EP3985137A1 - Alliage de nicocraly, poudre, revêtement et composant - Google Patents

Alliage de nicocraly, poudre, revêtement et composant Download PDF

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Publication number
EP3985137A1
EP3985137A1 EP20201694.5A EP20201694A EP3985137A1 EP 3985137 A1 EP3985137 A1 EP 3985137A1 EP 20201694 A EP20201694 A EP 20201694A EP 3985137 A1 EP3985137 A1 EP 3985137A1
Authority
EP
European Patent Office
Prior art keywords
coating
alloy
powder
optionally
coatings
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
EP20201694.5A
Other languages
German (de)
English (en)
Inventor
Xin-hai LI
Snezana Djordjevic
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Siemens Energy Global GmbH and Co KG
Original Assignee
Siemens Energy Global GmbH and Co KG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Siemens Energy Global GmbH and Co KG filed Critical Siemens Energy Global GmbH and Co KG
Priority to EP20201694.5A priority Critical patent/EP3985137A1/fr
Priority to US18/029,907 priority patent/US20230366066A1/en
Priority to PCT/EP2021/076386 priority patent/WO2022078733A1/fr
Priority to CN202180069346.5A priority patent/CN116324035A/zh
Priority to EP21786784.5A priority patent/EP4196620A1/fr
Publication of EP3985137A1 publication Critical patent/EP3985137A1/fr
Withdrawn legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C28/00Coating for obtaining at least two superposed coatings either by methods not provided for in a single one of groups C23C2/00 - C23C26/00 or by combinations of methods provided for in subclasses C23C and C25C or C25D
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22FWORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
    • B22F1/00Metallic powder; Treatment of metallic powder, e.g. to facilitate working or to improve properties
    • B22F1/10Metallic powder containing lubricating or binding agents; Metallic powder containing organic material
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22FWORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
    • B22F1/00Metallic powder; Treatment of metallic powder, e.g. to facilitate working or to improve properties
    • B22F1/12Metallic powder containing non-metallic particles
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C19/00Alloys based on nickel or cobalt
    • C22C19/03Alloys based on nickel or cobalt based on nickel
    • C22C19/05Alloys based on nickel or cobalt based on nickel with chromium
    • C22C19/051Alloys based on nickel or cobalt based on nickel with chromium and Mo or W
    • C22C19/056Alloys based on nickel or cobalt based on nickel with chromium and Mo or W with the maximum Cr content being at least 10% but less than 20%
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C30/00Alloys containing less than 50% by weight of each constituent
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C28/00Coating for obtaining at least two superposed coatings either by methods not provided for in a single one of groups C23C2/00 - C23C26/00 or by combinations of methods provided for in subclasses C23C and C25C or C25D
    • C23C28/30Coatings combining at least one metallic layer and at least one inorganic non-metallic layer
    • C23C28/32Coatings combining at least one metallic layer and at least one inorganic non-metallic layer including at least one pure metallic layer
    • C23C28/321Coatings combining at least one metallic layer and at least one inorganic non-metallic layer including at least one pure metallic layer with at least one metal alloy layer
    • C23C28/3215Coatings combining at least one metallic layer and at least one inorganic non-metallic layer including at least one pure metallic layer with at least one metal alloy layer at least one MCrAlX layer
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C28/00Coating for obtaining at least two superposed coatings either by methods not provided for in a single one of groups C23C2/00 - C23C26/00 or by combinations of methods provided for in subclasses C23C and C25C or C25D
    • C23C28/30Coatings combining at least one metallic layer and at least one inorganic non-metallic layer
    • C23C28/34Coatings combining at least one metallic layer and at least one inorganic non-metallic layer including at least one inorganic non-metallic material layer, e.g. metal carbide, nitride, boride, silicide layer and their mixtures, enamels, phosphates and sulphates
    • C23C28/345Coatings combining at least one metallic layer and at least one inorganic non-metallic layer including at least one inorganic non-metallic material layer, e.g. metal carbide, nitride, boride, silicide layer and their mixtures, enamels, phosphates and sulphates with at least one oxide layer
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C28/00Coating for obtaining at least two superposed coatings either by methods not provided for in a single one of groups C23C2/00 - C23C26/00 or by combinations of methods provided for in subclasses C23C and C25C or C25D
    • C23C28/30Coatings combining at least one metallic layer and at least one inorganic non-metallic layer
    • C23C28/34Coatings combining at least one metallic layer and at least one inorganic non-metallic layer including at least one inorganic non-metallic material layer, e.g. metal carbide, nitride, boride, silicide layer and their mixtures, enamels, phosphates and sulphates
    • C23C28/345Coatings combining at least one metallic layer and at least one inorganic non-metallic layer including at least one inorganic non-metallic material layer, e.g. metal carbide, nitride, boride, silicide layer and their mixtures, enamels, phosphates and sulphates with at least one oxide layer
    • C23C28/3455Coatings combining at least one metallic layer and at least one inorganic non-metallic layer including at least one inorganic non-metallic material layer, e.g. metal carbide, nitride, boride, silicide layer and their mixtures, enamels, phosphates and sulphates with at least one oxide layer with a refractory ceramic layer, e.g. refractory metal oxide, ZrO2, rare earth oxides or a thermal barrier system comprising at least one refractory oxide layer
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C30/00Coating with metallic material characterised only by the composition of the metallic material, i.e. not characterised by the coating process
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C4/00Coating by spraying the coating material in the molten state, e.g. by flame, plasma or electric discharge
    • C23C4/04Coating by spraying the coating material in the molten state, e.g. by flame, plasma or electric discharge characterised by the coating material
    • C23C4/06Metallic material
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C4/00Coating by spraying the coating material in the molten state, e.g. by flame, plasma or electric discharge
    • C23C4/04Coating by spraying the coating material in the molten state, e.g. by flame, plasma or electric discharge characterised by the coating material
    • C23C4/06Metallic material
    • C23C4/073Metallic material containing MCrAl or MCrAlY alloys, where M is nickel, cobalt or iron, with or without non-metal elements
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C4/00Coating by spraying the coating material in the molten state, e.g. by flame, plasma or electric discharge
    • C23C4/18After-treatment
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22FWORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
    • B22F2301/00Metallic composition of the powder or its coating
    • B22F2301/15Nickel or cobalt
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22FWORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
    • B22F2999/00Aspects linked to processes or compositions used in powder metallurgy

Definitions

  • the invention relates to a composition of a NiCoCrAlY based alloy especially used for gas turbines, a powder, a coating and a component.
  • This invention is to solve the problem by using recent research results and upgraded thermodynamic modelling to design an optimized and innovative NiCoCrAlX alloy coatings applied by means of thermal spraying in air, vacuum, or protected atmosphere, physical deposition, and plating on Ni or Co based superalloys.
  • X is a combination of minor elements such as Y, Ru, Ir, Si, Hf, Ta and etc. instead of Yttrium (Y) in the current NiCoCrAlY coatings. It means that we will introduce other minor elements to replace part of Yttrium (Y) functions in order to keep Yttrium (Y) content low.
  • NiCoCrAlX coatings are fabricated using Ruthenium (Ru) and Iridium (Ir) and reduces diffusion rate of Aluminum (Al) and forms diffusion barrier to minimize the interdiffusion between NiCoCrAlX coating and substrates. Ru addition increases mechanical durability of the coatings. Moreover, another approach in designing and manufacturing the innovative NiCoCrAlX coatings is reduce S content to ⁇ 10ppm to further increase coating lifetime.
  • the coating thickness should be in the range of 30-800 ⁇ m depending on type of applications and application methods.
  • the new NiCoCrAlX coating is Ni-based and possesses the preferred following composition (in wt%):
  • a powder with this alloy composition can be mixed with a binder and/or refractory metals or ceramics if used as an abrasive coating.
  • a metallic substrate like a nickel or cobalt based superalloy is used on which the inventive coating is applied on.
  • the coating is applied especially by the thermal spray and electron beam vapor deposition processes.
  • a layer system therefore at least comprises a metallic substrate, especially a Nickel based superalloy and at least a coating with the inventive alloy and optionally a ceramic layer on top the metallic bond and oxidation coating.
  • the ceramic layer comprises preferably a Zirconia based composition, partly or fully stabilized.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Metallurgy (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • Plasma & Fusion (AREA)
  • Ceramic Engineering (AREA)
  • Other Surface Treatments For Metallic Materials (AREA)
  • Paints Or Removers (AREA)
EP20201694.5A 2020-10-14 2020-10-14 Alliage de nicocraly, poudre, revêtement et composant Withdrawn EP3985137A1 (fr)

Priority Applications (5)

Application Number Priority Date Filing Date Title
EP20201694.5A EP3985137A1 (fr) 2020-10-14 2020-10-14 Alliage de nicocraly, poudre, revêtement et composant
US18/029,907 US20230366066A1 (en) 2020-10-14 2021-09-24 NiCoCrAlY- ALLOY, A POWDER, A COATING AND A COMPONENT
PCT/EP2021/076386 WO2022078733A1 (fr) 2020-10-14 2021-09-24 Alliage nicocraly, poudre, revêtement et composant
CN202180069346.5A CN116324035A (zh) 2020-10-14 2021-09-24 NiCoCrAlY合金、粉末、涂层和组件
EP21786784.5A EP4196620A1 (fr) 2020-10-14 2021-09-24 Alliage nicocraly, poudre, revêtement et composant

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
EP20201694.5A EP3985137A1 (fr) 2020-10-14 2020-10-14 Alliage de nicocraly, poudre, revêtement et composant

Publications (1)

Publication Number Publication Date
EP3985137A1 true EP3985137A1 (fr) 2022-04-20

Family

ID=72885364

Family Applications (2)

Application Number Title Priority Date Filing Date
EP20201694.5A Withdrawn EP3985137A1 (fr) 2020-10-14 2020-10-14 Alliage de nicocraly, poudre, revêtement et composant
EP21786784.5A Pending EP4196620A1 (fr) 2020-10-14 2021-09-24 Alliage nicocraly, poudre, revêtement et composant

Family Applications After (1)

Application Number Title Priority Date Filing Date
EP21786784.5A Pending EP4196620A1 (fr) 2020-10-14 2021-09-24 Alliage nicocraly, poudre, revêtement et composant

Country Status (4)

Country Link
US (1) US20230366066A1 (fr)
EP (2) EP3985137A1 (fr)
CN (1) CN116324035A (fr)
WO (1) WO2022078733A1 (fr)

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2000075398A1 (fr) * 1999-06-02 2000-12-14 Abb Research Ltd. Composition d'enduction conferant une protection contre des temperatures elevees
EP2256221A1 (fr) * 2008-03-28 2010-12-01 Mitsubishi Heavy Industries, Ltd. Matière d'alliage présentant une résistance à la corrosion à haute température, matière de revêtement de protection thermique, élément de turbine et turbine à gaz
EP2423439A2 (fr) * 2010-08-26 2012-02-29 Honeywell International, Inc. Procédés pour la formation de revêtements MCrA1Y sur des composants de moteur de turbine à gaz
WO2013056935A1 (fr) * 2011-10-20 2013-04-25 Siemens Aktiengesellschaft Revêtement, système de couche de revêtement, composant en superalliage recouvert

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US9138963B2 (en) * 2009-12-14 2015-09-22 United Technologies Corporation Low sulfur nickel base substrate alloy and overlay coating system
CN104757863B (zh) * 2015-03-17 2016-08-17 浙江三禾厨具有限公司 等离子不粘锅及其制造方法

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2000075398A1 (fr) * 1999-06-02 2000-12-14 Abb Research Ltd. Composition d'enduction conferant une protection contre des temperatures elevees
EP2256221A1 (fr) * 2008-03-28 2010-12-01 Mitsubishi Heavy Industries, Ltd. Matière d'alliage présentant une résistance à la corrosion à haute température, matière de revêtement de protection thermique, élément de turbine et turbine à gaz
EP2423439A2 (fr) * 2010-08-26 2012-02-29 Honeywell International, Inc. Procédés pour la formation de revêtements MCrA1Y sur des composants de moteur de turbine à gaz
WO2013056935A1 (fr) * 2011-10-20 2013-04-25 Siemens Aktiengesellschaft Revêtement, système de couche de revêtement, composant en superalliage recouvert

Non-Patent Citations (3)

* Cited by examiner, † Cited by third party
Title
NIJDAM TJSLOOF WG., ACTA MATERIALIA, vol. 55, 2007, pages 5980
SMIALEK JL.: "Metallurgical Transactions A", PHYSICAL METALLURGY AND MATERIALS SCIENCE, vol. 22A, 1991, pages 739
SMIALEK JLJAYNE DTSCHAEFFER JCMURPHY WH., THIN SOLID FILMS, vol. 253, 1994, pages 285

Also Published As

Publication number Publication date
EP4196620A1 (fr) 2023-06-21
WO2022078733A1 (fr) 2022-04-21
US20230366066A1 (en) 2023-11-16
CN116324035A (zh) 2023-06-23

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