Classifications

• • D—TEXTILES; PAPER
  • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
  • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
  • D21H27/00—Special paper not otherwise provided for, e.g. made by multi-step processes
  • D21H27/30—Multi-ply
  • D21H27/38—Multi-ply at least one of the sheets having a fibrous composition differing from that of other sheets
• • C—CHEMISTRY; METALLURGY
  • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
  • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
  • C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
  • C08J5/18—Manufacture of films or sheets
• • B—PERFORMING OPERATIONS; TRANSPORTING
  • B32—LAYERED PRODUCTS
  • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
  • B32B27/00—Layered products comprising a layer of synthetic resin
  • B32B27/06—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
  • B32B27/08—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
• • B—PERFORMING OPERATIONS; TRANSPORTING
  • B32—LAYERED PRODUCTS
  • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
  • B32B27/00—Layered products comprising a layer of synthetic resin
  • B32B27/06—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
  • B32B27/10—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material of paper or cardboard
• • B—PERFORMING OPERATIONS; TRANSPORTING
  • B32—LAYERED PRODUCTS
  • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
  • B32B27/00—Layered products comprising a layer of synthetic resin
  • B32B27/18—Layered products comprising a layer of synthetic resin characterised by the use of special additives
  • B32B27/26—Layered products comprising a layer of synthetic resin characterised by the use of special additives using curing agents
• • B—PERFORMING OPERATIONS; TRANSPORTING
  • B32—LAYERED PRODUCTS
  • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
  • B32B27/00—Layered products comprising a layer of synthetic resin
  • B32B27/32—Layered products comprising a layer of synthetic resin comprising polyolefins
• • B—PERFORMING OPERATIONS; TRANSPORTING
  • B32—LAYERED PRODUCTS
  • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
  • B32B29/00—Layered products comprising a layer of paper or cardboard
  • B32B29/002—Layered products comprising a layer of paper or cardboard as the main or only constituent of a layer, which is next to another layer of the same or of a different material
  • B32B29/005—Layered products comprising a layer of paper or cardboard as the main or only constituent of a layer, which is next to another layer of the same or of a different material next to another layer of paper or cardboard layer
• • B—PERFORMING OPERATIONS; TRANSPORTING
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  • B32B29/00—Layered products comprising a layer of paper or cardboard
  • B32B29/02—Layered products comprising a layer of paper or cardboard next to a fibrous or filamentary layer
• • B—PERFORMING OPERATIONS; TRANSPORTING
  • B32—LAYERED PRODUCTS
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  • B32B29/00—Layered products comprising a layer of paper or cardboard
  • B32B29/08—Corrugated paper or cardboard
• • B—PERFORMING OPERATIONS; TRANSPORTING
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  • B32B7/00—Layered products characterised by the relation between layers; Layered products characterised by the relative orientation of features between layers, or by the relative values of a measurable parameter between layers, i.e. products comprising layers having different physical, chemical or physicochemical properties; Layered products characterised by the interconnection of layers
  • B32B7/02—Physical, chemical or physicochemical properties
• • B—PERFORMING OPERATIONS; TRANSPORTING
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  • B32B7/00—Layered products characterised by the relation between layers; Layered products characterised by the relative orientation of features between layers, or by the relative values of a measurable parameter between layers, i.e. products comprising layers having different physical, chemical or physicochemical properties; Layered products characterised by the interconnection of layers
  • B32B7/04—Interconnection of layers
  • B32B7/12—Interconnection of layers using interposed adhesives or interposed materials with bonding properties
• • B—PERFORMING OPERATIONS; TRANSPORTING
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  • B32B9/00—Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00
  • B32B9/02—Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00 comprising animal or vegetable substances, e.g. cork, bamboo, starch
• • B—PERFORMING OPERATIONS; TRANSPORTING
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• • B—PERFORMING OPERATIONS; TRANSPORTING
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  • B32B9/045—Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00 comprising such particular substance as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
• • B—PERFORMING OPERATIONS; TRANSPORTING
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  • B32B9/00—Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00
  • B32B9/04—Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00 comprising such particular substance as the main or only constituent of a layer, which is next to another layer of the same or of a different material
  • B32B9/06—Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00 comprising such particular substance as the main or only constituent of a layer, which is next to another layer of the same or of a different material of paper or cardboard
• • B—PERFORMING OPERATIONS; TRANSPORTING
  • B82—NANOTECHNOLOGY
  • B82Y—SPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
  • B82Y30/00—Nanotechnology for materials or surface science, e.g. nanocomposites
• • C—CHEMISTRY; METALLURGY
  • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
  • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
  • C08L1/00—Compositions of cellulose, modified cellulose or cellulose derivatives
  • C08L1/02—Cellulose; Modified cellulose
• • D—TEXTILES; PAPER
  • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
  • D21F—PAPER-MAKING MACHINES; METHODS OF PRODUCING PAPER THEREON
  • D21F1/00—Wet end of machines for making continuous webs of paper
• • D—TEXTILES; PAPER
  • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
  • D21F—PAPER-MAKING MACHINES; METHODS OF PRODUCING PAPER THEREON
  • D21F11/00—Processes for making continuous lengths of paper, or of cardboard, or of wet web for fibre board production, on paper-making machines
  • D21F11/02—Processes for making continuous lengths of paper, or of cardboard, or of wet web for fibre board production, on paper-making machines of the Fourdrinier type
  • D21F11/04—Processes for making continuous lengths of paper, or of cardboard, or of wet web for fibre board production, on paper-making machines of the Fourdrinier type paper or board consisting on two or more layers
• • D—TEXTILES; PAPER
  • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
  • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
  • D21H11/00—Pulp or paper, comprising cellulose or lignocellulose fibres of natural origin only
  • D21H11/16—Pulp or paper, comprising cellulose or lignocellulose fibres of natural origin only modified by a particular after-treatment
  • D21H11/18—Highly hydrated, swollen or fibrillatable fibres
• • D—TEXTILES; PAPER
  • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
  • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
  • D21H21/00—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
  • D21H21/14—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by function or properties in or on the paper
  • D21H21/26—Agents rendering paper transparent or translucent
• • D—TEXTILES; PAPER
  • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
  • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
  • D21H27/00—Special paper not otherwise provided for, e.g. made by multi-step processes
  • D21H27/30—Multi-ply
• • B—PERFORMING OPERATIONS; TRANSPORTING
  • B32—LAYERED PRODUCTS
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  • B32B2250/00—Layers arrangement
  • B32B2250/02—2 layers
• • B—PERFORMING OPERATIONS; TRANSPORTING
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  • B32B2250/00—Layers arrangement
  • B32B2250/20—All layers being fibrous or filamentary
• • B—PERFORMING OPERATIONS; TRANSPORTING
  • B32—LAYERED PRODUCTS
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  • B32B2250/00—Layers arrangement
  • B32B2250/40—Symmetrical or sandwich layers, e.g. ABA, ABCBA, ABCCBA
• • B—PERFORMING OPERATIONS; TRANSPORTING
  • B32—LAYERED PRODUCTS
  • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
  • B32B2255/00—Coating on the layer surface
  • B32B2255/12—Coating on the layer surface on paper layer
• • B—PERFORMING OPERATIONS; TRANSPORTING
  • B32—LAYERED PRODUCTS
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  • B32B2262/00—Composition or structural features of fibres which form a fibrous or filamentary layer or are present as additives
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• • B—PERFORMING OPERATIONS; TRANSPORTING
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• • B—PERFORMING OPERATIONS; TRANSPORTING
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• • B—PERFORMING OPERATIONS; TRANSPORTING
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• • B—PERFORMING OPERATIONS; TRANSPORTING
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Definitions

• the present disclosure relates to gas barrier films, e.g. useful in paper and paperboard based packaging materials. More specifically, the present disclosure relates to methods for manufacturing films comprising highly refined cellulose fibers, particularly films comprising microfibrillated cellulose (MFC).
• MFC microfibrillated cellulose
• Oxygen-sensitive products include many food products, but also pharmaceutical products and electronic industry products.
• Known packaging materials with oxygen barrier properties may be comprised of one or several polymer films or of a fibrous paper or board coated with one or several layers of an oxygen barrier polymer, usually as part of a multilayer coating structure. Another important property for packaging for food products is resistance to grease and oil.
• MFC films have been developed, in which defibrillated cellulosic fibrils have been suspended e.g. in water, re organized and rebonded together to form a continuous film. MFC films have been found to provide good gas barrier properties as well as good resistance to grease and oil.
• MFC films may be made by use of casting technologies, including applying an MFC dispersion onto a non-porous cast substrate, such as a polymeric or metal substrate, and drying said film by evaporation.
• the advantages of this technology include uniform thickness distribution and a smooth surface of the film.
• the publication EP2771390 A4 describes preparation of MFC films, in which an aqueous cellulose nanofiber dispersion is coated on a paper or polymeric substrate, dried and finally peeled off as a nanofiber film sheet.
• a problem connected with the casting process is that when the film is forming in the drying step, the slow diffusion of water restricts the drying rate. The diffusion of water vapor through the film is a slow process which has a negative impact on the process efficiency.
• the film can be made by applying an MFC suspension on a porous substrate forming a web followed by dewatering of the web by draining water through the substrate for forming the film.
• the porous substrate may for example be a membrane or wire fabric or it can be a paper or paperboard substrate. Formation of the web can be accomplished e.g. by use of a paper- or paperboard machine type of process.
• US patent application US20120298319 A1 teaches a method of manufacturing an MFC film by applying a furnish comprising MFC directly on porous substrate thus allowing the MFC to be dewatered and filtered.
• Pinholes are microscopic holes that can appear in the web during the forming process. Examples of reasons for the appearance of pinholes include irregularities in the pulp suspension, e.g. formed by flocculation or re-flocculation of fibrils, rough dewatering fabric, uneven pulp distribution on the wire, or too low a web grammage. Pinhole formation typically increases with increased dewatering speed. Flowever, in pinhole free areas, the Oxygen Transmission Rate value is good when grammage is above 20-40 g/m 2 .
• Another solution would be to increase the grammage or coarseness of the film, but that will significantly increase dewatering time and increase risk for pinholes, respectively.
• MFC microfibrillated cellulose
• a method for manufacturing a multilayer film comprising highly refined cellulose fibers comprising the steps of: a) forming a first wet web by applying a first pulp suspension comprising highly refined cellulose fibers on a first wire; b) partially dewatering the first wet web to obtain a first partially dewatered web; c) forming a second wet web by applying a second pulp suspension comprising highly refined cellulose fibers on a second wire; d) partially dewatering the second wet web to obtain a second partially dewatered web; e) joining the first and second partially dewatered web to obtain a multilayer web; and f) further dewatering, and optionally drying, the multilayer web to obtain a multilayer film comprising highly refined cellulose fibers.
• the term film as used herein refers generally to a thin continuous sheet formed material. Depending on the composition of the pulp suspension, the film can also be considered as a thin paper or even as a membrane.
• the film preferably has a grammage below 100 g/m 2 , preferably in the range of 20-100 g/m 2
• the multilayer film is typically relatively dense. In some embodiments, the multilayer film has a density above 600 kg/m 3 , preferably above 900 kg/m 3 .
• the inventive method allows for manufacturing a film comprising highly refined cellulose fibers in a paper machine type of process. More importantly, the method allows for the manufacture of films having a relatively high grammage in the range of 20-100 g/m 2 which films have a very low occurrence of pinholes or are substantially pinhole free. Because of the content of highly refined cellulose fibers, the resulting multilayer film will typically have a density above 600 kg/m 3 , preferably above 900 kg/m 3 . Such films have been found to be very useful as gas barrier films, e.g. in packaging applications. The films can be used to replace conventional barrier films, such as synthetic polymer films which reduce the recyclability of paper or paperboard packaging products. The inventive films have high repulpability, providing for high recyclability of the films and paper or paperboard packaging products comprising the films.
• the manufacturing method involves the separate preparation and partial dewatering of two lower grammage webs.
• the partially dewatered but still wet webs are joined to form a higher grammage multilayer web, which is subsequently further dewatered and optionally dried to obtain a multilayer film comprising the highly refined cellulose fibers.
• Joining the webs while they are still wet ensures good adhesion between the layers.
• the composition of the two layers is identical, the resulting multilayer film may even be difficult to distinguish from a single layer film of corresponding thickness.
• the partial dewatering and lamination of the webs in the partially dewatered state has been found to substantially eliminate occurrence of pinholes in the finished multilayer film, while still allowing a high production speed.
• a paper machine (or paper-making machine) is an industrial machine which is used in the pulp and paper industry to create paper in large quantities at high speed.
• Modern paper-making machines are typically based on the principles of the Fourdrinier Machine, which uses a moving woven mesh, a “wire”, to create a continuous web by filtering out the fibers held in a pulp suspension and producing a continuously moving wet web of fiber. This wet web is dried in the machine to produce a strong paper web.
• the forming, dewatering and joining steps of the inventive method are preferably performed at the forming section of the paper machine, commonly called the wet end.
• the wet webs are formed on different wires in the forming section of the paper machine.
• the preferred type of forming section for use with the present invention includes 2 or 3 Fourdrinier wire sections, combined with supporting wire.
• the wires are preferably endless wires.
• the wire used in the inventive method preferably has relatively high porosity in order to allow fast dewatering and high drainage capacity.
• the air permeability of the wire is preferably above 5000 m 3 /m 2 /hour at 100 Pa.
• the wires may preferably comprise at least 500 knuckles per cm 2 , and more preferably at least 1000 knuckles per cm 2 to reduce fiber marking.
• the first and second pulp suspensions are aqueous suspensions comprising a water-suspended mixture of cellulose based fibrous material and optionally non- fibrous additives.
• the inventive method uses pulp suspensions comprising highly refined cellulose fibers. Refining, or beating, of cellulose pulps refers to mechanical treatment and modification of the cellulose fibers in order to provide them with desired properties.
• the highly refined cellulose fibers can be produced from different raw materials, for example softwood pulp or hardwood pulp.
• the highly refined cellulose fibers are preferably never dried cellulose fibers.
• highly refined cellulose fibers as used herein preferably refers to refined cellulose fibers having a Schopper-Riegler (SR) value of 65 or higher, preferably 70 or higher, as determined by standard ISO 5267-1.
• the first and/or second pulp suspension is formed from a cellulose furnish having a Schopper-Riegler (SR) value in the range of 65-99, preferably in the range of 70-90.
• the dry solids content of the first and/or second pulp suspension is typically in the range of 0.1 -0.7 wt%, preferably in the range of 0.15-0.5 wt%, more preferably in the range of 0.2-0.4 wt%.
• the dry solids content of the first and/or second pulp suspension may be comprised solely of the highly refined cellulose fibers, or it can comprise a mixture of highly refined cellulose fibers and other ingredients or additives.
• the first and/or second pulp suspension preferably includes highly refined cellulose fibers as its main component based on the total dry weight of the pulp suspension.
• the first and/or second pulp suspension comprises at least 50 wt%, preferably at least 70 wt%, more preferably at least 80 wt% or at least 90 wt% of highly refined cellulose fibers, based on the total dry weight of the pulp suspension.
• the highly refined cellulose fibers of the first and/or second pulp suspension is refined Kraft pulp.
• Refined Kraft pulp will typically comprise at least 10 % hemicellulose.
• the first and/or second pulp suspension comprises hemicellulose at an amount of at least 10 %, such as in the range of 10-25 %, of the amount of the highly refined cellulose fibers.
• the first and/or second pulp suspension may further comprise additives such as native starch or starch derivatives, cellulose derivatives such as sodium carboxymethyl cellulose, a filler, retention and/or drainage chemicals, flocculation additives, deflocculating additives, dry strength additives, softeners, cross-linking aids, sizing chemicals, dyes and colorants, wet strength resins, fixatives, de foaming aids, microbe and slime control aids, or mixtures thereof.
• the first and/or second pulp suspension may further comprise additives that will improve different properties of the mixture and/or the produced film such as latex and/or polyvinyl alcohol (PVOH) for enhancing the ductility of the film.
• PVOH polyvinyl alcohol
• the inventive method is especially useful for manufacturing films of so called microfibri Hated cellulose (MFC).
• MFC microfibri Hated cellulose
• the highly refined cellulose fibers is MFC.
• Microfibrillated cellulose shall in the context of the patent application be understood to mean a nano scale cellulose particle fiber or fibril with at least one dimension less than 100 nm.
• MFC comprises partly or totally fibrillated cellulose or lignocellulose fibers.
• the liberated fibrils have a diameter less than 100 nm, whereas the actual fibril diameter or particle size distribution and/or aspect ratio (length/width) depends on the source and the manufacturing methods.
• the smallest fibril is called elementary fibril and has a diameter of approximately 2-4 nm (see e.g.
• Chinga-Carrasco G., Cellulose fibres, nanofibrils and microfibrils,: The morphological sequence of MFC components from a plant physiology and fibre technology point of view, Nanoscale research letters 2011, 6:417), while it is common that the aggregated form of the elementary fibrils, also defined as microfibril ( Fengel , D., Ultrastructural behavior of cell wall polysaccharides, Tappi J., March 1970, Voi 53, No. 3.), is the main product that is obtained when making MFC e.g. by using an extended refining process or pressure-drop disintegration process. Depending on the source and the manufacturing process, the length of the fibrils can vary from around 1 to more than 10 micrometers. A coarse MFC grade might contain a substantial fraction of fibrillated fibers, i.e. protruding fibrils from the tracheid (cellulose fiber), and with a certain amount of fibrils liberated from the tracheid (cellulose fiber).
• MFC cellulose microfibrils, fibrillated cellulose, nanofibrillated cellulose, fibril aggregates, nanoscale cellulose fibrils, cellulose nanofibers, cellulose nanofibrils, cellulose microfibers, cellulose fibrils, microfibrillar cellulose, microfibril aggregates and cellulose microfibril aggregates.
• MFC can also be characterized by various physical or physical-chemical properties such as its large surface area or its ability to form a gel-like material at low solids (1-5 wt%) when dispersed in water.
• Various methods exist to make MFC such as single or multiple pass refining, pre hydrolysis followed by refining or high shear disintegration or liberation of fibrils.
• the cellulose fibers of the pulp to be utilized may thus be pre-treated, for example enzymatically or chemically, to hydrolyse or swell the fibers or to reduce the quantity of hemicellulose or lignin.
• the cellulose fibers may be chemically modified before fibrillation, such that the cellulose molecules contain other (or more) functional groups than found in the native cellulose.
• groups include, among others, carboxymethyl (CMC), aldehyde and/or carboxyl groups (cellulose obtained by N- oxyl mediated oxidation, for example "TEMPO"), quaternary ammonium (cationic cellulose) or phosphoryl groups.
• the nanofibrillar cellulose may contain some hemicelluloses, the amount of which is dependent on the plant source.
• Mechanical disintegration of the pre-treated fibers, e.g. hydrolysed, pre-swelled, or oxidized cellulose raw material is carried out with suitable equipment such as a refiner, grinder, homogenizer, colloider, friction grinder, ultrasound sonicator, fluidizer such as microfluidizer, macrofluidizer or fluidizer-type homogenizer.
• suitable equipment such as a refiner, grinder, homogenizer, colloider, friction grinder, ultrasound sonicator, fluidizer such as microfluidizer, macrofluidizer or fluidizer-type homogenizer.
• the product might also contain fines, or nanocrystalline cellulose, or other chemicals present in wood fibers or in papermaking process.
• the product might also contain various amounts of micron size fiber particles that have not been efficiently fibrillated.
• MFC is produced from wood cellulose fibers, both from hardwood and softwood fibers. It can also be made from microbial sources, agricultural fibers such as wheat straw pulp, bamboo, bagasse, or other non-wood fiber sources. It is preferably made from pulp including pulp from virgin fiber, e.g. mechanical, chemical and/or thermomechanical pulps. It can also be made from broke or recycled paper.
• the dry solids content of the first and/or second pulp suspension may be comprised solely of MFC, or it can comprise a mixture of MFC and other ingredients or additives.
• the first and/or second pulp suspension preferably includes MFC as its main component based on the total dry weight of the pulp suspension. In some embodiments, the first and/or second pulp suspension comprises 50-99 wt%, preferably at least 70-99 wt%, more preferably at least 80- 99 wt% MFC, based on the total dry weight of the pulp suspension.
• At least some of the MFC is obtained from MFC broke.
• the first and/or second pulp suspension may also comprise a certain amount of unrefined or slightly refined cellulose fibers.
• the term unrefined or slightly refined fibers as used herein preferably refers to cellulose fibers having a Schopper-Riegler (SR) value below 30, preferably below 28, as determined by standard ISO 5267-1. Unrefined or slightly refined cellulose fibers are useful to enhance dewatering and may also improve strength and fracture toughness of the multilayer film.
• the first and/or second pulp suspension comprises 0.1-50 wt%, preferably 0.1-30 wt%, and more preferably 0.1-10 wt% of unrefined or slightly refined cellulose fibers, based on the total dry weight of the pulp suspension.
• the unrefined or slightly refined cellulose fibers may for example be obtained from bleached or unbleached or mechanical or chemimechanical pulp or other high yield pulps.
• the unrefined or slightly refined cellulose fibers are preferably never dried cellulose fibers.
• the pH value of the first and/or second pulp suspension may typically be in the range of 4-10 preferably in the range of 5-8, and more preferably in the range of 5.5-7.5.
• the temperature of the first and/or second pulp suspension may typically be in the range of 30-70 °C, preferably in the range of 40-60 °C, and more preferably in the range of 45-55 °C.
• the composition of the first and second pulp suspension may be the same or different.
• one of the pulp suspensions may comprise unrefined or slightly refined cellulose fibers while the other pulp suspension does not comprise unrefined or slightly refined cellulose fibers.
• first pulp suspension with less highly refined cellulose fibers with lower SR value and/or a higher amount of unrefined or slightly refined cellulose fibers to provide faster dewatering and a second pulp suspension with more highly refined cellulose fibers with higher SR value and/or a lower amount of unrefined or slightly refined cellulose fibers to provide good barrier properties or to provide one surface having very high smoothness.
• the first web formed from the first pulp suspension may have a slightly higher grammage, e.g. in the range of 25-30 g/m 2 , than the second web formed from the second pulp suspension, e.g. having a grammage in the range of 15-20 g/m 2 .
• the first and second pulp suspension are provided from two different headboxes. This may be advantageous since the headboxes can be operated in slightly different manners, e.g. with different consistencies, head box jet angles, or jet-to-wire ratios.
• the wire used in the inventive method preferably has relatively high porosity in order to allow fast dewatering and high drainage capacity).
• the air permeability of the wire is preferably above 5000 m 3 /m 2 /hour at 100 Pa.
• the wire preferably has a high fibre support index (F.S.I), typically above 190 so that fine material does not penetrate into the structure and to cause less wire markings, and a coarse and open back side.
• F.S.I fibre support index
• the first and second pulp suspension have the same composition. This can simplify the process as only one pulp suspension source is required. Also, having the same composition may lead to less problems with curl in the finished film the two layers of the multilayer film will have the same composition.
• the basis weight of each of the first and/or second wet web based on the total dry weight of the web is preferably less than 50 g/m 2 and more preferably less than 30 g/m 2 . A grammage of less than 50 g/m 2 or 30 g/m 2 has been found to allow for a quick partial dewatering of the wet web with little pinhole formation.
• the basis weight of the first and/or second wet web based on the total dry weight of the web is preferably at least 5 g/m 2 . Thus, in some embodiments, the basis weight of the first and/or second wet web based on the total dry weight of the web is in the range of 5-50 g/m 2 , more preferably in the range of 5-30 g/m 2 .
• the first and second wet web are partially dewatered.
• Dewatering of the webs on the wire may be performed using methods and equipment known in the art, examples include but are not limited to table roll and foils, friction less dewatering and ultra-sound assisted dewatering.
• Partial dewatering means that the dry solids content of the wet web is reduced compared to the dry solids content of the pulp suspension, but that the dewatered web still comprises a significant amount of water.
• partial dewatering of the wet webs means that the dry solids content of the first and second partially dewatered web is above 1 wt% but below 15 wt%.
• partial dewatering of the wet webs means that the dry solids content of the first and second partially dewatered web is above 1 wt% but below 10 wt%.
• a dry solids content of the first and second partially dewatered web in this range has been found to be especially suitable for joining the first and second wet web into a multilayer web.
• the dry solids content of the first and second partially dewatered web prior to the joining step is in the range of 1.5-8 wt%, preferably in the range of 2.5-6 wt%, and more preferably in the range of 3- 4.5 wt%.
• the partially dewatered but still wet webs are joined to form a higher grammage multilayer web.
• the dry solids content of the first and second partially dewatered web when they are joined is preferably above 1 wt% but below 15 wt% and more preferably above 1 wt% but below 10 wt%. In some embodiments, the dry solids content of the first and second partially dewatered web when they are joined is in the range of 1.5-8 wt%, preferably in the range of 2.5-6 wt%, and more preferably in the range of 3-4.5 wt%.
• the partially dewatered webs are preferably joined by wet lamination.
• the waterline is indicative of a certain solids content of the web.
• the webs are preferably joined after the water line. Joining the webs while they are still wet ensures good adhesion between the layers. The joining can be achieved by applying one of the partially dewatered webs on top of the other. The joining may be done non-wire side against non-wire side, or wire-side against non-wire side. Joining and further dewatering of the formed multilayer web may be improved by various additional operations.
• the joining further comprises pressing the first and second partially dewatered web together. In some embodiments, the joining further comprises applying suction to the joined first and second partially dewatered web. Applying pressure and/or suction to the formed multilayer web improves adhesion between the web layers.
• the wire section of a paper machine may have various dewatering devices such as blade, table and/or foil elements, suction boxes, friction less dewatering, ultra-sound assisted dewatering, couch rolls, or a dandy roll.
• the surface of the web facing the wire is referred to as the wire side and the surface of the web facing away from the wire is referred to as the non-wire side.
• the joining of the webs may preferably be done non-wire side against non-wire side, or non-wire side against wire side. Joining the webs non-wire side against non-wire side, or wire side against non-wire side gives an additional advantage in that a larger portion of fines is concentrated towards the middle of the multilayer film. This concentration of fines contributes both to adhesion between the layers and to the gas barrier properties of the film. The fines may also contribute to a self- healing phenomenon, where fines redistribute to fill voids in the felted sheet on the wet wire, thus making produced film less porous.
• the dry solids content of the multilayer web is typically further increased during the joining step.
• the increase in dry solids content may be due to dewatering of the multilayer web on the wire with optional pressure and/or suction applied to the web, and also due to drying operations performed during or shortly after the joining, e.g. impingement drying or air or steam drying.
• the dry solids content of the multilayer web after joining, with optional application of pressure and/or suction is typically above 8 wt% but below 28 wt%.
• the dry solids content of the multilayer web prior to the further dewatering and optional drying step is in the range of 8-28 wt%, preferably in the range of 10-20 wt%, and more preferably in the range of 12-18 wt%.
• the basis weight of the multilayer web, and the multilayer film, based on the total dry weight of the web is typically less than 100 g/m 2 , preferably less than 60 g/m 2 , and more preferably less than 40 g/m 2 .
• the basis weight of the multilayer web, and the multilayer film, based on the total dry weight of the web is in the range of 10-100 g/m 2 , preferably in the range of 10-60 g/m 2 , more preferably in the range of 10-40 g/m 2 . Pinhole free films with basis weights in these ranges have been found have good oxygen barrier properties.
• the multilayer film is formed from two web layers comprising highly refined cellulose fibers.
• the multilayer film may also comprise additional web layers comprising highly refined cellulose fibers.
• the formed multilayer film is formed from three or more web layers comprising highly refined cellulose fibers, such as three, four, five, six, or seven layers.
• the forming, composition and structure of each additional layer may be further characterized as described above with reference to the first and second web layer.
• the method for manufacturing a multilayer film further comprises the steps: c2) forming a third wet web by applying a third pulp suspension comprising highly refined cellulose fibers on a third wire; d2) partially dewatering the third wet web to obtain a third partially dewatered web; e2) joining the first, second and third partially dewatered web to obtain a multilayer web.
• the dry solids content of the multilayer web is typically further increased.
• the resulting multilayer film preferably has a dry solids content above 90 wt%.
• the further dewatering typically comprises pressing the web to squeeze out as much water as possible.
• the further dewatering may for example include passing the formed multilayer web through a press section of a paper machine, where the web passes between large rolls loaded under high pressure to squeeze out as much water as possible.
• the removed water is typically received by a fabric or felt.
• the dry solids content of the multilayer film after the further dewatering is in the range of 15-48 wt%, preferably in the range of 18-40 wt%, and more preferably in the range of 22-35 wt%.
• the optional drying may for example include drying the multilayer web by passing the multilayer web around a series of heated drying cylinders. Drying may typically remove the water content down to a level of about 1-15 wt%, preferably to about 2-10 wt%.
• the dry solids content of the final multilayer film may vary depending on the intended use of the film.
• a film for use as a stand-alone product may have a dry solids content in the range of 85-99 wt%, preferably in the range of 90- 98 wt%
• a film for use in further lamination to form paper or paperboard based packaging material may have a dry solids content in the range of less than 90 wt%, preferably less than 85 wt%, such as in the range of 30-85 wt%.
• Pinholes are microscopic holes that can appear in the web during the forming process. Examples of reasons for the appearance of pinholes include irregularities in the pulp suspension, e.g. formed by flocculation or re-flocculation of fibrils, rough dewatering fabric, uneven pulp distribution on the wire, or too low a web grammage.
• the multilayer film comprises less than 10 pinholes/m 2 , preferably less than 8 pinholes/m 2 , and more preferably less than 2 pinholes/m 2 , as measured according to standard EN13676:2001. The measurement involves treating the multilayer film with a coloring solution (e.g. dyestuff E131 Blue in ethanol) and inspecting the surface microscopically.
• a coloring solution e.g. dyestuff E131 Blue in ethanol
• the multilayer film will typically exhibit good resistance to grease and oil.
• Grease resistance of the multilayer film was evaluated by the KIT-test according to standard ISO 16532-2.
• the test uses a series of mixtures of castor oil, toluene and heptane. As the ratio of oil to solvent is decreased, the viscosity and surface tension also decrease, making successive mixtures more difficult to withstand.
• the performance is rated by the highest numbered solution which does not darken the sheet after 15 seconds. The highest numbered solution (the most aggressive) that remains on the surface of the paper without causing failure is reported as the "kit rating" (maximum 12).
• the KIT value of the multilayer film is at least 6, preferably at least 8, as measured according to standard ISO 16532-2.
• the multilayer film has a Gurley Hill value of at least 10000 s/100ml, preferably at least 25000 s/100ml, and more preferably at least 40000 s/100ml, as measured according to standard ISO 5636/6.
• the multilayer film preferably has high repulpability.
• the multilayer film exhibits less than 30 %, preferably less than 20 %, and more preferably less than 10 % residues, when tested as a category II material according to the PTS-RH 021/97 test method.
• Films comprising high amounts of highly refined cellulose fibers are typically transparent or translucent to visible light.
• the multilayer film is transparent or translucent to visible light.
• the inventive method comprises: i) Preparing a first furnish from a fiber mix comprising a 5-15 wt% of unrefined or slightly refined bleached softwood or hardwood kraft pulp having a Schopper- Riegler (SR) value in the range of 15-25, preferably in the range of 20-25 and 95- 85% of highly refined bleached softwood or hardwood kraft pulp in the form of MFC having a SR value of at least 90.
• All of the cellulosic material can be prepared from same kraft pulp source, where the highly refined fiber is obtained by intensive refining and/or homogenization and optional enzymatic pre-treatment of the fibers.
• the pH of the first furnish is between 6.5 and 8.5.
• Water retention value (WRV) of the mixture is about 300-350 %.
• the SR value for the mix (without any further chemicals added) is at least 80, and preferably at least 85. Accordingly, the mixture will exhibit high drainage resistance.
• the first furnish is prepared to a consistency of 0.15-0.35 wt% and a temperature of 35-45 °C.
• process chemicals like retention aids (one or two or multicomponent), formation aids (non-ionic or anionic water soluble polymers such as CMC), and optionally other additives such as fillers ( ⁇ 10 wt%), wet strength additives, hydrophobizing chemicals ( ⁇ 5 kg/tn) are added.
• iii) Forming and dewatering a first web layer using a fourdrinier technique on a first wire. The grammage of the first layer is 20 g/m 2 .
• the obtained product is free from pinholes and has good oxygen barrier properties (less than 15 cc/m 2 /24h/atm as measured according to the standard ASTM D-3985 at 50% relative humidity and 23 °C) and grease barrier properties (KIT>11 ).
• the PPS10 surface roughness for the uncalendered base is above 3.0 and density is in the range of 600-900 kg/m 3 .
• the Gurley-Hill value for the film is 42 300.
• a multilayer film comprising highly refined cellulose, wherein the multilayer film is obtainable by the inventive method.
• the inventive multilayer films are especially suited as thin packaging films when coated or laminated with one or more layers of a thermoplastic polymer.
• the multilayer film may preferably be coated or laminated with one or more polymer layers.
• the multilayer film may be provided with a polymer layer on one side or on both sides.
• the polymer layer may comprise any of the thermoplastic polymers commonly used in paper or paperboard based packaging materials in general or polymers used in liquid packaging board in particular. Examples include polyethylene (PE), polyethylene terephthalate (PET), polypropylene (PP), polylactic acid (PLA), polyglycolic acid (PGA), starch and cellulose. Polyethylenes, especially low density polyethylene (LDPE) and high density polyethylene (HDPE), are the most common and versatile polymers used in liquid packaging board.
• PE polyethylene
• PET polyethylene terephthalate
• PP polypropylene
• PLA polylactic acid
• PGA polyglycolic acid
• cellulose starch and cellulose.
• Polyethylenes, especially low density polyethylene (LDPE) and high density polyethylene (HDPE) are the most common and versatile polymers used in liquid packaging board.
• the polymer layer comprises polypropylene or polyethylene.
• the polymer layer comprises polyethylene, more preferably LDPE or HDPE.
• the polymer layer may comprise one or more layers formed of the same polymeric resin or of different polymeric resins. In some embodiments the polymer layer comprises a mixture of two or more different polymeric resins. In some embodiments the polymer layer is a multilayer structure comprised of two or more layers, wherein a first layer is comprised of a first polymeric resin and a second layer is comprised of a second polymeric resin, which is different from the first polymeric resin.
• the polymer layer is formed by extrusion coating of the polymer onto a surface of the multilayer film.
• Extrusion coating is a process by which a molten plastic material is applied to a substrate to form a very thin, smooth and uniform layer.
• the coating can be formed by the extruded plastic itself, or the molten plastic can be used as an adhesive to laminate a solid plastic film onto the substrate.
• Common plastic resins used in extrusion coating include polyethylene (PE), polypropylene (PP), and polyethylene terephthalate (PET).
• the basis weight of each polymer layer of the multilayer film is preferably less than 50 g/m 2
• a basis weight of the polymer layer of at least 8 g/m 2 preferably at least 12 g/m 2 is typically required.
• the basis weight of the polymer layer is in the range of 8-50 g/m 2 , preferably in the range of 12-50 g/m 2 .
• the inventive multilayer film may preferably be used as a gas barrier layer in a paper or paperboard based packaging material, e.g. in liquid packaging board (LPB) for use in the packaging of liquids or liquid containing products. Therefore, according to a third aspect illustrated herein, there is provided a paper or paperboard based packaging material comprising: a paper or paperboard substrate; and a multilayer film obtainable by the inventive method.
• a paper or paperboard based packaging material comprising: a paper or paperboard substrate; and a multilayer film obtainable by the inventive method.
• Paper generally refers to a material manufactured in sheets or rolls from the pulp of wood or other fibrous substances comprising cellulose fibers, used for e.g. writing, drawing, or printing on, or as packaging material. Paper can either be bleached or unbleached, coated or uncoated, and produced in a variety of thicknesses, depending on the end-use requirements.
• Paperboard generally refers to strong, thick paper or cardboard comprising cellulose fibers used for example as flat substrates, trays, boxes and/or other types of packaging. Paperboard can either be bleached or unbleached, coated or uncoated, and produced in a variety of thicknesses, depending on the end-use requirements.
• the multilayer film of the paper or paperboard based packaging material according to the second aspect may be further defined as set out above with reference to the first aspect.
• the multilayer film is attached to the paper or paperboard substrate directly, e.g. when the multilayer film is wet laid onto the substrate.
• the multilayer film is in direct contact with the substrate.
• the multilayer film is attached to the paper or paperboard substrate indirectly, e.g. when the multilayer film is laminated onto the substrate using an adhesive layer disposed between the substrate and the multilayer film.
• the paper or paperboard based packaging material further comprises an adhesive layer disposed between the substrate and the multilayer film.
• the paper or paperboard based packaging material has a water vapor transfer rate (WVTR), measured according to the standard ISO 15106-2/ASTM F1249 at 50% relative humidity and 23 °C, of less than 200 g/m 2 /24h.
• WVTR water vapor transfer rate
• the paper or paperboard based packaging material has an oxygen transfer rate (OTR), measured according to the standard ASTM D-3985 at 50% relative humidity and 23 °C, of less than 1000 cc/m 2 /24h/atm, preferably less than 500 cc/m 2 /24h/atm, more preferably less than 100 cc/m 2 /24h/atm, and most preferably less than 50 cc/m 2 /24h/atm.
• OTR oxygen transfer rate
• Additives cationic starch, cationic retention aid, anionic retention aid, hydrophobic sizing, wet strength agent pH: 7.5
• a first web was run on wire section 1 and second web was run on wire section 2.
• Each web was run at 20 g/m 2 at a running speed of 30 m/min.
• the wire retention on each wire was 99.6 %.
• the webs were joined in the wet state to form a multilayer web with a combined weight of 40 g/m 2 and the multilayer web was further dewatered. Based on the water line position it was clear that much higher running speed would have been possible
• a first web was run on wire section 1 and second web was run on wire section 2.
• Each web was run at 15 g/m 2 at a running speed of 45 m/min.
• the wire retention on each wire was 98.8 %.
• the webs were joined in the wet state to form a multilayer web with a combined weight of 30 g/m 2 and the multilayer web was further dewatered. Based on the water line position it was clear that even higher running speed would have been possible

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