EP4337601A1 - Verfahren zur umwandlung von co2 - Google Patents
Verfahren zur umwandlung von co2Info
- Publication number
- EP4337601A1 EP4337601A1 EP22728965.9A EP22728965A EP4337601A1 EP 4337601 A1 EP4337601 A1 EP 4337601A1 EP 22728965 A EP22728965 A EP 22728965A EP 4337601 A1 EP4337601 A1 EP 4337601A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- production
- rwgs
- reactor
- electrified
- process according
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 238000000034 method Methods 0.000 title claims abstract description 99
- 230000008569 process Effects 0.000 title claims abstract description 98
- 238000006243 chemical reaction Methods 0.000 title claims abstract description 28
- 238000004519 manufacturing process Methods 0.000 claims abstract description 72
- 239000007789 gas Substances 0.000 claims abstract description 34
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 30
- 239000001257 hydrogen Substances 0.000 claims abstract description 24
- 229910052739 hydrogen Inorganic materials 0.000 claims abstract description 24
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims abstract description 17
- 239000000126 substance Substances 0.000 claims abstract description 13
- 239000000446 fuel Substances 0.000 claims abstract description 7
- 230000002441 reversible effect Effects 0.000 claims abstract description 5
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 claims description 153
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 claims description 36
- 230000015572 biosynthetic process Effects 0.000 claims description 34
- 238000003786 synthesis reaction Methods 0.000 claims description 34
- 150000002430 hydrocarbons Chemical class 0.000 claims description 20
- 229930195733 hydrocarbon Natural products 0.000 claims description 17
- 238000005868 electrolysis reaction Methods 0.000 claims description 15
- 239000007788 liquid Substances 0.000 claims description 15
- 238000000629 steam reforming Methods 0.000 claims description 15
- 230000003197 catalytic effect Effects 0.000 claims description 13
- 238000002453 autothermal reforming Methods 0.000 claims description 10
- 230000003647 oxidation Effects 0.000 claims description 9
- 238000007254 oxidation reaction Methods 0.000 claims description 9
- 230000036961 partial effect Effects 0.000 claims description 9
- 239000003345 natural gas Substances 0.000 claims description 8
- 238000002407 reforming Methods 0.000 claims description 6
- 239000006227 byproduct Substances 0.000 claims description 5
- 239000002253 acid Substances 0.000 claims description 4
- 239000000376 reactant Substances 0.000 claims description 4
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 abstract description 13
- 229910002091 carbon monoxide Inorganic materials 0.000 abstract description 13
- 230000000694 effects Effects 0.000 abstract description 10
- 239000003337 fertilizer Substances 0.000 abstract description 3
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 77
- 229910002092 carbon dioxide Inorganic materials 0.000 description 77
- 239000001569 carbon dioxide Substances 0.000 description 76
- 239000000243 solution Substances 0.000 description 24
- 238000010586 diagram Methods 0.000 description 13
- 229910052799 carbon Inorganic materials 0.000 description 10
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 9
- 238000005516 engineering process Methods 0.000 description 9
- 239000000203 mixture Substances 0.000 description 9
- 239000003054 catalyst Substances 0.000 description 6
- 238000011161 development Methods 0.000 description 5
- 230000018109 developmental process Effects 0.000 description 5
- 239000005431 greenhouse gas Substances 0.000 description 5
- 230000009467 reduction Effects 0.000 description 5
- 238000012546 transfer Methods 0.000 description 5
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 4
- 238000011956 best available technology Methods 0.000 description 4
- 239000000498 cooling water Substances 0.000 description 4
- 150000002431 hydrogen Chemical class 0.000 description 4
- 238000005984 hydrogenation reaction Methods 0.000 description 4
- 239000000047 product Substances 0.000 description 4
- 241000196324 Embryophyta Species 0.000 description 3
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 3
- 238000013459 approach Methods 0.000 description 3
- 239000004202 carbamide Substances 0.000 description 3
- 238000006555 catalytic reaction Methods 0.000 description 3
- 238000002485 combustion reaction Methods 0.000 description 3
- 230000005611 electricity Effects 0.000 description 3
- 238000010438 heat treatment Methods 0.000 description 3
- 239000012528 membrane Substances 0.000 description 3
- 239000005518 polymer electrolyte Substances 0.000 description 3
- 238000010926 purge Methods 0.000 description 3
- 239000004215 Carbon black (E152) Substances 0.000 description 2
- 229910021529 ammonia Inorganic materials 0.000 description 2
- 230000008901 benefit Effects 0.000 description 2
- 239000007795 chemical reaction product Substances 0.000 description 2
- 230000006872 improvement Effects 0.000 description 2
- 230000000670 limiting effect Effects 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 238000011084 recovery Methods 0.000 description 2
- 230000002829 reductive effect Effects 0.000 description 2
- 238000000926 separation method Methods 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 230000009466 transformation Effects 0.000 description 2
- 241000183024 Populus tremula Species 0.000 description 1
- QXZUUHYBWMWJHK-UHFFFAOYSA-N [Co].[Ni] Chemical compound [Co].[Ni] QXZUUHYBWMWJHK-UHFFFAOYSA-N 0.000 description 1
- 238000009825 accumulation Methods 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 150000001336 alkenes Chemical class 0.000 description 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 238000007084 catalytic combustion reaction Methods 0.000 description 1
- 229910010293 ceramic material Inorganic materials 0.000 description 1
- 238000001311 chemical methods and process Methods 0.000 description 1
- 230000006835 compression Effects 0.000 description 1
- 238000007906 compression Methods 0.000 description 1
- 229910052593 corundum Inorganic materials 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- 230000029087 digestion Effects 0.000 description 1
- 230000005674 electromagnetic induction Effects 0.000 description 1
- 230000003203 everyday effect Effects 0.000 description 1
- 239000008246 gaseous mixture Substances 0.000 description 1
- 230000007062 hydrolysis Effects 0.000 description 1
- 238000006460 hydrolysis reaction Methods 0.000 description 1
- 238000011065 in-situ storage Methods 0.000 description 1
- 239000011261 inert gas Substances 0.000 description 1
- PWPJGUXAGUPAHP-UHFFFAOYSA-N lufenuron Chemical compound C1=C(Cl)C(OC(F)(F)C(C(F)(F)F)F)=CC(Cl)=C1NC(=O)NC(=O)C1=C(F)C=CC=C1F PWPJGUXAGUPAHP-UHFFFAOYSA-N 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 239000002105 nanoparticle Substances 0.000 description 1
- 230000008520 organization Effects 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 244000045947 parasite Species 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 229920000515 polycarbonate Polymers 0.000 description 1
- 239000004417 polycarbonate Substances 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 239000011541 reaction mixture Substances 0.000 description 1
- 239000012088 reference solution Substances 0.000 description 1
- 230000029058 respiratory gaseous exchange Effects 0.000 description 1
- 230000009919 sequestration Effects 0.000 description 1
- 238000004088 simulation Methods 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
- 241000894007 species Species 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 238000000194 supercritical-fluid extraction Methods 0.000 description 1
- 230000001131 transforming effect Effects 0.000 description 1
- 238000010977 unit operation Methods 0.000 description 1
- 229910001845 yogo sapphire Inorganic materials 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
- C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
- C01B3/06—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of inorganic compounds containing electro-positively bound hydrogen, e.g. water, acids, bases, ammonia, with inorganic reducing agents
- C01B3/12—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of inorganic compounds containing electro-positively bound hydrogen, e.g. water, acids, bases, ammonia, with inorganic reducing agents by reaction of water vapour with carbon monoxide
- C01B3/16—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of inorganic compounds containing electro-positively bound hydrogen, e.g. water, acids, bases, ammonia, with inorganic reducing agents by reaction of water vapour with carbon monoxide using catalysts
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
- C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
- C01B3/32—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
- C01B3/34—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents
- C01B3/38—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using catalysts
- C01B3/386—Catalytic partial combustion
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
- C07C1/02—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon
- C07C1/12—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon from carbon dioxide with hydrogen
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
- C07C29/15—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively
- C07C29/151—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases
- C07C29/1516—Multisteps
- C07C29/1518—Multisteps one step being the formation of initial mixture of carbon oxides and hydrogen for synthesis
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10K—PURIFYING OR MODIFYING THE CHEMICAL COMPOSITION OF COMBUSTIBLE GASES CONTAINING CARBON MONOXIDE
- C10K3/00—Modifying the chemical composition of combustible gases containing carbon monoxide to produce an improved fuel, e.g. one of different calorific value, which may be free from carbon monoxide
- C10K3/02—Modifying the chemical composition of combustible gases containing carbon monoxide to produce an improved fuel, e.g. one of different calorific value, which may be free from carbon monoxide by catalytic treatment
- C10K3/026—Increasing the carbon monoxide content, e.g. reverse water-gas shift [RWGS]
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B1/00—Electrolytic production of inorganic compounds or non-metals
- C25B1/01—Products
- C25B1/02—Hydrogen or oxygen
- C25B1/04—Hydrogen or oxygen by electrolysis of water
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B15/00—Operating or servicing cells
- C25B15/08—Supplying or removing reactants or electrolytes; Regeneration of electrolytes
- C25B15/081—Supplying products to non-electrochemical reactors that are combined with the electrochemical cell, e.g. Sabatier reactor
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/10—Process efficiency
- Y02P20/133—Renewable energy sources, e.g. sunlight
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Combustion & Propulsion (AREA)
- Inorganic Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Health & Medical Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Electrochemistry (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Carbon And Carbon Compounds (AREA)
- Mram Or Spin Memory Techniques (AREA)
- Gasification And Melting Of Waste (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| IT102021000012551A IT202100012551A1 (it) | 2021-05-14 | 2021-05-14 | Processo per la conversione della co2 |
| PCT/IB2022/054338 WO2022238899A1 (en) | 2021-05-14 | 2022-05-10 | Process for the conversion of co2 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| EP4337601A1 true EP4337601A1 (de) | 2024-03-20 |
Family
ID=77126997
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| EP22728965.9A Pending EP4337601A1 (de) | 2021-05-14 | 2022-05-10 | Verfahren zur umwandlung von co2 |
Country Status (3)
| Country | Link |
|---|---|
| EP (1) | EP4337601A1 (de) |
| IT (1) | IT202100012551A1 (de) |
| WO (1) | WO2022238899A1 (de) |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2023194286A1 (en) * | 2022-04-08 | 2023-10-12 | Topsoe A/S | Methanol loop revamp by co intensification |
Family Cites Families (21)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| IT1272532B (it) | 1993-08-27 | 1997-06-23 | Snam Progetti | Processo di ossidazione parziale catalitica del gas naturale per ottenere gas di sintesi e formaldeide |
| IT1273491B (it) | 1995-02-03 | 1997-07-08 | Snam Progetti | Materiale avente struttura a strati tipo idrotalcite e relativi usi |
| IT1283585B1 (it) | 1996-04-11 | 1998-04-22 | Snam Progetti | Apparecchiatura per effettuare reazioni di ossidazione parziale |
| EA002517B1 (ru) | 1998-07-21 | 2002-06-27 | Халлор Топсёэ А/С | Получение синтез-газа путем риформинга в потоке водяного пара |
| ITMI20021133A1 (it) | 2002-05-24 | 2003-11-24 | Snam Progetti | Procedimento per reazioni di ossidazione parziale catalitica |
| ITMI20031739A1 (it) | 2003-09-11 | 2005-03-12 | Enitecnologie Spa | Procedimento di ossidazione parziale catalitica per |
| US20060024347A1 (en) | 2004-02-10 | 2006-02-02 | Biosurface Engineering Technologies, Inc. | Bioactive peptide coatings |
| ES1059642Y (es) | 2005-02-10 | 2005-09-01 | Fagor S Coop | Valvula rotatoria montada en un aparato de coccion multi-gas |
| ITMI20052002A1 (it) | 2005-10-21 | 2007-04-22 | Eni Spa | Dispositivo per miscelare fluidi inserito o combinato ad un reattore |
| ITMI20072209A1 (it) | 2007-11-21 | 2009-05-22 | Eni Spa | Procedimento migliorato per la produzione di gas di sintesi a partire da idrocarburi ossigenati ricavati da biomasse |
| ITMI20072228A1 (it) | 2007-11-23 | 2009-05-24 | Eni Spa | Procedimento per produrre gas di sintesi e idrogeno a partire da idrocarburi liquidi e gassosi |
| IT1398292B1 (it) | 2009-12-16 | 2013-02-22 | Eni Spa | Processo per la produzione di idrogeno a partire da idrocarburi liquidi, idrocarburi gassosi e/o composti ossigenati anche derivanti da biomasse |
| IT1400492B1 (it) | 2010-06-03 | 2013-06-11 | Eni Spa | Sistema catalitico per processi di ossidazione parziale catalitica a basso tempo di contatto |
| WO2016016256A1 (en) | 2014-07-29 | 2016-02-04 | Eni S.P.A. | Integrated sct-cpo/atr process for the production of synthesis gas |
| WO2016016253A1 (en) | 2014-07-29 | 2016-02-04 | Eni S.P.A. | Integrated short contact time catalytic partial oxidation/gas heated reforming process for the production of synthesis gas |
| WO2016016257A1 (en) | 2014-07-29 | 2016-02-04 | Eni S.P.A. | Integrated sct-cpo/pox process for producing synthesis gas |
| WO2016016251A1 (en) | 2014-07-29 | 2016-02-04 | Eni S.P.A. | Integrated sct-cpo/sr process for producing synthesis gas |
| DE112015006427A5 (de) * | 2015-04-08 | 2017-12-28 | Climeworks Ag | Herstellungsverfahren sowie herstellungsanlage zur herstellung von methan / gasförmigen und/oder flüssigen kohlenwasserstoffen |
| DE102018210303A1 (de) * | 2018-06-25 | 2020-01-02 | Siemens Aktiengesellschaft | Elektrochemische Niedertemperatur Reverse-Watergas-Shift Reaktion |
| CA3112531A1 (en) | 2018-09-19 | 2020-03-26 | Eni S.P.A. | Process for the production of methanol from gaseous hydrocarbons |
| JP2022550815A (ja) * | 2019-10-01 | 2022-12-05 | トプソー・アクチエゼルスカベット | メタノールからオンデマンド合成ガス |
-
2021
- 2021-05-14 IT IT102021000012551A patent/IT202100012551A1/it unknown
-
2022
- 2022-05-10 WO PCT/IB2022/054338 patent/WO2022238899A1/en active Application Filing
- 2022-05-10 EP EP22728965.9A patent/EP4337601A1/de active Pending
Also Published As
| Publication number | Publication date |
|---|---|
| WO2022238899A1 (en) | 2022-11-17 |
| IT202100012551A1 (it) | 2022-11-14 |
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Effective date: 20231211 |
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