EP3928996A1 - Markierung von gegenständen - Google Patents

Markierung von gegenständen Download PDF

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Publication number
EP3928996A1
EP3928996A1 EP20181353.2A EP20181353A EP3928996A1 EP 3928996 A1 EP3928996 A1 EP 3928996A1 EP 20181353 A EP20181353 A EP 20181353A EP 3928996 A1 EP3928996 A1 EP 3928996A1
Authority
EP
European Patent Office
Prior art keywords
colour
laser
forming
marking
article
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
EP20181353.2A
Other languages
English (en)
French (fr)
Inventor
Fabienne Goethals
Quentin VAN DEN HOVE D'ERTSENRYCK
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Agfa NV
Original Assignee
Agfa NV
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Agfa NV filed Critical Agfa NV
Priority to EP20181353.2A priority Critical patent/EP3928996A1/de
Publication of EP3928996A1 publication Critical patent/EP3928996A1/de
Withdrawn legal-status Critical Current

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Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
    • B41M1/00—Inking and printing with a printer's forme
    • B41M1/14—Multicolour printing
    • B41M1/18—Printing one ink over another
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
    • B41M5/00—Duplicating or marking methods; Sheet materials for use therein
    • B41M5/124—Duplicating or marking methods; Sheet materials for use therein using pressure to make a masked colour visible, e.g. to make a coloured support visible, to create an opaque or transparent pattern, or to form colour by uniting colour-forming components
    • B41M5/132—Chemical colour-forming components; Additives or binders therefor
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
    • B41M5/00—Duplicating or marking methods; Sheet materials for use therein
    • B41M5/124—Duplicating or marking methods; Sheet materials for use therein using pressure to make a masked colour visible, e.g. to make a coloured support visible, to create an opaque or transparent pattern, or to form colour by uniting colour-forming components
    • B41M5/132—Chemical colour-forming components; Additives or binders therefor
    • B41M5/136—Organic colour formers, e.g. leuco dyes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
    • B41M5/00—Duplicating or marking methods; Sheet materials for use therein
    • B41M5/26—Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used
    • B41M5/30—Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used using chemical colour formers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
    • B41M5/00—Duplicating or marking methods; Sheet materials for use therein
    • B41M5/26—Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used
    • B41M5/30—Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used using chemical colour formers
    • B41M5/323—Organic colour formers, e.g. leuco dyes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
    • B41M5/00—Duplicating or marking methods; Sheet materials for use therein
    • B41M5/26—Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used
    • B41M5/34—Multicolour thermography
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
    • B41M2205/00—Printing methods or features related to printing methods; Location or type of the layers
    • B41M2205/04—Direct thermal recording [DTR]
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
    • B41M2205/00—Printing methods or features related to printing methods; Location or type of the layers
    • B41M2205/42—Multiple imaging layers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
    • B41M3/00—Printing processes to produce particular kinds of printed work, e.g. patterns
    • B41M3/001—Printing processes to produce particular kinds of printed work, e.g. patterns using chemical colour-formers or chemical reactions, e.g. leuco dyes or acids
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
    • B41M3/00—Printing processes to produce particular kinds of printed work, e.g. patterns
    • B41M3/14—Security printing
    • B41M3/142—Security printing using chemical colour-formers or chemical reactions, e.g. leuco-dye/acid, photochromes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
    • B41M5/00—Duplicating or marking methods; Sheet materials for use therein
    • B41M5/124—Duplicating or marking methods; Sheet materials for use therein using pressure to make a masked colour visible, e.g. to make a coloured support visible, to create an opaque or transparent pattern, or to form colour by uniting colour-forming components
    • B41M5/165—Duplicating or marking methods; Sheet materials for use therein using pressure to make a masked colour visible, e.g. to make a coloured support visible, to create an opaque or transparent pattern, or to form colour by uniting colour-forming components characterised by the use of microcapsules; Special solvents for incorporating the ingredients

Definitions

  • a substituted or unsubstituted aralkyl group is preferably a phenyl or naphthyl group including one, two, three or more C 1 to C 6 -alkyl groups.
  • substituted in e.g. substituted alkyl group means that the alkyl group may be substituted by other atoms than the atoms normally present in such a group, i.e. carbon and hydrogen.
  • a substituted alkyl group may include a halogen atom or a thiol group.
  • An unsubstituted alkyl group contains only carbon and hydrogen atoms
  • compositions may also be provided onto a support by any printing method such as intaglio printing, screen printing, flexographic printing, offset printing, inkjet printing, valve jet printing, rotogravure printing, etc.
  • a printing method is preferred when only a part or several parts of a support has to be provided with the colour-forming layers.
  • a preferred aqueous based composition includes encapsulated leuco dyes.
  • leuco dyes are disclosed in for example EP-A 3297837 , EP-A 3470134 and EP-A 3470135 , all from Agfa Gevaert NV.
  • IR pigment is carbon black, such as acetylene black, channel black, furnace black, lamp black, and thermal black.
  • acid scavengers may improve the storage stability of the laser markable article.
  • UV-absorbers examples include 2-hydroxyphenyl-benzophenones (BP) such as Chimassorb TM 81 and Chimassorb TM 90 from BASF; 2-(2-hydroxyphenyl)-benzotriazoles (BTZ) such as Tinuvin TM 109, Tinuvin TM 1130, Tinuvin TM 171, Tinuvin TM 326, Tinuvin TM 328, Tinuvin TM 384-2, Tinuvin TM 99-2, Tinuvin TM 900, Tinuvin TM 928, Tinuvin TM Carboprotect TM Tinuvin TM 360, Tinuvin TM 1130, Tinuvin TM 327, Tinuvin TM 350, Tinuvin TM 234 from BASF, Mixxim TM BB/100 from FAIRMOUNT, Chiguard 5530 from Chitec; 2-hydroxy-phenyl-s-triazines (HPT) such as Tinuvin TM 460, Tinuvin TM 400, Tinuvin TM 405, Tinuvin
  • a preferred co-initiator is selected from the group consisting of an aliphatic amine, an aromatic amine and a thiol. Tertiary amines, heterocyclic thiols and 4-dialkylamino-benzoic acid are particularly preferred as co-initiator.
  • An interlayer maybe provided between the colour-forming layers.
  • the interlayer preferably contains an acid scavenger as described above to prevent diffusion of an acid from one laser markable layer to another.
  • compositions may be applied on any type of support, for example a metallic support, a glass support, a polymeric support, or a paper support.
  • the compositions may also be applied on a textile surface.
  • paper there is no real limitation on the type of paper and it includes newsprint paper, magazine paper, office paper, or wallpaper but also paper of higher grammage, usually referred to as paper boards, such as white lined chipboard, corrugated (fiber) board and packaging board.
  • paper boards such as white lined chipboard, corrugated (fiber) board and packaging board.
  • BOPET foils and supports are well-known in the art of preparing suitable supports for silver halide photographic films.
  • GB 811066 (ICI) teaches a process to produce biaxially oriented polyethylene terephthalate foils and supports.
  • Marking is preferably carried out in-line in the packaging process.
  • An advantage of laser or thermal printing marking is the possibility to add data at a very late stage of the packaging process.
  • the transparent support may include UV absorbers to act as a UV blocking layer.
  • a UV blocking layer may also be provided on either side of the support.
  • any laser may be used.
  • the laser is preferably an infrared (IR) laser.
  • Raster and vector are different graphic file types which require different modes of laser processing.
  • the main difference between vector and raster graphics is that raster graphics are composed of pixels, while vector graphics are composed of paths or lines.
  • Heat may be applied to the heat-sensitive article by means of a so-called thermal print heads.
  • the number of heating elements of a print head determines the print resolution. Typical values are 200 to 300 heating elements (dots) per inch (dpi). However, thermal printers with a resolution of 400 and 600 dpi are also available.
  • IR1064 is an infrared absorbing dye with the following structure, IR1064 can be prepared according to the synthetic methods reported in EP-A 2463109 (Agfa), paragraphs [0150] to [0159].
  • Ethyl Maleate is commercially available from TCI Europe.
  • Inimix is a 1/1/1/ mixture of Genocure DMHA, Genocure CPK and Genocure TPO.
  • Desmolux XP 2587 is an aliphatic urethane acrylate commercially available from Allnex.
  • a coating composition SUB-1 was prepared by mixing the components according to Table 1 using a dissolver. Table 1 wt% of components SUB-1 deionized water 76.66 CCE 18.45 Resorcinol 0.98 PAR-sol 0.57 PEA-sol 0.68 DOW-sol 1.33 Surfynsol 1.33

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Physics & Mathematics (AREA)
  • Optics & Photonics (AREA)
  • Heat Sensitive Colour Forming Recording (AREA)
  • Thermal Transfer Or Thermal Recording In General (AREA)
EP20181353.2A 2020-06-22 2020-06-22 Markierung von gegenständen Withdrawn EP3928996A1 (de)

Priority Applications (1)

Application Number Priority Date Filing Date Title
EP20181353.2A EP3928996A1 (de) 2020-06-22 2020-06-22 Markierung von gegenständen

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
EP20181353.2A EP3928996A1 (de) 2020-06-22 2020-06-22 Markierung von gegenständen

Publications (1)

Publication Number Publication Date
EP3928996A1 true EP3928996A1 (de) 2021-12-29

Family

ID=71120063

Family Applications (1)

Application Number Title Priority Date Filing Date
EP20181353.2A Withdrawn EP3928996A1 (de) 2020-06-22 2020-06-22 Markierung von gegenständen

Country Status (1)

Country Link
EP (1) EP3928996A1 (de)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE102023101175A1 (de) 2023-01-18 2024-07-18 Bundesdruckerei Gmbh Polymerschichtverbund für Sicherheits- und Wertdokumente, Herstellungsverfahren, Zubereitung und Verwendung

Citations (29)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US850287A (en) 1906-04-18 1907-04-16 Charles Bennett Combined fire and burglar alarm.
GB811066A (en) 1956-05-18 1959-03-25 Ici Ltd Biaxially oriented films
GB1401639A (en) * 1971-07-13 1975-07-16 Canon Kk Heat sensitive material comprising at least two colour forming compositions
WO2005068207A1 (en) 2004-01-14 2005-07-28 Datalase Ltd. Laser imaging
WO2007141522A1 (en) 2006-06-08 2007-12-13 Datalase Ltd. Laser marking
EP1911814A1 (de) 2006-10-11 2008-04-16 Agfa Graphics N.V. Härtbare Tintenstrahldrucktintensets und Verfahren zu ihrer Herstellung
WO2008099330A2 (en) 2007-02-15 2008-08-21 Kba-Giori S.A. Method and apparatus for forming an ink pattern exhibiting a two-dimensional ink gradient
WO2009059900A2 (en) 2007-11-05 2009-05-14 Basf Se Tungsten oxides used to increase the heat-input amount of near infrared radiation
WO2010056711A2 (en) 2008-11-14 2010-05-20 Cummins Filtration Ip Inc. Filter cartridge centering device
WO2012044400A1 (en) 2010-08-10 2012-04-05 Vardex Laser Solutions, Llc System for laser-based digital marking of objects with images or digital image projection with the laser beam shaped and amplified to have uniform irradiance distribution over the beam cross-section
EP2463109A1 (de) 2010-12-07 2012-06-13 Agfa-Gevaert Farblasermarkierungsverfahren für Sicherheitsdokumente
EP2648920A1 (de) 2010-12-07 2013-10-16 Agfa-Gevaert Farblasermarkierung von artikeln und vorläufern von sicherheitsdokumenten
EP2719540A1 (de) * 2012-10-11 2014-04-16 Agfa-Gevaert Farblasermarkierung
EP2722367A1 (de) 2012-10-11 2014-04-23 Agfa-Gevaert Infrarotfarbstoffe für die Lasermarkierung
WO2015015200A1 (en) 2013-07-30 2015-02-05 Datalase Ltd. Ink for laser imaging
WO2015091688A1 (en) 2013-12-19 2015-06-25 Agfa-Gevaert Laser markable laminates and documents
WO2015165854A1 (en) 2014-04-30 2015-11-05 Agfa-Gevaert Ir dyes and laser markable articles comprising such ir dyes
EP3297837A1 (de) 2015-05-19 2018-03-28 Agfa-Gevaert Lasermarkierbare zusammensetzungen, artikel und dokumente
US20180141364A1 (en) * 2015-05-19 2018-05-24 Agfa-Gevaert Laser markable compositions, materials and documents
WO2019010163A1 (en) 2017-07-06 2019-01-10 Ecolab USA, Inc. IMPROVED INJECTION OF MERCURY OXIDANTS
WO2019007833A1 (en) 2017-07-03 2019-01-10 Agfa Nv COMPOSITIONS THAT CAN BE MARKED USING NEAR INFRARED LASER (NIR)
EP3431304A1 (de) 2017-07-18 2019-01-23 Agfa-Gevaert Verfahren zur bereitstellung eines ovd auf einem sicherheitsdokument durch lasermarkierung
EP3470135A1 (de) 2017-10-13 2019-04-17 Agfa Nv Zusammensetzung mit lösungsmittel und hitzebeständigen kapseln
EP3470134A1 (de) 2017-10-13 2019-04-17 Agfa Nv Zusammensetzung mit lösungsmittel und hitzebeständigen kapseln
WO2019101683A1 (en) 2017-11-27 2019-05-31 Kba-Notasys Sa Printed security element comprising a rainbow feature and method of producing the same
US20200016904A1 (en) 2018-07-13 2020-01-16 Canon Kabushiki Kaisha Printing apparatus, printing method, and storage medium
WO2020020901A1 (en) 2018-07-27 2020-01-30 Datalase Ltd A method of forming a stable non-coloured or coloured state of a diacetylene compound
EP3626471A1 (de) 2018-09-24 2020-03-25 Agfa Nv Lasermarkierbare zusammensetzungen
EP3626472A1 (de) 2018-09-24 2020-03-25 Agfa Nv Lasermarkierbare zusammensetzungen

Patent Citations (30)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US850287A (en) 1906-04-18 1907-04-16 Charles Bennett Combined fire and burglar alarm.
GB811066A (en) 1956-05-18 1959-03-25 Ici Ltd Biaxially oriented films
GB1401639A (en) * 1971-07-13 1975-07-16 Canon Kk Heat sensitive material comprising at least two colour forming compositions
WO2005068207A1 (en) 2004-01-14 2005-07-28 Datalase Ltd. Laser imaging
WO2007141522A1 (en) 2006-06-08 2007-12-13 Datalase Ltd. Laser marking
EP1911814A1 (de) 2006-10-11 2008-04-16 Agfa Graphics N.V. Härtbare Tintenstrahldrucktintensets und Verfahren zu ihrer Herstellung
WO2008099330A2 (en) 2007-02-15 2008-08-21 Kba-Giori S.A. Method and apparatus for forming an ink pattern exhibiting a two-dimensional ink gradient
WO2009059900A2 (en) 2007-11-05 2009-05-14 Basf Se Tungsten oxides used to increase the heat-input amount of near infrared radiation
WO2010056711A2 (en) 2008-11-14 2010-05-20 Cummins Filtration Ip Inc. Filter cartridge centering device
WO2012044400A1 (en) 2010-08-10 2012-04-05 Vardex Laser Solutions, Llc System for laser-based digital marking of objects with images or digital image projection with the laser beam shaped and amplified to have uniform irradiance distribution over the beam cross-section
EP2463109A1 (de) 2010-12-07 2012-06-13 Agfa-Gevaert Farblasermarkierungsverfahren für Sicherheitsdokumente
EP2648920A1 (de) 2010-12-07 2013-10-16 Agfa-Gevaert Farblasermarkierung von artikeln und vorläufern von sicherheitsdokumenten
EP2719540A1 (de) * 2012-10-11 2014-04-16 Agfa-Gevaert Farblasermarkierung
EP2722367A1 (de) 2012-10-11 2014-04-23 Agfa-Gevaert Infrarotfarbstoffe für die Lasermarkierung
WO2015015200A1 (en) 2013-07-30 2015-02-05 Datalase Ltd. Ink for laser imaging
WO2015091688A1 (en) 2013-12-19 2015-06-25 Agfa-Gevaert Laser markable laminates and documents
EP3083261A1 (de) 2013-12-19 2016-10-26 Agfa-Gevaert Lasermarkierbare laminate und dokumente
WO2015165854A1 (en) 2014-04-30 2015-11-05 Agfa-Gevaert Ir dyes and laser markable articles comprising such ir dyes
EP3297837A1 (de) 2015-05-19 2018-03-28 Agfa-Gevaert Lasermarkierbare zusammensetzungen, artikel und dokumente
US20180141364A1 (en) * 2015-05-19 2018-05-24 Agfa-Gevaert Laser markable compositions, materials and documents
WO2019007833A1 (en) 2017-07-03 2019-01-10 Agfa Nv COMPOSITIONS THAT CAN BE MARKED USING NEAR INFRARED LASER (NIR)
WO2019010163A1 (en) 2017-07-06 2019-01-10 Ecolab USA, Inc. IMPROVED INJECTION OF MERCURY OXIDANTS
EP3431304A1 (de) 2017-07-18 2019-01-23 Agfa-Gevaert Verfahren zur bereitstellung eines ovd auf einem sicherheitsdokument durch lasermarkierung
EP3470135A1 (de) 2017-10-13 2019-04-17 Agfa Nv Zusammensetzung mit lösungsmittel und hitzebeständigen kapseln
EP3470134A1 (de) 2017-10-13 2019-04-17 Agfa Nv Zusammensetzung mit lösungsmittel und hitzebeständigen kapseln
WO2019101683A1 (en) 2017-11-27 2019-05-31 Kba-Notasys Sa Printed security element comprising a rainbow feature and method of producing the same
US20200016904A1 (en) 2018-07-13 2020-01-16 Canon Kabushiki Kaisha Printing apparatus, printing method, and storage medium
WO2020020901A1 (en) 2018-07-27 2020-01-30 Datalase Ltd A method of forming a stable non-coloured or coloured state of a diacetylene compound
EP3626471A1 (de) 2018-09-24 2020-03-25 Agfa Nv Lasermarkierbare zusammensetzungen
EP3626472A1 (de) 2018-09-24 2020-03-25 Agfa Nv Lasermarkierbare zusammensetzungen

Non-Patent Citations (4)

* Cited by examiner, † Cited by third party
Title
"Industrial Photoinitiators, A Technical Guide", 2010, CRC PRESS
CHEMICAL ABSTRACTS, Columbus, Ohio, US; abstract no. 127553-58-6
CRIVELLO, J.V. ET AL.: "Photoinitiators for Free Radical Cationic & Anionic Photopolymerization", vol. III, 1998, JOHN WILEY AND SONS LTD, pages: 287 - 294
NEAR-INFRARED DYES FOR HIGH TECHNOLOGY APPLICATIONS, ISBN: 978-0-7923-5101-6

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE102023101175A1 (de) 2023-01-18 2024-07-18 Bundesdruckerei Gmbh Polymerschichtverbund für Sicherheits- und Wertdokumente, Herstellungsverfahren, Zubereitung und Verwendung
EP4403371A1 (de) 2023-01-18 2024-07-24 Bundesdruckerei GmbH Polymerschichtverbund für sicherheits- und wertdokumente, herstellungsverfahren, zubereitung und verwendung

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