EP3873618A1 - Wirkstoffzusammensetzung zur pflege und oberflächenmodifikation von humanhaaren - Google Patents
Wirkstoffzusammensetzung zur pflege und oberflächenmodifikation von humanhaarenInfo
- Publication number
- EP3873618A1 EP3873618A1 EP19797672.3A EP19797672A EP3873618A1 EP 3873618 A1 EP3873618 A1 EP 3873618A1 EP 19797672 A EP19797672 A EP 19797672A EP 3873618 A1 EP3873618 A1 EP 3873618A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- group
- keratinous material
- alkyl group
- organic silicon
- cosmetic agent
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 26
- 210000004209 hair Anatomy 0.000 title abstract description 25
- 239000004480 active ingredient Substances 0.000 title abstract description 4
- 230000004048 modification Effects 0.000 title abstract description 3
- 238000012986 modification Methods 0.000 title abstract description 3
- 150000003377 silicon compounds Chemical class 0.000 claims abstract description 97
- 239000000463 material Substances 0.000 claims abstract description 79
- 239000002537 cosmetic Substances 0.000 claims abstract description 51
- 239000003093 cationic surfactant Substances 0.000 claims abstract description 30
- 239000003795 chemical substances by application Substances 0.000 claims description 59
- -1 Propyltriethoxysilane - hexyltrimethoxysilane - hexyltriethoxysilane - octyltrimethoxysilane - octyltriethoxysilane Chemical compound 0.000 claims description 33
- 125000000217 alkyl group Chemical group 0.000 claims description 29
- 150000001875 compounds Chemical class 0.000 claims description 21
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 20
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 15
- 238000011282 treatment Methods 0.000 claims description 14
- 125000004169 (C1-C6) alkyl group Chemical group 0.000 claims description 12
- 229920006395 saturated elastomer Polymers 0.000 claims description 12
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 claims description 11
- 230000002209 hydrophobic effect Effects 0.000 claims description 9
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 claims description 9
- 150000001450 anions Chemical class 0.000 claims description 6
- 125000002091 cationic group Chemical group 0.000 claims description 6
- 125000000816 ethylene group Chemical group [H]C([H])([*:1])C([H])([H])[*:2] 0.000 claims description 6
- WYTZZXDRDKSJID-UHFFFAOYSA-N (3-aminopropyl)triethoxysilane Chemical compound CCO[Si](OCC)(OCC)CCCN WYTZZXDRDKSJID-UHFFFAOYSA-N 0.000 claims description 5
- SJECZPVISLOESU-UHFFFAOYSA-N 3-trimethoxysilylpropan-1-amine Chemical compound CO[Si](OC)(OC)CCCN SJECZPVISLOESU-UHFFFAOYSA-N 0.000 claims description 5
- 125000000882 C2-C6 alkenyl group Chemical group 0.000 claims description 5
- 150000002148 esters Chemical group 0.000 claims description 5
- 239000002736 nonionic surfactant Substances 0.000 claims description 5
- NBXZNTLFQLUFES-UHFFFAOYSA-N triethoxy(propyl)silane Chemical compound CCC[Si](OCC)(OCC)OCC NBXZNTLFQLUFES-UHFFFAOYSA-N 0.000 claims description 4
- HQYALQRYBUJWDH-UHFFFAOYSA-N trimethoxy(propyl)silane Chemical compound CCC[Si](OC)(OC)OC HQYALQRYBUJWDH-UHFFFAOYSA-N 0.000 claims description 4
- 150000001408 amides Chemical group 0.000 claims description 3
- 230000003766 combability Effects 0.000 claims description 3
- YGUFXEJWPRRAEK-UHFFFAOYSA-N dodecyl(triethoxy)silane Chemical compound CCCCCCCCCCCC[Si](OCC)(OCC)OCC YGUFXEJWPRRAEK-UHFFFAOYSA-N 0.000 claims description 3
- SBRXLTRZCJVAPH-UHFFFAOYSA-N ethyl(trimethoxy)silane Chemical compound CC[Si](OC)(OC)OC SBRXLTRZCJVAPH-UHFFFAOYSA-N 0.000 claims description 3
- 238000005562 fading Methods 0.000 claims description 3
- CZWLNMOIEMTDJY-UHFFFAOYSA-N hexyl(trimethoxy)silane Chemical compound CCCCCC[Si](OC)(OC)OC CZWLNMOIEMTDJY-UHFFFAOYSA-N 0.000 claims description 3
- BFXIKLCIZHOAAZ-UHFFFAOYSA-N methyltrimethoxysilane Chemical compound CO[Si](C)(OC)OC BFXIKLCIZHOAAZ-UHFFFAOYSA-N 0.000 claims description 3
- MSRJTTSHWYDFIU-UHFFFAOYSA-N octyltriethoxysilane Chemical compound CCCCCCCC[Si](OCC)(OCC)OCC MSRJTTSHWYDFIU-UHFFFAOYSA-N 0.000 claims description 3
- 239000004094 surface-active agent Substances 0.000 claims description 3
- DENFJSAFJTVPJR-UHFFFAOYSA-N triethoxy(ethyl)silane Chemical compound CCO[Si](CC)(OCC)OCC DENFJSAFJTVPJR-UHFFFAOYSA-N 0.000 claims description 3
- WUMSTCDLAYQDNO-UHFFFAOYSA-N triethoxy(hexyl)silane Chemical compound CCCCCC[Si](OCC)(OCC)OCC WUMSTCDLAYQDNO-UHFFFAOYSA-N 0.000 claims description 3
- CPUDPFPXCZDNGI-UHFFFAOYSA-N triethoxy(methyl)silane Chemical compound CCO[Si](C)(OCC)OCC CPUDPFPXCZDNGI-UHFFFAOYSA-N 0.000 claims description 3
- BHWUCEATHBXPOV-UHFFFAOYSA-N 2-triethoxysilylethanamine Chemical compound CCO[Si](CCN)(OCC)OCC BHWUCEATHBXPOV-UHFFFAOYSA-N 0.000 claims description 2
- QHQNYHZHLAAHRW-UHFFFAOYSA-N 2-trimethoxysilylethanamine Chemical compound CO[Si](OC)(OC)CCN QHQNYHZHLAAHRW-UHFFFAOYSA-N 0.000 claims description 2
- BSBSHXOZJNDDHM-UHFFFAOYSA-N CN(CC[Si](OC)(OC)OC)C.CN(CCC[Si](OCC)(OCC)OCC)C Chemical compound CN(CC[Si](OC)(OC)OC)C.CN(CCC[Si](OCC)(OCC)OCC)C BSBSHXOZJNDDHM-UHFFFAOYSA-N 0.000 claims description 2
- 125000003158 alcohol group Chemical group 0.000 claims description 2
- 125000005233 alkylalcohol group Chemical group 0.000 claims description 2
- SCPWMSBAGXEGPW-UHFFFAOYSA-N dodecyl(trimethoxy)silane Chemical compound CCCCCCCCCCCC[Si](OC)(OC)OC SCPWMSBAGXEGPW-UHFFFAOYSA-N 0.000 claims description 2
- 125000001033 ether group Chemical group 0.000 claims description 2
- 229930182478 glucoside Natural products 0.000 claims description 2
- ZDAYYKNOKXBFSB-UHFFFAOYSA-N n',n'-bis(3-triethoxysilylpropyl)ethane-1,2-diamine Chemical compound CCO[Si](OCC)(OCC)CCCN(CCN)CCC[Si](OCC)(OCC)OCC ZDAYYKNOKXBFSB-UHFFFAOYSA-N 0.000 claims description 2
- RMBYJMVHGICGMN-UHFFFAOYSA-N n',n'-bis(3-trimethoxysilylpropyl)ethane-1,2-diamine Chemical compound CO[Si](OC)(OC)CCCN(CCN)CCC[Si](OC)(OC)OC RMBYJMVHGICGMN-UHFFFAOYSA-N 0.000 claims description 2
- XTOSZDRAGWRSBP-UHFFFAOYSA-N n,n-dimethyl-2-triethoxysilylethanamine Chemical compound CCO[Si](OCC)(OCC)CCN(C)C XTOSZDRAGWRSBP-UHFFFAOYSA-N 0.000 claims description 2
- QIOYHIUHPGORLS-UHFFFAOYSA-N n,n-dimethyl-3-trimethoxysilylpropan-1-amine Chemical compound CO[Si](OC)(OC)CCCN(C)C QIOYHIUHPGORLS-UHFFFAOYSA-N 0.000 claims description 2
- SLYCYWCVSGPDFR-UHFFFAOYSA-N octadecyltrimethoxysilane Chemical compound CCCCCCCCCCCCCCCCCC[Si](OC)(OC)OC SLYCYWCVSGPDFR-UHFFFAOYSA-N 0.000 claims description 2
- 229960003493 octyltriethoxysilane Drugs 0.000 claims description 2
- FZMJEGJVKFTGMU-UHFFFAOYSA-N triethoxy(octadecyl)silane Chemical compound CCCCCCCCCCCCCCCCCC[Si](OCC)(OCC)OCC FZMJEGJVKFTGMU-UHFFFAOYSA-N 0.000 claims description 2
- NMEPHPOFYLLFTK-UHFFFAOYSA-N trimethoxy(octyl)silane Chemical compound CCCCCCCC[Si](OC)(OC)OC NMEPHPOFYLLFTK-UHFFFAOYSA-N 0.000 claims description 2
- 125000000468 ketone group Chemical group 0.000 claims 1
- WGYKZJWCGVVSQN-UHFFFAOYSA-N propylamine Chemical group CCCN WGYKZJWCGVVSQN-UHFFFAOYSA-N 0.000 claims 1
- QQQSFSZALRVCSZ-UHFFFAOYSA-N triethoxysilane Chemical compound CCO[SiH](OCC)OCC QQQSFSZALRVCSZ-UHFFFAOYSA-N 0.000 claims 1
- 102000011782 Keratins Human genes 0.000 abstract description 3
- 108010076876 Keratins Proteins 0.000 abstract description 3
- 229920001577 copolymer Polymers 0.000 description 82
- 239000001993 wax Substances 0.000 description 33
- 150000003254 radicals Chemical class 0.000 description 27
- 150000001252 acrylic acid derivatives Chemical class 0.000 description 16
- OSCJHTSDLYVCQC-UHFFFAOYSA-N 2-ethylhexyl 4-[[4-[4-(tert-butylcarbamoyl)anilino]-6-[4-(2-ethylhexoxycarbonyl)anilino]-1,3,5-triazin-2-yl]amino]benzoate Chemical compound C1=CC(C(=O)OCC(CC)CCCC)=CC=C1NC1=NC(NC=2C=CC(=CC=2)C(=O)NC(C)(C)C)=NC(NC=2C=CC(=CC=2)C(=O)OCC(CC)CCCC)=N1 OSCJHTSDLYVCQC-UHFFFAOYSA-N 0.000 description 15
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical group [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 14
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 12
- 150000004756 silanes Chemical class 0.000 description 11
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 11
- 239000000047 product Substances 0.000 description 10
- 230000000694 effects Effects 0.000 description 9
- MWUXSHHQAYIFBG-UHFFFAOYSA-N nitrogen oxide Inorganic materials O=[N] MWUXSHHQAYIFBG-UHFFFAOYSA-N 0.000 description 8
- 229920000036 polyvinylpyrrolidone Polymers 0.000 description 8
- 239000001267 polyvinylpyrrolidone Substances 0.000 description 8
- 235000013855 polyvinylpyrrolidone Nutrition 0.000 description 8
- 229920002432 poly(vinyl methyl ether) polymer Polymers 0.000 description 7
- 229910052710 silicon Inorganic materials 0.000 description 7
- WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical compound OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 description 6
- 235000013871 bee wax Nutrition 0.000 description 6
- 239000012166 beeswax Substances 0.000 description 6
- 239000007859 condensation product Substances 0.000 description 6
- 229920000642 polymer Polymers 0.000 description 6
- 229920001059 synthetic polymer Polymers 0.000 description 6
- 125000000022 2-aminoethyl group Chemical group [H]C([*])([H])C([H])([H])N([H])[H] 0.000 description 5
- 125000000954 2-hydroxyethyl group Chemical group [H]C([*])([H])C([H])([H])O[H] 0.000 description 5
- 229920006037 cross link polymer Polymers 0.000 description 5
- 150000003961 organosilicon compounds Chemical class 0.000 description 5
- 235000019271 petrolatum Nutrition 0.000 description 5
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 description 5
- 239000000126 substance Substances 0.000 description 5
- RWLDCNACDPTRMY-UHFFFAOYSA-N 3-triethoxysilyl-n-(3-triethoxysilylpropyl)propan-1-amine Chemical compound CCO[Si](OCC)(OCC)CCCNCCC[Si](OCC)(OCC)OCC RWLDCNACDPTRMY-UHFFFAOYSA-N 0.000 description 4
- ROSDSFDQCJNGOL-UHFFFAOYSA-N Dimethylamine Chemical compound CNC ROSDSFDQCJNGOL-UHFFFAOYSA-N 0.000 description 4
- 239000004264 Petrolatum Substances 0.000 description 4
- 239000002253 acid Substances 0.000 description 4
- 229920006322 acrylamide copolymer Polymers 0.000 description 4
- 239000000809 air pollutant Substances 0.000 description 4
- 231100001243 air pollutant Toxicity 0.000 description 4
- 230000007062 hydrolysis Effects 0.000 description 4
- 238000006460 hydrolysis reaction Methods 0.000 description 4
- 239000004615 ingredient Substances 0.000 description 4
- 238000002844 melting Methods 0.000 description 4
- 230000008018 melting Effects 0.000 description 4
- 125000001570 methylene group Chemical group [H]C([H])([*:1])[*:2] 0.000 description 4
- GLDOVTGHNKAZLK-UHFFFAOYSA-N octadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCO GLDOVTGHNKAZLK-UHFFFAOYSA-N 0.000 description 4
- 229940066842 petrolatum Drugs 0.000 description 4
- 239000010703 silicon Substances 0.000 description 4
- 229920002554 vinyl polymer Polymers 0.000 description 4
- ZKYCLDTVJCJYIB-UHFFFAOYSA-N 2-methylidenedecanamide Chemical compound CCCCCCCCC(=C)C(N)=O ZKYCLDTVJCJYIB-UHFFFAOYSA-N 0.000 description 3
- MXRGSJAOLKBZLU-UHFFFAOYSA-N 3-ethenylazepan-2-one Chemical compound C=CC1CCCCNC1=O MXRGSJAOLKBZLU-UHFFFAOYSA-N 0.000 description 3
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 3
- 229940048053 acrylate Drugs 0.000 description 3
- 235000011037 adipic acid Nutrition 0.000 description 3
- 239000001361 adipic acid Substances 0.000 description 3
- 125000002947 alkylene group Chemical group 0.000 description 3
- 125000004432 carbon atom Chemical group C* 0.000 description 3
- 239000004203 carnauba wax Substances 0.000 description 3
- 235000013869 carnauba wax Nutrition 0.000 description 3
- 238000004140 cleaning Methods 0.000 description 3
- 239000000470 constituent Substances 0.000 description 3
- 229940008099 dimethicone Drugs 0.000 description 3
- 239000004205 dimethyl polysiloxane Substances 0.000 description 3
- 235000013870 dimethyl polysiloxane Nutrition 0.000 description 3
- 230000037308 hair color Effects 0.000 description 3
- 239000004200 microcrystalline wax Substances 0.000 description 3
- 235000019808 microcrystalline wax Nutrition 0.000 description 3
- 229910052757 nitrogen Inorganic materials 0.000 description 3
- 229920001223 polyethylene glycol Polymers 0.000 description 3
- 239000011734 sodium Substances 0.000 description 3
- 229910052708 sodium Inorganic materials 0.000 description 3
- 238000005728 strengthening Methods 0.000 description 3
- 230000035882 stress Effects 0.000 description 3
- 125000000383 tetramethylene group Chemical group [H]C([H])([*:1])C([H])([H])C([H])([H])C([H])([H])[*:2] 0.000 description 3
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 3
- DSEKYWAQQVUQTP-XEWMWGOFSA-N (2r,4r,4as,6as,6as,6br,8ar,12ar,14as,14bs)-2-hydroxy-4,4a,6a,6b,8a,11,11,14a-octamethyl-2,4,5,6,6a,7,8,9,10,12,12a,13,14,14b-tetradecahydro-1h-picen-3-one Chemical compound C([C@H]1[C@]2(C)CC[C@@]34C)C(C)(C)CC[C@]1(C)CC[C@]2(C)[C@H]4CC[C@@]1(C)[C@H]3C[C@@H](O)C(=O)[C@@H]1C DSEKYWAQQVUQTP-XEWMWGOFSA-N 0.000 description 2
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 2
- 125000003903 2-propenyl group Chemical group [H]C([*])([H])C([H])=C([H])[H] 0.000 description 2
- MWZXHAXMAVEYGN-UHFFFAOYSA-N 3-triethoxysilyl-n,n-bis(3-triethoxysilylpropyl)propan-1-amine Chemical compound CCO[Si](OCC)(OCC)CCCN(CCC[Si](OCC)(OCC)OCC)CCC[Si](OCC)(OCC)OCC MWZXHAXMAVEYGN-UHFFFAOYSA-N 0.000 description 2
- TZZGHGKTHXIOMN-UHFFFAOYSA-N 3-trimethoxysilyl-n-(3-trimethoxysilylpropyl)propan-1-amine Chemical compound CO[Si](OC)(OC)CCCNCCC[Si](OC)(OC)OC TZZGHGKTHXIOMN-UHFFFAOYSA-N 0.000 description 2
- JTHZUSWLNCPZLX-UHFFFAOYSA-N 6-fluoro-3-methyl-2h-indazole Chemical compound FC1=CC=C2C(C)=NNC2=C1 JTHZUSWLNCPZLX-UHFFFAOYSA-N 0.000 description 2
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- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 2
- 244000180278 Copernicia prunifera Species 0.000 description 2
- 235000010919 Copernicia prunifera Nutrition 0.000 description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- 229920002153 Hydroxypropyl cellulose Polymers 0.000 description 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 2
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- 125000003545 alkoxy group Chemical group 0.000 description 2
- 125000003282 alkyl amino group Chemical group 0.000 description 2
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- 239000011591 potassium Substances 0.000 description 2
- 229910052700 potassium Inorganic materials 0.000 description 2
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 2
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- VJMFMHVKXVNPNA-UHFFFAOYSA-N (1-amino-3-hydroxypentan-3-yl) prop-2-enoate Chemical class NCCC(O)(CC)OC(=O)C=C VJMFMHVKXVNPNA-UHFFFAOYSA-N 0.000 description 1
- 125000004209 (C1-C8) alkyl group Chemical group 0.000 description 1
- DMBUODUULYCPAK-UHFFFAOYSA-N 1,3-bis(docosanoyloxy)propan-2-yl docosanoate Chemical compound CCCCCCCCCCCCCCCCCCCCCC(=O)OCC(OC(=O)CCCCCCCCCCCCCCCCCCCCC)COC(=O)CCCCCCCCCCCCCCCCCCCCC DMBUODUULYCPAK-UHFFFAOYSA-N 0.000 description 1
- RTBFRGCFXZNCOE-UHFFFAOYSA-N 1-methylsulfonylpiperidin-4-one Chemical compound CS(=O)(=O)N1CCC(=O)CC1 RTBFRGCFXZNCOE-UHFFFAOYSA-N 0.000 description 1
- 229940114069 12-hydroxystearate Drugs 0.000 description 1
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- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 1
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-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/002—Preparations for repairing the hair, e.g. hair cure
Definitions
- Active ingredient composition for the care and surface modification of human hair
- the present invention relates to cosmetic compositions for treating a keratinous material, the composition comprising an organic silicon compound and a cationic surfactant, and to the
- Air pollutants include polycyclic aromatic hydrocarbons, volatile organic ones
- Air pollutants can be amplified in the presence of other air pollutants and under the influence of UV radiation.
- Free radicals are metabolic products that also occur naturally in the body. In large quantities, free radicals can promote irritation and inflammation and accelerate the aging process. In this case one speaks of "oxidative damage”. Free radicals can also cause hair damage, for example as
- Particles are a complex mixture that contain metals, minerals, organic toxins and / or biological materials. They too can promote the formation of free radicals.
- organosilicon compounds from the group of the silanes which comprise at least one hydroxyl group and / or hydrolyzable group. Due to the
- the silanes are reactive substances which hydrolyze or oligomerize or polymerize in the presence of water.
- the oligomerization or polymerization of the silanes initiated by the presence of the water ultimately leads to the formation of a film when used on a keratinic material, which film can develop a protective effect.
- the object underlying the present invention is to provide a product with an improved care and / or protective effect.
- the object of the present invention was to provide a cosmetic agent which, when used, offers increased acceptance, particularly in terms of softness of the hair.
- a cosmetic agent for the treatment of a keratinous material comprising
- a keratinous material means hair, skin, nails (such as fingernails and / or toenails). Wool, furs and feathers also fall under the definition of keratinous material.
- a keratin material is preferably understood to mean human hair, human skin and human nails, in particular fingernails and toenails.
- Keratinous material is very particularly preferably understood to mean human hair, in particular scalp and / or whiskers.
- the cosmetic agent for treating a keratinous material contains at least one organic silicon compound as the first constituent essential to the invention.
- Preferred organic silicon compounds are selected from silanes with one, two or three silicon atoms, the organic silicon compound comprising one or more hydroxyl groups and / or hydrolyzable groups per molecule.
- Organic silicon compounds which are also referred to alternatively as organosilicon compounds, are compounds which either have a direct silicon-carbon bond (Si-C) or in which the carbon is attached to the silicon via an oxygen, nitrogen or sulfur atom. Atom is attached.
- the organic silicon compounds are compounds that contain one to three silicon atoms.
- the organic silicon compounds particularly preferably contain one or two
- silane stands for a group of substances that are based on a silicon framework and hydrogen.
- the hydrogen atoms are completely or partially replaced by organic groups, such as (substituted) alkyl groups and / or alkoxy groups. Some of the hydrogen atoms in the organic silanes can also be replaced by hydroxyl groups.
- the agent for treating a keratinous material contains at least one organic
- Silicon compound which is preferably selected from silanes with one, two or three silicon atoms, wherein the organic silicon compound comprises one or more hydroxyl groups or hydrolyzable groups per molecule.
- the agent for treating a keratinous material has at least one organic silicon compound selected from silanes with one, two or three silicon atoms, the organic silicon compound also having one or more basic groups and one or more hydroxyl groups or hydrolyzable groups per molecule.
- This basic group can be, for example, an amino group, an alkylamino group or a dialkylamino group, which is preferably connected to a silicon atom via a linker.
- the basic group is preferably an amino group, a C -C -alkylamino group or a di (Ci-Ce) alkylamino group.
- the hydrolyzable group or groups is preferably a Ci-Ce alkoxy group, in particular an ethoxy group or a methoxy group. It is preferred if the hydrolyzable group is attached directly to the silicon atom. If, for example, the hydrolyzable group is an ethoxy group, the organic silicon compound preferably contains a structural unit R'R "R"'Si-0-CH 2 -CH3. The radicals R ', R "and R"' represent the three remaining free valences of the silicon atom.
- the agent for treating a keratinous material contains at least one organic silicon compound of the formula (I) and / or (II).
- the compounds of formulas (I) and (II) are organic silicon compounds selected from silanes with one, two or three silicon atoms, the organic silicon compound comprising one or more hydroxyl groups and / or hydrolyzable groups per molecule.
- the agent for treating a keratinous material contains at least one organic silicon compound of the formula (I) and / or (II),
- Ri, R2 both represent a hydrogen atom
- L represents a linear, double-bonded Ci-C6-alkylene group, preferably a propylene group (-CH2-CH2-CH2-) or an ethylene group (-CH2-CH2-),
- R, R independently of one another represent a methyl group or an ethyl group, a represents the number 3 and b represents the number 0,
- R5, R5 ', R5 "independently of one another represent a hydrogen atom or a C -C - alkyl group
- R6, R6 'and R6 "independently of one another represent a Ci-Ce alkyl group
- A, A ‘, A”, A “’ and A ““ independently of one another represent a linear or branched, double-bonded Ci-C o-alkylene group
- R and Re independently of one another represent a hydrogen atom, a Ci-C6-alkyl group, a hydroxy-Ci-C6-alkyl group, a C -C -alkenyl group, an amino-Ci-C6-alkyl group or a grouping of the formula (III) stand
- Examples of a C 1 -C 6 -alkyl group are the groups methyl, ethyl, propyl, isopropyl, n-butyl, s-butyl and t-butyl, n-pentyl and n-hexyl. Propyl, ethyl and methyl are preferred alkyl radicals.
- Examples of a C -C alkenyl group are vinyl, allyl, but-2-enyl, but-3-enyl and isobutenyl, preferred C -C-alkenyl radicals are vinyl and allyl.
- a hydroxy-Ci-C6-alkyl group are a hydroxymethyl, a 2-hydroxyethyl, a 2-hydroxypropyl, a 3-hydroxypropyl, a 4-hydroxybutyl group, a 5-hydroxypentyl and a 6-hydroxyhexyl group; a 2-hydroxyethyl group is particularly preferred.
- Examples of an amino-Ci-C6-alkyl group are the aminomethyl group, the 2-aminoethyl group, the 3-aminopropyl group. The 2-aminoethyl group is particularly preferred.
- Examples of a linear double-bonded Ci-C o-alkylene group are, for example, the methylene group (-CH -), the ethylene group (-CH -CH -), the propylene group (-CH -CH -CH -) and the butylene group (-CH -CH -CH - CH -).
- the propylene group (-CH -CH -CH -) is particularly preferred.
- the radicals Ri and R 2 independently of one another represent a hydrogen atom or a Ci-Ce alkyl group.
- the radicals R 1 and R 2 both very particularly preferably represent a hydrogen atom.
- the organic silicon compound In the middle part of the organic silicon compound is the structural unit or the linker -L- which stands for a linear or branched, double-bonded Ci-C 2 o-alkylene group.
- -L- preferably represents a linear, double-bonded Ci-C 2 o-alkylene group. More preferably, -L- stands for a linear double-bonded Ci-Ce alkylene group. Particularly preferably, -L- stands for a methylene group (-CH 2 -), an ethylene group (-CH 2 -CH 2 -), a propylene group (-CH 2 -CH 2 -CH 2 -) or a butylene group (-CH 2 - CH -CH -CH -). L very particularly preferably represents a propylene group (-CH -CH -CH -).
- the radical R 3 stands for a hydrogen atom or a Ci-C6-alkyl group
- the radical R stands for a Ci-C6-alkyl group.
- R 3 and R are particularly preferably independently of one another a methyl group or an ethyl group.
- a stands for an integer from 1 to 3, and b stands for the integer 3 - a. If a stands for the number 3, then b is 0. If a stands for the number 2, then b is 1. If a stands for the number 1, then b is 2.
- the agent for treating a keratinous material had at least one organic silicon compound of the formula (I ) contains, in which the radicals R 3 , R independently of one another represent a methyl group or an ethyl group.
- Organic silicon compounds of the formula (I) are particularly suitable
- (3-aminopropyl) trimethoxysilane can be purchased from Sigma-Aldrich.
- (3-Aminopropyl) triethoxysilane is also commercially available from Sigma-Aldrich.
- the agent for treating a keratinous material contains at least one organic silicon compound of the formula (II)
- the organosilicon compounds of the formula (II) have the silicon-containing groups (R50) c (R6) dSi- and -Si (R6 ’) d (OR5’) c ⁇ at their two ends.
- an organic silicon compound of the formula (II) contains at least one group from the group consisting of - (A) - and - [NR7- (A ') j- and - [O- (A')] - and - [NR8 - (A ”') j-
- the radicals R5, R5 ′′, R5“ independently of one another represent a hydrogen atom or a Ci-Ce alkyl group.
- the radicals R6, R6 'and R6 "independently of one another represent a Ci-C6-alkyl group.
- c stands for an integer from 1 to 3, and d stands for the integer 3 - c. If c stands for the number 3, then d is 0. If c stands for the number 2, then d is 1. If c stands for the number 1, then d is 2.
- c 'stands for an integer from 1 to 3 and d' stands for the integer 3 - c '. If c 'stands for the number 3, then d' is equal to 0. If c 'stands for the number 2, then d' is equal to 1. If c 'stands for the number 1, then d' is equal to 2.
- the agent for treating a keratinous material contains at least one organic silicon compound of the formula (II)
- R5 and R5 'independently of one another represent a methyl group or an ethyl group
- the radicals e, f, g and h can independently of one another stand for the number 0 or 1, at least one radical from e, f, g and h being different from zero.
- the abbreviations e, f, g and h therefore define which of the groupings - (A) e - and - [NR7- (A ')] f - and - [0- (A ”)] g - and - [ NR8- (A ”')] h - are located in the middle part of the organic silicon compound of the formula (II).
- the residues A, A ', A “, A”' and A “” independently of one another stand for a linear or branched, double-bonded CrC2o alkylene group.
- the radicals A, A ', A “, A”' and A “” independently of one another stand for a linear, double-bonded Ci-C2o-alkylene group. With further preference the radicals A, A ', A “, A”' and A “” independently of one another represent a linear double-bonded Ci-Cß-alkylene group.
- the radicals A, A ', A “, A”' and A “” are particularly preferably independently of one another a methylene group (- CH2-), an ethylene group (-CH2-CH2-), a propylene group (-CH2-CH2-CH2 -) or a butylene group (-CH2-CH2-CH2-).
- the radicals A, A ', A ", A”' and A “” very particularly preferably represent a propylene group (-CH2-CH2-). If the radical f stands for the number 1, then the organic silicon compound of the formula (II) contains a structural grouping - [NR7- (A ')] -.
- the organic silicon compound of the formula (II) contains a structural grouping - [NR8- (A ”’)] -.
- the radicals R and Re independently of one another represent a hydrogen atom, a C -C -alkyl group, a hydroxy-Ci-Ce-alkyl group, a C-Ce-alkenyl group, an amino-Ci-Ce-alkyl group or a grouping of the formula ( III)
- the radicals Rz and Re very particularly preferably independently of one another represent a hydrogen atom, a methyl group, a 2-hydroxyethyl group, a 2-alkenyl group, a 2-aminoethyl group or a group of the formula (III).
- the agent for treating a keratinous material contains at least one organic silicon compound of the formula (II)
- R7 represents a hydrogen atom, a methyl group, a 2-hydroxyethyl group, a 2-alkenyl group, a 2-aminoethyl group or a group of the formula (III).
- the agent for treating a keratinous material contains at least one organic silicon compound of the formula (II), wherein
- a and A 'independently of one another represent a methylene group (-CH -), an ethylene group (-CH -CH -) or a propylene group (-CH -CH -CH),
- - R represents a hydrogen atom, a methyl group, a 2-hydroxyethyl group, a 2-alkenyl group, a 2-aminoethyl group or a group of the formula (III).
- Organic silicon compounds of the formula (II) which are very suitable for solving the problem are - 3- (trimethoxysilyl) -N- [3- (trimethoxysilyl) propyl] -1-propanamine
- Bis (trimethoxysilylpropyl) amine with CAS number 82985-35-1 can be purchased, for example, from Sigma-Aldrich.
- Bis [3- (triethoxysilyl) propyl] amine also referred to as 3- (triethoxysilyl) -N- [3- (triethoxysilyl) propyl] -1-propanamine, with the CAS number 13497-18-2 can be obtained, for example, from Sigma -Aldrich can be purchased or is commercially available from Evonik under the Dynasylan 1122 product name.
- N-Methyl-3- (trimethoxysilyl) -N- [3- (trimethoxysilyl) propyl] -1-propanamine is alternatively also referred to as bis (3-trimethoxysilylpropyl) -N-methylamine and can be purchased commercially from Sigma-Aldrich or Fluorochem .
- the hair treatment agent used to treat a keratinous material contains at least one organic silicon compound of the formula (IV)
- the compounds of formula (IV) are organic silicon compounds selected from silanes with one, two or three silicon atoms, the organic silicon compound comprising one or more hydroxyl groups and / or hydrolyzable groups per molecule.
- organic silicon compound (s) of the formula (IV) can also be referred to as silanes of the alkylalkoxysilane or alkylhydroxysilane type,
- R 9 represents a Ci-Ci alkyl group
- Rio represents a hydrogen atom or a Ci-C6-alkyl group
- R represents a C 1 -C 6 -alkyl group
- the agent for treating a keratinous material contains, in addition to the organic silicon compound (s) of the formula (I), at least one further organic silicon compound of the formula (IV)
- R 9 represents a Ci-Ci alkyl group
- Rio represents a hydrogen atom or a Ci-Ce alkyl group
- R represents a C 1 -C 6 -alkyl group
- the agent for treating a keratinous material contains, in addition to the organic silicon compound (s) of formula (II), at least one further organic silicon compound of formula (IV)
- R 9 represents a Ci-Ci alkyl group
- Rio represents a hydrogen atom or a Ci-C6-alkyl group
- - R represents a Ci-Ce alkyl group
- the agent for treating a keratinous material contains, in addition to the organic silicon compounds of the formula (I) and (II), at least one further organic silicon compound of the formula (IV)
- Rg stands for a Ci-Ci alkyl group
- Rio represents a hydrogen atom or a Ci-Ce alkyl group
- R represents a C 1 -C 6 -alkyl group
- the radical R represents a Ci-Ci-alkyl group.
- This Ci-Ci alkyl group is saturated and can be linear or branched.
- R9 preferably represents a linear Ci-Ce alkyl group.
- R is preferably a methyl group, an ethyl group, an n-propyl group, an n-butyl group, an n-pentyl group, an n-hexyl group, an n-octyl group or an n-dodecyl group.
- R particularly preferably represents a methyl group, an ethyl group or an n-octyl group.
- the radical Rio represents a hydrogen atom or a Ci-C6-alkyl group.
- R particularly preferably represents a methyl group or an ethyl group.
- the radical R represents a Ci-Cs-alkyl group.
- R particularly preferably represents a methyl group or an ethyl group.
- k stands for an integer from 1 to 3, and m stands for the integer 3 - k. If k stands for the number 3, then m is 0. If k stands for the number 2, then m is 1. If k stands for the number 1, then m is 2.
- the agent for the treatment of a keratinous material contains at least one organic silicon compound of the formula (IV) in which the rest k stands for the number 3. In this case, the remainder m stands for the number 0.
- an agent is characterized in that it contains at least one organic silicon compound of the formula (I) and at least one organic silicon compound of the formula (IV).
- an agent in an explicitly very particularly preferred embodiment, contains at least one organic silicon compound of the formula (I) which is selected from the group consisting of (3-aminopropyl) triethoxysilane and (3-aminopropyl) trimethoxysilane, and additionally at least contains an organic silicon compound of the formula (IV) which is selected from the group consisting of methyltrimethoxysilane, methyltriethoxysilane, ethyltrimethoxysilane, ethyltriethoxysilane, propyltrimethoxysilane, propyltriethoxysilane, hexyltrimethoxysilane and hexyltriethoxysilane.
- organic silicon compound of the formula (I) which is selected from the group consisting of (3-aminopropyl) triethoxysilane and (3-aminopropyl) trimethoxysilane
- an organic silicon compound of the formula (IV) which is selected from the
- an agent is characterized in that the agent contains - based on the total weight of the agent:
- At least one first organic silicon compound which is selected from the group consisting of (3-aminopropyl) trimethoxysilane, (3-aminopropyl) triethoxysilane, (2-aminoethyl) trimethoxysilane, (2-aminoethyl) triethoxysilane , (3-Dimethylaminopropyl) trimethoxysilane, (3-Dimethylaminopropyl) triethoxysilane (2-Dimethylaminoethyl) trimethoxysilane and (2-Dimethylaminoethyl) triethoxysilane, and
- At least one second organic silicon compound which is selected from the group consisting of methyltrimethoxysilane, methyltriethoxysilane, ethyltrimethoxysilane, ethyltriethoxysilane, propyltrimethoxysilane, propyltriethoxysilane, hexyltrimethoxysilane, hexyltriethoxysilane
- Silicon compounds with at least one hydroxyl group can react with one another in a condensation reaction. For this reason, both the organosilicon compounds with at least one hydrolyzable group and their hydrolysis and / or condensation products can be present in the agent. When using organosilicon compounds with at least one hydroxyl group, both the organic silicon compounds with at least one hydroxyl group and their condensation products may be present in the agent.
- a condensation product is understood to mean a product that is formed by reacting at least two organic silicon compounds with at least one hydroxyl group or hydrolyzable group per molecule, with the elimination of water and / or with the elimination of an alkanol.
- the condensation products can be, for example, dimers, but also trimers or oligomers, the condensation products being in equilibrium with the monomers. Depending on the amount of water used or consumed in the hydrolysis, the balance shifts from monomeric organic silicon compounds to the condensation product.
- the cosmetic agent for treating a keratinous material contains a cationic surfactant.
- a cationic surfactant for example (3-aminopropyl) trimethoxysilane or (3-aminopropyl) triethoxysilane, with a cationic Surfactant can be combined.
- the combination of the at least one organic silicon compound and a cationic surfactant forms a layer on the hair. This ensures that oxidative hair colors are significantly protected from washing out. In addition, the hair surface in the case of hair damaged by oxidation is rendered hydrophobic again, which leads to the reduction of frizz. In addition, the combability of the hair is improved.
- the amount of cationic surfactant is 0.1 to 30% by weight, preferably 0.5 to 20% by weight, more preferably 1 to 10% by weight, based on the total weight of the cosmetic composition .
- the cationic surfactant comprises a hydrophobic head group with a cationic charge and one or two hydrophobic end parts, the hydrophobic end part or the hydrophobic end parts being straight-chain or branched, saturated or represent mono- or polyunsaturated alkyl groups which preferably have a chain length of C6 to C30, more preferably C8 to C26, particularly preferably C10 to C22.
- the cationic surfactant has an ester function, an ether function, a ketone function, an alcohol function or an amide function.
- the cosmetic agent contains at least one cationic surfactant of the formula (V),
- Rl2, Rl3, Rl4 independently of one another represent a C1-C6-alkyl group, a C2-C6-alkenyl group or a C2-C6-hydroxyalkyl group,
- Rl5 stands for a C8-C28-alkyl group, preferably a C10-C22-alkyl group and
- X- stands for a physiologically compatible anion, and / or the cosmetic agent contains at least one cationic surfactant of the formula (VI),
- R-ie represents a C1 -C6 alkyl group
- Rl7, Rl8 independently of one another for a C7-C27-alkyl group, preferably a C10-C22-
- X- stands for a physiologically compatible anion, and / or the cosmetic agent contains at least one cationic surfactant of the formula (VII), wherein
- X- stands for a physiologically compatible anion, and / or the cosmetic agent contains at least one cationic surfactant of the formula (VIII),
- (VIII) are a C1-C6-alkyl group, a C2-C6-alkenyl group or a C2-C6-hydroxyalkyl group, and
- the cationic surfactants of the formula (VIII) are amine derivatives, so-called
- the cosmetic composition further contains c) a nonionic surfactant.
- a nonionic surfactant selected from the group consisting of
- Alkyl glucamide comprising a saturated or unsaturated, branched or unbranched Ce to C22, preferably C10 to Cie, more preferably C12 to C-ib alkyl group,
- Alkyl fructoside comprising a saturated or unsaturated, branched or unbranched Ob to C22, preferably C10 to Cie, more preferably C12 to Cie alkyl group,
- Alkyl glucoside comprising a saturated or unsaturated, branched or unbranched Ce bis prefers to cis, more preferred to Alkyl group, and
- the cosmetic agent contains two structurally different surfactants. It is particularly preferred that the cosmetic agent contains two structurally different surfactants, preferably the cosmetic agent contains two structurally different cationic surfactants, or the cosmetic agent contains a cationic surfactant and a nonionic surfactant.
- the agent for treating a keratinous material can in particular comprise an agent for cleaning a keratinous material, an agent for maintaining a keratinous material, an agent for maintaining and cleaning a keratinous material and / or an agent for temporarily reshaping a keratinous material.
- the agent for treating a keratinous material further comprises 0.001 to 20% by weight of at least one quaternary compound. This applies in particular to agents for the care of a keratinous material and agents for the care and cleaning of a keratinous material.
- the at least one quaternary compound is selected from at least one of the groups consisting of
- Quaternized cellulose derivatives in particular Polyquaternium 10, Polyquaternium-24, Polyquaternium-27, Polyquaternium-67, Polyquaternium-72, and / or
- Dialkylaminoalkyl acrylate and methacrylate in particular polyquaternium-1 1 and / or
- Vinylpyrrolidone-vinylimidazolium methochloride copolymers in particular polyquaternium-16 and / or
- the hair treatment composition contains a cationic homopolymer, which falls under the INCI name Polyquaternium-37, as quaternary compounds. It may be preferred that the agent for treating a keratinous material further comprises a setting compound, preferably selected from the group consisting of waxes, synthetic polymers and mixtures thereof.
- a large number of synthetic polymers have already been developed as strengthening compounds which are used in the agent for treating a keratinous material Material can be used.
- waxes are used as strengthening compounds.
- the polymers and / or waxes when used on the keratinous material result in a polymer film or film which on the one hand gives the hairstyle a strong hold, but on the other hand is sufficiently flexible so that it does not break under stress.
- the synthetic polymers can be divided into cationic, anionic, nonionic and amphoteric setting polymers.
- Suitable synthetic polymers include, for example, polymers with the following INCI names: Acrylamide / Ammonium Acrylate Copolymer, Acrylamides / DMAPA Acrylates / Methoxy PEG Methacrylate Copolymer, Acrylamidopropyltrimonium Chloride / Acrylamide Copolymer,
- Copolymer Acrylates / Lauryl Acrylate / Stearyl Acrylate / Ethylamine Oxide Methacrylate Copolymer, Acrylates / Octylacrylamide Copolymer, Acrylates / Octylacrylamide / Diphenyl Amodimethicone Copolymer, Acrylates / Stearyl Acrylate / Ethylamine Oxide Methacrylate Copolymer, Acrylates / VA Copolymer, Acrylates / Hydroxyesters Acrylates Copolymer, Acrylates / VP Copolymer, Adipic Acid / Diethylenetriamine Copolymer, Adipic Acid / Dimethylaminohydroxypropyl Diethylenetriamine Copolymer, Adipic
- Polyacrylate-6 Polybeta-Alanine / Glutaric Acid Crosspolymer, Polybutylene Terephthalate, Polyester-1, Polyethylacrylate, Polyethylene Terephthalate, Polymethacryloyl Ethyl Betaine, Polypentaerythrityl Terephthalate, Polyperfluoroperhydrophenanthrene, Polyquaternium-1, Polyquaternium-1
- Polyvinylcaprolactam polyvinylformamide, polyvinyl imidazolinium acetate, polyvinyl methyl ether, potassium butyl ester of PVM / MA copolymer, potassium ethyl ester of PVM / MA copolymer, PPG-70 polyglyceryl-10 ether, PPG-12 / SMDI copolymer, PPG-51 / SMDI Copolymer, PPG-10 Sorbitol, PVM / MA Copolymer, PVP, PVP / VA / ltaconic Acid Copolymer, PVP / VA / Vinyl Propionate Copolymer, Rhizobian Gum, Rosin Acrylate, Shellac, Sodium Butyl Ester of PVM / MA Copolymer, Sodium Ethyl Ester of PVM / MA Copolymer, Sodium Polyacrylate, Sterculia Urens Gum, Terephthalic Acid / Isophthalic
- Caprolactam / VP / Dimethylaminoethyl Methacrylate Copolymer VP / Acrylates / Lauryl Methacrylate Copolymer, VP / Dimethylaminoethyl methacrylate Copolymer, VP / DMAPA Acrylates Copolymer, VP / Hexadecene Copolymer, VP / VA Copolymer, VP / Vinyl Caprolactam / DMAPA Acrylates Copolymer, Yeast Palmitate and Styrene / VP copolymer.
- Cellulose ethers such as
- Hydroxypropyl cellulose hydroxyethyl cellulose and methyl hydroxypropyl cellulose.
- Homopolyacrylic acid (INCI: Carbomer), which is commercially available under the name Carbopol® in various versions, is also suitable as a setting compound.
- the setting compound preferably comprises a vinylpyrrolidone-containing polymer.
- the setting compound particularly preferably comprises a polymer selected from the group consisting of
- Polyvinyl pyrrolidone PVP
- vinyl pyrrolidone-vinyl acetate copolymer VP / VA copolymer
- vinyl Caprolactam / VP / Dimethylaminoethyl Methacrylate Copolymer INCI
- VP / DMAPA Acrylates Copolymer INCI and mixtures thereof.
- Another preferred strengthening compound is octylacrylamide / acrylates / butylaminoethyl methacrylate copolymer (INCI), which is sold under the name “Amphomer®” by Akzo Nobel.
- the setting compound is a synthetic polymer selected from the group consisting of polyvinylpyrrolidone (PVP), vinylpyrrolidone-vinyl acetate copolymer (VP / VA copolymer), vinyl caprolactam / VP / dimethylaminoethyl methacrylate copolymer (INCI), VP / DMAPA Acrylates Copolymer (INCI), Octylacrylamide / Acrylates / Butylaminoethyl Methacrylate Copolymer (INCI) and mixtures thereof.
- PVP polyvinylpyrrolidone
- VP / VA copolymer vinyl caprolactam / VP / dimethylaminoethyl methacrylate copolymer
- VP / DMAPA Acrylates Copolymer INCCI
- Octylacrylamide / Acrylates / Butylaminoethyl Methacrylate Copolymer INCI
- the cosmetic composition can contain at least one natural or synthetic wax, which has a melting point of over 37 ° C., as a setting compound.
- Solid paraffins or isoparaffins plant waxes such as candelilla wax, carnauba wax, esparto grass wax, Japanese wax, cork wax, sugar cane wax, ouricury wax, montan wax, sunflower wax, fruit waxes and animal waxes, such as bees waxes and other insect waxes, wool wax and shellac wax, can be used as natural or synthetic waxes Bürzelfett, further mineral waxes, such as ceresin and ozokerite or the petrochemical waxes, such as petrolatum, paraffin waxes, microwaxes made of polyethylene or polypropylene and
- Polyethylene glycol waxes are used. It can be advantageous to use hydrogenated or hardened waxes. Furthermore, chemically modified waxes, in particular hard waxes, for example montan ester waxes, Sasol waxes and hydrogenated jojoba waxes, can also be used.
- triglycerides of saturated and optionally hydroxylated C16-30 fatty acids such as, for example, hardened triglyceride fats (hydrogenated palm oil, hydrogenated coconut oil, hydrogenated castor oil), glyceryl tribehenate or glyceryl tri-12-hydroxystearate.
- the wax components can also be selected from the group of the esters from saturated, unbranched alkane carboxylic acids with a chain length of 22 to 44 carbon atoms and saturated, unbranched alcohols with a chain length of 22 to 44 carbon atoms, provided that the wax component or all of the wax components at room temperature are firm.
- Silicone waxes for example stearyltrimethylsilane / stearyl alcohol, may also be advantageous.
- Natural, chemically modified and synthetic waxes can be used alone or in combination. This means that several waxes can also be used. Furthermore, a number of wax mixtures, possibly mixed with other additives, are commercially available.
- special wax 7686 OE a mixture of cetyl palmitate, beeswax, microcrystalline wax and polyethylene with a melting range of 73-75 ° C; Manufacturer: Kahl &
- Polywax® GP 200 (a mixture of stearyl alcohol and polyethylene glycol stearate with a melting point of 47-51 ° C; manufacturer: Croda) and "Weichceresin® FL 400" (a
- Vaseline / Vaseline oil / wax mixture with a melting point of 50-54 ° C; Manufacturer: Parafluid Mineralölgesellschaft) are examples of mixtures that can be used.
- the wax is preferably selected from carnauba wax (INCI: Copernicia Cerifera Cera) beeswax (INCI: Beeswax), petrolatum (INCI), microcrystalline wax and in particular mixtures thereof.
- Preferred mixtures include the combination of carnauba wax (INCI: Copernicia Cerifera Cera), petrolatum and microcrystalline wax or the combination of beeswax (INCI: Beeswax) and petrolatum.
- the wax or wax components should be solid at 25 ° C and should melt in the range of> 37 ° C
- the agent for treating a keratinous material preferably contains the setting compound in a total amount of 0.5 to 50% by weight, preferably 1 to 40% by weight, more preferably 1.5 to 30% by weight, even more preferably 2 to 25 wt .-%, based on the total weight of the cosmetic composition.
- suitable ingredients include nonionic polymers, anionic polymers, (further) cationic polymers, waxes, protein hydrolyzates, amino acids, oligopetides, vitamins, provitamins, vitamin precursors, betaines, bioquinones, purine (derivatives), care substances, plant extracts, silicones, ester oils, UV light protection filters , Structuring agents, thickeners, electrolytes, pH adjusting agents, swelling agents, dyes, anti-dandruff agents, complexing agents, opacifiers, pearlescent agents, pigments, stabilizers, blowing agents, antioxidants, perfume oils and / or preservatives.
- the preferably used organic silicon compounds are combined with the preferably used cationic surfactant in a cosmetic agent according to the invention.
- the * means that the steamidopropyl dimethylamine (INCI) used is the cationized form, ie it is actually a quaternized (and thus cationic) compound.
- the active ingredient combination of at least one organic silicon compound and a cationic surfactant can already be contained in the agent for the treatment of a keratinous material.
- the agent for treating a keratinous material is already in
- the agent itself is preferably packaged with little or no water.
- the at least one organic silicon compound is used for a maximum of 12 hours, preferably a maximum of 6 hours, more preferably a maximum of 3 hours, even more preferably a maximum of 1 hour before use of the agent for treating a keratinous material based on all the ingredients of the agent for treating a keratinous material Exception of the at least one organic silicon compound added.
- the organic silicon compound and the cationic surfactant are added to a cosmetic product only shortly before use, ie 1 minute to 12 hours, preferably 2 minutes to 6 hours, particularly preferably 1 minute to 3 hours, particularly preferably 1 minute to 1 hour .
- the bis (triethoxysilylpropyl) amine is added to an aqueous solution which is applied to the hair and in the second step an aqueous solution or a cosmetic agent which contains cationic surfactants is applied to the hair.
- the user can stir or spill an agent (a) which contains the organic silicon compound (s) with an agent ( ⁇ ) which comprises the remaining ingredients of the agent for treating a keratinous material.
- agent (a) which contains the organic silicon compound (s)
- agent ( ⁇ ) which comprises the remaining ingredients of the agent for treating a keratinous material.
- the user can now apply this mixture of (a) and (ß) to the keratinous materials - either directly after their production or after a short reaction time of 1 minute to 20 minutes.
- the agent (ß) can contain water, in particular water in an amount> 30 wt .-%, based on the total weight of the agent for the treatment of keratinous materials.
- Another object of the present application is the use of a cosmetic agent according to the invention for the treatment of a keratinous material
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- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
- Public Health (AREA)
- Veterinary Medicine (AREA)
- Birds (AREA)
- Epidemiology (AREA)
- Dermatology (AREA)
- Cosmetics (AREA)
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE102018127254.5A DE102018127254A1 (de) | 2018-10-31 | 2018-10-31 | Wirkstoffzusammensetzung zur Pflege und Oberflächenmodifikation von Humanhaaren |
PCT/EP2019/079771 WO2020089357A1 (de) | 2018-10-31 | 2019-10-31 | Wirkstoffzusammensetzung zur pflege und oberflächenmodifikation von humanhaaren |
Publications (1)
Publication Number | Publication Date |
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EP3873618A1 true EP3873618A1 (de) | 2021-09-08 |
Family
ID=68426468
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP19797672.3A Pending EP3873618A1 (de) | 2018-10-31 | 2019-10-31 | Wirkstoffzusammensetzung zur pflege und oberflächenmodifikation von humanhaaren |
Country Status (6)
Country | Link |
---|---|
US (1) | US20220031594A1 (ja) |
EP (1) | EP3873618A1 (ja) |
JP (1) | JP2022506206A (ja) |
CN (1) | CN112955229A (ja) |
DE (1) | DE102018127254A1 (ja) |
WO (1) | WO2020089357A1 (ja) |
Family Cites Families (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3050477A (en) * | 1959-10-13 | 1962-08-21 | Gen Tire & Rubber Co | Method of making polyurethane foam using an organic silane |
DE10233963A1 (de) * | 2002-07-25 | 2004-02-12 | Itn-Nanovation Gmbh | Verwendung von Silanen in kosmetischen Mitteln und Verfahren zur Haarbehandlung |
FR3013592B1 (fr) * | 2013-11-25 | 2016-07-29 | Oreal | Composition cosmetique comprenant au moins un silane particulier, au moins un polysacharride anionique et/ou non-ionique et au moins un sel mineral hydrosoluble |
DE102014205806A1 (de) * | 2014-03-28 | 2015-10-01 | Evonik Degussa Gmbh | Silan enthaltend jeweils mindestens zwei Alkoxygruppen sowie eine Guanidino- oder Harnstoffgruppe |
US10143644B2 (en) * | 2015-08-31 | 2018-12-04 | L'oreal | Composition comprising an anionic-ampholytic polymer association |
US10524999B2 (en) * | 2015-12-14 | 2020-01-07 | L'oreal | Composition comprising a combination of particular alkoxysilanes and a fatty substance |
US11642303B2 (en) * | 2016-03-31 | 2023-05-09 | L'oreal | Hair care compositions comprising cationic compounds, starch, and silane compounds |
US20180055751A1 (en) * | 2016-08-31 | 2018-03-01 | L'oreal | Compositions comprising an associaton of cationic compounds, silane compounds, esters and fatty substances |
-
2018
- 2018-10-31 DE DE102018127254.5A patent/DE102018127254A1/de active Pending
-
2019
- 2019-10-31 JP JP2021523416A patent/JP2022506206A/ja not_active Ceased
- 2019-10-31 WO PCT/EP2019/079771 patent/WO2020089357A1/de unknown
- 2019-10-31 US US17/290,210 patent/US20220031594A1/en active Pending
- 2019-10-31 CN CN201980071627.7A patent/CN112955229A/zh active Pending
- 2019-10-31 EP EP19797672.3A patent/EP3873618A1/de active Pending
Also Published As
Publication number | Publication date |
---|---|
CN112955229A (zh) | 2021-06-11 |
US20220031594A1 (en) | 2022-02-03 |
JP2022506206A (ja) | 2022-01-17 |
WO2020089357A1 (de) | 2020-05-07 |
DE102018127254A1 (de) | 2020-04-30 |
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