EP3966278A1 - Recycling method of cigarette butts - Google Patents
Recycling method of cigarette buttsInfo
- Publication number
- EP3966278A1 EP3966278A1 EP20806289.3A EP20806289A EP3966278A1 EP 3966278 A1 EP3966278 A1 EP 3966278A1 EP 20806289 A EP20806289 A EP 20806289A EP 3966278 A1 EP3966278 A1 EP 3966278A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- cigarette butts
- mixture
- recycling
- mixing
- ethanol
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 235000019504 cigarettes Nutrition 0.000 title claims abstract description 86
- 238000000034 method Methods 0.000 title claims description 52
- 238000004064 recycling Methods 0.000 title claims description 24
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims abstract description 67
- 238000002156 mixing Methods 0.000 claims abstract description 23
- 239000000203 mixture Substances 0.000 claims description 49
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 26
- 238000001914 filtration Methods 0.000 claims description 15
- 238000003825 pressing Methods 0.000 claims description 8
- 238000009835 boiling Methods 0.000 claims description 7
- 238000002386 leaching Methods 0.000 claims 1
- 239000000446 fuel Substances 0.000 abstract description 12
- 239000000126 substance Substances 0.000 abstract description 9
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 abstract description 8
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 abstract description 8
- 231100000614 poison Toxicity 0.000 abstract description 7
- 239000003440 toxic substance Substances 0.000 abstract description 5
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 abstract description 4
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 abstract description 4
- 229910021529 ammonia Inorganic materials 0.000 abstract description 4
- 239000001273 butane Substances 0.000 abstract description 4
- IJDNQMDRQITEOD-UHFFFAOYSA-N n-butane Chemical compound CCCC IJDNQMDRQITEOD-UHFFFAOYSA-N 0.000 abstract description 4
- OFBQJSOFQDEBGM-UHFFFAOYSA-N n-pentane Natural products CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 abstract description 4
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 abstract description 3
- 241000779819 Syncarpia glomulifera Species 0.000 abstract description 3
- 229910052785 arsenic Inorganic materials 0.000 abstract description 3
- RQNWIZPPADIBDY-UHFFFAOYSA-N arsenic atom Chemical compound [As] RQNWIZPPADIBDY-UHFFFAOYSA-N 0.000 abstract description 3
- 229910052793 cadmium Inorganic materials 0.000 abstract description 3
- BDOSMKKIYDKNTQ-UHFFFAOYSA-N cadmium atom Chemical compound [Cd] BDOSMKKIYDKNTQ-UHFFFAOYSA-N 0.000 abstract description 3
- 229910002091 carbon monoxide Inorganic materials 0.000 abstract description 3
- 239000001739 pinus spp. Substances 0.000 abstract description 3
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 abstract description 3
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 abstract description 3
- 229940036248 turpentine Drugs 0.000 abstract description 3
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 abstract description 2
- 238000004519 manufacturing process Methods 0.000 abstract description 2
- WSFSSNUMVMOOMR-NJFSPNSNSA-N methanone Chemical compound O=[14CH2] WSFSSNUMVMOOMR-NJFSPNSNSA-N 0.000 abstract description 2
- 229910052759 nickel Inorganic materials 0.000 abstract description 2
- 235000019441 ethanol Nutrition 0.000 description 18
- 241000208125 Nicotiana Species 0.000 description 12
- 235000002637 Nicotiana tabacum Nutrition 0.000 description 12
- 230000000391 smoking effect Effects 0.000 description 6
- 239000007789 gas Substances 0.000 description 5
- LELOWRISYMNNSU-UHFFFAOYSA-N hydrogen cyanide Chemical compound N#C LELOWRISYMNNSU-UHFFFAOYSA-N 0.000 description 4
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- 229920002301 cellulose acetate Polymers 0.000 description 3
- 239000007772 electrode material Substances 0.000 description 3
- 239000002574 poison Substances 0.000 description 3
- KWOLFJPFCHCOCG-UHFFFAOYSA-N Acetophenone Chemical compound CC(=O)C1=CC=CC=C1 KWOLFJPFCHCOCG-UHFFFAOYSA-N 0.000 description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 2
- UFWIBTONFRDIAS-UHFFFAOYSA-N Naphthalene Chemical compound C1=CC=CC2=CC=CC=C21 UFWIBTONFRDIAS-UHFFFAOYSA-N 0.000 description 2
- 239000010426 asphalt Substances 0.000 description 2
- 230000034994 death Effects 0.000 description 2
- 231100000517 death Toxicity 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 2
- 239000000047 product Substances 0.000 description 2
- 239000000779 smoke Substances 0.000 description 2
- 231100000331 toxic Toxicity 0.000 description 2
- 230000002588 toxic effect Effects 0.000 description 2
- 238000005406 washing Methods 0.000 description 2
- SNICXCGAKADSCV-JTQLQIEISA-N (-)-Nicotine Chemical compound CN1CCC[C@H]1C1=CC=CN=C1 SNICXCGAKADSCV-JTQLQIEISA-N 0.000 description 1
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 1
- 208000024172 Cardiovascular disease Diseases 0.000 description 1
- 206010058467 Lung neoplasm malignant Diseases 0.000 description 1
- HZEBHPIOVYHPMT-OUBTZVSYSA-N Polonium-210 Chemical compound [210Po] HZEBHPIOVYHPMT-OUBTZVSYSA-N 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 230000000711 cancerogenic effect Effects 0.000 description 1
- 239000001569 carbon dioxide Substances 0.000 description 1
- 229910002092 carbon dioxide Inorganic materials 0.000 description 1
- 231100000357 carcinogen Toxicity 0.000 description 1
- 239000003183 carcinogenic agent Substances 0.000 description 1
- 229920002678 cellulose Polymers 0.000 description 1
- 239000001913 cellulose Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000007598 dipping method Methods 0.000 description 1
- 208000037265 diseases, disorders, signs and symptoms Diseases 0.000 description 1
- 208000035475 disorder Diseases 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 125000000524 functional group Chemical group 0.000 description 1
- 239000003673 groundwater Substances 0.000 description 1
- 239000002917 insecticide Substances 0.000 description 1
- 201000005202 lung cancer Diseases 0.000 description 1
- 230000004199 lung function Effects 0.000 description 1
- 208000020816 lung neoplasm Diseases 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 229960002715 nicotine Drugs 0.000 description 1
- SNICXCGAKADSCV-UHFFFAOYSA-N nicotine Natural products CN1CCCC1C1=CC=CN=C1 SNICXCGAKADSCV-UHFFFAOYSA-N 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000012188 paraffin wax Substances 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 238000009656 pre-carbonization Methods 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 230000005855 radiation Effects 0.000 description 1
- 229910052704 radon Inorganic materials 0.000 description 1
- SYUHGPGVQRZVTB-UHFFFAOYSA-N radon atom Chemical compound [Rn] SYUHGPGVQRZVTB-UHFFFAOYSA-N 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 239000005871 repellent Substances 0.000 description 1
- 230000002940 repellent Effects 0.000 description 1
- 239000013049 sediment Substances 0.000 description 1
- 239000002689 soil Substances 0.000 description 1
- 230000029305 taxis Effects 0.000 description 1
- 230000001225 therapeutic effect Effects 0.000 description 1
- 231100000167 toxic agent Toxicity 0.000 description 1
- 239000002341 toxic gas Substances 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B09—DISPOSAL OF SOLID WASTE; RECLAMATION OF CONTAMINATED SOIL
- B09B—DISPOSAL OF SOLID WASTE NOT OTHERWISE PROVIDED FOR
- B09B3/00—Destroying solid waste or transforming solid waste into something useful or harmless
- B09B3/70—Chemical treatment, e.g. pH adjustment or oxidation
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B09—DISPOSAL OF SOLID WASTE; RECLAMATION OF CONTAMINATED SOIL
- B09B—DISPOSAL OF SOLID WASTE NOT OTHERWISE PROVIDED FOR
- B09B5/00—Operations not covered by a single other subclass or by a single other group in this subclass
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B09—DISPOSAL OF SOLID WASTE; RECLAMATION OF CONTAMINATED SOIL
- B09B—DISPOSAL OF SOLID WASTE NOT OTHERWISE PROVIDED FOR
- B09B3/00—Destroying solid waste or transforming solid waste into something useful or harmless
- B09B3/40—Destroying solid waste or transforming solid waste into something useful or harmless involving thermal treatment, e.g. evaporation
Definitions
- This invention is about a method of recycling tar in cigarette butts containing thousands of different toxic substances harmful to living creatures and nature, by mixing with ethanol, which is used as fuel.
- Tobacco is known to be used in a variety of ways for pleasure. Tobacco is consumed directly without any filtering process, however, it can be consumed in a filtered manner especially with cigarettes. Smoking is characterized as a visually contagious epidemic.
- the main chemical materials in cigarettes are polonium-210 (carcinogen), radon (radiation), methanol (missile fuel), toluene (thinner), cadmium (battery metal), butane (tube gas), ddt (insecticide), hydrogen cyanide (gas) chamber poison), acetone (nail polish remover), naphthalene (moth repellent), hydrogen cyanide (gas chamber poison), arsenic (mouse poison), ammonia (toilet cleaner), carbon monoxide (exhaust gas), tar (pitch) nicotine and 3,884 toxic substance.lt gives a serious damage to nature, living creatures and especially, human health.
- the cigarette butt from which cigarette smoke is filtered consists of cellulose acetate. During smoking, the gases emitted from tobacco passes through this filter into the mouth and the butts containing toxic gas are thrown into the nature.There had bee various studies and projects have been carried out in order to collect, recycle and reduce the harm to nature of cigarette butts all over the world.
- a group of researchers led by Abbas Mohajerani at the Royal Melbourne Institute of Technology in Australia ensured that butts were isolated using bitumen and paraffin wax to prevent toxic substances from leaking into the environment
- the isolated butts were mixed with hot asphalt mixture to obtain a concretey, dense and durable structure with low thermal conductivity. This compound was used on roads. In Brazil, under the leadership of Mark Poiato, a group of researchers produced paper from the sponge of butts. They separated the tar in the butts with the process by washing to reveal cellulose, which is the raw material of the paper.
- Chinese patent application CN108807014 discloses a method of preparing a supercapacitor electrode material using disposed cigarette butts. This method comprises the steps of chopping the disposed cigarette butts, dipping the chopped cigarette butts into water, transferring the chopped cigarette butts to the high pressure reaction vessel for pre carbonization, and then centrifuging, washing and drying.
- the supercapacitor electrode material prepared using disposed cigarette butts has a porous structure, an oxygen-rich functional group, and an ultra high specific surface area and a high nitrogen dose, so high capacitance, good speed performance and ultra high cycle stability when the material is used as the supercapacitor electrode material it provides.
- One of the advantages of the method according to the invention is that the average annual consumption of 6 trillion cigarettes consumed in the world causes harm to the atmosphere, as well as the non-biodegradable cellulose acetate-based and harmful heavy metal- containing cigarette butts, which emit into the sea, ocean, soil and groundwater after smoking which will reduce the damage.
- Another advantage of the method according to the invention is that 17 thousand people and countless living creatures will be prevented from fires caused by cigarettes every year.
- cigarette-induced fires are known to cause financial losses of more than $ 27 billion per year, which will be reduced as the method is intended to collect cigarette butts.
- Another advantage of the method according to the invention is the use of tar, turpentine, cellulosic acetate, propylene, acetophenone, ammonia, butane in cigarette butts in ethanol (ethyl alcohol) used as a fuel alone or as an additive mixed with gasoline in automobiles and other motor vehicles.
- ethanol ethyl alcohol
- Figure-1 It shows a flowchart of an alternative embodiment of the recycling method of cigarette butts of the invention..
- Figure-2 It shows a flowchart of another alternative embodiment of the recycling method of cigarette butts of the invention.
- cigarette butts are collected at the first stage and taken to the environment at 0-60°C temperature and put into water.A mixture of cigarette butts and water is mixed with mechanical or magnetic stirrers. After mixing, the mixture is filtered by means of a strainer or filters and boiled It is also possible to proceed directly to the boiling step of the mixture without filtration. Preferably, the filtered mixture is allowed to stand at 50-1 10 ° C for 1 -24 hoursAfter boiling, the mixture of cigarette tar and water is mixed with ethanol. In the other process , the collected cigarette butts are taken to a temperature of 0-60° C and placed in ethanol and mixed.. The mixture must be rest to settle the precipitates. The mixture is left to wait for 15 minutes and then it becomes ready for use after filtration.
- a process in the recycling method of cigarette butts of the present invention is essentially comprised of;
- Cigarette butts are collected at this stage The collection can be made by collecting cigarettes thrown into the environment or by creating smoking collection areas.
- Putting cigarette butts into water (110) At this stage, the collected cigarette butts are placed in an environment with a temperature between 0-60°C and the amount of cigarette butts between 5 grams and 320 grams is put into 1 liter of water.
- Filtering the mixture (130) At this stage, the mixture of water and butts is filtered by filters and the water is purified from butts. Filtration can be carried out without applying pressure with the filter or by applying pressure from the micro filters.
- Boiling the mixture (140) At this stage, tar water, separated from cigarette butts, is kept at 50-1 10°C for 1 -24 hours and this makes the water evaporated. The aim is to reduce the water content in the mixture and increase its densityAt this stage, the tar water heater can be heated or kept in a closed chamber or environment with a temperature of 50-1 10°C.
- Cigarette butts are collected at this stage The collection can be made by collecting cigarettes thrown into the environment or by creating smoking collection areas.
- Putting cigarette butts into ethanol (210) At this stage, the collected cigarette butts are prepared in an environment with a temperature between 0-60°C and a butt-ethanol mixture with a density of 5-320 g / L is prepared.
- Filtering the mixture (240) At this stage, the mixture of water and butts is filtered by filters and the water is purified from butts. Filtration can be carried out without applying pressure with the filter or by applying pressure from the micro filters.
- the fuel obtained by the method according to the invention can be used primarily as an alternative fuel in automobiles and other motor vehicles, as well as for use in machines in the industrial sector.
Landscapes
- Engineering & Computer Science (AREA)
- Environmental & Geological Engineering (AREA)
- Physics & Mathematics (AREA)
- Thermal Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Toxicology (AREA)
- Processing Of Solid Wastes (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
Description
Claims
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
TR2019/07070A TR201907070A2 (en) | 2019-05-10 | 2019-05-10 | RECYCLING METHOD OF SMOKING ISMARITES |
PCT/TR2020/050057 WO2020231362A1 (en) | 2019-05-10 | 2020-01-29 | Recycling method of cigarette butts |
Publications (2)
Publication Number | Publication Date |
---|---|
EP3966278A1 true EP3966278A1 (en) | 2022-03-16 |
EP3966278A4 EP3966278A4 (en) | 2022-06-22 |
Family
ID=67952198
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP20806289.3A Pending EP3966278A4 (en) | 2019-05-10 | 2020-01-29 | Recycling method of cigarette butts |
Country Status (3)
Country | Link |
---|---|
EP (1) | EP3966278A4 (en) |
TR (1) | TR201907070A2 (en) |
WO (1) | WO2020231362A1 (en) |
Family Cites Families (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US7560059B2 (en) * | 2005-09-19 | 2009-07-14 | Blake Burich | Process and method for recycling cigarette butts |
KR20160005298A (en) * | 2014-07-06 | 2016-01-14 | 박종호 | Withdrawal method of efficiency element in a cigarette butt |
CN106928486B (en) * | 2017-03-27 | 2020-08-21 | 浙大宁波理工学院 | Method for recovering acetate fibers from cigarette end filter tip |
CN107946082A (en) * | 2017-10-27 | 2018-04-20 | 西安理工大学 | A kind of preparation method and its usage of cigarette filter/graphene composite material |
-
2019
- 2019-05-10 TR TR2019/07070A patent/TR201907070A2/en unknown
-
2020
- 2020-01-29 EP EP20806289.3A patent/EP3966278A4/en active Pending
- 2020-01-29 WO PCT/TR2020/050057 patent/WO2020231362A1/en unknown
Also Published As
Publication number | Publication date |
---|---|
WO2020231362A1 (en) | 2020-11-19 |
EP3966278A4 (en) | 2022-06-22 |
TR201907070A2 (en) | 2019-06-21 |
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Legal Events
Date | Code | Title | Description |
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STAA | Information on the status of an ep patent application or granted ep patent |
Free format text: STATUS: THE INTERNATIONAL PUBLICATION HAS BEEN MADE |
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PUAI | Public reference made under article 153(3) epc to a published international application that has entered the european phase |
Free format text: ORIGINAL CODE: 0009012 |
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STAA | Information on the status of an ep patent application or granted ep patent |
Free format text: STATUS: REQUEST FOR EXAMINATION WAS MADE |
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17P | Request for examination filed |
Effective date: 20211208 |
|
AK | Designated contracting states |
Kind code of ref document: A1 Designated state(s): AL AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HR HU IE IS IT LI LT LU LV MC MK MT NL NO PL PT RO RS SE SI SK SM TR |
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A4 | Supplementary search report drawn up and despatched |
Effective date: 20220523 |
|
RIC1 | Information provided on ipc code assigned before grant |
Ipc: C08J 11/00 20060101AFI20220517BHEP |