EP3993763A1 - Préparation nettoyante contenant des polyglycérylesters d'acide gras - Google Patents

Préparation nettoyante contenant des polyglycérylesters d'acide gras

Info

Publication number
EP3993763A1
EP3993763A1 EP20731842.9A EP20731842A EP3993763A1 EP 3993763 A1 EP3993763 A1 EP 3993763A1 EP 20731842 A EP20731842 A EP 20731842A EP 3993763 A1 EP3993763 A1 EP 3993763A1
Authority
EP
European Patent Office
Prior art keywords
polyglyceryl
preparation according
caprate
weight
preparation
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
EP20731842.9A
Other languages
German (de)
English (en)
Inventor
Kay Sven DEMITZ
Thomas Raschke
Katrin VETTER
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Beiersdorf AG
Original Assignee
Beiersdorf AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Beiersdorf AG filed Critical Beiersdorf AG
Publication of EP3993763A1 publication Critical patent/EP3993763A1/fr
Pending legal-status Critical Current

Links

Classifications

    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/33Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
    • A61K8/39Derivatives containing from 2 to 10 oxyalkylene groups
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61QSPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q1/00Make-up preparations; Body powders; Preparations for removing make-up
    • A61Q1/14Preparations for removing make-up
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K2800/00Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
    • A61K2800/20Chemical, physico-chemical or functional or structural properties of the composition as a whole
    • A61K2800/30Characterized by the absence of a particular group of ingredients
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K2800/00Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
    • A61K2800/20Chemical, physico-chemical or functional or structural properties of the composition as a whole
    • A61K2800/30Characterized by the absence of a particular group of ingredients
    • A61K2800/33Free of surfactant

Definitions

  • the present invention relates to a cleaning preparation which contains at least one fatty acid polyglyceryl ester.
  • This preparation is preferably suitable for removing make-up from human skin, in particular from facial skin.
  • the make-up used must also be removed again.
  • skin cleansing products for removing make-up from the facial area, namely facial cleansing products. Since the facial skin is particularly sensitive, particularly mild and non-irritating products are used for facial cleansing.
  • Decorative cosmetics A large number of different substances are used today in the field of decorative cosmetics.
  • inorganic pigments such as silicates [magnesium silicate (talc), aluminum silicate (kaolin)] and metal oxides (chromium, iron, manganese, titanium and zinc oxides)
  • organic color pigments are used as dyes.
  • Stearic acid esters, lanolin alcohol and acetate are used as binders.
  • Waxes such as beeswax or carnauba wax and oils such as paraffin oils, silicone oils or castor oil are used in many formulations.
  • Decorative cosmetics can also contain preservatives, antioxidants, thickeners and other additives.
  • Mascara, eyeshadow and kohl pencils On the other hand, they must be as kind to the skin as possible, please include in order not to cause any reddening of the skin or irritation of the mucous membranes in the users.
  • preparations have already been disclosed which are suitable for make-up removal or which have been specially developed for this purpose.
  • Various forms of preparation have been described and corresponding products are already available for purchase.
  • These preparations can be in the form of emulsions, which in turn are predominantly creamy, milky or liquid, gels or oily compositions.
  • multiphase compositions are known, in particular two-phase compositions which have two visually separate phases which are mixed by shaking the who. The resulting largely homogeneous phase is then applied to the skin.
  • WO 2016/146360 A1 discloses a facial cleansing preparation which is suitable for removing make-up and at the same time for refreshing the skin.
  • This preparation has an aqueous and an oily phase and is free of silicone compounds.
  • WO 2017/005485 A1 describes an impregnating agent for wipes.
  • the corresponding cleaning cloth is intended for facial cleaning.
  • the impregnation agent is based on Mi cell technology and contains a combination of surfactants, namely anionic surfactants in the form of acyl glutamates and nonionic surfactants in the form of alkyl glycosides and poloxamers.
  • washing gels which contain tenside in concentrations of around 3 to 10%, must be rinsed off. Furthermore, preparations can be made available that contain significantly fewer surfactants and therefore do not have to be rinsed off the skin.
  • micellar water also belong to the last-mentioned type of preparation. They are distinguished by the fact that the surfactant (s) is / are present in such a concentration that surfactant micelles can form.
  • the micelles are usually arranged in such a way that the lipophilic parts of the surfactants are directed inside the micelle and the hydrophilic parts of the surfactants point outwards into the aqueous environment.
  • the micelles can interact with the molecules on the surface of the skin. These molecules can be from makeup or Make-up residues, sebum or dead skin cells and other things come from it. In this way, the micelles help solubilize these molecules. With the help of a cotton wool pad or the like or with the help of water, these molecules, ie also the dirt, can now be removed from the skin.
  • Cleansing preparations that are designed so that they do not necessarily have to be rinsed off the skin with water can be removed from the surface of the skin, for example with a cotton ball, a cloth or the like, together with dissolved / undissolved dirt particles or molecules. In the case of such preparations, however, it must be ensured that they are sufficiently mild so that skin irritations are (largely) avoided.
  • ⁇ 0.9 wt .-% preferably ⁇ 0.5 wt .-%, particularly preferably ⁇ 0.3 wt .-% of at least one fatty acid polyglyceryl ester, based on the total weight of the preparation and based on the active content,
  • the preparation according to the invention is an aqueous preparation.
  • the preparation according to the invention is a cosmetic preparation.
  • the preparation according to the invention is advantageously used for cleaning human skin, in particular the facial skin, and in particular for removing make-up.
  • the preparation according to the invention contains at least one fatty acid polyglyceryl ester. These esters have at least two glycerol molecules that are linked to one another.
  • the free OH groups are esterified with fatty acids; partial esterification is present if not all OH groups are esterified with fatty acids.
  • Partial fatty acid polyglyceryl esters can be described, for example, by the following formula: where Ri is a linear or branched, saturated or unsaturated alkyl or alkenyl radical, the alkyl or alkenyl radical only or predominantly having alkyl or alkenyl radicals with 6 to 12 carbon atoms, preferably with 6 to 10 carbon atoms and n is an integer from 1 to 11.
  • the term predominantly means that more than 55%, in particular more than 65%, further in particular more than 80% of the radicals mentioned have 6 to 12 carbon atoms, preferably 6 to 10 carbon atoms.
  • the fatty acid polyglyceryl esters are uncharged, but the glycerine molecules contain oxygen atoms and ester bonds that contribute to the hydrophilicity, while the alkyl / alkylene radicals of the fatty acids contribute to the lipophilicity.
  • the fatty acid polyglyceryl esters are amphiphilic molecules.
  • the fatty acid polyglyceryl esters can therefore also act and be referred to as nonionic surfactants.
  • Surfactants are amphiphilic substances that, among other things, are able to dissolve organic, non-polar substances in water. They are characterized by an ambivalent behavior towards water and lipids.
  • the surfactant molecule contains at least one hydrophilic and one lipophilic group each, which enable attachment to the interface between an aqueous phase and a lipid phase. In this way, surfactants reduce the surface tension of the water, wetting the skin, making it easier to loosen and remove dirt, easy rinsing and, optionally, foam regulation. This provides the basis for removing dirt containing lipids.
  • EP 2455062 A2 discloses a heavy hand cleaner which contains various components, including an emollient in an amount of at least 0.1% by weight, this emollient can be a polyglyceryl partial ester and 2 to 40% by weight of a surfactant selected from fatty alcohol lethoxylates, fatty alcohol ether sulfates and salts of sulfated and / or sulfonated fatty acids. There is no disclosure of a facial cleanser or make-up remover. US 2012/0157366 A1 describes skin and hair cleansing preparations that have a low irritant potential.
  • the preparations contain a fatty acid polyglyceryl ester and anionic and amphoteric surfactants in an amount of 2 to 7% by weight. There is no disclosure that these preparations are suitable as facial cleansers or make-up removers.
  • US 2012/0157365 A1 discloses clear and mild cleaning preparations which are essentially free of ethoxylated compounds and have a pH of 5.4 or less. These preparations contain a nonionic surfactant, which can be a fatty acid polyglyceryl ester, a zwitterionic surfactant and a selected anionic surfactant. There is no disclosure that the preparations mentioned are intended to be used as make-up removers.
  • No. 10,117,818 B2 describes a concentrate for wet wipes.
  • This concentrate contains an emulsifier, which can be a fatty acid polyglyceryl ester, a humectant and an emollient.
  • the emulsifier is used in amounts of 15 to 60% by weight.
  • US 9,544,007 B2 discloses a tear-free cleaner for babies.
  • This cleaner contains, among others. 5 to 30 wt% polyglyceryl partial ester.
  • the cleaning preparation according to the invention contains only at least one fatty acid polyglyceryl ester in a total amount as surfactant (s)
  • ⁇ 0.9% by weight preferably ⁇ 0.5% by weight, particularly preferably ⁇ 0.3% by weight, based on the total weight of the preparation and based on the active content.
  • the cleaning preparation according to the invention contains at least one fatty acid polyglyceryl ester in a total amount
  • ⁇ 0.9% by weight preferably ⁇ 0.5% by weight, particularly preferably ⁇ 0.3% by weight, based on the total weight of the preparation and based on the active content and further surfactants selected from at least one anionic surfactant or at least one amphoteric surfactant and / or another nonionic surfactant.
  • the group of amphoteric surfactants also includes zwitterionic surfactants.
  • the other nonionic surfactants do not include any fatty acid polyglyceryl esters.
  • fatty acid polyglyceryl esters are compounds such as polyglyceryl-4
  • caprylate / caprate Polyglyceryl-5 caprylate / caprate, Polyglyceryl-6 caprylate / caprate, Polyglyceryl-7 caprylate / caprate, Polyglyceryl-8 caprylate / caprate, Polyglyceryl-9
  • polyglyceryl-10 caprylate / caprate Polyglyceryl-10 caprylate / caprate, Polyglyceryl-4 caprate, Polyglyceryl-5 caprate, Polyglyceryl-6 caprate, Polyglyceryl-7 caprate, Polyglyceryl-8 caprate, Polyglyceryl-9 caprate, Polyglyceryl-10 caprate, Polyglycerate-4 , Polyglyceryl-5 laurate, polyglyceryl-6 laurate, polyglyceryl-7 laurate, polyglyceryl-8 laurate, polyglyceryl-9 laurate, polyglyceryl-10 laurate.
  • the compound polyglyceryl-10 caprylate / caprate is preferred. This connection can be purchased from Lonza, for example, under the trade name Polyaldo® 10-1-CC.
  • the preparation according to the invention contains the at least one fatty acid polyglyceryl ester with a content of 0.007 to 0.8% by weight, preferably from 0.01 to 0.5% by weight, particularly preferably 0.05 to 0.3% by weight. % before, based on the total amount of the preparation and based on the active content.
  • these surfactants can be selected from various surfactant classes.
  • surfactants can be selected that are based on amino acids, that is, amino acid-based surfactants.
  • Suitable amino acid-based surfactants can be selected, for example, from:
  • Glycinates such as acyl glycinates.
  • acyl glutamate (s) and / or acyl glycinate (s) are contained.
  • a particularly advantageous acyl glutamate is Disodium Cocoyl Glutamate, which is available, for example, with the trade name Hostapon - CCG from Clariant.
  • acyl glycinate with the name sodium cocoyl glycinate which is available, for example, under the trade name Hostapon SG from Clariant.
  • the preparation according to the invention contains one or more surfactants based on amino acids
  • the total content of the one or more surfactants mentioned is in the range from 0.001 to 0.5% by weight, preferably 0.05 to 0, 3% by weight, based on the total weight of the preparation and the respective active content.
  • the preparations according to the invention do not contain any surfactants which have sulfate groups. It is further preferred if the entire preparation according to the invention does not contain any compounds which have sulfate groups. It is further particularly preferred if the preparation according to the invention is entirely sulfate-free.
  • sulfates is understood to mean salts and esters of sulfuric acid.
  • the salts can be represented by the formulas SO4 2 (anion) and HSO4 2 (hydrogen sulfate anion), while the esters have the general formula R-0-S0 2 -0-R ', where R and / or R' are organic radicals are and R 'also be hydrogen.
  • R and / or R' are organic radicals are and R 'also be hydrogen.
  • the acid dissociates and is present as a salt.
  • sulfate-free means that the respective raw material or the respective composition is less than 0.1% by weight, preferably less than
  • amphoteric surfactants have both anionic and cationic groups and accordingly behave like anionic or cationic surfactants in aqueous solution, depending on the pH. They have a positive charge in a strongly acidic environment and a negative charge in an alkaline environment. In the neutral pH range, however, they are zwitterionic, as the following example should clarify:
  • Suitable amphoteric surfactants can be selected, for example, from:
  • Acyl / dialkyl ethylenediamine for example sodium acylamphoacetate, disodium macylamphodipropionate, disodium alkylamphodiacetate, disodium cocoamphodiacetate, disodium cocoamphomonoacetate, sodium acylamphohydroxypropylsulfonate, disodium macylamphodiacetate and sodium
  • Betaines for example Coco Betaine, Cocoamidopropyl Betaine,
  • Sultaines for example lauryl hydroxy sultaine.
  • amphoteric surfactant (s) are selected from the group of betaines, more preferably from the group of alkylamidopropyl betaines and alkyl betaines. It is particularly preferred if the amphoteric surfactant is cocamidopropyl betaine.
  • amphoteric surfactant (s) are selected from the group of the sultaines, more preferably from the group of hydroxysultaines and / or amidopropylhydroxysultaines.
  • amphoteric surfactant or surfactants are selected from acyl / dialkylethylenediamine, in particular from acylamphoacetates, which can be described by the following formula:
  • R is an alkyl radical having 8 to 30 carbon atoms.
  • acylamphoacetates are synthesized in two steps. First, a fatty acid or a mixture of fatty acids that come from a natural oil is added to a vegetable oil, such as coconut oil, soybean oil or palm oil, with N- (2-hydroxyethyl) ethylenediamine. The resulting 2-alkyl-1-hydroxyethylimidazolines who hydrolyzed to linear amidoamines with NaOH. These in turn are mixed with monochloroacetic acid. Acyl monoamphoacetates are formed. If larger molar amounts of monochloroacetic acid are used, acylamphodiacetates are formed.
  • Acylamphacetates are amphoteric surfactants which, depending on the pH value, are available as anionic, zwitterioni cal or cationic surfactants.
  • the sodium salts of acylamphoacetates are known to have little imitative effect.
  • the acyl radical is derived from fatty acids of vegetable origin, preferably from fatty acids obtained from coconut oil.
  • the sodium salts of the acylamphoacetates are selected.
  • the total content of the at least one amphoteric surfactant is in the range from 0.001 to 0.5% by weight, preferably 0.05 to 0.3% by weight, based on the total weight the preparation and the respective active content.
  • Nonionic surfactants are characterized by the fact that they do not form any ions in the aqueous medium.
  • Suitable nonionic surfactants can be selected, for example, from the group of the alkyl polyglycosides, such as lauryl glucoside, decyl glucoside and cocoglucoside.
  • Alkyl polyglycosides can be represented by the general structural formula RO- (Z) x , where R is an alkyl radical with 6 to 30 carbon atoms, Z is a sugar radical and x is the number of sugar radicals.
  • the alkyl radical can be a radical with a specific number of carbon atoms or can be a mixture of alkyl radicals. Such mixtures are obtained when natural oils such as palm oil, soybean oil or coconut oil are used as the starting material for the production of the alkyl polyglucosides. It is preferred if the alkyl groups have essentially 12 to 18 carbon atoms
  • the sugar residues can be monosaccharides or oligosaccharides, which preferably have sugar residues with 5 or 6 carbon atoms.
  • Suitable sugar residues are, for example, glucose, fructose, galactose, arabinose, ribose, xylose, allose, mannose, gulose, idose, talose and sucrose.
  • Glucose and sucrose are particularly preferred, glucose being particularly preferred.
  • Alkyl polyglycosides contain on average 1.1 to 5, preferably 1.1 to 2.0, sugar residues per molecule.
  • the total content of the at least one nonionic surfactant is in the range from 0.001 to 0.5% by weight, preferably 0.05 to 0.3% by weight, based on the total weight of the preparation and the respective active content.
  • the total amount of surfactant is 0.05 to 0.9% by weight, preferably 0.1 to 0.5% by weight, based on the total weight of the preparation and the respective active content.
  • the total amount of surfactant comprises the content of the at least one fatty acid polyglyceryl ester and the content of at least one further surfactant.
  • Micelles can form in the preparations according to the invention if the contents of the surfactants contained in each case assume suitable values.
  • the preparation according to the invention can advantageously contain preservatives.
  • Preservatives are those preserving substances that are approved for use in cosmetic products for Europe in accordance with the Cosmetics Regulation for Germany and Regulation (EC) No. 1223/2009 on cosmetic agents.
  • the at least one preservative can advantageously be selected from the group consisting of phenoxyethanol, methyl paraben, polyaminopropyl biguanide, benzoic acid and / or a physiologically acceptable salt thereof, benzethonium chloride and / or benzyl alcohol.
  • stabilizers are those substances that are not included in the list of permitted preservatives (Cosmetics Ordinance Annex 6; Regulation (EC) No. 1223/2009, Annex V), but nevertheless one have a stabilizing effect and / or, when used together with preservatives, promote the stability of the preparation for 36 months.
  • ethylhexylglycerol 1,2-hexanediol, trisodium EDTA, methylpropanediol, caprylyl glycol, glyceryl caprylate and / or pentylene glycol.
  • the preparation according to the invention contains the at least one preservative and / or the at least one stabilizer with a content of 0.0001 to 6% by weight, preferably from 0.0005 to 5% by weight, particularly preferably from 0.001 to 4% by weight before, based on the total weight of the preparation.
  • Humectants can, for example, give the skin moisture and / or help prevent moisture loss in the skin.
  • the humectants are hygroscopic substances that can bind water. This water-binding capacity is based on hydrophilic groups such as hydroxyl groups, but also amine groups and carboxyl groups.
  • Humectants are, for example, propylene glycol, butylene glycol, glycerine, sorbitol, xylitol, aloe vera gel. The use of propylene glycol and / or glycerine is preferred according to the invention.
  • the humectant or humectants is / are present with a total content of 0.01 to 10% by weight, preferably 0.1 to 5.0% by weight, based on the total weight of the preparation.
  • oils are additionally incorporated into the preparation according to the invention.
  • the oils can be selected from the group of polar oils, for example from the group of fatty acid triglycerides, namely the triglycerol esters of saturated and / or unsaturated, branched and / or unbranched alkanecarboxylic acids with a chain length of 8 to 24, especially 12 to 18 carbon atoms - men.
  • the fatty acid triglycerides can, for example, advantageously be selected from the group of synthetic, semi-synthetic and natural oils, such as. B.
  • cocoglyceride Olive oil, sunflower oil, soybean oil, peanut oil, rapeseed oil, almond oil, palm oil, coconut oil, wheat germ oil, grapeseed oil, safflower oil, evening primrose oil, macadamia oil and the like.
  • polar oil components can be selected for the purposes of the present invention further from the group of monoesters of saturated and / or unsaturated, branched and / or unbranched alkanecarboxylic acids with a chain length of 3 to 30 carbon atoms and saturated and / or unsaturated, branched and / or unbranched alcohols get a chain length of 3 to 30 carbon atoms and from the group of esters of aromatic carboxylic acids and saturated and / or unsaturated, branched and / or unbranched alcohols with a chain length of 3 to 30 carbon atoms.
  • ester oils can then advantageously be chosen from the group of octyl palmitate, octyl cocoate, octyl isostearate, octyl dodeceyl myristate, cetearyl isononanoate, isopropyl myristate, isopropyl palmitate, isopropyl stearate, isopropyl oleate, n-butyl stearate, n-butyl stearate, n-butyl stearate, isonate iso-isonolate, n-butyl isonolate, n-hexyl isonolate, n-butyl isonate, n-butyl stearate, n-hexyl isonate, n-butyl isonate, n-butyl-isonate Ethylhexyl palmitate, 2-ethylhexyl laurate, 2-ethy
  • the oil component can advantageously be selected from the group of dialkyl ethers and dialkyl carbonates; B. dicaprylyl ether (for example available under the trade name Cetiol OE) and / or dicaprylyl carbonate (for example available under the trade name Cetiol CC).
  • Oils such as sunflower oil, soybean oil, jojoba oil, grape seed oil, almond oil and / or macadamia oil, which can be referred to as nourishing oils, are particularly preferred.
  • the oil or oils is / are advantageously present with a total content of 0.01 to 3.0% by weight, preferably 0.05 to 2.0% by weight, based on the total weight of the preparation.
  • the incorporation of at least one oil, in particular a natural, vegetable oil, into the preparation according to the invention helps to achieve or improve care performance. At the same time, the cleaning performance of the preparation according to the invention is increased.
  • the preparation according to the invention can advantageously contain perfume.
  • the perfume used is a mixture of perfume raw materials.
  • the perfume is mainly contained in order to give the preparation according to the invention a pleasant odor.
  • the perfume is present with a content of 0.05 to 0.5% by weight, in particular 0.1 to 0.4% by weight, based on the total weight of the preparation.
  • the preparation according to the invention can contain cosmetic auxiliaries such as are customarily used in such preparations, e.g. complexing agents or other customary components of a cosmetic formulation.
  • Sodium hydroxide or citric acid for example, are used to adjust the pH.
  • the pH of the preparations according to the invention is in the range 5.0 to 8.0, before given in the range 6.5 to 7.5.
  • the color pigment Sicovit Brown 70 E172 (Venator Pigments), a mixture of the iron oxides CI 77492, CI77491 and CI 77499, was introduced into various surfactant solutions that did not contain any thickening additives.
  • the pigment mentioned can usually be incorporated into make-up preparations, such as foundations and mascaras, for example.
  • Aqueous facial cleansing products (the quantities given are active contents):

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  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Animal Behavior & Ethology (AREA)
  • General Health & Medical Sciences (AREA)
  • Public Health (AREA)
  • Veterinary Medicine (AREA)
  • Emergency Medicine (AREA)
  • Birds (AREA)
  • Epidemiology (AREA)
  • Cosmetics (AREA)

Abstract

L'invention concerne une préparation nettoyante contenant des polyglycérylesters d'acide gras, notamment du polyglycéryl-10 caprylate/caprate, pour le nettoyage de la peau du visage humaine, notamment pour le démaquillage.
EP20731842.9A 2019-07-05 2020-06-08 Préparation nettoyante contenant des polyglycérylesters d'acide gras Pending EP3993763A1 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE102019209908.4A DE102019209908A1 (de) 2019-07-05 2019-07-05 Fettsäure-Polyglycerylester-haltige Reinigungszubereitung
PCT/EP2020/065768 WO2021004711A1 (fr) 2019-07-05 2020-06-08 Préparation nettoyante contenant des polyglycérylesters d'acide gras

Publications (1)

Publication Number Publication Date
EP3993763A1 true EP3993763A1 (fr) 2022-05-11

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Family Applications (1)

Application Number Title Priority Date Filing Date
EP20731842.9A Pending EP3993763A1 (fr) 2019-07-05 2020-06-08 Préparation nettoyante contenant des polyglycérylesters d'acide gras

Country Status (3)

Country Link
EP (1) EP3993763A1 (fr)
DE (1) DE102019209908A1 (fr)
WO (1) WO2021004711A1 (fr)

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP3981385B1 (fr) * 2020-10-08 2023-06-21 Oleon N.V. Émollient et agent de nettoyage

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DE102007022693A1 (de) 2007-05-11 2009-01-15 Evonik Stockhausen Gmbh Haut- und Händereinigungsmittel mit hydrophilen Emollients
US8831073B2 (en) 2009-08-31 2014-09-09 Sony Corporation Wireless transmission system, wireless communication device, and wireless communication method
US8227393B2 (en) 2010-12-21 2012-07-24 Johnson & Johnson Consumer Companies, Inc. Compositions comprising a polyglyceryl nonionic surfactant and a zwitterionic surfactant
US8338348B2 (en) * 2010-12-21 2012-12-25 Johnson & Johnson Consumer Companies, Inc. Skin cleansing compositions with polyglycerol esters and hydrophobically modified polymers
DE102013224957A1 (de) * 2013-12-05 2015-06-11 Evonik Industries Ag Polyglycerinpartialester, ihre Herstellung und Verwendung
JP2015178467A (ja) * 2014-03-19 2015-10-08 ロレアル 内部オレフィンスルホン酸塩及び1種の起泡増強剤又は起泡増進剤を含有する起泡性組成物
WO2016145561A1 (fr) * 2015-03-13 2016-09-22 Evonik Specialty Chemicals (Shanghai) Co., Ltd. Émulsion d'huile dans l'eau à faible viscosité, stable, sans peg et son utilisation
DE102015204662A1 (de) 2015-03-16 2016-09-22 Beiersdorf Ag Multifunktionszubereitung zur Gesichtsreinigung
EP3081207B1 (fr) * 2015-04-16 2022-09-21 Symrise AG Utilisation d'une composition de liposomes
DE102015212822A1 (de) 2015-07-09 2017-01-12 Beiersdorf Ag Reinigungstücher getränkt mit Tränkungsmitteln basierend auf einer Mizellentechnologie
MX2018001778A (es) 2015-08-13 2018-06-06 Arch Personal Care Products Lp Concentrado para paño limpiador humedo.
CN107811874A (zh) * 2017-10-31 2018-03-20 武汉润欣科技股份有限公司 一种不含peg‑系表面活性剂温和保湿卸妆水及其制备工艺
US10813852B2 (en) * 2017-11-16 2020-10-27 L'oreal Bi-phase micellar liquid product comprising ceramides
CN111601580B (zh) * 2017-12-26 2023-09-05 莱雅公司 用于卸除皮肤上的彩妆的包含疏水聚合物的固体无水组合物

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WO2021004711A1 (fr) 2021-01-14
DE102019209908A1 (de) 2021-01-07

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