EP3755456B1 - Container with multiple chambers for storing and mixing a multicomponent liquid coating or gluing system - Google Patents
Container with multiple chambers for storing and mixing a multicomponent liquid coating or gluing system Download PDFInfo
- Publication number
- EP3755456B1 EP3755456B1 EP19705206.1A EP19705206A EP3755456B1 EP 3755456 B1 EP3755456 B1 EP 3755456B1 EP 19705206 A EP19705206 A EP 19705206A EP 3755456 B1 EP3755456 B1 EP 3755456B1
- Authority
- EP
- European Patent Office
- Prior art keywords
- chamber
- mixture
- mixture component
- multichamber vessel
- vessel
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Links
- 238000002156 mixing Methods 0.000 title claims description 37
- 238000000576 coating method Methods 0.000 title claims description 22
- 239000011248 coating agent Substances 0.000 title claims description 21
- 239000007788 liquid Substances 0.000 title claims description 19
- 238000004026 adhesive bonding Methods 0.000 title 1
- 239000000203 mixture Substances 0.000 claims description 90
- 239000000463 material Substances 0.000 claims description 31
- 239000003054 catalyst Substances 0.000 claims description 25
- 239000003973 paint Substances 0.000 claims description 21
- 239000000853 adhesive Substances 0.000 claims description 19
- 230000001070 adhesive effect Effects 0.000 claims description 19
- 238000000034 method Methods 0.000 claims description 16
- 230000000149 penetrating effect Effects 0.000 claims description 16
- 239000007921 spray Substances 0.000 claims description 14
- 239000002904 solvent Substances 0.000 claims description 7
- 239000002775 capsule Substances 0.000 claims description 5
- 230000007704 transition Effects 0.000 claims description 4
- 230000004308 accommodation Effects 0.000 claims 1
- 238000013019 agitation Methods 0.000 claims 1
- 238000005192 partition Methods 0.000 description 36
- 239000011888 foil Substances 0.000 description 8
- 230000008901 benefit Effects 0.000 description 7
- 239000000758 substrate Substances 0.000 description 7
- 239000004814 polyurethane Substances 0.000 description 6
- 230000008569 process Effects 0.000 description 6
- 238000006243 chemical reaction Methods 0.000 description 5
- 238000005520 cutting process Methods 0.000 description 5
- 229920003023 plastic Polymers 0.000 description 5
- 239000004033 plastic Substances 0.000 description 5
- 229920002635 polyurethane Polymers 0.000 description 5
- 238000012545 processing Methods 0.000 description 5
- 239000011230 binding agent Substances 0.000 description 4
- 239000002131 composite material Substances 0.000 description 4
- 238000013461 design Methods 0.000 description 4
- 229910052751 metal Inorganic materials 0.000 description 4
- 239000002184 metal Substances 0.000 description 4
- 239000004848 polyfunctional curative Substances 0.000 description 4
- 238000003860 storage Methods 0.000 description 4
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 3
- -1 PE-LLD Polymers 0.000 description 3
- 239000004972 Polyurethane varnish Substances 0.000 description 3
- 150000001875 compounds Chemical class 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 238000004806 packaging method and process Methods 0.000 description 3
- 238000001179 sorption measurement Methods 0.000 description 3
- 239000010457 zeolite Substances 0.000 description 3
- 239000004593 Epoxy Substances 0.000 description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- 229920006771 PE-C Polymers 0.000 description 2
- 229920006832 PE-MD Polymers 0.000 description 2
- 229920006448 PE-UHMW Polymers 0.000 description 2
- 229910021536 Zeolite Inorganic materials 0.000 description 2
- 229910052782 aluminium Inorganic materials 0.000 description 2
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 2
- 150000001412 amines Chemical class 0.000 description 2
- 230000004888 barrier function Effects 0.000 description 2
- 229910052797 bismuth Inorganic materials 0.000 description 2
- 239000000919 ceramic Substances 0.000 description 2
- 230000008859 change Effects 0.000 description 2
- 125000003636 chemical group Chemical group 0.000 description 2
- 230000000295 complement effect Effects 0.000 description 2
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 2
- 229920001903 high density polyethylene Polymers 0.000 description 2
- 239000012948 isocyanate Substances 0.000 description 2
- 150000002513 isocyanates Chemical class 0.000 description 2
- 239000004922 lacquer Substances 0.000 description 2
- 230000035515 penetration Effects 0.000 description 2
- 238000000926 separation method Methods 0.000 description 2
- 230000008961 swelling Effects 0.000 description 2
- 238000006845 Michael addition reaction Methods 0.000 description 1
- 239000002033 PVDF binder Substances 0.000 description 1
- 239000004696 Poly ether ether ketone Substances 0.000 description 1
- 229920001153 Polydicyclopentadiene Polymers 0.000 description 1
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 150000001252 acrylic acid derivatives Chemical group 0.000 description 1
- 239000012190 activator Substances 0.000 description 1
- JUPQTSLXMOCDHR-UHFFFAOYSA-N benzene-1,4-diol;bis(4-fluorophenyl)methanone Chemical compound OC1=CC=C(O)C=C1.C1=CC(F)=CC=C1C(=O)C1=CC=C(F)C=C1 JUPQTSLXMOCDHR-UHFFFAOYSA-N 0.000 description 1
- JCXGWMGPZLAOME-UHFFFAOYSA-N bismuth atom Chemical compound [Bi] JCXGWMGPZLAOME-UHFFFAOYSA-N 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 238000004132 cross linking Methods 0.000 description 1
- 230000006378 damage Effects 0.000 description 1
- 238000009792 diffusion process Methods 0.000 description 1
- 238000006073 displacement reaction Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 150000002118 epoxides Chemical class 0.000 description 1
- 229920000840 ethylene tetrafluoroethylene copolymer Polymers 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 235000013305 food Nutrition 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 239000010439 graphite Substances 0.000 description 1
- 229910002804 graphite Inorganic materials 0.000 description 1
- 230000005484 gravity Effects 0.000 description 1
- 238000007210 heterogeneous catalysis Methods 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 239000003999 initiator Substances 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 239000007791 liquid phase Substances 0.000 description 1
- 229920001684 low density polyethylene Polymers 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 150000002734 metacrylic acid derivatives Chemical group 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 239000002808 molecular sieve Substances 0.000 description 1
- 238000007591 painting process Methods 0.000 description 1
- 150000002978 peroxides Chemical class 0.000 description 1
- 239000012071 phase Substances 0.000 description 1
- 229920006260 polyaryletherketone Polymers 0.000 description 1
- 229920006393 polyether sulfone Polymers 0.000 description 1
- 229920002530 polyetherether ketone Polymers 0.000 description 1
- 239000004800 polyvinyl chloride Substances 0.000 description 1
- 229920002981 polyvinylidene fluoride Polymers 0.000 description 1
- 230000002441 reversible effect Effects 0.000 description 1
- URGAHOPLAPQHLN-UHFFFAOYSA-N sodium aluminosilicate Chemical compound [Na+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O URGAHOPLAPQHLN-UHFFFAOYSA-N 0.000 description 1
- 239000011949 solid catalyst Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 229910052718 tin Inorganic materials 0.000 description 1
- 239000010936 titanium Substances 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- 125000002348 vinylic group Chemical group 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
- 229910052726 zirconium Inorganic materials 0.000 description 1
Images
Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01F—MIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
- B01F35/00—Accessories for mixers; Auxiliary operations or auxiliary devices; Parts or details of general application
- B01F35/71—Feed mechanisms
- B01F35/716—Feed mechanisms characterised by the relative arrangement of the containers for feeding or mixing the components
- B01F35/7162—A container being placed inside the other before contacting the contents
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
- B65D—CONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
- B65D81/00—Containers, packaging elements, or packages, for contents presenting particular transport or storage problems, or adapted to be used for non-packaging purposes after removal of contents
- B65D81/32—Containers, packaging elements, or packages, for contents presenting particular transport or storage problems, or adapted to be used for non-packaging purposes after removal of contents for packaging two or more different materials which must be maintained separate prior to use in admixture
- B65D81/3216—Rigid containers disposed one within the other
- B65D81/3222—Rigid containers disposed one within the other with additional means facilitating admixture
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01F—MIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
- B01F33/00—Other mixers; Mixing plants; Combinations of mixers
- B01F33/50—Movable or transportable mixing devices or plants
- B01F33/501—Movable mixing devices, i.e. readily shifted or displaced from one place to another, e.g. portable during use
- B01F33/5011—Movable mixing devices, i.e. readily shifted or displaced from one place to another, e.g. portable during use portable during use, e.g. hand-held
- B01F33/50114—Movable mixing devices, i.e. readily shifted or displaced from one place to another, e.g. portable during use portable during use, e.g. hand-held of the hand-held gun type
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01F—MIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
- B01F35/00—Accessories for mixers; Auxiliary operations or auxiliary devices; Parts or details of general application
- B01F35/30—Driving arrangements; Transmissions; Couplings; Brakes
- B01F35/32—Driving arrangements
- B01F35/32005—Type of drive
- B01F35/3202—Hand driven
- B01F35/32021—Shaking by hand a portable receptacle or stirrer for mixing
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01F—MIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
- B01F35/00—Accessories for mixers; Auxiliary operations or auxiliary devices; Parts or details of general application
- B01F35/71—Feed mechanisms
- B01F35/713—Feed mechanisms comprising breaking packages or parts thereof, e.g. piercing or opening sealing elements between compartments or cartridges
- B01F35/7137—Piercing, perforating or melting membranes or closures which seal the compartments
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05B—SPRAYING APPARATUS; ATOMISING APPARATUS; NOZZLES
- B05B7/00—Spraying apparatus for discharge of liquids or other fluent materials from two or more sources, e.g. of liquid and air, of powder and gas
- B05B7/24—Spraying apparatus for discharge of liquids or other fluent materials from two or more sources, e.g. of liquid and air, of powder and gas with means, e.g. a container, for supplying liquid or other fluent material to a discharge device
- B05B7/2402—Apparatus to be carried on or by a person, e.g. by hand; Apparatus comprising containers fixed to the discharge device
- B05B7/2472—Apparatus to be carried on or by a person, e.g. by hand; Apparatus comprising containers fixed to the discharge device comprising several containers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05B—SPRAYING APPARATUS; ATOMISING APPARATUS; NOZZLES
- B05B7/00—Spraying apparatus for discharge of liquids or other fluent materials from two or more sources, e.g. of liquid and air, of powder and gas
- B05B7/24—Spraying apparatus for discharge of liquids or other fluent materials from two or more sources, e.g. of liquid and air, of powder and gas with means, e.g. a container, for supplying liquid or other fluent material to a discharge device
- B05B7/2402—Apparatus to be carried on or by a person, e.g. by hand; Apparatus comprising containers fixed to the discharge device
- B05B7/2478—Gun with a container which, in normal use, is located above the gun
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01F—MIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
- B01F2101/00—Mixing characterised by the nature of the mixed materials or by the application field
- B01F2101/2305—Mixers of the two-component package type, i.e. where at least two components are separately stored, and are mixed in the moment of application
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01F—MIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
- B01F2101/00—Mixing characterised by the nature of the mixed materials or by the application field
- B01F2101/36—Mixing of ingredients for adhesives or glues; Mixing adhesives and gas
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05B—SPRAYING APPARATUS; ATOMISING APPARATUS; NOZZLES
- B05B7/00—Spraying apparatus for discharge of liquids or other fluent materials from two or more sources, e.g. of liquid and air, of powder and gas
- B05B7/24—Spraying apparatus for discharge of liquids or other fluent materials from two or more sources, e.g. of liquid and air, of powder and gas with means, e.g. a container, for supplying liquid or other fluent material to a discharge device
- B05B7/2402—Apparatus to be carried on or by a person, e.g. by hand; Apparatus comprising containers fixed to the discharge device
- B05B7/2405—Apparatus to be carried on or by a person, e.g. by hand; Apparatus comprising containers fixed to the discharge device using an atomising fluid as carrying fluid for feeding, e.g. by suction or pressure, a carried liquid from the container to the nozzle
- B05B7/2408—Apparatus to be carried on or by a person, e.g. by hand; Apparatus comprising containers fixed to the discharge device using an atomising fluid as carrying fluid for feeding, e.g. by suction or pressure, a carried liquid from the container to the nozzle characterised by the container or its attachment means to the spray apparatus
Definitions
- the invention relates to a multi-chamber container for storing and mixing a multi-component liquid coating or adhesive system with a first chamber for a first mixture component and at least one further chamber for a further mixture component, the first chamber and the at least one further chamber being liquid-tight from one another by at least one partition are separated, wherein the at least one partition wall comprises a pierceable partition layer, and with a piercing element for piercing the pierceable partition layer, in such a way that the first and the one further mixture component mix in the first or at least one further chamber.
- the present invention also relates to a system for applying a coating or an adhesive and a method for mixing a multicomponent liquid coating or adhesive system.
- Multi-chamber containers of the type mentioned are known from the prior art. For example, they are used together with paint spray guns for automotive refinish paints. In the case of one-component paints, these are simply filled into a cup-like container or made available in this, which is placed on the paint spray gun. If two-component paint systems are used, the components must first be mixed before being applied by the spray gun. Usually this is done manually. Systems in which the two components are stored separately from one another in different chambers of a cup that can be screwed onto the paint spray gun have proven to be particularly expedient. The partition between the chambers is destroyed for the purpose of mixing the components before the painting process, so that the components flow into one another and mix. The mixture can then be applied immediately afterwards by means of the spray gun.
- Typical two-component paint systems include a binder as the first component and a hardener as the second component.
- paint systems are polyurethane paints with an isocyanate-containing and an isocyanate-reactive, e.g. hydroxyl-containing component, and epoxy paints with an epoxy-containing and an epoxy-reactive, e.g. amine component.
- a generic multi-chamber system of the type described above is from US2009 / 0188987 A1 known.
- two (in one embodiment also three) chambers are arranged one above the other in a common cup-like container and are provided with a separating film spatially separated from each other.
- the separating film is pierced with a mandrel so that the paint components mix with one another in the lower chamber.
- the film barrier due to its flexibility, shows a rather undefined behavior when it is pierced, so that a defined destruction of the barrier often does not succeed in the desired form.
- the multi-chamber container disclosed in this publication comprises a flexible bag made of a liquid-tight material, which is spanned by an articulated frame. Due to the centrally arranged hinge, the bag can be divided into two separate partial volumes into which the two mixture components can be filled. To mix the components, the frame is stretched so that the liquids run into one another and mix. The mixture can then be applied via a valve at the edge and introduced into a spray gun, for example. Due to the flexible structure, this variant of a multi-chamber container has advantages in terms of waste disposal, but overall it is too mechanically sensitive.
- the spatial separation of the mixture components is not optimal for the purpose of a long shelf life as possible.
- the wall thicknesses of the flexible bag materials are rather small, so that a significant swelling or even instability must be expected for solvent-based paint systems. If, on the other hand, foil composites with a metal foil, for example an aluminum foil, are used to prevent swelling, the user cannot visually check the lacquer materials to ensure that they are in perfect condition before use.
- the DE 35 45 614 A1 in turn discloses a cartridge consisting of two containers that can be connected to one another for a two-component mass which is used in particular in construction.
- the partitions arranged in the connecting area of the containers are removed immediately before or after connecting the containers.
- the two components are then mixed and the resulting, reactive mixture of the components can be pressed out of the containers through the mouthpiece by means of a plunger.
- the present invention is based on the object of providing a multi-chamber container for storing and mixing a multi-component liquid coating or adhesive system, with which on the one hand safe storage of the mixed components and on the other hand simple and safe feasible mixing process is possible and which also allows a simple discharge of the mixture.
- a multi-chamber container for storing and mixing a multi-component liquid coating or adhesive system according to the preamble of claim 1 in that the at least one further chamber is arranged coaxially in the outer container, the first chamber also being an outer container is formed, wherein the at least one further chamber in the outer container is designed as a cup-shaped insert, wherein the separating layer is partially formed in the partition, wherein the piercing element is hollow, in particular cylindrically hollow, and has at least two longitudinally offset openings for introducing one of the first or the further mixture component into the chamber of the respective other mixture component, wherein the piercing element is further supported on a curved support surface which, when a force is applied above a pressure threshold, moves from a first position to a second position e passes in such a way that the piercing element is displaced from a first position to a second position during the transition from the first to the second position, the piercing element in the process penetrating the pierceable
- the multi-chamber container comprises a first chamber for a first mixture component and at least one further chamber for a further mixture component, the first chamber and the at least one further chamber being separated from one another in a liquid-tight manner by a partition.
- the number of chambers is therefore not limited, so that the multi-chamber container according to the invention is also suitable for liquid coating or adhesive systems with more than, for example, two components.
- the particular advantage of the multi-chamber container according to the invention lies in the safe storage of the individual mixture components without the risk of parts of the mixture components flowing into one another if the multi-chamber container is improperly handled. This is ensured by the partition wall provided between the first and the at least one further chamber.
- the piercing element cooperating with the pierceable separating layer ensures the production of a defined fluid-conducting connection between the chambers, so that intensive mixing of the mixture components is possible.
- the penetrable separating layer is partially formed in the separating wall ensures that a defined penetration of the separating wall can take place at any time, since, due to the limited extent of the separating surface within the separating wall, undesired rebounding of the separating surface when penetrating by means of the piercing element is avoided.
- Has a partial partition furthermore the advantage that it is only exposed to low mechanical stress when moving the multi-chamber container.
- the forces acting on the partition wall when the container filled with liquid is shaken are greater, the larger the pierceable and thus inherently mechanically unstable separating layer.
- a smaller, non-full-area separating layer is therefore advantageous.
- the separating layer is preferably formed by a film material which, on the one hand, is durable and sufficiently resistant to unintentional pressurization and the chemicals used, but on the other hand can be pierced easily and precisely by the piercing element.
- Suitable foil materials are metal foils such as aluminum foils, plastic foils made of ABS, CA, COC, CTA, E / P, ETFE, FEP, PA, PAEK, PAN, PBT, PC, PCCE, PCO, PCT, PDCPD, PE (PE-C, PE-HD, PE-LD, PE-LLD, PE-MD, PE-UHMW, PE-ULD), PEC, PEEK, PESTUR, PESU, PET, PEUR, PHB, PI, POM, PP, PS, PTT, PUR , PVC, PVDF (abbreviations according to DIN EN ISO 1043-1: 2012-03).
- composite foils made of metal and plastic are preferably suitable. These combine properties such as preventing diffusion between the mixture components of the individual chambers, sealability in order to tightly bond the corresponding film materials to the material of the chamber container, as well as mechanical strength against stress caused by fluid movements in the chambers during transport of the container and easy penetrability.
- Corresponding film composites are known, for example, from the packaging sector for foods, for example.
- the at least one further chamber is arranged coaxially to the first chamber.
- This coaxial arrangement ensures that, for example, when using the multi-chamber container according to the invention together with an application unit for the multi-component liquid coating or adhesive system, in particular a paint spray gun, no disruptive overturning moments arise before mixing.
- coaxial arrangements can be implemented by means of particularly simple structural designs.
- the first chamber is formed by an outer container, the at least one further chamber in the outer container being designed as a cup-shaped insert. This also reduces the design and manufacturing effort in that the multi-chamber container is formed by comparatively few elements that can be assembled manually or by machine without any effort.
- the relative volume ratio of the first chamber for the first mixture component to at least one further chamber for the further mixture component (s) is 1: 1 to 9: 1, preferably 1: 1 to 5: 1. This takes into account the usual volumes to be mixed with one another when preparing and processing common liquid coating or adhesive systems.
- the piercing element is hollow, in particular cylindrically hollow, and has at least two longitudinally offset openings for introducing one of the first or the further mixture component into the chamber of the respective other mixture component.
- the mixing process in particular the mixing speed, can be precisely influenced, for example quantitatively, by the size of the openings and the internal dimensions of the piercing element.
- At least one of the two longitudinally offset openings is expediently arranged in the end face of the piercing element, in particular in the region of a cutting edge.
- the piercing element can be made of different materials and also have different geometries.
- the piercing element is preferably designed in the form of a pin or rod and has a sharpened tip or circumferential cutting edge which enables the separating layer to be pierced easily and safely.
- the geometry of the piercing element should be designed in such a way that, regardless of the vertical position of the piercing element, complete emptying of the liquid from the upper chamber is ensured during and after the piercing and the outlet opening is not blocked.
- the piercing element is also supported on a curved support surface, the curved support surface transitioning from a first position to a second position when force is applied, in such a way that the piercing element is displaced from a first position to a second position during the transition from the first to the second position wherein the piercing element pierces the pierceable separating layer.
- This enables particularly precise piercing of the separating layer and at the same time limits the movement of the piercing element in such a way that the multi-chamber container is not damaged if the piercing element is accidentally subjected to excessive force.
- the curved support surface only changes from the first position to the second position when a force is applied above a defined threshold.
- the multi-chamber container according to the invention can comprise more than two chambers.
- the partition between the chambers can be designed in such a way that the first chamber is separated from the second and third chambers via a common partition, a first partition section separating the first chamber from the second chamber and a second partition separates the first chamber from the third chamber.
- each partition wall section has a pierceable partition layer which is formed over part of the surface of the respective partition wall section and which is each pierceable with a piercing element.
- a piercing element can be provided for each of the second and third chambers, which pierces the respective partition wall section when actuated, so that as a result the components preferably mix in the first chamber.
- each of the two dividing walls has a dividing layer formed over part of the area. If the two partition walls are in alignment with one another, the partition layers of both partition walls can preferably be pierced one after the other by a single piercing element.
- the separating layer which extends partially over the separating wall, is arranged centrally in the separating wall.
- the partition surrounding the partition is preferably conical. This facilitates the leakage of one mixture component into the other chamber due to gravity and there the mixing of the two mixture components after the separation layer has been pierced.
- half the opening angle of the cone to the longitudinal axis of the multi-chamber container is preferably not more than 85 °, preferably not more than 80 °.
- the material used to manufacture the multi-chamber container and the first chamber and / or the at least one further chamber are plastics, metals, glass, ceramics and composite materials and coated materials and combinations of the aforementioned materials. Your selection is based on the requirements resulting from the material properties of the mixing components, as well as the expected mechanical stress profile (e.g. use in a paint shop) change so that they become unusable, nor are the mixed components themselves allowed to change the material or materials so that they cannot fulfill their function as packaging for the mixed components.
- the selection of the materials is therefore based on simple tests, in that mixed components are stored in packaging made of the respective material and the material and mixed component are regularly checked.
- Plastic is preferred as the material, in particular PA, PBT, PE (PE-C, PE-HD, PE -LD, PE-LLD, PE-MD, PE-UHMW, PE-ULD), PET (abbreviations according to DIN EN ISO 1043-1: 2012-03).
- PE PE-C, PE-HD, PE -LD, PE-LLD, PE-MD, PE-UHMW, PE-ULD
- PET abbreviations according to DIN EN ISO 1043-1: 2012-03
- the multi-chamber container and the first chamber and / or the at least one further chamber are preferably formed from a transparent or translucent material. This allows the respective filling level of the mixing components in the chambers to be determined in a simple manner. Furthermore, the penetration of the separating layer can be observed and supported, for example, by shaking the multi-chamber container.
- the multi-chamber container In order to discharge the mixture formed from the mixture components from the multi-chamber container and, for example, to direct it into a spray gun, the multi-chamber container preferably has a closable outlet opening. If, according to the above, the first chamber is formed by an outer container, the at least one further chamber in the outer container being designed as a cup-shaped insert, the outlet opening is preferably provided in the outer container forming the first chamber.
- a catalyst capsule containing a catalyst material is arranged at the outlet opening in such a way that the mixture formed from the first and the further mixture component comes into contact with the catalyst material as it flows out.
- the mixture formed from the mixture components can have a comparatively long processing time (pot life), so that processing does not have to take place immediately after the mixing process, which is an advantage depending on the particular application.
- an accelerated chemical reaction crosslinking
- crosslinking takes place, which shortens the processing time, so that, for example, when the mixture is applied immediately after this, rapid curing takes place on a surface.
- the catalyst material can be designed in the form of a catalyst bed which contains a catalyst reversibly sorbed on a substrate.
- a defined volume, which contains substrate and catalyst, is regarded as a catalyst bed, the catalyst not being able to leave the substrate (for example by using sieve inserts).
- the catalyst is reversibly sorbed on the substrate. Both adsorption and absorption can be considered here.
- the sorption can take place in that the substrate is impregnated with a solution of the catalyst and then the solvent is evaporated.
- the fact that the sorption is reversible means that a sorbed catalyst can also be given back to a liquid phase in an amount effective to catalyze the reaction. Therefore, it is also preferred that the substrate is not graphite or activated carbon.
- Suitable substrates can be solid catalysts and catalyst supports, as they are known from heterogeneous catalysis. This also includes zeolites / molecular sieves such as zeolite A and zeolite X and other porous ceramics.
- suitable catalysts depend on the type of mixing components. For example, if a polyurethane reaction is to be catalyzed because one mixed component contains an isocyanate-containing compound and the other mixed component contains an isocyanate-reactive compound, then titanium, zirconium, bismuth, tin and / or iron-containing catalysts are preferred. Dialkyltin dicarboxylates and bismuth carboxylates are particularly preferred in this case.
- the outlet opening can be closed with a simple, space-saving closure, for example a screw closure.
- a simple, space-saving closure for example a screw closure.
- the multi-chamber container has a recess for receiving an outlet valve, the outlet valve being connectable to the outlet opening.
- the outlet nozzle is preferably held in this recess by means of a clamp, i.e. in a non-positive manner. This prevents the outlet nozzle from getting lost during the storage phase.
- the piercing element can, as already mentioned, be shaped in various ways. Cylindrical rod-shaped shapes are preferred.
- a further embodiment of the invention provides that the first chamber or the at least one further chamber has a guide for the piercing element. It goes without saying that the guide is adapted to the respective geometry of the piercing element in order to enable a preferably axial piercing movement as precisely as possible.
- the first and / or the at least one further chamber has a closable opening for introducing a solvent.
- One of the openings can be identical to the outlet opening.
- Another aspect of the present invention relates to a system for applying a paint coating or an adhesive comprising a multi-chamber container for storing and mixing a multi-component liquid coating or adhesive system according to one of claims 1 to 12 and an application unit, in particular a spray gun, which can be detachably connected to the multi-chamber container.
- the system has a comparatively simple structure and enables the mixing components to be mixed intensively, assisted by shaking the container.
- the advantages mentioned above in connection with the multi-chamber container apply accordingly.
- the method according to the invention can be carried out simply and inexpensively.
- the advantages mentioned above in connection with the multi-chamber container also apply to the method.
- the advantages mentioned in connection with the method according to the invention also apply accordingly to the multi-chamber container.
- Coating materials are used as mixture components provided according to the invention, in which it is advantageous to keep two or more components separately during transport and storage and to mix them only shortly before application.
- coating materials in which the two components have chemical groups that are complementary to one another. Examples include -NCO and -OH, -SH and / or -NH, furthermore epoxide and amine, furthermore acceptor and donor compounds for Michael additions.
- the individual mixing components can also contain catalysts for the reaction of the complementary groups. Alternatively, polymerizable chemical groups can be present in one component, while corresponding initiators or activators are contained in the other component.
- the multi-chamber container according to the invention is particularly advantageous for mixed components of low viscosity.
- the mixed components have a viscosity below 10,000 mPas, particularly preferably below 2,000 mPas and very particularly preferably below 250 mPas.
- the viscosity data relate to measurements according to DIN EN ISO 3219 / A3 at 23 ° C. and a shear gradient of 100 s -1, measured with a Physica MCR 51 rheometer from Anton Paar Germany GmbH (DE).
- the viscosity of the two mixing components should therefore not be more than 500%, preferably 150%, particularly preferably not 50%, higher than the other component.
- the volume ratio between the first mixture component in the first chamber and the one further mixture component in the at least one further chamber is 1: 1 to 9: 1, preferably 1: 1 to 5: 1.
- Fig. 1 shows a multi-chamber container 1 * for storing and mixing a multi-component liquid coating or adhesive system M in a perspective view.
- the multi-chamber container 1 * comprises an outer container 1a * with a slightly conically shaped outer wall 1b *, which on the underside merges into a strongly funnel-shaped wall section 1c *.
- the multi-chamber container 1 * has an outlet opening 1d * on the underside, which in the present case is closed with a screw cap 1e *.
- Fig. 2 shows the multi-chamber container 1 of Fig. 1 in a transparent version in a perspective view.
- the multi-chamber containers 1 *, 1 of the differ Figs. 1 and 2 not further.
- the multi-chamber container 1 comprises a first chamber 10 for a first mixture component, for example the binder B of a 2K polyurethane paint.
- the multi-chamber container 1 comprises a second chamber 20 for a second mixture component, for example the hardener H of the 2K polyurethane varnish.
- the first chamber 10 and the second chamber 20 are separated from one another in a liquid-tight manner by a partition wall 30.
- the partition wall 30 comprises a pierceable partition layer 40, which is formed over part of the area in the partition wall 30. Furthermore, the multi-chamber container 1 comprises a Piercing element 50 for piercing the pierceable separating layer 40. This has the function of penetrating the separating layer 40 when actuated in such a way that the mixture components B, H are in either the first or the second chamber 10, 20, in the present embodiment in the first chamber 10, mix.
- the first chamber 10 is formed by the outer container 1a of the multi-chamber container 1, while the second chamber 20 is designed as a cup-shaped insert in the outer container 1a.
- the partition wall 30 with the pierceable partition layer 40 is formed by the bottom of the cup-shaped insert of the second chamber 20.
- the partition wall 30 is slightly curved or conically shaped. This makes it easier for the mixture component H contained in the second chamber 20 to run out completely.
- the separating layer 40 is arranged over part of the surface - and in the present case also centrally - in the separating wall 30 which forms the bottom of the cup-shaped insert.
- the second chamber 20 also has a cylindrical guide 21 arranged centrally in the second chamber 20 and comprising two axially aligned elongated holes 22, in which the piercing element 50 is guided, as will be described further below.
- the piercing element 50 has an essentially cylindrical shape which is adapted to the cylindrical guide 21 as part of the second chamber 20 configured as a cup-shaped insert.
- the piercing element 50 is hollow on the inside and has a first end opening 53, a second end opening 54 provided opposite the first end opening 53, and elongated holes 51 on the outside.
- the frontal opening 53 is surrounded by a cutting edge 52 with which the separating layer 40 can be pierced reliably and precisely when the penetrating element 50 moves axially in the direction of the separating layer 40.
- a solvent can also be added to the mixture component H of the second chamber 20, if necessary.
- the opening 54 can also be used to add a solvent for the mixture M produced.
- the second end opening 54 can be closed by a closure 55, for example a screw closure.
- the multi-chamber container 1 has a second cup-shaped or shell-shaped insert 60 which, in the assembled state of the multi-chamber container 1, is arranged above the second chamber 20.
- This insert 60 has an inwardly curved base area 61 and a further central cylindrical guide 62 for the piercing element 50.
- the multi-chamber container 1 is closed at the top by means of a cover 63, for example in the form of a film.
- the piercing element 50 is over the closure 55 is supported on the curved base surface 61, which changes from a first position to a second position when a force is applied above a pressure threshold.
- the piercing element 50 is displaced from a first position to a second position during the transition from the first to the second position and in the process pierces the pierceable separating layer. At the same time, the axial displacement of the piercing element 50 is limited.
- the first chamber 10 is partially filled with a first mixture component B, in this case the binding agent of a 2K polyurethane varnish, while the second chamber 20 in the form of a cup-shaped insert in the correct proportion to the first mixture component with a second mixture component H, in this case the hardener of the 2K -Polyurethane varnish, is filled.
- the piercing element 50 is in its starting position, in which the cutting edge 52 is arranged directly above the pierceable separating layer 40, which is central with respect to the separating surface 30, and the elongated holes 51 of the piercing element 50 are arranged axially offset from the elongated holes 22 of the cylindrical guide 21.
- the piercing element 50 is closed at its frontal opening 54 with a closure 55, the top side of which also serves as an actuating surface for the piercing element 50.
- the piercing element By corresponding pressure on the closure 55, the piercing element is moved axially in the direction of the separating layer 40, the cutting edge 52 precisely penetrating the separating layer.
- the axial movement is limited in that the curved surface 61 of the second cup-shaped insert 60, preferably by means of a snap movement from the rest position, in which the curved surface 61 is curved inward relative to the second cup-shaped insert 60 ( Figure 6a ), to an operating position in which the curved surface 61 is curved outward ( Figure 6b ), transforms.
- the elongated holes 51 of the piercing element 50 and the elongated holes 22 of the cylindrical guide 21 begin to align, so that a fluid-conducting connection is created between the second chamber 20 and the inner volume of the hollow piercing element 50, as in FIG Figure 6b recognizable, the second mixture component H flowing into the inner volume of the piercing element 50.
- the perforation of the separating layer 40 also established a fluid-conducting connection between the inner volume of piercing element 50 and the first chamber 10, so that the second mixture component H flows into the first chamber 10 and mixes with the first mixture component B.
- the mixing effect can be intensified by shaking the multi-chamber container 1 accordingly.
- the multi-chamber container 1 is shown in the first chamber 10 with the mixture M consisting of binder B and hardener H, which react with one another to produce the 2K polyurethane paint.
- the second chamber 20 is completely emptied, which is favored by the slightly conical shape of the partition wall 30.
- Fig. 7 shows the multi-chamber container of Fig. 1 in a perspective view with a separate, screw-on outlet nozzle.
- Fig. 8 shows a particularly advantageous embodiment in which the separate, screw-on outlet nozzle 70 comprises an annular catalyst capsule containing a catalyst material.
- FIGS. 9a and 9b show the connection of a multi-chamber container according to Fig. 1 with a spray gun S.
- the spray gun S can be of conventional design and operated with compressed air.
Description
Die Erfindung betrifft einen Mehrkammerbehälter zum Aufbewahren und Mischen eines mehrkomponentigen flüssigen Beschichtungs- oder Klebesystems mit einer ersten Kammer für eine erste Mischungskomponente und wenigstens einer weiteren Kammer für eine weitere Mischungskomponente, wobei die erste Kammer und die wenigstens eine weitere Kammer durch wenigstens eine Trennwand flüssigkeitsdicht voneinander abgetrennt sind, wobei die wenigstens eine Trennwand eine durchstoßbare Trennschicht umfasst, und mit einem Durchstoßelement zum Durchstoßen der durchstoßbaren Trennschicht, derart, dass die erste und die eine weitere Mischungskomponente sich in der ersten oder wenigstens einen weiteren Kammer vermischen. Ferner betrifft die vorliegende Erfindung ein System zur Ausbringung einer Beschichtung oder eines Klebstoffes sowie ein Verfahren zum Mischen eines mehrkomponentigen flüssigen Beschichtungs- oder Klebesystems.The invention relates to a multi-chamber container for storing and mixing a multi-component liquid coating or adhesive system with a first chamber for a first mixture component and at least one further chamber for a further mixture component, the first chamber and the at least one further chamber being liquid-tight from one another by at least one partition are separated, wherein the at least one partition wall comprises a pierceable partition layer, and with a piercing element for piercing the pierceable partition layer, in such a way that the first and the one further mixture component mix in the first or at least one further chamber. The present invention also relates to a system for applying a coating or an adhesive and a method for mixing a multicomponent liquid coating or adhesive system.
Mehrkammerbehälter der eingangs genannten Art sind aus dem Stand der Technik bekannt. Sie werden beispielsweise zusammen mit Lacksprühpistolen für Autoreparaturlacke eingesetzt. Bei einkomponentigen Lacken werden diese einfach in einen becherartigen Behälter gefüllt oder in diesem bereit gestellt, welcher auf die Lacksprühpistole aufgesetzt wird. Kommen zweikomponentige Lacksysteme zum Einsatz müssen die Komponenten vor der Ausbringung durch die Sprühpistole zunächst gemischt werden. In der Regel erfolgt dies manuell. Als besonders zweckmäßig erweisen sich solche Systeme, bei denen beide Komponenten getrennt voneinander in unterschiedlichen Kammern eines auf die Lacksprühpistole aufschraubbaren Bechers gelagert werden. Dabei wird die Trennwand zwischen den Kammern zum Zwecke der Mischung der Komponenten vor dem Lackiervorgang zerstört, so dass die Komponenten ineinander fließen und sich vermischen. Das Gemisch kann dann unmittelbar im Anschluss daran mittels der Sprühpistole ausgebracht werden.Multi-chamber containers of the type mentioned are known from the prior art. For example, they are used together with paint spray guns for automotive refinish paints. In the case of one-component paints, these are simply filled into a cup-like container or made available in this, which is placed on the paint spray gun. If two-component paint systems are used, the components must first be mixed before being applied by the spray gun. Usually this is done manually. Systems in which the two components are stored separately from one another in different chambers of a cup that can be screwed onto the paint spray gun have proven to be particularly expedient. The partition between the chambers is destroyed for the purpose of mixing the components before the painting process, so that the components flow into one another and mix. The mixture can then be applied immediately afterwards by means of the spray gun.
Typische zweikomponentige Lacksysteme umfassen ein Bindemittel als erste Komponente und einen Härter als zweite Komponente. Beispiele für solche Lacksysteme sind Polyurethanlacke mit einer isocyanathaltigen und einer isocyanatreaktiven, z.B. hydroxyhaltigen, Komponente, sowie Epoxidlacke mit einer epoxyhaltigen und einer epoxyreaktiven, z.B. aminischen, Komponente.Typical two-component paint systems include a binder as the first component and a hardener as the second component. Examples of such paint systems are polyurethane paints with an isocyanate-containing and an isocyanate-reactive, e.g. hydroxyl-containing component, and epoxy paints with an epoxy-containing and an epoxy-reactive, e.g. amine component.
Ein gattungsgemäßes Mehrkammersystem der vorstehend beschriebenen Art ist aus der
Ein weiterer Mehrkammerbehälter zum Aufbewahren und Mischen eines mehrkomponentigen flüssigen Beschichtungs- oder Klebesystems ist aus der
Die
Ausgehend von dem vorstehend diskutierten Stand der Technik liegt der vorliegenden Erfindung die Aufgabe zugrunde, einen Mehrkammerbehälter zum Aufbewahren und Mischen eines mehrkomponentigen flüssigen Beschichtungs- oder Klebesystems bereitzustellen, mit welchem einerseits eine sichere Lagerung der Mischkomponenten sowie andererseits ein einfach und sicher durchführbarer Mischvorgang möglich ist und der ferner ein einfaches Ausbringen der Mischung erlaubt.Based on the prior art discussed above, the present invention is based on the object of providing a multi-chamber container for storing and mixing a multi-component liquid coating or adhesive system, with which on the one hand safe storage of the mixed components and on the other hand simple and safe feasible mixing process is possible and which also allows a simple discharge of the mixture.
Die Aufgabe wird erfindungsgemäß mit einem Mehrkammerbehälter zum Aufbewahren und Mischen eines mehrkomponentigen flüssigen Beschichtungs- oder Klebesystems nach dem Oberbegriff des Patentanspruches 1 dadurch gelöst, dass die wenigstens eine weitere Kammer koaxial in dem äußeren Behälter angeordnet ist, wobei die erste Kammer ferner durch einen äußeren Behälter ausgebildet ist, wobei die wenigstens eine weitere Kammer in dem äußeren Behälter als becherförmiger Einsatz ausgebildet ist, wobei die Trennschicht teilflächig in der Trennwand ausgebildet ist, wobei das Durchstoßelement hohl, insbesondere zylindrisch hohl, ausgebildet ist und wenigstens zwei längsversetzte Öffnungen aufweist zur Einleitung einer der ersten oder der weiteren Mischungskomponente in die Kammer der jeweils anderen Mischungskomponente, wobei das Durchstoßelement ferner auf einer gewölbten Stützfläche abgestützt ist, welche bei Kraftbeaufschlagung oberhalb einer Druckschwelle aus einer ersten Lage in eine zweite Lage übergeht, derart, dass das Durchstoßelement beim Übergang von der ersten in die zweite Lage aus einer ersten Position in eine zweite Position verlagert wird, wobei das Durchstoßelement dabei die durchstoßbare Trennschicht durchstößt.The object is achieved according to the invention with a multi-chamber container for storing and mixing a multi-component liquid coating or adhesive system according to the preamble of
Erfindungsgemäß umfasst der Mehrkammerbehälter eine erste Kammer für eine erste Mischungskomponente und wenigstens eine weitere Kammer für eine weitere Mischungskomponente auf, wobei die erste Kammer und die wenigstens eine weitere Kammer durch ein Trennwand flüssigkeitsdicht voneinander abgetrennt sind. Die Anzahl der Kammern ist demnach nicht beschränkt, so dass der erfindungsgemäße Mehrkammerbehälter auch für flüssige Beschichtungs- oder Klebesysteme mit mehr als beispielsweise zwei Komponenten geeignet ist.According to the invention, the multi-chamber container comprises a first chamber for a first mixture component and at least one further chamber for a further mixture component, the first chamber and the at least one further chamber being separated from one another in a liquid-tight manner by a partition. The number of chambers is therefore not limited, so that the multi-chamber container according to the invention is also suitable for liquid coating or adhesive systems with more than, for example, two components.
Der besondere Vorteil des erfindungsgemäßen Mehrkammerbehälters liegt in einer sicheren Aufbewahrung der einzelnen Mischungskomponenten, ohne dass die Gefahr besteht, dass bei unsachgemäßer Handhabung des Mehrkammerbehälters Teile der Mischungskomponenten ineinander fließen können. Dies wird durch die zwischen der ersten und der wenigstens einen weiteren Kammer vorgesehene Trennwand sichergestellt. Andererseits gewährleistet das mit der durchstoßbaren Trennschicht zusammenwirkende Durchstoßelement die Herstellung einer definierten flüssigkeitsleitenden Verbindung zwischen den Kammern, so dass eine intensive Vermischung der Mischungskomponenten möglich ist. Dadurch, dass die durchstoßbare Trennschicht teilflächig in der Trennwand ausgebildet ist, ist sichergestellt, dass jederzeit ein definiertes Durchstoßen der Trennwand erfolgen kann, da aufgrund der begrenzten Ausdehnung der Trennfläche innerhalb der Trennwand ein unerwünschtes Nachfedern der Trennfläche beim Durchstoßen mittels des Durchstoßelements vermieden wird. Eine teilflächige Trennwand hat weiterhin den Vorteil, dass sie nur geringer mechanischer Belastung beim Bewegen des Mehrkammerbehälters ausgesetzt ist. So sind die beim Schütteln des mit Flüssigkeit gefüllten Behälters auf die Trennwand einwirkenden Kräfte umso größer, je größer die durchstoßbare und damit inhärent mechanisch labile Trennschicht ist. Um ein unbeabsichtigtes Vermischen durch Erschütterungen beispielsweise beim Transport der Behälter zu verhindern, ist daher eine kleinere, nicht vollflächige Trennschicht von Vorteil.The particular advantage of the multi-chamber container according to the invention lies in the safe storage of the individual mixture components without the risk of parts of the mixture components flowing into one another if the multi-chamber container is improperly handled. This is ensured by the partition wall provided between the first and the at least one further chamber. On the other hand, the piercing element cooperating with the pierceable separating layer ensures the production of a defined fluid-conducting connection between the chambers, so that intensive mixing of the mixture components is possible. The fact that the penetrable separating layer is partially formed in the separating wall ensures that a defined penetration of the separating wall can take place at any time, since, due to the limited extent of the separating surface within the separating wall, undesired rebounding of the separating surface when penetrating by means of the piercing element is avoided. Has a partial partition furthermore the advantage that it is only exposed to low mechanical stress when moving the multi-chamber container. Thus, the forces acting on the partition wall when the container filled with liquid is shaken are greater, the larger the pierceable and thus inherently mechanically unstable separating layer. In order to prevent unintentional mixing due to vibrations, for example when the container is being transported, a smaller, non-full-area separating layer is therefore advantageous.
Die Trennschicht wird bevorzugt durch ein Folienmaterial gebildet, welches einerseits haltbar und hinreichend widerstandsfähig gegen unbeabsichtigte Druckbeaufschlagung sowie die jeweils verwendeten Chemikalien ist, andererseits jedoch leicht und präzise durch das Durchstoßelement durchstoßen werden kann. Geeignete Folienmaterialien sind Metallfolien wie z.B. Aluminiumfolien, Kunststofffolien aus ABS, CA, COC, CTA, E/P, ETFE, FEP, PA, PAEK, PAN, PBT, PC, PCCE, PCO, PCT, PDCPD, PE (PE-C, PE-HD, PE-LD, PE-LLD, PE-MD, PE-UHMW, PE-ULD), PEC, PEEK, PESTUR, PESU, PET, PEUR, PHB, PI, POM, PP, PS, PTT, PUR, PVC, PVDF (Kurzbezeichnungen nach DIN EN ISO 1043-1:2012-03). Weiterhin sind Verbundfolien aus Metall und Kunststoff bevorzugt geeignet. Diese kombinieren Eigenschaften wie Verhindern von Diffusion zwischen den Mischungskomponenten der einzelnen Kammern, Siegelfähigkeit, um entsprechende Folienmaterialen dicht mit dem Material des Kammerbehälters zu verbinden, sowie mechanische Festigkeit gegen Beanspruchung durch Flüssigkeitsbewegungen in den Kammern bei Transport des Behälters und einfache Durchstoßbarkeit. Entsprechende Folienverbünde sind z.B. aus dem Verpackungsbereich für beispielsweise Lebensmittel bekannt.The separating layer is preferably formed by a film material which, on the one hand, is durable and sufficiently resistant to unintentional pressurization and the chemicals used, but on the other hand can be pierced easily and precisely by the piercing element. Suitable foil materials are metal foils such as aluminum foils, plastic foils made of ABS, CA, COC, CTA, E / P, ETFE, FEP, PA, PAEK, PAN, PBT, PC, PCCE, PCO, PCT, PDCPD, PE (PE-C, PE-HD, PE-LD, PE-LLD, PE-MD, PE-UHMW, PE-ULD), PEC, PEEK, PESTUR, PESU, PET, PEUR, PHB, PI, POM, PP, PS, PTT, PUR , PVC, PVDF (abbreviations according to DIN EN ISO 1043-1: 2012-03). Furthermore, composite foils made of metal and plastic are preferably suitable. These combine properties such as preventing diffusion between the mixture components of the individual chambers, sealability in order to tightly bond the corresponding film materials to the material of the chamber container, as well as mechanical strength against stress caused by fluid movements in the chambers during transport of the container and easy penetrability. Corresponding film composites are known, for example, from the packaging sector for foods, for example.
Erfindungsgemäß ist ferner vorgesehen, dass die wenigstens eine weitere Kammer koaxial zu der ersten Kammer angeordnet ist. Durch diese koaxiale Anordnung ist sichergestellt, dass beispielsweise bei der Benutzung des erfindungsgemäßen Mehrkammerbehälters zusammen mit einer Ausbringungseinheit für das mehrkomponentige flüssige Beschichtungs- oder Klebesystem, insbesondere einer Farbsprühpistole, vor dem Mischen keine störenden Kippmomente entstehen. Ferner lassen sich koaxiale Anordnungen durch besonders einfache konstruktive Ausgestaltungen realisieren.According to the invention it is further provided that the at least one further chamber is arranged coaxially to the first chamber. This coaxial arrangement ensures that, for example, when using the multi-chamber container according to the invention together with an application unit for the multi-component liquid coating or adhesive system, in particular a paint spray gun, no disruptive overturning moments arise before mixing. Furthermore, coaxial arrangements can be implemented by means of particularly simple structural designs.
In diesem Zusammenhang ist erfindungsgemäß ferner vorgesehen, dass die erste Kammer durch einen äußeren Behälter ausgebildet ist, wobei die wenigstens eine weitere Kammer in dem äußeren Behälter als becherförmiger Einsatz ausgebildet ist. Hierdurch wird auch der konstruktive und fertigungstechnische Aufwand reduziert, indem der Mehrkammerbehälter durch vergleichsweise wenige Elemente gebildet wird, die sich ohne Aufwand manuell oder maschinell zusammensetzen lassen.In this context, it is further provided according to the invention that the first chamber is formed by an outer container, the at least one further chamber in the outer container being designed as a cup-shaped insert. This also reduces the design and manufacturing effort in that the multi-chamber container is formed by comparatively few elements that can be assembled manually or by machine without any effort.
Nach einer weiteren vorteilhaften Ausgestaltung der Erfindung beträgt das relative Volumenverhältnis der ersten Kammer für die erste Mischungskomponente zur wenigstens einen weiteren Kammer für die weitere Mischungskomponente(n) 1:1 bis 9:1, bevorzugt 1:1 bis 5:1. Dies berücksichtigt die üblichen miteinander zu mischenden Volumina bei der Bereitstellung und Verarbeitung gängiger flüssiger Beschichtungs- oder Klebesysteme.According to a further advantageous embodiment of the invention, the relative volume ratio of the first chamber for the first mixture component to at least one further chamber for the further mixture component (s) is 1: 1 to 9: 1, preferably 1: 1 to 5: 1. This takes into account the usual volumes to be mixed with one another when preparing and processing common liquid coating or adhesive systems.
Erfindungsgemäß ist ferner vorgesehen, dass das Durchstoßelement hohl, insbesondere zylindrisch hohl, ausgebildet ist und wenigstens zwei längsversetzte Öffnungen aufweist zur Einleitung einer der ersten oder der weiteren Mischungskomponente in die Kammer der jeweils anderen Mischungskomponente. Hierdurch ist es somit nicht erforderlich, dass die Trennschicht auch in der Umgebung des Durchstoßelements (unkontrolliert) zerstört wird, um ein Mischen der Mischungskomponenten zu ermöglichen, indem eine der Mischungskomponenten gleichsam am Durchstoßelement vorbei in die jeweils andere Kammer fließt. Vielmehr kann der Mischungsprozess, insbesondere die Mischungsgeschwindigkeit beispielsweise quantitativ durch die Größe der Öffnungen und die Innenabmessungen des Durchstoßelements präzise beeinflusst werden. Sinnvollerweise ist zumindest eine der beiden zueinander längsversetzten Öffnungen in der Stirnfläche des Durchstoßelements, insbesondere im Bereich einer Schneide, angeordnet.According to the invention it is further provided that the piercing element is hollow, in particular cylindrically hollow, and has at least two longitudinally offset openings for introducing one of the first or the further mixture component into the chamber of the respective other mixture component. As a result, it is therefore not necessary for the separating layer to be destroyed (in an uncontrolled manner) in the vicinity of the piercing element in order to enable the mixture components to be mixed, in that one of the mixing components flows past the piercing element into the other chamber. Rather, the mixing process, in particular the mixing speed, can be precisely influenced, for example quantitatively, by the size of the openings and the internal dimensions of the piercing element. At least one of the two longitudinally offset openings is expediently arranged in the end face of the piercing element, in particular in the region of a cutting edge.
Das Durchstoßelement kann aus unterschiedlichen Materialien gefertigt sein und ebenso unterschiedliche Geometrien aufweisen. Bevorzugt ist das Durchstoßelement stift- oder stabförmig ausgebildet und weist eine geschärfte Spitze oder umlaufende Schneidkante auf, die ein einfaches und sicheres Durchstoßen der Trennschicht ermöglicht. Die Geometrie des Durchstoßelements soll dabei derart gestaltet sein, dass unabhängig von der vertikalen Position des Durchstoßelements während und nach dem Durchstoßen eine restlose Entleerung der Flüssigkeit aus der oberen Kammer gewährleistet ist und die Austrittsöffnung nicht blockiert wird.The piercing element can be made of different materials and also have different geometries. The piercing element is preferably designed in the form of a pin or rod and has a sharpened tip or circumferential cutting edge which enables the separating layer to be pierced easily and safely. The geometry of the piercing element should be designed in such a way that, regardless of the vertical position of the piercing element, complete emptying of the liquid from the upper chamber is ensured during and after the piercing and the outlet opening is not blocked.
Erfindungsgemäß ist das Durchstoßelement ferner auf einer gewölbten Stützfläche abgestützt, wobei die gewölbte Stützfläche bei Kraftbeaufschlagung aus einer ersten Lage in eine zweite Lage übergeht, derart, dass das Durchstoßelement beim Übergang von der ersten in die zweite Lage aus einer ersten Position in eine zweite Position verlagert wird, wobei das Durchstoßelement dabei die durchstoßbare Trennschicht durchstößt. Hierdurch wird ein besonders präzises Durchstoßen der Trennschicht ermöglicht und gleichzeitig die Bewegung des Durchstoßelements derart begrenzt, dass bei versehentlich zu hoher Kraftbeaufschlagung des Durchstoßelements keine Beschädigung des Mehrkammerbehälters erfolgt. Bevorzugt geht dabei die gewölbte Stützfläche erst bei Kraftbeaufschlagung oberhalb einer definierten Schwelle aus der ersten Lage in die zweite Lage über.According to the invention, the piercing element is also supported on a curved support surface, the curved support surface transitioning from a first position to a second position when force is applied, in such a way that the piercing element is displaced from a first position to a second position during the transition from the first to the second position wherein the piercing element pierces the pierceable separating layer. This enables particularly precise piercing of the separating layer and at the same time limits the movement of the piercing element in such a way that the multi-chamber container is not damaged if the piercing element is accidentally subjected to excessive force. Preferably, the curved support surface only changes from the first position to the second position when a force is applied above a defined threshold.
Wie erwähnt, kann der erfindungsgemäße Mehrkammerbehälter mehr als zwei Kammern umfassen. Bei mehr als zwei Mischungskomponenten, beispielsweise drei Mischungskomponenten, kann die Trennwand zwischen den Kammern derart ausgestaltet sein, dass die erste Kammer über eine gemeinsame Trennwand von der zweiten und dritten Kammer abgetrennt ist, wobei ein erster Trennwandabschnitt die erste Kammer von der zweiten Kammer abtrennt und ein zweiter Trennwand die erste Kammer von der dritten Kammer abtrennt. In diesem Fall weist jeder Trennwandabschnitt eine bezogen auf den jeweiligen Trennwandabschnitt teilflächig ausgebildete durchstoßbare Trennschicht auf, die jeweils mit einem Durchstoßelement durchstoßbar ausgebildet ist. Dabei kann für die zweite und die dritte Kammer jeweils ein Durchstoßelement vorgesehen sein, welches den jeweiligen Trennwandabschnitt bei Betätigung durchstößt, so dass sich im Ergebnis die Komponenten bevorzugt in der ersten Kammer vermischen.As mentioned, the multi-chamber container according to the invention can comprise more than two chambers. In the case of more than two mixture components, for example three mixture components, the partition between the chambers can be designed in such a way that the first chamber is separated from the second and third chambers via a common partition, a first partition section separating the first chamber from the second chamber and a second partition separates the first chamber from the third chamber. In this case, each partition wall section has a pierceable partition layer which is formed over part of the surface of the respective partition wall section and which is each pierceable with a piercing element. A piercing element can be provided for each of the second and third chambers, which pierces the respective partition wall section when actuated, so that as a result the components preferably mix in the first chamber.
Ebenso kann nach einer Ausgestaltung der Erfindung vorgesehen sein, dass wiederum bei drei Mischungskomponenten und drei Kammern eine Kammer zwischen den beiden anderen Kammern in der Weise angeordnet ist, dass beispielsweise die erste von der zweiten Kammer durch eine erste Trennwand abgetrennt ist und die zweite von der dritten Kammer durch eine zweite Trennwand abgetrennt ist. Jeder der beiden Trennwände weist erfindungsgemäß jeweils eine teilflächig ausgebildete Trennschicht auf. Liegen die beiden Trennwände in der Flucht zueinander, können die Trennschichten beider Trennwände bevorzugt durch ein einziges Durchstoßelement nacheinander durchstoßen werden.Likewise, according to one embodiment of the invention, it can be provided that again with three mixture components and three chambers, one chamber is arranged between the two other chambers in such a way that, for example, the first is separated from the second chamber by a first partition and the second is separated from the third chamber is separated by a second partition. According to the invention, each of the two dividing walls has a dividing layer formed over part of the area. If the two partition walls are in alignment with one another, the partition layers of both partition walls can preferably be pierced one after the other by a single piercing element.
Nach einer vorteilhaften Ausgestaltung der Erfindung ist die sich teilflächig über die Trennwand erstreckende Trennschicht zentral in der Trennwand angeordnet. Bevorzugt ist dabei die die Trennschicht umgebende Trennwand konisch ausgebildet. Hierdurch wird schwerkraftbedingt ein Auslaufen der einen Mischungskomponente in die andere Kammer und dort das Mischen der beiden Mischungskomponenten nach erfolgtem Durchstoßen der Trennschicht erleichtert. Um ein schnelles und vollständiges Abfließen der einen Mischungskomponente zu ermöglichen, beträgt der halbe Öffnungswinkel des Konus zur Längsachse des Mehrkammerbehälters bevorzugt nicht mehr als 85°, bevorzugt nicht mehr als 80°.According to an advantageous embodiment of the invention, the separating layer, which extends partially over the separating wall, is arranged centrally in the separating wall. The partition surrounding the partition is preferably conical. This facilitates the leakage of one mixture component into the other chamber due to gravity and there the mixing of the two mixture components after the separation layer has been pierced. In order to enable the one mixture component to drain off quickly and completely, half the opening angle of the cone to the longitudinal axis of the multi-chamber container is preferably not more than 85 °, preferably not more than 80 °.
Als Material zur Herstellung der Mehrkammerbehälter und der ersten Kammer und/oder der wenigstens einen weiteren Kammer kommen Kunststoffe, Metalle, Glas, Keramik sowie Verbundmaterialien sowie beschichtete Materialien sowie Kombinationen der vorgenannten Materialen zum Einsatz. Ihre Auswahl richtet sich nach den Anforderungen, die sich durch die Materialeigenschaften der Mischkomponenten ergeben, sowie aus dem zu erwarteten mechanischen Beanspruchungsprofil (beispielsweise Benutzung in einer Lackierwerkstatt), In jedem Fall dürfen sich die Mischkomponenten durch den Kontakt mit dem Material oder den Materialien weder derart verändern, dass diese unbrauchbar werden, noch dürfen die Mischkomponenten selbst das oder die Materialien verändern, so dass diese ihre Funktion als Verpackung für die Mischkomponenten nicht erfüllen können. Die Auswahl der Materialien erfolgt daher nach einfachen Tests, indem Mischkomponenten in Verpackungen aus dem jeweiligen Material gelagert werden und regelmäßig Material und Mischkomponente überprüft werden, Bevorzugt ist Kunststoff als Material, insbesondere PA, PBT, PE (PE-C, PE-HD, PE-LD, PE-LLD, PE-MD, PE-UHMW, PE-ULD), PET (Kurzbezeichnungen nach DIN EN ISO 1043-1:2012-03). Um die Beständigkeit der Kammermaterialien gegen beispielsweise lösemittelhaltige Mischkomponenten zu erhöhen, kann es zweckmäßig sein, die Kunststoffe mindestens an den Flächen, die in Kontakt mit den Mischkomponenten stehen, mit entsprechend beständigen Beschichtungen zu versehen.The material used to manufacture the multi-chamber container and the first chamber and / or the at least one further chamber are plastics, metals, glass, ceramics and composite materials and coated materials and combinations of the aforementioned materials. Your selection is based on the requirements resulting from the material properties of the mixing components, as well as the expected mechanical stress profile (e.g. use in a paint shop) change so that they become unusable, nor are the mixed components themselves allowed to change the material or materials so that they cannot fulfill their function as packaging for the mixed components. The selection of the materials is therefore based on simple tests, in that mixed components are stored in packaging made of the respective material and the material and mixed component are regularly checked.Plastic is preferred as the material, in particular PA, PBT, PE (PE-C, PE-HD, PE -LD, PE-LLD, PE-MD, PE-UHMW, PE-ULD), PET (abbreviations according to DIN EN ISO 1043-1: 2012-03). In order to increase the resistance of the chamber materials to, for example, solvent-based mixing components, it can be expedient to provide the plastics with correspondingly resistant coatings at least on the surfaces that are in contact with the mixing components.
Bevorzugt sind der Mehrkammerbehälter und die erste Kammer und/oder die wenigstens eine weitere Kammer aus einem transparenten oder transluzenten Material gebildet. Hierdurch kann auf einfache Weise der jeweilige Füllstand der Mischkomponenten in den Kammern ermittelt werden. Ferner kann das Durchstoßen der Trennschicht beobachtet und beispielsweise durch Schütteln des Mehrkammerbehälters unterstützt werden.The multi-chamber container and the first chamber and / or the at least one further chamber are preferably formed from a transparent or translucent material. This allows the respective filling level of the mixing components in the chambers to be determined in a simple manner. Furthermore, the penetration of the separating layer can be observed and supported, for example, by shaking the multi-chamber container.
Um die aus den Mischungskomponenten gebildete Mischung aus dem Mehrkammerbehälter auszutragen und beispielsweise in eine Sprühpistole zu leiten, weist der Mehrkammerbehälter bevorzugt eine verschließbare Auslauföffnung auf. Ist entsprechend dem Vorstehenden die erste Kammer durch einen äußeren Behälter ausgebildet, wobei die wenigstens eine weitere Kammer in dem äußeren Behälter als becherförmiger Einsatz ausgebildet ist, so ist die Auslauföffnung bevorzugt in dem die erste Kammer ausbildenden äußeren Behälter vorgesehen.In order to discharge the mixture formed from the mixture components from the multi-chamber container and, for example, to direct it into a spray gun, the multi-chamber container preferably has a closable outlet opening. If, according to the above, the first chamber is formed by an outer container, the at least one further chamber in the outer container being designed as a cup-shaped insert, the outlet opening is preferably provided in the outer container forming the first chamber.
Nach einer besonders vorteilhaften Ausgestaltung der Erfindung ist vorgesehen, dass an der Auslauföffnung eine Katalysatorkapsel enthaltend ein Katalysatormaterial angeordnet ist, derart, dass die aus der ersten und der weiteren Mischungskomponente gebildete Mischung beim Ausströmen mit dem Katalysatormaterial in Kontakt kommt. Beispielsweise kann die aus den Mischungskomponenten gebildete Mischung eine vergleichsweise lange Verarbeitungszeit (Topfzeit) aufweisen, so dass eine Verarbeitung nicht unmittelbar nach dem Mischungsvorgang erfolgen muss, was in Abhängigkeit von der jeweiligen Anwendung einen Vorteil darstellt. Sobald die Mischung dann mit dem in der Katalysatorkapsel enthaltenen Katalysatormaterial in Kontakt kommt erfolgt eine beschleunigte chemische Reaktion (Vernetzung), durch welche die Verarbeitungszeit verkürzt wird, so dass beispielsweise bei einem sich unmittelbar daran anschließenden Ausbringen der Mischung eine schnelle Aushärtung auf einer Oberfläche erfolgt.According to a particularly advantageous embodiment of the invention, a catalyst capsule containing a catalyst material is arranged at the outlet opening in such a way that the mixture formed from the first and the further mixture component comes into contact with the catalyst material as it flows out. For example, the mixture formed from the mixture components can have a comparatively long processing time (pot life), so that processing does not have to take place immediately after the mixing process, which is an advantage depending on the particular application. As soon as the mixture comes into contact with the catalyst material contained in the catalyst capsule, an accelerated chemical reaction (crosslinking) takes place, which shortens the processing time, so that, for example, when the mixture is applied immediately after this, rapid curing takes place on a surface.
Dazu kann das Katalysatormaterial in der Form eines Katalysatorbettes gestaltet sein, welches einen auf einem Substrat reversibel sorbierten Katalysator enthält. Als Katalysatorbett wird hierbei ein definiertes Volumen angesehen, welches Substrat und Katalysator enthält, wobei der Katalysator das Substrat nicht verlassen kann (beispielsweise durch Verwendung von Siebeinsätzen).For this purpose, the catalyst material can be designed in the form of a catalyst bed which contains a catalyst reversibly sorbed on a substrate. A defined volume, which contains substrate and catalyst, is regarded as a catalyst bed, the catalyst not being able to leave the substrate (for example by using sieve inserts).
Es ist erfindungsgemäß vorgesehen, dass der Katalysator reversibel auf dem Substrat sorbiert ist. Hierbei kann sowohl eine Adsorption als auch eine Absorption in Frage kommen. Die Sorption kann dadurch erfolgen, dass das Substrat mit einer Lösung des Katalysators getränkt wird und anschließend das Lösungsmittel verdampft wird. Dass die Sorption reversibel ist, bedeutet, dass ein sorbierter Katalysator auch wieder an eine flüssige Phase in einer zur Katalyse der Reaktion wirksamen Menge abgegeben werden kann. Daher ist es auch bevorzugt, dass das Substrat nicht Graphit oder Aktivkohle ist.According to the invention, it is provided that the catalyst is reversibly sorbed on the substrate. Both adsorption and absorption can be considered here. The sorption can take place in that the substrate is impregnated with a solution of the catalyst and then the solvent is evaporated. The fact that the sorption is reversible means that a sorbed catalyst can also be given back to a liquid phase in an amount effective to catalyze the reaction. Therefore, it is also preferred that the substrate is not graphite or activated carbon.
Geeignete Substrate können feste Katalysatoren und Katalysatorträger, wie sie aus der heterogenen Katalyse bekannt sind, sein. Hierunter fallen auch Zeolithe/Molekularsiebe wie Zeolith A und Zeolith X und sonstige poröse Keramiken. Beispiele für geeignete Katalysatoren richten sich nach der Art der Mischkomponenten. Soll beispielsweise eine Polyurethanreaktion katalysiert werden, da eine Mischkomponenten eine isocyanathaltige und die andere Mischkomponenten eine isocyanatreaktive Verbindungen enthält, so sind Titan-, Zirkonium-, Bismut-, Zinn- und/oder eisenhaltige Katalysatoren bevorzugt. Besonders bevorzugt sind in diesem Fall Dialkylzinndicarboxylate und Bismutcarboxylate.Suitable substrates can be solid catalysts and catalyst supports, as they are known from heterogeneous catalysis. This also includes zeolites / molecular sieves such as zeolite A and zeolite X and other porous ceramics. Examples of suitable catalysts depend on the type of mixing components. For example, if a polyurethane reaction is to be catalyzed because one mixed component contains an isocyanate-containing compound and the other mixed component contains an isocyanate-reactive compound, then titanium, zirconium, bismuth, tin and / or iron-containing catalysts are preferred. Dialkyltin dicarboxylates and bismuth carboxylates are particularly preferred in this case.
Die Auslauföffnung kann mit einem einfachen, platzsparenden Verschluss, beispielsweise einem Schraubverschluss, verschlossen sein. Es kann allerdings erforderlich sein, bei Verbindung des Mehrkammerbehälters beispielsweise mit einer Sprühpistole ein Ventil oder eine separate Auslaufdüse vorzusehen, um ein kontrolliertes Ausbringen der Mischung sicherzustellen. Hierzu kann nach einer vorteilhaften Ausgestaltung der Erfindung vorgesehen sein, dass der Mehrkammerbehälter eine Ausnehmung zur Aufnahme eines Auslaufventils aufweist, wobei das Auslaufventils mit der Auslauföffnung verbindbar ist. Handelt es sich bei dem Mehrkammerbehälter beispielsweise um ein spritzgegossenes Teil, so kann eine an die Geometrie des Auslaufventils angepasste Form der Ausnehmung ohne weiteres vorgesehen sein. Bevorzugt wird die Auslaufdüse in diese Ausnehmung über eine Klemmung, d.h. kraftschlüssig, gehalten. Hierdurch wird vermieden, dass die Auslaufdüse in der Phase der Lagerung abhandenkommt.The outlet opening can be closed with a simple, space-saving closure, for example a screw closure. However, when the multi-chamber container is connected, for example to a spray gun, it may be necessary to provide a valve or a separate outlet nozzle in order to ensure a controlled discharge of the mixture. To this end, according to an advantageous embodiment of the invention, it can be provided that the multi-chamber container has a recess for receiving an outlet valve, the outlet valve being connectable to the outlet opening. If the multi-chamber container is, for example, an injection-molded part, a shape of the recess adapted to the geometry of the outlet valve can readily be provided. The outlet nozzle is preferably held in this recess by means of a clamp, i.e. in a non-positive manner. This prevents the outlet nozzle from getting lost during the storage phase.
Um zu erreichen, dass eine restlose Entleerung der einen Kammer nach Durchstoßung der durchstoßbaren Trennschicht stattfindet, kann das Durchstoßelement, wie bereits erwähnt, auf verschiedene Weise geformt sein. Bevorzugt sind zylindrische stabförmige Formen. Um ein präzises Durchstoßen der Trennschicht sicherzustellen, ist nach einer weiteren Ausgestaltung der Erfindung vorgesehen, dass die erste Kammer oder die wenigstens eine weitere Kammer eine Führung für das Durchstoßelement aufweist. Es versteht sich, dass die Führung auf die jeweilige Geometrie des Durchstoßelements angepasst ist, um eine möglichst präzise bevorzugt axiale Durchstoßbewegung zu ermöglichen.In order to ensure that the one chamber is completely emptied after the pierceable separating layer has been pierced, the piercing element can, as already mentioned, be shaped in various ways. Cylindrical rod-shaped shapes are preferred. To be precise To ensure that the separating layer is pierced, a further embodiment of the invention provides that the first chamber or the at least one further chamber has a guide for the piercing element. It goes without saying that the guide is adapted to the respective geometry of the piercing element in order to enable a preferably axial piercing movement as precisely as possible.
Nach einer vorteilhaften Ausgestaltung der Erfindung kann weiterhin vorgesehen sein, dass die erste und/oder die wenigstens eine weitere Kammer eine verschließbare Öffnung zur Einleitung eines Lösungsmittels aufweist. Eine der Öffnungen kann dabei mit der Auslauföffnung identisch sein.According to an advantageous embodiment of the invention, it can furthermore be provided that the first and / or the at least one further chamber has a closable opening for introducing a solvent. One of the openings can be identical to the outlet opening.
Ein weiterer Aspekt der vorliegenden Erfindung betrifft ein System zur Ausbringung einer Lackbeschichtung oder eines Klebstoffes umfassend einen Mehrkammerbehälter zum Aufbewahren und Mischen eines mehrkomponentigen flüssigen Beschichtungs- oder Klebesystems nach einem der Ansprüche 1 bis 12 sowie einer mit dem Mehrkammerbehälter lösbar verbindbaren Ausbringungseinheit insbesondere eine Sprühpistole.Another aspect of the present invention relates to a system for applying a paint coating or an adhesive comprising a multi-chamber container for storing and mixing a multi-component liquid coating or adhesive system according to one of
Das System ist vergleichsweise einfach aufgebaut und ermöglicht das intensive Mischen der Mischungskomponenten allein unterstützt durch Schütteln des Behälters. Im Übrigen gelten die vorstehend im Zusammenhang mit dem Mehrkammerbehälter genannten Vorteile entsprechend.The system has a comparatively simple structure and enables the mixing components to be mixed intensively, assisted by shaking the container. In addition, the advantages mentioned above in connection with the multi-chamber container apply accordingly.
Verfahrensmäßig wird die eingangs genannte Aufgabe mit einem Verfahren zum Mischen eines mehrkomponentigen flüssigen Beschichtungs- oder Klebesystems in einem Mehrkammerbehälter nach einem der Ansprüche 1 bis 12, umfassend die folgenden Verfahrensschritte gelöst:
- Bereitstellen der ersten Mischungskomponente in der als äußerer Behälter ausgebildeten ersten Kammer,
- Bereitstellen der einen weiteren Mischungskomponente in der wenigstens einen weiteren Kammer,
- Durchstoßen der von der Trennwand umfassten durchstoßbaren Trennschicht mittels des hohlen, auf der gewölbten Stützfläche abgestützten Durchstoßelementes, wobei das Durchstoßelement aus der ersten Lage in die zweite Lage übergeht und wobei die erste Mischungskomponente oder die eine weitere Mischungskomponente durch das hohle Durchstoßelement in die Kammer der jeweils anderen Mischungskomponente eingeleitet wird, und
- Vermischen der ersten Mischungskomponente mit der einen weiteren Mischungskomponente, bevorzugt unterstützt durch Schütteln des Mehrkammerbehälters.
- Providing the first mixture component in the first chamber designed as an outer container,
- Providing the one further mixture component in the at least one further chamber,
- Piercing of the pierceable partition comprised by the partition wall by means of the hollow piercing element supported on the arched support surface, the piercing element merging from the first layer into the second layer and wherein the first mixture component or the one further mixture component through the hollow piercing element into the chamber of the respective another mixture component is introduced, and
- Mixing the first mixture component with the one further mixture component, preferably assisted by shaking the multi-chamber container.
Das erfindungsgemäße Verfahren lässt sich einfach und kostengünstig durchführen. Im Übrigen gelten die vorstehend im Zusammenhang mit dem Mehrkammerbehälter genannten Vorteile auch für das Verfahren. Ebenso gelten die im Zusammenhang mit dem erfindungsgemäßen Verfahren genannten Vorteile sinngemäß auch für den Mehrkammerbehälter.The method according to the invention can be carried out simply and inexpensively. In addition, the advantages mentioned above in connection with the multi-chamber container also apply to the method. The advantages mentioned in connection with the method according to the invention also apply accordingly to the multi-chamber container.
Als erfindungsgemäß vorgesehene Mischungskomponenten kommen Beschichtungsmaterialien, insbesondere Lack und Klebstoffe zum Einsatz, bei denen es von Vorteil ist, zwei oder mehr Komponenten während Transport und Lagerung getrennt aufzubewahren und diese erst kurz vor der Applikation zu vermischen. Beispiele sind Beschichtungsmaterialien bei denen die beiden Komponenten zueinander komplementäre chemische Gruppen aufweisen. Beispielhaft erwähnt seien -NCO und -OH, -SH und/oder -NH, weiterhin Epoxid und Amin, weiterhin Akzeptor und Donorverbindungen für Michael-Additionen. Die einzelnen Mischkomponenten können zusätzlich noch Katalysatoren für die Reaktion der komplementären Gruppen enthalten. Alternativ können in der einen Komponente polymerisierbare chemische Gruppen vorhanden sein, während in der anderen Komponente entsprechende Initiatoren oder Aktivatoren enthalten sind. Beispielsweise können in der einen Komponente vinylische Gruppen wie Acrylate oder Methacrylate sowie in der anderen Komponente Peroxide enthalten sein. Der erfindungsgemäße Mehrkammerbehälter ist insbesondere für Mischkomponenten niedriger Viskosität von Vorteil. Insbesondere weisen die Mischkomponenten eine Viskosität unter 10.000 mPas, besonders bevorzugt unter 2.000 mPas und ganz besonders bevorzugt unter 250 mPas auf. Die Angaben zur Viskosität beziehen sich auf Messungen nach DIN EN ISO 3219/A3 bei 23 °C und einem Schergefälle von 100 s-1 gemessen mit einen Gerät Physica MCR 51 Rheometer der Fa. Anton Paar Germany GmbH (DE).Coating materials, in particular lacquer and adhesives, are used as mixture components provided according to the invention, in which it is advantageous to keep two or more components separately during transport and storage and to mix them only shortly before application. Examples are coating materials in which the two components have chemical groups that are complementary to one another. Examples include -NCO and -OH, -SH and / or -NH, furthermore epoxide and amine, furthermore acceptor and donor compounds for Michael additions. The individual mixing components can also contain catalysts for the reaction of the complementary groups. Alternatively, polymerizable chemical groups can be present in one component, while corresponding initiators or activators are contained in the other component. For example, vinylic groups such as acrylates or methacrylates can be contained in one component and peroxides in the other component. The multi-chamber container according to the invention is particularly advantageous for mixed components of low viscosity. In particular, the mixed components have a viscosity below 10,000 mPas, particularly preferably below 2,000 mPas and very particularly preferably below 250 mPas. The viscosity data relate to measurements according to DIN EN ISO 3219 / A3 at 23 ° C. and a shear gradient of 100 s -1, measured with a
Es ist weiterhin von Vorteil für die Vermischung, wenn die Viskosität der beiden Mischkomponenten nicht zu unterschiedlich ist. Die Viskosität der viskoseren Komponente soll daher nicht mehr als 500%, bevorzugt 150%, insbesondere bevorzugt nicht 50% über der anderen Komponente liegen.It is also advantageous for mixing if the viscosity of the two mixing components is not too different. The viscosity of the more viscous component should therefore not be more than 500%, preferably 150%, particularly preferably not 50%, higher than the other component.
Nach einer vorteilhaften Ausgestaltung der Erfindung beträgtdas Volumenverhältnis zwischen der ersten Mischungskomponente in der ersten Kammer und der einen weiteren Mischungskomponente in der wenigstens einen weiteren Kammer 1:1 bis 9:1, bevorzugt 1:1 bis 5:1.According to an advantageous embodiment of the invention, the volume ratio between the first mixture component in the first chamber and the one further mixture component in the at least one further chamber is 1: 1 to 9: 1, preferably 1: 1 to 5: 1.
Im Folgenden wird die Erfindung anhand einer Ausführungsbeispiel darstellenden Zeichnung näher erläutert. Es zeigen:
- Fig. 1
- einen Mehrkammerbehälter zum Aufbewahren und Mischen eines mehrkomponentigen flüssigen Beschichtungs- oder Klebesystems in perspektivischer Ansicht,
- Fig. 2
- den Mehrkammerbehälter der
Fig. 1 in transparenter Ausführung in perspektivischer Ansicht, - Fig. 3
- der Mehrkammerbehälter der
Fig. 2 in einer Explosionsansicht, - Fig. 4
- den Mehrkammerbehälter der
Fig. 2 in seitlichem Längsschnitt, - Fig. 5
- den Mehrkammerbehälter der
Fig. 2 in perspektivischer Längsschnittansicht, - Fig. 6a-c
- das Mischen eines zweikomponentigen Lacksystems in einem Mehrkammerbehälter gemäß
Fig. 1 oder 2 , - Fig. 7
- den Mehrkammerbehälter der
Fig. 1 in perspektivischer Ansicht mit einem Auslaufdüse, - Fig. 8
- den Mehrkammerbehälter der
Fig. 1 in perspektivischer Ansicht mit einem Auslaufdüse mit integrierter Katalysatorkapsel und - Fig. 9a, b
- die Verbindung eines Mehrkammerbehälters gemäß
Fig. 1 mit einer Sprühpistole.
- Fig. 1
- a multi-chamber container for storing and mixing a multi-component liquid coating or adhesive system in a perspective view,
- Fig. 2
- the multi-chamber container of the
Fig. 1 in a transparent design in a perspective view, - Fig. 3
- the multi-chamber container of the
Fig. 2 in an exploded view, - Fig. 4
- the multi-chamber container of the
Fig. 2 in lateral longitudinal section, - Fig. 5
- the multi-chamber container of the
Fig. 2 in perspective longitudinal sectional view, - Figures 6a-c
- the mixing of a two-component paint system in a multi-chamber container according to
Fig. 1 or 2 , - Fig. 7
- the multi-chamber container of the
Fig. 1 in a perspective view with an outlet nozzle, - Fig. 8
- the multi-chamber container of the
Fig. 1 in a perspective view with an outlet nozzle with integrated catalyst capsule and - Figures 9a, b
- the connection of a multi-chamber container according to
Fig. 1 with a spray gun.
Die erste Kammer 10 wird vorliegend durch den äußeren Behälter 1a des Mehrkammerbehälters 1 gebildet, während die zweite Kammer 20 als becherförmiger Einsatz in dem äußeren Behälter 1a ausgebildet ist. Ferner wird die Trennwand 30 mit der durchstoßbaren Trennschicht 40 durch den Boden des becherförmigen Einsatzes des zweiten Kammer 20 gebildet. Wie insbesondere in der Längsschnittansicht der
Wie insbesondere in der Explosionsdarstellung der
Wie in den
Im Zusammenhang mit den
Durch entsprechenden Druck auf den Verschluss 55 wird das Durchstoßelement axial in Richtung der Trennschicht 40 bewegt, wobei die Schneide 52 die Trennschicht präzise durchstößt. Die axiale Bewegung wird dabei dadurch begrenzt, dass die gewölbte Fläche 61 des zweiten schalenförmigen Einsatzes 60 bevorzugt mittels einer Schnappbewegung aus der Ruheposition, in der die gewölbte Fläche 61 bezogen auf den zweiten schalenförmigen Einsatz 60 nach innen gewölbt ist (
Dabei beginnen die Langlöcher 51 des Durchstoßelements 50 und die Langlöcher 22 der zylindrischen Führung 21 zu fluchten, so dass eine flüssigkeitsleitende Verbindung zwischen der zweiten Kammer 20 und dem inneren Volumen des hohl ausgebildeten Durchstoßelements 50 entsteht, wie in
In
Die
Claims (13)
- Multichamber vessel (1, 1*) for storing and mixing a multicomponent liquid coating or adhesive system (M) having a first chamber (10) for a first mixture component (B) and at least one further chamber (20) for a further mixture component (H), where the first chamber (10) and the at least one further chamber (20) are divided from one another in a liquid-tight manner by at least one dividing wall (30), where the dividing wall (30) comprises a penetrable dividing layer (40), and having at least one penetrating element (50) for penetrating the penetrable dividing layer (40) in such a way that the first and the one further mixture components (B, H) mix in the first or the at least one further chamber (10, 20),
where the at least one further chamber (20) is arranged coaxially relative to the first chamber (10), where the first chamber (10) further takes the form of an outer vessel (1a, 1a*), where the at least one further chamber (20) is designed as an insert in the form of a cup in the outer vessel (1a, 1a*), where the dividing layer (40) forms part of the area of the dividing wall (30), where the penetrating element (50) is in hollow form, especially hollow cylindrical form, and has at least two longitudinally offset openings (51) for introduction of one of the first or further mixture components (B, H) into the chamber (10, 20) of the respective other mixture component (H, B), where the penetrating element (50) is further braced on a curved brace surface (61) which moves from a first location to a second location when a force above a pressure threshold is exerted, in such a way that the penetrating element (50) is moved from a first position to a second position at the transition from the first to the second location, where the penetrating element (50) penetrates the penetrable dividing layer (40). - Multichamber vessel (1, 1*) according to Claim,
characterized in that the volume ratio between the first chamber (10) for the first mixture component (B) and the at least one further chamber (20) for the further mixture component (H) is 1:1 to 9:1, preferably 1:1 to 5:1. - Multichamber vessel (1, 1*) according to Claim 1 or 2,
characterized in that the dividing layer (40) is arranged centrally in the dividing wall (30), - Multichamber vessel (1, 1*) according to any of Claims 1 to 3,
characterized in that the dividing wall (30) surrounding the dividing layer (40) is in conical form. - Multichamber vessel (1, 1*) according to any of Claims 1 to 4,
characterized in that the multichamber vessel (1, 1*) and the first chamber (10) and/or the at least one further chamber (20) are formed from a transparent or translucent material. - Multichamber vessel (1, 1*) according to any of Claims 1 to 5,
characterized in that the multichamber vessel (1, 1*) has a closable outflow opening (1d, 1d*) for the mixture (M) formed from the first and further mixture components (B, H). - Multichamber vessel (1, 1*) according to Claim 6,
characterized in that a catalyst capsule (70) containing a catalyst material is disposed at the outflow opening, in such a way that the mixture (M) formed from the first and further mixture components (B, H) comes into contact with the catalyst material as it flows out. - Multichamber vessel (1, 1*) according to Claim 6 or 7,
characterized in that the multichamber vessel (1, 1*) has a recess for accommodation, especially in a force-fitting manner, of an outflow nozzle (70), where the outflow nozzle is connectable to the outflow opening (1d, 1d*). - Multichamber vessel (1, 1*) according to any of Claims 1 to 8,
characterized in that the first chamber (10) or the at least one further chamber (20) has a guide for the penetrating element (21) . - Multichamber vessel (1, 1*) according to any of Claims 1 to 9,
characterized in that the first and/or the at least one further chamber (10, 20) has a closable opening (54) for introducing a solvent. - System for deploying a paint coating or an adhesive, comprising a multichamber vessel (1, 1*) for storing and mixing a multicomponent liquid coating or adhesive system (M) according to any of Claims 1 to 10, and a deployment unit, especially a spray gun (S), releasably connectable to the multichamber vessel (1, 1*).
- Method of mixing a multicomponent liquid coating or adhesive system in a multichamber vessel (1, 1*) according to any of Claims 1 to 10, comprising the following method steps:- providing the first mixture component (B) in the first chamber (10) designed as the outer vessel (1a, 1a*),- providing the one further mixture component (H) in the at least one further chamber (20),- penetrating the penetrable dividing layer (40) encompassed by the dividing wall (30) by means of the hollow penetrating element (50) braced on the curved brace surface (61), where the penetrating element (50) moves from the first location into the second location and where the first mixture component (B) or the one further mixture component (H) is introduced through the hollow penetrating element into the chamber (10, 20) of the respective other mixture component (H, B), and- mixing the first mixture component (B) with the one further mixture component (H), preferably assisted by agitation of the multichamber vessel (1, 1*).
- Method according to Claim 12,
characterized in that the volume ratio between the first mixture component (B) in the first chamber (10) and the one further mixture component (H) in the at least one further chamber (20) is 1:1 to 9:1, preferably 1:1 to 5:1.
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP18158105 | 2018-02-22 | ||
EP18168745.0A EP3560582A1 (en) | 2018-04-23 | 2018-04-23 | Container with multiple chambers for storing and mixing a multicomponent liquid coating or gluing system |
PCT/EP2019/054354 WO2019162397A1 (en) | 2018-02-22 | 2019-02-21 | Multiple-chamber container for storing and mixing a multi-component liquid coating or adhesive system |
Publications (2)
Publication Number | Publication Date |
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EP3755456A1 EP3755456A1 (en) | 2020-12-30 |
EP3755456B1 true EP3755456B1 (en) | 2021-12-08 |
Family
ID=65411891
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
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EP19705206.1A Active EP3755456B1 (en) | 2018-02-22 | 2019-02-21 | Container with multiple chambers for storing and mixing a multicomponent liquid coating or gluing system |
Country Status (5)
Country | Link |
---|---|
US (1) | US11911735B2 (en) |
EP (1) | EP3755456B1 (en) |
CN (1) | CN111867715B (en) |
ES (1) | ES2906469T3 (en) |
WO (1) | WO2019162397A1 (en) |
Families Citing this family (3)
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DE102020120229A1 (en) | 2020-07-31 | 2022-02-03 | Sata Gmbh & Co. Kg | Gravity cup for a spray gun with an aeration device |
USD1003432S1 (en) * | 2021-06-17 | 2023-10-31 | Covestro Deutschland Ag | Transparent liquid container |
CN114590480A (en) * | 2022-03-31 | 2022-06-07 | 淮安赫德兹彩色印刷包装有限公司 | Two ingredient hybrid wrapping bags |
Family Cites Families (14)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2078627A5 (en) * | 1970-02-27 | 1971-11-05 | Dentaire Ivoclar Ets | |
US3860114A (en) * | 1970-11-04 | 1975-01-14 | Volker Merckardt | Multi-chamber container |
DE2248784A1 (en) | 1972-10-05 | 1974-04-18 | Diener Berthold | Two component plastics stored in plastics vessel - which is not subject to buckling and thus well adapted for mixing the components |
DE3545614A1 (en) * | 1985-12-21 | 1987-06-25 | Hilti Ag | COMBINED CARTRIDGE FOR TWO-COMPONENT SIZES |
EP0254564A3 (en) * | 1986-07-23 | 1989-07-05 | Advanced Curing Technology Pty. Limited | A spray gun |
JPH0626686B2 (en) * | 1987-03-24 | 1994-04-13 | 大阪エヤゾ−ル工業株式会社 | Content mixing container and content mixing and discharging device using the container |
US6513650B2 (en) * | 1997-10-14 | 2003-02-04 | Biogaia Ab | Two-compartment container |
KR100833826B1 (en) * | 2000-12-11 | 2008-06-02 | 쉘 인터내셔날 리서치 마챠피즈 비.브이. | Mixing device comprising a swirl chamber for mixing liquid |
JP2007253948A (en) * | 2004-04-30 | 2007-10-04 | Sadao Nozawa | Plastic container |
JP5020972B2 (en) | 2005-12-19 | 2012-09-05 | ミン リー、ジュン | Pressurized cap receiving device with storage space for different substances |
CA2672200C (en) * | 2006-12-15 | 2015-01-13 | 3M Innovative Properties Company | Mixing and dispensing curable multi-component materials |
US20090188987A1 (en) * | 2008-01-30 | 2009-07-30 | Ppg Industries Ohio, Inc. | Multi-chambered coating cartridge |
WO2010084140A1 (en) | 2009-01-23 | 2010-07-29 | Akzo Nobel Coatings International B.V. | Packaging for two or more fluids |
US20150016208A1 (en) * | 2013-07-15 | 2015-01-15 | Solutions Biomed, Llc | Multi-chamber container for storing and mixing liquids |
-
2019
- 2019-02-21 CN CN201980015074.3A patent/CN111867715B/en active Active
- 2019-02-21 EP EP19705206.1A patent/EP3755456B1/en active Active
- 2019-02-21 ES ES19705206T patent/ES2906469T3/en active Active
- 2019-02-21 WO PCT/EP2019/054354 patent/WO2019162397A1/en active Search and Examination
- 2019-02-21 US US16/971,940 patent/US11911735B2/en active Active
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CN111867715A (en) | 2020-10-30 |
ES2906469T3 (en) | 2022-04-18 |
EP3755456A1 (en) | 2020-12-30 |
US20210197153A1 (en) | 2021-07-01 |
US11911735B2 (en) | 2024-02-27 |
WO2019162397A1 (en) | 2019-08-29 |
CN111867715B (en) | 2023-05-19 |
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