EP4075999B1 - Confectionery product and manufacturing process thereof - Google Patents
Confectionery product and manufacturing process thereof Download PDFInfo
- Publication number
- EP4075999B1 EP4075999B1 EP20830132.5A EP20830132A EP4075999B1 EP 4075999 B1 EP4075999 B1 EP 4075999B1 EP 20830132 A EP20830132 A EP 20830132A EP 4075999 B1 EP4075999 B1 EP 4075999B1
- Authority
- EP
- European Patent Office
- Prior art keywords
- sugar
- chewy
- candy
- glucose syrup
- layer
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 235000009508 confectionery Nutrition 0.000 title claims description 140
- 238000004519 manufacturing process Methods 0.000 title claims description 9
- 235000000346 sugar Nutrition 0.000 claims description 101
- 239000000463 material Substances 0.000 claims description 92
- WQZGKKKJIJFFOK-GASJEMHNSA-N Glucose Natural products OC[C@H]1OC(O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-GASJEMHNSA-N 0.000 claims description 75
- 239000008103 glucose Substances 0.000 claims description 75
- 239000006188 syrup Substances 0.000 claims description 50
- 235000020357 syrup Nutrition 0.000 claims description 50
- 229920002148 Gellan gum Polymers 0.000 claims description 46
- 235000010492 gellan gum Nutrition 0.000 claims description 39
- 239000000216 gellan gum Substances 0.000 claims description 39
- 239000010410 layer Substances 0.000 claims description 34
- 229920000159 gelatin Polymers 0.000 claims description 29
- 235000019322 gelatine Nutrition 0.000 claims description 28
- 238000000576 coating method Methods 0.000 claims description 21
- 239000011248 coating agent Substances 0.000 claims description 20
- 239000000416 hydrocolloid Substances 0.000 claims description 15
- 238000000034 method Methods 0.000 claims description 10
- 108010010803 Gelatin Proteins 0.000 claims description 6
- 239000011247 coating layer Substances 0.000 claims description 6
- 239000008273 gelatin Substances 0.000 claims description 6
- 235000011852 gelatine desserts Nutrition 0.000 claims description 6
- 150000002016 disaccharides Chemical class 0.000 claims description 5
- 150000002772 monosaccharides Chemical class 0.000 claims description 5
- OWEGMIWEEQEYGQ-UHFFFAOYSA-N 100676-05-9 Natural products OC1C(O)C(O)C(CO)OC1OCC1C(O)C(O)C(O)C(OC2C(OC(O)C(O)C2O)CO)O1 OWEGMIWEEQEYGQ-UHFFFAOYSA-N 0.000 claims description 3
- GUBGYTABKSRVRQ-PICCSMPSSA-N Maltose Natural products O[C@@H]1[C@@H](O)[C@H](O)[C@@H](CO)O[C@@H]1O[C@@H]1[C@@H](CO)OC(O)[C@H](O)[C@H]1O GUBGYTABKSRVRQ-PICCSMPSSA-N 0.000 claims description 3
- 150000008163 sugars Chemical class 0.000 claims description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 33
- 239000001828 Gelatine Substances 0.000 description 23
- 239000000796 flavoring agent Substances 0.000 description 18
- 235000019634 flavors Nutrition 0.000 description 18
- 239000003925 fat Substances 0.000 description 17
- 235000019197 fats Nutrition 0.000 description 17
- 239000000843 powder Substances 0.000 description 16
- 239000004615 ingredient Substances 0.000 description 14
- 244000215068 Acacia senegal Species 0.000 description 13
- 229920000084 Gum arabic Polymers 0.000 description 13
- 235000010489 acacia gum Nutrition 0.000 description 13
- 239000000205 acacia gum Substances 0.000 description 13
- 238000011156 evaluation Methods 0.000 description 13
- 239000007787 solid Substances 0.000 description 11
- 239000000203 mixture Substances 0.000 description 7
- IIZPXYDJLKNOIY-JXPKJXOSSA-N 1-palmitoyl-2-arachidonoyl-sn-glycero-3-phosphocholine Chemical compound CCCCCCCCCCCCCCCC(=O)OC[C@H](COP([O-])(=O)OCC[N+](C)(C)C)OC(=O)CCC\C=C/C\C=C/C\C=C/C\C=C/CCCCC IIZPXYDJLKNOIY-JXPKJXOSSA-N 0.000 description 6
- 230000000052 comparative effect Effects 0.000 description 6
- 235000010445 lecithin Nutrition 0.000 description 6
- 239000000787 lecithin Substances 0.000 description 6
- 229940067606 lecithin Drugs 0.000 description 6
- 239000003086 colorant Substances 0.000 description 5
- 238000010411 cooking Methods 0.000 description 5
- FYGDTMLNYKFZSV-MRCIVHHJSA-N dextrin Chemical compound O[C@@H]1[C@@H](O)[C@H](O)[C@@H](CO)OC1O[C@@H]1[C@@H](CO)OC(O[C@@H]2[C@H](O[C@H](O)[C@H](O)[C@H]2O)CO)[C@H](O)[C@H]1O FYGDTMLNYKFZSV-MRCIVHHJSA-N 0.000 description 5
- 239000003995 emulsifying agent Substances 0.000 description 5
- 125000005456 glyceride group Chemical group 0.000 description 5
- 150000003445 sucroses Chemical class 0.000 description 5
- 239000003349 gelling agent Substances 0.000 description 4
- 235000019866 hydrogenated palm kernel oil Nutrition 0.000 description 4
- 239000003921 oil Substances 0.000 description 4
- 229920002472 Starch Polymers 0.000 description 3
- 239000002253 acid Substances 0.000 description 3
- 150000007513 acids Chemical class 0.000 description 3
- 235000010418 carrageenan Nutrition 0.000 description 3
- 239000000679 carrageenan Substances 0.000 description 3
- 229920001525 carrageenan Polymers 0.000 description 3
- 229940113118 carrageenan Drugs 0.000 description 3
- 238000001816 cooling Methods 0.000 description 3
- 235000003599 food sweetener Nutrition 0.000 description 3
- 239000008107 starch Substances 0.000 description 3
- 235000019698 starch Nutrition 0.000 description 3
- 235000012094 sugar confectionery Nutrition 0.000 description 3
- 239000003765 sweetening agent Substances 0.000 description 3
- UHVMMEOXYDMDKI-JKYCWFKZSA-L zinc;1-(5-cyanopyridin-2-yl)-3-[(1s,2s)-2-(6-fluoro-2-hydroxy-3-propanoylphenyl)cyclopropyl]urea;diacetate Chemical compound [Zn+2].CC([O-])=O.CC([O-])=O.CCC(=O)C1=CC=C(F)C([C@H]2[C@H](C2)NC(=O)NC=2N=CC(=CC=2)C#N)=C1O UHVMMEOXYDMDKI-JKYCWFKZSA-L 0.000 description 3
- 241001465754 Metazoa Species 0.000 description 2
- CZMRCDWAGMRECN-UGDNZRGBSA-N Sucrose Chemical compound O[C@H]1[C@H](O)[C@@H](CO)O[C@@]1(CO)O[C@@H]1[C@H](O)[C@@H](O)[C@H](O)[C@@H](CO)O1 CZMRCDWAGMRECN-UGDNZRGBSA-N 0.000 description 2
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 2
- 239000000654 additive Substances 0.000 description 2
- 239000013256 coordination polymer Substances 0.000 description 2
- 238000009792 diffusion process Methods 0.000 description 2
- 238000001125 extrusion Methods 0.000 description 2
- 238000000855 fermentation Methods 0.000 description 2
- 230000004151 fermentation Effects 0.000 description 2
- 235000013373 food additive Nutrition 0.000 description 2
- 239000002778 food additive Substances 0.000 description 2
- -1 for example Substances 0.000 description 2
- 230000005012 migration Effects 0.000 description 2
- 238000013508 migration Methods 0.000 description 2
- 229920001277 pectin Polymers 0.000 description 2
- 239000001814 pectin Substances 0.000 description 2
- 235000010987 pectin Nutrition 0.000 description 2
- 239000004033 plastic Substances 0.000 description 2
- 229920000642 polymer Polymers 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 238000004513 sizing Methods 0.000 description 2
- 239000001959 sucrose esters of fatty acids Substances 0.000 description 2
- 235000010965 sucrose esters of fatty acids Nutrition 0.000 description 2
- 239000002562 thickening agent Substances 0.000 description 2
- 229920001285 xanthan gum Polymers 0.000 description 2
- 239000000230 xanthan gum Substances 0.000 description 2
- 235000010493 xanthan gum Nutrition 0.000 description 2
- 229940082509 xanthan gum Drugs 0.000 description 2
- 229920000936 Agarose Polymers 0.000 description 1
- 241000179442 Anacharis Species 0.000 description 1
- SHZGCJCMOBCMKK-UHFFFAOYSA-N D-mannomethylose Natural products CC1OC(O)C(O)C(O)C1O SHZGCJCMOBCMKK-UHFFFAOYSA-N 0.000 description 1
- 229920001353 Dextrin Polymers 0.000 description 1
- 239000004375 Dextrin Substances 0.000 description 1
- IAJILQKETJEXLJ-UHFFFAOYSA-N Galacturonsaeure Natural products O=CC(O)C(O)C(O)C(O)C(O)=O IAJILQKETJEXLJ-UHFFFAOYSA-N 0.000 description 1
- 108010007666 IMP cyclohydrolase Proteins 0.000 description 1
- 102100020796 Inosine 5'-monophosphate cyclohydrolase Human genes 0.000 description 1
- SHZGCJCMOBCMKK-JFNONXLTSA-N L-rhamnopyranose Chemical compound C[C@@H]1OC(O)[C@H](O)[C@H](O)[C@H]1O SHZGCJCMOBCMKK-JFNONXLTSA-N 0.000 description 1
- PNNNRSAQSRJVSB-UHFFFAOYSA-N L-rhamnose Natural products CC(O)C(O)C(O)C(O)C=O PNNNRSAQSRJVSB-UHFFFAOYSA-N 0.000 description 1
- 229920000161 Locust bean gum Polymers 0.000 description 1
- 241000183024 Populus tremula Species 0.000 description 1
- 229930006000 Sucrose Natural products 0.000 description 1
- 240000008042 Zea mays Species 0.000 description 1
- 235000005824 Zea mays ssp. parviglumis Nutrition 0.000 description 1
- 235000002017 Zea mays subsp mays Nutrition 0.000 description 1
- 239000001785 acacia senegal l. willd gum Substances 0.000 description 1
- 125000002777 acetyl group Chemical group [H]C([H])([H])C(*)=O 0.000 description 1
- 125000002252 acyl group Chemical group 0.000 description 1
- IAJILQKETJEXLJ-QTBDOELSSA-N aldehydo-D-glucuronic acid Chemical compound O=C[C@H](O)[C@@H](O)[C@H](O)[C@H](O)C(O)=O IAJILQKETJEXLJ-QTBDOELSSA-N 0.000 description 1
- WQZGKKKJIJFFOK-VFUOTHLCSA-N beta-D-glucose Chemical compound OC[C@H]1O[C@@H](O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-VFUOTHLCSA-N 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- VQLYBLABXAHUDN-UHFFFAOYSA-N bis(4-fluorophenyl)-methyl-(1,2,4-triazol-1-ylmethyl)silane;methyl n-(1h-benzimidazol-2-yl)carbamate Chemical compound C1=CC=C2NC(NC(=O)OC)=NC2=C1.C=1C=C(F)C=CC=1[Si](C=1C=CC(F)=CC=1)(C)CN1C=NC=N1 VQLYBLABXAHUDN-UHFFFAOYSA-N 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 235000019219 chocolate Nutrition 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 235000005822 corn Nutrition 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 238000002425 crystallisation Methods 0.000 description 1
- 230000008025 crystallization Effects 0.000 description 1
- 238000005520 cutting process Methods 0.000 description 1
- 235000019425 dextrin Nutrition 0.000 description 1
- 235000020805 dietary restrictions Nutrition 0.000 description 1
- 238000010410 dusting Methods 0.000 description 1
- 230000001804 emulsifying effect Effects 0.000 description 1
- 238000011049 filling Methods 0.000 description 1
- 239000006260 foam Substances 0.000 description 1
- 235000021588 free fatty acids Nutrition 0.000 description 1
- 235000001727 glucose Nutrition 0.000 description 1
- 125000002791 glucosyl group Chemical group C1([C@H](O)[C@@H](O)[C@H](O)[C@H](O1)CO)* 0.000 description 1
- 229940097043 glucuronic acid Drugs 0.000 description 1
- 150000004676 glycans Chemical class 0.000 description 1
- 125000003976 glyceryl group Chemical group [H]C([*])([H])C(O[H])([H])C(O[H])([H])[H] 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 235000010420 locust bean gum Nutrition 0.000 description 1
- 239000000711 locust bean gum Substances 0.000 description 1
- 244000005700 microbiome Species 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 239000000178 monomer Substances 0.000 description 1
- 229920001542 oligosaccharide Polymers 0.000 description 1
- 150000002482 oligosaccharides Chemical class 0.000 description 1
- 235000019865 palm kernel oil Nutrition 0.000 description 1
- 239000003346 palm kernel oil Substances 0.000 description 1
- 238000005498 polishing Methods 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 229920001282 polysaccharide Polymers 0.000 description 1
- 239000005017 polysaccharide Substances 0.000 description 1
- 239000005720 sucrose Substances 0.000 description 1
- 150000005846 sugar alcohols Chemical class 0.000 description 1
- 230000035900 sweating Effects 0.000 description 1
- 230000008719 thickening Effects 0.000 description 1
- 239000004408 titanium dioxide Substances 0.000 description 1
- 235000013311 vegetables Nutrition 0.000 description 1
- 235000003563 vegetarian diet Nutrition 0.000 description 1
- 238000005303 weighing Methods 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23G—COCOA; COCOA PRODUCTS, e.g. CHOCOLATE; SUBSTITUTES FOR COCOA OR COCOA PRODUCTS; CONFECTIONERY; CHEWING GUM; ICE-CREAM; PREPARATION THEREOF
- A23G3/00—Sweetmeats; Confectionery; Marzipan; Coated or filled products
- A23G3/34—Sweetmeats, confectionery or marzipan; Processes for the preparation thereof
- A23G3/50—Sweetmeats, confectionery or marzipan; Processes for the preparation thereof characterised by shape, structure or physical form, e.g. products with supported structure
- A23G3/54—Composite products, e.g. layered, coated, filled
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23G—COCOA; COCOA PRODUCTS, e.g. CHOCOLATE; SUBSTITUTES FOR COCOA OR COCOA PRODUCTS; CONFECTIONERY; CHEWING GUM; ICE-CREAM; PREPARATION THEREOF
- A23G3/00—Sweetmeats; Confectionery; Marzipan; Coated or filled products
- A23G3/0002—Processes of manufacture not relating to composition and compounding ingredients
- A23G3/0063—Coating or filling sweetmeats or confectionery
- A23G3/0065—Processes for making filled articles, composite articles, multi-layered articles
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23G—COCOA; COCOA PRODUCTS, e.g. CHOCOLATE; SUBSTITUTES FOR COCOA OR COCOA PRODUCTS; CONFECTIONERY; CHEWING GUM; ICE-CREAM; PREPARATION THEREOF
- A23G3/00—Sweetmeats; Confectionery; Marzipan; Coated or filled products
- A23G3/34—Sweetmeats, confectionery or marzipan; Processes for the preparation thereof
- A23G3/36—Sweetmeats, confectionery or marzipan; Processes for the preparation thereof characterised by the composition containing organic or inorganic compounds
- A23G3/42—Sweetmeats, confectionery or marzipan; Processes for the preparation thereof characterised by the composition containing organic or inorganic compounds characterised by the carbohydrates used, e.g. polysaccharides
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23V—INDEXING SCHEME RELATING TO FOODS, FOODSTUFFS OR NON-ALCOHOLIC BEVERAGES AND LACTIC OR PROPIONIC ACID BACTERIA USED IN FOODSTUFFS OR FOOD PREPARATION
- A23V2002/00—Food compositions, function of food ingredients or processes for food or foodstuffs
Definitions
- the invention relates to coated gelatine-free confectionery products having a chewy center containing gellan gum, and to a method for producing them.
- Chewy candies with a chewy center with a hard candy shell are known in the art.
- EP1104652A1 discloses confectionery products in which a mixture of starch and pectin is used as a gelling agent. It also discloses a process for preparing a hydrocolloid confectionery product.
- the hydrocolloid confectionery product is preferably gelatin-free.
- WO 2006/083784 and WO 2008/091476 disclose multilayer confectionary product having a chewy center including an ingestible dextrin, optionally gum arabic, a sweetener, water and flavour, an intermediate layer including a flavour and a sweetener which is at least partially crystalline and an outer shell which is a crunchy hard shell.
- the sweeteners may be sucrose and corn syrup.
- Hydrocolloids are commonly used as gelling agent in a sugar/glucose syrup system.
- gelatine used primarily as a gelling agent.
- Gelatine imparts to the chewy sugar confectionery an unique viscoelastic texture (referred to as e.g. springiness and resilience) especially desirable to consumers.
- the presence of gelatine improve the manufacturing process, providing a desirable viscosity to the semi-finished confectionery material, making easier to pump, extrude or convey the material along the different stages of the production.
- gelatine has an emulsifying power which allows to homogenize fat with sugar, glucose syrup and residual moisture of chewy candies.
- gelatine is of animal origin.
- Gum arabic reported in WO2006/083784 , is a thickening and gelling agent of vegetable origin used in chewy confectionery and can be an alternative to gelatine, however the geographical origin of gum arabic, which is produced in some African countries, makes the supply extremely variable year after year. Thus, it is also desirable to find alternatives to gum arabic as well as to gelatine.
- WO2011/153229 discloses a dough-like confectionary material employed as layering or coating material which contain 70-98% of solid particulates of sugar, sugar alcohol or mixtures thereof and 0.1-20% of a diffusion controller which may be, among the others, gelatine or gellan.
- the diffusion controller used in the examples is xanthan gum.
- WO02/30214 discloses gelatine-free gummy confections comprising gellan gum and a carrageenan. Carrageenan is added to the gelatine-free confectionery product because the gellan products "lack the gelatine-like texture due to their relatively low springiness and resiliency".
- the products containing gellan gum present processing difficulties such as the collapse of the chewy center after forming due to viscosity, which is lower than the one characterizing the products made with gelatine and a reduction of water migration due to the hygroscopicity of gellan gum which reduces the water migration from the chewy center to the surrounding candy layer.
- the multilayer confectionary products of the invention have, during processing, a chewy center coated by a surrounding at least partially amorphous candy layer with enough viscosity to be formed and optionally coated without collapsing.
- a specific ratio sugar/glucose syrup in the surrounding at least partially amorphous candy layer was surprisingly found to allow the surrounding candy layer to at least partially crystallize and to have the desired texture when the product reaches the consumer.
- the present invention discloses a confectionery product including a chewy center comprising sugar, glucose syrup and gellan gum, a layer of at least partially amorphous candy material surrounding said chewy center, wherein the ratio sugar/glucose syrup in the chewy center ranges from 54:46 to 49:51 on dry weight basis, wherein glucose syrup used in the chewy material and/or in the at least partially amorphous candy layer is characterized by a content of mono and disaccharides ranging from 25% to 35% by weight, on dry weight basis and containing at least 19% by weight of sugars having a DP index greater than 9, compared to the total weight of glucose syrup on dry weight basis, the chewy center being free of gelatin and other hydrocolloids different from gellan gum.
- Object of the present invention is a confectionery product including a chewy center comprising sugar, glucose syrup and gellan gum, a layer of at least partially amorphous candy material surrounding said chewy center, wherein the ratio sugar/glucose syrup in the chewy center ranges from 54:46 to 49:51 on dry weight basis characterized in that the chewy center is free of gelatin and other hydrocolloids different from gellan gum.
- the chewy center and the candy layer do not comprise gelatine and do not comprise gum arabic or other hydrocolloids different from gellan gum.
- hydrocolloids different from gellan gum means' in particular, hydrocolloids such as, for example, gum arabic, xanthan gum, agarose, pectin, starch, carrageenan, locust bean gum and their derivatives.
- the chewable center contains gellan gum as the only hydrocolloid.
- the layer of candy material does not comprise gelatin, gellan gum and other hydrocolloids such as for example those defined above.
- the confectionery material has at least one additional coating layer surrounding the candy layer.
- Gellan gum useful herein is or is derived from native gellan gum also referred as high acyl gellan.
- Native gellan gum is a polymer produced by inoculating a carefully formulated fermentation medium with the microorganism Sphingamonas elodea (ATIC 31461). Methods disclosed e.g. in U.S. Patents 4,326,052 and 4,385,123 . The outcome of the fermentation is a polysaccharide with a straight chain made of three monomers: glucose, rhamnose and glucuronic acid. The hydroxyl groups at C2 and C6 of glucose units can be esterified with acetyl and glyceryl groups. The native gellan polymer can be deacetylated to various extents.
- Gellan gum useful herein includes native gellan gum and any form derived therefrom and available, such as, but not limited to: non-clarified, clarified, and partially clarified native, deacetylated and partially deacetylated forms as well as mixtures thereof and the like.
- Gellan gum is available from CP Kelco Company, 1313 North Market Street, Wilmington, Delaware 19894, USA. Typical brand names include KELCOGEL and GELRITE. KELCOGEL and GELRITE are trademarks of CP Kelco Company.
- KELCOGEL F is particularly preferred.
- the amount of gellan gum in the chewy center preferably ranges from 0.02% to 1% by weight compared to the total weight of the chewy center, most preferably from 0.03% to 0.07% by weight compared to the total weight of the chewy center.
- the moisture content in the chewy center ranges from 6% to 10% by weight, most preferably from 6.8% to 8% by weight, compared to the total weight of the chewy center.
- the chewy center may further contain flavours, fats, emulsifiers, colours, acids and authorized food additives in general as reported for example in Reg.1129/2011 of the European Union or in the Codex Alimentarius.
- the fat is present from 1% to 12% by weight of the chewy candy material, preferably from 3% to 10% by weight of the chewy candy material, even more preferably from 5% to 8% by weight of the chewy candy material.
- the surrounding candy layer of at least partially amorphous candy material comprises sugar and glucose syrup.
- the ratio sugar/glucose syrup in the surrounding at least partially amorphous candy layer preferably ranges from 55:45 to 48:52 on dry weight basis, more preferably from 54:46 to 49:51 on dry weight basis and even more preferably from 53:47 to 50:50 on dry weight basis.
- the moisture content in the surrounding at least partially amorphous candy layer preferably ranges from 4% to 8% and more preferably from 4.5% to 5.8% by weight, compared to the weight of the surrounding at least partially amorphous candy layer.
- the surrounding at least partially amorphous candy layer may further contain flavour, fats, emulsifiers, colours, acids and authorized food additives in general as reported for example in Reg.1129/2011 of the European Union or in the Codex Alimentarius.
- the sugar used in the chewy material and in the surrounding at least partially amorphous candy layer is preferably selected from refined sugar with ICUMSA grade ⁇ 50, preferably ⁇ 30.
- the glucose syrup used in the chewy material and in the surrounding at least partially amorphous candy layer is characterized by a content of mono and disaccharides ranging from 25% to 35% by weight, more preferably from 28% to 34% by weight, on dry weight basis.
- Glucose syrup contains at least 19% by weight, more preferably from 20% to 28% by weight, of oligosaccharides having a DP index (degree of polymerization) greater than 9, compared to the total weight of glucose syrup on dry weight basis.
- the glucose syrup is high maltose glucose syrup, preferably containing total mono and disaccharides from 40% to 70%.
- the high maltose syrup preferably employed in the invention contains >50% total mono and disaccharides.
- the coating layer may be a hard or soft coating or a combination of hard and soft coating.
- the coating layer may have known composition and can be manufactured according to known methods as reported in E.B. Jackson, Sugar confectionery manufacture, 2nd Edition, Aspen Publishers Inc, Geithersburg, Maryland (1999 ) or J.A. Merl and K.W. Stock, Silesia Confiserie Manual No 4, Silesia Gerhard Hanke KG, Abt. frabucherei, Neuss - Germany (1996 ).
- the coating layer contains sugar, glucose, flavors, natural or artificial colours, thickeners (referred also as binding agents, e.g. starch), quick coat, fats, emulsifiers and additives in general.
- the coating does not contain titanium dioxide.
- confectionary products of the invention may be produced by a method comprising the steps of
- the chewy candy confectionery material provided at the phase a) can be prepared by sugar, glucose syrup and water which are combined in the preferred ratios and cooked under vacuum to the preferred water content.
- Gellan gum can be added as a solution after cooking.
- a gellan solution is added to the sugar, glucose syrup and water mix before cooking. It has been surprisingly found that when gellan gum replaces gelatine, the vacuum cooked mass generates less foam. This translates in higher efficiency, allowing the cooker to work continuously more than 72h and even more than 100h vs 24h of continuous operation with gelatine containing formula.
- Emulsifiers and fats are added before or after cooking.
- the chewy mass is lecithin free and sucrose esters of fatty acids are preferred emulsifiers. It has been surprisingly found that sucrose esters of fatty acids speed up the sugar crystal formation in the chewy mass, reducing the time needed for pulling.
- the cooked mass is preferably pulled, inseminated with powdered sugar or previously crystallized chewy mass.
- Flavours, colours, acids are added in the pulling machines or in in line mixers or at the moment of the extrusion.
- the chewy mass completed with previously mentioned ingredients is combined with the hard candy mass.
- the mass of candy confectionery material is prepared by mixing sugar, glucose syrup and water and cooked under vacuum according to known methods to the target residual moisture.
- the candy mass After cooking the candy mass is added with flavours, colours and other additives.
- the boiled mass of candy confectionery material is added with powdered sugar.
- Both the candy confectionery material and the chewy candy material are cooled and transported to a combining unit, like an extrusion machine or a batch roller machine, or any suitable means known to the technician used to prepare a rope of concentrically combined materials, wherein the inner part is made by the chewy confectionery material comprising at least partially crystallized sugar and the outer part, surrounding said chewy confectionery material, is made by hard candy confectionery material comprising at least partly amorphous sugar.
- the chewy candy confectionery material comprises sugar in crystalline state for more than 80%, preferably more than 90%, or even more than 95% over the total sugar of the chewy candy material.
- the hard candy confectionery material comprises sugar in amorphous form from 80% to 99.9% of the sugar present in the hard candy confectionery material, preferably from 95% to 99.5% of the sugar present in the hard candy confectionery material.
- the rope of combined confectionery material is reduced to the desired diameter in a rope sizer comprising at least two couples sizing wheels, preferably at least four couples of sizing wheels, and then reduced to singles pieces by any suitable means, comprising die forming, stamping, cutting, ball forming.
- the single pieces of combined candy material are cooled in cooling tunnel.
- the resulting candies have an outer hard layer of at least partially amorphous candy and an inner core of chewy material and can be then packed and sold after a suitable time to allow the amorphous sugar to crystallize.
- the candies can be polished, dusted or coated in a coating pan.
- Any type of coating is possible, comprised chocolate coating, compound coating, hard coating, soft coating, sanding, dusting and silvering.
- One or more coatings can be combined together and a final polishing layer can be included to add shine and lustre to the candies.
- coating operations are started from a few minutes to 24h after candy forming.
- coated candies are packed and sold after a suitable time to allow the amorphous sugar to crystallize.
- the amorphous sugar of the candy material is induced to at least partially crystallized in controlled conditions.
- compositions of the chewy centers and the evaluation of the obtained product are reported in the following Tables 1-5.
- Example 1 (comparative -Arabic gum based recipe, gelatine free, according to EP2117336B1 - example 2)
- Example 3 gellan gum based recipe- preferred range of sugar/glucose ratio
- Example 4 gellan gum based recipe- borderline value of the range of sugar/glucose ratio
- Example 5 gellan gum based recipe- borderline value of the range of sugar/glucose ratio
- compositions of the candy layer and the evaluation of the obtained product are reported in the following Tables 6-10.
- Example 6 (comparative according to EP2117336B1 - example 2)
- Example 8 (preferred range of sugar/glucose ratio)
- Example 11 Candies with acceptable quality, some portion of the candy material is soft as reported in EP2117336B1 .
- Example 12 Candies with very good quality, better than 11, all the candy material is soft and crystallized. Chewiness is consistent without breaking of the center in pieces. Good crack of the coating part.
- Example 13 Candies with very good quality, non-distinguishable from those of Ex.12, better than those of Ex.11, all the candy material is soft and crystallized. Chewiness is consistent without breaking of the center in pieces. Good crack of the coating part.
- Example 14 Candies with acceptable quality, the candy material is soft and crystallized. Chewiness tend to be too plastic with reduced elasticity and changes from candy to candy, a residual part of the candies start to have too much or too little filling, some deshaping during coating. Very good crack of the coating part.
- Example 15 Candies with acceptable quality, some portion of the candy material is soft similarly to EP2117336 . Chewiness tend to be difficult to evaluate because in a residual part of the pieces the hard candy part being in part soft and in part hard. Good crack of the coating part.
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Food Science & Technology (AREA)
- Polymers & Plastics (AREA)
- Health & Medical Sciences (AREA)
- Molecular Biology (AREA)
- Inorganic Chemistry (AREA)
- Confectionery (AREA)
- Jellies, Jams, And Syrups (AREA)
Description
- The invention relates to coated gelatine-free confectionery products having a chewy center containing gellan gum, and to a method for producing them.
- Chewy candies with a chewy center with a hard candy shell are known in the art.
-
EP1104652A1 discloses confectionery products in which a mixture of starch and pectin is used as a gelling agent. It also discloses a process for preparing a hydrocolloid confectionery product. The hydrocolloid confectionery product is preferably gelatin-free. -
WO 2006/083784 andWO 2008/091476 disclose multilayer confectionary product having a chewy center including an ingestible dextrin, optionally gum arabic, a sweetener, water and flavour, an intermediate layer including a flavour and a sweetener which is at least partially crystalline and an outer shell which is a crunchy hard shell. The sweeteners may be sucrose and corn syrup. - Hydrocolloids are commonly used as gelling agent in a sugar/glucose syrup system. One of the most common hydrocolloids used in sugar confectionery is gelatine used primarily as a gelling agent. Gelatine imparts to the chewy sugar confectionery an unique viscoelastic texture (referred to as e.g. springiness and resilience) especially desirable to consumers. The presence of gelatine improve the manufacturing process, providing a desirable viscosity to the semi-finished confectionery material, making easier to pump, extrude or convey the material along the different stages of the production. Moreover, gelatine has an emulsifying power which allows to homogenize fat with sugar, glucose syrup and residual moisture of chewy candies. However, gelatine is of animal origin.
- Due to ethical, religious, dietary restrictions or a vegetarian diet, there is an increasing demand of products that are free from ingredients derived from animal sources. Thus, alternatives to gelatine have been sought to produce gelatine-free confectionary products with a gelatine-like texture.
- Gum arabic, reported in
WO2006/083784 , is a thickening and gelling agent of vegetable origin used in chewy confectionery and can be an alternative to gelatine, however the geographical origin of gum arabic, which is produced in some African countries, makes the supply extremely variable year after year. Thus, it is also desirable to find alternatives to gum arabic as well as to gelatine. -
WO2011/153229 discloses a dough-like confectionary material employed as layering or coating material which contain 70-98% of solid particulates of sugar, sugar alcohol or mixtures thereof and 0.1-20% of a diffusion controller which may be, among the others, gelatine or gellan. The diffusion controller used in the examples is xanthan gum. -
WO02/30214 - The products containing gellan gum present processing difficulties such as the collapse of the chewy center after forming due to viscosity, which is lower than the one characterizing the products made with gelatine and a reduction of water migration due to the hygroscopicity of gellan gum which reduces the water migration from the chewy center to the surrounding candy layer.
- It has now been found that a chewy center based on sugar/glucose syrup wherein gelatine has been replaced by gellan gum preferably without the presence of gum arabic and other hydrocolloids has the desired properties of viscosity when the ratio sugar/glucose syrup is maintained in a specific range.
- The multilayer confectionary products of the invention have, during processing, a chewy center coated by a surrounding at least partially amorphous candy layer with enough viscosity to be formed and optionally coated without collapsing.
- Furthermore, a specific ratio sugar/glucose syrup in the surrounding at least partially amorphous candy layer was surprisingly found to allow the surrounding candy layer to at least partially crystallize and to have the desired texture when the product reaches the consumer.
- The present invention is defined by the claims.The present invention discloses a confectionery product including a chewy center comprising sugar, glucose syrup and gellan gum, a layer of at least partially amorphous candy material surrounding said chewy center, wherein the ratio sugar/glucose syrup in the chewy center ranges from 54:46 to 49:51 on dry weight basis, wherein glucose syrup used in the chewy material and/or in the at least partially amorphous candy layer is characterized by a content of mono and disaccharides ranging from 25% to 35% by weight, on dry weight basis and containing at least 19% by weight of sugars having a DP index greater than 9, compared to the total weight of glucose syrup on dry weight basis, the chewy center being free of gelatin and other hydrocolloids different from gellan gum.
- Object of the present invention is a confectionery product including a chewy center comprising sugar, glucose syrup and gellan gum, a layer of at least partially amorphous candy material surrounding said chewy center, wherein the ratio sugar/glucose syrup in the chewy center ranges from 54:46 to 49:51 on dry weight basis characterized in that the chewy center is free of gelatin and other hydrocolloids different from gellan gum.
- The chewy center and the candy layer do not comprise gelatine and do not comprise gum arabic or other hydrocolloids different from gellan gum.
- The expression "other hydrocolloids different from gellan gum" means' in particular, hydrocolloids such as, for example, gum arabic, xanthan gum, agarose, pectin, starch, carrageenan, locust bean gum and their derivatives.
- In other words, the chewable center contains gellan gum as the only hydrocolloid.
- Preferably the layer of candy material does not comprise gelatin, gellan gum and other hydrocolloids such as for example those defined above.
- Preferably the confectionery material has at least one additional coating layer surrounding the candy layer.
- The preferred ratio sugar/glucose syrup in the chewy layer 50:50 to 53:47on dry weight basis.
- Gellan gum useful herein is or is derived from native gellan gum also referred as high acyl gellan.
- Native gellan gum is a polymer produced by inoculating a carefully formulated fermentation medium with the microorganism Sphingamonas elodea (ATIC 31461). Methods disclosed e.g. in
U.S. Patents 4,326,052 and4,385,123 . The outcome of the fermentation is a polysaccharide with a straight chain made of three monomers: glucose, rhamnose and glucuronic acid. The hydroxyl groups at C2 and C6 of glucose units can be esterified with acetyl and glyceryl groups. The native gellan polymer can be deacetylated to various extents. - (a) Native or high-acyl gellan gum
- (b) Low-acyl gellan gum
- Gellan gum useful herein includes native gellan gum and any form derived therefrom and available, such as, but not limited to: non-clarified, clarified, and partially clarified native, deacetylated and partially deacetylated forms as well as mixtures thereof and the like.
- Gellan gum is available from CP Kelco Company, 1313 North Market Street, Wilmington, Delaware 19894, USA. Typical brand names include KELCOGEL and GELRITE. KELCOGEL and GELRITE are trademarks of CP Kelco Company.
- Particularly preferred is KELCOGEL F.
- The amount of gellan gum in the chewy center preferably ranges from 0.02% to 1% by weight compared to the total weight of the chewy center, most preferably from 0.03% to 0.07% by weight compared to the total weight of the chewy center.
- Preferably. the moisture content in the chewy center ranges from 6% to 10% by weight, most preferably from 6.8% to 8% by weight, compared to the total weight of the chewy center.
- The chewy center may further contain flavours, fats, emulsifiers, colours, acids and authorized food additives in general as reported for example in Reg.1129/2011 of the European Union or in the Codex Alimentarius.
- In one embodiment the fat is present from 1% to 12% by weight of the chewy candy material, preferably from 3% to 10% by weight of the chewy candy material, even more preferably from 5% to 8% by weight of the chewy candy material.
- The surrounding candy layer of at least partially amorphous candy material comprises sugar and glucose syrup.
- The ratio sugar/glucose syrup in the surrounding at least partially amorphous candy layer preferably ranges from 55:45 to 48:52 on dry weight basis, more preferably from 54:46 to 49:51 on dry weight basis and even more preferably from 53:47 to 50:50 on dry weight basis.
- The moisture content in the surrounding at least partially amorphous candy layer preferably ranges from 4% to 8% and more preferably from 4.5% to 5.8% by weight, compared to the weight of the surrounding at least partially amorphous candy layer.
- The surrounding at least partially amorphous candy layer may further contain flavour, fats, emulsifiers, colours, acids and authorized food additives in general as reported for example in Reg.1129/2011 of the European Union or in the Codex Alimentarius.
- The sugar used in the chewy material and in the surrounding at least partially amorphous candy layer is preferably selected from refined sugar with ICUMSA grade <50, preferably ≤30.
- The glucose syrup used in the chewy material and in the surrounding at least partially amorphous candy layer is characterized by a content of mono and disaccharides ranging from 25% to 35% by weight, more preferably from 28% to 34% by weight, on dry weight basis.
- Glucose syrup contains at least 19% by weight, more preferably from 20% to 28% by weight, of oligosaccharides having a DP index (degree of polymerization) greater than 9, compared to the total weight of glucose syrup on dry weight basis.
- Alternatively, as not part of the invention, the glucose syrup is high maltose glucose syrup, preferably containing total mono and disaccharides from 40% to 70%. The high maltose syrup preferably employed in the invention contains >50% total mono and disaccharides.
- The coating layer may be a hard or soft coating or a combination of hard and soft coating.
- The coating layer may have known composition and can be manufactured according to known methods as reported in E.B. Jackson, Sugar confectionery manufacture, 2nd Edition, Aspen Publishers Inc, Geithersburg, Maryland (1999) or J.A. Merl and K.W. Stock, Silesia Confiserie Manual No 4, Silesia Gerhard Hanke KG, Abt. Fachbucherei, Neuss - Germany (1996).
- Preferably the coating layer contains sugar, glucose, flavors, natural or artificial colours, thickeners (referred also as binding agents, e.g. starch), quick coat, fats, emulsifiers and additives in general. Preferably the coating does not contain titanium dioxide.
- The confectionary products of the invention may be produced by a method comprising the steps of
- a) providing a gelatine free chewy candy confectionery material comprising sugar, glucose syrup and gellan gum wherein the ratio sugar/glucose syrup ranges from 54:46 to 49:51 on dry weight basis characterized in that the chewy center is free of gelatin and other hydrocolloids different from gellan gum;
- b) providing a candy confectionery material comprising at least partially amorphous sugar and glucose syrup;
- c) combining the chewy confectionery material and the candy material so that the candy material surrounds a core of confectionery material;
- d) allowing the amorphous sugar of the candy material to at least partially crystallize.
- The chewy candy confectionery material provided at the phase a) can be prepared by sugar, glucose syrup and water which are combined in the preferred ratios and cooked under vacuum to the preferred water content. Gellan gum can be added as a solution after cooking. In a preferred embodiment a gellan solution is added to the sugar, glucose syrup and water mix before cooking. It has been surprisingly found that when gellan gum replaces gelatine, the vacuum cooked mass generates less foam. This translates in higher efficiency, allowing the cooker to work continuously more than 72h and even more than 100h vs 24h of continuous operation with gelatine containing formula.
- Emulsifiers and fats are added before or after cooking. Preferably the chewy mass is lecithin free and sucrose esters of fatty acids are preferred emulsifiers. It has been surprisingly found that sucrose esters of fatty acids speed up the sugar crystal formation in the chewy mass, reducing the time needed for pulling.
- The cooked mass is preferably pulled, inseminated with powdered sugar or previously crystallized chewy mass. Flavours, colours, acids are added in the pulling machines or in in line mixers or at the moment of the extrusion. The chewy mass completed with previously mentioned ingredients is combined with the hard candy mass.
- The mass of candy confectionery material is prepared by mixing sugar, glucose syrup and water and cooked under vacuum according to known methods to the target residual moisture.
- After cooking the candy mass is added with flavours, colours and other additives. In a preferred embodiment, the boiled mass of candy confectionery material is added with powdered sugar.
- Both the candy confectionery material and the chewy candy material are cooled and transported to a combining unit, like an extrusion machine or a batch roller machine, or any suitable means known to the technician used to prepare a rope of concentrically combined materials, wherein the inner part is made by the chewy confectionery material comprising at least partially crystallized sugar and the outer part, surrounding said chewy confectionery material, is made by hard candy confectionery material comprising at least partly amorphous sugar.
- In one preferred embodiment, at this stage the chewy candy confectionery material comprises sugar in crystalline state for more than 80%, preferably more than 90%, or even more than 95% over the total sugar of the chewy candy material.
- At the same time the hard candy confectionery material comprises sugar in amorphous form from 80% to 99.9% of the sugar present in the hard candy confectionery material, preferably from 95% to 99.5% of the sugar present in the hard candy confectionery material.
- The rope of combined confectionery material is reduced to the desired diameter in a rope sizer comprising at least two couples sizing wheels, preferably at least four couples of sizing wheels, and then reduced to singles pieces by any suitable means, comprising die forming, stamping, cutting, ball forming.
- The single pieces of combined candy material are cooled in cooling tunnel.
- The resulting candies have an outer hard layer of at least partially amorphous candy and an inner core of chewy material and can be then packed and sold after a suitable time to allow the amorphous sugar to crystallize.
- Alternatively the candies can be polished, dusted or coated in a coating pan.
- Any type of coating is possible, comprised chocolate coating, compound coating, hard coating, soft coating, sanding, dusting and silvering.
- One or more coatings can be combined together and a final polishing layer can be included to add shine and lustre to the candies.
- In a preferred embodiment coating operations are started from a few minutes to 24h after candy forming.
- The coated candies are packed and sold after a suitable time to allow the amorphous sugar to crystallize. In a preferred embodiment the amorphous sugar of the candy material is induced to at least partially crystallized in controlled conditions.
- It has been surprisingly found that controlling the conditions as reported above allows the crystallization of the amorphous sugar originally present in the hard candy confectionery material of ≥ 80%, preferably ≥ 90% in percentage of the sugar present in the originally hard candy material.
- The ingredients were weighed and combined according to the method reported in Example 1 of
EP2117336B1 . - The compositions of the chewy centers and the evaluation of the obtained product are reported in the following Tables 1-5.
-
Table 1 Ingredient Solids % Wet weight % Dry weight (Kg) Final chewy material weight % Sugar/Glucose ratio (dry basis) Sugar 100 33 33 37.35 55 Glucose Syrup 80 33 27.06 30.63 45 Water 0 11 0 Nutriose 100 6 6 6.79 Water 0 2 0 Gum Arabic 100 2 2 2.26 Gelatine 100 Gellan gum 100 Fat - Hydrogenated Palm Kernel Oil 100 8 8 9.06 Fat - Fractionated oil 100 Glyceride 100 0.2 0.2 0.23 Lecithin 100 0.2 0.2 0.23 Sucrose esters 100 Powder Sugar 100 5 5 5.66 Rework 93 Flavor 100 0.7 0.7 0.79 Residual water 7.00 Total 101.1 82.16 100.00 Evaluation: The obtained chewy material is a consistent dough, fully grained, with some fat sweating and some gum arabic flavor. -
Table 2 Ingredient Solids % Wet weight (Kg) Dry weight (kg) Final chewy material weight % Sugar/Glucose ratio (dry basis) Sugar 100 10.6 10.6 48.02 55 Glucose Syrup 80 10.6 8.7 39.38 45 Water 0 2.8 Nutriose 100 Water 0 1 Gum Arabic 100 Gelatine 100 0.01 0.01 0.05 Gellan gum 100 Fat - Hydrogenated 100 1 1 4.53 Palm Kernel Oil 100 Fat - Fractionated 100 Glyceride 100 Lecithin Sucrose esters 100 0.01 0.01 0.05 Powder Sugar 100 Rework 93 0.2 0.186 0.84 Flavor 100 0.03 0.03 0.14 Residual water 7.00 Total 26.25 20.51 100.00 Evaluation: The obtained chewy material is a consistent dough, fully grained. It can be easily transported and joined to the candy material -
Table 3 Ingredient solids % Wet weight (Kg) Dry weight (kg) Final chewy material % Sugar/Glucose ratio (dry basis) Sugar 100 12.00 12.00 43.53 50 Glucose Syrup 82 14.50 11.89 43.13 50 Water 0 5.00 Nutriose 100 Water 0 Gum Arabic 100 Gelatine 100 Gellan gum 100 0.01 0.01 0.05 Fat - Hydrogenated Palm Kernel Oil 100 Fat - Fractionated oil 100 1.65 1.65 5.99 Glyceride 100 Lecithin 100 Sucrose esters 100 0.01 0.01 0.05 Powder Sugar 100 Rework 93 Flavor 100 0.07 0.07 0.25 Residual water 7 Total 33.248 25.6 100.0 -
Table 4 Ingredient solids % Wet Weight (Kg) Dry weight (kg) Final chewy material % Sugar/Glucose ratio (dry basis) Sugar 100 13.00 13.00 46.83 54 Glucose Syrup 82 13.50 11.07 39.88 46 Water 0 5.00 Nutriose 100 Water 0 Gum Arabic 100 Gelatine 100 Gellan gum 100 0.01 0.01 0.05 Fat - Hydrogenated Palm Kernel Oil 100 Fat - Fractionated oil 100 1.65 1.65 5.94 Glyceride 100 Lecithin 100 Sucrose esters 100 0.01 0.01 0.05 Powder Sugar 100 Rework 93 Flavor 100 0.07 0.07 0.25 Residual water 7 Total 33.248 25.8 100.0 Evaluation: The obtained chewy material is a soft acceptable dough (somewhat softer than the chewy material of Example 1 and Example 2), fully crystallized. It can be transported but the transport parameters need to be adjusted (time- cooling) -
Table 5 Ingredient solids % Wet weight (Kg) Dry weight (kg) Final chewy material % Sugar/Glucose ratio (dry basis) Sugar 100 11.50 11.50 41.86 48 Glucose Syrup 82 15.00 12.30 44.77 52 Water 0 5.00 Nutriose 100 Water 0 Gum Arabic 100 Gelatine 100 Gellan gum 100 0.01 0.01 0.05 Fat - Hydrogenated Palm Kernel Oil 100 Fat - Fractionated oil 100 1.65 1.65 6.01 Glyceride 100 Lecithin 100 Sucrose esters 100 0.01 0.01 0.05 Powder Sugar 100 Rework 93 Flavor 100 0.07 0.07 0.25 Residual water 7 Total 33.248 25.5 100.0 Evaluation: The obtained chewy material is an acceptable tough dough (somewhat harder with the chewy material of Example 1 and Example 2), fully crystallized. It can be transported but the transport parameters need to be adjusted (time- cooling) - Candy material is prepared according to the method of Example 1 of
EP2117336B1 , weighing the ingredients except powder sugar and boiling under vacuum till reaching the desired residual water. The obtained liquid mass is combined after cooking with the powder sugar and cooled to a plastic pliable mass. - The compositions of the candy layer and the evaluation of the obtained product are reported in the following Tables 6-10.
-
Table 6 Ingredient Solids % Wet weight (Kg) Dry weight (Kg) Final candy material % Sugar/Glucose ratio (dry basis)) Sugar 100 57 57 66.25 70 Glucose Syrup 82 30 24.6 28.59 30 Water 0 12 Powder Sugar 100 Flavor 100 1 1 1.16 Residual water 4.00 Total 100 82.6 100.00 Evaluation: The obtained candy material is a consistent dough, fully glassy, with poor plasticity and some tendency to break even when warm. -
Table 7 Ingredient Solids % Wet weight (Kg) Dry weight (kg) Final candy material % Sugar/Glucose ratio (dry) Sugar 100 49 49.00 50.67 54 Glucose Syrup 82 51 41.82 43.24 46 Water 0 Powder Sugar 100 1.88 1.88 1.94 Flavor 100 0.14 0.14 0.14 Residual water 4.00 Total 102.02 92.84 100.00 Evaluation: The obtained candy material is a consistent dough, fully amorphous except for the powder sugar part. -
Table 8 Ingredient Solids % Wet weight (Kg) Dry weight (kg) Final candy material % Sugar/Glucose ratio (dry) Sugar 100 10.69 10.69 48.96 52 Glucose Syrup 82 11.96 9.81 44.92 48 Water 0 3.23 0.00 Powder Sugar 100 0.43 0.43 1.97 Flavor 100 0.03 0.03 0.15 Residual water 4 Total 26.34 20.96 100.00 Evaluation: The obtained candy material is a consistent dough, fully amorphous except for the powder sugar part. -
Table 9 Ingredient Solids % Wet weight (Kg) Dry weight (kg) Final candy material % Sugar/Glucose ratio (dry) Sugar 100 10.95 10.95 50.24 54 Glucose Syrup 82 11.60 9.51 43.64 46 Water 0 3.23 Powder Sugar 100 0.43 0.43 1.97 Flavor 100 0.03 0.03 0.15 Residual water 4 Total 26.24 20.92 100.00 Evaluation: The obtained candy material is a consistent dough, fully amorphous except for the powder sugar part -
Table 10 Ingredient Solids % Wet weight (Kg) Dry weight (kg) Final candy material % Sugar/Glucose ratio (dry) Sugar 100 9.80 9.80 44.97 48 Glucose Syrup 82 13.00 10.66 48.91 52 Water 0 3.23 Powder Sugar 100 0.43 0.43 1.97 Flavor 100 0.03 0.03 0.15 Residual water 4 Total 26.49 20.92 100.00 Evaluation: The obtained candy material, is a consistent dough, fully amorphous except for the powder sugar part - The chewy material and the candy material obtained in the previous examples were combined and formed according to known methods to form centers with two concentric layers, an inner core of chewy material surrounded by a layer of candy material. Suitable methods are reported in
WO00/06127 TABLE 11 Ex. 11 (comparative) Ex. 12 (comparative) Ex. 13 Ex. 14 Ex. 15 Material Sugar/Glucose ratio (dry basis) % % % % % Chewy material- Ex.1 (comparative- EP21173336B1 55/45 60 Chewy material- Ex.2 (comparative-gelatine based recipe) 54/46 40 Chewy material- Ex.3 (preferred range of sugar/glucose ratio) 50/50 40 Chewy material- Ex.4 (borderline value of sugar/glucose ratio) 54/46 40 Chewy material -Ex.5 (borderline value of sugar/glucose ratio) 48/52 40 Candy material- Ex.6 (comparative- EP21173336B1 70/30 40 Candy material- Ex.7 (borderline value of preferred sugar/glucose ratio) 54/46 60 Candy material- Ex.8 (preferred range of sugar/glucose ratio) 52/48 60 Candy material- Ex.9 (borderline value of preferred sugar/glucose ratio) 54/46 60 Candy material- Ex. 10 (borderline value of preferred sugar/glucose ratio) 48/52 60 Total 100 100 100 100 100 Hard coating Overweight % 30 30 30 30 30 Evaluation Average crack (1-10) 7 8 8 9 8 Average softness first bite (1-10) 5 7 7 8 5 Average chew experience (1-10) 6 8 8 6 6 - Example 11 (comparative): Candies with acceptable quality, some portion of the candy material is soft as reported in
EP2117336B1 . - Example 12 (comparative): Candies with very good quality, better than 11, all the candy material is soft and crystallized. Chewiness is consistent without breaking of the center in pieces. Good crack of the coating part.
- Example 13: Candies with very good quality, non-distinguishable from those of Ex.12, better than those of Ex.11, all the candy material is soft and crystallized. Chewiness is consistent without breaking of the center in pieces. Good crack of the coating part.
- Example 14: Candies with acceptable quality, the candy material is soft and crystallized. Chewiness tend to be too plastic with reduced elasticity and changes from candy to candy, a residual part of the candies start to have too much or too little filling, some deshaping during coating. Very good crack of the coating part.
- Example 15: Candies with acceptable quality, some portion of the candy material is soft similarly to
EP2117336 . Chewiness tend to be difficult to evaluate because in a residual part of the pieces the hard candy part being in part soft and in part hard. Good crack of the coating part.
Claims (11)
- A confectionery product including a chewy center comprising sugar, glucose syrup and gellan gum, a layer of at least partially amorphous candy material surrounding said chewy center, wherein the ratio sugar/glucose syrup in the chewy center ranges from 54:46 to 49:51on dry weight basis, wherein glucose syrup used in the chewy material and/or in the at least partially amorphous candy layer is characterized by a content of mono and disaccharides ranging from 25% to 35% by weight, on dry weight basis and containing at least 19% by weight of sugars having a DP index greater than 9, compared to the total weight of glucose syrup on dry weight basis, the chewy center being free of gelatin and other hydrocolloids different from gellan gum.
- The confectionery product according to claim 1 wherein the ratio sugar/glucose syrup in the chewy layer is 50:50 to 53:47 on dry weight basis.
- The confectionery product according to claim 1 or 2 wherein the amount of gellan gum in the chewy center ranges from 0.02% to 1% by weight compared to the total weight of the chewy center.
- The confectionary product according to anyone of the preceding claims wherein the moisture content in the chewy center ranges from 6% to 10% by weight compared to the total weight of the chewy center.
- The confectionary product according to anyone of the preceding claims wherein the layer of said at least partially amorphous candy material comprises sugar and glucose syrup.
- The confectionary product according to claim 5 wherein the ratio sugar/glucose syrup in the layer of said at least partially amorphous candy material ranges from 55:45 to 48:52 on dry weight basis.
- The confectionary product according to anyone of the preceding claims wherein the moisture content in the in the at least partially amorphous candy layer preferably ranges from 4% to 8% by weight compared to the total weight of the at least partially amorphous candy layer.
- The confectionary product according to anyone of claims 1 to 7 wherein the glucose syrup is high maltose glucose syrup.
- The confectionery product according to claim 1 additionally comprising at least one coating layer.
- The confectionary product according to anyone of the preceding claims wherein at least one coating layer is a hard or soft coating or a combination of hard and soft coating.
- A method for manufacturing the confectionary product as defined in claim 1 comprising the steps of:a) providing a chewy candy confectionery material comprising sugar, glucose syrup and gellan gum wherein the ratio sugar/glucose syrup ranges from 54:46 to 49:51 on dry weight basis characterized in that the chewy center is free of gelatin and other hydrocolloids different from gellan gum;b) providing a candy material comprising at least partly amorphous sugar and glucose syrup wherein the ratio sugar/glucose syrup ranges from 55:45 to 48:52;c) combining the chewy confectionery material and the candy material so that the candy material surrounds a core of chewy confectionery material:d) allowing the amorphous sugar of the candy material to at least partially crystallize.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
IT102019000024027A IT201900024027A1 (en) | 2019-12-16 | 2019-12-16 | CONFECTIONERY PRODUCT AND ITS MANUFACTURING PROCESS |
PCT/EP2020/085999 WO2021122463A1 (en) | 2019-12-16 | 2020-12-14 | Confectionery product and manufacturing process thereof |
Publications (2)
Publication Number | Publication Date |
---|---|
EP4075999A1 EP4075999A1 (en) | 2022-10-26 |
EP4075999B1 true EP4075999B1 (en) | 2024-04-10 |
Family
ID=69904104
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP20830132.5A Active EP4075999B1 (en) | 2019-12-16 | 2020-12-14 | Confectionery product and manufacturing process thereof |
Country Status (14)
Country | Link |
---|---|
US (1) | US20230036873A1 (en) |
EP (1) | EP4075999B1 (en) |
JP (1) | JP2023505733A (en) |
CN (1) | CN114845558B (en) |
AU (1) | AU2020410249A1 (en) |
BR (1) | BR112022011900A2 (en) |
CA (1) | CA3161911A1 (en) |
DK (1) | DK4075999T3 (en) |
FI (1) | FI4075999T3 (en) |
IT (1) | IT201900024027A1 (en) |
MX (1) | MX2022007283A (en) |
PL (1) | PL4075999T3 (en) |
PT (1) | PT4075999T (en) |
WO (1) | WO2021122463A1 (en) |
Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP1023841B1 (en) * | 1999-01-29 | 2006-08-09 | Societe Des Produits Nestle S.A. | Chewy confectionery product |
Family Cites Families (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
KR830002802B1 (en) | 1978-12-04 | 1983-12-16 | 제임스 에프 · 너우톤 | Method for preparing polysaccharide S-60 by bacterial fermentation |
US4385123A (en) | 1979-06-08 | 1983-05-24 | Merck & Co., Inc. | Deacetylated polysaccharide S-60 |
WO2000006127A1 (en) | 1998-07-30 | 2000-02-10 | Warner-Lambert Company | Centerfill delivery system for nutraceuticals |
GB9928688D0 (en) * | 1999-12-03 | 2000-02-02 | Nestle Sa | Hydrocolloid confectionery product |
US6586032B2 (en) | 2000-10-12 | 2003-07-01 | Cp Kelco U.S. Inc. | Gelatin-free gummy confection using gellan gum and carrageenan |
US8048470B2 (en) | 2005-02-01 | 2011-11-01 | Wm. Wrigley, Jr. Company | Coated confectionary product |
CN101588726A (en) | 2007-01-19 | 2009-11-25 | Wm.雷格利Jr.公司 | Method of preparing a coated confectionary product |
ES2564646T3 (en) | 2010-06-02 | 2016-03-28 | Intercontinental Great Brands Llc | Confectionery composition and article |
EP3345487A1 (en) * | 2017-01-04 | 2018-07-11 | Perfetti Van Melle S.p.A. | Method for preparing a multilayer confectionary product |
CN111093381A (en) * | 2017-09-15 | 2020-05-01 | Wm.雷格利 Jr.公司 | Chewy confectionery product |
CN107821714A (en) * | 2017-10-13 | 2018-03-23 | 奇峰(福建)食品有限公司 | A kind of Collagent casing for sausages fruit juice jelly and preparation method thereof |
-
2019
- 2019-12-16 IT IT102019000024027A patent/IT201900024027A1/en unknown
-
2020
- 2020-12-14 FI FIEP20830132.5T patent/FI4075999T3/en active
- 2020-12-14 AU AU2020410249A patent/AU2020410249A1/en active Pending
- 2020-12-14 PT PT208301325T patent/PT4075999T/en unknown
- 2020-12-14 PL PL20830132.5T patent/PL4075999T3/en unknown
- 2020-12-14 DK DK20830132.5T patent/DK4075999T3/en active
- 2020-12-14 WO PCT/EP2020/085999 patent/WO2021122463A1/en unknown
- 2020-12-14 CN CN202080087022.XA patent/CN114845558B/en active Active
- 2020-12-14 EP EP20830132.5A patent/EP4075999B1/en active Active
- 2020-12-14 US US17/785,336 patent/US20230036873A1/en active Pending
- 2020-12-14 MX MX2022007283A patent/MX2022007283A/en unknown
- 2020-12-14 BR BR112022011900A patent/BR112022011900A2/en unknown
- 2020-12-14 CA CA3161911A patent/CA3161911A1/en active Pending
- 2020-12-14 JP JP2022536535A patent/JP2023505733A/en active Pending
Patent Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP1023841B1 (en) * | 1999-01-29 | 2006-08-09 | Societe Des Produits Nestle S.A. | Chewy confectionery product |
Also Published As
Publication number | Publication date |
---|---|
DK4075999T3 (en) | 2024-04-29 |
IT201900024027A1 (en) | 2021-06-16 |
WO2021122463A1 (en) | 2021-06-24 |
EP4075999A1 (en) | 2022-10-26 |
MX2022007283A (en) | 2022-07-12 |
FI4075999T3 (en) | 2024-07-09 |
CN114845558B (en) | 2024-06-25 |
AU2020410249A1 (en) | 2022-08-04 |
CA3161911A1 (en) | 2021-06-24 |
JP2023505733A (en) | 2023-02-10 |
US20230036873A1 (en) | 2023-02-02 |
PL4075999T3 (en) | 2024-07-08 |
BR112022011900A2 (en) | 2022-11-22 |
CN114845558A (en) | 2022-08-02 |
PT4075999T (en) | 2024-06-20 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
US6531174B2 (en) | Chewy confectionery product | |
EP1774856B1 (en) | Low-calorie food bar | |
US8029849B2 (en) | Multi-piece food product and method for making the same | |
US10327466B2 (en) | All natural fruit snack and method of manufacturing an all natural fruit snack | |
US20220346404A1 (en) | Confectionery product and multilayer confectionary item | |
JP5729113B2 (en) | Sugarless hard gummy candy and method for producing the same | |
JP5492537B2 (en) | Sugar coating composition, bakery product coated with the sugar coating composition, and method for producing the bakery product | |
JP2017158526A (en) | Gummy edible composition | |
KR101776888B1 (en) | Composition and Manufacturing Method of Soft Candy Sugar Free | |
EP2943073B1 (en) | Chewy confectionery product | |
JP4929027B2 (en) | Chocolate with high moisture content | |
EP4075999B1 (en) | Confectionery product and manufacturing process thereof | |
EP4075998B1 (en) | Confectionery product with reduced amount of sugar and manufacturing process thereof | |
RU2826394C1 (en) | Confectionary product and method for production thereof | |
EP3727009B1 (en) | Chewy confectionary product comprising erythritol | |
JP2012161260A (en) | Hard gummi candy with reduced surface recession | |
AU2015201069B2 (en) | All natural fruit snack and method of manufacturing an all natural fruit snack | |
JP2010088410A (en) | Frozen jelly sweet covered with chocolate and method for producing the same | |
JP2010273651A (en) | Massive gummi candy composition and method for producing the same | |
MXPA00000944A (en) | Chewy confectionery product | |
JP2013143922A (en) | Gel-containing chocolate combined cake and method for producing the same |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
STAA | Information on the status of an ep patent application or granted ep patent |
Free format text: STATUS: UNKNOWN |
|
STAA | Information on the status of an ep patent application or granted ep patent |
Free format text: STATUS: THE INTERNATIONAL PUBLICATION HAS BEEN MADE |
|
PUAI | Public reference made under article 153(3) epc to a published international application that has entered the european phase |
Free format text: ORIGINAL CODE: 0009012 |
|
STAA | Information on the status of an ep patent application or granted ep patent |
Free format text: STATUS: REQUEST FOR EXAMINATION WAS MADE |
|
17P | Request for examination filed |
Effective date: 20220701 |
|
AK | Designated contracting states |
Kind code of ref document: A1 Designated state(s): AL AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HR HU IE IS IT LI LT LU LV MC MK MT NL NO PL PT RO RS SE SI SK SM TR |
|
DAV | Request for validation of the european patent (deleted) | ||
DAX | Request for extension of the european patent (deleted) | ||
P01 | Opt-out of the competence of the unified patent court (upc) registered |
Effective date: 20230331 |
|
GRAP | Despatch of communication of intention to grant a patent |
Free format text: ORIGINAL CODE: EPIDOSNIGR1 |
|
STAA | Information on the status of an ep patent application or granted ep patent |
Free format text: STATUS: GRANT OF PATENT IS INTENDED |
|
INTG | Intention to grant announced |
Effective date: 20231215 |
|
GRAS | Grant fee paid |
Free format text: ORIGINAL CODE: EPIDOSNIGR3 |
|
GRAA | (expected) grant |
Free format text: ORIGINAL CODE: 0009210 |
|
STAA | Information on the status of an ep patent application or granted ep patent |
Free format text: STATUS: THE PATENT HAS BEEN GRANTED |
|
AK | Designated contracting states |
Kind code of ref document: B1 Designated state(s): AL AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HR HU IE IS IT LI LT LU LV MC MK MT NL NO PL PT RO RS SE SI SK SM TR |
|
REG | Reference to a national code |
Ref country code: GB Ref legal event code: FG4D |
|
REG | Reference to a national code |
Ref country code: CH Ref legal event code: EP |
|
REG | Reference to a national code |
Ref country code: DK Ref legal event code: T3 Effective date: 20240422 |
|
REG | Reference to a national code |
Ref country code: DE Ref legal event code: R096 Ref document number: 602020028899 Country of ref document: DE |
|
REG | Reference to a national code |
Ref country code: IE Ref legal event code: FG4D |
|
REG | Reference to a national code |
Ref country code: SE Ref legal event code: TRGR |
|
REG | Reference to a national code |
Ref country code: NL Ref legal event code: FP |
|
REG | Reference to a national code |
Ref country code: PT Ref legal event code: SC4A Ref document number: 4075999 Country of ref document: PT Date of ref document: 20240620 Kind code of ref document: T Free format text: AVAILABILITY OF NATIONAL TRANSLATION Effective date: 20240614 |
|
REG | Reference to a national code |
Ref country code: GR Ref legal event code: EP Ref document number: 20240401135 Country of ref document: GR Effective date: 20240611 |
|
REG | Reference to a national code |
Ref country code: LT Ref legal event code: MG9D |
|
REG | Reference to a national code |
Ref country code: AT Ref legal event code: MK05 Ref document number: 1673899 Country of ref document: AT Kind code of ref document: T Effective date: 20240410 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: IS Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20240810 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: BG Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20240410 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: HR Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20240410 |