EP3850120A1 - Method for coating a component and coated component - Google Patents
Method for coating a component and coated componentInfo
- Publication number
- EP3850120A1 EP3850120A1 EP19778427.5A EP19778427A EP3850120A1 EP 3850120 A1 EP3850120 A1 EP 3850120A1 EP 19778427 A EP19778427 A EP 19778427A EP 3850120 A1 EP3850120 A1 EP 3850120A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- coated
- component
- crater
- laser
- depth
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C4/00—Coating by spraying the coating material in the molten state, e.g. by flame, plasma or electric discharge
- C23C4/02—Pretreatment of the material to be coated, e.g. for coating on selected surface areas
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C24/00—Coating starting from inorganic powder
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C24/00—Coating starting from inorganic powder
- C23C24/02—Coating starting from inorganic powder by application of pressure only
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C24/00—Coating starting from inorganic powder
- C23C24/02—Coating starting from inorganic powder by application of pressure only
- C23C24/04—Impact or kinetic deposition of particles
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C24/00—Coating starting from inorganic powder
- C23C24/08—Coating starting from inorganic powder by application of heat or pressure and heat
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C4/00—Coating by spraying the coating material in the molten state, e.g. by flame, plasma or electric discharge
- C23C4/12—Coating by spraying the coating material in the molten state, e.g. by flame, plasma or electric discharge characterised by the method of spraying
- C23C4/129—Flame spraying
Definitions
- the present invention relates to a method for coating a component.
- the invention also relates to a component coated according to the method.
- a surface of a component is coated by depositing a powdery coating material.
- a heated gas such as nitrogen or helium is accelerated to very high speeds, for example by expansion in a lava nozzle in the direction of the surface to be coated.
- the speeds are above the speed of sound and are, for example, 500-1000 m / s.
- the powder coating material is injected into the accelerated gas jet.
- the powdery coating material impacts the surface to be coated at such a high speed that the particles of the powder plastically deform upon impact and as a result adhere to the surface to be coated.
- thermal coating processes such as plasma spraying, arc spraying, flame spraying, the particles of the powder are not melted.
- the impact of a powder particle on the surface to be coated creates a shear stress that plastically deforms the material of a powder particle.
- the resulting shear stress leads to adiabatic shear instability, which brings the surface areas of a powder particle to temperatures close to the melting point of the coating material and thus softens it, thereby binding powder particles and component to one another.
- Good adhesion between a substrate and the coating material is therefore a problem
- Cold gas spraying requires that sufficient shear instabilities are created by the impact.
- a component can be coated with metals, polymers, ceramics, composite materials and nanocristailin powder by cold gas spraying.
- the object of the invention is to further develop the coating of a component.
- the object of the invention is achieved by a method according to claim 1.
- a subsidiary claim relates to a component coated according to the method.
- Advantageous configurations result from the dependent claims.
- the object of the invention is achieved by a method for coating a component, in which a surface of the component to be coated is roughened by a laser and the roughened surface is coated with a high-energy thermal spraying method, such as cold gas spraying. Basically, it is roughened like a crater.
- the inventors have found that a combination of the two measures “roughening by laser” and “coating by cold gas spraying” lead to particularly stable adhesion between the component and the layer. It has been found that roughening using a laser does not disadvantageously modify the material of the component on its surface physically or chemically in such a way that adhesion between the component and the layer is reduced. Roughening using a laser is therefore advantageous compared to roughening by sandblasting. It has further been found that the physical and chemical properties of the surface are also not adversely changed by cold gas spraying, so that the combination of Both measures a very good adhesion between the component and the coating can be achieved.
- the surface of the component to be coated is ground and / or polished, that is, smoothed, before it is roughened by means of a laser.
- ground and / or polished surface areas can advantageously be retained even after processing by a laser in order to favorably influence adiabatic shear instabilities and thereby achieve further improved adhesion properties.
- the surface of the component to be coated is exposed at predetermined locations by means of a laser in such a way that crater-like depressions occur at the exposed locations and other areas of the surface to be coated also after the production of crater-shaped depressions in the previous state, that is to say in particular in one ground and / or polished and thus smoothed.
- the ratio between crater-shaped depressions and areas not roughened by laser can be optimized in order to achieve particularly good adhesive properties.
- the surface of the component to be coated is pulse-exposed several times by laser in such a way that crater-shaped depressions are formed at the exposed locations, in particular to achieve crater depths of at least 1 Cpm or 20 pm, preferably to at least crater depths 30 pm to further improve the adhesion properties. It has been found that excessively great depths deteriorate adhesion properties again. Therefore, the depth of a crater-shaped depression is preferably limited to 60 pm, particularly preferably to 50 pm.
- the diameter of the crater-shaped depression at the upper edge corresponds approximately to the depth of the crater-shaped depression. So shows a crater-shaped depression upper edge, for example, has a diameter of approx. 40 pm, then a depth of approx. 40 miti is preferred. The depth should preferably not deviate from the diameter by more than 20%. So if the diameter is 40 pm, the depth should be at least 32 pm and not more than 48 pm in order to further improve the adhesion properties. In one embodiment, the crater-shaped depressions have a diameter of 30 pm to 50 pm and a depth of 30 pm to 50 pm.
- Time intervals are preferably provided between the individual light pulses in such a way that material melted by laser light can only solidify again before the predetermined point is exposed again. Crater-shaped depressions can thus be further optimized. The adhesion between the component and the coating can be further improved in this way.
- each predetermined location is exposed to the light of the laser at least 3 times, preferably at least 5 times, and / or not more than 25 times, preferably not more than 15 times, in order to produce crater-shaped depressions in an optimized manner, and thus particularly good adhesion properties.
- the crater-shaped depressions have circular diameters. This configuration ensures that areas of the surface to be coated remain between crater-shaped depressions that have not been exposed by the laser and have therefore not been roughened.
- the upper edge of the crater-shaped depressions protrudes in a bead-like manner towards regions of the surface to be coated which have not been exposed by the light of the laser.
- the upper edge protrudes in particular by at least 5 pm, preferably by at least 10 pm and / or by no more than 20 pm from regions of the surface to be coated which have not been exposed to the light of the laser.
- the component is in a gas atmosphere made of noble gas, preferably argon, or nitrogen during its processing.
- the component is then in a room through which, for example, an inert gas or nitrogen is passed, or else the is gastight and has previously been introduced into the noble gas or nitrogen.
- a protective gas jacket is produced which surrounds the laser beam during the exposure.
- a protective gas jacket can be created using nozzles which are arranged around the light of the laser in such a way that the light beam of the laser impinging on the component is enveloped by the gas which emerges from the nozzles. The adhesion between the component and the coating can be further improved in this way.
- the coating material matches the material of the surface to be coated. If the material of a component has been damaged by external influences, such damage can be repaired particularly stably and reliably by a coating according to the invention with the same material.
- beads of crater-shaped depressions adjoin one another and / or overlap or overlap.
- the diameter of each crater-shaped depression then corresponds approximately to the distance between two center points of two adjacent crater-shaped depressions.
- the predetermined locations and thus the crater-shaped depressions are arranged according to a repeating pattern and thus according to plan.
- This can be a checkerboard pattern, for example.
- the predetermined locations and thus the crater-shaped depressions are arranged one behind the other and next to each other along a straight line.
- the craters are not arranged randomly.
- the gas is heated to temperatures of 500 ° C. to 1200 ° C. during cold gas spraying, in order to improve adhesion properties.
- the component to be coated is preferably not additionally heated. In this way, thermally induced physical and / or chemical changes to the surface to be coated are advantageously avoided. Nitrogen can be used as the gas.
- the laser beam strikes the surface of the component at a right angle so as to produce crater-shaped depressions. It is but it is also possible to provide an angle deviating from 90 ° in order to suitably roughen the surface of the component by means of laser light.
- Figure 1 sectional views of a surface created according to the invention
- FIG. 2 top view of the surface of a component to be coated
- Figure 3 cross section of a component coated according to the invention.
- the surface of the substrate to be coated was removed at a frequency of 35 kHz and a pulse length of 120 ns at full power, which corresponds to a peak power of 15 kW.
- crater-shaped depressions with a diameter of 40 ⁇ m were produced on the surface to be coated.
- Craters were made one behind the other and side by side, i.e. in a checkerboard fashion, at a distance of 40 pm. Every single place where a crater was to be created was exposed a total of 12 times by the light of the laser. However, a single spot was not immediately exposed the next time after exposure immediately afterwards.
- each location was first exposed for the first time and then in the same order a second time, etc., until all locations were exposed twelve times in this way. Every single position could cool down after exposure and solidify again before exposure again. Undesired oxidation of the surface could thus be avoided better.
- a second part of the substrates was not further processed for comparison tests.
- the surface to be coated thus remained in the state smoothed by grinding and polishing.
- the surfaces to be coated of substrates made of the alloy IN738 were also roughened by sandblasting. These surfaces to be coated were also previously sanded and polished.
- FIG. 1 shows two sectional representations of the surface to be coated according to the invention, according to the aforementioned first part of the substrates, which were determined with a laser microscope. On the one hand, a sectional view of exposed areas in the xz direction and on the other hand in the yz direction is shown. The two sectional representations make it clear that a crater-shaped depression with a diameter of approximately 0.4 pm was created at an exposed location. The depth was almost 0.4 pm.
- the centers of the essentially circular, crater-shaped depressions were regularly arranged on the polished surface of the component at a distance of 40 pm in accordance with a checkerboard pattern.
- FIG. 2 shows an image of the laser microscope on the surface of a component to be coated, that is to say a substrate.
- This photograph shows a top view of the distribution of the crater-shaped depressions 1, which was created by repeated exposure, in accordance with a chessboard pattern.
- the edges of the craters have a solidification pattern 3 on the edges due to the individual exposure that protrude up to approx. 15 pm above the unexposed, polished areas, i.e. in the z direction.
- the bead-like solidification patterns 3 form upper edges of the crater-shaped depressions 1.
- Upper edges 3 of the craters overlap or at least adjoin one another.
- the depth of the crater-shaped depressions 1 is approximately 20 pm in relation to the polished base area. In total, a depth of about 35 pm was created.
- roughness of surfaces of the substrates processed according to the invention and roughness of surfaces to be coated of the other substrates were determined for comparison purposes.
- Three substrates each made of the IN738 alloy were coated in the commercially available “GGT-Oerlikon Metco Kinetics 8000” system with a water-cooled D-24 De-Laval nozzle with IN738 powder with an average diameter of 7.89 pm, the first three Substrates treated according to the invention had surfaces to be coated, the second three substrates had surfaces treated by sandblasting and surfaces to be coated and the third three substrates had polished surfaces to be coated.
- a pressure of 40 bar nitrogen, a gas temperature of 950 ° C. and a coating distance of 60 mm were chosen as coating parameters. The layer thicknesses thus produced were approximately 400 pm.
- coated substrates were bonded between two cylinders for adhesive peel tests, so that the substrate was bonded to one of the cylinders and the coating produced to the other cylinder.
- the coating detached from the substrate.
- a cylinder always detached from the coated substrate. It was thus found that in the case of the surfaces to be coated treated according to the invention, significantly better adhesion between the coating and the substrate was achieved.
- FIG. 3 shows a cross section of a component 4 coated according to the invention with a layer 5 on the substrate 6 after the adhesion removal tests have been carried out in the region of a crater-shaped depression 1.
- FIG. 3 illustrates that the Crater-shaped depressions 1 were completely filled by the cold gas spraying and the adhesive detachment tests carried out could not change anything. No cracks have formed.
- the invention is not restricted to the exemplary embodiment. For example, it is also possible, alternatively or additionally, to prepare the surface of a component in a different way compared to grinding and polishing, for example by sandblasting or shot peening, in order to subsequently roughen it using a laser.
- Good adhesion properties can also be achieved in this way, especially in comparison to a surface preparation which only comprises sandblasting, in order to then coat.
- another thermal coating method can be provided instead of cold gas spraying, in which the coating material is brought to a high speed so as to coat.
- HVAF High Velocity Air-Fuel
- the alternatives mentioned relating to sandblasting, shot peening or HVAF are less preferable.
- the object of the invention can also be achieved by a method for coating a component, in which a surface of the component to be coated is roughened by a laser and the roughened surface is coated with high kinetic energy such as cold gas spraying or HVFA by a thermal spraying method.
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Physics & Mathematics (AREA)
- Plasma & Fusion (AREA)
- Laser Beam Processing (AREA)
- Application Of Or Painting With Fluid Materials (AREA)
Abstract
Description
Claims
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE102018215389.2A DE102018215389A1 (en) | 2018-09-11 | 2018-09-11 | Method for coating a component and coated component |
PCT/EP2019/072137 WO2020052917A1 (en) | 2018-09-11 | 2019-08-19 | Method for coating a component and coated component |
Publications (1)
Publication Number | Publication Date |
---|---|
EP3850120A1 true EP3850120A1 (en) | 2021-07-21 |
Family
ID=68069721
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP19778427.5A Pending EP3850120A1 (en) | 2018-09-11 | 2019-08-19 | Method for coating a component and coated component |
Country Status (4)
Country | Link |
---|---|
US (1) | US20210317558A1 (en) |
EP (1) | EP3850120A1 (en) |
DE (1) | DE102018215389A1 (en) |
WO (1) | WO2020052917A1 (en) |
Family Cites Families (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH0757904B2 (en) * | 1989-01-23 | 1995-06-21 | 住友金属工業株式会社 | Heat treatment furnace roll and manufacturing method thereof |
EP1854903B1 (en) * | 2006-05-08 | 2013-10-02 | Ford-Werke GmbH | Method for manufacturing wear-resistant coatings on a metal base |
DE102007023418B4 (en) * | 2007-05-18 | 2010-09-09 | Daimler Ag | Process for roughening surfaces for subsequent application of sprayed coatings, corresponding roughened components and coated metal components |
DE102011106564A1 (en) * | 2011-07-05 | 2013-01-10 | Mahle International Gmbh | Method for producing a cylinder surface and cylinder liner |
US20130209745A1 (en) * | 2012-02-10 | 2013-08-15 | National Research Council Of Canada | Method of coating of a substrate with a thermal spray coating material and coated substrate formed thereby |
DE102012217685A1 (en) * | 2012-09-28 | 2014-04-03 | Siemens Aktiengesellschaft | Process for coating by thermal spraying with inclined particle jet |
DE102015207602A1 (en) | 2015-04-24 | 2016-10-27 | Gfe Metalle Und Materialien Gmbh | Method for producing a tubular cathode for use in PVD ARC coating systems |
DE102016200951A1 (en) * | 2016-01-25 | 2017-07-27 | Volkswagen Aktiengesellschaft | Method for producing a wear and / or corrosion-resistant coating on a friction surface of a brake body as well as brake body produced by the method |
-
2018
- 2018-09-11 DE DE102018215389.2A patent/DE102018215389A1/en active Pending
-
2019
- 2019-08-19 EP EP19778427.5A patent/EP3850120A1/en active Pending
- 2019-08-19 US US17/267,729 patent/US20210317558A1/en active Pending
- 2019-08-19 WO PCT/EP2019/072137 patent/WO2020052917A1/en unknown
Also Published As
Publication number | Publication date |
---|---|
US20210317558A1 (en) | 2021-10-14 |
WO2020052917A1 (en) | 2020-03-19 |
DE102018215389A1 (en) | 2020-03-12 |
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