EP3930061A1 - Système d'électricité de production d'hydrogène pour produire de l'électricité à partir d'hydrogène à l'aide d'une substance de support d'hydrogène et procédé de fonctionnement du système d'électricité de production d'hydrogène - Google Patents

Système d'électricité de production d'hydrogène pour produire de l'électricité à partir d'hydrogène à l'aide d'une substance de support d'hydrogène et procédé de fonctionnement du système d'électricité de production d'hydrogène Download PDF

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Publication number
EP3930061A1
EP3930061A1 EP20181731.9A EP20181731A EP3930061A1 EP 3930061 A1 EP3930061 A1 EP 3930061A1 EP 20181731 A EP20181731 A EP 20181731A EP 3930061 A1 EP3930061 A1 EP 3930061A1
Authority
EP
European Patent Office
Prior art keywords
reaction chamber
hydrogen
gas stream
water
carrier substance
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
EP20181731.9A
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German (de)
English (en)
Inventor
Martinus Arnoldus Petrus Maria SWINKELS
Max Johannes Robertus Aerts
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Dens BV
Original Assignee
Dens BV
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Dens BV filed Critical Dens BV
Priority to EP20181731.9A priority Critical patent/EP3930061A1/fr
Priority to EP21732349.2A priority patent/EP4169100A1/fr
Priority to CN202180049775.6A priority patent/CN115769405A/zh
Priority to CA3183574A priority patent/CA3183574A1/fr
Priority to PCT/EP2021/067024 priority patent/WO2021259941A1/fr
Priority to KR1020237002388A priority patent/KR20230029834A/ko
Priority to US18/012,429 priority patent/US20230268532A1/en
Priority to JP2022580117A priority patent/JP2023531068A/ja
Publication of EP3930061A1 publication Critical patent/EP3930061A1/fr
Withdrawn legal-status Critical Current

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    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/04—Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids
    • H01M8/04298—Processes for controlling fuel cells or fuel cell systems
    • H01M8/04694—Processes for controlling fuel cells or fuel cell systems characterised by variables to be controlled
    • H01M8/04828—Humidity; Water content
    • H01M8/04835—Humidity; Water content of fuel cell reactants
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/04—Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids
    • H01M8/04082—Arrangements for control of reactant parameters, e.g. pressure or concentration
    • H01M8/04089—Arrangements for control of reactant parameters, e.g. pressure or concentration of gaseous reactants
    • H01M8/04119—Arrangements for control of reactant parameters, e.g. pressure or concentration of gaseous reactants with simultaneous supply or evacuation of electrolyte; Humidifying or dehumidifying
    • H01M8/04126—Humidifying
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/04—Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids
    • H01M8/04298—Processes for controlling fuel cells or fuel cell systems
    • H01M8/04313—Processes for controlling fuel cells or fuel cell systems characterised by the detection or assessment of variables; characterised by the detection or assessment of failure or abnormal function
    • H01M8/0432—Temperature; Ambient temperature
    • H01M8/04373—Temperature; Ambient temperature of auxiliary devices, e.g. reformers, compressors, burners
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/04—Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids
    • H01M8/04298—Processes for controlling fuel cells or fuel cell systems
    • H01M8/04313—Processes for controlling fuel cells or fuel cell systems characterised by the detection or assessment of variables; characterised by the detection or assessment of failure or abnormal function
    • H01M8/0438—Pressure; Ambient pressure; Flow
    • H01M8/04425—Pressure; Ambient pressure; Flow at auxiliary devices, e.g. reformers, compressors, burners
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/04—Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids
    • H01M8/04298—Processes for controlling fuel cells or fuel cell systems
    • H01M8/04313—Processes for controlling fuel cells or fuel cell systems characterised by the detection or assessment of variables; characterised by the detection or assessment of failure or abnormal function
    • H01M8/04492—Humidity; Ambient humidity; Water content
    • H01M8/045—Humidity; Ambient humidity; Water content of anode reactants at the inlet or inside the fuel cell
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/04—Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids
    • H01M8/04298—Processes for controlling fuel cells or fuel cell systems
    • H01M8/04694—Processes for controlling fuel cells or fuel cell systems characterised by variables to be controlled
    • H01M8/04701—Temperature
    • H01M8/04738—Temperature of auxiliary devices, e.g. reformer, compressor, burner
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/04—Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids
    • H01M8/04298—Processes for controlling fuel cells or fuel cell systems
    • H01M8/04694—Processes for controlling fuel cells or fuel cell systems characterised by variables to be controlled
    • H01M8/04746—Pressure; Flow
    • H01M8/04776—Pressure; Flow at auxiliary devices, e.g. reformer, compressor, burner
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/06—Combination of fuel cells with means for production of reactants or for treatment of residues
    • H01M8/0606—Combination of fuel cells with means for production of reactants or for treatment of residues with means for production of gaseous reactants
    • H01M8/0612—Combination of fuel cells with means for production of reactants or for treatment of residues with means for production of gaseous reactants from carbon-containing material
    • H01M8/0618—Reforming processes, e.g. autothermal, partial oxidation or steam reforming
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/06—Combination of fuel cells with means for production of reactants or for treatment of residues
    • H01M8/0606—Combination of fuel cells with means for production of reactants or for treatment of residues with means for production of gaseous reactants
    • H01M8/0612—Combination of fuel cells with means for production of reactants or for treatment of residues with means for production of gaseous reactants from carbon-containing material
    • H01M8/0625—Combination of fuel cells with means for production of reactants or for treatment of residues with means for production of gaseous reactants from carbon-containing material in a modular combined reactor/fuel cell structure
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/06—Combination of fuel cells with means for production of reactants or for treatment of residues
    • H01M8/0606—Combination of fuel cells with means for production of reactants or for treatment of residues with means for production of gaseous reactants
    • H01M8/0612—Combination of fuel cells with means for production of reactants or for treatment of residues with means for production of gaseous reactants from carbon-containing material
    • H01M8/0625—Combination of fuel cells with means for production of reactants or for treatment of residues with means for production of gaseous reactants from carbon-containing material in a modular combined reactor/fuel cell structure
    • H01M8/0631—Reactor construction specially adapted for combination reactor/fuel cell
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30—Hydrogen technology
    • Y02E60/50—Fuel cells

Definitions

  • the water providing means comprises at least one of:
  • said catalyst comprises a complex of the formula: M(L) n (I) in which,
  • the pressure valve arrangement 31 is arranged for controlling the internal pressure of the reaction chamber 5 by controllingly allowing the hydrogen gas stream originating from the reaction chamber 5 to pass the pressure valve arrangement 31.
  • the lower side wall 27 comprises a mixture outflow opening 11 that is provided in a centre part of a bottom side of the reactor vessel 3.
  • a surface level sensor is provided at the reaction chamber 5 and is arranged to measure the liquid surface level of the reaction mixture in the reaction chamber 5.
  • the humidity determining unit 45 determines the humidity level of the H 2 gas stream based on the measured surface level (height). The operation of the surface level sensor is further explained below in the examples section.
  • the method 101 further comprises a step 111 of controlling, in response to a signal of the humidity determining unit 45 provided to the control unit 41, at least one of an internal gas pressure of the reaction chamber and a reaction temperature of the reaction chamber in order to control the humidity level of the H 2 gas stream.
  • step 111 may comprise a step of controlling the internal gas pressure of the reaction chamber 111a and may comprise a step of controlling the reaction temperature of the reaction chamber 111b, or may comprise a combination of step 111a and step 111b.
  • the control unit 41 may decide which of the steps 111a, 111b is used in any combination. Specifically, the control unit 41 may select the steps 111a and 111b depending on other desired attributes of the H 2 gas stream, such as hydrogen production flow rate, and on attributes of the reaction chamber and reaction mixture, such as operating temperatures of the reaction chamber.
  • the mixture is introduced into the reaction chamber 5 in the predetermined direction having the tangential component T for stirring 39, in use, said mixture in said reaction chamber 5.
  • the mixture is introduced in a direction along the reactor wall 7, wherein said direction of introduction has the tangential component T.
  • the reaction mixture inside the reaction chamber 5 comprises a catalyst comprising a complex of the formula M(L)n (I) in which,

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  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Sustainable Development (AREA)
  • Sustainable Energy (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Fuel Cell (AREA)
  • Hydrogen, Water And Hydrids (AREA)
EP20181731.9A 2020-06-23 2020-06-23 Système d'électricité de production d'hydrogène pour produire de l'électricité à partir d'hydrogène à l'aide d'une substance de support d'hydrogène et procédé de fonctionnement du système d'électricité de production d'hydrogène Withdrawn EP3930061A1 (fr)

Priority Applications (8)

Application Number Priority Date Filing Date Title
EP20181731.9A EP3930061A1 (fr) 2020-06-23 2020-06-23 Système d'électricité de production d'hydrogène pour produire de l'électricité à partir d'hydrogène à l'aide d'une substance de support d'hydrogène et procédé de fonctionnement du système d'électricité de production d'hydrogène
EP21732349.2A EP4169100A1 (fr) 2020-06-23 2021-06-22 Système d'électricité par génération d'hydrogène destiné à produire de l'électricité à partir d'hydrogène à l'aide d'une substance de transport d'hydrogène et procédé de mise en fonctionnement du système d'électricité par génération d'hydrogène
CN202180049775.6A CN115769405A (zh) 2020-06-23 2021-06-22 用于使用氢载体物质从氢产生电的氢发电系统和用于操作氢发电系统的方法
CA3183574A CA3183574A1 (fr) 2020-06-23 2021-06-22 Systeme d'electricite par generation d'hydrogene destine a produire de l'electricite a partir d'hydrogene a l'aide d'une substance de transport d'hydrogene et procede de mise en fonctionnement du systeme d'electricite par generation d'hydrogene
PCT/EP2021/067024 WO2021259941A1 (fr) 2020-06-23 2021-06-22 Système d'électricité par génération d'hydrogène destiné à produire de l'électricité à partir d'hydrogène à l'aide d'une substance de transport d'hydrogène et procédé de mise en fonctionnement du système d'électricité par génération d'hydrogène
KR1020237002388A KR20230029834A (ko) 2020-06-23 2021-06-22 수소 운반체 물질을 사용하여 수소로부터 전기를 생산하기 위한 수소 발생 전기 시스템 및 수소 발생 전기 시스템의 작동 방법
US18/012,429 US20230268532A1 (en) 2020-06-23 2021-06-22 A Hydrogen Generation Electricity System for Producing Electricity from Hydrogen Using a Hydrogen Carrier Substance and a Method for Operating the Hydrogen Generation Electricity System
JP2022580117A JP2023531068A (ja) 2020-06-23 2021-06-22 水素担体物質を使用して水素から電力を製造する水素生成電力システム、及び水素生成電力システムの操作方法

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
EP20181731.9A EP3930061A1 (fr) 2020-06-23 2020-06-23 Système d'électricité de production d'hydrogène pour produire de l'électricité à partir d'hydrogène à l'aide d'une substance de support d'hydrogène et procédé de fonctionnement du système d'électricité de production d'hydrogène

Publications (1)

Publication Number Publication Date
EP3930061A1 true EP3930061A1 (fr) 2021-12-29

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Family Applications (2)

Application Number Title Priority Date Filing Date
EP20181731.9A Withdrawn EP3930061A1 (fr) 2020-06-23 2020-06-23 Système d'électricité de production d'hydrogène pour produire de l'électricité à partir d'hydrogène à l'aide d'une substance de support d'hydrogène et procédé de fonctionnement du système d'électricité de production d'hydrogène
EP21732349.2A Pending EP4169100A1 (fr) 2020-06-23 2021-06-22 Système d'électricité par génération d'hydrogène destiné à produire de l'électricité à partir d'hydrogène à l'aide d'une substance de transport d'hydrogène et procédé de mise en fonctionnement du système d'électricité par génération d'hydrogène

Family Applications After (1)

Application Number Title Priority Date Filing Date
EP21732349.2A Pending EP4169100A1 (fr) 2020-06-23 2021-06-22 Système d'électricité par génération d'hydrogène destiné à produire de l'électricité à partir d'hydrogène à l'aide d'une substance de transport d'hydrogène et procédé de mise en fonctionnement du système d'électricité par génération d'hydrogène

Country Status (7)

Country Link
US (1) US20230268532A1 (fr)
EP (2) EP3930061A1 (fr)
JP (1) JP2023531068A (fr)
KR (1) KR20230029834A (fr)
CN (1) CN115769405A (fr)
CA (1) CA3183574A1 (fr)
WO (1) WO2021259941A1 (fr)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2023232451A1 (fr) * 2022-05-31 2023-12-07 Robert Bosch Gmbh Stratégie de fonctionnement pour faire fonctionner un système de pile à combustible

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20030224230A1 (en) * 2002-05-31 2003-12-04 Ballard Generation Systems Utilization based power plant control system
US20100196776A1 (en) * 2009-02-05 2010-08-05 Samsung Sdi Co., Ltd. Auto ignition type autothermal reformer and fuel cell system having the same
US20100227232A1 (en) * 2005-08-02 2010-09-09 Tiancun Xiao Initiating a Reaction Between Hydrogen Peroxide and an Organic Compound
US20100273082A1 (en) * 2007-01-23 2010-10-28 Bloom Energy Corporation Structure and method for optimizing system efficiency when operating an SOFC system with alcohol fuels
US20110059378A1 (en) * 2009-09-10 2011-03-10 The University Of Hong Kong Catalyst for hydrogen generation from small organic molecules

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20030224230A1 (en) * 2002-05-31 2003-12-04 Ballard Generation Systems Utilization based power plant control system
US20100227232A1 (en) * 2005-08-02 2010-09-09 Tiancun Xiao Initiating a Reaction Between Hydrogen Peroxide and an Organic Compound
US20100273082A1 (en) * 2007-01-23 2010-10-28 Bloom Energy Corporation Structure and method for optimizing system efficiency when operating an SOFC system with alcohol fuels
US20100196776A1 (en) * 2009-02-05 2010-08-05 Samsung Sdi Co., Ltd. Auto ignition type autothermal reformer and fuel cell system having the same
US20110059378A1 (en) * 2009-09-10 2011-03-10 The University Of Hong Kong Catalyst for hydrogen generation from small organic molecules

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2023232451A1 (fr) * 2022-05-31 2023-12-07 Robert Bosch Gmbh Stratégie de fonctionnement pour faire fonctionner un système de pile à combustible

Also Published As

Publication number Publication date
JP2023531068A (ja) 2023-07-20
WO2021259941A1 (fr) 2021-12-30
CN115769405A (zh) 2023-03-07
EP4169100A1 (fr) 2023-04-26
KR20230029834A (ko) 2023-03-03
US20230268532A1 (en) 2023-08-24
CA3183574A1 (fr) 2021-12-30

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