EP3993763A1 - Préparation nettoyante contenant des polyglycérylesters d'acide gras - Google Patents
Préparation nettoyante contenant des polyglycérylesters d'acide grasInfo
- Publication number
- EP3993763A1 EP3993763A1 EP20731842.9A EP20731842A EP3993763A1 EP 3993763 A1 EP3993763 A1 EP 3993763A1 EP 20731842 A EP20731842 A EP 20731842A EP 3993763 A1 EP3993763 A1 EP 3993763A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- polyglyceryl
- preparation according
- caprate
- weight
- preparation
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 238000002360 preparation method Methods 0.000 title claims abstract description 109
- 235000014113 dietary fatty acids Nutrition 0.000 title claims abstract description 40
- 150000002148 esters Chemical class 0.000 title claims abstract description 40
- 239000000194 fatty acid Substances 0.000 title claims abstract description 40
- 229930195729 fatty acid Natural products 0.000 title claims abstract description 40
- 150000004665 fatty acids Chemical class 0.000 title claims abstract description 38
- 238000004140 cleaning Methods 0.000 claims abstract description 35
- WWZKQHOCKIZLMA-UHFFFAOYSA-M octanoate Chemical class CCCCCCCC([O-])=O WWZKQHOCKIZLMA-UHFFFAOYSA-M 0.000 claims abstract description 18
- 239000004094 surface-active agent Substances 0.000 claims description 40
- GHVNFZFCNZKVNT-UHFFFAOYSA-M decanoate Chemical compound CCCCCCCCCC([O-])=O GHVNFZFCNZKVNT-UHFFFAOYSA-M 0.000 claims description 33
- -1 acyl glutamates Chemical class 0.000 claims description 26
- 239000003921 oil Substances 0.000 claims description 21
- 235000019198 oils Nutrition 0.000 claims description 21
- 239000002280 amphoteric surfactant Substances 0.000 claims description 17
- 125000004432 carbon atom Chemical group C* 0.000 claims description 15
- 230000001815 facial effect Effects 0.000 claims description 15
- 239000002736 nonionic surfactant Substances 0.000 claims description 14
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims description 13
- 125000000217 alkyl group Chemical group 0.000 claims description 13
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 claims description 12
- POULHZVOKOAJMA-UHFFFAOYSA-M dodecanoate Chemical compound CCCCCCCCCCCC([O-])=O POULHZVOKOAJMA-UHFFFAOYSA-M 0.000 claims description 11
- 229940070765 laurate Drugs 0.000 claims description 11
- 239000003755 preservative agent Substances 0.000 claims description 10
- 150000001875 compounds Chemical class 0.000 claims description 9
- 239000003906 humectant Substances 0.000 claims description 9
- 150000003839 salts Chemical class 0.000 claims description 9
- 125000002252 acyl group Chemical group 0.000 claims description 7
- 239000003945 anionic surfactant Substances 0.000 claims description 7
- WVDDGKGOMKODPV-UHFFFAOYSA-N Benzyl alcohol Chemical compound OCC1=CC=CC=C1 WVDDGKGOMKODPV-UHFFFAOYSA-N 0.000 claims description 6
- 150000001413 amino acids Chemical class 0.000 claims description 6
- 235000011187 glycerol Nutrition 0.000 claims description 6
- 239000003381 stabilizer Substances 0.000 claims description 6
- 230000002335 preservative effect Effects 0.000 claims description 5
- 239000003549 soybean oil Substances 0.000 claims description 5
- 235000012424 soybean oil Nutrition 0.000 claims description 5
- QAOWNCQODCNURD-UHFFFAOYSA-L sulfate group Chemical group S(=O)(=O)([O-])[O-] QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 claims description 5
- WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid Chemical compound OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 claims description 4
- LXCFILQKKLGQFO-UHFFFAOYSA-N methylparaben Chemical compound COC(=O)C1=CC=C(O)C=C1 LXCFILQKKLGQFO-UHFFFAOYSA-N 0.000 claims description 4
- 235000019489 Almond oil Nutrition 0.000 claims description 3
- 235000019493 Macadamia oil Nutrition 0.000 claims description 3
- 235000019486 Sunflower oil Nutrition 0.000 claims description 3
- 239000008168 almond oil Substances 0.000 claims description 3
- 239000008169 grapeseed oil Substances 0.000 claims description 3
- 229940119170 jojoba wax Drugs 0.000 claims description 3
- 239000010469 macadamia oil Substances 0.000 claims description 3
- 239000002600 sunflower oil Substances 0.000 claims description 3
- PUPZLCDOIYMWBV-UHFFFAOYSA-N (+/-)-1,3-Butanediol Chemical compound CC(O)CCO PUPZLCDOIYMWBV-UHFFFAOYSA-N 0.000 claims description 2
- 229940015975 1,2-hexanediol Drugs 0.000 claims description 2
- 229940043375 1,5-pentanediol Drugs 0.000 claims description 2
- QWGRWMMWNDWRQN-UHFFFAOYSA-N 2-methylpropane-1,3-diol Chemical compound OCC(C)CO QWGRWMMWNDWRQN-UHFFFAOYSA-N 0.000 claims description 2
- QCDWFXQBSFUVSP-UHFFFAOYSA-N 2-phenoxyethanol Chemical compound OCCOC1=CC=CC=C1 QCDWFXQBSFUVSP-UHFFFAOYSA-N 0.000 claims description 2
- ANZUDYZHSVGBRF-UHFFFAOYSA-N 3-ethylnonane-1,2,3-triol Chemical compound CCCCCCC(O)(CC)C(O)CO ANZUDYZHSVGBRF-UHFFFAOYSA-N 0.000 claims description 2
- 244000144927 Aloe barbadensis Species 0.000 claims description 2
- 235000002961 Aloe barbadensis Nutrition 0.000 claims description 2
- 239000005711 Benzoic acid Substances 0.000 claims description 2
- FBPFZTCFMRRESA-FSIIMWSLSA-N D-Glucitol Natural products OC[C@H](O)[C@H](O)[C@@H](O)[C@H](O)CO FBPFZTCFMRRESA-FSIIMWSLSA-N 0.000 claims description 2
- FBPFZTCFMRRESA-JGWLITMVSA-N D-glucitol Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)[C@H](O)CO FBPFZTCFMRRESA-JGWLITMVSA-N 0.000 claims description 2
- QZKRHPLGUJDVAR-UHFFFAOYSA-K EDTA trisodium salt Chemical compound [Na+].[Na+].[Na+].OC(=O)CN(CC([O-])=O)CCN(CC([O-])=O)CC([O-])=O QZKRHPLGUJDVAR-UHFFFAOYSA-K 0.000 claims description 2
- 229920001090 Polyaminopropyl biguanide Polymers 0.000 claims description 2
- TVXBFESIOXBWNM-UHFFFAOYSA-N Xylitol Natural products OCCC(O)C(O)C(O)CCO TVXBFESIOXBWNM-UHFFFAOYSA-N 0.000 claims description 2
- 235000011399 aloe vera Nutrition 0.000 claims description 2
- UREZNYTWGJKWBI-UHFFFAOYSA-M benzethonium chloride Chemical compound [Cl-].C1=CC(C(C)(C)CC(C)(C)C)=CC=C1OCCOCC[N+](C)(C)CC1=CC=CC=C1 UREZNYTWGJKWBI-UHFFFAOYSA-M 0.000 claims description 2
- 229960001950 benzethonium chloride Drugs 0.000 claims description 2
- 235000010233 benzoic acid Nutrition 0.000 claims description 2
- 229960004365 benzoic acid Drugs 0.000 claims description 2
- 235000019445 benzyl alcohol Nutrition 0.000 claims description 2
- PXEDJBXQKAGXNJ-QTNFYWBSSA-L disodium L-glutamate Chemical compound [Na+].[Na+].[O-]C(=O)[C@@H](N)CCC([O-])=O PXEDJBXQKAGXNJ-QTNFYWBSSA-L 0.000 claims description 2
- 229940079779 disodium cocoyl glutamate Drugs 0.000 claims description 2
- 229940087068 glyceryl caprylate Drugs 0.000 claims description 2
- FHKSXSQHXQEMOK-UHFFFAOYSA-N hexane-1,2-diol Chemical compound CCCCC(O)CO FHKSXSQHXQEMOK-UHFFFAOYSA-N 0.000 claims description 2
- HEBKCHPVOIAQTA-UHFFFAOYSA-N meso ribitol Natural products OCC(O)C(O)C(O)CO HEBKCHPVOIAQTA-UHFFFAOYSA-N 0.000 claims description 2
- 235000010270 methyl p-hydroxybenzoate Nutrition 0.000 claims description 2
- 239000004292 methyl p-hydroxybenzoate Substances 0.000 claims description 2
- 229960002216 methylparaben Drugs 0.000 claims description 2
- 229940100573 methylpropanediol Drugs 0.000 claims description 2
- AEIJTFQOBWATKX-UHFFFAOYSA-N octane-1,2-diol Chemical compound CCCCCCC(O)CO AEIJTFQOBWATKX-UHFFFAOYSA-N 0.000 claims description 2
- WCVRQHFDJLLWFE-UHFFFAOYSA-N pentane-1,2-diol Chemical compound CCCC(O)CO WCVRQHFDJLLWFE-UHFFFAOYSA-N 0.000 claims description 2
- 229960005323 phenoxyethanol Drugs 0.000 claims description 2
- 229940093424 polyaminopropyl biguanide Drugs 0.000 claims description 2
- 229940097941 polyglyceryl-10 laurate Drugs 0.000 claims description 2
- GHBFNMLVSPCDGN-UHFFFAOYSA-N rac-1-monooctanoylglycerol Chemical compound CCCCCCCC(=O)OCC(O)CO GHBFNMLVSPCDGN-UHFFFAOYSA-N 0.000 claims description 2
- 229940065859 sodium cocoyl glycinate Drugs 0.000 claims description 2
- IKGKWKGYFJBGQJ-UHFFFAOYSA-M sodium;2-(dodecanoylamino)acetate Chemical compound [Na+].CCCCCCCCCCCC(=O)NCC([O-])=O IKGKWKGYFJBGQJ-UHFFFAOYSA-M 0.000 claims description 2
- 239000000600 sorbitol Substances 0.000 claims description 2
- 235000010356 sorbitol Nutrition 0.000 claims description 2
- 239000000811 xylitol Substances 0.000 claims description 2
- 235000010447 xylitol Nutrition 0.000 claims description 2
- HEBKCHPVOIAQTA-SCDXWVJYSA-N xylitol Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)CO HEBKCHPVOIAQTA-SCDXWVJYSA-N 0.000 claims description 2
- 229960002675 xylitol Drugs 0.000 claims description 2
- 125000005534 decanoate group Chemical group 0.000 abstract 1
- 210000003491 skin Anatomy 0.000 description 21
- 239000000203 mixture Substances 0.000 description 13
- 239000002537 cosmetic Substances 0.000 description 11
- 239000000049 pigment Substances 0.000 description 11
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 8
- 239000011734 sodium Substances 0.000 description 7
- 239000000126 substance Substances 0.000 description 7
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 6
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 6
- 239000000693 micelle Substances 0.000 description 6
- 229910052708 sodium Inorganic materials 0.000 description 6
- 239000002304 perfume Substances 0.000 description 5
- 239000012071 phase Substances 0.000 description 5
- 229920006395 saturated elastomer Polymers 0.000 description 5
- QXNVGIXVLWOKEQ-UHFFFAOYSA-N Disodium Chemical compound [Na][Na] QXNVGIXVLWOKEQ-UHFFFAOYSA-N 0.000 description 4
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 4
- 125000000129 anionic group Chemical group 0.000 description 4
- ULBTUVJTXULMLP-UHFFFAOYSA-N butyl octadecanoate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCCCC ULBTUVJTXULMLP-UHFFFAOYSA-N 0.000 description 4
- 239000003240 coconut oil Substances 0.000 description 4
- 235000019864 coconut oil Nutrition 0.000 description 4
- 239000000243 solution Substances 0.000 description 4
- WQZGKKKJIJFFOK-GASJEMHNSA-N Glucose Natural products OC[C@H]1OC(O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-GASJEMHNSA-N 0.000 description 3
- 235000019482 Palm oil Nutrition 0.000 description 3
- 239000002253 acid Substances 0.000 description 3
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 3
- 239000003974 emollient agent Substances 0.000 description 3
- 239000000499 gel Substances 0.000 description 3
- 239000008103 glucose Substances 0.000 description 3
- 229930195712 glutamate Natural products 0.000 description 3
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 3
- 150000002632 lipids Chemical class 0.000 description 3
- OQILCOQZDHPEAZ-UHFFFAOYSA-N octyl palmitate Chemical compound CCCCCCCCCCCCCCCC(=O)OCCCCCCCC OQILCOQZDHPEAZ-UHFFFAOYSA-N 0.000 description 3
- BARWIPMJPCRCTP-CLFAGFIQSA-N oleyl oleate Chemical compound CCCCCCCC\C=C/CCCCCCCCOC(=O)CCCCCCC\C=C/CCCCCCCC BARWIPMJPCRCTP-CLFAGFIQSA-N 0.000 description 3
- 239000002540 palm oil Substances 0.000 description 3
- 239000000725 suspension Substances 0.000 description 3
- 240000007124 Brassica oleracea Species 0.000 description 2
- 229920000742 Cotton Polymers 0.000 description 2
- SRBFZHDQGSBBOR-IOVATXLUSA-N D-xylopyranose Chemical compound O[C@@H]1COC(O)[C@H](O)[C@H]1O SRBFZHDQGSBBOR-IOVATXLUSA-N 0.000 description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- CZMRCDWAGMRECN-UGDNZRGBSA-N Sucrose Chemical compound O[C@H]1[C@H](O)[C@@H](CO)O[C@@]1(CO)O[C@@H]1[C@H](O)[C@@H](O)[C@H](O)[C@@H](CO)O1 CZMRCDWAGMRECN-UGDNZRGBSA-N 0.000 description 2
- 229930006000 Sucrose Natural products 0.000 description 2
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 2
- 150000007513 acids Chemical class 0.000 description 2
- 239000000654 additive Substances 0.000 description 2
- 150000001298 alcohols Chemical class 0.000 description 2
- 150000001450 anions Chemical class 0.000 description 2
- PYMYPHUHKUWMLA-UHFFFAOYSA-N arabinose Natural products OCC(O)C(O)C(O)C=O PYMYPHUHKUWMLA-UHFFFAOYSA-N 0.000 description 2
- SRBFZHDQGSBBOR-UHFFFAOYSA-N beta-D-Pyranose-Lyxose Natural products OC1COC(O)C(O)C1O SRBFZHDQGSBBOR-UHFFFAOYSA-N 0.000 description 2
- WQZGKKKJIJFFOK-VFUOTHLCSA-N beta-D-glucose Chemical compound OC[C@H]1O[C@@H](O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-VFUOTHLCSA-N 0.000 description 2
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 2
- 150000001735 carboxylic acids Chemical class 0.000 description 2
- 239000003093 cationic surfactant Substances 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- FOCAUTSVDIKZOP-UHFFFAOYSA-N chloroacetic acid Chemical compound OC(=O)CCl FOCAUTSVDIKZOP-UHFFFAOYSA-N 0.000 description 2
- MRUAUOIMASANKQ-UHFFFAOYSA-N cocamidopropyl betaine Chemical compound CCCCCCCCCCCC(=O)NCCC[N+](C)(C)CC([O-])=O MRUAUOIMASANKQ-UHFFFAOYSA-N 0.000 description 2
- 239000012141 concentrate Substances 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 239000003995 emulsifying agent Substances 0.000 description 2
- 239000004744 fabric Substances 0.000 description 2
- 238000009472 formulation Methods 0.000 description 2
- 125000002347 octyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- 229920001296 polysiloxane Polymers 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- 159000000000 sodium salts Chemical class 0.000 description 2
- 239000005720 sucrose Substances 0.000 description 2
- 235000015112 vegetable and seed oil Nutrition 0.000 description 2
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- 239000001993 wax Substances 0.000 description 2
- 239000002888 zwitterionic surfactant Substances 0.000 description 2
- NKJOXAZJBOMXID-UHFFFAOYSA-N 1,1'-Oxybisoctane Chemical compound CCCCCCCCOCCCCCCCC NKJOXAZJBOMXID-UHFFFAOYSA-N 0.000 description 1
- LWLRMRFJCCMNML-UHFFFAOYSA-N 2-ethylhexyl dodecanoate Chemical compound CCCCCCCCCCCC(=O)OCC(CC)CCCC LWLRMRFJCCMNML-UHFFFAOYSA-N 0.000 description 1
- OPJWPPVYCOPDCM-UHFFFAOYSA-N 2-ethylhexyl octadecanoate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCC(CC)CCCC OPJWPPVYCOPDCM-UHFFFAOYSA-N 0.000 description 1
- MWKPHOIHTLQZIY-UHFFFAOYSA-N 2-hexyldecyl octadecanoate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCC(CCCCCC)CCCCCCCC MWKPHOIHTLQZIY-UHFFFAOYSA-N 0.000 description 1
- RUDXBXPTJPNTSO-UHFFFAOYSA-N 2-octyldodecyl hexadecanoate Chemical compound CCCCCCCCCCCCCCCC(=O)OCC(CCCCCCCC)CCCCCCCCCC RUDXBXPTJPNTSO-UHFFFAOYSA-N 0.000 description 1
- AGNTUZCMJBTHOG-UHFFFAOYSA-N 3-[3-(2,3-dihydroxypropoxy)-2-hydroxypropoxy]propane-1,2-diol Chemical class OCC(O)COCC(O)COCC(O)CO AGNTUZCMJBTHOG-UHFFFAOYSA-N 0.000 description 1
- DDGPBVIAYDDWDH-UHFFFAOYSA-N 3-[dodecyl(dimethyl)azaniumyl]-2-hydroxypropane-1-sulfonate Chemical compound CCCCCCCCCCCC[N+](C)(C)CC(O)CS([O-])(=O)=O DDGPBVIAYDDWDH-UHFFFAOYSA-N 0.000 description 1
- UPMLOUAZCHDJJD-UHFFFAOYSA-N 4,4'-Diphenylmethane Diisocyanate Chemical compound C1=CC(N=C=O)=CC=C1CC1=CC=C(N=C=O)C=C1 UPMLOUAZCHDJJD-UHFFFAOYSA-N 0.000 description 1
- HIQIXEFWDLTDED-UHFFFAOYSA-N 4-hydroxy-1-piperidin-4-ylpyrrolidin-2-one Chemical compound O=C1CC(O)CN1C1CCNCC1 HIQIXEFWDLTDED-UHFFFAOYSA-N 0.000 description 1
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 1
- 239000005995 Aluminium silicate Substances 0.000 description 1
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 1
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- WQZGKKKJIJFFOK-IVMDWMLBSA-N D-allopyranose Chemical compound OC[C@H]1OC(O)[C@H](O)[C@H](O)[C@@H]1O WQZGKKKJIJFFOK-IVMDWMLBSA-N 0.000 description 1
- WQZGKKKJIJFFOK-QTVWNMPRSA-N D-mannopyranose Chemical compound OC[C@H]1OC(O)[C@@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-QTVWNMPRSA-N 0.000 description 1
- HMFHBZSHGGEWLO-SOOFDHNKSA-N D-ribofuranose Chemical compound OC[C@H]1OC(O)[C@H](O)[C@@H]1O HMFHBZSHGGEWLO-SOOFDHNKSA-N 0.000 description 1
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- 241001399594 Venator Species 0.000 description 1
- TXZRBCSUYLEATA-GALHSAGASA-N [(z)-docos-13-enyl] (z)-octadec-9-enoate Chemical compound CCCCCCCC\C=C/CCCCCCCCCCCCOC(=O)CCCCCCC\C=C/CCCCCCCC TXZRBCSUYLEATA-GALHSAGASA-N 0.000 description 1
- YKTSYUJCYHOUJP-UHFFFAOYSA-N [O--].[Al+3].[Al+3].[O-][Si]([O-])([O-])[O-] Chemical compound [O--].[Al+3].[Al+3].[O-][Si]([O-])([O-])[O-] YKTSYUJCYHOUJP-UHFFFAOYSA-N 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- HMFHBZSHGGEWLO-UHFFFAOYSA-N alpha-D-Furanose-Ribose Natural products OCC1OC(O)C(O)C1O HMFHBZSHGGEWLO-UHFFFAOYSA-N 0.000 description 1
- WQZGKKKJIJFFOK-PHYPRBDBSA-N alpha-D-galactose Chemical compound OC[C@H]1O[C@H](O)[C@H](O)[C@@H](O)[C@H]1O WQZGKKKJIJFFOK-PHYPRBDBSA-N 0.000 description 1
- 235000012211 aluminium silicate Nutrition 0.000 description 1
- 125000003277 amino group Chemical group 0.000 description 1
- LHIJANUOQQMGNT-UHFFFAOYSA-N aminoethylethanolamine Chemical compound NCCNCCO LHIJANUOQQMGNT-UHFFFAOYSA-N 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
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- PYMYPHUHKUWMLA-WDCZJNDASA-N arabinose Chemical compound OC[C@@H](O)[C@@H](O)[C@H](O)C=O PYMYPHUHKUWMLA-WDCZJNDASA-N 0.000 description 1
- 230000003796 beauty Effects 0.000 description 1
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- 239000011230 binding agent Substances 0.000 description 1
- 150000004649 carbonic acid derivatives Chemical class 0.000 description 1
- 235000013869 carnauba wax Nutrition 0.000 description 1
- 239000004203 carnauba wax Substances 0.000 description 1
- 239000004359 castor oil Substances 0.000 description 1
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- 125000002091 cationic group Chemical group 0.000 description 1
- 150000001768 cations Chemical class 0.000 description 1
- 210000004027 cell Anatomy 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 229910052804 chromium Inorganic materials 0.000 description 1
- 239000011651 chromium Substances 0.000 description 1
- 239000012459 cleaning agent Substances 0.000 description 1
- 229940073507 cocamidopropyl betaine Drugs 0.000 description 1
- 229940080421 coco glucoside Drugs 0.000 description 1
- 229940071160 cocoate Drugs 0.000 description 1
- 229940071124 cocoyl glutamate Drugs 0.000 description 1
- 239000008139 complexing agent Substances 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- JDRSMPFHFNXQRB-IBEHDNSVSA-N decyl glucoside Chemical compound CCCCCCCCCCO[C@@H]1O[C@H](CO)[C@@H](O)[C@H](O)[C@H]1O JDRSMPFHFNXQRB-IBEHDNSVSA-N 0.000 description 1
- 229940073499 decyl glucoside Drugs 0.000 description 1
- 150000001983 dialkylethers Chemical class 0.000 description 1
- PKPOVTYZGGYDIJ-UHFFFAOYSA-N dioctyl carbonate Chemical compound CCCCCCCCOC(=O)OCCCCCCCC PKPOVTYZGGYDIJ-UHFFFAOYSA-N 0.000 description 1
- 229940047642 disodium cocoamphodiacetate Drugs 0.000 description 1
- 239000000975 dye Substances 0.000 description 1
- 239000000839 emulsion Substances 0.000 description 1
- 239000010696 ester oil Substances 0.000 description 1
- 230000032050 esterification Effects 0.000 description 1
- 238000005886 esterification reaction Methods 0.000 description 1
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 1
- GJQLBGWSDGMZKM-UHFFFAOYSA-N ethylhexyl palmitate Chemical compound CCCCCCCCCCCCCCCC(=O)OC(CC)CCCCC GJQLBGWSDGMZKM-UHFFFAOYSA-N 0.000 description 1
- 235000008524 evening primrose extract Nutrition 0.000 description 1
- 239000010475 evening primrose oil Substances 0.000 description 1
- 229940089020 evening primrose oil Drugs 0.000 description 1
- 150000002191 fatty alcohols Chemical class 0.000 description 1
- 239000006260 foam Substances 0.000 description 1
- 229930182830 galactose Natural products 0.000 description 1
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 description 1
- 229930182470 glycoside Natural products 0.000 description 1
- 210000004209 hair Anatomy 0.000 description 1
- PMMXXYHTOMKOAZ-UHFFFAOYSA-N hexadecyl 7-methyloctanoate Chemical compound CCCCCCCCCCCCCCCCOC(=O)CCCCCC(C)C PMMXXYHTOMKOAZ-UHFFFAOYSA-N 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-M hydrogensulfate Chemical compound OS([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-M 0.000 description 1
- 125000002951 idosyl group Chemical class C1([C@@H](O)[C@H](O)[C@@H](O)[C@H](O1)CO)* 0.000 description 1
- 238000005470 impregnation Methods 0.000 description 1
- 238000010348 incorporation Methods 0.000 description 1
- 239000001023 inorganic pigment Substances 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 235000013980 iron oxide Nutrition 0.000 description 1
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N iron oxide Inorganic materials [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 1
- 235000010213 iron oxides and hydroxides Nutrition 0.000 description 1
- 239000004407 iron oxides and hydroxides Substances 0.000 description 1
- VBMVTYDPPZVILR-UHFFFAOYSA-N iron(2+);oxygen(2-) Chemical class [O-2].[Fe+2] VBMVTYDPPZVILR-UHFFFAOYSA-N 0.000 description 1
- 239000002085 irritant Substances 0.000 description 1
- 231100000021 irritant Toxicity 0.000 description 1
- 230000007794 irritation Effects 0.000 description 1
- XUGNVMKQXJXZCD-UHFFFAOYSA-N isopropyl palmitate Chemical compound CCCCCCCCCCCCCCCC(=O)OC(C)C XUGNVMKQXJXZCD-UHFFFAOYSA-N 0.000 description 1
- 229940089456 isopropyl stearate Drugs 0.000 description 1
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 1
- 235000019388 lanolin Nutrition 0.000 description 1
- 229940039717 lanolin Drugs 0.000 description 1
- PYIDGJJWBIBVIA-UYTYNIKBSA-N lauryl glucoside Chemical compound CCCCCCCCCCCCO[C@@H]1O[C@H](CO)[C@@H](O)[C@H](O)[C@H]1O PYIDGJJWBIBVIA-UYTYNIKBSA-N 0.000 description 1
- 229940048848 lauryl glucoside Drugs 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- ZADYMNAVLSWLEQ-UHFFFAOYSA-N magnesium;oxygen(2-);silicon(4+) Chemical compound [O-2].[O-2].[O-2].[Mg+2].[Si+4] ZADYMNAVLSWLEQ-UHFFFAOYSA-N 0.000 description 1
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 229910044991 metal oxide Inorganic materials 0.000 description 1
- 150000004706 metal oxides Chemical class 0.000 description 1
- 150000002772 monosaccharides Chemical class 0.000 description 1
- 210000004400 mucous membrane Anatomy 0.000 description 1
- 229940105132 myristate Drugs 0.000 description 1
- 125000004108 n-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 125000001280 n-hexyl group Chemical group C(CCCCC)* 0.000 description 1
- 230000007935 neutral effect Effects 0.000 description 1
- 231100000344 non-irritating Toxicity 0.000 description 1
- 235000016709 nutrition Nutrition 0.000 description 1
- 230000035764 nutrition Effects 0.000 description 1
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical class CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 1
- BARWIPMJPCRCTP-UHFFFAOYSA-N oleic acid oleyl ester Natural products CCCCCCCCC=CCCCCCCCCOC(=O)CCCCCCCC=CCCCCCCCC BARWIPMJPCRCTP-UHFFFAOYSA-N 0.000 description 1
- 125000001117 oleyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])/C([H])=C([H])\C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 229920001542 oligosaccharide Polymers 0.000 description 1
- 150000002482 oligosaccharides Chemical class 0.000 description 1
- 239000004006 olive oil Substances 0.000 description 1
- 235000008390 olive oil Nutrition 0.000 description 1
- 125000004430 oxygen atom Chemical group O* 0.000 description 1
- 239000012188 paraffin wax Substances 0.000 description 1
- 239000000312 peanut oil Substances 0.000 description 1
- 229920001983 poloxamer Polymers 0.000 description 1
- PZQSQRCNMZGWFT-QXMHVHEDSA-N propan-2-yl (z)-octadec-9-enoate Chemical compound CCCCCCCC\C=C/CCCCCCCC(=O)OC(C)C PZQSQRCNMZGWFT-QXMHVHEDSA-N 0.000 description 1
- ZPWFUIUNWDIYCJ-UHFFFAOYSA-N propan-2-yl octadecanoate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OC(C)C ZPWFUIUNWDIYCJ-UHFFFAOYSA-N 0.000 description 1
- 230000009993 protective function Effects 0.000 description 1
- 235000005713 safflower oil Nutrition 0.000 description 1
- 239000003813 safflower oil Substances 0.000 description 1
- FSYKKLYZXJSNPZ-UHFFFAOYSA-N sarcosine Chemical compound C[NH2+]CC([O-])=O FSYKKLYZXJSNPZ-UHFFFAOYSA-N 0.000 description 1
- 210000002374 sebum Anatomy 0.000 description 1
- 238000004062 sedimentation Methods 0.000 description 1
- 150000004760 silicates Chemical class 0.000 description 1
- 229920002545 silicone oil Polymers 0.000 description 1
- 210000004927 skin cell Anatomy 0.000 description 1
- 230000036556 skin irritation Effects 0.000 description 1
- 231100000475 skin irritation Toxicity 0.000 description 1
- 230000000087 stabilizing effect Effects 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- ABTZKZVAJTXGNN-UHFFFAOYSA-N stearyl heptanoate Chemical compound CCCCCCCCCCCCCCCCCCOC(=O)CCCCCC ABTZKZVAJTXGNN-UHFFFAOYSA-N 0.000 description 1
- 229940098758 stearyl heptanoate Drugs 0.000 description 1
- 150000003467 sulfuric acid derivatives Chemical class 0.000 description 1
- 239000000454 talc Substances 0.000 description 1
- 229910052623 talc Inorganic materials 0.000 description 1
- TUNFSRHWOTWDNC-UHFFFAOYSA-N tetradecanoic acid Chemical compound CCCCCCCCCCCCCC(O)=O TUNFSRHWOTWDNC-UHFFFAOYSA-N 0.000 description 1
- 230000008719 thickening Effects 0.000 description 1
- 239000002562 thickening agent Substances 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- 239000010936 titanium Substances 0.000 description 1
- 239000004408 titanium dioxide Substances 0.000 description 1
- 125000002889 tridecyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- GKAVWWCJCPVMNR-UHFFFAOYSA-N tridecyl octadecanoate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCCCCCCCCCCCCC GKAVWWCJCPVMNR-UHFFFAOYSA-N 0.000 description 1
- 125000004417 unsaturated alkyl group Chemical group 0.000 description 1
- 235000013311 vegetables Nutrition 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- 238000009736 wetting Methods 0.000 description 1
- 239000010497 wheat germ oil Substances 0.000 description 1
- 235000014692 zinc oxide Nutrition 0.000 description 1
- RNWHGQJWIACOKP-UHFFFAOYSA-N zinc;oxygen(2-) Chemical class [O-2].[Zn+2] RNWHGQJWIACOKP-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/39—Derivatives containing from 2 to 10 oxyalkylene groups
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q1/00—Make-up preparations; Body powders; Preparations for removing make-up
- A61Q1/14—Preparations for removing make-up
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/20—Chemical, physico-chemical or functional or structural properties of the composition as a whole
- A61K2800/30—Characterized by the absence of a particular group of ingredients
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/20—Chemical, physico-chemical or functional or structural properties of the composition as a whole
- A61K2800/30—Characterized by the absence of a particular group of ingredients
- A61K2800/33—Free of surfactant
Definitions
- the present invention relates to a cleaning preparation which contains at least one fatty acid polyglyceryl ester.
- This preparation is preferably suitable for removing make-up from human skin, in particular from facial skin.
- the make-up used must also be removed again.
- skin cleansing products for removing make-up from the facial area, namely facial cleansing products. Since the facial skin is particularly sensitive, particularly mild and non-irritating products are used for facial cleansing.
- Decorative cosmetics A large number of different substances are used today in the field of decorative cosmetics.
- inorganic pigments such as silicates [magnesium silicate (talc), aluminum silicate (kaolin)] and metal oxides (chromium, iron, manganese, titanium and zinc oxides)
- organic color pigments are used as dyes.
- Stearic acid esters, lanolin alcohol and acetate are used as binders.
- Waxes such as beeswax or carnauba wax and oils such as paraffin oils, silicone oils or castor oil are used in many formulations.
- Decorative cosmetics can also contain preservatives, antioxidants, thickeners and other additives.
- Mascara, eyeshadow and kohl pencils On the other hand, they must be as kind to the skin as possible, please include in order not to cause any reddening of the skin or irritation of the mucous membranes in the users.
- preparations have already been disclosed which are suitable for make-up removal or which have been specially developed for this purpose.
- Various forms of preparation have been described and corresponding products are already available for purchase.
- These preparations can be in the form of emulsions, which in turn are predominantly creamy, milky or liquid, gels or oily compositions.
- multiphase compositions are known, in particular two-phase compositions which have two visually separate phases which are mixed by shaking the who. The resulting largely homogeneous phase is then applied to the skin.
- WO 2016/146360 A1 discloses a facial cleansing preparation which is suitable for removing make-up and at the same time for refreshing the skin.
- This preparation has an aqueous and an oily phase and is free of silicone compounds.
- WO 2017/005485 A1 describes an impregnating agent for wipes.
- the corresponding cleaning cloth is intended for facial cleaning.
- the impregnation agent is based on Mi cell technology and contains a combination of surfactants, namely anionic surfactants in the form of acyl glutamates and nonionic surfactants in the form of alkyl glycosides and poloxamers.
- washing gels which contain tenside in concentrations of around 3 to 10%, must be rinsed off. Furthermore, preparations can be made available that contain significantly fewer surfactants and therefore do not have to be rinsed off the skin.
- micellar water also belong to the last-mentioned type of preparation. They are distinguished by the fact that the surfactant (s) is / are present in such a concentration that surfactant micelles can form.
- the micelles are usually arranged in such a way that the lipophilic parts of the surfactants are directed inside the micelle and the hydrophilic parts of the surfactants point outwards into the aqueous environment.
- the micelles can interact with the molecules on the surface of the skin. These molecules can be from makeup or Make-up residues, sebum or dead skin cells and other things come from it. In this way, the micelles help solubilize these molecules. With the help of a cotton wool pad or the like or with the help of water, these molecules, ie also the dirt, can now be removed from the skin.
- Cleansing preparations that are designed so that they do not necessarily have to be rinsed off the skin with water can be removed from the surface of the skin, for example with a cotton ball, a cloth or the like, together with dissolved / undissolved dirt particles or molecules. In the case of such preparations, however, it must be ensured that they are sufficiently mild so that skin irritations are (largely) avoided.
- ⁇ 0.9 wt .-% preferably ⁇ 0.5 wt .-%, particularly preferably ⁇ 0.3 wt .-% of at least one fatty acid polyglyceryl ester, based on the total weight of the preparation and based on the active content,
- the preparation according to the invention is an aqueous preparation.
- the preparation according to the invention is a cosmetic preparation.
- the preparation according to the invention is advantageously used for cleaning human skin, in particular the facial skin, and in particular for removing make-up.
- the preparation according to the invention contains at least one fatty acid polyglyceryl ester. These esters have at least two glycerol molecules that are linked to one another.
- the free OH groups are esterified with fatty acids; partial esterification is present if not all OH groups are esterified with fatty acids.
- Partial fatty acid polyglyceryl esters can be described, for example, by the following formula: where Ri is a linear or branched, saturated or unsaturated alkyl or alkenyl radical, the alkyl or alkenyl radical only or predominantly having alkyl or alkenyl radicals with 6 to 12 carbon atoms, preferably with 6 to 10 carbon atoms and n is an integer from 1 to 11.
- the term predominantly means that more than 55%, in particular more than 65%, further in particular more than 80% of the radicals mentioned have 6 to 12 carbon atoms, preferably 6 to 10 carbon atoms.
- the fatty acid polyglyceryl esters are uncharged, but the glycerine molecules contain oxygen atoms and ester bonds that contribute to the hydrophilicity, while the alkyl / alkylene radicals of the fatty acids contribute to the lipophilicity.
- the fatty acid polyglyceryl esters are amphiphilic molecules.
- the fatty acid polyglyceryl esters can therefore also act and be referred to as nonionic surfactants.
- Surfactants are amphiphilic substances that, among other things, are able to dissolve organic, non-polar substances in water. They are characterized by an ambivalent behavior towards water and lipids.
- the surfactant molecule contains at least one hydrophilic and one lipophilic group each, which enable attachment to the interface between an aqueous phase and a lipid phase. In this way, surfactants reduce the surface tension of the water, wetting the skin, making it easier to loosen and remove dirt, easy rinsing and, optionally, foam regulation. This provides the basis for removing dirt containing lipids.
- EP 2455062 A2 discloses a heavy hand cleaner which contains various components, including an emollient in an amount of at least 0.1% by weight, this emollient can be a polyglyceryl partial ester and 2 to 40% by weight of a surfactant selected from fatty alcohol lethoxylates, fatty alcohol ether sulfates and salts of sulfated and / or sulfonated fatty acids. There is no disclosure of a facial cleanser or make-up remover. US 2012/0157366 A1 describes skin and hair cleansing preparations that have a low irritant potential.
- the preparations contain a fatty acid polyglyceryl ester and anionic and amphoteric surfactants in an amount of 2 to 7% by weight. There is no disclosure that these preparations are suitable as facial cleansers or make-up removers.
- US 2012/0157365 A1 discloses clear and mild cleaning preparations which are essentially free of ethoxylated compounds and have a pH of 5.4 or less. These preparations contain a nonionic surfactant, which can be a fatty acid polyglyceryl ester, a zwitterionic surfactant and a selected anionic surfactant. There is no disclosure that the preparations mentioned are intended to be used as make-up removers.
- No. 10,117,818 B2 describes a concentrate for wet wipes.
- This concentrate contains an emulsifier, which can be a fatty acid polyglyceryl ester, a humectant and an emollient.
- the emulsifier is used in amounts of 15 to 60% by weight.
- US 9,544,007 B2 discloses a tear-free cleaner for babies.
- This cleaner contains, among others. 5 to 30 wt% polyglyceryl partial ester.
- the cleaning preparation according to the invention contains only at least one fatty acid polyglyceryl ester in a total amount as surfactant (s)
- ⁇ 0.9% by weight preferably ⁇ 0.5% by weight, particularly preferably ⁇ 0.3% by weight, based on the total weight of the preparation and based on the active content.
- the cleaning preparation according to the invention contains at least one fatty acid polyglyceryl ester in a total amount
- ⁇ 0.9% by weight preferably ⁇ 0.5% by weight, particularly preferably ⁇ 0.3% by weight, based on the total weight of the preparation and based on the active content and further surfactants selected from at least one anionic surfactant or at least one amphoteric surfactant and / or another nonionic surfactant.
- the group of amphoteric surfactants also includes zwitterionic surfactants.
- the other nonionic surfactants do not include any fatty acid polyglyceryl esters.
- fatty acid polyglyceryl esters are compounds such as polyglyceryl-4
- caprylate / caprate Polyglyceryl-5 caprylate / caprate, Polyglyceryl-6 caprylate / caprate, Polyglyceryl-7 caprylate / caprate, Polyglyceryl-8 caprylate / caprate, Polyglyceryl-9
- polyglyceryl-10 caprylate / caprate Polyglyceryl-10 caprylate / caprate, Polyglyceryl-4 caprate, Polyglyceryl-5 caprate, Polyglyceryl-6 caprate, Polyglyceryl-7 caprate, Polyglyceryl-8 caprate, Polyglyceryl-9 caprate, Polyglyceryl-10 caprate, Polyglycerate-4 , Polyglyceryl-5 laurate, polyglyceryl-6 laurate, polyglyceryl-7 laurate, polyglyceryl-8 laurate, polyglyceryl-9 laurate, polyglyceryl-10 laurate.
- the compound polyglyceryl-10 caprylate / caprate is preferred. This connection can be purchased from Lonza, for example, under the trade name Polyaldo® 10-1-CC.
- the preparation according to the invention contains the at least one fatty acid polyglyceryl ester with a content of 0.007 to 0.8% by weight, preferably from 0.01 to 0.5% by weight, particularly preferably 0.05 to 0.3% by weight. % before, based on the total amount of the preparation and based on the active content.
- these surfactants can be selected from various surfactant classes.
- surfactants can be selected that are based on amino acids, that is, amino acid-based surfactants.
- Suitable amino acid-based surfactants can be selected, for example, from:
- Glycinates such as acyl glycinates.
- acyl glutamate (s) and / or acyl glycinate (s) are contained.
- a particularly advantageous acyl glutamate is Disodium Cocoyl Glutamate, which is available, for example, with the trade name Hostapon - CCG from Clariant.
- acyl glycinate with the name sodium cocoyl glycinate which is available, for example, under the trade name Hostapon SG from Clariant.
- the preparation according to the invention contains one or more surfactants based on amino acids
- the total content of the one or more surfactants mentioned is in the range from 0.001 to 0.5% by weight, preferably 0.05 to 0, 3% by weight, based on the total weight of the preparation and the respective active content.
- the preparations according to the invention do not contain any surfactants which have sulfate groups. It is further preferred if the entire preparation according to the invention does not contain any compounds which have sulfate groups. It is further particularly preferred if the preparation according to the invention is entirely sulfate-free.
- sulfates is understood to mean salts and esters of sulfuric acid.
- the salts can be represented by the formulas SO4 2 (anion) and HSO4 2 (hydrogen sulfate anion), while the esters have the general formula R-0-S0 2 -0-R ', where R and / or R' are organic radicals are and R 'also be hydrogen.
- R and / or R' are organic radicals are and R 'also be hydrogen.
- the acid dissociates and is present as a salt.
- sulfate-free means that the respective raw material or the respective composition is less than 0.1% by weight, preferably less than
- amphoteric surfactants have both anionic and cationic groups and accordingly behave like anionic or cationic surfactants in aqueous solution, depending on the pH. They have a positive charge in a strongly acidic environment and a negative charge in an alkaline environment. In the neutral pH range, however, they are zwitterionic, as the following example should clarify:
- Suitable amphoteric surfactants can be selected, for example, from:
- Acyl / dialkyl ethylenediamine for example sodium acylamphoacetate, disodium macylamphodipropionate, disodium alkylamphodiacetate, disodium cocoamphodiacetate, disodium cocoamphomonoacetate, sodium acylamphohydroxypropylsulfonate, disodium macylamphodiacetate and sodium
- Betaines for example Coco Betaine, Cocoamidopropyl Betaine,
- Sultaines for example lauryl hydroxy sultaine.
- amphoteric surfactant (s) are selected from the group of betaines, more preferably from the group of alkylamidopropyl betaines and alkyl betaines. It is particularly preferred if the amphoteric surfactant is cocamidopropyl betaine.
- amphoteric surfactant (s) are selected from the group of the sultaines, more preferably from the group of hydroxysultaines and / or amidopropylhydroxysultaines.
- amphoteric surfactant or surfactants are selected from acyl / dialkylethylenediamine, in particular from acylamphoacetates, which can be described by the following formula:
- R is an alkyl radical having 8 to 30 carbon atoms.
- acylamphoacetates are synthesized in two steps. First, a fatty acid or a mixture of fatty acids that come from a natural oil is added to a vegetable oil, such as coconut oil, soybean oil or palm oil, with N- (2-hydroxyethyl) ethylenediamine. The resulting 2-alkyl-1-hydroxyethylimidazolines who hydrolyzed to linear amidoamines with NaOH. These in turn are mixed with monochloroacetic acid. Acyl monoamphoacetates are formed. If larger molar amounts of monochloroacetic acid are used, acylamphodiacetates are formed.
- Acylamphacetates are amphoteric surfactants which, depending on the pH value, are available as anionic, zwitterioni cal or cationic surfactants.
- the sodium salts of acylamphoacetates are known to have little imitative effect.
- the acyl radical is derived from fatty acids of vegetable origin, preferably from fatty acids obtained from coconut oil.
- the sodium salts of the acylamphoacetates are selected.
- the total content of the at least one amphoteric surfactant is in the range from 0.001 to 0.5% by weight, preferably 0.05 to 0.3% by weight, based on the total weight the preparation and the respective active content.
- Nonionic surfactants are characterized by the fact that they do not form any ions in the aqueous medium.
- Suitable nonionic surfactants can be selected, for example, from the group of the alkyl polyglycosides, such as lauryl glucoside, decyl glucoside and cocoglucoside.
- Alkyl polyglycosides can be represented by the general structural formula RO- (Z) x , where R is an alkyl radical with 6 to 30 carbon atoms, Z is a sugar radical and x is the number of sugar radicals.
- the alkyl radical can be a radical with a specific number of carbon atoms or can be a mixture of alkyl radicals. Such mixtures are obtained when natural oils such as palm oil, soybean oil or coconut oil are used as the starting material for the production of the alkyl polyglucosides. It is preferred if the alkyl groups have essentially 12 to 18 carbon atoms
- the sugar residues can be monosaccharides or oligosaccharides, which preferably have sugar residues with 5 or 6 carbon atoms.
- Suitable sugar residues are, for example, glucose, fructose, galactose, arabinose, ribose, xylose, allose, mannose, gulose, idose, talose and sucrose.
- Glucose and sucrose are particularly preferred, glucose being particularly preferred.
- Alkyl polyglycosides contain on average 1.1 to 5, preferably 1.1 to 2.0, sugar residues per molecule.
- the total content of the at least one nonionic surfactant is in the range from 0.001 to 0.5% by weight, preferably 0.05 to 0.3% by weight, based on the total weight of the preparation and the respective active content.
- the total amount of surfactant is 0.05 to 0.9% by weight, preferably 0.1 to 0.5% by weight, based on the total weight of the preparation and the respective active content.
- the total amount of surfactant comprises the content of the at least one fatty acid polyglyceryl ester and the content of at least one further surfactant.
- Micelles can form in the preparations according to the invention if the contents of the surfactants contained in each case assume suitable values.
- the preparation according to the invention can advantageously contain preservatives.
- Preservatives are those preserving substances that are approved for use in cosmetic products for Europe in accordance with the Cosmetics Regulation for Germany and Regulation (EC) No. 1223/2009 on cosmetic agents.
- the at least one preservative can advantageously be selected from the group consisting of phenoxyethanol, methyl paraben, polyaminopropyl biguanide, benzoic acid and / or a physiologically acceptable salt thereof, benzethonium chloride and / or benzyl alcohol.
- stabilizers are those substances that are not included in the list of permitted preservatives (Cosmetics Ordinance Annex 6; Regulation (EC) No. 1223/2009, Annex V), but nevertheless one have a stabilizing effect and / or, when used together with preservatives, promote the stability of the preparation for 36 months.
- ethylhexylglycerol 1,2-hexanediol, trisodium EDTA, methylpropanediol, caprylyl glycol, glyceryl caprylate and / or pentylene glycol.
- the preparation according to the invention contains the at least one preservative and / or the at least one stabilizer with a content of 0.0001 to 6% by weight, preferably from 0.0005 to 5% by weight, particularly preferably from 0.001 to 4% by weight before, based on the total weight of the preparation.
- Humectants can, for example, give the skin moisture and / or help prevent moisture loss in the skin.
- the humectants are hygroscopic substances that can bind water. This water-binding capacity is based on hydrophilic groups such as hydroxyl groups, but also amine groups and carboxyl groups.
- Humectants are, for example, propylene glycol, butylene glycol, glycerine, sorbitol, xylitol, aloe vera gel. The use of propylene glycol and / or glycerine is preferred according to the invention.
- the humectant or humectants is / are present with a total content of 0.01 to 10% by weight, preferably 0.1 to 5.0% by weight, based on the total weight of the preparation.
- oils are additionally incorporated into the preparation according to the invention.
- the oils can be selected from the group of polar oils, for example from the group of fatty acid triglycerides, namely the triglycerol esters of saturated and / or unsaturated, branched and / or unbranched alkanecarboxylic acids with a chain length of 8 to 24, especially 12 to 18 carbon atoms - men.
- the fatty acid triglycerides can, for example, advantageously be selected from the group of synthetic, semi-synthetic and natural oils, such as. B.
- cocoglyceride Olive oil, sunflower oil, soybean oil, peanut oil, rapeseed oil, almond oil, palm oil, coconut oil, wheat germ oil, grapeseed oil, safflower oil, evening primrose oil, macadamia oil and the like.
- polar oil components can be selected for the purposes of the present invention further from the group of monoesters of saturated and / or unsaturated, branched and / or unbranched alkanecarboxylic acids with a chain length of 3 to 30 carbon atoms and saturated and / or unsaturated, branched and / or unbranched alcohols get a chain length of 3 to 30 carbon atoms and from the group of esters of aromatic carboxylic acids and saturated and / or unsaturated, branched and / or unbranched alcohols with a chain length of 3 to 30 carbon atoms.
- ester oils can then advantageously be chosen from the group of octyl palmitate, octyl cocoate, octyl isostearate, octyl dodeceyl myristate, cetearyl isononanoate, isopropyl myristate, isopropyl palmitate, isopropyl stearate, isopropyl oleate, n-butyl stearate, n-butyl stearate, n-butyl stearate, isonate iso-isonolate, n-butyl isonolate, n-hexyl isonolate, n-butyl isonate, n-butyl stearate, n-hexyl isonate, n-butyl isonate, n-butyl-isonate Ethylhexyl palmitate, 2-ethylhexyl laurate, 2-ethy
- the oil component can advantageously be selected from the group of dialkyl ethers and dialkyl carbonates; B. dicaprylyl ether (for example available under the trade name Cetiol OE) and / or dicaprylyl carbonate (for example available under the trade name Cetiol CC).
- Oils such as sunflower oil, soybean oil, jojoba oil, grape seed oil, almond oil and / or macadamia oil, which can be referred to as nourishing oils, are particularly preferred.
- the oil or oils is / are advantageously present with a total content of 0.01 to 3.0% by weight, preferably 0.05 to 2.0% by weight, based on the total weight of the preparation.
- the incorporation of at least one oil, in particular a natural, vegetable oil, into the preparation according to the invention helps to achieve or improve care performance. At the same time, the cleaning performance of the preparation according to the invention is increased.
- the preparation according to the invention can advantageously contain perfume.
- the perfume used is a mixture of perfume raw materials.
- the perfume is mainly contained in order to give the preparation according to the invention a pleasant odor.
- the perfume is present with a content of 0.05 to 0.5% by weight, in particular 0.1 to 0.4% by weight, based on the total weight of the preparation.
- the preparation according to the invention can contain cosmetic auxiliaries such as are customarily used in such preparations, e.g. complexing agents or other customary components of a cosmetic formulation.
- Sodium hydroxide or citric acid for example, are used to adjust the pH.
- the pH of the preparations according to the invention is in the range 5.0 to 8.0, before given in the range 6.5 to 7.5.
- the color pigment Sicovit Brown 70 E172 (Venator Pigments), a mixture of the iron oxides CI 77492, CI77491 and CI 77499, was introduced into various surfactant solutions that did not contain any thickening additives.
- the pigment mentioned can usually be incorporated into make-up preparations, such as foundations and mascaras, for example.
- Aqueous facial cleansing products (the quantities given are active contents):
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Abstract
L'invention concerne une préparation nettoyante contenant des polyglycérylesters d'acide gras, notamment du polyglycéryl-10 caprylate/caprate, pour le nettoyage de la peau du visage humaine, notamment pour le démaquillage.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE102019209908.4A DE102019209908A1 (de) | 2019-07-05 | 2019-07-05 | Fettsäure-Polyglycerylester-haltige Reinigungszubereitung |
PCT/EP2020/065768 WO2021004711A1 (fr) | 2019-07-05 | 2020-06-08 | Préparation nettoyante contenant des polyglycérylesters d'acide gras |
Publications (1)
Publication Number | Publication Date |
---|---|
EP3993763A1 true EP3993763A1 (fr) | 2022-05-11 |
Family
ID=71078516
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP20731842.9A Pending EP3993763A1 (fr) | 2019-07-05 | 2020-06-08 | Préparation nettoyante contenant des polyglycérylesters d'acide gras |
Country Status (3)
Country | Link |
---|---|
EP (1) | EP3993763A1 (fr) |
DE (1) | DE102019209908A1 (fr) |
WO (1) | WO2021004711A1 (fr) |
Families Citing this family (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP3981385B1 (fr) * | 2020-10-08 | 2023-06-21 | Oleon N.V. | Émollient et agent de nettoyage |
Family Cites Families (15)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
BRPI0600941A (pt) * | 2006-03-30 | 2007-11-20 | Botica Com Farmaceutica S A | nanoemulsão, método de produção e composição cosmética e dermatológica contendo a mesma |
DE102007022693A1 (de) | 2007-05-11 | 2009-01-15 | Evonik Stockhausen Gmbh | Haut- und Händereinigungsmittel mit hydrophilen Emollients |
US8831073B2 (en) | 2009-08-31 | 2014-09-09 | Sony Corporation | Wireless transmission system, wireless communication device, and wireless communication method |
US8227393B2 (en) | 2010-12-21 | 2012-07-24 | Johnson & Johnson Consumer Companies, Inc. | Compositions comprising a polyglyceryl nonionic surfactant and a zwitterionic surfactant |
US8338348B2 (en) * | 2010-12-21 | 2012-12-25 | Johnson & Johnson Consumer Companies, Inc. | Skin cleansing compositions with polyglycerol esters and hydrophobically modified polymers |
DE102013224957A1 (de) * | 2013-12-05 | 2015-06-11 | Evonik Industries Ag | Polyglycerinpartialester, ihre Herstellung und Verwendung |
JP2015178467A (ja) * | 2014-03-19 | 2015-10-08 | ロレアル | 内部オレフィンスルホン酸塩及び1種の起泡増強剤又は起泡増進剤を含有する起泡性組成物 |
WO2016145561A1 (fr) * | 2015-03-13 | 2016-09-22 | Evonik Specialty Chemicals (Shanghai) Co., Ltd. | Émulsion d'huile dans l'eau à faible viscosité, stable, sans peg et son utilisation |
DE102015204662A1 (de) | 2015-03-16 | 2016-09-22 | Beiersdorf Ag | Multifunktionszubereitung zur Gesichtsreinigung |
EP3081207B1 (fr) * | 2015-04-16 | 2022-09-21 | Symrise AG | Utilisation d'une composition de liposomes |
DE102015212822A1 (de) | 2015-07-09 | 2017-01-12 | Beiersdorf Ag | Reinigungstücher getränkt mit Tränkungsmitteln basierend auf einer Mizellentechnologie |
MX2018001778A (es) | 2015-08-13 | 2018-06-06 | Arch Personal Care Products Lp | Concentrado para paño limpiador humedo. |
CN107811874A (zh) * | 2017-10-31 | 2018-03-20 | 武汉润欣科技股份有限公司 | 一种不含peg‑系表面活性剂温和保湿卸妆水及其制备工艺 |
US10813852B2 (en) * | 2017-11-16 | 2020-10-27 | L'oreal | Bi-phase micellar liquid product comprising ceramides |
CN111601580B (zh) * | 2017-12-26 | 2023-09-05 | 莱雅公司 | 用于卸除皮肤上的彩妆的包含疏水聚合物的固体无水组合物 |
-
2019
- 2019-07-05 DE DE102019209908.4A patent/DE102019209908A1/de active Pending
-
2020
- 2020-06-08 EP EP20731842.9A patent/EP3993763A1/fr active Pending
- 2020-06-08 WO PCT/EP2020/065768 patent/WO2021004711A1/fr unknown
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Publication number | Publication date |
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WO2021004711A1 (fr) | 2021-01-14 |
DE102019209908A1 (de) | 2021-01-07 |
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