EP3766614A1 - Outil de coupe à surface revêtue et son procédé de fabrication - Google Patents

Outil de coupe à surface revêtue et son procédé de fabrication Download PDF

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Publication number
EP3766614A1
EP3766614A1 EP18909974.0A EP18909974A EP3766614A1 EP 3766614 A1 EP3766614 A1 EP 3766614A1 EP 18909974 A EP18909974 A EP 18909974A EP 3766614 A1 EP3766614 A1 EP 3766614A1
Authority
EP
European Patent Office
Prior art keywords
face
region
ticn layer
plane
flank
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
EP18909974.0A
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German (de)
English (en)
Other versions
EP3766614A4 (fr
Inventor
Satoshi Ono
Shinya Imamura
Susumu Okuno
Anongsack Paseuth
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Sumitomo Electric Hardmetal Corp
Original Assignee
Sumitomo Electric Hardmetal Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Sumitomo Electric Hardmetal Corp filed Critical Sumitomo Electric Hardmetal Corp
Publication of EP3766614A1 publication Critical patent/EP3766614A1/fr
Publication of EP3766614A4 publication Critical patent/EP3766614A4/fr
Pending legal-status Critical Current

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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B23—MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
    • B23B—TURNING; BORING
    • B23B27/00—Tools for turning or boring machines; Tools of a similar kind in general; Accessories therefor
    • B23B27/14—Cutting tools of which the bits or tips or cutting inserts are of special material
    • B23B27/148—Composition of the cutting inserts
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B23—MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
    • B23B—TURNING; BORING
    • B23B51/00—Tools for drilling machines
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B23—MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
    • B23C—MILLING
    • B23C5/00—Milling-cutters
    • B23C5/16—Milling-cutters characterised by physical features other than shape
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B23—MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
    • B23P—METAL-WORKING NOT OTHERWISE PROVIDED FOR; COMBINED OPERATIONS; UNIVERSAL MACHINE TOOLS
    • B23P15/00—Making specific metal objects by operations not covered by a single other subclass or a group in this subclass
    • B23P15/28—Making specific metal objects by operations not covered by a single other subclass or a group in this subclass cutting tools
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B24—GRINDING; POLISHING
    • B24C—ABRASIVE OR RELATED BLASTING WITH PARTICULATE MATERIAL
    • B24C1/00—Methods for use of abrasive blasting for producing particular effects; Use of auxiliary equipment in connection with such methods
    • B24C1/10—Methods for use of abrasive blasting for producing particular effects; Use of auxiliary equipment in connection with such methods for compacting surfaces, e.g. shot-peening
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C16/00—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes
    • C23C16/04—Coating on selected surface areas, e.g. using masks
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C16/00—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes
    • C23C16/22—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes characterised by the deposition of inorganic material, other than metallic material
    • C23C16/30—Deposition of compounds, mixtures or solid solutions, e.g. borides, carbides, nitrides
    • C23C16/36—Carbonitrides
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C16/00—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes
    • C23C16/44—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes characterised by the method of coating
    • C23C16/455—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes characterised by the method of coating characterised by the method used for introducing gases into reaction chamber or for modifying gas flows in reaction chamber
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C16/00—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes
    • C23C16/44—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes characterised by the method of coating
    • C23C16/455—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes characterised by the method of coating characterised by the method used for introducing gases into reaction chamber or for modifying gas flows in reaction chamber
    • C23C16/45523—Pulsed gas flow or change of composition over time
    • C23C16/45525—Atomic layer deposition [ALD]
    • C23C16/45527—Atomic layer deposition [ALD] characterized by the ALD cycle, e.g. different flows or temperatures during half-reactions, unusual pulsing sequence, use of precursor mixtures or auxiliary reactants or activations
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C16/00—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes
    • C23C16/44—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes characterised by the method of coating
    • C23C16/455—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes characterised by the method of coating characterised by the method used for introducing gases into reaction chamber or for modifying gas flows in reaction chamber
    • C23C16/45523—Pulsed gas flow or change of composition over time
    • C23C16/45525—Atomic layer deposition [ALD]
    • C23C16/45527—Atomic layer deposition [ALD] characterized by the ALD cycle, e.g. different flows or temperatures during half-reactions, unusual pulsing sequence, use of precursor mixtures or auxiliary reactants or activations
    • C23C16/45531—Atomic layer deposition [ALD] characterized by the ALD cycle, e.g. different flows or temperatures during half-reactions, unusual pulsing sequence, use of precursor mixtures or auxiliary reactants or activations specially adapted for making ternary or higher compositions
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C16/00—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes
    • C23C16/44—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes characterised by the method of coating
    • C23C16/455—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes characterised by the method of coating characterised by the method used for introducing gases into reaction chamber or for modifying gas flows in reaction chamber
    • C23C16/45523—Pulsed gas flow or change of composition over time
    • C23C16/45525—Atomic layer deposition [ALD]
    • C23C16/45555—Atomic layer deposition [ALD] applied in non-semiconductor technology
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C28/00—Coating for obtaining at least two superposed coatings either by methods not provided for in a single one of groups C23C2/00 - C23C26/00 or by combinations of methods provided for in subclasses C23C and C25C or C25D
    • C23C28/04—Coating for obtaining at least two superposed coatings either by methods not provided for in a single one of groups C23C2/00 - C23C26/00 or by combinations of methods provided for in subclasses C23C and C25C or C25D only coatings of inorganic non-metallic material
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C28/00—Coating for obtaining at least two superposed coatings either by methods not provided for in a single one of groups C23C2/00 - C23C26/00 or by combinations of methods provided for in subclasses C23C and C25C or C25D
    • C23C28/04—Coating for obtaining at least two superposed coatings either by methods not provided for in a single one of groups C23C2/00 - C23C26/00 or by combinations of methods provided for in subclasses C23C and C25C or C25D only coatings of inorganic non-metallic material
    • C23C28/042—Coating for obtaining at least two superposed coatings either by methods not provided for in a single one of groups C23C2/00 - C23C26/00 or by combinations of methods provided for in subclasses C23C and C25C or C25D only coatings of inorganic non-metallic material including a refractory ceramic layer, e.g. refractory metal oxides, ZrO2, rare earth oxides
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C28/00—Coating for obtaining at least two superposed coatings either by methods not provided for in a single one of groups C23C2/00 - C23C26/00 or by combinations of methods provided for in subclasses C23C and C25C or C25D
    • C23C28/04—Coating for obtaining at least two superposed coatings either by methods not provided for in a single one of groups C23C2/00 - C23C26/00 or by combinations of methods provided for in subclasses C23C and C25C or C25D only coatings of inorganic non-metallic material
    • C23C28/044—Coating for obtaining at least two superposed coatings either by methods not provided for in a single one of groups C23C2/00 - C23C26/00 or by combinations of methods provided for in subclasses C23C and C25C or C25D only coatings of inorganic non-metallic material coatings specially adapted for cutting tools or wear applications
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C30/00—Coating with metallic material characterised only by the composition of the metallic material, i.e. not characterised by the coating process
    • C23C30/005—Coating with metallic material characterised only by the composition of the metallic material, i.e. not characterised by the coating process on hard metal substrates
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B23—MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
    • B23B—TURNING; BORING
    • B23B2200/00—Details of cutting inserts
    • B23B2200/24—Cross section of the cutting edge
    • B23B2200/242—Cross section of the cutting edge bevelled or chamfered
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B23—MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
    • B23B—TURNING; BORING
    • B23B2200/00—Details of cutting inserts
    • B23B2200/24—Cross section of the cutting edge
    • B23B2200/245—Cross section of the cutting edge rounded
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B23—MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
    • B23B—TURNING; BORING
    • B23B2200/00—Details of cutting inserts
    • B23B2200/24—Cross section of the cutting edge
    • B23B2200/247—Cross section of the cutting edge sharp
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B23—MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
    • B23B—TURNING; BORING
    • B23B2222/00—Materials of tools or workpieces composed of metals, alloys or metal matrices
    • B23B2222/28—Details of hard metal, i.e. cemented carbide
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B23—MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
    • B23B—TURNING; BORING
    • B23B2224/00—Materials of tools or workpieces composed of a compound including a metal
    • B23B2224/04—Aluminium oxide
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B23—MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
    • B23B—TURNING; BORING
    • B23B2224/00—Materials of tools or workpieces composed of a compound including a metal
    • B23B2224/32—Titanium carbide nitride (TiCN)
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B23—MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
    • B23B—TURNING; BORING
    • B23B2228/00—Properties of materials of tools or workpieces, materials of tools or workpieces applied in a specific manner
    • B23B2228/04—Properties of materials of tools or workpieces, materials of tools or workpieces applied in a specific manner applied by chemical vapour deposition [CVD]
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B23—MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
    • B23B—TURNING; BORING
    • B23B2228/00—Properties of materials of tools or workpieces, materials of tools or workpieces applied in a specific manner
    • B23B2228/10—Coatings
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B23—MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
    • B23B—TURNING; BORING
    • B23B2228/00—Properties of materials of tools or workpieces, materials of tools or workpieces applied in a specific manner
    • B23B2228/10—Coatings
    • B23B2228/105—Coatings with specified thickness
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B23—MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
    • B23B—TURNING; BORING
    • B23B2228/00—Properties of materials of tools or workpieces, materials of tools or workpieces applied in a specific manner
    • B23B2228/36—Multi-layered
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B23—MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
    • B23B—TURNING; BORING
    • B23B27/00—Tools for turning or boring machines; Tools of a similar kind in general; Accessories therefor
    • B23B27/14—Cutting tools of which the bits or tips or cutting inserts are of special material
    • B23B27/141—Specially shaped plate-like cutting inserts, i.e. length greater or equal to width, width greater than or equal to thickness
    • B23B27/145—Specially shaped plate-like cutting inserts, i.e. length greater or equal to width, width greater than or equal to thickness characterised by having a special shape

Definitions

  • the present disclosure relates to a surface-coated cutting tool and a method of manufacturing the same.
  • the present application claims the priority of Japanese Patent Application No. 2018-049285 filed on March 16, 2018 , the entire contents of which are hereby incorporated by reference.
  • Japanese Patent Laying-Open No. 06-158325 (PTL 1) and Japanese Patent Laying-Open No. 11-124672 (PTL 2) each disclose a cutting tool including a base material and a coating formed on a surface of the base material.
  • a surface-coated cutting tool is a surface-coated cutting tool including a base material and a coating covering the base material, wherein the base material includes a rake face and a flank face, the coating includes a TiCN layer, the TiCN layer has a (422) orientation in a region d1 in the rake face, the TiCN layer has a (311) orientation in a region d2 in the flank face, when the rake face and the flank face are continuous with each other with a cutting edge face therebetween,
  • a method of manufacturing a surface-coated cutting tool according to the present disclosure is a method of manufacturing the surface-coated cutting tool described above, the method including:
  • the performance (e.g., chipping resistance or wear resistance) of a cutting tool is improved by providing a hard coating on a surface of a base material.
  • a rake face and a flank face of the cutting tool are desired to have different performance, the rake face and the flank face are provided with coatings of the same quality in the cutting tools described in PTL 1 and PTL 2.
  • the performance of the flank face may be insufficient. Under such circumstances, the cutting tool having a coating provided on its surface is desired to be improved further.
  • the present disclosure has been made in view of the above circumstances, and has an object to provide a surface-coated cutting tool having excellent chipping resistance and also having excellent crater wear resistance in high-speed machining, and a method of manufacturing the same.
  • a surface-coated cutting tool having excellent chipping resistance and also having excellent crater wear resistance in high-speed machining, and a method of manufacturing the same can be provided.
  • an equation in the form of "A to B" means a range's upper and lower limits (that is, not less than A and not greater than B), and when A is not accompanied by any unit and B alone is accompanied by a unit, A has the same unit as B.
  • composition formula (chemical formula) when a compound is represented by a composition formula (chemical formula) with its constituent element ratio unspecified, such as "TiC," the composition formula (or chemical formula) shall encompass any conventionally known composition (element ratio).
  • the composition formula (chemical formula) shall include not only a stoichiometric composition but also a nonstoichiometric composition.
  • the composition formula (chemical formula) of "TiC” includes not only a stoichiometric composition "Ti 1 C 1 " but also a nonstoichiometric composition, for example, "Ti 1 C 0.8 .” Compounds other than "TiC" are also similarly described.
  • a surface-coated cutting tool is a surface-coated cutting tool including a base material and a coating covering the base material, wherein the base material includes a rake face and a flank face, the coating includes a TiCN layer, the TiCN layer has a (422) orientation in a region d1 in the rake face, the TiCN layer has a (311) orientation in a region d2 in the flank face, when the rake face and the flank face are continuous with each other with a cutting edge face therebetween,
  • the surface-coated cutting tool of the present embodiment includes a base material and a coating that covers the base material (hereinbelow, also merely referred to as a "cutting tool").
  • the cutting tool can be, for example, a drill, an end mill, an indexable insert for drill, an indexable insert for end mill, an indexable insert for milling, an indexable insert for turning, a metal-slitting saw, a gear-cutting tool, a reamer, or a tap.
  • the base material of the present embodiment may be any conventionally known base material of this type.
  • the base material preferably includes one selected from the group consisting of cemented carbide (e.g., tungsten carbide (WC)-based cemented carbide, cemented carbide containing Co in addition to WC, cemented carbide containing WC and additionally containing carbonitride of Cr, Ti, Ta, Nb, or the like), cermet (mainly containing TiC, TiN, TiCN, or the like), high-speed steel, ceramic (e.g., titanium carbide, silicon carbide, silicon nitride, aluminium nitride, or aluminium oxide), cubic boron nitride sintered body (cBN sintered body), and diamond sintered body, and more preferably includes one selected from the group consisting of cemented carbide, cermet, and cBN sintered body.
  • cemented carbide e.g., tungsten carbide (WC)-based cemented carbide, cemented carbide containing Co in addition
  • WC-based cemented carbide or cermet is preferably selected among these types of base materials. This is because these base materials particularly have an excellent balance between hardness and strength at high temperatures and have excellent characteristics as a base material of the surface-coated cutting tool for the above application purpose.
  • the base material when the base material is cemented carbide, the base material preferably contains cobalt in an amount of not less than 7 mass% and not greater than 12 mass%, more preferably contains cobalt in an amount of not less than 8 mass% and not greater than 11 mass%, and still more preferably contains cobalt in an amount of not less than 9 mass% and not greater than 10.5 mass% relative to a total mass of the base material.
  • the content ratio of cobalt can be determined by, for example, titration.
  • the base material has a rake face and a flank face.
  • the "rake face” means a face that rakes chips chipped from a workpiece material.
  • the "flank face” means a face, part of which is in contact with the workpiece material.
  • Base materials are categorized into the following two cases: a “case in which the rake face and the flank face are continuous with each other with a cutting edge face therebetween," and a “case in which the rake face and the flank face are continuous with each other with a ridge line therebetween.” This will be described below with reference to Figs. 1 to 6 .
  • Fig. 1 is a perspective view illustrating an aspect of a cutting tool
  • Fig. 2 is a sectional view taken along a line X-X in Fig. 1 .
  • the cutting tool having such a shape is used as an indexable insert for turning.
  • a cutting tool 10 shown in Figs. 1 and 2 has surfaces including an upper surface, a lower surface, and four lateral surfaces, and has a shape of a quadrangular prism which has a somewhat low vertical profile in its entirety.
  • Cutting tool 10 also has a through hole passing through its upper and lower surfaces, and the adjacent lateral surfaces are connected to each other by an arc face at each of boundaries of the four lateral surfaces.
  • the upper surface and the lower surface form rake faces 1a
  • the four lateral surfaces (and the arc faces connecting these lateral surfaces to each other) form flank faces 1b
  • the arc faces each connecting rake face 1a to flank face 1b form cutting edge faces 1c.
  • Fig. 3 is a partially enlarged view of Fig. 2 .
  • Fig. 3 shows an imaginary plane A, a boundary AA, an imaginary plane B, a boundary BB, and an imaginary ridge line AB'.
  • Imaginary plane A corresponds to a face obtained by extending rake face 1a.
  • Boundary AA is a boundary between rake face 1a and cutting edge face 1c.
  • Imaginary plane B corresponds to a face obtained by extending flank face 1b.
  • Boundary BB is a boundary between flank face 1b and cutting edge face 1c.
  • Imaginary ridge line AB' is an intersection between the face (imaginary plane A) obtained by extending rake face 1a and the face (imaginary plane B) obtained by extending flank face 1b, and imaginary plane A and imaginary plane B intersect each other to define imaginary ridge line AB'.
  • cutting edge face 1c is an arc face (horning).
  • Rake face 1a and flank face 1b are continuous with each other with cutting edge face 1c therebetween, and cutting edge face 1c and portions of rake face 1a and flank face 1b, which are adjacent to cutting edge face 1c, form the cutting edge portion of cutting tool 10.
  • imaginary plane A and imaginary plane B are each shown in the form of a line
  • boundary AA, boundary BB, and imaginary ridge line AB' are each shown in the form of a point.
  • Figs. 1 to 3 show the case in which cutting edge face 1c is an arc face (horning), the shape of cutting edge face 1c is not limited thereto.
  • cutting edge face 1c may have a plane shape (negative land).
  • Fig. 5 cutting edge face 1c may have a shape (a shape combining horning and negative land) including both of a plane and an arc face.
  • rake face 1a and flank face 1b are continuous with each other with cutting edge face 1c therebetween, and imaginary plane A, boundary AA, imaginary plane B, boundary BB, and imaginary ridge line AB' are defined.
  • cutting edge face 1c can be determined from its shape alone. This is because cutting edge face 1c in this case is not included in imaginary plane A or imaginary plane B, and accordingly can be visually differentiated from rake face 1a and flank face 1b.
  • Cutting edge face 1c is typically a surface of base material 1 and may include a face formed by mechanically machining the edges of intersecting faces.
  • base material 1 is obtained by mechanically machining at least part of the surface of a base material precursor formed of, for example, a sintered body, and cutting edge face 1c may include a face formed by chamfering through mechanical machining.
  • base material 1 has a sharp edge shape as shown in Fig. 6 is included in the "case in which the rake face and the flank face are continuous with each other with a ridge line therebetween.”
  • rake face 1a and flank face 1b are adjacent to each other, the boundary between rake face 1a and flank face 1b defines ridge line AB, and ridge line AB and portions of rake face 1a and flank face 1b, which are adjacent to ridge line AB, form the cutting edge portion of cutting tool 10.
  • the shape of and the names of the portions of base material 1 have been described with reference to Figs. 1 to 6 , the shape and the names of the portions which correspond to those of the above base material are used similarly for the surface-coated cutting tool according to the present embodiment. That is to say, the surface-coated cutting tool has a rake face and a flank face.
  • a “coating” according to the present embodiment means a film covering at least part of the rake face and at least part of the flank face in the base material. Even when the structure of the base material partially differs in part of the base material, it is within the scope of the present embodiment.
  • the thickness of the coating is preferably not less than 6.5 ⁇ m and not greater than 14 ⁇ m, and is more preferably not less than 8 ⁇ m and not greater than 11 ⁇ m.
  • the thickness of the coating means a total of the thicknesses of layers constituting a coating, such as a TiCN layer, an Al 2 O 3 layer, and any other layer described below.
  • the thickness of the coating can be measured by, for example, measuring a cross section of the surface-coated cutting tool at a 1000-fold magnification using an optical microscope. Specifically, the thickness can be obtained by measuring any three points in the cross section and taking an average value of the thicknesses of the measured three points. The same holds true for the measurement of the respective thicknesses of the TiCN layer, the Al 2 O 3 layer, and any other layer described below.
  • the coating includes a TiCN layer.
  • the "TiCN layer” means a layer made of TiCN.
  • the TiCN layer may contain inevitable impurities to such an extent that the effects achieved by the surface-coated cutting tool according to the present embodiment are not impaired. The same holds true for "any other layer” described below.
  • the thickness of the TiCN layer is preferably not less than 6 ⁇ m and not greater than 10 ⁇ m, and is more preferably not less than 7 ⁇ m and not greater than 9 ⁇ m.
  • the thickness of the TiCN layer can be measured by, for example, measuring a cross section of the surface-coated cutting tool at a 1000-fold magnification using an optical microscope.
  • the coating may further include any other layer to such an extent that the effects of the present embodiment are not impaired.
  • any other layer include a TiN layer, a TiBNO layer, a TiCNO layer, a TiB2 layer, a TiAIN layer, a TiAlCN layer, a TiAlON layer, a TiAlONC layer, and an Al 2 O 3 layer.
  • the order of stacking these layers is not particularly limited. That is to say, the TiCN layer may be an outermost layer in the coating.
  • an Al 2 O 3 layer may be provided on the TiCN layer.
  • the description "an Al 2 O 3 layer is provided on the TiCN layer” means that an Al 2 O 3 layer is merely required to be provided over the TiCN layer, and does not require a contact between these layers. In other words, any other layer may be provided between the TiCN layer and the Al 2 O 3 layer.
  • an Al 2 O 3 layer may be provided directly on the TiCN layer.
  • the thickness of the Al 2 O 3 layer is preferably not less than 0.5 ⁇ m and not greater than 4 ⁇ m, is more preferably not less than 0.5 ⁇ m and not greater than 3 ⁇ m, and is still more preferably not less than 1 ⁇ m and not greater than 2 ⁇ m.
  • the thickness of the Al 2 O 3 layer can be measured by, for example, measuring a cross section of the surface-coated cutting tool at a 1000-fold magnification using an optical microscope.
  • the TiCN layer has a (422) orientation in region d1 in rake face 1a.
  • region d1 is a "region sandwiched between imaginary line D1, which is 500 ⁇ m apart from imaginary ridge line AB' on rake face 1a, and boundary AA between rake face 1a and cutting edge face 1c.”
  • region d1 is a "region sandwiched between ridge line AB and imaginary line D1 which is 500 ⁇ m apart from ridge line AB on rake face 1a.”
  • the TiCN layer may have a (422) orientation in a region which is in the rake face and is other than region d1, in addition to region d1.
  • the TiCN layer may have a (422) orientation in the entire rake face.
  • TiCN layer has a (422) orientation means that, among texture coefficients TC (hkl) defined by the following equation (1), a texture coefficient TC (422) of the (422) plane in the TiCN layer is greater than the texture coefficient of any other crystal orientation plane. In other words, it means that texture coefficient TC (422) is greatest among the texture coefficients of other crystal orientation planes.
  • I(hkl) and I(h x k y l z ) represent a measured diffraction intensity of a (hkl) plane and a measured diffraction intensity of a (h x k y l z ) plane, respectively.
  • I o (hkl) represents an average value of a powder diffraction intensity of TiC (card No. 32-1383) in a (hkl) plane and a powder diffraction intensity of TiN (card No. 38-1420) in a (hkl) plane according to the Joint Committee on Powder Diffraction Standard database (JCPDS database).
  • I o (h x k y l z ) represents an average value of a powder diffraction intensity of TiC (card No. 32-1383) in a (h x k y l z ) plane and a powder diffraction intensity of TiN (card No.
  • Texture coefficient TC (hkl) can be obtained by, for example, X-ray diffraction measurement performed under the following conditions. Specifically, when base material 1 (i.e., cutting tool 10) has a sharp edge shape as shown in Fig. 6 , any three points in region d1 sandwiched between ridge line AB and imaginary line D1 which is 500 ⁇ m apart from ridge line AB are subjected to X-ray diffraction measurement, and an average value of texture coefficients of a (hkl) plane obtained at these three points according to equation (1) above is taken as a texture coefficient TC (hkl) in region d1 of rake face 1a ( Fig. 7 ). Although three points on imaginary line D1 are selected in Fig.
  • any three points can be selected as long as they are located in region d1.
  • any three points in region d1 sandwiched between boundary AA and imaginary line D1 are subjected to X-ray diffraction measurement, and an average value of the texture coefficients of the (hkl) plane obtained at these three points is taken as a texture coefficient TC (hkl) in region d1 of the rake face.
  • TC rake (hkl) the texture coefficient in region d1 of the rake face.
  • X-ray output 45kV, 200 mA X-ray source, wavelength CuK ⁇ , 1.541862 ⁇ Detector D/teX Ultra 250 Axis of scan 2 ⁇ / ⁇ Longitudinal limiting slit width 2.0 mm Scan mode CONTINUOUS Scan speed 20°/min
  • the diffraction intensity of X rays is calculated according to integrated intensity measurement.
  • the (422) texture coefficient in region d1 of the rake face is preferably not less than 3 and is more preferably not less than 4.
  • the TiCN layer has a (311) orientation in region d2 in flank face 1b.
  • region d2 is a "region sandwiched between imaginary line D2, which is 500 ⁇ m apart from imaginary ridge line AB' on flank face 1b, and boundary BB between flank face 1b and cutting edge face 1c.”
  • region d2 is a "region sandwiched between ridge line AB and imaginary line D2 which is 500 ⁇ m apart from ridge line AB on flank face 1b.”
  • the TiCN layer may have a (311) orientation in a region which is in the flank surface and is other than region d2, in addition to region d2.
  • the TiCN layer may have a (311) orientation in the entire flank face.
  • the TiCN layer has a (311) orientation means that, among the texture coefficients TC (hkl) defined by equation (1) above, texture coefficient TC (311) of the (311) plane in the TiCN layer is greater than the texture coefficient of any other crystal orientation plane. In other words, it means that texture coefficient TC (311) is greatest among the texture coefficients of other crystal orientation planes. Texture coefficient TC (hkl) described above can be obtained by a method similar to a method described in ⁇ Orientation of TiCN Layer in Region d1 of Rake Face> above.
  • region d2 is a "region sandwiched between imaginary line D2, which is 500 ⁇ m apart from imaginary ridge line AB' on flank face 1b, and boundary BB between flank face 1b and cutting edge face 1c.”
  • region d2 is a "region sandwiched between ridge line AB and imaginary line D2 which is 500 ⁇ m apart from ridge line AB on flank face 1b.”
  • TC flank (hkl) the texture coefficient in region d2 of the flank face
  • TC flank (hkl) the texture coefficient in region d2 of the flank face
  • the (311) texture coefficient in region d2 of the flank face is preferably not less than 3 and is more preferably not less than 4.
  • a ratio TC flank (311)/TC flank (422) of the (311) texture coefficient to the (422) texture coefficient in region d2 of the flank face is preferably greater than 1, is more preferably not less than 1.2, and is still more preferably not less than 1.5.
  • TC flank (311)/ TC flank (422) is determined to be greater than 1.
  • TC flank (311)/ TC flank (422), which is greater than 1, achieves the effects according to the present embodiment.
  • ratio TC flank (422)/TC rake (422) of the (422) texture coefficient in region d2 of the flank face to the (422) texture coefficient in region d1 of the rake face is preferably not greater than 1, is more preferably not greater than 0.8, and is still more preferably not greater than 0.7.
  • TC flank (422)/ TC rake (422), which is not greater than 1, achieves the effects according to the present embodiment.
  • a method of manufacturing a surface-coated cutting tool according to the present embodiment is a method of manufacturing the above surface-coated cutting tool, the method including:
  • the base material is prepared.
  • the base material may be any base material which has been conventionally known as the base material of this type as described above.
  • the base material is made of cemented carbide
  • raw material powder having a mix composition (mass%) shown in Table 1 described below is mixed uniformly using a commercially available attritor, and then, this powder mixture is compression-molded into a predetermined shape (e.g., CNMG120408NUX).
  • a compact of the raw material powder is sintered at 1300°C to 1500°C or lower temperature for one to two hours in a predetermined sintering furnace, thereby obtaining the base material made of cemented carbide.
  • At least part of the rake face and at least part of the flank face are covered with a TiCN layer.
  • rake face is a region in rake face 1a and includes region d1 sandwiched between ridge line AB, which is an intersection between rake face 1a and flank face 1b, and imaginary line D1 which is 500 ⁇ m apart from ridge line AB (e.g., Fig. 6 ).
  • flank face is a region in flank face 1b and includes region d2 sandwiched between ridge line AB, which is an intersection between rake face 1a and flank face 1b, and imaginary line D2 which is 500 ⁇ m apart from ridge line AB (e.g., Fig. 6 ).
  • "at least part of the rake face” is a region in rake face 1a and includes region d1 sandwiched between boundary AA between rake face 1a and cutting edge face 1c and imaginary line D1 which is 500 ⁇ m apart from imaginary ridge line AB' which is an intersection between imaginary plane A including rake face 1a and imaginary plane B including flank face 1b (e.g., Figs. 3 to 5 ).
  • "at least part of the flank face” is a region in flank face 1b and includes region d2 sandwiched between boundary BB between flank face 1b and cutting edge face 1c and imaginary line D2 which is 500 ⁇ m apart from imaginary ridge line AB' (e.g., Figs. 3 to 5 ).
  • the method of covering at least part of the rake face and at least part of the flank face with the TiCN layer is performed by chemical vapor deposition (CVD), and includes discontinuously supplying a source gas of the TiCN layer to form the TiCN layer. That is to say, the TiCN layer covering step is performed by chemical vapor deposition and includes discontinuously supplying a source gas of the TiCN layer.
  • CVD chemical vapor deposition
  • TiCl 4 , CH 3 CN, N 2 , and H 2 are used as the source gas.
  • mixing amounts are as follows: TiCl 4 is in an amount of 2 to 10 vol%, CH 3 CN is in an amount of 0.4 to 2.5 vol%, N 2 is in an amount of 15 vol%, and the remainder is H 2 .
  • the temperature in the reaction chamber during reaction by CVD is preferably 800°C to 850°C.
  • the pressure in the reaction chamber during reaction by CVD is preferably 6 kPa to 7 kPa and is more preferably 6 kPa to 6.7 kPa.
  • a total gas flow rate during reaction by CVD is preferably 80 L/min to 120 L/min and is more preferably 80 L/min to 100 L/min.
  • An example of the method of discontinuously supplying a source gas is alternately supplying a source gas and a H 2 gas (100 vol%) per predetermined period of time. More specifically, supply of the source gas is stopped every time the source gas has been supplied for 15 minutes, and the H2 gas of an equal volume to that of the source gas is supplied for one minute. Consequently, TiCN is subjected to atomization, which makes it possible to form a TiCN layer that is more likely to change to have a (311) orientation by peening.
  • Any other layer such as an Al 2 O 3 layer may be stacked after the formation of the TiCN layer.
  • the TiCN layer in the flank face is peened.
  • "Peening” means a process of colliding (projecting) a host of small spherical bodies (media) of steel, nonferrous metal, or the like against the surface of a flank face or the like at high speed to change the properties of the surface such as orientation and compressive stress.
  • peening of the flank face reduces the ratio of the (422) plane and increases the ratio of the (311) plane in the TiCN layer of the flank face. Consequently, the TiCN layer has improved toughness and has excellent chipping resistance.
  • the media can be projected in any manner as long as the orientation of the TiCN layer changes, and may be projected directly onto the TiCN layer or projected onto any other layer (e.g., Al 2 O 3 layer) provided on the TiCN layer.
  • the media can be projected in any manner as long as it is projected onto region d2 of the flank face, and for example, the media may be projected onto the entire flank face.
  • the distance between the projection unit that projects the media and the surface of the flank face or the like (hereinbelow, also referred to as a "projection distance") is preferably 80 mm to 120 mm and is more preferably 80 mm 100 mm.
  • the pressure applied to the media in projection (hereinbelow, also referred to as a "projection pressure”) is preferably 0.1 MPa to 0.5 MPa and is more preferably 0.1 MPa to 0.3 MPa.
  • the process time of peening is preferably 10 seconds to 60 seconds and is more preferably 10 seconds to 30 seconds.
  • an additional step may be performed appropriately in addition to the steps described above to such an extent that the effects of peening are not impaired.
  • the present embodiment preferably further includes an Al 2 O 3 layer stacking step of stacking the Al 2 O 3 layer on the TiCN layer after the TiCN layer covering step or the peening step.
  • the layer can be stacked as follows. First, AlCl 3 , HCl, CO 2 , H 2 S, and H 2 are used as a source gas.
  • AlCl 3 is in an amount of 1.6 vol%
  • HCl is in an amount of 3.5 vol%
  • CO 2 is in an amount of 4.5 vol%
  • H 2 S is in an amount of 0.2 vol%
  • the remainder is H 2 .
  • the conditions of CVD at this time may be a temperature of 1000°C, a pressure of 6.7 kPa, and a gas flow rate (total gas amount) of 56.3 L/min.
  • this layer may be formed by a conventional method.
  • a surface-coated cutting tool including a base material and a coating covering the base material, wherein the base material includes a rake face, a flank face, and a cutting edge portion connecting the rake face and the flank face to each other, the coating includes a TiCN layer, the TiCN layer has a (422) orientation in a region d1, the region d1 being a region in the rake face and being sandwiched between a ridge line and an imaginary line D1, the ridge line being an intersection between the rake face and the flank face, the imaginary line D1 being 500 ⁇ m apart from the ridge line, and the TiCN layer has a (311) orientation in a region d2, region d2 being a region in the flank face and being sandwiched between the ridge line and an imaginary line D2 which is 500 ⁇ m apart from the ridge line.
  • the total thickness of a coating, the thickness of a TiCN layer, and the thickness of an Al 2 O 3 layer were measured by observing a cross-section of the coating which is parallel to the normal direction of the surface of the base material at a 1000-fold magnification using an optical microscope. Specifically, these thicknesses were obtained by measuring any three points in the cross section and then taking an average value of the measured thicknesses at the three points.
  • a base material K, a base material L, and a base material M which are to be covered with a coating were prepared. Specifically, raw material powder having a mixing composition (mass%) shown in Table 1 was mixed uniformly using a commercially available attritor, thereby obtaining a powder mixture.
  • this powder mixture was compression-molded into a predetermined shape (CNMG120408NUX), and a resultant compact was put into a sintering furnace and sintered at 1300°C to 1500°C for one to two hours, thereby obtaining base material K, base material L, and base material M made of cemented carbide.
  • "CNMG120408NUX” is the shape of an indexable insert for turning.
  • the "remainder” in Table 1 represents that WC accounts for the rest of the mixing composition (mass%).
  • Type Mixing composition (mass%) Co Cr 3 C 2 NbC TaC WC Base material K 7.0 0.4 3 2.0 Remainder L 10.0 0.4 3 2.0 Remainder M 12.0 0.4 3 2.0 Remainder
  • the surfaces (including a rake face and a flank face) of base material K, base material L, and base material M are covered with a TiCN layer with a thickness as shown in Table 4 by CVD using a gas having a composition shown in Table 2.
  • H2 gas being "Remainder” means that the H2 gas accounts for the rest of the reaction gas composition (vol%).
  • reaction was accelerated by stopping the source gas per 15 minutes and flowing H2 (100 vol%) for one minute. That is to say, for formation conditions a, b, and c, reaction was accelerated by discontinuously supplying the source gas of the TiCN layer.
  • Al 2 O 3 layer was stacked with a thickness as shown in Table 4 on the TiCN layer by CVD after the TiCN layer covering step (Al 2 O 3 layer stacking step).
  • AlCl 3 , HCl, CO 2 , H 2 S, and H 2 were used as the source gas at this time.
  • the reaction conditions used were as follows. Temperature in reaction chamber: 1000°C Pressure in reaction chamber: 6.7 kPa Total gas flow rate: 56.3 L/min
  • the coating after coating in the flank face of the cutting tool was peened from the front surface side on the peening conditions shown in Table 3, thereby changing the orientation of the TiCN layer in the flank face.
  • Peening was performed by projecting media onto the Al 2 O 3 layer provided on the TiCN layer on the conditions that the pressure applied to the media in projection (hereinafter, also referred to as a "projection pressure”) is 0.3 MPa, the distance between the projection portion that projects media and the surface of the rake face or the like (hereinafter, also referred to as a "projection distance”) is 100 mm, and the processing time is 10 to 30 seconds.
  • Peening conditions Projection distance (mm)
  • Table 4 shows the structure of and manufacturing conditions of cutting tools of Sample Nos. 1 to 19 manufactured in the above procedure.
  • the cutting tools of Sample Nos. 1 to 15 correspond to examples, and the cutting tools of Sample Nos. 16 to 19 correspond to comparative examples.
  • Sample No. 1 to 15 correspond to examples
  • the cutting tools of Sample Nos. 16 to 19 correspond to comparative examples.
  • the texture coefficient of the orientation plane in each of the rake face and the flank face of the cutting tool was measured using the cutting tools of Sample Nos. 1 to 19 manufactured as described above. Measurement was performed on the following conditions. Measurement was performed by measuring three points of region d1 (or d2) (e.g., Fig. 7 ), and an average value thereof was calculated as the texture coefficient of each of region d1 of the rake face and region d2 of the flank face ( Fig. 8 , flank face; Fig. 9 , rake face). Table 5 shows the results focusing on the (422) texture coefficient and the (311) texture coefficient.
  • test 1 and test 2 revealed that the cutting tools (Sample Nos. 1 to 15) whose rake face has the (422) orientation and whose flank face has the (311) orientation have excellent chipping resistance and also have excellent crater wear resistance in high-speed machining.
  • 1 base material 1a rake face, 1b flank face, 1c cutting edge face, 10 cutting tool, AA boundary, AB ridge line, AB' imaginary ridge line, BB boundary, D1, D2 imaginary line, d1 region sandwiched between boundary AA and imaginary line D1 (or region sandwiched between ridge line AB and imaginary line D1), d2 region sandwiched between boundary BB and imaginary line D2 (region sandwiched between ridge line AB and imaginary line D2).

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