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  • C22C—ALLOYS
  • C22C38/00—Ferrous alloys, e.g. steel alloys
  • C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
  • C22C38/40—Ferrous alloys, e.g. steel alloys containing chromium with nickel
  • C22C38/58—Ferrous alloys, e.g. steel alloys containing chromium with nickel with more than 1.5% by weight of manganese
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  • C22C38/02—Ferrous alloys, e.g. steel alloys containing silicon
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  • C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
  • C21D1/00—General methods or devices for heat treatment, e.g. annealing, hardening, quenching or tempering
  • C21D1/18—Hardening; Quenching with or without subsequent tempering
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  • C21D1/00—General methods or devices for heat treatment, e.g. annealing, hardening, quenching or tempering
  • C21D1/18—Hardening; Quenching with or without subsequent tempering
  • C21D1/19—Hardening; Quenching with or without subsequent tempering by interrupted quenching
  • C21D1/22—Martempering
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  • C21D1/00—General methods or devices for heat treatment, e.g. annealing, hardening, quenching or tempering
  • C21D1/18—Hardening; Quenching with or without subsequent tempering
  • C21D1/25—Hardening, combined with annealing between 300 degrees Celsius and 600 degrees Celsius, i.e. heat refining ("Vergüten")
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  • C21D1/00—General methods or devices for heat treatment, e.g. annealing, hardening, quenching or tempering
  • C21D1/26—Methods of annealing
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  • C21D1/00—General methods or devices for heat treatment, e.g. annealing, hardening, quenching or tempering
  • C21D1/56—General methods or devices for heat treatment, e.g. annealing, hardening, quenching or tempering characterised by the quenching agents
  • C21D1/60—Aqueous agents
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  • C21D6/00—Heat treatment of ferrous alloys
  • C21D6/004—Heat treatment of ferrous alloys containing Cr and Ni
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  • C21D6/00—Heat treatment of ferrous alloys
  • C21D6/008—Heat treatment of ferrous alloys containing Si
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  • C21D8/00—Modifying the physical properties by deformation combined with, or followed by, heat treatment
  • C21D8/02—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips
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  • C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
  • C21D8/00—Modifying the physical properties by deformation combined with, or followed by, heat treatment
  • C21D8/02—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips
  • C21D8/0221—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips characterised by the working steps
  • C21D8/0226—Hot rolling
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  • C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
  • C21D8/00—Modifying the physical properties by deformation combined with, or followed by, heat treatment
  • C21D8/02—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips
  • C21D8/0247—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips characterised by the heat treatment
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  • C21—METALLURGY OF IRON
  • C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
  • C21D8/00—Modifying the physical properties by deformation combined with, or followed by, heat treatment
  • C21D8/02—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips
  • C21D8/0247—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips characterised by the heat treatment
  • C21D8/0263—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips characterised by the heat treatment following hot rolling
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  • C21D8/00—Modifying the physical properties by deformation combined with, or followed by, heat treatment
  • C21D8/02—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips
  • C21D8/0247—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips characterised by the heat treatment
  • C21D8/0273—Final recrystallisation annealing
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  • C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
  • C21D9/00—Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor
  • C21D9/42—Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor for armour plate
• • C—CHEMISTRY; METALLURGY
  • C21—METALLURGY OF IRON
  • C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
  • C21D9/00—Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor
  • C21D9/46—Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor for sheet metals
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  • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
  • C22C—ALLOYS
  • C22C38/00—Ferrous alloys, e.g. steel alloys
  • C22C38/001—Ferrous alloys, e.g. steel alloys containing N
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  • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
  • C22C—ALLOYS
  • C22C38/00—Ferrous alloys, e.g. steel alloys
  • C22C38/002—Ferrous alloys, e.g. steel alloys containing In, Mg, or other elements not provided for in one single group C22C38/001 - C22C38/60
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  • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
  • C22C—ALLOYS
  • C22C38/00—Ferrous alloys, e.g. steel alloys
  • C22C38/04—Ferrous alloys, e.g. steel alloys containing manganese
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  • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
  • C22C—ALLOYS
  • C22C38/00—Ferrous alloys, e.g. steel alloys
  • C22C38/06—Ferrous alloys, e.g. steel alloys containing aluminium
• • C—CHEMISTRY; METALLURGY
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  • C22C—ALLOYS
  • C22C38/00—Ferrous alloys, e.g. steel alloys
  • C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
  • C22C38/34—Ferrous alloys, e.g. steel alloys containing chromium with more than 1.5% by weight of silicon
• • C—CHEMISTRY; METALLURGY
  • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
  • C22C—ALLOYS
  • C22C38/00—Ferrous alloys, e.g. steel alloys
  • C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
  • C22C38/40—Ferrous alloys, e.g. steel alloys containing chromium with nickel
  • C22C38/44—Ferrous alloys, e.g. steel alloys containing chromium with nickel with molybdenum or tungsten
• • C—CHEMISTRY; METALLURGY
  • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
  • C22C—ALLOYS
  • C22C38/00—Ferrous alloys, e.g. steel alloys
  • C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
  • C22C38/40—Ferrous alloys, e.g. steel alloys containing chromium with nickel
  • C22C38/46—Ferrous alloys, e.g. steel alloys containing chromium with nickel with vanadium
• • C—CHEMISTRY; METALLURGY
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  • C22C—ALLOYS
  • C22C38/00—Ferrous alloys, e.g. steel alloys
  • C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
  • C22C38/40—Ferrous alloys, e.g. steel alloys containing chromium with nickel
  • C22C38/48—Ferrous alloys, e.g. steel alloys containing chromium with nickel with niobium or tantalum
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  • C22C—ALLOYS
  • C22C38/00—Ferrous alloys, e.g. steel alloys
  • C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
  • C22C38/40—Ferrous alloys, e.g. steel alloys containing chromium with nickel
  • C22C38/50—Ferrous alloys, e.g. steel alloys containing chromium with nickel with titanium or zirconium
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  • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
  • C22C—ALLOYS
  • C22C38/00—Ferrous alloys, e.g. steel alloys
  • C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
  • C22C38/40—Ferrous alloys, e.g. steel alloys containing chromium with nickel
  • C22C38/54—Ferrous alloys, e.g. steel alloys containing chromium with nickel with boron
• • C—CHEMISTRY; METALLURGY
  • C21—METALLURGY OF IRON
  • C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
  • C21D2211/00—Microstructure comprising significant phases
  • C21D2211/001—Austenite
• • C—CHEMISTRY; METALLURGY
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  • C21D2211/00—Microstructure comprising significant phases
  • C21D2211/008—Martensite

Definitions

• the armored steel may have a thickness of 5 to 20 mm.
• [C] and [Si] refer to contents (weight %) of carbon (C) and silicon (Si) included in the steel slab, and 0 is substituted when the corresponding element is not intentionally added.
• a residence time during the primary heat treatment may be 1.3t * 10 minutes (t: plate thickness (mm)) or more.
• a holding time during the secondary heat treatment may be 1.9t+10 minutes (t: plate thickness (mm)) or more.
• % represents a content of each element based on weight, unless otherwise particularly specified.
• Nitrogen (N) is an element which is favorable to improve strength of steel by forming precipitates in steel, but when a content of nitrogen (N) is more than a certain level, which may rather cause deterioration in toughness of steel.
• an upper limit of a content of nitrogen (N) may be limited to 0.006%. However, 0% may be excluded considering an inevitably contained level.
• an upper limit of the content of molybdenum (Mo) may be limited to 0.5%.
• the upper limit of the content of molybdenum (Mo) may be 0.48%, and more preferably, the upper limit of the content of molybdenum (Mo) may be 0.45%.
• Boron (B) is an element effectively contributing to strength improvement by increasing quenching properties of steel even with a small addition amount thereof.
• 0.0002% or more of boron (B) may be contained.
• a lower limit of a content of boron (B) may be 0.0005%, and more preferably, the lower limit of the content of boron (B) may be 0.001%.
• an upper limit of the content of boron (B) may be limited to 0.005%.
• the upper limit of the content of boron (B) may be 0.004%, and more preferably, the upper limit of the content of boron (B) may be 0.003%.
• Ca an element having a good binding force with sulfur (S) and producing CaS on the periphery (around) MnS, thereby suppressing elongation of MnS to improve toughness in a direction perpendicular to a rolling direction.
• CaS produced by adding Ca has an effect of increasing corrosion resistance under a humid external environment.
• 0.0005% or more of Ca may be included.
• a lower limit of a content of calcium (Ca) may be 0.001%.
• an upper limit of the content of calcium (Ca) may be limited to 0.004%.
• the upper limit of the content of calcium (Ca) may be 0.003%.
• armored steel of the present disclosure may further include the following elements for the purpose of favorably securing target physical properties.
• the armor steel of the present disclosure may further include at least one of titanium (Ti) and vanadium (V).
• V Vanadium (V): 0.2% or less (including 0%)
• the armored steel according to an aspect of the present disclosure may include a remainder of Fe and other inevitable impurities in addition to the components described above.
• the component since in the common manufacturing process, unintended impurities may be inevitably incorporated from raw materials or the surrounding environment, the component may not be excluded. Since these impurities are known to any person skilled in the common manufacturing process, the entire contents thereof are not particularly mentioned in the present specification. In addition, further addition of effective ingredients other than the above-mentioned ingredients is not entirely excluded.
• the inventors of the present disclosure have conducted in-depth research on a method capable of securing high-hardness characteristics and excellent low-temperature impact toughness of a steel sheet at the same time, and have derived that it is effective to control not only a content range of each respective alloy composition, but also a relative content range of the specific alloy composition included in the steel sheet.
• not only the content range of each respective alloy composition included in the steel sheet is controlled to be within a certain range, but also the relative content range of carbon (C) and silicon (Si) is controlled to be within a certain range, as illustrated in [Relational Expression 1], so that high hard characteristics and excellent low-temperature impact toughness may be effectively compatible.
• 10*[C]*[Si] defined by Relational Expression 1 may be 6.0 or more.
• Armored steel of the present disclosure having the alloy composition described above may have a tempered martensite base structure including retained austenite as a microstructure, and may further include other inevitable structures.
• a fraction of retained austenite may be 1% by area to 10% by area
• a fraction of tempered martensite may be 10% or more by area.
• the armored steel of the present disclosure may have the above-described microstructural configuration over the entire thickness.
• the surface hardness refers to an average value of three measurements after milling a surface of the armored steel at 2 mm in a thickness direction using a Brinell hardness tester (load: 3000 kgf, 10 mm tungsten injection port).
• a lower limit of the tempering temperature is not separately specified, but is preferably 100 °C or higher in order to obtain the effect described above. It is preferable to perform tempering, more preferably at a temperature of 125 °C or higher, and even more preferably 150 °C or higher. In the present disclosure, a lower limit of a holding time during the tempering is not particularly limited.
• the hot-rolled steel sheet obtained through the above-described series of manufacturing processes is a steel material having a thickness of 5 to 20 mm, and can provide excellent bullet-proof resistance by securing high hardness and high toughness.
• Cooli ng end tempe ratur e (°C) Cooli ng rate (°C/s ) Heatin 9 temper ature (°C) Holdin g time (min.) 1 A 6 1188 1069 876 900 23 43 67.2 273 32 2 A 12 1164 1045 905 915 28 29 50.1 252 45 3 A 18 1159 1040 923 903 35 30 46.4 225 44 4 B 10 1179 1031 907 904 26 24 53.5 535 40 5 B 15 1146 1025 921 908 31 19 44.2 605 52 6 B 20 1152 1031 930 899 40 35 41.6 315 62 7 C 8 1181 1065 879 912 22 17 60.8 204 37 8 C 10 1168 1053 902 908 24 24 55.1 441 40 9 C 15 1155 1026 933 901 31 25 45.3 217 53 10 D 6 1180 1049 880 905 20 29 70.4 221 35 11 D 10 1163 1026 904 907 23 25 50.9 203 44 12 D 20 1160 1041

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• Crystallography & Structural Chemistry (AREA)
• Heat Treatment Of Steel (AREA)

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• 2020
  • 2020-12-18 KR KR1020200179078A patent/KR102498150B1/ko active Active
• 2021
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  • 2021-11-04 EP EP21906846.7A patent/EP4265791A4/de active Pending

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