EP3775309B1 - Alliage d'aluminium pour coulée sous pression - Google Patents
Alliage d'aluminium pour coulée sous pression Download PDFInfo
- Publication number
- EP3775309B1 EP3775309B1 EP20711910.8A EP20711910A EP3775309B1 EP 3775309 B1 EP3775309 B1 EP 3775309B1 EP 20711910 A EP20711910 A EP 20711910A EP 3775309 B1 EP3775309 B1 EP 3775309B1
- Authority
- EP
- European Patent Office
- Prior art keywords
- die casting
- alloy
- weight
- casting alloy
- optionally
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 229910045601 alloy Inorganic materials 0.000 title claims description 37
- 239000000956 alloy Substances 0.000 title claims description 37
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 title claims description 20
- 229910052782 aluminium Inorganic materials 0.000 title claims description 20
- 238000004512 die casting Methods 0.000 title claims description 8
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 claims description 14
- 229910052750 molybdenum Inorganic materials 0.000 claims description 14
- 239000011733 molybdenum Substances 0.000 claims description 14
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 claims description 13
- 229910052748 manganese Inorganic materials 0.000 claims description 13
- 239000011572 manganese Substances 0.000 claims description 13
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 claims description 12
- 229910052804 chromium Inorganic materials 0.000 claims description 12
- 239000011651 chromium Substances 0.000 claims description 12
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 8
- 229910052710 silicon Inorganic materials 0.000 claims description 5
- 239000010703 silicon Substances 0.000 claims description 5
- 238000010438 heat treatment Methods 0.000 claims description 4
- 229910052742 iron Inorganic materials 0.000 claims description 4
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims description 3
- 229910052749 magnesium Inorganic materials 0.000 claims description 3
- 239000011777 magnesium Substances 0.000 claims description 3
- 229910052720 vanadium Inorganic materials 0.000 claims description 3
- LEONUFNNVUYDNQ-UHFFFAOYSA-N vanadium atom Chemical compound [V] LEONUFNNVUYDNQ-UHFFFAOYSA-N 0.000 claims description 3
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 2
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 claims description 2
- 229910052712 strontium Inorganic materials 0.000 claims description 2
- CIOAGBVUUVVLOB-UHFFFAOYSA-N strontium atom Chemical compound [Sr] CIOAGBVUUVVLOB-UHFFFAOYSA-N 0.000 claims description 2
- 239000010936 titanium Substances 0.000 claims description 2
- 229910052719 titanium Inorganic materials 0.000 claims description 2
- 229910052726 zirconium Inorganic materials 0.000 claims description 2
- 239000004411 aluminium Substances 0.000 claims 5
- 239000012535 impurity Substances 0.000 claims 1
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 claims 1
- 238000005266 casting Methods 0.000 description 7
- 239000000203 mixture Substances 0.000 description 6
- 238000000034 method Methods 0.000 description 5
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 4
- 229910000838 Al alloy Inorganic materials 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 230000000694 effects Effects 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000000356 contaminant Substances 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 238000010791 quenching Methods 0.000 description 1
- 230000000171 quenching effect Effects 0.000 description 1
- 238000007711 solidification Methods 0.000 description 1
- 230000008023 solidification Effects 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C21/00—Alloys based on aluminium
- C22C21/02—Alloys based on aluminium with silicon as the next major constituent
- C22C21/04—Modified aluminium-silicon alloys
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22D—CASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
- B22D21/00—Casting non-ferrous metals or metallic compounds so far as their metallurgical properties are of importance for the casting procedure; Selection of compositions therefor
- B22D21/002—Castings of light metals
- B22D21/007—Castings of light metals with low melting point, e.g. Al 659 degrees C, Mg 650 degrees C
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C21/00—Alloys based on aluminium
- C22C21/02—Alloys based on aluminium with silicon as the next major constituent
Definitions
- the invention relates to an aluminum die-cast alloy and a structural component for a motor vehicle.
- an aluminum alloy for die-casting of components with high elongation in the as-cast state is known. Further compositions for aluminum die-cast alloys are in the EP 1 719 820 A2 , the DE 10 2006 039 684 B4 , the DE 10 2010 055 011 A1 , the EP 2 653 579 A1 , the EP 2 865 773 A1 or the EP 1 443 122 B1 described.
- manganese is partially added to the alloy in order to reduce the tendency to stick to the die and thus improve the demoldability of the finished cast parts.
- the manganese content is typically between 0.3 and 0.8% by weight. If the manganese content is less than 0.3% by weight, there is an increased tendency to stick and a complex casting can no longer be removed from the mold. Such a tendency to stick is not only disruptive to the process and the dimensional accuracy, but also leads to increased wear on the casting tool.
- an excessively high proportion of manganese of more than 0.8% by weight due to the formation of coarse, intermetallic precipitates, causes the material to become brittle and thus a reduction in ductility or deformability.
- Molybdenum is added to the alloy. By adding Molybdenum can counteract the increased tendency to stick by reducing the manganese content.
- Molybdenum as an element is relatively expensive, which increases the cost of such a raw material.
- From the EP 1 443 122 B1 is an aluminum alloy for the die-casting of components with high elongation in the as-cast state.
- the inventors have surprisingly found that a reduction in the molybdenum content such that molybdenum is present in a proportion of 0.001 to 0.048% by weight, in particular 0.001 to 0.043% by weight, in particular 0.024 to 0.043% by weight, and a simultaneous use of chromium promote the reduction of the tendency to stick and the increase in ductility.
- a proportion of molybdenum has also proven to be very suitable with regard to good demoldability and high ductility.
- a proportion of Molybdenum replaced by chromium.
- even very small amounts of chromium are sufficient to achieve a significant effect.
- the following additional optional or facultative alloy components are provided in the aluminum die-cast alloy according to the invention: 0.001 to 0.15% by weight of iron and / or 0.004 to 0.15% by weight of titanium and / or 0.01 to 0, 2% by weight zirconium and / or 0.008 to 0.02% by weight strontium and / or 0.001 to 0.1% by weight vanadium.
- iron as a contaminant element always occurs in small quantities in the alloy, ie the lower the iron content, the more expensive the pure aluminum.
- the silicon content of 7.5 to 11.5% by weight present in the alloy according to the invention ensures sufficient strength and a high mold filling capacity of the aluminum die-cast alloy according to the invention. Furthermore, silicon counteracts solidification voids during cooling.
- the manganese content in the alloy can be reduced to a proportion of 0.25 to 0.6% by weight, which improves the demoldability and result in higher ductility.
- the surprising thing about the alloy composition according to the invention is therefore that small proportions of chromium make it possible to reduce the proportion of molybdenum, which significantly improves both the elongation at break and the demoldability.
- chromium is provided in a proportion of 0.04 to 0.05% by weight, in particular 0.04 to 0.048% by weight, the tendency of the material to stick can be further reduced and the ductility of the same can be optimized.
- manganese is present in a proportion of 0.35 to 0.6% by weight, in particular 0.45 to 0.55% by weight. Such a proportion of manganese has proven to be particularly advantageous with regard to a low tendency to stick.
- a structural component for a motor vehicle, produced from an aluminum die-cast alloy according to the invention, is specified in claim 4.
- Such a structural component can be used for a wide variety of purposes in motor vehicles, since it has the required strength as well as sufficient ductility and good demoldability.
- a very advantageous development of the structural component can consist in that the structural component is designed as a thin-walled strut mount, battery tray or connecting part and is manufactured without heat treatment.
- the aluminum die-cast alloy according to the invention is particularly well suited for the components mentioned; however, it can also be used for other components. By dispensing with heat treatment of the structural component, warping of the same is avoided, so that a high level of accuracy of the components can be achieved.
- the aluminum die-cast alloy according to the invention was used achievable improved demoldability can be clearly demonstrated, as can also be seen in the following table.
- the mechanical parameters, ie the strength and the ductility, were determined on flat tensile specimens with an average wall thickness of 3.5 mm.
- composition of the base alloy used was as follows: AlSi10Fe0.13Mg0.04Ti0.09Zr0.15Sr0.012. alloy composition Yield strength Rp0.2 in MPa Elongation at break A5 in% Demoldability 1 Base + Mn0.66 123 6.7 250 2 Base + Mn0.5 119 8.8 55 3 Base + Mn0.42 115 9.2 7th 4th Base + Mn0.41Mo0.15 124 10.0 40 5 Base + Mn0.55Mo0.10 122 8.5 107 6th Base + Mn0.51Mo0.03Cr0.048 122 10.7 250 7th Base + Mn0.35Mo0.03Cr0.047 121 13.2 250
- Alloy 1 according to the prior art could be demolded very well, but had a very low elongation at break due to the high manganese content.
- the manganese content was reduced, which, however, led to an increased tendency to stick and thus poorer demoldability. Basically, the reduction in the manganese content is also noticeable in a higher elongation at break with a slightly lower yield point.
- Alloys 6 and 7 are two different versions of the aluminum die-cast alloy according to the present invention. Compared to alloys 4 and 5, the molybdenum content was reduced and chromium was also added. As a result, the elongation at break increased to values acceptable for use in motor vehicles and there was a very low tendency to stick and therefore very good demoldability. The strength of the two alloys 6 and 7 is also sufficient for the purpose for which they are intended.
- the table shows the above-described effect of the proportions of molybdenum and chromium used for the properties of the aluminum die-cast alloy.
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Molds, Cores, And Manufacturing Methods Thereof (AREA)
- Body Structure For Vehicles (AREA)
Claims (5)
- Alliage d'aluminium moulé sous pression avec les constituants d'alliage suivants :7,5 à 11,5 % en poids de silicium,0,25 à 0,6 % en poids de manganèse,0,03 à 0,06 % en poids de chrome,0,001 à 0,048 % en poids, en particulier 0,001 à 0,043 % en poids, en particulier 0,024 à 0,043 % en poids, de molybdène,0,001 à 0,08 % en poids de magnésium,facultativement 0,001 à 0,15 % en poids de fer,facultativement 0,004 à 0,15 % en poids de titane,facultativement 0,01 à 0,2 % en poids de zirconium,facultativement 0,008 à 0,02 % en poids de strontium,facultativement 0,001 à 0,1 % en poids de vanadium,le reste étant de l'aluminium et des impuretés inévitables.
- Alliage d'aluminium moulé sous pression selon la revendication 1,
caractérisé par
0,04 à 0,05 % en poids, en particulier 0,04 à 0,048 % en poids, de chrome. - Alliage d'aluminium moulé sous pression selon la revendication 1 ou 2,
caractérisé par
0,35 à 0,6 % en poids, en particulier 0,45 à 0,55 % en poids, de manganèse. - Composant de structure pour un véhicule automobile, fabriqué à partir d'un alliage d'aluminium moulé sous pression selon l'une quelconque des revendications 1 à 3.
- Composant de structure selon la revendication 4,
caractérisé en ce que
le composant de structure est réalisé en tant que logement de jambe de suspension à paroi mince, bac à batterie ou pièce de connexion et est fabriqué sans traitement thermique.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE102019205267.3A DE102019205267B3 (de) | 2019-04-11 | 2019-04-11 | Aluminium-Druckgusslegierung |
PCT/EP2020/057086 WO2020207708A1 (fr) | 2019-04-11 | 2020-03-16 | Alliage d'aluminium pour coulée sous pression |
Publications (2)
Publication Number | Publication Date |
---|---|
EP3775309A1 EP3775309A1 (fr) | 2021-02-17 |
EP3775309B1 true EP3775309B1 (fr) | 2021-12-15 |
Family
ID=69845424
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP20711910.8A Active EP3775309B1 (fr) | 2019-04-11 | 2020-03-16 | Alliage d'aluminium pour coulée sous pression |
Country Status (4)
Country | Link |
---|---|
EP (1) | EP3775309B1 (fr) |
DE (1) | DE102019205267B3 (fr) |
ES (1) | ES2904262T3 (fr) |
WO (1) | WO2020207708A1 (fr) |
Families Citing this family (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE102021114484A1 (de) | 2021-06-07 | 2022-12-08 | Audi Aktiengesellschaft | Aluminium-Gusslegierung |
DE102021131973A1 (de) | 2021-12-03 | 2023-06-07 | Audi Aktiengesellschaft | Aluminium-Druckgusslegierung |
DE102021131935A1 (de) | 2021-12-03 | 2023-06-07 | Audi Aktiengesellschaft | Aluminium-Druckgusslegierung |
Family Cites Families (13)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DD281718A7 (de) * | 1984-02-09 | 1990-08-22 | Dmi | Aluminiumgusslegierung |
AT404844B (de) * | 1997-03-03 | 1999-03-25 | Aluminium Lend Gmbh | Druckgusslegierung |
US20050161128A1 (en) * | 2002-03-19 | 2005-07-28 | Dasgupta Rathindra | Aluminum alloy |
DE502004009801D1 (de) * | 2003-01-23 | 2009-09-10 | Rheinfelden Aluminium Gmbh | Druckgusslegierung aus Aluminiumlegierung |
EP1719820A3 (fr) * | 2005-05-03 | 2006-12-27 | ALUMINIUM RHEINFELDEN GmbH | Alliage d' aluminium coulé |
DE102006039684B4 (de) * | 2006-08-24 | 2008-08-07 | Audi Ag | Aluminium-Sicherheitsbauteil |
DE102009012073B4 (de) * | 2009-03-06 | 2019-08-14 | Andreas Barth | Verwendung einer Aluminiumgusslegierung |
DE102010055011A1 (de) * | 2010-12-17 | 2012-06-21 | Trimet Aluminium Ag | Gut gießbare, duktile AlSi-Legierung und Verfahren zur Herstellung eines Gussteils unter Verwendung der AlSi-Gusslegierung |
EP2471967B1 (fr) * | 2010-12-28 | 2014-07-09 | Casa Maristas Azterlan | Procédé pour obtenir des propriétés mécaniques améliorées dans des moulages d'aluminium recyclés dépourvus de phases bêta en forme de plaquettes |
EP2653579B1 (fr) * | 2012-04-17 | 2014-10-15 | Georg Fischer Druckguss GmbH & Co. KG | Alliage d'aluminium |
EP2735621B1 (fr) * | 2012-11-21 | 2015-08-12 | Georg Fischer Druckguss GmbH & Co. KG | Alliage à coulée sous pression en aluminium |
ES2582529T3 (es) * | 2013-10-23 | 2016-09-13 | Befesa Aluminio, S.L. | Aleación de aluminio para fundición |
DE102016004216A1 (de) * | 2016-04-07 | 2016-09-29 | Daimler Ag | Aluminiumlegierung, insbesondere für ein Gießverfahren, sowie Verfahren zum Herstellen eines Bauteils aus einer solchen Aluminiumlegierung |
-
2019
- 2019-04-11 DE DE102019205267.3A patent/DE102019205267B3/de active Active
-
2020
- 2020-03-16 WO PCT/EP2020/057086 patent/WO2020207708A1/fr unknown
- 2020-03-16 EP EP20711910.8A patent/EP3775309B1/fr active Active
- 2020-03-16 ES ES20711910T patent/ES2904262T3/es active Active
Also Published As
Publication number | Publication date |
---|---|
WO2020207708A1 (fr) | 2020-10-15 |
DE102019205267B3 (de) | 2020-09-03 |
EP3775309A1 (fr) | 2021-02-17 |
ES2904262T3 (es) | 2022-04-04 |
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