EP4200065A1 - Generator of a vortex braid broken up into a system of toroid vortices - Google Patents
Generator of a vortex braid broken up into a system of toroid vorticesInfo
- Publication number
- EP4200065A1 EP4200065A1 EP21718168.4A EP21718168A EP4200065A1 EP 4200065 A1 EP4200065 A1 EP 4200065A1 EP 21718168 A EP21718168 A EP 21718168A EP 4200065 A1 EP4200065 A1 EP 4200065A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- stator
- rotor
- generator
- flow
- notches
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
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Classifications
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- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/34—Treatment of water, waste water, or sewage with mechanical oscillations
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F15—FLUID-PRESSURE ACTUATORS; HYDRAULICS OR PNEUMATICS IN GENERAL
- F15D—FLUID DYNAMICS, i.e. METHODS OR MEANS FOR INFLUENCING THE FLOW OF GASES OR LIQUIDS
- F15D1/00—Influencing flow of fluids
- F15D1/009—Influencing flow of fluids by means of vortex rings
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- B01F25/60—Pump mixers, i.e. mixing within a pump
- B01F25/64—Pump mixers, i.e. mixing within a pump of the centrifugal-pump type, i.e. turbo-mixers
- B01F25/642—Pump mixers, i.e. mixing within a pump of the centrifugal-pump type, i.e. turbo-mixers consisting of a stator-rotor system with intermeshing teeth or cages
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- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
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- B01F27/00—Mixers with rotary stirring devices in fixed receptacles; Kneaders
- B01F27/27—Mixers with stator-rotor systems, e.g. with intermeshing teeth or cylinders or having orifices
- B01F27/271—Mixers with stator-rotor systems, e.g. with intermeshing teeth or cylinders or having orifices with means for moving the materials to be mixed radially between the surfaces of the rotor and the stator
- B01F27/2712—Mixers with stator-rotor systems, e.g. with intermeshing teeth or cylinders or having orifices with means for moving the materials to be mixed radially between the surfaces of the rotor and the stator provided with ribs, ridges or grooves on one surface
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- B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J19/18—Stationary reactors having moving elements inside
- B01J19/1806—Stationary reactors having moving elements inside resulting in a turbulent flow of the reactants, such as in centrifugal-type reactors, or having a high Reynolds-number
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- B01J19/241—Stationary reactors without moving elements inside of the pulsating type
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- B02—CRUSHING, PULVERISING, OR DISINTEGRATING; PREPARATORY TREATMENT OF GRAIN FOR MILLING
- B02C—CRUSHING, PULVERISING, OR DISINTEGRATING IN GENERAL; MILLING GRAIN
- B02C19/00—Other disintegrating devices or methods
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- B03—SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
- B03D—FLOTATION; DIFFERENTIAL SEDIMENTATION
- B03D3/00—Differential sedimentation
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- C02F1/52—Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities
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- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
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- C—CHEMISTRY; METALLURGY
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- C10G9/00—Thermal non-catalytic cracking, in the absence of hydrogen, of hydrocarbon oils
- C10G9/34—Thermal non-catalytic cracking, in the absence of hydrogen, of hydrocarbon oils by direct contact with inert preheated fluids, e.g. with molten metals or salts
- C10G9/36—Thermal non-catalytic cracking, in the absence of hydrogen, of hydrocarbon oils by direct contact with inert preheated fluids, e.g. with molten metals or salts with heated gases or vapours
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- B01F2025/91—Direction of flow or arrangement of feed and discharge openings
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- B01F2025/9121—Radial flow from the center to the circumference, i.e. centrifugal flow
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- B01F25/00—Flow mixers; Mixers for falling materials, e.g. solid particles
- B01F2025/91—Direction of flow or arrangement of feed and discharge openings
- B01F2025/915—Reverse flow, i.e. flow changing substantially 180° in direction
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- C—CHEMISTRY; METALLURGY
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- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2204/00—Structure or properties of graphene
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- C01B2204/28—Solid content in solvents
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- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2204/00—Structure or properties of graphene
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2103/00—Nature of the water, waste water, sewage or sludge to be treated
- C02F2103/08—Seawater, e.g. for desalination
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2103/00—Nature of the water, waste water, sewage or sludge to be treated
- C02F2103/32—Nature of the water, waste water, sewage or sludge to be treated from the food or foodstuff industry, e.g. brewery waste waters
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2103/00—Nature of the water, waste water, sewage or sludge to be treated
- C02F2103/34—Nature of the water, waste water, sewage or sludge to be treated from industrial activities not provided for in groups C02F2103/12 - C02F2103/32
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2301/00—General aspects of water treatment
- C02F2301/02—Fluid flow conditions
- C02F2301/024—Turbulent
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02A—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
- Y02A20/00—Water conservation; Efficient water supply; Efficient water use
- Y02A20/124—Water desalination
Definitions
- the invention relates to a generator for generating toroidal and spatial vortices in a liquid, comprising a substantially rotationally symmetrical stator housing with an axis and an axial inlet opening and an eccentric outlet opening directed in a plane that is oriented normal to the axis, and a rotor rotatably arranged around the axis in the stator housing with radially outwardly extending channels in constant fluid connection to the inlet opening.
- the invention further relates to a method of operation of such a generator and a use of this method.
- the examples cited above presuppose a vortex generator designed as a standalone technical device with the medium fed thereto by an additional dedicated external device.
- the cited devices are not capable of simultaneously processing liquid and gas with a volume ratio of at least 1:1.
- these devices are not capable of processing a liquid and a solid dispersed in such liquid, such as rock cuttings in crude oil, with a mass ratio of at least 2:1.
- the generator comprises by a rotor disc, which is attached to the rotor in a rotationally fixed manner radially outside the rotor, with a side surface normal to the axis.
- This side surface comprises inner notches spaced apart from one another and equidistant from the axis and in constant fluid connection to the rotor channels, for portion and temporarily blocking the liquid.
- the generator comprises a stator disc attached to the stator housing with torque proof connection.
- the stator disc comprises a side surface facing the side surface of the rotor disc.
- stator disc comprises stator notches spaced apart from one another and equidistant from the axis, for providing passages for the liquid to form a periodical liquid flow from the inner notches to the stator notches, when these notches face each other due to rotation of the rotor disc in operation.
- stator notches spaced apart from one another and equidistant from the axis, for providing passages for the liquid to form a periodical liquid flow from the inner notches to the stator notches, when these notches face each other due to rotation of the rotor disc in operation.
- This allows the generation of toroidal vortices in the portioned liquid during use by shear stress as the portions of liquid pass from the inner notches to the stator notches and move back and forth.
- These notches provide passages for the liquid radially passing the stator disc and the rotor disc to the outlet opening, contributing between 70 and 95% of a total liquid flow through the Generator.
- the rotor disc and the stator disc are spaced apart by a gap to allow a permanent liquid flow through that gap from the inner notches to the outlet opening.
- This generates spatial vortices during use in the laminar liquid flow due to the velocity difference of the side surfaces defining the gap, and due to periodical disruptions by the portioned liquid passing the gap in axial direction.
- This laminar liquid flow is contributing between 5% and 30% of the total liquid flow through the generator.
- the side surface of the rotor disc further comprises outer notches radially outside of the inner notches spaced apart from one another and equidistant to the axis, for channelling the periodical liquid flow before it may exit the rotor disc.
- the inventive method operation of such a generator for generating toroidal and spatial vortices in a liquid comprises the steps of bringing a liquid to the inlet opening and bringing the rotor with the rotor disc attached into rotation. Further, a permanent liquid flow and a periodical liquid flow between the stator disc and the rotor disc are produced.
- the capacity of the generator is about 200 mVhour ⁇ 20%.
- the rotation speed between the two discs at their side surfaces is about 180 km/hour.
- the liquid of the constant flow in the gap which is about 1 mm wide, is accelerated in vortex and thereby transformed to small toroids.
- the same is true for the liquid entering the inner notches of the rotor disc, when the next stator notch is not jet opposite this inner notch.
- the liquid is exposed to the same speed of 3000 m/min., while the exit is closed.
- This flow might leave the stator-rotor disc system into a spiral of a guide vane which is arranged radially outside of the stator disc and ends in the outlet opening, or it might further pass through outer notches in the rotor disc before entering the guide vane. If such outer notches are built in the side surface of the rotor ring, then the liquid must again change its direction parallel to the axial direction, which further increases the building of vortex and twists the internal flow vis-a-vis the total flow of its vortex portion.
- a generator (1) for generating toroidal and spatial vortices in a liquid (2) comprising a substantially rotationally symmetrical stator housing (3) with an axis (7) and an axial inlet opening (4) and an eccentric outlet opening (5) directed in a plane (6) that is oriented normal to the axis (7), and a rotor (8) rotatably arranged around the axis (7) in the stator housing (3) with radially outwardly extending channels (9) in constant fluid connection to the inlet opening (4), characterizes by a rotor disc (10), which is attached to the rotor (8) in a rotationally fixed manner radially outside the rotor (8), comprising a side surface (11) of the rotor disc (10) normal to the axis (7) with inner notches (12) spaced apart from one another and equidistant from the axis (7) and in constant fluid connection to the rotor channels (9), for portion and temporarily blocking the liquid (2), as well
- the side surface (11) of the rotor disc (10) may comprise outer notches (13) arranged radially outside of the inner notches (12) spaced apart from one another and equidistant from the axis (7), for further increasing the building of toroid vortices within the periodical liquid flow (19) before it may exit the rotor disc (10).
- the number of the inner notches (12) may equal the number of the outer notches (13).
- the number of the inner notches (12) may equal the number of the stator notches (16).
- the number of notches (12, 13, 16) of each kind may be between 16 and 42.
- the generator (1) may further comprise a guide vane (21) inside the stator housing (3) radially outside the stator disc (14) and the rotor disc (10) for guiding the total liquid flow (20) to the outlet opening (5).
- the rotor (8) may have an outer diameter of 30 cm, ⁇ 20%.
- a method of operation of a generator (1) as aforementioned for generating toroidal and spatial vortices in a liquid (2) by the steps of a) bringing the liquid (2) to the inlet opening (4); b) bringing the rotor (8) with the rotor disc (10) attached into rotation; c) producing a permanent liquid flow (18) and a periodical liquid flow (19) between the stator disc (14) and the rotor disc (10); d) generating toroidal vortices in the portioned liquid (2) of the periodical liquid flow (19) by shear stress as the portions of liquid (2) pass from the inner notches (12) to the stator notches (16) and move back and forth; e) generating spatial vortices in the permanent liquid flow (18) in the gap (17) between the side surfaces (11, 15) due to the velocity difference of the side surfaces (11, 15) and due to periodical disruptions by the portioned liquid (2) passing the gap (17) in axial direction; f) combining the
- the rotor (8) may rotate with 3000 revolutions per minute, ⁇ 20%.
- the capacity of the generator (1) may be about 200 mVhour, ⁇ 20%.
- the liquid (2) brought to the inlet opening (4) may be water with dissolved inorganic salts, such as sea water, and the total liquid flow (20) conducted away from the outlet opening (5) is fresh water with admixed water-soluble crystallised inorganic salts.
- the total liquid flow (20) may be filtered after conducted away from the outlet opening (5) for obtaining fresh water separated from the water-soluble crystallised inorganic salts.
- a generator comprising a notched stator; and a notched rotor arranged to rotate in cooperation with the notched stator to block and open cyclically a plurality of passages for a fluid to form a flow with toroidal vortices.
- the toroidal vortices can provide alternating flow velocities and alternating pressures in a fluid.
- a pressure in the generator may be between 8 and 12 atmosphere (between 0.81 MPa and 1.216 MPa).
- An average pressure in the flow generated by the generator may be between 8 and 12 atmosphere (between 0.81 MPa and 1.216 MPa).
- a pressure in the fluid outside a toroid vortex may be between 8 and 12 atmosphere (between 0.81 MPa and 1.216 MPa).
- the flow may comprise local pressures of at least 10 MPa, preferably at least 25 MPa, further preferably at least 50 MPa.
- the flow may comprise local pressures of up to 1 mPa, preferably up to 0.1 mPa, further preferably up to 0.01 mPa.
- the flow may comprise local velocities of at least 100 meters per second, preferably at least 150 meters per second, further preferably at least 200 meters per second.
- the flow may comprise local velocities of 200-400 meters per second.
- the flow may comprise local velocities of 2-4 meters per second.
- the peripheral flow velocity in a toroidal vortex may be greater than the flow velocity in the fluid outside the toroidal vortex by a factor of at least 10, preferably by a factor of at least 16, further preferably by a factor of at least 20.
- the flow may comprise high-frequency alternating flow velocities.
- the flow may comprise high-frequency alternating pressures.
- the flow may comprise alternating flow velocities produced at a frequency of at least 500 Hz, preferably 1000 Hz, further preferably 3000 Hz.
- the flow may comprise alternating pressures produced at a frequency of at least 500 Hz, preferably at least 1000 Hz, further preferably at least 2000 Hz.
- the flow may comprise high-frequency alternating flow velocities and/or high-frequency alternating pressures produced at a frequency of 600 to 2500 Hz or 640 to 2520 Hz.
- the toroidal vortices may have a typical diameter of at least 10 pm, preferably at least 20 pm, further preferably at least 40 pm.
- the flow may include at least 150, preferably at least 200, further preferably at least 500 toroidal vortices per litre of fluid.
- the flow may include 200 to 3000 toroidal vortices per litre of fluid or 190- 2940 toroidal vortices per litre of fluid.
- the liquid is changing its characteristics. For example, demineralization of aquatic salt solutions and concentration of inorganic salts extracted from aquatic salt solutions can be achieved, if sea water is brought to the inlet opening. All nonorganic salts get crystallized in the generator in operation. By filtering the water immediately after it exits the generator, fresh water is separated from most of the salt and minerals. Further examples of the application of the said generator include the low-temperature cracking in the context of processing crude oil feedstocks, mixing, dispersing, emulsifying, suspending, homogenizing, and dissolving.
- the invention can be used in petroleum, refining, petrochemical, pharmaceutical, chemical, food processing, and construction industries. Further it can be used in the water treatment in power generation and in the food processing, in the energy sector in the water steam production, in industries for production of fresh potable and non- potable water, for production of monomolecular layers as graphene in dispersing solids whereby the solids are split along flat parallel layers; in the nuclear power sector to treat contaminated effluents while producing concentrated isotopes of radioactive materials and fresh non-potable water, in the wastewater treatment sector to treat industrial and household effluents in order to remove dissolved inorganic salts and to obtain purified water plus dry inorganic salts, as well as in the treatment of sea and ocean water to remove water-soluble minerals and the concentration of such removed water-soluble inorganic salt.
- Fig. 1 a cross sectional view of a generator
- Fig. 2 a perspective view of a rotor disc
- Fig. 3 a perspective view of a stator disc
- Fig. 4 a perspective drawing of the permanent flow
- Fig. 5 a perspective drawing of the periodical flow
- FIG. 6 sectional and plan view schematic of flows when a stator notch is aligned with a rotor notch
- FIG. 7 sectional and plan view schematic of flows when a rotor notch has no overlap with a stator notch
- FIG. 8 sectional and plan view schematic of flows when a stator notch has no overlap with a rotor notch
- Fig. 9 a cross sectional view of a portion of the generator of Fig. 1;
- Fig. 10 a cross sectional view along the section A-A of Fig. 6a;
- Fig. 11 a cross sectional view of a generator with outlet duct
- Fig. 12 a perspective drawing indicating different notch dimensions
- Fig. 13a, 13b and 13c graphs of local flow velocity, acceleration and absolute pressure in flow in a generator during different phases of operation
- Fig. 14 a photo of an evolving toroid
- Fig. 15 a photo of a fully formed toroid
- Fig. 16 a cross sectional side view of a generator with a nozzle
- Fig. 17 a cross sectional front view of the generator with a nozzle of Fig. 17;
- Fig. 18 a cross sectional side view of a generator with a nozzle
- Fig. 19 a schematic illustration of another rotor ring
- Fig. 20 a perspective drawing of flows with the rotor ring of Fig. 19;
- Fig. 21a a schematic view of another rotor ring
- FIG. 21b another view of the rotor ring of Fig. 21a;
- Fig. 22 a perspective drawing of another rotor ring and stator ring; and Fig. 23 a schematic illustration of an alternative generator with axial flow.
- Figure 1 shows a cross sectional view of a generator 1 for generating toroidal and spatial vortices in a liquid 2.
- spatial vortex is used to distinguish non-toroid vortices from toroid vortices, and includes vortices where the axis of rotation does not form a closed loop (e.g. tubular vortices, cone-shaped vortices).
- the generator 1 comprises: a substantially rotationally symmetrical stator housing 3, symmetrical about axis 7; an axial inlet opening 4; an eccentric outlet opening 5 directed in a plane 6 that is oriented normal to the axis 7; and a rotor 8 rotatably arranged around the axis 7 in the stator housing 3, the rotor 8 comprising radially outwardly extending channels 9 in constant fluid connection to the inlet opening 4.
- the rotor 8 has an outer diameter of about 30 cm, ⁇ 20%.
- the generator further comprises a rotor disc 10 (also referred to as a rotor ring) and a stator disc 14 (also referred to as a stator ring) rotatable about axis 7.
- Figures 2 and 3 illustrate a perspective view of a rotor disc 10 and a stator disc 14 of a generator 1 respectively.
- Inner notches 12 are arranged periodically about the rotor disc 10, and notches 16 are arranged periodically about the stator disc 14.
- the rotor disc 10 as shown in Figure 2 is attached to the rotor 8 in a rotationally fixed manner radially outside the rotor 8.
- the rotor disc 10 comprises a side surface 11 normal to the axis 7 with inner notches 12 spaced apart from one another and equidistant from the axis 7, for channelling the liquid 2.
- the rotor disc 10 may also comprise outer notches 13 on the same surface 11 as the inner notches 12. These outer notches 13 are also spaced apart from one another and equidistant from the axis 7. It should be appreciated that the rotor disc 10 may be provided as a separate part that is distinct from the rotor 8, or it may equally be provided as an integral feature or portion of the rotor 8.
- the stator disc 14, shown in Figure 3, is attached with torque proof connection to the stator housing 3. It comprises a side surface 15 for facing the side surface 11 of the rotor disc 10 and stator notches 16 spaced apart from one another and equidistant from the axis 7. They provide passages for the liquid 2 to form a periodical liquid flow 19 from the inner notches 12 to the stator notches 16. It should be appreciated that the stator disc 14 may be provided as a separate part that is distinct from the stator housing 3, or it may equally be provided as an integral feature or portion of the stator housing 14.
- the notches 12, 13, 16 do not need to be arranged equidistant from one another on the respective discs 10, 14, but it is preferred.
- the number of the inner notches 12 may equals the number of the outer notches 13 and/or the number of the stator notches 16. This is the case in Figures 2 and 3.
- Figures 4 and 5 illustrate perspective views of a permanent flow 18 and a periodic flow 19 generated by conditions in a generator 1 respectively.
- Figures 4 and 5 illustrate how the conditions change as the rotor disc 10 and the stator disc 14 move relative to one another.
- a permanent flow 18 flows in a direction illustrated by arrows in Figure 4 and flows perpendicular to a periodic flow 19 illustrated by an arrow in Figure 5. Manipulation of these flows helps to create toroid vortices in the liquid 2.
- a permanent liquid flow 18 between the discs 10, 14 flows between the flat parallel side surface 11, 15 of rotor disc 10 and stator disc 14 and moves in a constant radial direction, independent of the positioning of the notches 12, 16.
- the rotor disc 10 and the stator disc 14 are spaced apart by a gap 17.
- This gap allows a liquid flow, defined as the permanent liquid flow 18, through that gap 17 from the inner notches 12 to the outlet opening 5.
- the gap 17 is for generating spatial vortices during use in the laminar liquid 2 flow due to the velocity difference of the side surfaces 11, 15 defining the gap 17, and due to periodical disruptions by the portioned liquid 2 passing the gap 17 in axial direction from the center of the discs outward as illustrated by arrows 18 in Figure 4.
- This permanent liquid flow 18 contributes between 5% and 30% of the total liquid flow 20 through the generator 1 depending on the size of the gap 17.
- the gap 17 between the rotor disc 10 and stator disc 14 is between 0.8 mm and 1.2 mm wide. In other examples the gap 17 between the rotor disc 10 and stator disc 14 is between 1 mm and 1.8 mm wide.
- This permanent liquid flow 18 is independent of the actual position of the rotor disc 14.
- Inner and outer notches 12, 13 of the rotor disc 10 and stator notches 16 of the stator disc 14 provide volumes in which to form a periodic liquid flow 19 of liquid 2.
- the periodic liquid flow 19 flows between the inner notches 12 and the stator notches 16 as illustrated, for example, in Figure 5.
- the liquid 2 flows from the inner notches 12 to the stator notches 16, forming the periodic flow 19.
- Portions of liquid 2 pass back and forth from the inner notches 12 to the stator notches 16 caused by a change in volume as the rotor 8 rotates and the notches 12, 13, 16 successively align and misalign with each other.
- the periodic flow 19 helps to generate toroid vortices in the portioned liquid 2 by shear stress.
- Liquid 2 leaves the rotor 8 to enter the inner notches 12 of rotor disc 10 when it comes opposite the stator notch 16 of stator disc 14; it has roughly the same linear peripheral speed up until the rotor disc 10 rotates aside and comes opposite the enclosed space between the notches 12, 13, 16. At that point, the passage for liquid 2 to exit the chamber of the rotor disc groove would close off. This would produce a pressure spike in the inner notch 12 of rotor disc 10 until an exit for the liquid 2 opens up and the liquid 2 is able to flow into the stator notch 16 formed in the stator disc 14.
- Figure 4 illustrates the case after the closure point of the flow from an inner notch 12 to a stator notch 16.
- the periodical flow 19 becomes further accelerated; a portion of the flow turns 180° and begins to move in the opposite direction to the principal flow within the inner notches 12, taking the shape of a twisted flow and forming a stable vortex braid 22 along the full length of the inner notches 12, which partially enters the stator notch 16.
- each stator notch 16 is filled with a screw-like vortex braid that, once the total flow of liquid reverses its direction 180°, breaks up into portions, generating similar toroid vortices.
- the time period when the stator notches 16 are fully open, and fully aligned with the inner notches 12, is very brief, as the rotor disc 10 rotates at around 3000 revolutions per minute (50 revolutions per second).
- the number of revolutions per minute (the impeller rotation speed) can be adjusted to achieve variations in pressure experienced by the liquid 2.
- the rotor’s continued rotation tightens the spaces for the vortex braid, as the inner notches 12 gradually close. This promotes continued breakup of the vortex braid into toroid vortices.
- stator notches 16 are closed off from the inner notches 12 again. Once the stator notches 16 fully close, the entire process repeats, submitting the liquid 2 to high frequency alternating flow velocities and pressures. Rotation of the rotor ring creates a suction effect and draws fluid in.
- the generator 1 can be used for generating toroidal and spatial vortices in a liquid 2, by the steps of bringing the liquid 2 to the inlet opening 4, bringing the rotor 8 with the rotor disc 10 attached into rotation, and producing a permanent liquid flow 18 and a periodical liquid flow 19 between the stator disc 14 and the rotor disc 10.
- toroidal vortices are generated by shear stress as the portions of liquid 2 pass from the inner notches 12 to the stator notches 16 and move back and forth. Further, spatial vortices are generated in the permanent liquid flow 18 in the gap 17 between the side surfaces 11, 15 due to the velocity difference of the side surfaces 11, 15 and due to periodical disruptions by the portioned liquid 2 passing the gap 17 in axial direction.
- the rotor 8 rotates with 3000 revolutions per minute, ⁇ 20% and the capacity of the generator 1 is about 200 Vhour, ⁇ 20%.
- the capacity of the generator 1 is about 200 Vhour, ⁇ 20%.
- Figures 6, 7 and 8 illustrate the flows between the stator disc 10 and the rotor disc 14 in different configurations in more detail.
- Figure 6 shows the flows when a stator notch is aligned with a rotor notch, in sectional and plan views.
- Figure 7 shows the flows when a rotor notch has no overlap with a stator notch, in sectional and plan views.
- Figure 8 shows the flows when a stator notch has no overlap with an inner rotor notch, in sectional and plan views.
- the configuration shown in Figure 8 it can be seen that in the sections between inner rotor notches fluid is blocked from entering the gap between rotor ring and stator ring. Liquid flow can only exit via an inner rotor notch, as illustrated in Figures 6 and 7.
- Figure 6 shows a number of vortices being formed in the periodic flow 19 due to shear along the various notch surfaces of the rotor and stator rings.
- the flow can enter the outer rotor notch 13 but in other examples the outer rotor notch 13 is omitted and the flow is redirected out of the stator notch 14.
- the notches provide curved surfaces to redirect the flow in the inner rotor notches 12 by approximately 60-90°, and also to redirect the flow in the stator notches 14 by 60-120° or by approximately 60-90° depending on whether or not outer rotor notches 13 are provided. As the flow moves through the notches a number of toroid vortices are formed perpendicular to the liquid flow. The redirections in the notches cause flow shearing and produce vortex zones within the notches.
- Figure 7 shows the permanent liquid flow 18 between the discs 10, 14 that gets squeezed up between the flat parallel side surface 11, 15 of rotor disc 10 and stator disc 14 and moves radially.
- the permanent liquid flow 18 is affected by shear stresses the rotor disc 10 generates as it moves vis-a-vis the stator disc 14.
- the outer notches 12 continuously disrupt the linear nature of the inter-disc flow 18 and generates spatial vortices therein.
- the permanent liquid flow 18 is further disturbed by vortex flows as the inner notches 12 start to line up with the stator notches 16 and provide a flow path that passes from the inner notches 12 to the stator notches 16 perpendicular to that permanent liquid flow 18.
- a conical funnel-shaped spatial vortex forms at a rotor ring notch as the stator ring blocks the periodic flow 19.
- the inner notch 12 is closed off, the outside portion of the vortex braid produces a maximum diameter funnel and unfolds towards the rotor ring entrance.
- toroidal vortices As those spatial vortices come in contact with toroidal vortices, first from the inner notches 12 and then from the stator notches 16, they morph into yet smaller and more intense toroid vortices and, along with toroid vortices from the stator disc notches 12, are dispersed in total flow 20 and carried out into a discharge system. Alternating flow velocities may be produced in the total flow 20 at a frequency of at least 500 Hz, for example. Alternating pressures may also be produced in the total flow 20 at a frequency of at least 500 Hz, for example.
- the flow area of the permanent liquid flow 18 via the gap 17 is much smaller than the flow area of the periodic liquid flow 19 via the stator notches. Under rotation the flow conditions change very quickly, at high frequency, with large changes in both flow velocity and in flow direction. These effects contribute to the development of a highly turbulent flow which produces a sizable number of toroidal vortices that persist in the flow downstream of the stator disc and rotor disc.
- the generator 2 may optionally comprise guide vanes 21 inside the stator housing 3 radially outside the stator disc 14 and rotor disc 10 for guiding a total liquid flow 20 to the eccentric outlet opening 5. Passages 23 radially outside of the stator disc 14 to the outlet opening 5 are provided by the spiral guide vanes 21, with blades bent in the opposite direction to the impeller blades. At the nearest point to the rotor and stator discs the guide vanes leave only a very small gap.
- Figures 9 and 10 show the vanes 21 arranged in the stator housing 3 providing passages 23 for the flow downstream of the stator disc 14 and rotor disc 10.
- Figure 11 shows the guide vanes 21 feeding into the pump’s spiral discharge duct 24 leading to the outlet opening 5, as is well known in the art.
- the liquid exiting the stator disc 14 and rotor disc 10 passes through the passages 23 between the evenly spaced guide vanes 21 to enter the pump’s spiral discharge duct 24 and exits the generator via the outlet opening 5.
- the guide vanes 21 are intended to reduce the velocity of liquid exiting the stator disc 14 and rotor disc 10.
- the stream’s kinetic energy is partially converted into pressure energy, with the pressure at the guide vane exit greater than the pressure at the entry thereto.
- the vanes can be optimized to meet specific desired operating parameters for a pump.
- the vanes can promote vortices staying intact downstream of the rotor/stator discs, for up to 3 to 5 meters within the discharge pipeline.
- the liquid 2 brought to the inlet opening 4 can be water with dissolved inorganic salts, such as sea water, and the total liquid flow 20 conducted away from the outlet opening 5 is fresh water with admixed water-soluble crystallised inorganic salts.
- the total liquid flow 20 must be filtered after conducted away from the outlet opening 5 for obtaining fresh water separated from the water-soluble crystallised inorganic salts.
- the liquid 2 brought to the inlet opening 4 may be fuel oil with 3- 5% sulphur an up to 3% water
- the total liquid flow 20 conducted away from the outlet opening 5 is fuel oil with 0.3-0.5% sulphur, up to 5% colloidal sulphur and up to 1% liquid hydrocarbon.
- the total liquid flow 20 is filtered after conducted away from the outlet opening 5 for obtaining fuel oil separated from colloidal sulphur.
- the method can be used in one of the following industries, to name a few: In petroleum, refining, petrochemical, pharmaceutical, chemical, food processing, and construction industries; in the water treatment in power generation and in the food processing; in the energy sector in the water steam production; in industries for production of fresh potable and non-potable water; for production of monomolecular layers as graphene in dispersing solids whereby the solids are split along flat parallel layers; in the nuclear power sector to treat contaminated effluents while producing concentrated isotopes of radioactive materials and fresh non-potable water; in the wastewater treatment sector to treat industrial and household effluents in order to remove dissolved inorganic salts and to obtain purified water plus dry inorganic salts; in the treatment of sea and ocean water to remove water-soluble minerals, and the concentration of such removed water-soluble inorganic salt.
- industries to name a few: In petroleum, refining, petrochemical, pharmaceutical, chemical, food processing, and construction industries; in the water treatment in power generation and in the
- N p 18 Rotor inner notch width
- h p 0.025 m Rotor inner notch height
- L p 0.015 m Rotor inner notch depth
- a p 0.025 m Stator ring parameters:
- n c 18 Stator notch width
- h c 0.025 m Stator notch height
- L c 0.020 m Stator notch depth
- a c 0.020 m
- An actual petroleum pump can be modified to provide a generator by installing a rotor disc and stator disc.
- the dimensions and configurations of the rotor disc and stator disc are consistent with the objective of forming a flow with toroid vortices.
- the outer diameter of the rotor and stator discs can be made to match the outer diameter of the pump’s impeller such that the modified impeller with the rotor disc can be installed in the pump housing.
- rotor 8 and rotor disc 10 While in operation, rotor 8 and rotor disc 10 fixedly attached thereto rotate at some 3000 revolutions per minute +/- 20%; the rotor disc’s outer diameter ranges from 0.25 to 0.40 meter +/- 20%. Its linear peripheral speed averages 47-125.7 meters per second or 170-450 kilometers per hour. In case of such device with a rotor disc 10 of 0.3-meter outer diameter, its linear peripheral speed would amount to 94 meters per second or 340 kilometers per hour.
- Figures 13a, 13b and 13c show graphs of local flow velocity, acceleration and absolute pressure in flow in an exemplary generator during different phases of operation.
- the notch 12 is in its closed configuration (with only flow through the gap 17) for 0.00064 second.
- the notch 12 remains in its open configuration (fully or partially lined up with a stator notch) for 0.00046 second.
- the forces that develop in the process produce pressure in a portion of liquid flow, which varies from 500 bar (50 Megapascal MPa or 510 atmosphere atm) overpressure to 0.1 bar (0.01 MPa) vacuum over a period of 0.00046 seconds. In a 0.000092 second timespan the pressure drops from 500 bar (50 MPa) overpressure to 0.7 bar (0.07 MPa) vacuum.
- Such rapid pressure changes, from overpressure to vacuum and back, can be very effective at flaking particles that may be in the flow along stress lines and structural defects.
- the maximum local pressure in a toroid vortex may reach 200-400 kg/cm 2 (around 20-40 MPa) and flow velocity change per unit of time (acceleration) is 50,000 G (around 490,000 m/sec 2 ).
- Peripheral liquid flow velocity in a toroid vortex is greater than that of the fluid outside the toroid vortex.
- peripheral flow velocity in a toroid vertex may be between 5 and 10 times that of the flow velocity outside the toroid vertex.
- Peripheral flow velocities of liquid flow in a toroid vortex may be at least 100 m/s, for example, 200 m/s to 400 m/s.
- Pressure of a toroid vortex may also be greater than the pressure in the fluid outside the toroid vortex. Local pressures of at least 500 kPa may be achieved.
- the vortex braid generation process is near enough continuous to be effectively continuous.
- the spatial vortexes formed in the chamber comprised by rotor ring notches and stator ring notches may be deemed stable, and their number deemed consistent with the number of notches, i.e., 12 to 48; in their turn, the spatial vortexes produce a large number of smaller toroid vortexes with a typical torus diameter of 20-40 micrometers.
- the vortex braid breaks down into toroid vortexes typically ranging from 20 to 40 micrometers in diameter. Larger and smaller toroid vortexes are present as well, but in lower numbers.
- toroid vortexes As the toroid vortexes travel in the flow they gradually dissipate and shrink. In an example at a distance of 3 meters from the outlet port of the generator 20-40 micrometer vortexes are still found in the pipeline. At that point smaller vortexes may have dissipated and may not be observed, whereas larger vortexes may have split into smaller ones and coincide in the 20-40 micrometer size.
- the rotor ring rotates at 40-60 Hz and has 16-42 notches to generate toroid vortices at 640 to 2520Hz. In this example 256-1764 vortices are produced per revolution.
- the generator throughput is about 160-240 m 3 /hour, a density of around 190-3000 primary vortices may be generated per litre of fluid.
- Figure 14 shows a photo of an evolving toroid and Figure. 15 a photo of a fully formed toroid.
- the photo was made using a confocal laser scanning microscope. Its approximate transverse resolution is 0.2-0.5 pm.
- the frame size is 2 ⁇ 00 dots per frame, 400 pm - 1 cm.
- the approximate resolution along the Z axis is 0.3 pm.
- the photos show toroidal features with a diameter of around 20-40 micrometers. It is calculated that around its outer diameter, such a liquid toroid vortex registers peripheral speeds of 200-400 meters per second while staying in the stream of that same liquid that moves at 2-4 meters per second.
- vacuum distillation tower residue from an oil refinery (with a softening point of +32 °C and a flash point of +328 °C) was provided at atmospheric pressure and fed to a generator as described above.
- the vacuum distillation tower residue was provided to a bitumen production column using the generator at a process temperature of +200 °C and at atmospheric pressure, and the ambient temperature was -15 °C.
- Bitumen so obtained and featuring a softening point of +48 °C, and a flash point of +326 °C was chosen for examination due to its high viscosity so as to preserve the altered internal structure throughout the freeze period.
- the product was flowed via a pipeline with 12 mm internal diameter into air cooler, then into a water cooler, and then into a liquid nitrogen tank of 50-liter capacity for immediate freezing. After a portion of frozen bitumen was obtained in the tank, the portion was held in the tank for 1 hour under liquid nitrogen, whereupon a frozen sample of finished product was extracted from the tank.
- the sample constituted a glassy black mass in the form of a cylinder. It was chipped, in the frozen state, to form flat surfaces for examination using the method described above. Visually, the sample presented a smooth black glossy surface; examination under confocal laser scanning microscope revealed the internal structure seen in Figures 14 and 15.
- the sample obtained using the generator and frozen as described above was evaluated further after examination and producing the images seen in Figures 14 and 15.
- the product was reheated to 90°C, held under such temperature until liquid, was re-frozen again in liquid nitrogen and examined for its internal structure. In this case, its internal structure revealed no difference compared to the reference sample.
- the generator 1 is capable of processing a liquid 2 and a solid dispersed in such liquid (e.g., rock cuttings in crude oil) with a mass ratio of at least 2:1.
- the generator 1 is also capable of processing liquids with kinematic viscosity in excess of 400 mm 2 /sec.
- a nozzle is included in a generator in order to introduce a second fluid into the primary flow.
- a second fluid for example air or water vapour or other gases, or a fluid that is heterogenous in respect to the primary flow, or a dispersion of a solid in a liquid, or a flowable solid such a powder can by introduced into the primary flow by way of the nozzle.
- Figures 16 and 17 show an example of a nozzle 27 in a generator otherwise as described with reference to figures 1-15.
- liquid enters the generator 1 at the inlet of the generator.
- Gas e.g. air
- the nozzle serves to deliver gas (or other fluids) to the generator such that the gas contacts liquid as the latter leaves the stator and rotor ring structures.
- the end of the nozzle 27 that delivers gas to the flow is situated in proximity to the rotor ring 10 and stator ring 14 assembly such that gas leaving the nozzle 27 contacts liquid as it leaves the rotor ring 10 and stator ring 114 assembly.
- Nozzles of various design and configuration may be used. Movement of the rotor ring’s upper portion creates suction within the generator, which draws fluid through the nozzle 27 and into the fluid flow.
- the nozzle 27 passes through a guide vane 21; the nozzle 27 functions independent of the guide vane 21 and the nozzle can be provided in the absence of a guide vane.
- one nozzle is provided on the circumference of the rotor/stator ring assembly. In other examples two or more nozzles are distributed around the circumference of the rotor/stator ring assembly.
- the diameter of the nozzle outlet is less than the width of an outer notch of the rotor ring.
- the centre of the nozzle outlet is aligned with the centre of the outer notches of the rotor ring.
- the nozzle outlet is located 2-3 mm from the outer surface of the rotor ring to enable this suction effect to act on the water vapour in the nozzle. Movement of the rotor ring’s upper portion creates a vacuum zone of 0.2-0.6 atm, which ensures continuous suction of gas into the flow.
- Figure 18 illustrates another configuration of a nozzle 27, with an angled outlet plane.
- Figure 18 also indicates two speeds at different positions in the housing outside the rotor/stator rings: vi outside the rotor ring but prior to the nozzle, and V2 between the nozzle outlet and the rotor ring.
- vi 10 m/sec
- V2 133 m/sec.
- the different flow speeds give rise to the Venturi effect, and the zone in the gap between the nozzle outlet and the rotor ring is at a relatively lower pressure, causing entrainment of the gas from the nozzle into the flow.
- the outer surface of the rotor ring moves at a greater speed than vi.
- vortexes are generated and destroyed within the stator ring notches and outer rotor notches with high intensity. This too can cause a low-pressure zone near the nozzle, similar to a vortex pump with the rotor ring acting as a vortex impeller; the rotation of the rotor also assists in drawing gas from the nozzle into the flow.
- water from the depth of 5 to 8 meters could be lifted through the nozzle thanks to a vacuum of about 200-500 mm Hg or about 50-80 kPa at the nozzle outlet, which is generated by the synergy between the Venturi effect and the operation of the rotor ring notches.
- gas is provided (or, equivalently “injected”) at a pressure below the average pressure of the liquid flow at the nozzle outlet, to prevent disruption of the flow produced by the generator and to prevent formation of gas bubbles in the liquid stream.
- the nozzle delivers gas (or other fluid) to the flow and permit gas (or other fluid) to be drawn into and interact with the flow.
- a rotor and stator ring are formed of a steel, for example a stainless steel that comprises from 17% to 19% by weight chromium, from 9% to 11% by weight nickel, 0.8% by weight titanium, 1.5% by weight manganese and 0.03% by weight copper.
- a stainless steel comprises following composition:
- a toroid vortex dispersion can similarly be created at lower or higher RPM provided the rotor’s diameter is suitably increased or decreased.
- RPM revolutions per minute
- a suitable rotor rotation speed is around 2000 revolutions per minute.
- a suitable rotor rotation speed is around 1000 revolutions per minute.
- the peripheral speed (tangential speed) of the rotating rotor, at the rotor disc is around 47 m/sec.
- the peripheral speed of the rotor, at the rotor disc is preferably 30 m/sec or more.
- a peripheral speed in the range from 20-29 m/sec is borderline and may be unstable or ineffective, though it may permit formation of a toroid vortex dispersion.
- a peripheral speed in the range from 15-19 m/sec may in some configurations (e.g. in otherwise particularly effective configurations) permit formation of a toroid vortex dispersion.
- the inner notches 12 and the outer notches 13 of the rotor ring 8 are aligned with one another, e.g. as seen in Figures 5 and 10; in others they are not aligned, e.g. as seen in Figure 2, or some are aligned and others are not.
- the inner notches and the outer notches of the rotor ring have the same or similar widths; in other examples the inner notches and the outer notches of the rotor ring do not have the same widths, e.g. as seen in Figure 10 where the inner notches are narrow than the outer notches.
- Figure 19 shows another arrangement of notches that is observed to be particularly effective at creating a flow of toroid vortexes.
- Figure 20 illustrates the rotor ring of Figure 19 with a stator ring 14 in a generator. In this rotor ring 10, one outer notch 13 spans two inner notches 12. In the stator ring 14 the stator notches 16 are such that a stator notch 16 spans two inner notches 12. A stator notch 16 may be same or similar width as an outer rotor notch 13.
- Figure 20 illustrates some flow paths in the generator with the rotor ring 10 of Figure 19. Flow from a pair of inner notches 12 of the rotor ring 10 is directed to a common rotor notch 16 of rotor ring 14.
- Each inner notch 12 is formed to channel liquid at an angle to its neighboring notch, such that a pair of inner notches 12 that face the same outer notch 13 channel fluid toward a common area.
- the central flow axes of a pair of inner notches are at a converging angle to one another; the angle is such that a point of intersection of the two flow axis is inside the volume of the notch of the stator ring, as illustrated in Figure 20.
- Movement of the rotor ring 10 is now considered, starting from when two inner rotor notches 12 of the rotor ring 10 are fully aligned with a stator notch 16 of the stator ring 16, as seen in Figure 20.
- one of the pair of inner notches remains fully open, while the other of the pair of inner notches becomes partially closed.
- the flow speed via the partially obstructed inner notch is significantly higher than the flow speed via the fully open inner notch.
- the two flows interact in the stator notch. The presence of an angle between these flows causes the faster flow to accelerate the slower flow.
- stator notches spanning two inner notches so as to conmingle the periodic flows from two inner notches in a stator notch.
- a stator notch need not span exactly two inner notches; it may for example be sized to span more, or less, than two inner notches.
- one stator notch spans one inner notch as illustrated in e.g. Figures 2 and 3, but the outer notches 16 are sized so as to span two stator notches. In this way the periodic flow from two stator notches is conmingled in an outer notch. Flow interactions are promoted, and the number of toroid vortices generated is increased.
- Figures 21a and 21b show plan and front view schematics of outer rotor notches 13 with a bottleneck design.
- the outer notches of the rotor ring have parallel side walls, as seen e.g. in Figure 7.
- the exit section of the outer notches 13 of the rotor ring 10 may be formed to provide channels that are progressively narrower and with smaller flow area and that resemble a bottleneck. The liquid is compressed as it moves along these channels. Flow speeds are increased as are flow interactions, and the number of toroid vortices generated is increased.
- Figure 22 shows a variant where the rotor ring 10 does not provide outer notches.
- the outside part of the rotor ring constitutes an outer surface 28 shaped like a carved-out toroid with a certain curvature; the cross section of the outer surface 28 is same as or similar to the cross section of an outer notch, such that the outer surface 28 can provide a redirection of the flow similar to the outer notches as described above.
- the stator 14 includes prongs 29 between the stator notches 16 that project toward the outer surface 28 of the rotor ring 10.
- the gap 17 between the opposing side surfaces of the rotor disc and stator disc extends further between the prongs 29 and the outer surface 28 of the rotor, to permit movement of liquid along the outer surface 28 of the stator ring 10 and provide a passage via the gap 17 for a permanent liquid flow.
- the prongs 29 also form a notch-like channel for fluid to pass between the prongs 29 after exiting the stator notches, similar to the outer rotor notches in the other variants.
- Figure 23 provides a schematic illustration of an alternative generator with a rotor disc and a stator disc adapted for axial flow, rather than radial flow, with an axial flow impeller 27 instead of a radial flow impeller as described above.
- stator ring 26 is arranged concentrically outside the rotor ring 25 with a gap between the inner cylindrical surface of the stator ring 26 and the outer cylindrical surface of the rotor ring 25.
- the rotor ring 25 has inner rotor notches on a flow-facing side such that flow from the impeller can enter the inner rotor notches.
- the stator ring 26 has stator notches arranged on its inner cylindrical surface, facing the rotor ring. The flow is redirected by the inner rotor notches toward the stator ring, either entering the gap between the rings (in the configuration illustrated in the lower half of the cross section in Figure 23) or entering a stator notch (in the configuration illustrated in the upper half of the cross section in Figure 23).
- the stator notches redirect the fluid further.
- the flow entering the inner rotor notches has a tangential velocity (tangential to the rotational motion of the rotor) of e.g. at least 15-25 m/sec.
- Suitable guide vanes can be provided upstream of the rotor ring, to ensure that the flow entering the inner rotor notches has a suitable tangential velocity, while ensuring that the generator creates a pressure of at least 5 to 7 atmospheres (506-709 kPa).
- the rotor ring causes such a tangential velocity component to be produced in the flow, which can result in a relevant loss of energy and less efficient formation of toroidal vortices.
- stator ring (axial flow variant)
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Abstract
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Applications Claiming Priority (7)
Application Number | Priority Date | Filing Date | Title |
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GB2013075.3A GB2593241B (en) | 2020-03-16 | 2020-08-21 | Separation method and apparatus for monomolecular layers |
GB2013079.5A GB2593243B (en) | 2020-03-16 | 2020-08-21 | Flaking method and apparatus for monomolecular layers |
GB2013078.7A GB2593242B (en) | 2020-03-16 | 2020-08-21 | Alignment method and apparatus for monomolecular layers |
GB2016345.7A GB2593955B (en) | 2020-03-16 | 2020-10-15 | Aquacracking - method and apparatus for oil refining |
GB2018405.7A GB2593256A (en) | 2020-03-16 | 2020-11-23 | Method and apparatus for water processing |
GB2019678.8A GB2594546A (en) | 2020-03-16 | 2020-12-14 | Method and apparatus for water processing |
PCT/GB2021/050640 WO2021186155A1 (en) | 2020-03-16 | 2021-03-15 | Generator of a vortex braid broken up into a system of toroid vortices |
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EP21718168.4A Pending EP4200065A1 (en) | 2020-08-21 | 2021-03-15 | Generator of a vortex braid broken up into a system of toroid vortices |
EP21718170.0A Pending EP4200254A1 (en) | 2020-08-21 | 2021-03-16 | Method and apparatus for water processing |
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