EP4235848A3 - Positive electrode active material and lithium ion battery - Google Patents

Positive electrode active material and lithium ion battery Download PDF

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Publication number
EP4235848A3
EP4235848A3 EP23176946.4A EP23176946A EP4235848A3 EP 4235848 A3 EP4235848 A3 EP 4235848A3 EP 23176946 A EP23176946 A EP 23176946A EP 4235848 A3 EP4235848 A3 EP 4235848A3
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EP
European Patent Office
Prior art keywords
particle
active material
ion battery
positive electrode
electrode active
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
EP23176946.4A
Other languages
German (de)
French (fr)
Other versions
EP4235848A2 (en
Inventor
Qiao ZENG
Kefei Wang
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Ningde Amperex Technology Ltd
Original Assignee
Ningde Amperex Technology Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from CN201810123144.4A external-priority patent/CN110120497B/en
Priority claimed from CN201810779137.XA external-priority patent/CN110729477B/en
Application filed by Ningde Amperex Technology Ltd filed Critical Ningde Amperex Technology Ltd
Publication of EP4235848A2 publication Critical patent/EP4235848A2/en
Publication of EP4235848A3 publication Critical patent/EP4235848A3/en
Pending legal-status Critical Current

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    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00Electrodes
    • H01M4/02Electrodes composed of, or comprising, active material
    • H01M4/36Selection of substances as active materials, active masses, active liquids
    • H01M4/362Composites
    • H01M4/364Composites as mixtures
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01GCOMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
    • C01G51/00Compounds of cobalt
    • C01G51/40Complex oxides containing cobalt and at least one other metal element
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01GCOMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
    • C01G51/00Compounds of cobalt
    • C01G51/40Complex oxides containing cobalt and at least one other metal element
    • C01G51/42Complex oxides containing cobalt and at least one other metal element containing alkali metals, e.g. LiCoO2
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01GCOMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
    • C01G51/00Compounds of cobalt
    • C01G51/40Complex oxides containing cobalt and at least one other metal element
    • C01G51/42Complex oxides containing cobalt and at least one other metal element containing alkali metals, e.g. LiCoO2
    • C01G51/44Complex oxides containing cobalt and at least one other metal element containing alkali metals, e.g. LiCoO2 containing manganese
    • C01G51/50Complex oxides containing cobalt and at least one other metal element containing alkali metals, e.g. LiCoO2 containing manganese of the type (MnO2)n-, e.g. Li(CoxMn1-x)O2 or Li(MyCoxMn1-x-y)O2
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01GCOMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
    • C01G53/00Compounds of nickel
    • C01G53/40Complex oxides containing nickel and at least one other metal element
    • C01G53/42Complex oxides containing nickel and at least one other metal element containing alkali metals, e.g. LiNiO2
    • C01G53/44Complex oxides containing nickel and at least one other metal element containing alkali metals, e.g. LiNiO2 containing manganese
    • C01G53/50Complex oxides containing nickel and at least one other metal element containing alkali metals, e.g. LiNiO2 containing manganese of the type (MnO2)n-, e.g. Li(NixMn1-x)O2 or Li(MyNixMn1-x-y)O2
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00Electrodes
    • H01M4/02Electrodes composed of, or comprising, active material
    • H01M4/13Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
    • H01M4/131Electrodes based on mixed oxides or hydroxides, or on mixtures of oxides or hydroxides, e.g. LiCoOx
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00Electrodes
    • H01M4/02Electrodes composed of, or comprising, active material
    • H01M4/36Selection of substances as active materials, active masses, active liquids
    • H01M4/48Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
    • H01M4/485Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of mixed oxides or hydroxides for inserting or intercalating light metals, e.g. LiTi2O4 or LiTi2OxFy
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00Electrodes
    • H01M4/02Electrodes composed of, or comprising, active material
    • H01M4/36Selection of substances as active materials, active masses, active liquids
    • H01M4/48Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
    • H01M4/50Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of manganese
    • H01M4/505Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of manganese of mixed oxides or hydroxides containing manganese for inserting or intercalating light metals, e.g. LiMn2O4 or LiMn2OxFy
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00Electrodes
    • H01M4/02Electrodes composed of, or comprising, active material
    • H01M4/36Selection of substances as active materials, active masses, active liquids
    • H01M4/48Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
    • H01M4/52Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of nickel, cobalt or iron
    • H01M4/525Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of nickel, cobalt or iron of mixed oxides or hydroxides containing iron, cobalt or nickel for inserting or intercalating light metals, e.g. LiNiO2, LiCoO2 or LiCoOxFy
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00Electrodes
    • H01M4/02Electrodes composed of, or comprising, active material
    • H01M4/62Selection of inactive substances as ingredients for active masses, e.g. binders, fillers
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00Electrodes
    • H01M4/02Electrodes composed of, or comprising, active material
    • H01M4/62Selection of inactive substances as ingredients for active masses, e.g. binders, fillers
    • H01M4/628Inhibitors, e.g. gassing inhibitors, corrosion inhibitors
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01PINDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2004/00Particle morphology
    • C01P2004/01Particle morphology depicted by an image
    • C01P2004/03Particle morphology depicted by an image obtained by SEM
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01PINDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2004/00Particle morphology
    • C01P2004/51Particles with a specific particle size distribution
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01PINDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2004/00Particle morphology
    • C01P2004/60Particles characterised by their size
    • C01P2004/61Micrometer sized, i.e. from 1-100 micrometer
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01PINDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2006/00Physical properties of inorganic compounds
    • C01P2006/40Electric properties
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00Secondary cells; Manufacture thereof
    • H01M10/05Accumulators with non-aqueous electrolyte
    • H01M10/052Li-accumulators
    • H01M10/0525Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00Electrodes
    • H01M4/02Electrodes composed of, or comprising, active material
    • H01M2004/021Physical characteristics, e.g. porosity, surface area
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00Electrodes
    • H01M4/02Electrodes composed of, or comprising, active material
    • H01M2004/026Electrodes composed of, or comprising, active material characterised by the polarity
    • H01M2004/028Positive electrodes
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10Energy storage using batteries

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  • Chemical & Material Sciences (AREA)
  • Electrochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Organic Chemistry (AREA)
  • Composite Materials (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Manufacturing & Machinery (AREA)
  • Battery Electrode And Active Subsutance (AREA)
  • Secondary Cells (AREA)
  • Inorganic Compounds Of Heavy Metals (AREA)

Abstract

The present application provides a positive active material, a positive electrode and a lithium-ion battery. The positive active material comprising a first particle and a second particle, wherein the first particle has a chemical formula of LieCogM1-gO2-i, and the second particle has a chemical formula of LifCohN1-hO2-j, the element M is at least two selected from a group consisting of Ni, Mn, Al, Mg, Ti, La, Y and Zr, the element N is at least one selected from a group consisting of Ni, Mn, Al, Mg, Ti, La, Y and Zr, and 0.8≤e≤1.2, 0<g<1, -0.1<i<0.2, 0.8<f<1.2, 0<h<1, -0.1≤j≤0.2, the number of types of the element M in the first particle is greater than the number of types of the element N in the second particles.. The present application stabilizes the first particles and the second particles by adjusting the type and content of the doping elements in the first particle and in the second particle, so that the capacity retention rate of the lithium-ion battery is improved.
EP23176946.4A 2018-02-07 2018-12-21 Positive electrode active material and lithium ion battery Pending EP4235848A3 (en)

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
CN201810123144.4A CN110120497B (en) 2018-02-07 2018-02-07 An active material and lithium-ion battery
CN201810779137.XA CN110729477B (en) 2018-07-16 2018-07-16 Cathode Active Materials and Lithium-Ion Batteries
EP18905006.5A EP3731314B1 (en) 2018-02-07 2018-12-21 Positive electrode active material and lithium ion battery
PCT/CN2018/122758 WO2019153909A1 (en) 2018-02-07 2018-12-21 Positive electrode active material and lithium ion battery

Related Parent Applications (2)

Application Number Title Priority Date Filing Date
EP18905006.5A Division EP3731314B1 (en) 2018-02-07 2018-12-21 Positive electrode active material and lithium ion battery
EP18905006.5A Division-Into EP3731314B1 (en) 2018-02-07 2018-12-21 Positive electrode active material and lithium ion battery

Publications (2)

Publication Number Publication Date
EP4235848A2 EP4235848A2 (en) 2023-08-30
EP4235848A3 true EP4235848A3 (en) 2023-10-04

Family

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Family Applications (2)

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EP23176946.4A Pending EP4235848A3 (en) 2018-02-07 2018-12-21 Positive electrode active material and lithium ion battery
EP18905006.5A Active EP3731314B1 (en) 2018-02-07 2018-12-21 Positive electrode active material and lithium ion battery

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Country Status (6)

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US (2) US20190245199A1 (en)
EP (2) EP4235848A3 (en)
JP (1) JP7059381B2 (en)
CN (2) CN117457872A (en)
CA (1) CA3090720A1 (en)
WO (1) WO2019153909A1 (en)

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JP7397792B2 (en) 2018-06-22 2023-12-13 株式会社半導体エネルギー研究所 Positive electrode active material, positive electrode, secondary battery, and method for producing positive electrode
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CN112467078B (en) * 2020-11-30 2022-06-17 宁德新能源科技有限公司 Electrochemical device and electronic device
CN113745452B (en) * 2021-09-08 2023-06-20 东莞新能安科技有限公司 A kind of electrochemical device and electronic device
WO2023050054A1 (en) * 2021-09-28 2023-04-06 宁德新能源科技有限公司 Electrochemical apparatus, and electric device including electrochemical apparatus
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Also Published As

Publication number Publication date
CA3090720A1 (en) 2019-08-15
WO2019153909A1 (en) 2019-08-15
US12170363B2 (en) 2024-12-17
EP4235848A2 (en) 2023-08-30
JP7059381B2 (en) 2022-04-25
CN117457872A (en) 2024-01-26
JP2021513193A (en) 2021-05-20
US20220336793A1 (en) 2022-10-20
EP3731314A1 (en) 2020-10-28
CN111699576A (en) 2020-09-22
US20190245199A1 (en) 2019-08-08
EP3731314B1 (en) 2023-08-02
EP3731314A4 (en) 2021-04-21

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