used to fasten the support to the assembly in use, or may be used to generate particular aerosol-generating material shapes.
- the aerosol-generating substrate may comprise one or more magnets which can be used to fasten the substrate to an induction heater in use.
- the support may be substantially or wholly impermeable to gas and/or aerosol. This prevents aerosol or gas passage through the support layer, thereby controlling the flow and ensuring it is delivered to the user. This can also be used to prevent condensation or other deposition of the gas/aerosol in use on, for example, the surface of a heater provided in an aerosol generating assembly. Thus, consumption efficiency and hygiene can be improved in some cases.
- the surface of the support that abuts the aerosol-generating material may be porous.
- the support comprises paper.
- a porous support such as paper is particularly suitable for the present invention; the porous (e.g. paper) layer abuts the aerosol-generating layer and forms a strong bond.
- the aerosol-generating material is formed by drying a gel and, without being limited by theory, it is thought that the slurry from which the gel is formed partially impregnates the porous support (e.g. paper) so that when the gel sets and forms cross-links, the support is partially bound into the gel. This provides a strong binding between the gel and the support (and between the dried gel and the support).
- surface roughness may contribute to the strength of bond between the aerosol-generating material and the support.
- the paper roughness (for the surface abutting the support) may suitably be in the range of 50-1000 Bekk seconds, suitably 50-150 Bekk seconds, suitably 100 Bekk seconds (measured over an air pressure interval of 50.66-48.00 kPa).
- a Bekk smoothness tester is an instrument used to determine the smoothness of a paper surface, in which air at a specified pressure is leaked between a smooth glass surface and a paper sample, and the time (in seconds) for a fixed volume of air to seep between these surfaces is the "Bekk smoothness”.
- the surface of the support facing away from the aerosolgenerating material may be arranged in contact with the heater, and a smoother surface may provide more efficient heat transfer.
- the support is disposed so as to have a rougher side abutting the aerosol-generating material and a smoother side facing away from the aerosol-generating material.
- the support may be a paper-backed foil; the paper layer abuts the aerosol-generating material layer and the properties discussed in the previous paragraphs are afforded by this abutment.
- the foil backing is substantially impermeable, providing control of the aerosol flow path.
- a metal foil backing may also serve to conduct heat to the aerosol-generating material.
- the foil layer of the paper-backed foil abuts the aerosolgenerating material.
- the foil is substantially impermeable, thereby preventing water provided in the aerosol-generating material to be absorbed into the paper which could weaken its structural integrity.
- the support is formed from or comprises metal foil, such as aluminium foil. A metallic support may allow for better conduction of thermal energy to the aerosol-generating material.
- a metal foil may function as a susceptor in an induction heating system.
- the support comprises a metal foil layer and a support layer, such as cardboard.
- the metal foil layer may have a thickness of less than 20pm, such as from about 1 pm to about 10pm, suitably about 5pm.
- the support may have a thickness of between about 0.017mm and about 2.0mm, suitably from about 0.02mm, 0.05mm or 0.1 mm to about 1 ,5mm, 1.0mm, or 0.5mm.
- the aerosol-generating material may be made from a gel, and this gel may additionally comprise a solvent, included at 0.1-50wt%.
- a solvent in which the flavour is soluble may reduce the gel stability and the flavour may crystallise out of the gel.
- the gel does not include a solvent in which the flavour is soluble.
- An aspect of the present invention relates to an article (also referred to herein as a consumable).
- a consumable is an article, part or all of which is intended to be consumed during use by a user.
- a consumable may comprise or consist of aerosolgenerating composition.
- a consumable may comprise one or more other elements, such as a filter or an aerosol modifying substance.
- a consumable may comprise a heating element that emits heat to cause the aerosol-generating composition to generate aerosol in use.
- the heating element may, for example, comprise combustible material, or may comprise a susceptor that is heatable by penetration with a varying magnetic field.
- Articles of the present invention may be provided in any suitable shape.
- the article is provided as a rod (e.g. substantially cylindrical).
- An article provided as a rod may include the aerosol-generating composition as a shredded sheet, optionally blended with cut tobacco.
- the article provided as a rod may include the aerosol-generating composition as a sheet, such as a sheet circumscribing a rod of aerosol-generating material (e.g. tobacco, or a combination of tobacco and an aerosol-generating material such as that described herein).
- the article comprises a layer portion of aerosolgenerating composition disposed on a carrier.
- the article may have at least one substantially planar (flat) surface.
- the aerosol-generating material may comprise or be in the form of an aerosol-generating film.
- the aerosol-generating film may be substantially free from botanical material.
- the aerosol-generating film is substantially tobacco free.
- the aerosol-generating film may have a thickness of about 0.015 mm to about 1 mm.
- the thickness may be in the range of about 0.05 mm, 0.1 mm or 0.15 mm to about 0.5 mm or 0.3 mm.
- the aerosol-generating film may be continuous.
- the film may comprise or be a continuous sheet of material.
- the sheet may be in the form of a wrapper, it may be gathered to form a gathered sheet or it may be shredded to form a shredded sheet.
- the shredded sheet may comprise one or more strands or strips of aerosol-generating material.
- the aerosol-generating film is shredded and blended with another shredded aerosol-generating film.
- the aerosolgenerating films comprise different binders.
- the first aerosol-generating film comprises a cellulosic binder and the second aerosol- generating film comprises a non-cellulosic binder.
- an aerosolgenerating film comprising alginate is blended with an aerosol-generating film comprising CMC.
- the inclusion of aerosol-generating films comprising different films may increase the temperature range over which flavour is released.
- a consumable for use in a non-combustible aerosol-provision system comprising a planar support with complete coverage of the aerosol-generating material (e.g.
- FIG. 14 provides a schematic illustration of such a consumable, which includes a support layer 4 and an aerosol-generating material layer 2.
- the aerosol-generating film may be discontinuous,
- the aerosol-generating film may comprise one or more discrete portions or regions of aerosol-generating material, such as dots, stripes or lines, which may be supported on a support.
- the support may be planar or non-planar.
- the discrete portions of aerosol-generating material are substantially round, cylindrical or hemispherical. In some cases, there is a gridshaped distribution of the substantially round, cylindrical or hemispherical aerosol- generating material.
- a consumable for use in a non-combustible aerosol-provision system comprising a planar support with a discontinuous aerosolgenerating film (which comprises a plurality of discrete portions of aerosol- generating material) deposited on it.
- Figure 15 provides an example of a consumable (401) wherein a discontinuous aerosol-generating film (which comprises a discrete portion of aerosol-generating material (403)) are provided on the consumable.
- a discontinuous aerosol-generating film which comprises a discrete portion of aerosol-generating material (403)
- a susceptor is material that is heatable by penetration with a varying magnetic field, such as an alternating magnetic field.
- the heating material may be an electrically-conductive material, so that penetration thereof with a varying magnetic field causes induction heating of the heating material.
- the heating material may be magnetic material, so that penetration thereof with a varying magnetic field causes magnetic hysteresis heating of the heating material.
- the heating material may be both electrically-conductive and magnetic, so that the heating material is heatable by both heating mechanisms.
- Induction heating is a process in which an electrically-conductive object is heated by penetrating the object with a varying magnetic field. The process is described by Faraday's law of induction and Ohm's law.
- An induction heater may comprise an electromagnet and a device for passing a varying electrical current, such as an alternating current, through the electromagnet.
- a varying electrical current such as an alternating current
- the electromagnet and the object to be heated are suitably relatively positioned so that the resultant varying magnetic field produced by the electromagnet penetrates the object, one or more eddy currents are generated inside the object.
- the object has a resistance to the flow of electrical currents. Therefore, when such eddy currents are generated in the object, their flow against the electrical resistance of the object causes the object to be heated. This process is called Joule, ohmic, or resistive heating.
- the susceptor is in the form of a closed circuit. It has been found that, when the susceptor is in the form of a closed circuit, magnetic coupling between the susceptor and the electromagnet in use is enhanced, which results in greater or improved Joule heating.
- Magnetic hysteresis heating is a process in which an object made of a magnetic material is heated by penetrating the object with a varying magnetic field.
- a magnetic material can be considered to comprise many atomic-scale magnets, or magnetic dipoles. When a magnetic field penetrates such material, the magnetic dipoles align with the magnetic field. Therefore, when a varying magnetic field, such as an alternating magnetic field, for example as produced by an electromagnet, penetrates the magnetic material, the orientation of the magnetic dipoles changes with the varying applied magnetic field. Such magnetic dipole reorientation causes heat to be generated in the magnetic material.
- the thickness values stipulated herein are mean values for the thickness in question. In some cases, the thickness may vary by no more than 25%, 20%, 15%, 10%, 5% or 1%.
- the “thickness” of the aerosol-generating material describes the shortest distance between a first surface and a second surface.
- the thickness of the aerosolgenerating material is the shortest distance between a first planar surface of the sheet and a second planar surface of the sheet which opposes the first planar surface of the sheet.
- the aerosol-generating composition may have a thickness of about 0.015mm to about 1.0mm.
- the thickness may be in the range of about 0.05mm, 0.1mm or 0.15mm to about 0.5mm or 0.3mm.
- the aerosol-generating material may comprise more than one layer, and the thickness described herein refers to the aggregate thickness of those layers.
- the aerosol-generating material may have a thickness of about 0.015mm to about 1.0mm.
- the thickness may be in the range of about
- the aerosol-generating material may comprise more than one layer, and the thickness described herein refers to the aggregate thickness of those layers.
- the aerosol-generating composition comprising the aerosol-generating material may have any suitable area density, such as from 30 g/m 2 to 120 g/m 2 . In some embodiments, aerosol-generating composition may have an area density of from about 30 to 70 g/m 2 , or about 40 to 60 g/m 2 . In some embodiments, the aerosolgenerating composition may have an area density of from about 80 to 120 g/m 2 , or from about 70 to 110 g/m 2 , or particularly from about 90 to 110 g/m 2 .
- An aspect of the invention provides non-combustible aerosol provision system comprising an article according as described herein and non-combustible aerosol provision device comprising a heater which is configured to heat not burn the aerosol-generating article.
- a non-combustible aerosol provision system may also be referred to as an aerosol generating assembly.
- a non-combustible aerosol provision device may be referred to as an aerosol generating apparatus.
- the heater may heat, without burning, the aerosolgenerating material to a temperature equal to or less than 350 °C, such as between 120°C and 350 °C. In some cases, the heater may heat, without burning, the aerosolgenerating composition to between 140 °C and 250 °C in use, or between 220 °C and 280 °C. In some cases in use, substantially all of the aerosol-generating material is less than about 4mm, 3mm, 2mm or 1mm from the heater. In some cases, the material is disposed between about 0.010mm and 2.0mm from the heater, suitably between about 0.02mm and 1.0mm, suitably 0.1mm to 0.5mm.
- the heater is configured to heat not burn the aerosol-generating article, and thus the aerosol-generating composition.
- the heater may be, in some cases, a thin film, electrically resistive heater. In other cases, the heater may comprise an induction heater or the like.
- the heater may be a combustible heat source or a chemical heat source which undergoes an exothermic reaction to product heat in use.
- the aerosol generating assembly may comprise a plurality of heaters. The heater(s) may be powered by a battery.
- the aerosol-generating article may additionally comprise a cooling element and/or a filter.
- the cooling element if present, may act or function to cool gaseous or aerosol components. In some cases, it may act to cool gaseous components such that they condense to form an aerosol. It may also act to space the very hot parts of the non-combustible aerosol provision device from the user.
- the filter if present, may comprise any suitable filter known in the art such as a cellulose acetate plug.
- the aerosol generating assembly may be a heat-not-burn device. That is, it may contain a solid tobacco-containing material (and no liquid aerosol-generating material). In some cases, the aerosol-generating material may comprise the tobacco material.
- a heat-not-burn device is disclosed in WO 2015/062983 A2, which is incorporated by reference in its entirety.
- the aerosol generating assembly may be an electronic tobacco hybrid device. That is, it may contain a solid aerosol-generating composition and a liquid aerosol-generating material. In some cases, the aerosol-generating material may comprise nicotine. In some cases, the aerosol-generating material may comprise a tobacco material. In some cases, the aerosol-generating material may comprise a tobacco material and a separate nicotine source. The separate aerosolgenerating compositions may be heated by separate heaters, the same heater or, in one case, a downstream aerosol-generating material may be heated by a hot aerosol which is generated from the upstream aerosol-generating composition.
- An electronic tobacco hybrid device is disclosed in WO 2016/135331 A1, which is incorporated by reference in its entirety.
- the aerosol-generating article (which may be referred to herein as an article, a cartridge or a consumable) may be adapted for use in a THP, an electronic tobacco hybrid device or another aerosol generating device.
- the article may additionally comprise a filter and/or cooling element (which have been described above).
- the aerosol-generating article may be circumscribed by a wrapping material such as paper.
- the aerosol-generating article may additionally comprise ventilation apertures. These may be provided in the sidewall of the article. In some cases, the ventilation apertures may be provided in the filter and/or cooling element. These apertures may allow cool air to be drawn into the article during use, which can mix with the heated volatilised components thereby cooling the aerosol.
- the ventilation enhances the generation of visible heated volatilised components from the article when it is heated in use.
- the heated volatilised components are made visible by the process of cooling the heated volatilised components such that supersaturation of the heated volatilised components occurs.
- the heated volatilised components then undergo droplet formation, otherwise known as nucleation, and eventually the size of the aerosol particles of the heated volatilised components increases by further condensation of the heated volatilised components and by coagulation of newly formed droplets from the heated volatilised components.
- the ratio of the cool air to the sum of the heated volatilised components and the cool air is at least 15%.
- a ventilation ratio of 15% enables the heated volatilised components to be made visible by the method described above. The visibility of the heated volatilised components enables the user to identify that the volatilised components have been generated and adds to the sensory experience of the smoking experience.
- the ventilation ratio is between 50% and 85% to provide additional cooling to the heated volatilised components. In some cases, the ventilation ratio may be at least 60% or 65%.
- the aerosol-generating composition may be included in the article/assembly in sheet form. In some cases, the aerosol-generating composition may be included as a planar sheet. In some cases, the aerosol-generating composition may be included as a planar sheet, as a bunched or gathered sheet, as a crimped sheet, or as a rolled sheet (i.e. in the form of a tube). In some such cases, the aerosol-generating material of these embodiments may be included in an aerosolgenerating article/assembly as a sheet, such as a sheet circumscribing a rod of aerosol-generating material (e.g. tobacco).
- a sheet circumscribing a rod of aerosol-generating material e.g. tobacco
- the aerosolgenerating composition may be formed as a sheet and then shredded and incorporated into the article.
- the shredded sheet may be mixed with cut rag tobacco and incorporated into the article.
- the first and second aerosol-generating materials described herein may both be formed as a sheet and then shredded and mixed together to form an aerosol-generating composition. Said composition may then be incorporated into the article.
- the shredded sheets may also be mixed with cut rag tobacco and incorporated into the article.
- the aerosol-generating material in sheet form may have a tensile strength of from around 200 N/m to around 900 N/m.
- the aerosol-generating material may have a tensile strength of from 200 N/m to 400 N/m, or 200 N/m to 300 N/m, or about 250 N/m.
- tensile strengths may be particularly suitable for embodiments wherein the aerosol-generating composition is formed as a sheet and then shredded and incorporated into an aerosol-generating article.
- the aerosol-generating material may have a tensile strength of from 600 N/m to 900 N/m, or from 700 N/m to 900 N/m, or around 800 N/m.
- Such tensile strengths may be particularly suitable for embodiments wherein the aerosol-generating composition is included in an aerosol-generating article/assembly as a rolled sheet, suitably in the form of a tube.
- the aerosol-generating material is formed as a film on a support.
- the aerosol-generating film may be a continuous film or a discontinuous film, such as an arrangement of discrete portions of film on a support. In some cases, the aerosol-generating film does not comprise a filler.
- FIG. 1 and 2 there are shown a partially cut-away section view and a perspective view of an example of an aerosol-generating article 101.
- the article 101 is adapted for use with a device having a power source and a heater.
- the article 101 of this embodiment is particularly suitable for use with the device 1 shown in Figures 5 to 7, described below.
- the article 101 may be removably inserted into the device shown in Figure 5 at an insertion point 20 of the device 1.
- the article 101 of one example is in the form of a substantially cylindrical rod that includes a body of aerosol-generating composition 103 and a filter assembly 105 in the form of a rod.
- the aerosol-generating composition comprises the aerosolgenerating material described herein. In some embodiments, it may be included in sheet form. In some embodiments it may be included in the form of a shredded sheet. In some embodiments, the aerosol-generating composition described herein may be incorporated in sheet form and in shredded form.
- the filter assembly 105 includes three segments, a cooling segment 107, a filter segment 109 and a mouth end segment 111.
- the article 101 has a first end 113, also known as a mouth end or a proximal end and a second end 115, also known as a distal end.
- the body of aerosol-generating composition 103 is located towards the distal end 115 of the article 101.
- the cooling segment 107 is located adjacent the body of aerosol-generating composition 103 between the body of aerosol-generating composition 103 and the filter segment 109, such that the cooling segment 107 is in an abutting relationship with the aerosol-generating composition 103 and the filter segment 103.
- the filter segment 109 is located in between the cooling segment 107 and the mouth end segment 111.
- the mouth end segment 111 is located towards the proximal end 113 of the article 101 , adjacent the filter segment 109.
- the filter segment 109 is in an abutting relationship with the mouth end segment 111.
- the total length of the filter assembly 105 is between 37mm and 45mm, more preferably, the total length of the filter assembly 105 is 41mm.
- the rod of aerosol-generating composition 103 is between 34mm and 50mm in length, suitably between 38mm and 46mm in length, suitably 42mm in length. In one example, the total length of the article 101 is between 71mm and
- 95mm suitably between 79mm and 87mm, suitably 83mm.
- An axial end of the body of aerosol-generating composition 103 is visible at the distal end 115 of the article 101.
- the distal end 115 of the article 101 may comprise an end member (not shown) covering the axial end of the body of aerosol-generating composition 103.
- the body of aerosol-generating composition 103 is joined to the filter assembly 105 by annular tipping paper (not shown), which is located substantially around the circumference of the filter assembly 105 to surround the filter assembly 105 and extends partially along the length of the body of aerosol-generating composition 103.
- the tipping paper is made of 58GSM standard tipping base paper.
- the tipping paper has a length of between 42mm and 50mm, suitably of 46mm.
- the cooling segment 107 is an annular tube and is located around and defines an air gap within the cooling segment.
- the air gap provides a chamber for heated volatilised components generated from the body of aerosol- generating composition 103 to flow.
- the cooling segment 107 is hollow to provide a chamber for aerosol accumulation yet rigid enough to withstand axial compressive forces and bending moments that might arise during manufacture and whilst the article 101 is in use during insertion into the device 1.
- the thickness of the wall of the cooling segment 107 is approximately 0.29mm.
- the cooling segment 107 provides a physical displacement between the aerosol-generating composition 103 and the filter segment 109.
- the physical displacement provided by the cooling segment 107 will provide a thermal gradient across the length of the cooling segment 107.
- the cooling segment 107 is configured to provide a temperature differential of at least 40 degrees Celsius between a heated volatilised component entering a first end of the cooling segment 107 and a heated volatilised component exiting a second end of the cooling segment 107.
- the cooling segment 107 is configured to provide a temperature differential of at least 60 degrees Celsius between a heated volatilised component entering a first end of the cooling segment 107 and a heated volatilised component exiting a second end of the cooling segment 107.
- the length of the cooling segment 107 is at least 15mm. In one example, the length of the cooling segment 107 is between 20mm and 30mm, more particularly 23mm to 27mm, more particularly 25mm to 27mm, suitably 25mm.
- the cooling segment 107 is made of paper, which means that it is comprised of a material that does not generate compounds of concern, for example, toxic compounds when in use adjacent to the heater of the device 1.
- the cooling segment 107 is manufactured from a spirally wound paper tube which provides a hollow internal chamber yet maintains mechanical rigidity. Spirally wound paper tubes are able to meet the tight dimensional accuracy requirements of highspeed manufacturing processes with respect to tube length, outer diameter, roundness and straightness.
- the cooling segment 107 is a recess created from stiff plug wrap or tipping paper.
- the stiff plug wrap or tipping paper is manufactured to have a rigidity that is sufficient to withstand the axial compressive forces and bending moments that might arise during manufacture and whilst the article 101 is in use during insertion into the device 1.
- the filter segment 109 may be formed of any filter material sufficient to remove one or more volatilised compounds from heated volatilised components from the aerosol-generating material.
- the filter segment 109 is made of a mono-acetate material, such as cellulose acetate. The filter segment 109 provides cooling and irritation-reduction from the heated volatilised components without depleting the quantity of the heated volatilised components to an unsatisfactory level for a user.
- a capsule may be provided in filter segment 109. It may be disposed substantially centrally in the filter segment 109, both across the filter segment 109 diameter and along the filter segment 109 length. In other cases, it may be offset in one or more dimension.
- the capsule may in some cases, where present, contain a volatile component such as a flavourant or aerosol generating agent.
- the density of the cellulose acetate tow material of the filter segment 109 controls the pressure drop across the filter segment 109, which in turn controls the draw resistance of the article 101. Therefore the selection of the material of the filter segment 109 is important in controlling the resistance to draw of the article 101.
- the filter segment performs a filtration function in the article 101.
- the filter segment 109 is made of a 8Y15 grade of filter tow material, which provides a filtration effect on the heated volatilised material, whilst also reducing the size of condensed aerosol droplets which result from the heated volatilised material.
- the presence of the filter segment 109 provides an insulating effect by providing further cooling to the heated volatilised components that exit the cooling segment 107. This further cooling effect reduces the contact temperature of the user’s lips on the surface of the filter segment 109.
- the filter segment 109 is between 6mm to 10mm in length, suitably 8mm.
- the mouth end segment 111 is an annular tube and is located around and defines an air gap within the mouth end segment 111.
- the air gap provides a chamber for heated volatilised components that flow from the filter segment 109.
- the mouth end segment 111 is hollow to provide a chamber for aerosol accumulation yet rigid enough to withstand axial compressive forces and bending moments that might arise during manufacture and whilst the article is in use during insertion into the device 1.
- the thickness of the wall of the mouth end segment 111 is approximately 0.29mm.
- the length of the mouth end segment 111 is between 6mm to 10mm, suitably 8mm.
- the mouth end segment 111 may be manufactured from a spirally wound paper tube which provides a hollow internal chamber yet maintains critical mechanical rigidity. Spirally wound paper tubes are able to meet the tight dimensional accuracy requirements of high-speed manufacturing processes with respect to tube length, outer diameter, roundness and straightness. The mouth end segment 111 provides the function of preventing any liquid condensate that accumulates at the exit of the filter segment 109 from coming into direct contact with a user.
- the mouth end segment 111 and the cooling segment 107 may be formed of a single tube and the filter segment 109 is located within that tube separating the mouth end segment 111 and the cooling segment 107.
- FIGS 3 and 4 there are shown a partially cut-away section and perspective views of an example of an article 301.
- the reference signs shown in Figures 3 and 4 are equivalent to the reference signs shown in Figures 1 and 2, but with an increment of 200.
- a ventilation region 317 is provided in the article 301 to enable air to flow into the interior of the article 301 from the exterior of the article 301.
- the ventilation region 317 takes the form of one or more ventilation holes 317 formed through the outer layer of the article 301.
- the ventilation holes may be located in the cooling segment 307 to aid with the cooling of the article 301.
- the ventilation region 317 comprises one or more rows of holes, and preferably, each row of holes is arranged circumferentially around the article 301 in a cross-section that is substantially perpendicular to a longitudinal axis of the article 301.
- each row of ventilation holes may have between 12 to 36 ventilation holes 317.
- the ventilation holes 317 may, for example, be between 100 to 500pm in diameter.
- an axial separation between rows of ventilation holes 317 is between 0.25mm and 0.75mm, suitably 0.5mm.
- the ventilation holes 317 are of uniform size. In another example, the ventilation holes 317 vary in size.
- the ventilation holes can be made using any suitable technique, for example, one or more of the following techniques: laser technology, mechanical perforation of the cooling segment 307 or preperforation of the cooling segment 307 before it is formed into the article 301.
- the ventilation holes 317 are positioned so as to provide effective cooling to the article 301.
- the rows of ventilation holes 317 are located at least 11mm from the proximal end 313 of the article, suitably between 17mm and 20mm from the proximal end 313 of the article 301.
- the location of the ventilation holes 317 is positioned such that user does not block the ventilation holes 317 when the article 301 is in use.
- Providing the rows of ventilation holes between 17mm and 20mm from the proximal end 313 of the article 301 enables the ventilation holes 317 to be located outside of the device 1 , when the article 301 is fully inserted in the device 1, as can be seen in Figures 6 and 7.
- By locating the ventilation holes outside of the device non-heated air is able to enter the article 301 through the ventilation holes from outside the device 1 to aid with the cooling of the article 301.
- the length of the cooling segment 307 is such that the cooling segment 307 will be partially inserted into the device 1, when the article 301 is fully inserted into the device 1.
- the length of the cooling segment 307 provides a first function of providing a physical gap between the heater arrangement of the device 1 and the heat sensitive filter arrangement 309, and a second function of enabling the ventilation holes 317 to be located in the cooling segment, whilst also being located outside of the device 1 , when the article 301 is fully inserted into the device 1.
- the majority of the cooling element 307 is located within the device 1. However, there is a portion of the cooling element 307 that extends out of the device 1. It is in this portion of the cooling element 307 that extends out of the device 1 in which the ventilation holes 317 are located.
- FIG. 5 to 7 there is shown an example of a device 1 arranged to heat aerosol-generating composition to volatilise at least one component of said aerosol-generating composition, typically to form an aerosol which can be inhaled.
- the device 1 is a heating device which releases compounds by heating, but not burning, the aerosol-generating composition.
- a first end 3 is sometimes referred to herein as the mouth or proximal end 3 of the device 1 and a second end 5 is sometimes referred to herein as the distal end 5 of the device 1.
- the device 1 has an on/off button 7 to allow the device 1 as a whole to be switched on and off as desired by a user.
- the device 1 comprises a housing 9 for locating and protecting various internal components of the device 1.
- the housing 9 comprises a uni-body sleeve 11 that encompasses the perimeter of the device 1 , capped with a top panel 17 which defines generally the ‘top’ of the device 1 and a bottom panel 19 which defines generally the ‘bottom’ of the device 1.
- the housing comprises a front panel, a rear panel and a pair of opposite side panels in addition to the top panel 17 and the bottom panel 19.
- the top panel 17 and/or the bottom panel 19 may be removably fixed to the uni-body sleeve 11 , to permit easy access to the interior of the device 1 , or may be “permanently” fixed to the uni-body sleeve 11 , for example to deter a user from accessing the interior of the device 1.
- the panels 17 and 19 are made of a plastics material, including for example glass-filled nylon formed by injection moulding, and the uni-body sleeve 11 is made of aluminium, though other materials and other manufacturing processes may be used.
- the top panel 17 of the device 1 has an opening 20 at the mouth end 3 of the device 1 through which, in use, the article 101 , 301 including the aerosol-generating composition may be inserted into the device 1 and removed from the device 1 by a user.
- the housing 9 has located or fixed therein a heater arrangement 23, control circuitry 25 and a power source 27.
- the heater arrangement 23, the control circuitry 25 and the power source 27 are laterally adjacent (that is, adjacent when viewed from an end), with the control circuitry 25 being located generally between the heater arrangement 23 and the power source 27, though other locations are possible.
- the control circuitry 25 may include a controller, such as a microprocessor arrangement, configured and arranged to control the heating of the aerosolgenerating composition in the article 101 , 301 as discussed further below.
- a controller such as a microprocessor arrangement
- the power source 27 may be for example a battery, which may be a rechargeable battery or a non-rechargeable battery.
- suitable batteries include for example a lithium-ion battery, a nickel battery (such as a nickel-cadmium battery), an alkaline battery and/ or the like.
- the battery 27 is electrically coupled to the heater arrangement 23 to supply electrical power when required and under control of the control circuitry 25 to heat the aerosol-generating composition in the article (as discussed, to volatilise the aerosol-generating material without causing the aerosol-generating composition to burn).
- An advantage of locating the power source 27 laterally adjacent to the heater arrangement 23 is that a physically large power source 25 may be used without causing the device 1 as a whole to be unduly lengthy.
- a physically large power source 25 has a higher capacity (that is, the total electrical energy that can be supplied, often measured in Amp-hours or the like) and thus the battery life for the device 1 can be longer.
- the heater arrangement 23 is generally in the form of a hollow cylindrical tube, having a hollow interior heating chamber 29 into which the article 101, 301 comprising the aerosol-generating material is inserted for heating in use.
- the heater arrangement 23 may comprise a single heating element or may be formed of plural heating elements aligned along the longitudinal axis of the heater arrangement 23.
- the or each heating element may be annular or tubular, or at least part-annular or part-tubular around its circumference.
- the or each heating element may be a thin film heater.
- the or each heating element may be made of a ceramics material.
- suitable ceramics materials include alumina and aluminium nitride and silicon nitride ceramics, which may be laminated and sintered.
- Other heating arrangements are possible, including for example inductive heating, infrared heater elements, which heat by emitting infrared radiation, or resistive heating elements formed by for example a resistive electrical winding.
- the heater arrangement 23 is supported by a stainless steel support tube and comprises a polyimide heating element. The heater arrangement 23 is dimensioned so that substantially the whole of the body of aerosolgenerating composition 103, 303 of the article 101 , 301 is inserted into the heater arrangement 23 when the article 101 , 301 is inserted into the device 1.
- the or each heating element may be arranged so that selected zones of the aerosol-generating material can be independently heated, for example in turn (over time, as discussed above) or together (simultaneously) as desired.
- the heater arrangement 23 in this example is surrounded along at least part of its length by a thermal insulator 31.
- the insulator 31 helps to reduce heat passing from the heater arrangement 23 to the exterior of the device 1. This helps to keep down the power requirements for the heater arrangement 23 as it reduces heat losses generally.
- the insulator 31 also helps to keep the exterior of the device 1 cool during operation of the heater arrangement 23.
- the insulator 31 may be a double-walled sleeve which provides a low pressure region between the two walls of the sleeve.
- the insulator 31 may be for example a “vacuum” tube, i.e. a tube that has been at least partially evacuated so as to minimise heat transfer by conduction and/or convection.
- a “vacuum” tube i.e. a tube that has been at least partially evacuated so as to minimise heat transfer by conduction and/or convection.
- Other arrangements for the insulator 31 are possible, including using heat insulating materials, including for example a suitable foam-type material, in addition to or instead of a double-walled sleeve.
- the housing 9 may further comprises various internal support structures 37 for supporting all internal components, as well as the heating arrangement 23.
- the device 1 further comprises a collar 33 which extends around and projects from the opening 20 into the interior of the housing 9 and a generally tubular chamber 35 which is located between the collar 33 and one end of the vacuum sleeve 31.
- the chamber 35 further comprises a cooling structure 35f, which in this example, comprises a plurality of cooling fins 35f spaced apart along the outer surface of the chamber 35, and each arranged circumferentially around outer surface of the chamber 35.
- the air gap 36 is around all of the circumference of the article 101 , 301 over at least part of the cooling segment 307.
- the collar 33 comprises a plurality of ridges 60 arranged circumferentially around the periphery of the opening 20 and which project into the opening 20.
- the ridges 60 take up space within the opening 20 such that the open span of the opening 20 at the locations of the ridges 60 is less than the open span of the opening 20 at the locations without the ridges 60.
- the ridges 60 are configured to engage with an article 101, 301 inserted into the device to assist in securing it within the device 1.
- Open spaces (not shown in the Figures) defined by adjacent pairs of ridges 60 and the article 101 , 301 form ventilation paths around the exterior of the article 101 , 301.
- the body of aerosol-generating composition 103, 303 which is located towards the distal end 115, 315 of the article 101, 301 , is entirely received within the heater arrangement 23 of the device 1.
- the proximal end 113, 313 of the article 101, 301 extends from the device 1 and acts as a mouthpiece assembly for a user.
- the heater arrangement 23 will heat the article 101, 301 to volatilise at least one component of the aerosol-generating composition from the body of aerosol-generating composition 103, 303.
- the primary flow path for the heated volatilised components from the body of aerosol-generating composition 103, 303 is axially through the article 101 , 301, through the chamber inside the cooling segment 107, 307, through the filter segment 109, 309, through the mouth end segment 111 , 313 to the user.
- the temperature of the heated volatilised components that are generated from the body of aerosol-generating composition is between 60°C and 250°C, which may be above the acceptable inhalation temperature for a user. As the heated volatilised component travels through the cooling segment 107, 307, it will cool and some volatilised components will condense on the inner surface of the cooling segment 107, 307.
- cool air will be able to enter the cooling segment 307 via the ventilation holes 317 formed in the cooling segment 307. This cool air will mix with the heated volatilised components to provide additional cooling to the heated volatilised components.
- Another aspect of the invention provides a method of making an aerosolgenerating composition according to the first aspect.
- the method may comprise (a) forming a slurry comprising components of the aerosol-generating material or precursors thereof, (b) forming a layer of the slurry, (c) optionally setting the slurry, and (d) drying to form an aerosol-generating material.
- Step (b) of forming a layer of the slurry may comprise spraying, casting or extruding the slurry, for example.
- the slurry layer is formed by electrospraying the slurry.
- the slurry layer is formed by casting the slurry.
- (b) and/or (c) and/or (d) may, at least partially, occur simultaneously (for example, during electrospraying). In some cases, (b), (c) and (d) may occur sequentially.
- the slurry is applied to a support.
- the layer may be formed on a support.
- the slurry comprises binder, aerosol-generating agent, flavour and emulsifier.
- the slurry may comprise these components in any of the proportions given herein in relation to the composition of the aerosol-generating composition.
- the slurry may comprise: - an aerosol-generating agent in an amount of from about 1 to about 80 wt% of the aerosol-generating material;
- the total amount of binder is from about 5 to about 50 wt% of the aerosol-generating material, and wherein the one or more binders include a cellulosic binder;
- an emulsifier in an amount of from about 1 to about 25 wt% of the aerosolgenerating material; and - optionally a filler.
- the setting of the gel (c) may comprise the addition of a setting agent or crosslinking agent to the slurry.
- the slurry may comprise sodium, potassium or ammonium alginate as a gel-precursor, and a setting agent or crosslinking agent comprising a calcium source (such as calcium chloride), may be added to the slurry to form a calcium alginate gel.
- the total amount of the setting agent or crosslinking agent such as a calcium source, may be 0.5-5wt% (calculated on a dry weight basis).
- the addition of too little setting agent or crosslinking agent may result in an aerosol-generating material which does not stabilise the aerosol-generating material components and results in these components dropping out of the aerosol-generating material.
- the addition of too much setting agent or crosslinking agent results in an aerosol-generating material that is very tacky and consequently has poor handleability.
- Alginate salts are derivatives of alginic acid and are typically high molecular weight polymers (10-600 kDa).
- Alginic acid is a copolymer of b-D-mannuronic (M) and a-L-guluronic acid (G) units (blocks) linked together with (1,4)-glycosidic bonds to form a polysaccharide.
- M b-D-mannuronic
- G a-L-guluronic acid
- the alginate crosslinks to form a gel.
- Alginate salts with a high G monomer content more readily form a gel on addition of the calcium source.
- the gel-precursor may comprise an alginate salt in which at least about 40%, 45%, 50%, 55%, 60% or 70% of the monomer units in the alginate copolymer are a-L-guluronic acid (G) units.
- Setting the gel in step (c) may not be required, for example when the only binder present is a cellulosic binder such as CMC.
- the slurry may further comprise a setting agent or crosslinking agent and/or a setting agent or crosslinking agent may be applied to the slurry.
- the method may further comprise the step (c) of setting the slurry.
- the drying (d) may, in some cases, remove from about 50wt%, 60wt%, 70wt%, 80wt% or 90wt% to about 80wt%, 90wt% or 95wt% (WWB) of water in the slurry.
- the drying (d) may, in some cases, may reduce the cast material thickness by at least 80%, suitably 85% or 87%.
- the slurry may be cast at a thickness of 2mm, and the resulting dried aerosol-generating material may have a thickness of 0.2mm.
- the slurry may be heated to remove at least about 60 wt%, 70 wt%, 80 wt%, 85 wt% or 90 wt% of the solvent.
- the aerosol-generating film may be formed by combining the aerosol- forming agent, binders, flavour, emulsifier, a solvent and any optional further components to form a slurry and then heating the slurry to volatilise at least some of the solvent to form the aerosol-generating film.
- the slurry may be heated to remove at least about 60 wt%, 70 wt%, 80 wt%, 85 wt% or 90 wt% of the solvent.
- the slurry itself may also form part of the invention.
- the slurry solvent may consist essentially of or consist of water.
- the slurry may comprise from about 50wt%, 60wt%, 70wt%, 80wt% or 90wt% of solvent (WWB).
- the dry weight content of the slurry may match the dry weight content of the aerosol-generating material.
- the discussion herein relating to the solid composition is explicitly disclosed in combination with the slurry aspect of the invention.
- the method comprises heating the aerosolgenerating material to a temperature of less than or equal to 350 °C. In some embodiments, the method comprises heating the aerosol-generating material to a temperature of from about 220 °C to about 280 °C.
- the method comprises heating at least a portion of the aerosol-generating material to a temperature of from about 220 °C to about 280 °C over a session of use.
- “Session of use” as used herein refers to a single period of use of the noncombustible aerosol provision system by a user.
- the session of use begins at the point at which power is first supplied to at least one heating unit present in the heating assembly.
- the device will be ready for use after a period of time has elapsed from the start of the session of use.
- the session of use ends at the point at which no power is supplied to any of the heating elements in the aerosol-generating device.
- the end of the session of use may coincide with the point at which the smoking article is depleted (the point at which the total particulate matter yield (mg) in each puff would be deemed unacceptably low by a user).
- the session will have a duration of a plurality of puffs. Said session may have a duration less than 7 minutes, or 6 minutes, or 5 minutes, or 4 minutes and 30 seconds, or 4 minutes, or 3 minutes and 30 seconds. In some embodiments, the session of use may have a duration of from 2 to 5 minutes, or from 3 to 4.5 minutes, or 3.5 to 4.5 minutes, or suitably 4 minutes.
- a session may be initiated by the user actuating a button or switch on the device, causing at least one heating element to begin rising in temperature.
- At least 20wt% of the flavour present in the aerosol-generating material is aerosolised, or at least 30wt%, 40wt% or 50wt%. That is, after a session of use, the amount of flavour in the aerosolgenerating material is depleted by 20wt%, 30wt%, 40wt% or 50wt%.
- the ratio of cellulosic binder to non-cellulosic binder in the aerosol-generating material as described herein may allow for more efficient delivery of active substance to a user (e.g. a higher proportion of flavour is aerosolised from the aerosol-generating material).
- Embodiment 2 The aerosol-generating material or slurry of Embodiment 1, comprising about 0.1-50 wt% flavour.
- Embodiment 3 The aerosol-generating material or slurry of Embodiment 2, comprising about 1- 50wt% flavour.
- the aerosol-generating material or slurry of Embodiment 1 comprising about 5- 50 wt% flavour. 5.
- the aerosol-generating material or slurry of Embodiment 5A comprising about 10-25 wt% flavour.
- Embodiment 5B The aerosol-generating material or slurry of Embodiment 5A, comprising about 10-20 wt% flavour.
- Embodiment 5C The aerosol-generating material or slurry of Embodiment 5B, comprising about 15-20 wt% flavour.
- the aerosol-generating material or slurry of Embodiment 4 comprising about 15- 45 wt% flavour.
- the aerosol-generating material or slurry of Embodiment 1 comprising about 20-
- the aerosol-generating material or slurry of Embodiment 8 comprising about 30- 50 wt% flavour.
- the aerosol-generating material or slurry of Embodiment 10 comprising about 35-50 wt% flavour. 12.
- the aerosol-generating material or slurry of Embodiment 13 comprising about 10-45 wt% of one or more binders.
- Embodiment 13a The aerosol-generating material or slurry of Embodiment 13a, comprising about 10-40 wt% of one or more binders.
- the aerosol-generating material or slurry of Embodiment 14 comprising about 10-35 wt% of one or more binders.
- the aerosol-generating material or slurry of Embodiment 15 comprising about 10-30 wt% of one or more binders. 17.
- the aerosol-generating material or slurry of Embodiment 18, comprising about 15-40 wt% of one or more binders.
- the aerosol-generating material or slurry of Embodiment 19 comprising about 15-35 wt% of one or more binders.
- the aerosol-generating material or slurry of Embodiment 20 comprising about 15-30 wt% of one or more binders. 22.
- the aerosol-generating material or slurry of Embodiment 21 comprising about
- the aerosol-generating material or slurry of Embodiment 23 comprising about 20-40 wt% of one or more binders.
- the aerosol-generating material or slurry of Embodiment 24 comprising about 20-35 wt% of one or more binders.
- the aerosol-generating material or slurry of Embodiment 25 comprising about 20-30 wt% of one or more binders.
- the aerosol-generating material or slurry of Embodiment 26 comprising about 20-25 wt% of one or more binders.
- the aerosol-generating material or slurry of any preceding Embodiment comprising about 5-35 wt% aerosol-generating agent. 29.
- the aerosol-generating material or slurry of Embodiment 28 comprising about
- the aerosol-generating material or slurry of any of Embodiments 1-27 comprising about 5-30 wt% aerosol-generating agent.
- the aerosol-generating material or slurry of any of Embodiments 1-27 comprising about 5-25 wt% aerosol-generating agent.
- the aerosol-generating material or slurry of any of Embodiments 1-27 comprising about 5-15 wt% aerosol-generating agent.
- the aerosol-generating material or slurry of Embodiment 30 comprising about 10-30 wt% aerosol-generating agent.
- the aerosol-generating material or slurry of Embodiment 31 comprising about
- Embodiment 33 The aerosol-generating material or slurry of Embodiment 32, comprising about 10-20 wt% aerosol-generating agent.
- aerosol-generating material or slurry of any of Embodiments 1-27 comprising about 12-30 wt% aerosol-generating agent.
- Embodiment 35 The aerosol-generating material or slurry of Embodiment 34, comprising about 12-25 wt% aerosol-generating agent.
- Embodiment 36 The aerosol-generating material or slurry of Embodiment 35, comprising about 12-20 wt% aerosol-generating agent.
- 37 The aerosol-generating material or slurry of any preceding Embodiment, comprising about 1-20 wt% emulsifier.
- Embodiment 37a The aerosol-generating material or slurry of Embodiment 37, comprising about 1-15 wt% emulsifier.
- Embodiment 37b The aerosol-generating material or slurry of Embodiment 37a. comprising about 1-12 wt% emulsifier.
- Embodiment 37b The aerosol-generating material or slurry of Embodiment 37b, comprising about 1-10 wt% emulsifier.
- Embodiment 39 The aerosol-generating material or slurry of Embodiment 38, comprising about 1-7 wt% emulsifier. 40. The aerosol-generating material or slurry of any of Embodiments 1 -36, comprising about 3-12 wt% emulsifier.
- the aerosol-generating material or slurry of Embodiment 40 comprising about 3-10 wt% emulsifier.
- the aerosol-generating material or slurry of Embodiment 41 comprising about
- Embodiment 44 The aerosol-generating material or slurry of Embodiment 43, comprising about 5-10 wt% emulsifier.
- Embodiment 45 The aerosol-generating material or slurry of Embodiment 44, comprising about 5-7 wt% emulsifier.
- the aerosol-generating agent comprises (or is) one or more of glycerol, propylene glycol, diethylene glycol, triethylene glycol, tetraethylene glycol, 1 ,3- butylene glycol, erythritol, meso-Erythritol, ethyl vanillate, ethyl laurate, a diethyl suberate, triethyl citrate, triacetin, a diacetin mixture, benzyl benzoate, benzyl phenyl acetate, tributyrin, lauryl acetate, lauric acid, myristic acid, and propylene carbonate. 47.
- the cellulosic binder comprises (or is) one or more compounds selected from hydroxymethyl cellulose, hydroxyethyl cellulose, hydroxypropyl cellulose, carboxymethylcellulose (CMC), hydroxypropyl methylcellulose (HPMC), methyl cellulose, ethyl cellulose, cellulose acetate (CA), cellulose acetate butyrate (CAB), and cellulose acetate propionate (CAP).
- the aerosol-generating material or slurry of Embodiment 49 wherein the cellulosic binder comprises (or is) one or more compounds selected from hydroxyethyl cellulose, hydroxypropyl cellulose, and/or carboxymethylcellulose.
- the cellulosic binder comprises (or is) carboxymethylcellulose.
- the aerosol-generating material or slurry of any preceding Embodiment wherein the one or more binders include a cellulosic binder and a non-cellulosic binder.
- the aerosol-generating material or slurry of Embodiment 52 wherein the non- cellulosic binder comprises (or is) one or more compounds selected from alginates, pectins, starches (and derivatives), gums, silica or silicones compounds, clays and/or polyvinyl alcohol.
- the non-cellulosic binder comprises (or is) one or more compounds selected from alginates, pectins, pullulan, xanthan gum, guar gum, carrageenan, agarose, acacia gum, fumed silica, PDMS, sodium silicate, kaolin and/or polyvinyl alcohol.
- the binder comprises one or more of hydroxyethyl cellulose, hydroxypropyl cellulose and/or carboxymethylcellulose and one or more of alginates, pectins, pullulan, xanthan gum, guar gum, carrageenan, agarose, acacia gum, fumed silica, PDMS, sodium silicate, kaolin and polyvinyl alcohol.
- Embodiment 57 The aerosol-generating material or slurry of Embodiment 57, wherein the weight ratio of cellulosic binder to non-cellulosic binder is from about 1 : 1 to about 1:2.
- Embodiment 58 The aerosol-generating material or slurry of Embodiment 58, wherein the weight ratio of cellulosic binder to non-cellulosic binder is from about 2:3 to about 3:2.
- Embodiment 60 The aerosol-generating material or slurry of Embodiment 59, wherein the weight ratio of cellulosic binder to non-cellulosic binder is from 1:1 to 3:2.
- Embodiment 65 The aerosol-generating material or slurry of Embodiment 63 or 64, comprising about 0.5-5wt% crosslinking agent.
- Embodiment 67 The aerosol-generating material or slurry of Embodiment 67, wherein the fillers are selected from inorganic filler materials, wood pulp, hemp fibre, cellulose and cellulose derivatives, such as wood pulp and/or MCC.
- 68B The aerosol-generating material or slurry of any of Embodiments 1-66, wherein the aerosol-generating material comprises less than 10 wt% filler.
- 68C The aerosol-generating material or slurry of any of Embodiments 1 -66, wherein the aerosol-generating material comprises less than 5 wt% filler.
- 68G The aerosol-generating material or slurry of any of Embodiments 1 -66, wherein the aerosol-generating material comprises from about 40 to about 60 wt% filler.
- 68H The aerosol-generating material or slurry of any of Embodiments 1-66, wherein the aerosol-generating material comprises from about 45 to about 55 wt% filler.
- 71 The aerosol-generating material or slurry of any preceding Embodiment, wherein the aerosol-generating material or slurry does not comprise tobacco fibres. 71a. The aerosol-generating material or slurry of any preceding Embodiment, wherein the aerosol-generating material comprises caramel.
- aerosol-generating material of any preceding Embodiment wherein the aerosol-generating material consists of, or consists essentially of, binder, water, aerosol-generating agent, flavour, emulsifier and optionally an active substance and/or a filler.
- aerosol-generating material of any preceding embodiment wherein the aerosol-generating material consists of, or consists essentially of binder, water, aerosol-generating agent, flavour and emulsifier.
- aerosol-generating material consists of, or consists essentially of binder, water, aerosol-generating agent, flavour and emulsifier.
- aerosol-generating material is present on a support.
- An aerosol-generating composition comprising an aerosol-generating material according to any preceding Embodiment.
- the aerosol-generating composition of Embodiment 75 further comprising a second aerosol-generating material having a different composition, which comprises: an aerosol-generating agent in an amount of from about 1 to about 80 wt% of the aerosol-generating material; one or more binders, wherein the total amount of binder is from about 5 to about 50 wt% of the aerosol-generating material; - flavour in an amount of from about 0.1 to about 60 wt% of the aerosolgenerating material; an emulsifier in an amount of from about 1 to about 25 wt% of the aerosolgenerating material; and optionally a filler.
- a second aerosol-generating material having a different composition which comprises: an aerosol-generating agent in an amount of from about 1 to about 80 wt% of the aerosol-generating material; one or more binders, wherein the total amount of binder is from about 5 to about 50 wt% of the aerosol-generating material; - flavour in an amount of from about 0.1 to about 60 wt% of the
- the aerosol-generating composition of Embodiment 76 wherein the second aerosol-generating material comprises: an aerosol-generating agent in an amount of from about 1 to about 80 wt% of the aerosol-generating material; one or more binders, wherein the total amount of binder is from about 10 to about 50 wt% of the aerosol-generating material; flavour in an amount of from about 0.1 to about 60 wt% of the aerosolgenerating material; - an emulsifier in an amount of from about 1 to about 15 wt% of the aerosolgenerating material; and optionally a filler.
- Embodiment 76 or 76a wherein the second aerosol-generating material is as defined in any of Embodiments 1-48 or 62-74.
- Embodiment 78 or 78A wherein the cellulosic binder comprises (or is) one or more compounds selected from hydroxymethyl cellulose, hydroxyethyl cellulose, hydroxypropyl cellulose, carboxymethylcellulose (CMC), hydroxypropyl methylcellulose (HPMC), methyl cellulose, ethyl cellulose, cellulose acetate (CA), cellulose acetate butyrate (CAB), and cellulose acetate propionate (CAP).
- CMC carboxymethylcellulose
- HPMC hydroxypropyl methylcellulose
- CA cellulose acetate
- CAB cellulose acetate butyrate
- CAP cellulose acetate propionate
- Embodiment 80 The aerosol-generating composition of Embodiment 79, wherein the cellulosic binder comprises (or is) one or more compounds selected from hydroxyethyl cellulose, hydroxypropyl cellulose, and/or carboxymethylcellulose.
- Embodiment 80 The aerosol-generating composition of Embodiment 80, wherein the cellulosic binder comprises (or is) carboxymethylcellulose.
- non-cellulosic binder comprises (or is) one or more compounds selected from alginates, pectins, starches (and derivatives), gums, silica or silicones compounds, clays and/or polyvinyl alcohol.
- the aerosol-generating composition of Embodiment 82, wherein the non- cellulosic binder comprises (or is) one or more compounds selected from alginates, pectins, pullulan, xanthan gum, guar gum, carrageenan, agarose, acacia gum, fumed silica, PDMS, sodium silicate, kaolin and/or polyvinyl alcohol.
- the aerosol-generating composition of Embodiment 85 wherein the weight ratio of first to second aerosol-generating material is from 2:3 to 3:2.
- aerosol-generating composition of any of Embodiments 75-88, wherein the other functional materials comprise one or more pH regulators, colouring agents, preservatives, binders, fillers, stabilisers, and/or antioxidants.
- Embodiment 89 or 90 The aerosol-generating composition of Embodiment 89 or 90, wherein the fillers are selected from inorganic filler materials, wood pulp, hemp fibre, cellulose and cellulose derivatives.
- Embodiment 89 or 90 The aerosol-generating composition of Embodiment 89 or 90, wherein the fillers are selected from maltodextrin or microcrystalline cellulose.
- Embodiment 89 or 90 The aerosol-generating composition of Embodiment 89 or 90, wherein the fillers have a density of less than about 2 g/cm 3 .
- Embodiment 91c The aerosol-generating composition of Embodiment 91b, wherein the fillers have a density of less than about 0.5 g/cm 3 .
- the aerosol-generating composition of any of Embodiments 75-94 comprising a total of from about 50-100 wt% (WWB) of aerosol-generating material.
- the aerosol-generating composition of any of Embodiments 75-94 comprising a total of from about 60-100 wt% (WWB) of the aerosol-generating material.
- the aerosol-generating composition of any of Embodiments 75-94 comprising a total of from about 60-95 wt% (WWB) of the aerosol-generating material.
- the aerosol-generating composition of any of Embodiments 75-94 comprising a total of from about 60-90 wt% (WWB) of the aerosol-generating material.
- the aerosol-generating composition of any of Embodiments 75-94 comprising a total of from about 70-100 wt% (WWB) of the aerosol-generating material.
- a consumable for use in a non-combustible aerosol provision device comprising the aerosol-generating composition of any of Embodiments 75-104.
- 106. A non-combustible aerosol provision system comprising the consumable of Embodiment 105 and a non-combustible aerosol provision device.
- Embodiment 110 The method of Embodiment 109 or the slurry of any of Embodiments 1-71 wherein the solvent comprises water.
- Embodiment 109 The method of Embodiment 109 or the slurry of any of Embodiments 1 -71 wherein the solvent consists essentially of, or consists of water.
- WWB solvent
- Exemplary and non-limiting formulations for twelve aerosol-generating compositions comprising an aerosol-generating material are provided in the table below. The percentages are given on a dry weight basis.
- Figure 8 shows the release profile of flavour (in this case menthol) from
- Formulation 1 shows flavour release at 190-200 °C.
- the temperature at which the flavour (i.e. menthol) is released can be increased to about 250 °C by using CMC instead of alginate (see Formulation 2 and Figure 9).
- a cellulosic binder such as CMC may be preferable to other binders (such as alginate) for reasons of reduced cost and/or ease of manufacturing. If a lower flavour release temperature is desired than is obtained when using CMC alone, then a mixture of CMC and alginate can be used (see Formulations 4 and 7-9 and Figures 10-13).
- the combination of cellulosic and non-cellulosic binders e.g.
- CMC and alginate allows for the flavour release temperature to be adjusted, whilst also allowing for reduced costs and/or easier manufacturer than formulations containing alginate alone.
- the formulations containing a combination of CMC and alginate also showed an increased longevity of flavour release.
- a cellulosic binder e.g. CMC
- a non-cellulosic binder e.g. alginate
- combining a cellulosic binder (e.g. CMC) with a non-cellulosic binder (e.g. alginate) in particular ratios may influence the temperature at which the flavour is released from the aerosol-generating material when heated and/or the point in a session of use at which point flavour is released.
- the temperature of flavour release can be increased.
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Abstract
The present invention relates to aerosol-generating materials; aerosol-generating compositions comprising the aerosol-generating material; articles for use with a non- combustible aerosol provision device; and non-combustible aerosol provision devices comprising the article. The aerosol-generating material comprises: about 1 to about 80wt% of an aerosol-generating material; about 5 to about 50wt% of one or more binders, wherein the one or more binders include a cellulosic binder; about 0.1 to about 60wt% flavour; about 1 to about 25wt% of an emulsifier; and optionally a filler.
Description
AEROSOL GENERATING COMPOSITION
Technical Field
The present invention relates to aerosol-generating compositions comprising an aerosol-generating material; consumables for use within a non-combustible aerosol provision system, the consumables comprising the aerosol-generating composition; and non-combustible aerosol provision systems.
Background Smoking consumables such as cigarettes, cigars and the like burn tobacco during use to create tobacco smoke. Alternatives to these types of consumables release an inhalable aerosol or vapour by releasing compounds from a substrate material by heating without burning. These may be referred to as non-combustible smoking consumables or aerosol generating assemblies.
One example of such a product is a heating device which releases compounds by heating, but not burning, a solid aerosol-generating material. This solid aerosol-generating material may, in some cases, contain a botanical material. The heating volatilises at least one component of the material, typically forming an inhalable aerosol. These products may be referred to as heat-not-burn devices, tobacco heating devices or tobacco heating products. Various different arrangements for volatilising at least one component of the solid aerosol-generating material are known. As another example, there are hybrid devices. These contain a liquid source
(which may or may not contain nicotine) which is vaporised by heating to produce an inhalable vapour or aerosol. The device additionally contains a solid aerosolgenerating material (which may or may not contain a tobacco material) and components of this material are entrained in the inhalable vapour or aerosol to produce the inhaled medium.
Summary
According to a first aspect of the present invention, there is provided an aerosol-generating material for use in aerosol generation, the aerosol-generating material comprising: - an aerosol-generating agent in an amount of from about 1 to about 80 wt% of the aerosol-generating material;
- one or more binders, wherein the total amount of binder is from about 5 to about 50 wt% of the aerosol-generating material, and wherein the one or more binders include a cellulosic binder; - flavour in an amount of from about 0.1 to about 60 wt% of the aerosolgenerating material;
- an emulsifier in an amount of from about 1 to about 25 wt% of the aerosolgenerating material; and
- optionally a filler.
In an embodiment the aerosol-generating material comprises:
- an aerosol-generating agent in an amount of from about 1 to about 80 wt% of the aerosol-generating material;
- one or more binders, wherein the total amount of binder is from about 10 to about 50 wt% of the aerosol-generating material, and wherein the one or more binders include a cellulosic binder;
- flavour in an amount of from about 0.1 to about 60 wt% of the aerosolgenerating material;
- an emulsifier in an amount of from about 1 to about 15 wt% of the aerosol- generating material; and
- optionally a filler.
In a second aspect, there is provided an aerosol-generating composition comprising the aerosol-generating material of the first aspect. According to a further aspect of the present invention, there is provided an aerosol-generating composition comprising a first aerosol-generating material and a second aerosol-generating material, wherein the first aerosol-generating material is defined according to the first aspect, and wherein the second aerosol-generating comprises
- an aerosol-generating agent in an amount of from about 1 to about 80 wt% of the aerosol-generating material;
- one or more binders, wherein the total amount of binder is from about 5 to about 50 wt% of the aerosol-generating material; - flavour in an amount of from about 0.1 to about 60 wt% of the aerosolgenerating material;
- an emulsifier in an amount of from about 1 to about 25 wt% of the aerosolgenerating material; and
- optionally a filler, wherein the composition of the second aerosol-generating material is different to the composition of the first aerosol-generating material.
In an embodiment the second aerosol-generating material comprises:
- an aerosol-generating agent in an amount of from about 1 to about 80 wt% of the aerosol-generating material;
- one or more binders, wherein the total amount of binder is from about 10 to about 50 wt% of the aerosol-generating material;
- flavour in an amount of from about 0.1 to about 60 wt% of the aerosolgenerating material; - an emulsifier in an amount of from about 1 to about 15 wt% of the aerosolgenerating material; and
- optionally a filler.
According to a further aspect of the present invention, there is provided a consumable for use within a non-combustible aerosol provision system, the consumable comprising the aerosol-generating composition as defined herein.
According to a further aspect of the present invention, there is provided a noncombustible aerosol provision system comprising the consumable as defined herein and a non-combustible aerosol provision device, the non-combustible aerosol provision device comprising an aerosol-generation device arranged to generate aerosol from the consumable when the consumable is used with the non-combustible aerosol provision device.
According to a further aspect of the invention, there is provided the use of an aerosol-generating composition as defined herein in a consumable for use in a noncombustible aerosol provision device, the non-combustible aerosol provision device comprising an aerosol-generation device arranged to generate aerosol from the consumable when the consumable is used with the non-combustible aerosol provision device.
According to a further aspect of the present invention, there is provided a method of making an aerosol-generating material or an aerosol-generating composition as described herein.
According to a further aspect of the present invention, there is provided a method of generating an aerosol using a non-combustible aerosol provision system as described herein, the method comprising heating the aerosol-generating material. In some embodiments, the method comprises heating the aerosol-generating material to a temperature of less than or equal to 350 °C. In some embodiments, the method comprises heating the aerosol-generating material to a temperature of from about 220 °C to about 280 °C. Further features and advantages of the invention will become apparent from the following description of preferred embodiments of the invention, given by way of example only, which is made with reference to the accompanying drawings.
Brief Description of the Drawings Figure 1 shows a section view of an example of an aerosol-generating article.
Figure 2 shows a perspective view of the article of Figure 1.
Figure 3 shows a sectional elevation of an example of an aerosol-generating article.
Figure 4 shows a perspective view of the article of Figure 3.
Figure 5 shows a perspective view of an example of an aerosol generating assembly.
Figure 6 shows a section view of an example of an aerosol generating assembly. Figure 7 shows a perspective view of an example of an aerosol generating assembly. Figure 8 shows the menthol release profile of an alginate containing gel.
Figure 9 shows the menthol release profile of a CMC containing gel.
Figures 10-13 show the menthol release profile of Alginate:CMC containing gels.
Figure 14 shows an exploded diagram of an example consumable.
Figure 15 shows an example of a consumable comprising a plurality of discrete portions of aerosol-generating material.
Detailed Description
The aerosol-generating compositions described herein are compositions that are capable of generating aerosol, for example when heated, irradiated or energized in any other way. The aerosol-generating composition may, for example, be in the form of a solid, liquid or gel which may or may not contain nicotine. The aerosolgenerating composition comprises an aerosol-generating material. The aerosolgenerating material may be an “amorphous solid”. In some embodiments, the amorphous solid is a “monolithic solid”. The aerosol-generating material may be non-fibrous or fibrous. In some embodiments, the aerosol-generating material may be a dried gel. The aerosol-generating material may be a solid material that may retain some fluid, such as liquid, within it. In some embodiments, the aerosolgenerating composition may for example comprise from about 50wt%, 60wt% or 70wt% of aerosol-generating material, to about 90wt%, 95wt% or 100wt% of aerosolgenerating material. In some cases, the aerosol-generating composition consists of aerosol-generating material.
As described hereinabove, the invention provides an aerosol-generating material, wherein the aerosol-generating material comprises:
an aerosol-generating agent in an amount of from about 1 to about 80 wt% of the aerosol-generating material; one or more binders, wherein the total amount of binder is from about 5 to about 50 wt% of the aerosol-generating material, and wherein the one or more binders include a cellulosic binder; flavour in an amount of from about 0.1 to about 60 wt% of the aerosolgenerating material; an emulsifier in an amount of from about 1 to about 25 wt% of the aerosolgenerating material; and optionally a filler.
The inventors have established that one or more binders including a cellulosic binder may provide an improved substrate. The use of a binder which comprises a cellulosic binder, such as carboxymethyl cellulose, may be advantageous due to lower material costs. The ease of manufacturing may also be improved as the specific choice of binder can circumvent the requirement of a crosslinking agent which can be challenging to apply. In one embodiment, the one or more binders include a cellulosic binder and a non-cellulosic binder. Without wishing to be bound by theory, it is believed that a combination of a cellulosic binder and a non-cellulosic binder may have a synergistic effect on the binding in the aerosol-generating material. For example, the ability of the aerosol-generating material to release flavour during use may be improved by using a combination of a cellulosic binder and a non-cellulosic binder.
Further, combining a cellulosic binder with a non-cellulosic binder in particular ratios may influence the temperature at which the flavour (such as menthol) is released from the aerosol-generating material when heated and/or the point in a session of use at which point flavour (such as menthol) is released.
The aerosol-generating material comprises about 1wt%, 5wt%, 10wt%, 12wt% or 13wt% to about 18wt%, 20wt%, 25wt%, 30wt%, 35wt%, 45wt%, 55wt%, 65wt%, 75wt% or 80wt% of an aerosol-generating agent (all calculated on a dry
weight basis). In exemplary embodiments, the aerosol-generating material comprises from 5-35wt%, 5-20wt%, 5-15wt%, 10-35wt%, 10-30wt%, 12-25wt%, 13-20wt% or 13-18wt% of an aerosol-generating agent (all calculated on a dry weight basis). In some embodiments, the aerosol-generating agent may comprise one or more of glycerol, propylene glycol, diethylene glycol, triethylene glycol, tetraethylene glycol, 1,3-butylene glycol, erythritol, meso-Erythritol, ethyl vanillate, ethyl laurate, a diethyl suberate, triethyl citrate, triacetin, a diacetin mixture, benzyl benzoate, benzyl phenyl acetate, tributyrin, lauryl acetate, lauric acid, myristic acid, and propylene carbonate. In some cases, the aerosol-generating agent comprises, consists essentially of or consists of glycerol.
The aerosol-generating material may comprise a total amount of about 5wt%, 10wt%, 12wt%, 15wt%, 17wt% or 20wt% to about 25wt%, 30wt%, 40wt%, 45wt% or 50wt% of one or more binders (all calculated on a dry weight basis). In exemplary embodiments, the aerosol-generating material comprises a total amount of 15wt%, 17wt%, 19wt% or 20wt% to about 25wt%, 27wt% or 30wt% of one or more binders. For example, the aerosol-generating material may comprise a total amount of 15- 30wt%, 17-27wt%, 17-25wt% or 20-25wt% of one or more binders.
The one or more binders include a cellulosic binder. Examples of cellulosic binders which may be used include, but are not limited to, hydroxymethyl cellulose, hydroxyethyl cellulose, hydroxypropyl cellulose, carboxymethylcellulose (CMC), hydroxypropyl methylcellulose (HPMC), methyl cellulose, ethyl cellulose, cellulose acetate (CA), cellulose acetate butyrate (CAB), and cellulose acetate propionate (CAP). In some embodiments, the cellulosic binder is selected from hydroxyethyl cellulose, hydroxypropyl cellulose, and/or carboxymethylcellulose. In some embodiments, the cellulosic binder comprises carboxymethylcellulose (CMC). In some embodiments, the cellulosic binder is carboxymethylcellulose (CMC).
In some cases, the one or more binders include a cellulosic binder and a non- cellulosic binder. The cellulosic binder may be selected from those listed above. In some embodiments, the cellulosic binder is selected from hydroxyethyl cellulose, hydroxypropyl cellulose and/or carboxymethylcellulose. In some embodiments, the
cellulosic binder comprises carboxymethylcellulose. In some embodiments, the cellulosic binder is carboxymethylcellulose. The non-cellulosic binder may be selected from the group comprising alginates, pectins, starches (and derivatives), gums, silica or silicones compounds, clays, polyvinyl alcohol and combinations thereof. In some embodiments, the non-cellulosic binder is selected from the group consisting of alginates, pectins, pullulan, xanthan gum, guar gum, carrageenan, agarose, acacia gum, fumed silica, PDMS, sodium silicate, kaolin and polyvinyl alcohol. In some embodiments, the non-cellulosic binder comprises alginate. In some embodiments, the cellulosic binder is alginate.
In some embodiments, the binder comprises one or more of hydroxyethyl cellulose, hydroxypropyl cellulose and/or carboxymethylcellulose, and one or more of alginates, pectins, pullulan, xanthan gum, guar gum, carrageenan, agarose, acacia gum, fumed silica, PDMS, sodium silicate, kaolin and polyvinyl alcohol. In some cases, the binder comprises, consists essentially of or consists of carboxymethyl cellulose. In some cases, the binder comprises, consists essentially of or consists of carboxymethyl cellulose and alginate.
In some embodiments, the aerosol-generating composition comprises a crosslinking agent. In some cases, the crosslinking agent comprises calcium ions. In some cases, the aerosol-generating composition may comprise carboxymethyl cellulose and a calcium-crosslinked alginate. The crosslinking agent may also be described as a setting agent. In some embodiments, the aerosol-generating composition does not comprise a crosslinking agent.
In some embodiments, the binder comprises carboxymethyl cellulose, and the carboxymethyl cellulose is present in the aerosol-generating composition in an amount from 5-50wt%, 5-25wt%, 5-20wt%, 5-15wt%, 10-50wt%, 15-40wt%, 20- 35wt% or 20-30wt% of the aerosol-generating material (calculated on a dry weight basis). In some embodiments, carboxymethyl cellulose is the only binder present in the aerosol-generating composition. In other embodiments, the binder comprises
carboxymethyl cellulose and at least one further non-cellulosic binder, such as alginate.
Suitably, the binder comprises a cellulosic binder and a non-cellulosic binder. In some embodiments, the weight ratio of cellulosic binder to non-cellulosic binder is from 1 :4 to 4:1 , from 1 :1 to 2:1, from 2:3 to 7:3, from 2:3 to 3:2 or from 1 :1 to 3:2. In some embodiments, the weight ratio of cellulosic binder to non-cellulosic binder is >1 :1. That is, in some embodiments, the cellulosic binder is present in an amount greater than the amount of non-cellulosic binder. In some embodiments, the weight ratio of cellulosic binder to non-cellulosic binder is about 1 :1. In some embodiments, the weight ratio of cellulosic binder to non-cellulosic binder is about 3:2
The inventors have found that by including one or more binders in the aerosolgenerating material, flavourant compounds (for example menthol) are stabilised within the binder matrix allowing controlled release of flavourant over the course of a smoking session. The flavouring (e.g. menthol) is stabilised at high concentrations and the products have a good shelf life.
The aerosol-generating material may comprise about 0.1wt%, 0.5 wt%, 1wt%, 5wt%, 10wt%, 15wt%, 20wt%, 25wt%, 30wt% or 35wt% to about 45wt%, 50wt% or
60wt% of flavour (all calculated on a dry weight basis). In exemplary embodiments, the aerosol-generating material comprises 1 wt%, 5 wt%, 10 wt%, 20 wt%, 30wt%, or 35wt% to about 42wt%, 45wt% or 47wt% of flavour. For example, the aerosolgenerating material may comprise 1-45wt%, 10-45wt%, 20-50wt%, 30-50wt%, 30-45wt% or 35-45wt% of flavour. Alternatively, the aerosol-generating material may comprise 5-25wt%, 10-25wt%, 10-20wt% or 15-20wt% of flavour.
As used herein, the terms “flavour” and “flavourant” refer to materials which, where local regulations permit, may be used to create a desired taste, aroma, or other somatosensorial sensation in a product for adult consumers. They may include naturally occurring flavour materials, botanicals, extracts of botanicals, synthetically obtained materials, or combinations thereof (e.g., tobacco, cannabis, licorice (liquorice), hydrangea, eugenol, Japanese white bark magnolia leaf, chamomile, fenugreek, clove, maple, matcha, menthol, Japanese mint, aniseed (anise),
cinnamon, turmeric, Indian spices, Asian spices, herb, wintergreen, cherry, berry, red berry, cranberry, peach, apple, orange, mango, clementine, lemon, lime, tropical fruit, papaya, rhubarb, grape, durian, dragon fruit, cucumber, blueberry, mulberry, citrus fruits, Drambuie, bourbon, scotch, whiskey, gin, tequila, rum, spearmint, peppermint, lavender, aloe vera, cardamom, celery, cascarilla, nutmeg, sandalwood, bergamot, geranium, khat, naswar, betel, shisha, pine, honey essence, rose oil, vanilla, lemon oil, orange oil, orange blossom, cherry blossom, cassia, caraway, cognac, jasmine, ylang-ylang, sage, fennel, wasabi, piment, ginger, coriander, coffee, hemp, a mint oil from any species of the genus Mentha, eucalyptus, star anise, cocoa, lemongrass, rooibos, flax, ginkgo biloba, hazel, hibiscus, laurel, mate, orange skin, rose, tea such as green tea or black tea, thyme, juniper, elderflower, basil, bay leaves, cumin, oregano, paprika, rosemary, saffron, lemon peel, mint, beefsteak plant, curcuma, cilantro, myrtle, cassis, valerian, pimento, mace, damien, marjoram, olive, lemon balm, lemon basil, chive, carvi, verbena, tarragon, limonene, thymol, camphene), flavour enhancers, bitterness receptor site blockers, sensorial receptor site activators or stimulators, sugars and/or sugar substitutes (e.g., sucralose, acesulfame potassium, aspartame, saccharine, cyclamates, lactose, sucrose, glucose, fructose, sorbitol, or mannitol), and other additives such as charcoal, chlorophyll, minerals, botanicals, or breath freshening agents. They may be imitation, synthetic or natural ingredients or blends thereof. They may be in any suitable form, for example, liquid such as an oil, solid such as a powder, or gas.
In some embodiments, the flavour comprises menthol, spearmint and/or peppermint. In some embodiments, the flavour comprises, consists essentially of or consists of menthol.
In some embodiments, the flavour comprises flavour components of cucumber, blueberry, citrus fruits and/or redberry. In some embodiments, the flavour comprises eugenol.
In some embodiments, the flavour comprises flavour components extracted from tobacco.
In some embodiments, the flavour comprises flavour components extracted from cannabis.
In some embodiments, the flavour may comprise a sensate, which is intended to achieve a somatosensorial sensation which are usually chemically induced and perceived by the stimulation of the fifth cranial nerve (trigeminal nerve), in addition to or in place of aroma or taste nerves, and these may include agents providing heating, cooling, tingling, numbing effect. A suitable heat effect agent may be, but is not limited to, vanillyl ethyl ether and a suitable cooling agent may be, but not limited to eucolyptol or WS-3 (/V-ethyl-2-isopropyl-5-methylcyclohexanecarboxamide).
The aerosol-generating material may comprise about 1wt%, 3wt% or 5wt% to about 7wt%, 10wt%, 12wt%, 15wt%, 20wt% or 25wt% of emulsifier (all calculated on a dry weight basis). In exemplary embodiments, the aerosol-generating material comprises about 3wt%, 4wt% or 5wt% to about 7wt%, 8wt% or 10wt% of emulsifier. For example, the aerosol-generating material may comprise 4-8wt% or 5-7wt% of emulsifier.
In some cases, the emulsifier comprises one or more compounds selected from agar, xanthan gum, gum Arabic (acacia gum), guar gum, locust bean gum, pectin, carrageenan and lecithin. In some cases, the emulsifier comprises, consists essentially of or consists of guar gum.
In some embodiments, the aerosol-generating material comprises less than 35wt% of a filler, such as from about 1wt%, 5wt% or 10wt% to about 20wt%, 25wt%,
30wt% or 35wt% of filler (all calculated on a dry weight basis). In exemplary embodiments, the aerosol-generating material comprises about 7wt%, 10wt% or 11wt% to about 15wt%, 20wt% or 25wt% of filler. For example, the aerosolgenerating material may comprise 7-25wt%, 10-20wt%, 15-20wt%, 10-15wt% or 11-15wt% of filler.
In some embodiments, the aerosol-generating material comprises less than 60wt% of filler, such as from about 30wt%, 40wt% or 45wt% to about 50wt%, 55wt%, or 60wt% of filler (all calculated on a dry weight basis). In exemplary embodiments,
the aerosol-generating material comprises about 40-60wt%, 40-55wt% or 45-55wt% of filler.
In other embodiments, the aerosol-generating material may comprise less than 20 wt%, suitably less than 10 wt% or less than 5 wt% of filler. In some cases, the aerosol-generating material comprises less than 1 wt% of filler, and in some cases the aerosol-generating material comprises no filler.
The filler, if present, may comprise one or more inorganic filler materials, such as calcium carbonate, perlite, vermiculite, diatomaceous earth, colloidal silica, magnesium oxide, magnesium sulphate, magnesium carbonate, and suitable inorganic sorbents, such as molecular sieves. The filler, if present, may comprise one or more organic filler materials such as wood pulp, cellulose and cellulose derivatives. In particular cases, aerosol-generating material comprises no calcium carbonate such as chalk.
In particular embodiments which include filler, the filler is fibrous. For example, the filler may be a fibrous organic filler material such as wood pulp, hemp fibre, cellulose or cellulose derivatives, such as microcrystalline cellulose (MCC) and/or nanocrystalline cellulose. In some embodiments the filler comprises (or is) wood pulp and/or MCC. Without wishing to be bound by theory, it is believed that including fibrous filler in an aerosol-generating material may increase the tensile strength of the material. This may be particularly advantageous in examples wherein the aerosol-generating material is provided as a sheet, such as when an aerosolgenerating material sheet circumscribes a rod of aerosol-generating composition.
In some cases, the filler comprises maltodextrin or microcrystalline cellulose
(MCC).
As would be well understood by the skilled person, microcrystalline cellulose may be formed by depolymerising cellulose by a chemical process (e.g. using an acid or enzyme). One example method for forming microcrystalline cellulose involves acid hydrolysis of cellulose, using an acid such as HCI. The cellulose produced after this
treatment is crystalline (i.e. no amorphous regions remain). Suitable methods and conditions for forming microcrystalline cellulose are well-known in the art.
In some cases, the filler has a density of less than about 2 g/cm3, such as less than about 0.5 g/cm3 or less than about 0.3 g/cm3.
The aerosol-generating material may have any suitable water content, such as from 1wt % to 15wt%. Suitably, the water content of the aerosol-generating material may be from about 5wt%, 7wt% or 9wt% to about 15wt%, 13wt% or 11wt% (wet weight basis) (WWB). The water content of the aerosol-generating material may, for example, be determined by Karl-Fischer-titration or Gas Chromatography with Thermal Conductivity Detector (GC-TCD).
The aerosol-generating material may comprise a colourant. The addition of a colourant may alter the visual appearance of the aerosol-generating material. The presence of colourant in the aerosol-generating material may enhance the visual appearance of the aerosol-generating material and the aerosol-generating composition. By adding a colourant to the aerosol-generating material, the aerosolgenerating material may be colour-matched to other components of the aerosol- generating composition or to other components of an article comprising the aerosolgenerating material.
A variety of colourants may be used depending on the desired colour of the aerosol-generating material. The colour of aerosol-generating material may be, for example, white, green, red, purple, blue, brown or black. Other colours are also envisaged. Natural or synthetic colourants, such as natural or synthetic dyes, food- grade colourants and pharmaceutical-grade colourants may be used. In certain embodiments, the colourant is caramel, which may confer the aerosol-generating material with a brown appearance (e.g. similar to tobacco). In certain embodiments, the aerosol-generating material comprises up to 5 wt% of a colourant such as caramel, for example from about 1 to about 4 wt% (calculated on a dry weight basis). In such embodiments, the colour of the aerosol-generating material may be similar to the colour of other components (such as tobacco material) in an aerosolgenerating composition comprising the aerosol-generating material. In some
embodiments, the addition of a colourant to the aerosol-generating material renders it visually indistinguishable from other components in the aerosol-generating composition. The colourant may be incorporated during the formation of the aerosolgenerating material (e.g. when forming a slurry comprising the materials that form the aerosol-generating material) or it may be applied to the aerosol-generating material after its formation (e.g. by spraying it onto the aerosol-generating material). In some embodiments, the aerosol-generating composition additionally comprises an active substance. For example, in some cases, the aerosol-generating composition additionally comprises a tobacco material and/or nicotine. In some cases, the aerosol-generating composition may comprise 5-60wt% (calculated on a dry weight basis) of a tobacco material and/or nicotine. In some cases, the aerosol- generating composition may comprise from about 1wt%, 5wt%, 10wt%, 15wt%, 20wt% or 25wt% to about 70wt%, 60wt%, 50wt%, 45wt%, 40wt%, 35wt%, or 30wt% (calculated on a dry weight basis) of an active substance. In some cases, the aerosolgenerating composition may comprise from about 1wt%, 5wt%, 10wt%, 15wt%, 20wt% or 25wt% to about 70wt%, 60wt%, 50wt%, 45wt%, 40wt%, 35wt%, or 30wt% (calculated on a dry weight basis) of a tobacco material. For example, the aerosolgenerating composition may comprise 10-50wt%, 15-40wt% or 20-35wt% of a tobacco material. In some cases, the aerosol-generating composition may comprise from about 1wt%, 2wt%, 3wt% or 4wt% to about 20wt%, 18wt%, 15wt% or 12wt% (calculated on a dry weight basis) of nicotine. For example, the aerosol-generating composition may comprise 1-20wt%, 2-18wt% or 3-12wt% of nicotine.
In some cases, the aerosol-generating composition comprises an active substance such as tobacco extract. In some cases, the aerosol-generating composition may comprise 5-60wt% (calculated on a dry weight basis) of tobacco extract. In some cases, the aerosol-generating composition may comprise from about 5wt%, 10wt%, 15wt%, 20wt% or 25wt% to about 60wt%, 50wt%, 45wt%, 40wt%, 35wt%, or 30wt% (calculated on a dry weight basis) tobacco extract. For example, the aerosol-generating composition may comprise 10-50wt%, 15-40wt% or 20- 35wt% of tobacco extract. The tobacco extract may contain nicotine at a
concentration such that the aerosol-generating composition comprises 1wt% 1.5wt%, 2wt% or2.5wt% to about 10wt%, 8wt%, 6wt%, 5wt%, 4.5wt% or4wt% (calculated on a dry weight basis) of nicotine. In some embodiments, the aerosol-generating composition may comprise 1-10 wt%, 2.5-8 wt% or 2-6wt% nicotine. In some cases, there may be no nicotine in the aerosol-generating composition other than that which results from the tobacco extract.
In some embodiments, the aerosol-generating composition comprises no tobacco material but does comprise nicotine. In some such cases, the aerosol- generating composition may comprise from about 1wt%, 2wt%, 3wt% or 4wt% to about 20wt%, 18wt%, 15wt% or 12wt% (calculated on a dry weight basis) of nicotine. For example, the aerosol-generating composition may comprise 1-20wt%, 2-18wt% or 3-12wt% of nicotine. The aerosol-generating composition may comprise an acid. The acid may be an organic acid. In some of these embodiments, the acid may be at least one of a monoprotic acid, a diprotic acid and a triprotic acid. In some such embodiments, the acid may contain at least one carboxyl functional group. In some such embodiments, the acid may be at least one of an alpha-hydroxy acid, carboxylic acid, dicarboxylic acid, tricarboxylic acid and keto acid. In some such embodiments, the acid may be an alpha-keto acid.
In some such embodiments, the acid may be at least one of succinic acid, lactic acid, benzoic acid, citric acid, tartaric acid, fumaric acid, levulinic acid, acetic acid, malic acid, formic acid, sorbic acid, benzoic acid, propanoic and pyruvic acid.
Suitably the acid is lactic acid. In other embodiments, the acid is benzoic acid. In other embodiments the acid may be an inorganic acid. In some of these embodiments the acid may be a mineral acid. In some such embodiments, the acid may be at least one of sulphuric acid, hydrochloric acid, boric acid and phosphoric acid. In some embodiments, the acid is levulinic acid.
Inclusion of an acid is particularly preferred in embodiments in which the aerosol-generating composition comprises nicotine. In such embodiments, the
presence of an acid may stabilise dissolved species in the slurry from which the aerosol-generating composition is formed. The presence of the acid may reduce or substantially prevent evaporation of nicotine during drying of the slurry, thereby reducing loss of nicotine during manufacturing. The presence of the acid may also improve the flavour of the aerosol when nicotine is present. For example, the perceived harshness of the nicotine may be reduced by the presence of the acid.
In some embodiments, the aerosol-generating material is substantially free from tobacco. By “substantially free from” it is meant that the material comprises less than 1wt%, such as less than 0.5wt% tobacco. In some embodiments, the aerosolgenerating material is free from tobacco. In some embodiments, the aerosolgenerating material does not comprise tobacco fibres. In particular embodiments, the aerosol-generating material does not comprise fibrous material. In some embodiments, the aerosol-generating composition does not comprise tobacco fibres. In particular embodiments, the aerosol-generating composition does not comprise fibrous material.
In some embodiments, the aerosol-generating composition comprises a first and a second aerosol-generating material, where the composition of the second aerosol-generating material is different from the composition of the first aerosolgenerating material.
The first aerosol-generating material is as defined herein, and comprises - an aerosol-generating agent in an amount of from about 1 to about 80 wt% of the aerosol-generating material;
- one or more binders, wherein the total amount of binder is from about 5 to about 50 wt% of the aerosol-generating material, and wherein the one or more binders include a cellulosic binder; - flavour in an amount of from about 0.1 to about 60 wt% of the aerosolgenerating material;
- an emulsifier in an amount of from about 1 to about 25 wt% of the aerosolgenerating material; and optionally a filler.
The second aerosol-generating material comprises:
- an aerosol-generating agent in an amount of from about 1 to about 80 wt% of the aerosol-generating material; - one or more binders, wherein the total amount of binder is from about 5 to about 50 wt% of the aerosol-generating material;
- flavour in an amount of from about 0.1 to about 60 wt% of the aerosolgenerating material;
- an emulsifier in an amount of from about 1 to about 25 wt% of the aerosol- generating material; and
- optionally a filler.
In one embodiment the first aerosol-generating material is as defined herein, and comprises - an aerosol-generating agent in an amount of from about 1 to about 80 wt% of the aerosol-generating material;
- one or more binders, wherein the total amount of binder is from about 10 to about 50 wt% of the aerosol-generating material, and wherein the one or more binders include a cellulosic binder; - flavour in an amount of from about 0.1 to about 60 wt% of the aerosolgenerating material;
- an emulsifier in an amount of from about 1 to about 15 wt% of the aerosolgenerating material; and optionally a filler; and the second aerosol-generating material comprises:
- an aerosol-generating agent in an amount of from about 1 to about 80 wt% of the aerosol-generating material;
- one or more binders, wherein the total amount of binder is from about 10 to about 50 wt% of the aerosol-generating material; - flavour in an amount of from about 0.1 to about 60 wt% of the aerosolgenerating material;
- an emulsifier in an amount of from about 1 to about 15 wt% of the aerosolgenerating material; and
- optionally a filler.
All of the embodiments disclosed herein in relation to the aerosol-generating material apply equally to both the first and the second aerosol-generating materials, apart from the fact that the second aerosol-generating material does not need to include a cellulosic binder. In one aspect, the one or more binders in the second aerosol generating composition are different to the one or more binders in the first aerosol generating composition.
In particular embodiments, the one or more binders in the second aerosol- generating material are different to the one or more binders in the first aerosolgenerating material. In particular embodiments, the one or more binders in the second aerosol-generating material include a non-cellulosic binder. In some cases, the non-cellulosic binder is alginate. An aerosol-generating composition comprising two different aerosolgenerating materials may allow for the release of flavour at two different temperatures, or over a temperature range. This may especially be the case when the aerosol-generating materials comprise different binders. For example, the flavour (e.g. menthol) may be released from the first aerosol-generating material at a lower temperature than from the second aerosol-generating material or vice versa, allowing for the release of flavour over a wider temperature range and potentially a longer time. Without wishing to be bound by theory, it is believed that the flavour (e.g. menthol) will be released at a lower temperature when a non-cellulosic binder is used. In some embodiments, the aerosol-generating article does not comprise tobacco fibres. In particular embodiments, the aerosol-generating article does not comprise fibrous material.
The aerosolisable or aerosol-generating material may be present on or in a support to form a substrate. The support functions as a support on which the aerosolgenerating material layer forms, easing manufacture. The support may provide rigidity to the aerosol-generating material layer, easing handling.
The support may be any suitable material which can be used to support an aerosol-generating material. In some cases, the support may be formed from materials selected from metal foil, paper, carbon paper, greaseproof paper, ceramic, carbon allotropes such as graphite and graphene, plastic, cardboard, wood or combinations thereof. In some cases, the support may comprise or consist of a tobacco material, such as a sheet of reconstituted tobacco. In some cases, the support may be formed from materials selected from metal foil, paper, cardboard, wood or combinations thereof. In some cases, the support comprises paper. In some cases, the support itself may be a laminate structure comprising layers of materials selected from the preceding lists. In some cases, the support may also function as a flavour support. For example, the support may be impregnated with a flavourant or with tobacco extract.
Suitably, the thickness of the support layer may be in the range of about 10pm, 15pm, 17pm, 20pm, 23pm, 25pm, 50pm, 75pm or 0.1mm to about 2.5mm,
2.0mm, 1.5mm, 1.0mm or 0.5mm. The support may comprise more than one layer, and the thickness described herein refers to the aggregate thickness of those layers.
In some cases, the support may be magnetic. This functionality may be used to fasten the support to the assembly in use, or may be used to generate particular aerosol-generating material shapes. In some cases, the aerosol-generating substrate may comprise one or more magnets which can be used to fasten the substrate to an induction heater in use. In some cases, the support may be substantially or wholly impermeable to gas and/or aerosol. This prevents aerosol or gas passage through the support layer, thereby controlling the flow and ensuring it is delivered to the user. This can also be used to prevent condensation or other deposition of the gas/aerosol in use on, for example, the surface of a heater provided in an aerosol generating assembly. Thus, consumption efficiency and hygiene can be improved in some cases.
In some cases, the surface of the support that abuts the aerosol-generating material may be porous. For example, in one case, the support comprises paper. A porous support such as paper is particularly suitable for the present invention; the
porous (e.g. paper) layer abuts the aerosol-generating layer and forms a strong bond. The aerosol-generating material is formed by drying a gel and, without being limited by theory, it is thought that the slurry from which the gel is formed partially impregnates the porous support (e.g. paper) so that when the gel sets and forms cross-links, the support is partially bound into the gel. This provides a strong binding between the gel and the support (and between the dried gel and the support).
Additionally, surface roughness may contribute to the strength of bond between the aerosol-generating material and the support. The paper roughness (for the surface abutting the support) may suitably be in the range of 50-1000 Bekk seconds, suitably 50-150 Bekk seconds, suitably 100 Bekk seconds (measured over an air pressure interval of 50.66-48.00 kPa). (A Bekk smoothness tester is an instrument used to determine the smoothness of a paper surface, in which air at a specified pressure is leaked between a smooth glass surface and a paper sample, and the time (in seconds) for a fixed volume of air to seep between these surfaces is the "Bekk smoothness”.)
Conversely, the surface of the support facing away from the aerosolgenerating material may be arranged in contact with the heater, and a smoother surface may provide more efficient heat transfer. Thus, in some cases, the support is disposed so as to have a rougher side abutting the aerosol-generating material and a smoother side facing away from the aerosol-generating material.
In one particular case, the support may be a paper-backed foil; the paper layer abuts the aerosol-generating material layer and the properties discussed in the previous paragraphs are afforded by this abutment. The foil backing is substantially impermeable, providing control of the aerosol flow path. A metal foil backing may also serve to conduct heat to the aerosol-generating material. In another case, the foil layer of the paper-backed foil abuts the aerosolgenerating material. The foil is substantially impermeable, thereby preventing water provided in the aerosol-generating material to be absorbed into the paper which could weaken its structural integrity.
In some cases, the support is formed from or comprises metal foil, such as aluminium foil. A metallic support may allow for better conduction of thermal energy to the aerosol-generating material. Additionally, or alternatively, a metal foil may function as a susceptor in an induction heating system. In particular embodiments, the support comprises a metal foil layer and a support layer, such as cardboard. In these embodiments, the metal foil layer may have a thickness of less than 20pm, such as from about 1 pm to about 10pm, suitably about 5pm.
In some cases, the support may have a thickness of between about 0.017mm and about 2.0mm, suitably from about 0.02mm, 0.05mm or 0.1 mm to about 1 ,5mm, 1.0mm, or 0.5mm.
The aerosol-generating material may be made from a gel, and this gel may additionally comprise a solvent, included at 0.1-50wt%. However, the inclusion of a solvent in which the flavour is soluble may reduce the gel stability and the flavour may crystallise out of the gel. As such, in some cases, the gel does not include a solvent in which the flavour is soluble.
An aspect of the present invention relates to an article (also referred to herein as a consumable). A consumable is an article, part or all of which is intended to be consumed during use by a user. A consumable may comprise or consist of aerosolgenerating composition. A consumable may comprise one or more other elements, such as a filter or an aerosol modifying substance. A consumable may comprise a heating element that emits heat to cause the aerosol-generating composition to generate aerosol in use. The heating element may, for example, comprise combustible material, or may comprise a susceptor that is heatable by penetration with a varying magnetic field.
Articles of the present invention may be provided in any suitable shape. In some examples, the article is provided as a rod (e.g. substantially cylindrical). An article provided as a rod may include the aerosol-generating composition as a shredded sheet, optionally blended with cut tobacco. Alternatively, or additionally, the article provided as a rod may include the aerosol-generating composition as a sheet, such as a sheet circumscribing a rod of aerosol-generating material (e.g. tobacco, or
a combination of tobacco and an aerosol-generating material such as that described herein). In some embodiments, the article comprises a layer portion of aerosolgenerating composition disposed on a carrier. In examples, the article may have at least one substantially planar (flat) surface.
The aerosol-generating material may comprise or be in the form of an aerosol-generating film. The aerosol-generating film may be substantially free from botanical material. In particular, in some embodiments, the aerosol-generating film is substantially tobacco free.
The aerosol-generating film may have a thickness of about 0.015 mm to about 1 mm. For example, the thickness may be in the range of about 0.05 mm, 0.1 mm or 0.15 mm to about 0.5 mm or 0.3 mm. The aerosol-generating film may be continuous. For example, the film may comprise or be a continuous sheet of material. The sheet may be in the form of a wrapper, it may be gathered to form a gathered sheet or it may be shredded to form a shredded sheet. The shredded sheet may comprise one or more strands or strips of aerosol-generating material.
In one case, the aerosol-generating film is shredded and blended with another shredded aerosol-generating film. In particular embodiments, the aerosolgenerating films comprise different binders. In particular embodiments, the first aerosol-generating film comprises a cellulosic binder and the second aerosol- generating film comprises a non-cellulosic binder. For example, an aerosolgenerating film comprising alginate is blended with an aerosol-generating film comprising CMC. The inclusion of aerosol-generating films comprising different films may increase the temperature range over which flavour is released. In one case, there is provided a consumable for use in a non-combustible aerosol-provision system comprising a planar support with complete coverage of the aerosol-generating material (e.g. a continuous aerosol-generating film). Figure 14 provides a schematic illustration of such a consumable, which includes a support layer 4 and an aerosol-generating material layer 2.
The aerosol-generating film may be discontinuous, For example, the aerosol-generating film may comprise one or more discrete portions or regions of aerosol-generating material, such as dots, stripes or lines, which may be supported on a support. In such embodiments, the support may be planar or non-planar.
In some cases, the discrete portions of aerosol-generating material are substantially round, cylindrical or hemispherical. In some cases, there is a gridshaped distribution of the substantially round, cylindrical or hemispherical aerosol- generating material.
In some cases, there is provided a consumable for use in a non-combustible aerosol-provision system comprising a planar support with a discontinuous aerosolgenerating film (which comprises a plurality of discrete portions of aerosol- generating material) deposited on it.
Figure 15 provides an example of a consumable (401) wherein a discontinuous aerosol-generating film (which comprises a discrete portion of aerosol-generating material (403)) are provided on the consumable.
A susceptor is material that is heatable by penetration with a varying magnetic field, such as an alternating magnetic field. The heating material may be an electrically-conductive material, so that penetration thereof with a varying magnetic field causes induction heating of the heating material. The heating material may be magnetic material, so that penetration thereof with a varying magnetic field causes magnetic hysteresis heating of the heating material. The heating material may be both electrically-conductive and magnetic, so that the heating material is heatable by both heating mechanisms. Induction heating is a process in which an electrically-conductive object is heated by penetrating the object with a varying magnetic field. The process is described by Faraday's law of induction and Ohm's law. An induction heater may comprise an electromagnet and a device for passing a varying electrical current, such as an alternating current, through the electromagnet. When the electromagnet and
the object to be heated are suitably relatively positioned so that the resultant varying magnetic field produced by the electromagnet penetrates the object, one or more eddy currents are generated inside the object. The object has a resistance to the flow of electrical currents. Therefore, when such eddy currents are generated in the object, their flow against the electrical resistance of the object causes the object to be heated. This process is called Joule, ohmic, or resistive heating.
In some embodiments, the susceptor is in the form of a closed circuit. It has been found that, when the susceptor is in the form of a closed circuit, magnetic coupling between the susceptor and the electromagnet in use is enhanced, which results in greater or improved Joule heating.
Magnetic hysteresis heating is a process in which an object made of a magnetic material is heated by penetrating the object with a varying magnetic field. A magnetic material can be considered to comprise many atomic-scale magnets, or magnetic dipoles. When a magnetic field penetrates such material, the magnetic dipoles align with the magnetic field. Therefore, when a varying magnetic field, such as an alternating magnetic field, for example as produced by an electromagnet, penetrates the magnetic material, the orientation of the magnetic dipoles changes with the varying applied magnetic field. Such magnetic dipole reorientation causes heat to be generated in the magnetic material.
When an object is both electrically-conductive and magnetic, penetrating the object with a varying magnetic field can cause both Joule heating and magnetic hysteresis heating in the object. Moreover, the use of magnetic material can strengthen the magnetic field, which can intensify the Joule heating.
In each of the above processes, as heat is generated inside the object itself, rather than by an external heat source by heat conduction, a rapid temperature rise in the object and more uniform heat distribution can be achieved, particularly through selection of suitable object material and geometry, and suitable varying magnetic field magnitude and orientation relative to the object. Moreover, as induction heating and magnetic hysteresis heating do not require a physical connection to be provided
between the source of the varying magnetic field and the object, design freedom and control over the heating profile may be greater, and cost may be lower.
The thickness values stipulated herein are mean values for the thickness in question. In some cases, the thickness may vary by no more than 25%, 20%, 15%, 10%, 5% or 1%.
The “thickness” of the aerosol-generating material describes the shortest distance between a first surface and a second surface. In embodiments where the aerosol-generating material is in the form of a sheet, the thickness of the aerosolgenerating material is the shortest distance between a first planar surface of the sheet and a second planar surface of the sheet which opposes the first planar surface of the sheet. In some cases, the aerosol-generating composition may have a thickness of about 0.015mm to about 1.0mm. Suitably, the thickness may be in the range of about 0.05mm, 0.1mm or 0.15mm to about 0.5mm or 0.3mm. The aerosol-generating material may comprise more than one layer, and the thickness described herein refers to the aggregate thickness of those layers.
In some cases, the aerosol-generating material may have a thickness of about 0.015mm to about 1.0mm. Suitably, the thickness may be in the range of about
0.05mm, 0.1mm or 0.15mm to about 0.5mm or 0.3mm. The aerosol-generating material may comprise more than one layer, and the thickness described herein refers to the aggregate thickness of those layers. The aerosol-generating composition comprising the aerosol-generating material may have any suitable area density, such as from 30 g/m2 to 120 g/m2. In some embodiments, aerosol-generating composition may have an area density of from about 30 to 70 g/m2, or about 40 to 60 g/m2. In some embodiments, the aerosolgenerating composition may have an area density of from about 80 to 120 g/m2, or from about 70 to 110 g/m2, or particularly from about 90 to 110 g/m2. Such area densities may be particularly suitable where the aerosol-generating composition is included in an aerosol-generating article/assembly in sheet form, or as a shredded sheet (described further hereinbelow).
An aspect of the invention provides non-combustible aerosol provision system comprising an article according as described herein and non-combustible aerosol provision device comprising a heater which is configured to heat not burn the aerosol-generating article. A non-combustible aerosol provision system may also be referred to as an aerosol generating assembly. A non-combustible aerosol provision device may be referred to as an aerosol generating apparatus.
In some cases, in use, the heater may heat, without burning, the aerosolgenerating material to a temperature equal to or less than 350 °C, such as between 120°C and 350 °C. In some cases, the heater may heat, without burning, the aerosolgenerating composition to between 140 °C and 250 °C in use, or between 220 °C and 280 °C. In some cases in use, substantially all of the aerosol-generating material is less than about 4mm, 3mm, 2mm or 1mm from the heater. In some cases, the material is disposed between about 0.010mm and 2.0mm from the heater, suitably between about 0.02mm and 1.0mm, suitably 0.1mm to 0.5mm. These minimum distances may, in some cases, reflect the thickness of a support that supports the aerosol-generating material. In some cases, a surface of the aerosol-generating material may directly abut the heater. The heater is configured to heat not burn the aerosol-generating article, and thus the aerosol-generating composition. The heater may be, in some cases, a thin film, electrically resistive heater. In other cases, the heater may comprise an induction heater or the like. The heater may be a combustible heat source or a chemical heat source which undergoes an exothermic reaction to product heat in use. The aerosol generating assembly may comprise a plurality of heaters. The heater(s) may be powered by a battery.
The aerosol-generating article may additionally comprise a cooling element and/or a filter. The cooling element, if present, may act or function to cool gaseous or aerosol components. In some cases, it may act to cool gaseous components such that they condense to form an aerosol. It may also act to space the very hot parts of the non-combustible aerosol provision device from the user. The filter, if present, may comprise any suitable filter known in the art such as a cellulose acetate plug.
In some cases, the aerosol generating assembly may be a heat-not-burn device. That is, it may contain a solid tobacco-containing material (and no liquid aerosol-generating material). In some cases, the aerosol-generating material may comprise the tobacco material. A heat-not-burn device is disclosed in WO 2015/062983 A2, which is incorporated by reference in its entirety.
In some cases, the aerosol generating assembly may be an electronic tobacco hybrid device. That is, it may contain a solid aerosol-generating composition and a liquid aerosol-generating material. In some cases, the aerosol-generating material may comprise nicotine. In some cases, the aerosol-generating material may comprise a tobacco material. In some cases, the aerosol-generating material may comprise a tobacco material and a separate nicotine source. The separate aerosolgenerating compositions may be heated by separate heaters, the same heater or, in one case, a downstream aerosol-generating material may be heated by a hot aerosol which is generated from the upstream aerosol-generating composition. An electronic tobacco hybrid device is disclosed in WO 2016/135331 A1, which is incorporated by reference in its entirety.
The aerosol-generating article (which may be referred to herein as an article, a cartridge or a consumable) may be adapted for use in a THP, an electronic tobacco hybrid device or another aerosol generating device. In some cases, the article may additionally comprise a filter and/or cooling element (which have been described above). In some cases, the aerosol-generating article may be circumscribed by a wrapping material such as paper.
The aerosol-generating article may additionally comprise ventilation apertures. These may be provided in the sidewall of the article. In some cases, the ventilation apertures may be provided in the filter and/or cooling element. These apertures may allow cool air to be drawn into the article during use, which can mix with the heated volatilised components thereby cooling the aerosol.
The ventilation enhances the generation of visible heated volatilised components from the article when it is heated in use. The heated volatilised components are made visible by the process of cooling the heated volatilised
components such that supersaturation of the heated volatilised components occurs. The heated volatilised components then undergo droplet formation, otherwise known as nucleation, and eventually the size of the aerosol particles of the heated volatilised components increases by further condensation of the heated volatilised components and by coagulation of newly formed droplets from the heated volatilised components.
In some cases, the ratio of the cool air to the sum of the heated volatilised components and the cool air, known as the ventilation ratio, is at least 15%. A ventilation ratio of 15% enables the heated volatilised components to be made visible by the method described above. The visibility of the heated volatilised components enables the user to identify that the volatilised components have been generated and adds to the sensory experience of the smoking experience.
In another example, the ventilation ratio is between 50% and 85% to provide additional cooling to the heated volatilised components. In some cases, the ventilation ratio may be at least 60% or 65%.
In some cases, the aerosol-generating composition may be included in the article/assembly in sheet form. In some cases, the aerosol-generating composition may be included as a planar sheet. In some cases, the aerosol-generating composition may be included as a planar sheet, as a bunched or gathered sheet, as a crimped sheet, or as a rolled sheet (i.e. in the form of a tube). In some such cases, the aerosol-generating material of these embodiments may be included in an aerosolgenerating article/assembly as a sheet, such as a sheet circumscribing a rod of aerosol-generating material (e.g. tobacco). In some other cases, the aerosolgenerating composition may be formed as a sheet and then shredded and incorporated into the article. In some cases, the shredded sheet may be mixed with cut rag tobacco and incorporated into the article. In some cases, the first and second aerosol-generating materials described herein may both be formed as a sheet and then shredded and mixed together to form an aerosol-generating composition. Said composition may then be incorporated into the article. In some cases, the shredded sheets may also be mixed with cut rag tobacco and incorporated into the article.
In some examples, the aerosol-generating material in sheet form may have a tensile strength of from around 200 N/m to around 900 N/m. In some examples, such as where the aerosol-generating material does not comprise a filler, the aerosol- generating material may have a tensile strength of from 200 N/m to 400 N/m, or 200 N/m to 300 N/m, or about 250 N/m. Such tensile strengths may be particularly suitable for embodiments wherein the aerosol-generating composition is formed as a sheet and then shredded and incorporated into an aerosol-generating article. In some examples, such as where the aerosol-generating material comprises a filler, the aerosol-generating material may have a tensile strength of from 600 N/m to 900 N/m, or from 700 N/m to 900 N/m, or around 800 N/m. Such tensile strengths may be particularly suitable for embodiments wherein the aerosol-generating composition is included in an aerosol-generating article/assembly as a rolled sheet, suitably in the form of a tube.
In some embodiments, the aerosol-generating material is formed as a film on a support. The aerosol-generating film may be a continuous film or a discontinuous film, such as an arrangement of discrete portions of film on a support. In some cases, the aerosol-generating film does not comprise a filler.
Referring to Figures 1 and 2, there are shown a partially cut-away section view and a perspective view of an example of an aerosol-generating article 101. The article 101 is adapted for use with a device having a power source and a heater. The article 101 of this embodiment is particularly suitable for use with the device 1 shown in Figures 5 to 7, described below. In use, the article 101 may be removably inserted into the device shown in Figure 5 at an insertion point 20 of the device 1.
The article 101 of one example is in the form of a substantially cylindrical rod that includes a body of aerosol-generating composition 103 and a filter assembly 105 in the form of a rod. The aerosol-generating composition comprises the aerosolgenerating material described herein. In some embodiments, it may be included in sheet form. In some embodiments it may be included in the form of a shredded sheet. In some embodiments, the aerosol-generating composition described herein may be incorporated in sheet form and in shredded form.
The filter assembly 105 includes three segments, a cooling segment 107, a filter segment 109 and a mouth end segment 111. The article 101 has a first end 113, also known as a mouth end or a proximal end and a second end 115, also known as a distal end. The body of aerosol-generating composition 103 is located towards the distal end 115 of the article 101. In one example, the cooling segment 107 is located adjacent the body of aerosol-generating composition 103 between the body of aerosol-generating composition 103 and the filter segment 109, such that the cooling segment 107 is in an abutting relationship with the aerosol-generating composition 103 and the filter segment 103. In other examples, there may be a separation between the body of aerosol-generating composition 103 and the cooling segment 107 and between the body of aerosol-generating composition 103 and the filter segment 109. The filter segment 109 is located in between the cooling segment 107 and the mouth end segment 111. The mouth end segment 111 is located towards the proximal end 113 of the article 101 , adjacent the filter segment 109. In one example, the filter segment 109 is in an abutting relationship with the mouth end segment 111. In one embodiment, the total length of the filter assembly 105 is between 37mm and 45mm, more preferably, the total length of the filter assembly 105 is 41mm.
In one example, the rod of aerosol-generating composition 103 is between 34mm and 50mm in length, suitably between 38mm and 46mm in length, suitably 42mm in length. In one example, the total length of the article 101 is between 71mm and
95mm, suitably between 79mm and 87mm, suitably 83mm.
An axial end of the body of aerosol-generating composition 103 is visible at the distal end 115 of the article 101. However, in other embodiments, the distal end 115 of the article 101 may comprise an end member (not shown) covering the axial end of the body of aerosol-generating composition 103.
The body of aerosol-generating composition 103 is joined to the filter assembly 105 by annular tipping paper (not shown), which is located substantially
around the circumference of the filter assembly 105 to surround the filter assembly 105 and extends partially along the length of the body of aerosol-generating composition 103. In one example, the tipping paper is made of 58GSM standard tipping base paper. In one example the tipping paper has a length of between 42mm and 50mm, suitably of 46mm.
In one example, the cooling segment 107 is an annular tube and is located around and defines an air gap within the cooling segment. The air gap provides a chamber for heated volatilised components generated from the body of aerosol- generating composition 103 to flow. The cooling segment 107 is hollow to provide a chamber for aerosol accumulation yet rigid enough to withstand axial compressive forces and bending moments that might arise during manufacture and whilst the article 101 is in use during insertion into the device 1. In one example, the thickness of the wall of the cooling segment 107 is approximately 0.29mm.
The cooling segment 107 provides a physical displacement between the aerosol-generating composition 103 and the filter segment 109. The physical displacement provided by the cooling segment 107 will provide a thermal gradient across the length of the cooling segment 107. In one example the cooling segment 107 is configured to provide a temperature differential of at least 40 degrees Celsius between a heated volatilised component entering a first end of the cooling segment 107 and a heated volatilised component exiting a second end of the cooling segment 107. In one example the cooling segment 107 is configured to provide a temperature differential of at least 60 degrees Celsius between a heated volatilised component entering a first end of the cooling segment 107 and a heated volatilised component exiting a second end of the cooling segment 107. This temperature differential across the length of the cooling element 107 protects the temperature sensitive filter segment 109 from the high temperatures of the aerosol-generating composition 103 when it is heated by the device 1. If the physical displacement was not provided between the filter segment 109 and the body of aerosol-generating composition 103 and the heating elements of the device 1, then the temperature sensitive filter segment may 109 become damaged in use, so it would not perform its required functions as effectively.
In one example the length of the cooling segment 107 is at least 15mm. In one example, the length of the cooling segment 107 is between 20mm and 30mm, more particularly 23mm to 27mm, more particularly 25mm to 27mm, suitably 25mm. The cooling segment 107 is made of paper, which means that it is comprised of a material that does not generate compounds of concern, for example, toxic compounds when in use adjacent to the heater of the device 1. In one example, the cooling segment 107 is manufactured from a spirally wound paper tube which provides a hollow internal chamber yet maintains mechanical rigidity. Spirally wound paper tubes are able to meet the tight dimensional accuracy requirements of highspeed manufacturing processes with respect to tube length, outer diameter, roundness and straightness.
In another example, the cooling segment 107 is a recess created from stiff plug wrap or tipping paper. The stiff plug wrap or tipping paper is manufactured to have a rigidity that is sufficient to withstand the axial compressive forces and bending moments that might arise during manufacture and whilst the article 101 is in use during insertion into the device 1. The filter segment 109 may be formed of any filter material sufficient to remove one or more volatilised compounds from heated volatilised components from the aerosol-generating material. In one example the filter segment 109 is made of a mono-acetate material, such as cellulose acetate. The filter segment 109 provides cooling and irritation-reduction from the heated volatilised components without depleting the quantity of the heated volatilised components to an unsatisfactory level for a user.
In some embodiments, a capsule (not illustrated) may be provided in filter segment 109. It may be disposed substantially centrally in the filter segment 109, both across the filter segment 109 diameter and along the filter segment 109 length. In other cases, it may be offset in one or more dimension. The capsule may in some cases, where present, contain a volatile component such as a flavourant or aerosol generating agent.
The density of the cellulose acetate tow material of the filter segment 109 controls the pressure drop across the filter segment 109, which in turn controls the draw resistance of the article 101. Therefore the selection of the material of the filter segment 109 is important in controlling the resistance to draw of the article 101. In addition, the filter segment performs a filtration function in the article 101.
In one example, the filter segment 109 is made of a 8Y15 grade of filter tow material, which provides a filtration effect on the heated volatilised material, whilst also reducing the size of condensed aerosol droplets which result from the heated volatilised material.
The presence of the filter segment 109 provides an insulating effect by providing further cooling to the heated volatilised components that exit the cooling segment 107. This further cooling effect reduces the contact temperature of the user’s lips on the surface of the filter segment 109.
In one example, the filter segment 109 is between 6mm to 10mm in length, suitably 8mm. The mouth end segment 111 is an annular tube and is located around and defines an air gap within the mouth end segment 111. The air gap provides a chamber for heated volatilised components that flow from the filter segment 109. The mouth end segment 111 is hollow to provide a chamber for aerosol accumulation yet rigid enough to withstand axial compressive forces and bending moments that might arise during manufacture and whilst the article is in use during insertion into the device 1. In one example, the thickness of the wall of the mouth end segment 111 is approximately 0.29mm. In one example, the length of the mouth end segment 111 is between 6mm to 10mm, suitably 8mm. The mouth end segment 111 may be manufactured from a spirally wound paper tube which provides a hollow internal chamber yet maintains critical mechanical rigidity. Spirally wound paper tubes are able to meet the tight dimensional accuracy requirements of high-speed manufacturing processes with respect to tube length, outer diameter, roundness and straightness.
The mouth end segment 111 provides the function of preventing any liquid condensate that accumulates at the exit of the filter segment 109 from coming into direct contact with a user.
It should be appreciated that, in one example, the mouth end segment 111 and the cooling segment 107 may be formed of a single tube and the filter segment 109 is located within that tube separating the mouth end segment 111 and the cooling segment 107.
Referring to Figures 3 and 4, there are shown a partially cut-away section and perspective views of an example of an article 301. The reference signs shown in Figures 3 and 4 are equivalent to the reference signs shown in Figures 1 and 2, but with an increment of 200.
In the example of the article 301 shown in Figures 3 and 4, a ventilation region 317 is provided in the article 301 to enable air to flow into the interior of the article 301 from the exterior of the article 301. In one example the ventilation region 317 takes the form of one or more ventilation holes 317 formed through the outer layer of the article 301. The ventilation holes may be located in the cooling segment 307 to aid with the cooling of the article 301. In one example, the ventilation region 317 comprises one or more rows of holes, and preferably, each row of holes is arranged circumferentially around the article 301 in a cross-section that is substantially perpendicular to a longitudinal axis of the article 301.
In one example, there are between one to four rows of ventilation holes to provide ventilation for the article 301. Each row of ventilation holes may have between 12 to 36 ventilation holes 317. The ventilation holes 317 may, for example, be between 100 to 500pm in diameter. In one example, an axial separation between rows of ventilation holes 317 is between 0.25mm and 0.75mm, suitably 0.5mm.
In one example, the ventilation holes 317 are of uniform size. In another example, the ventilation holes 317 vary in size. The ventilation holes can be made using any suitable technique, for example, one or more of the following techniques:
laser technology, mechanical perforation of the cooling segment 307 or preperforation of the cooling segment 307 before it is formed into the article 301. The ventilation holes 317 are positioned so as to provide effective cooling to the article 301.
In one example, the rows of ventilation holes 317 are located at least 11mm from the proximal end 313 of the article, suitably between 17mm and 20mm from the proximal end 313 of the article 301. The location of the ventilation holes 317 is positioned such that user does not block the ventilation holes 317 when the article 301 is in use.
Providing the rows of ventilation holes between 17mm and 20mm from the proximal end 313 of the article 301 enables the ventilation holes 317 to be located outside of the device 1 , when the article 301 is fully inserted in the device 1, as can be seen in Figures 6 and 7. By locating the ventilation holes outside of the device, non-heated air is able to enter the article 301 through the ventilation holes from outside the device 1 to aid with the cooling of the article 301.
The length of the cooling segment 307 is such that the cooling segment 307 will be partially inserted into the device 1, when the article 301 is fully inserted into the device 1. The length of the cooling segment 307 provides a first function of providing a physical gap between the heater arrangement of the device 1 and the heat sensitive filter arrangement 309, and a second function of enabling the ventilation holes 317 to be located in the cooling segment, whilst also being located outside of the device 1 , when the article 301 is fully inserted into the device 1. As can be seen from Figures 6 and 7, the majority of the cooling element 307 is located within the device 1. However, there is a portion of the cooling element 307 that extends out of the device 1. It is in this portion of the cooling element 307 that extends out of the device 1 in which the ventilation holes 317 are located.
Referring now to Figures 5 to 7 in more detail, there is shown an example of a device 1 arranged to heat aerosol-generating composition to volatilise at least one component of said aerosol-generating composition, typically to form an aerosol which
can be inhaled. The device 1 is a heating device which releases compounds by heating, but not burning, the aerosol-generating composition.
A first end 3 is sometimes referred to herein as the mouth or proximal end 3 of the device 1 and a second end 5 is sometimes referred to herein as the distal end 5 of the device 1. The device 1 has an on/off button 7 to allow the device 1 as a whole to be switched on and off as desired by a user.
The device 1 comprises a housing 9 for locating and protecting various internal components of the device 1. In the example shown, the housing 9 comprises a uni-body sleeve 11 that encompasses the perimeter of the device 1 , capped with a top panel 17 which defines generally the ‘top’ of the device 1 and a bottom panel 19 which defines generally the ‘bottom’ of the device 1. In another example the housing comprises a front panel, a rear panel and a pair of opposite side panels in addition to the top panel 17 and the bottom panel 19.
The top panel 17 and/or the bottom panel 19 may be removably fixed to the uni-body sleeve 11 , to permit easy access to the interior of the device 1 , or may be “permanently” fixed to the uni-body sleeve 11 , for example to deter a user from accessing the interior of the device 1. In an example, the panels 17 and 19 are made of a plastics material, including for example glass-filled nylon formed by injection moulding, and the uni-body sleeve 11 is made of aluminium, though other materials and other manufacturing processes may be used. The top panel 17 of the device 1 has an opening 20 at the mouth end 3 of the device 1 through which, in use, the article 101 , 301 including the aerosol-generating composition may be inserted into the device 1 and removed from the device 1 by a user.
The housing 9 has located or fixed therein a heater arrangement 23, control circuitry 25 and a power source 27. In this example, the heater arrangement 23, the control circuitry 25 and the power source 27 are laterally adjacent (that is, adjacent when viewed from an end), with the control circuitry 25 being located generally
between the heater arrangement 23 and the power source 27, though other locations are possible.
The control circuitry 25 may include a controller, such as a microprocessor arrangement, configured and arranged to control the heating of the aerosolgenerating composition in the article 101 , 301 as discussed further below.
The power source 27 may be for example a battery, which may be a rechargeable battery or a non-rechargeable battery. Examples of suitable batteries include for example a lithium-ion battery, a nickel battery (such as a nickel-cadmium battery), an alkaline battery and/ or the like. The battery 27 is electrically coupled to the heater arrangement 23 to supply electrical power when required and under control of the control circuitry 25 to heat the aerosol-generating composition in the article (as discussed, to volatilise the aerosol-generating material without causing the aerosol-generating composition to burn).
An advantage of locating the power source 27 laterally adjacent to the heater arrangement 23 is that a physically large power source 25 may be used without causing the device 1 as a whole to be unduly lengthy. As will be understood, in general a physically large power source 25 has a higher capacity (that is, the total electrical energy that can be supplied, often measured in Amp-hours or the like) and thus the battery life for the device 1 can be longer.
In one example, the heater arrangement 23 is generally in the form of a hollow cylindrical tube, having a hollow interior heating chamber 29 into which the article 101, 301 comprising the aerosol-generating material is inserted for heating in use. Different arrangements for the heater arrangement 23 are possible. For example, the heater arrangement 23 may comprise a single heating element or may be formed of plural heating elements aligned along the longitudinal axis of the heater arrangement 23. The or each heating element may be annular or tubular, or at least part-annular or part-tubular around its circumference. In an example, the or each heating element may be a thin film heater. In another example, the or each heating element may be made of a ceramics material. Examples of suitable ceramics materials include alumina and aluminium nitride and silicon nitride ceramics, which may be laminated
and sintered. Other heating arrangements are possible, including for example inductive heating, infrared heater elements, which heat by emitting infrared radiation, or resistive heating elements formed by for example a resistive electrical winding. In one particular example, the heater arrangement 23 is supported by a stainless steel support tube and comprises a polyimide heating element. The heater arrangement 23 is dimensioned so that substantially the whole of the body of aerosolgenerating composition 103, 303 of the article 101 , 301 is inserted into the heater arrangement 23 when the article 101 , 301 is inserted into the device 1.
The or each heating element may be arranged so that selected zones of the aerosol-generating material can be independently heated, for example in turn (over time, as discussed above) or together (simultaneously) as desired. The heater arrangement 23 in this example is surrounded along at least part of its length by a thermal insulator 31. The insulator 31 helps to reduce heat passing from the heater arrangement 23 to the exterior of the device 1. This helps to keep down the power requirements for the heater arrangement 23 as it reduces heat losses generally. The insulator 31 also helps to keep the exterior of the device 1 cool during operation of the heater arrangement 23. In one example, the insulator 31 may be a double-walled sleeve which provides a low pressure region between the two walls of the sleeve. That is, the insulator 31 may be for example a “vacuum” tube, i.e. a tube that has been at least partially evacuated so as to minimise heat transfer by conduction and/or convection. Other arrangements for the insulator 31 are possible, including using heat insulating materials, including for example a suitable foam-type material, in addition to or instead of a double-walled sleeve.
The housing 9 may further comprises various internal support structures 37 for supporting all internal components, as well as the heating arrangement 23.
The device 1 further comprises a collar 33 which extends around and projects from the opening 20 into the interior of the housing 9 and a generally tubular chamber 35 which is located between the collar 33 and one end of the vacuum sleeve 31. The chamber 35 further comprises a cooling structure 35f, which in this example,
comprises a plurality of cooling fins 35f spaced apart along the outer surface of the chamber 35, and each arranged circumferentially around outer surface of the chamber 35. There is an air gap 36 between the hollow chamber 35 and the article 101, 301 when it is inserted in the device 1 over at least part of the length of the hollow chamber 35. The air gap 36 is around all of the circumference of the article 101 , 301 over at least part of the cooling segment 307.
The collar 33 comprises a plurality of ridges 60 arranged circumferentially around the periphery of the opening 20 and which project into the opening 20. The ridges 60 take up space within the opening 20 such that the open span of the opening 20 at the locations of the ridges 60 is less than the open span of the opening 20 at the locations without the ridges 60. The ridges 60 are configured to engage with an article 101, 301 inserted into the device to assist in securing it within the device 1. Open spaces (not shown in the Figures) defined by adjacent pairs of ridges 60 and the article 101 , 301 form ventilation paths around the exterior of the article 101 , 301. These ventilation paths allow hot vapours that have escaped from the article 101 , 301 to exit the device 1 and allow cooling air to flow into the device 1 around the article 101 , 301 in the air gap 36. In operation, the article 101, 301 is removably inserted into an insertion point
20 of the device 1 , as shown in Figures 5 to 7. Referring particularly to Figure 6, in one example, the body of aerosol-generating composition 103, 303, which is located towards the distal end 115, 315 of the article 101, 301 , is entirely received within the heater arrangement 23 of the device 1. The proximal end 113, 313 of the article 101, 301 extends from the device 1 and acts as a mouthpiece assembly for a user.
In operation, the heater arrangement 23 will heat the article 101, 301 to volatilise at least one component of the aerosol-generating composition from the body of aerosol-generating composition 103, 303.
The primary flow path for the heated volatilised components from the body of aerosol-generating composition 103, 303 is axially through the article 101 , 301, through the chamber inside the cooling segment 107, 307, through the filter segment 109, 309, through the mouth end segment 111 , 313 to the user. In one example, the
temperature of the heated volatilised components that are generated from the body of aerosol-generating composition is between 60°C and 250°C, which may be above the acceptable inhalation temperature for a user. As the heated volatilised component travels through the cooling segment 107, 307, it will cool and some volatilised components will condense on the inner surface of the cooling segment 107, 307.
In the examples of the article 301 shown in Figures 3 and 4, cool air will be able to enter the cooling segment 307 via the ventilation holes 317 formed in the cooling segment 307. This cool air will mix with the heated volatilised components to provide additional cooling to the heated volatilised components.
Another aspect of the invention provides a method of making an aerosolgenerating composition according to the first aspect. The method may comprise (a) forming a slurry comprising components of the aerosol-generating material or precursors thereof, (b) forming a layer of the slurry, (c) optionally setting the slurry, and (d) drying to form an aerosol-generating material.
Step (b) of forming a layer of the slurry may comprise spraying, casting or extruding the slurry, for example. In some cases, the slurry layer is formed by electrospraying the slurry. In some cases, the slurry layer is formed by casting the slurry.
In some cases, (b) and/or (c) and/or (d) may, at least partially, occur simultaneously (for example, during electrospraying). In some cases, (b), (c) and (d) may occur sequentially.
In some cases, the slurry is applied to a support. The layer may be formed on a support.
In examples, the slurry comprises binder, aerosol-generating agent, flavour and emulsifier. The slurry may comprise these components in any of the proportions given herein in relation to the composition of the aerosol-generating composition. For example, the slurry may comprise:
- an aerosol-generating agent in an amount of from about 1 to about 80 wt% of the aerosol-generating material;
- one or more binders, wherein the total amount of binder is from about 5 to about 50 wt% of the aerosol-generating material, and wherein the one or more binders include a cellulosic binder;
- flavour in an amount of from about 0.1 to about 60 wt% of the aerosolgenerating material;
- an emulsifier in an amount of from about 1 to about 25 wt% of the aerosolgenerating material; and - optionally a filler.
The setting of the gel (c) may comprise the addition of a setting agent or crosslinking agent to the slurry. For example, the slurry may comprise sodium, potassium or ammonium alginate as a gel-precursor, and a setting agent or crosslinking agent comprising a calcium source (such as calcium chloride), may be added to the slurry to form a calcium alginate gel.
The total amount of the setting agent or crosslinking agent, such as a calcium source, may be 0.5-5wt% (calculated on a dry weight basis). The addition of too little setting agent or crosslinking agent may result in an aerosol-generating material which does not stabilise the aerosol-generating material components and results in these components dropping out of the aerosol-generating material. The addition of too much setting agent or crosslinking agent results in an aerosol-generating material that is very tacky and consequently has poor handleability.
Alginate salts are derivatives of alginic acid and are typically high molecular weight polymers (10-600 kDa). Alginic acid is a copolymer of b-D-mannuronic (M) and a-L-guluronic acid (G) units (blocks) linked together with (1,4)-glycosidic bonds to form a polysaccharide. On addition of calcium cations, the alginate crosslinks to form a gel. Alginate salts with a high G monomer content more readily form a gel on addition of the calcium source. In some cases therefore, the gel-precursor may comprise an alginate salt in which at least about 40%, 45%, 50%, 55%, 60% or 70% of the monomer units in the alginate copolymer are a-L-guluronic acid (G) units.
Setting the gel in step (c) may not be required, for example when the only binder present is a cellulosic binder such as CMC. When a non-cellulosic binder agent is present, such as alginate, the slurry may further comprise a setting agent or crosslinking agent and/or a setting agent or crosslinking agent may be applied to the slurry. In this case, the method may further comprise the step (c) of setting the slurry.
The drying (d) may, in some cases, remove from about 50wt%, 60wt%, 70wt%, 80wt% or 90wt% to about 80wt%, 90wt% or 95wt% (WWB) of water in the slurry.
The drying (d) may, in some cases, may reduce the cast material thickness by at least 80%, suitably 85% or 87%. For instance, the slurry may be cast at a thickness of 2mm, and the resulting dried aerosol-generating material may have a thickness of 0.2mm.
During step (d) the slurry may be heated to remove at least about 60 wt%, 70 wt%, 80 wt%, 85 wt% or 90 wt% of the solvent.
The aerosol-generating film may be formed by combining the aerosol- forming agent, binders, flavour, emulsifier, a solvent and any optional further components to form a slurry and then heating the slurry to volatilise at least some of the solvent to form the aerosol-generating film. The slurry may be heated to remove at least about 60 wt%, 70 wt%, 80 wt%, 85 wt% or 90 wt% of the solvent. The slurry itself may also form part of the invention. In some cases, the slurry solvent may consist essentially of or consist of water. In some cases, the slurry may comprise from about 50wt%, 60wt%, 70wt%, 80wt% or 90wt% of solvent (WWB).
In cases where the solvent consists of water, the dry weight content of the slurry may match the dry weight content of the aerosol-generating material. Thus, the discussion herein relating to the solid composition is explicitly disclosed in combination with the slurry aspect of the invention.
According to an aspect of the present invention there is provided a method of generating an aerosol using a non-combustible aerosol provision system as described herein. In some embodiments, the method comprises heating the aerosolgenerating material to a temperature of less than or equal to 350 °C. In some embodiments, the method comprises heating the aerosol-generating material to a temperature of from about 220 °C to about 280 °C. In some embodiments, the method comprises heating at least a portion of the aerosol-generating material to a temperature of from about 220 °C to about 280 °C over a session of use. “Session of use” as used herein refers to a single period of use of the noncombustible aerosol provision system by a user. The session of use begins at the point at which power is first supplied to at least one heating unit present in the heating assembly. The device will be ready for use after a period of time has elapsed from the start of the session of use. The session of use ends at the point at which no power is supplied to any of the heating elements in the aerosol-generating device. The end of the session of use may coincide with the point at which the smoking article is depleted (the point at which the total particulate matter yield (mg) in each puff would be deemed unacceptably low by a user). The session will have a duration of a plurality of puffs. Said session may have a duration less than 7 minutes, or 6 minutes, or 5 minutes, or 4 minutes and 30 seconds, or 4 minutes, or 3 minutes and 30 seconds. In some embodiments, the session of use may have a duration of from 2 to 5 minutes, or from 3 to 4.5 minutes, or 3.5 to 4.5 minutes, or suitably 4 minutes. A session may be initiated by the user actuating a button or switch on the device, causing at least one heating element to begin rising in temperature.
In some embodiments, during a session of use, at least 20wt% of the flavour present in the aerosol-generating material is aerosolised, or at least 30wt%, 40wt% or 50wt%. That is, after a session of use, the amount of flavour in the aerosolgenerating material is depleted by 20wt%, 30wt%, 40wt% or 50wt%. The ratio of cellulosic binder to non-cellulosic binder in the aerosol-generating material as described herein may allow for more efficient delivery of active substance to a user (e.g. a higher proportion of flavour is aerosolised from the aerosol-generating material).
Example embodiments
1. An aerosol-generating material or slurry as defined in the Summary of the Disclosure.
2. The aerosol-generating material or slurry of Embodiment 1, comprising about 0.1-50 wt% flavour.
3. The aerosol-generating material or slurry of Embodiment 2, comprising about 1- 50wt% flavour.
4. The aerosol-generating material or slurry of Embodiment 1 , comprising about 5- 50 wt% flavour. 5. The aerosol-generating material or slurry of Embodiment 4, comprising about 10-
45 wt% flavour.
5A. The aerosol-generating material or slurry of Embodiment 5, comprising about 10-25 wt% flavour.
5B. The aerosol-generating material or slurry of Embodiment 5A, comprising about 10-20 wt% flavour.
5C. The aerosol-generating material or slurry of Embodiment 5B, comprising about 15-20 wt% flavour.
6. The aerosol-generating material or slurry of Embodiment 4, comprising about 15- 45 wt% flavour. 7. The aerosol-generating material or slurry of Embodiment 1 , comprising about 20-
50 wt% flavour.
8. The aerosol-generating material or slurry of Embodiment 7, comprising about 25- 50wt% flavour.
9. The aerosol-generating material or slurry of Embodiment 8, comprising about 30- 50 wt% flavour.
10. The aerosol-generating material or slurry of Embodiment 1, comprising about 30-45 wt% flavour.
11. The aerosol-generating material or slurry of Embodiment 10, comprising about 35-50 wt% flavour. 12. The aerosol-generating material or slurry of Embodiment 11, comprising about
35-45 wt% flavour.
12a. The aerosol-generating material or slurry of Embodiment 1 , comprising about 5-25 wt% flavour.
12b. The aerosol-generating material or slurry of any preceding Embodiment, wherein the flavour comprises (or is) menthol.
12c. The aerosol-generating material or slurry of any of Embodiments 1 -12a, wherein the flavour comprises (or is) spearmint. 13. The aerosol-generating material or slurry of any preceding Embodiment, comprising about 10-50 wt% of one or more binders.
13a. The aerosol-generating material or slurry of Embodiment 13, comprising about 10-45 wt% of one or more binders.
14. The aerosol-generating material or slurry of Embodiment 13a, comprising about 10-40 wt% of one or more binders.
15. The aerosol-generating material or slurry of Embodiment 14, comprising about 10-35 wt% of one or more binders.
16. The aerosol-generating material or slurry of Embodiment 15, comprising about 10-30 wt% of one or more binders. 17. The aerosol-generating material or slurry of Embodiment 16, comprising about
10-25 wt% of one or more binders.
18. The aerosol-generating material or slurry of any of Embodiments 1-12, comprising about 15-45 wt% of one or more binders.
19. The aerosol-generating material or slurry of Embodiment 18, comprising about 15-40 wt% of one or more binders.
20. The aerosol-generating material or slurry of Embodiment 19, comprising about 15-35 wt% of one or more binders.
21. The aerosol-generating material or slurry of Embodiment 20, comprising about 15-30 wt% of one or more binders. 22. The aerosol-generating material or slurry of Embodiment 21 , comprising about
15-25 wt% of one or more binders.
23. The aerosol-generating material or slurry of any of Embodiments 1-12, comprising about 20-45 wt% of one or more binders.
24. The aerosol-generating material or slurry of Embodiment 23, comprising about 20-40 wt% of one or more binders.
25. The aerosol-generating material or slurry of Embodiment 24, comprising about 20-35 wt% of one or more binders.
26. The aerosol-generating material or slurry of Embodiment 25, comprising about 20-30 wt% of one or more binders.
27. The aerosol-generating material or slurry of Embodiment 26, comprising about 20-25 wt% of one or more binders.
28. The aerosol-generating material or slurry of any preceding Embodiment, comprising about 5-35 wt% aerosol-generating agent. 29. The aerosol-generating material or slurry of Embodiment 28 comprising about
10-35 wt% aerosol-generating agent.
30. The aerosol-generating material or slurry of any of Embodiments 1-27 comprising about 5-30 wt% aerosol-generating agent.
30A. The aerosol-generating material or slurry of any of Embodiments 1-27 comprising about 5-25 wt% aerosol-generating agent.
30B. The aerosol-generating material or slurry of any of Embodiments 1-27 comprising about 5-15 wt% aerosol-generating agent.
31. The aerosol-generating material or slurry of Embodiment 30 comprising about 10-30 wt% aerosol-generating agent. 32. The aerosol-generating material or slurry of Embodiment 31 , comprising about
10-25 wt% aerosol-generating agent.
33. The aerosol-generating material or slurry of Embodiment 32, comprising about 10-20 wt% aerosol-generating agent.
34. The aerosol-generating material or slurry of any of Embodiments 1-27, comprising about 12-30 wt% aerosol-generating agent.
35. The aerosol-generating material or slurry of Embodiment 34, comprising about 12-25 wt% aerosol-generating agent.
36. The aerosol-generating material or slurry of Embodiment 35, comprising about 12-20 wt% aerosol-generating agent. 37. The aerosol-generating material or slurry of any preceding Embodiment, comprising about 1-20 wt% emulsifier.
37a. The aerosol-generating material or slurry of Embodiment 37, comprising about 1-15 wt% emulsifier.
37b. The aerosol-generating material or slurry of Embodiment 37a. comprising about 1-12 wt% emulsifier.
38. The aerosol-generating material or slurry of Embodiment 37b, comprising about 1-10 wt% emulsifier.
39. The aerosol-generating material or slurry of Embodiment 38, comprising about 1-7 wt% emulsifier.
40. The aerosol-generating material or slurry of any of Embodiments 1 -36, comprising about 3-12 wt% emulsifier.
41. The aerosol-generating material or slurry of Embodiment 40, comprising about 3-10 wt% emulsifier. 42. The aerosol-generating material or slurry of Embodiment 41 , comprising about
3-7 wt% emulsifier.
43. The aerosol-generating material or slurry of any of Embodiments 1 -36, comprising about 5-12 wt% emulsifier.
44. The aerosol-generating material or slurry of Embodiment 43, comprising about 5-10 wt% emulsifier.
45. The aerosol-generating material or slurry of Embodiment 44, comprising about 5-7 wt% emulsifier.
46. The aerosol-generating material or slurry of any preceding Embodiment, wherein the aerosol-generating agent comprises (or is) one or more of glycerol, propylene glycol, diethylene glycol, triethylene glycol, tetraethylene glycol, 1 ,3- butylene glycol, erythritol, meso-Erythritol, ethyl vanillate, ethyl laurate, a diethyl suberate, triethyl citrate, triacetin, a diacetin mixture, benzyl benzoate, benzyl phenyl acetate, tributyrin, lauryl acetate, lauric acid, myristic acid, and propylene carbonate. 47. The aerosol-generating material or slurry of Embodiment 46, wherein the aerosol-generating agent comprises (or is) one or more of erythritol, propylene glycol, glycerol, and triacetin.
48. The aerosol-generating material or slurry of Embodiment 46 or 47, wherein the aerosol-generating agent comprises (or is) glycerol optionally in combination with propylene glycol.
49. The aerosol-generating material or slurry of any preceding Embodiment, wherein the cellulosic binder comprises (or is) one or more compounds selected from hydroxymethyl cellulose, hydroxyethyl cellulose, hydroxypropyl cellulose, carboxymethylcellulose (CMC), hydroxypropyl methylcellulose (HPMC), methyl cellulose, ethyl cellulose, cellulose acetate (CA), cellulose acetate butyrate (CAB), and cellulose acetate propionate (CAP).
50. The aerosol-generating material or slurry of Embodiment 49, wherein the cellulosic binder comprises (or is) one or more compounds selected from hydroxyethyl cellulose, hydroxypropyl cellulose, and/or carboxymethylcellulose.
51. The aerosol-generating material or slurry of Embodiment 49 or 50, wherein the cellulosic binder comprises (or is) carboxymethylcellulose.
52. The aerosol-generating material or slurry of any preceding Embodiment, wherein the one or more binders include a cellulosic binder and a non-cellulosic binder.
53. The aerosol-generating material or slurry of Embodiment 52, wherein the non- cellulosic binder comprises (or is) one or more compounds selected from alginates, pectins, starches (and derivatives), gums, silica or silicones compounds, clays and/or polyvinyl alcohol. 54. The aerosol-generating material or slurry of Embodiment 52 or 53, wherein the non-cellulosic binder comprises (or is) one or more compounds selected from alginates, pectins, pullulan, xanthan gum, guar gum, carrageenan, agarose, acacia gum, fumed silica, PDMS, sodium silicate, kaolin and/or polyvinyl alcohol.
55. The aerosol-generating material or slurry of any preceding Embodiment, wherein the binder comprises one or more of hydroxyethyl cellulose, hydroxypropyl cellulose and/or carboxymethylcellulose and one or more of alginates, pectins, pullulan, xanthan gum, guar gum, carrageenan, agarose, acacia gum, fumed silica, PDMS, sodium silicate, kaolin and polyvinyl alcohol.
56. The aerosol-generating material or slurry of any preceding Embodiment, wherein the binder comprises (or consists of) carboxymethyl cellulose and alginate.
57. The aerosol-generating material or slurry of any of Embodiments 52-56, wherein the weight ratio of cellulosic binder to non-cellulosic binder is from 1 :4 to 4:1.
58. The aerosol-generating material or slurry of Embodiment 57, wherein the weight ratio of cellulosic binder to non-cellulosic binder is from 2:3 to 7:3.
58A. The aerosol-generating material or slurry of Embodiment 57, wherein the weight ratio of cellulosic binder to non-cellulosic binder is from about 1 : 1 to about 1:2.
59. The aerosol-generating material or slurry of Embodiment 58, wherein the weight ratio of cellulosic binder to non-cellulosic binder is from about 2:3 to about 3:2.
60. The aerosol-generating material or slurry of Embodiment 59, wherein the weight ratio of cellulosic binder to non-cellulosic binder is from 1:1 to 3:2.
61. The aerosol-generating material or slurry of any of Embodiments 52-56, wherein the weight ratio of cellulosic binder to non-cellulosic binder is >1:1.
62. The aerosol-generating material or slurry of any preceding Embodiment, wherein there is no crosslinking agent.
63. The aerosol-generating material or slurry of any of Embodiments 1 -61 , comprising crosslinking agent. 64. The aerosol-generating material or slurry of Embodiment 63, wherein the crosslinking agent comprises calcium ions.
65. The aerosol-generating material or slurry of Embodiment 63 or 64, comprising about 0.5-5wt% crosslinking agent.
66. The aerosol-generating material or slurry of any preceding Embodiment further comprising one or more other functional materials.
67. The aerosol-generating material or slurry of any preceding Embodiment further comprising one or more fillers.
68. The aerosol-generating material or slurry of Embodiment 67, wherein the fillers are selected from inorganic filler materials, wood pulp, hemp fibre, cellulose and cellulose derivatives, such as wood pulp and/or MCC.
68A. The aerosol-generating material or slurry of any of Embodiments 1-66, wherein the aerosol-generating material comprises less than 20 wt% filler.
68B. The aerosol-generating material or slurry of any of Embodiments 1-66, wherein the aerosol-generating material comprises less than 10 wt% filler. 68C. The aerosol-generating material or slurry of any of Embodiments 1 -66, wherein the aerosol-generating material comprises less than 5 wt% filler.
68D. The aerosol-generating material or slurry of any of Embodiments 1 -66, wherein the aerosol-generating material comprises less than 1 wt% filler.
68E. The aerosol-generating material or slurry of any of Embodiments 1-66, wherein the aerosol-generating material comprises no filler.
68F. The aerosol-generating material or slurry of any of Embodiments 1-66, wherein the aerosol-generating material comprises less than 60 wt% filler.
68G. The aerosol-generating material or slurry of any of Embodiments 1 -66, wherein the aerosol-generating material comprises from about 40 to about 60 wt% filler. 68H. The aerosol-generating material or slurry of any of Embodiments 1-66, wherein the aerosol-generating material comprises from about 45 to about 55 wt% filler.
69. The aerosol-generating material or slurry of Embodiment 68, wherein the aerosol-generating material or slurry comprises no calcium carbonate such as chalk.
70. The aerosol-generating material or slurry of any preceding Embodiment, wherein the aerosol-generating material or slurry does not comprise fibrous material.
71. The aerosol-generating material or slurry of any preceding Embodiment, wherein the aerosol-generating material or slurry does not comprise tobacco fibres. 71a. The aerosol-generating material or slurry of any preceding Embodiment, wherein the aerosol-generating material comprises caramel.
72. The aerosol-generating material of any preceding Embodiment, wherein the aerosol-generating material consists of, or consists essentially of, binder, water, aerosol-generating agent, flavour, emulsifier and optionally an active substance and/or a filler.
73. The aerosol-generating material of any preceding embodiment, wherein the aerosol-generating material consists of, or consists essentially of binder, water, aerosol-generating agent, flavour and emulsifier. 74, The aerosol-generating material of any preceding embodiment, wherein the aerosol-generating material is present on a support.
75. An aerosol-generating composition comprising an aerosol-generating material according to any preceding Embodiment.
76. The aerosol-generating composition of Embodiment 75 further comprising a second aerosol-generating material having a different composition, which comprises: an aerosol-generating agent in an amount of from about 1 to about 80 wt% of the aerosol-generating material; one or more binders, wherein the total amount of binder is from about 5 to about 50 wt% of the aerosol-generating material; - flavour in an amount of from about 0.1 to about 60 wt% of the aerosolgenerating material; an emulsifier in an amount of from about 1 to about 25 wt% of the aerosolgenerating material; and optionally a filler. 76a. The aerosol-generating composition of Embodiment 76 wherein the second aerosol-generating material comprises: an aerosol-generating agent in an amount of from about 1 to about 80 wt% of the aerosol-generating material;
one or more binders, wherein the total amount of binder is from about 10 to about 50 wt% of the aerosol-generating material; flavour in an amount of from about 0.1 to about 60 wt% of the aerosolgenerating material; - an emulsifier in an amount of from about 1 to about 15 wt% of the aerosolgenerating material; and optionally a filler.
77. The aerosol-generating composition of Embodiment 76 or 76a wherein the second aerosol-generating material is as defined in any of Embodiments 1-48 or 62-74.
78. The aerosol-generating composition of Embodiment 76, 76a or 77 wherein the binder in the first aerosol-generating material includes a cellulosic binder and the binder in the second aerosol-generating material includes a non-cellulosic binder. 78A. The aerosol-generating composition of Embodiment 78 wherein the binder in the first aerosol-generating material is a cellulosic binder and the binder in the second aerosol-generating material is a non-cellulosic binder.
79. The aerosol-generating composition of Embodiment 78 or 78A, wherein the cellulosic binder comprises (or is) one or more compounds selected from hydroxymethyl cellulose, hydroxyethyl cellulose, hydroxypropyl cellulose, carboxymethylcellulose (CMC), hydroxypropyl methylcellulose (HPMC), methyl cellulose, ethyl cellulose, cellulose acetate (CA), cellulose acetate butyrate (CAB), and cellulose acetate propionate (CAP).
80. The aerosol-generating composition of Embodiment 79, wherein the cellulosic binder comprises (or is) one or more compounds selected from hydroxyethyl cellulose, hydroxypropyl cellulose, and/or carboxymethylcellulose.
81. The aerosol-generating composition of Embodiment 80, wherein the cellulosic binder comprises (or is) carboxymethylcellulose.
82. The aerosol-generating composition of any of Embodiments 78-81, wherein the non-cellulosic binder comprises (or is) one or more compounds selected from alginates, pectins, starches (and derivatives), gums, silica or silicones compounds, clays and/or polyvinyl alcohol.
83. The aerosol-generating composition of Embodiment 82, wherein the non- cellulosic binder comprises (or is) one or more compounds selected from alginates,
pectins, pullulan, xanthan gum, guar gum, carrageenan, agarose, acacia gum, fumed silica, PDMS, sodium silicate, kaolin and/or polyvinyl alcohol.
84. The aerosol-generating composition of Embodiment 83, wherein the non- cellulosic binder comprises alginate. 84A. The aerosol-generating composition of Embodiment 78, wherein the binder in the first aerosol-generating material comprises CMC and the binder in the second aerosol-generating material comprises alginate.
84B. The aerosol-generating composition of Embodiment 78, wherein the binder in the first aerosol-generating material is CMC and the binder in the second aerosol- generating material is alginate.
85. The aerosol-generating composition of any of Embodiments 76-84B, wherein the weight ratio of first to second aerosol-generating material is from 1 :4 to 4:1.
86. The aerosol-generating composition of Embodiment 85, wherein the weight ratio of first to second aerosol-generating material is from 2:3 to 3:2. 87. The aerosol-generating composition of Embodiment 86, wherein the weight ratio of first to second aerosol-generating material is about 1:1.
88. The aerosol-generating composition of any of Embodiments 75-87 further comprising one or more other functional materials.
89. The aerosol-generating composition of any of Embodiments 75-88, wherein the other functional materials comprise one or more pH regulators, colouring agents, preservatives, binders, fillers, stabilisers, and/or antioxidants.
90. The aerosol-generating composition of Embodiment 89, wherein the other functional materials comprise one or more fillers.
91. The aerosol-generating composition of Embodiment 89 or 90, wherein the fillers are selected from inorganic filler materials, wood pulp, hemp fibre, cellulose and cellulose derivatives.
91a. The aerosol-generating composition of Embodiment 89 or 90, wherein the fillers are selected from maltodextrin or microcrystalline cellulose.
91b. The aerosol-generating composition of Embodiment 89 or 90, wherein the fillers have a density of less than about 2 g/cm3.
91c. The aerosol-generating composition of Embodiment 91b, wherein the fillers have a density of less than about 0.5 g/cm3.
91 d. The aerosol-generating composition of Embodiment 91c, wherein the fillers have a density of less than about 0.3 g/cm3.
92. The aerosol-generating composition of any of Embodiment 75-91 d, wherein the aerosol-generating composition comprises no calcium carbonate such as chalk.
93. The aerosol-generating composition of any of Embodiments 75-90 or 92, wherein the aerosol-generating composition does not comprise fibrous material. 94. The aerosol-generating composition of any of Embodiments 75-93, wherein the aerosol-generating composition does not comprise tobacco fibres.
95. The aerosol-generating composition of any of Embodiments 75-94, comprising a total of from about 50-100 wt% (WWB) of aerosol-generating material.
96. The aerosol-generating composition of any of Embodiments 75-94, comprising a total of from about 50-95 wt% (WWB) of the aerosol-generating material.
97. The aerosol-generating composition of any of Embodiments 75-94, comprising a total of from about 50-90 wt% (WWB) of the aerosol-generating material.
98. The aerosol-generating composition of any of Embodiments 75-94, comprising a total of from about 60-100 wt% (WWB) of the aerosol-generating material. 99. The aerosol-generating composition of any of Embodiments 75-94, comprising a total of from about 60-95 wt% (WWB) of the aerosol-generating material.
100. The aerosol-generating composition of any of Embodiments 75-94, comprising a total of from about 60-90 wt% (WWB) of the aerosol-generating material. 101. The aerosol-generating composition of any of Embodiments 75-94, comprising a total of from about 70-100 wt% (WWB) of the aerosol-generating material.
102. The aerosol-generating composition of any of Embodiments 75-94, comprising a total of from about 70-95 wt% (WWB) of the aerosol-generating material.
103. The aerosol-generating composition of any of Embodiments 75-94, comprising a total of from about 70-90 wt% (WWB) of the aerosol-generating material.
104. The aerosol-generating composition of any of Embodiments 75-94, consisting of, or consisting essentially of the aerosol-generating material(s).
105. A consumable for use in a non-combustible aerosol provision device, the consumable comprising the aerosol-generating composition of any of Embodiments 75-104.
106. A non-combustible aerosol provision system comprising the consumable of Embodiment 105 and a non-combustible aerosol provision device.
107. The consumable for use in a non-combustible aerosol provision device of Embodiment 105, or the non-combustible aerosol provision system of Embodiment 106, wherein the non-combustible aerosol provision device is a heat-not-burn device.
108. The consumable for use in a non-combustible aerosol provision device of Embodiment 105, or the non-combustible aerosol provision system of Embodiment 106, wherein the non-combustible aerosol provision device is an electronic tobacco hybrid device.
109. A method of forming an aerosol-generating material as defined in any of Embodiments 1-73, the method comprising
(a) providing a slurry comprising the flavour, binder, aerosol-generating agent, emulsifier, a solvent and any optional further components of the aerosol-generating material;
(b) forming a layer of the slurry;
(c) optionally setting the layer of the slurry; and
(d) drying the slurry to form the aerosol-generating material.
110. The method of Embodiment 109 or the slurry of any of Embodiments 1-71 wherein the solvent comprises water.
111. The method of Embodiment 109 or the slurry of any of Embodiments 1 -71 wherein the solvent consists essentially of, or consists of water.
112. The method of Embodiments 109-111 or the slurry of any of Embodiments 1-71 , 110 or 111 wherein the slurry comprises from about 50 wt%, 60 wt%, 70 wt%, 80 wt% or 90 wt% of solvent (WWB).
Examples
Exemplary and non-limiting formulations for twelve aerosol-generating compositions comprising an aerosol-generating material, are provided in the table below. The percentages are given on a dry weight basis.
Some of the above formulations were tested and their flavour (i.e. menthol) release profile was obtained (see Figures 8-13). Figure 8 shows the release profile of flavour (in this case menthol) from
Formulation 1, and shows flavour release at 190-200 °C.
In comparison, the temperature at which the flavour (i.e. menthol) is released can be increased to about 250 °C by using CMC instead of alginate (see Formulation 2 and Figure 9). As discussed above, a cellulosic binder such as CMC may be preferable to other binders (such as alginate) for reasons of reduced cost and/or ease of manufacturing.
If a lower flavour release temperature is desired than is obtained when using CMC alone, then a mixture of CMC and alginate can be used (see Formulations 4 and 7-9 and Figures 10-13). Thus, the combination of cellulosic and non-cellulosic binders (e.g. CMC and alginate) allows for the flavour release temperature to be adjusted, whilst also allowing for reduced costs and/or easier manufacturer than formulations containing alginate alone. The formulations containing a combination of CMC and alginate also showed an increased longevity of flavour release.
Finally, as can be seen from a comparison of Figure 10-13, combining a cellulosic binder (e.g. CMC) with a non-cellulosic binder (e.g. alginate) in particular ratios may influence the temperature at which the flavour is released from the aerosol-generating material when heated and/or the point in a session of use at which point flavour is released. For example, by increasing the ratio of CMC to alginate, the temperature of flavour release can be increased.
Claims
1. An aerosol-generating material comprising:
- an aerosol-generating agent in an amount of from about 1 to about 80 wt% of the aerosol-generating material; one or more binders, wherein the total amount of binder is from about 5 to about 50 wt% of the aerosol-generating material, and wherein the one or more binders include a cellulosic binder; flavour in an amount of from about 0.1 to about 60 wt% of the aerosolgenerating material; an emulsifier in an amount of from about 1 to about 25 wt% of the aerosolgenerating material; and optionally a filler.
2. The aerosol-generating material according to claim 1, wherein the one or more binders include a cellulosic binder and a non-cellulosic binder.
3. The aerosol-generating material according to claim 1 or 2, wherein the cellulosic binder comprises carboxymethyl cellulose.
4. The aerosol-generating material according to claim 2, wherein the non- cellulosic binder comprises alginate.
5. The aerosol-generating material according to claim 2, wherein the one or more binders include carboxymethyl cellulose and alginate.
6. The aerosol-generating material according to claim 2 or 5, wherein the weight ratio of cellulosic binder to non-cellulosic binder is from about 1 :4 to about 4:1.
7. The aerosol-generating material according to any of claims 1 to 6, wherein the flavour comprises menthol.
8. The aerosol-generating material according to any of claims 1 to 6, wherein the flavour comprises spearmint.
9. The aerosol-generating material according to any of claims 1 to 8, wherein the aerosol-generating agent comprises one or more glycerol, propylene glycol, diethylene glycol, triethylene glycol, tetraethylene glycol, 1 ,3-butylene glycol, erythritol, meso-Erythritol, ethyl vanillate, ethyl laurate, a diethyl suberate, triethyl citrate, triacetin, a diacetin mixture, benzyl benzoate, benzyl phenyl acetate, tributyrin, lauryl acetate, lauric acid, myristic acid, and propylene carbonate.
10. The aerosol-generating material according to any of claims 1 to 9, wherein the aerosol-generating agent comprises glycerol.
11. The aerosol-generating material according to any of claims 1 to 10, wherein the emulsifier comprises one or more compounds selected from agar, xanthan gum, gum Arabic (acacia gum), guar gum, locust bean gum, pectin, carrageenan and lecithin.
12. The aerosol-generating material according to any of claims 1 to 11, wherein the emulsifier comprises guar gum.
13. The aerosol-generating material according to any of claims 1 to 12, wherein the aerosol-generating material comprises filler in an amount up to about 25 wt%.
14. The aerosol-generating material according to any of claims 1 to 12, wherein the aerosol-generating material comprises less than 1 wt% filler.
15. The aerosol-generating material according to any of claims 1 to 14, wherein any filler comprises maltodextrin or microcrystalline cellulose (MCC),
16. The aerosol-generating material according to any of claims 1 to 14, wherein any filler has a density of less than about 0.5 g/cm3.
17. The aerosol-generating material according to any of claims 1 to 16, wherein the aerosol-generating agent is present in an amount of from about 10 to about 35 wt% of the total weight of the aerosol-generating material.
18. The aerosol-generating material according to any of claims 1 to 17, wherein the flavour is present in an amount of from about 10 to about 50 wt% of the total weight of the aerosol-generating material.
19. The aerosol-generating material according to any of claims 1 to 18, wherein the flavour is present in an amount of from about 30 to about 50 wt% of the total weight of the aerosol-generating material.
20. The aerosol-generating material according to any of claims 1 to 19, wherein the flavour is present in an amount of from about 5 to about 25 wt% of the total weight of the aerosol-generating material.
21. The aerosol-generating material according to any of claims 1 to 19, wherein the aerosol-generating material further comprises a crosslinking agent.
22. The aerosol-generating material according to claim 21, wherein the crosslinking agent comprises calcium ions.
23. The aerosol-generating material according to any of claims 1 to 20, wherein the aerosol-generating material does not comprise a crosslinking agent.
24. The aerosol-generating material according to any of claims 1 to 23, wherein the aerosol-generating material is substantially free from tobacco.
25. The aerosol-generating material according to any of claims 1 to 24, wherein the aerosol-generating material is in the form of a sheet.
26. The aerosol-generating material according to any of claims 1 to 24, wherein the aerosol-generating material is in the form of a film on a support.
27. An aerosol-generating composition comprising the aerosol-generating material of any of claims 1-26.
28. The aerosol-generating composition according to claim 27, further comprising a second aerosol-generating material which comprises:
- an aerosol-generating agent in an amount of from about 1 to about 80 wt% of the aerosol-generating material; - one or more binders, wherein the total amount of binder is from about 5 to about 50 wt% of the aerosol-generating material;
- flavour in an amount of from about 0.1 to about 60 wt% of the aerosolgenerating material;
- an emulsifier in an amount of from about 1 to about 25 wt% of the aerosol- generating material; and
- optionally a filler, wherein the composition of the second aerosol-generating material is different to the composition of the first aerosol-generating material.
29. The aerosol-generating composition according to claim 28, wherein the one or more binders in the second aerosol-generating material include a non-cellulosic binder, preferably alginate.
30. An article for use with a non-combustible aerosol provision device, the article comprising the aerosol-generating composition according to any of claims
27-29.
31. A non-combustible aerosol provision system comprising the article according to claim 30 and a non-combustible aerosol provision device, wherein the non- combustible aerosol provision device is configured to generate aerosol from the article when the article is used with the non-combustible aerosol provision device.
32. The system according to claim 31 wherein the non-combustible aerosol provision device comprises a heater configured to heat but not burn the article.
33. Use of an aerosol-generating composition according to any of claims 27-29 in a consumable for use in a non-combustible aerosol provision device, the noncombustible aerosol provision device comprising an aerosol-generation device to
generate aerosol from the consumable when the consumable is used with the noncombustible aerosol provision device.
34. A slurry comprising: - an aerosol-generating agent in an amount of from about 1 to about 80 wt%;
- one or more binders, wherein the total amount of binder is from about 5 to about 50 wt%, and wherein the one or more binders include carboxymethyl cellulose; - flavour in an amount of from about 0.1 to about 60 wt%;
- an emulsifier in an amount of from about 1 to about 25 wt%; and
- optionally a filler; wherein these weights are calculated on a dry weight basis, and
- a solvent.
35. A method of making an aerosol-generating material according to any one of claims 1 to 26, the method comprising:
(i) combining
- an aerosol-generating agent in an amount of from about 1 to about 80 wt%;
- one or more binders, wherein the total amount of binder is from about 5 to about 50 wt%, and wherein the one or more binders include carboxymethyl cellulose;
- flavour in an amount of from about 0.1 to about 60 wt%; - an emulsifier in an amount of from about 1 to about 25 wt%; and
- optionally a filler; wherein these weights are calculated on a dry weight basis, and
- a solvent;
(ii) forming a layer of the slurry; and (iii) drying the slurry to form the aerosol-generating material.
36. A slurry according to claim 34 or the method according to claim 35, wherein the solvent is water.
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GBGB2110571.3A GB202110571D0 (en) | 2021-07-22 | 2021-07-22 | Aerosol generating composition |
GBGB2114194.0A GB202114194D0 (en) | 2021-10-04 | 2021-10-04 | Aerosol generating composition |
PCT/EP2022/070656 WO2023002031A1 (en) | 2021-07-22 | 2022-07-22 | Aerosol generating composition |
Publications (1)
Publication Number | Publication Date |
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EP4373306A1 true EP4373306A1 (en) | 2024-05-29 |
Family
ID=82851665
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP22754096.0A Pending EP4373306A1 (en) | 2021-07-22 | 2022-07-22 | Aerosol generating composition |
Country Status (6)
Country | Link |
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EP (1) | EP4373306A1 (en) |
KR (1) | KR20240036573A (en) |
AU (1) | AU2022314991A1 (en) |
CA (1) | CA3224483A1 (en) |
IL (1) | IL309582A (en) |
WO (1) | WO2023002031A1 (en) |
Family Cites Families (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB0324525D0 (en) * | 2003-10-21 | 2003-11-26 | British American Tobacco Co | Smoking articles and smokable filler material therefor |
KR101880270B1 (en) | 2013-10-29 | 2018-07-20 | 브리티시 아메리칸 토바코 (인베스트먼츠) 리미티드 | Apparatus for heating smokable material |
EP3261467B1 (en) | 2015-02-27 | 2022-03-30 | Nicoventures Trading Limited | Cartridge, components and methods for generating an inhalable medium |
GB201917475D0 (en) * | 2019-11-29 | 2020-01-15 | Nicoventures Trading Ltd | Aerosol generation |
-
2022
- 2022-07-22 IL IL309582A patent/IL309582A/en unknown
- 2022-07-22 WO PCT/EP2022/070656 patent/WO2023002031A1/en active Application Filing
- 2022-07-22 EP EP22754096.0A patent/EP4373306A1/en active Pending
- 2022-07-22 KR KR1020247002243A patent/KR20240036573A/en unknown
- 2022-07-22 AU AU2022314991A patent/AU2022314991A1/en active Pending
- 2022-07-22 CA CA3224483A patent/CA3224483A1/en active Pending
Also Published As
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IL309582A (en) | 2024-02-01 |
WO2023002031A1 (en) | 2023-01-26 |
AU2022314991A1 (en) | 2024-01-18 |
CA3224483A1 (en) | 2023-01-26 |
KR20240036573A (en) | 2024-03-20 |
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