EP3715081B1 - Method for producing composite material - Google Patents

Method for producing composite material Download PDF

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Publication number
EP3715081B1
EP3715081B1 EP19754442.2A EP19754442A EP3715081B1 EP 3715081 B1 EP3715081 B1 EP 3715081B1 EP 19754442 A EP19754442 A EP 19754442A EP 3715081 B1 EP3715081 B1 EP 3715081B1
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EP
European Patent Office
Prior art keywords
fabric
resin
composite material
flow path
producing
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
EP19754442.2A
Other languages
German (de)
French (fr)
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EP3715081A4 (en
EP3715081A1 (en
Inventor
Kodai Shimono
Hiroshi Tokutomi
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Mitsubishi Heavy Industries Ltd
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Mitsubishi Heavy Industries Ltd
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Publication date
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Publication of EP3715081A1 publication Critical patent/EP3715081A1/en
Publication of EP3715081A4 publication Critical patent/EP3715081A4/en
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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C70/00—Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts
    • B29C70/04—Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts comprising reinforcements only, e.g. self-reinforcing plastics
    • B29C70/28—Shaping operations therefor
    • B29C70/40—Shaping or impregnating by compression not applied
    • B29C70/42—Shaping or impregnating by compression not applied for producing articles of definite length, i.e. discrete articles
    • B29C70/46—Shaping or impregnating by compression not applied for producing articles of definite length, i.e. discrete articles using matched moulds, e.g. for deforming sheet moulding compounds [SMC] or prepregs
    • B29C70/48—Shaping or impregnating by compression not applied for producing articles of definite length, i.e. discrete articles using matched moulds, e.g. for deforming sheet moulding compounds [SMC] or prepregs and impregnating the reinforcements in the closed mould, e.g. resin transfer moulding [RTM], e.g. by vacuum
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C39/00—Shaping by casting, i.e. introducing the moulding material into a mould or between confining surfaces without significant moulding pressure; Apparatus therefor
    • B29C39/02—Shaping by casting, i.e. introducing the moulding material into a mould or between confining surfaces without significant moulding pressure; Apparatus therefor for making articles of definite length, i.e. discrete articles
    • B29C39/10—Shaping by casting, i.e. introducing the moulding material into a mould or between confining surfaces without significant moulding pressure; Apparatus therefor for making articles of definite length, i.e. discrete articles incorporating preformed parts or layers, e.g. casting around inserts or for coating articles
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C39/00—Shaping by casting, i.e. introducing the moulding material into a mould or between confining surfaces without significant moulding pressure; Apparatus therefor
    • B29C39/22—Component parts, details or accessories; Auxiliary operations
    • B29C39/24—Feeding the material into the mould
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C43/00—Compression moulding, i.e. applying external pressure to flow the moulding material; Apparatus therefor
    • B29C43/32—Component parts, details or accessories; Auxiliary operations
    • B29C43/36—Moulds for making articles of definite length, i.e. discrete articles
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C70/00—Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts
    • B29C70/04—Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts comprising reinforcements only, e.g. self-reinforcing plastics
    • B29C70/06—Fibrous reinforcements only
    • B29C70/08—Fibrous reinforcements only comprising combinations of different forms of fibrous reinforcements incorporated in matrix material, forming one or more layers, and with or without non-reinforced layers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C70/00—Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts
    • B29C70/04—Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts comprising reinforcements only, e.g. self-reinforcing plastics
    • B29C70/06—Fibrous reinforcements only
    • B29C70/10—Fibrous reinforcements only characterised by the structure of fibrous reinforcements, e.g. hollow fibres
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C70/00—Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts
    • B29C70/04—Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts comprising reinforcements only, e.g. self-reinforcing plastics
    • B29C70/28—Shaping operations therefor
    • B29C70/40—Shaping or impregnating by compression not applied
    • B29C70/50—Shaping or impregnating by compression not applied for producing articles of indefinite length, e.g. prepregs, sheet moulding compounds [SMC] or cross moulding compounds [XMC]
    • B29C70/52—Pultrusion, i.e. forming and compressing by continuously pulling through a die
    • B29C70/525—Component parts, details or accessories; Auxiliary operations
    • B29C70/528—Heating or cooling
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C70/00—Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts
    • B29C70/04—Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts comprising reinforcements only, e.g. self-reinforcing plastics
    • B29C70/28—Shaping operations therefor
    • B29C70/54—Component parts, details or accessories; Auxiliary operations, e.g. feeding or storage of prepregs or SMC after impregnation or during ageing
    • B29C70/546—Measures for feeding or distributing the matrix material in the reinforcing structure
    • B29C70/547—Measures for feeding or distributing the matrix material in the reinforcing structure using channels or porous distribution layers incorporated in or associated with the product
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2101/00—Use of unspecified macromolecular compounds as moulding material
    • B29K2101/10—Thermosetting resins

Definitions

  • the present invention relates to a method for producing a composite material.
  • a composite material composed of a fiber material such as a glass fiber or a carbon fiber and a resin material is produced by various methods, for example, a VaRTM (Vacuum Assisted Resin Transfer Molding) method.
  • a VaRTM Vauum Assisted Resin Transfer Molding
  • the VaRTM method is to produce a composite material by infiltrating resin into a fiber base material by using vacuum pressure and then curing the infiltrated resin by heating and compressing the fiber base material with the infiltrated resin (refer to, for example, JP 2008- 137 179 A ) .
  • US 2005/070182 A1 on which the preamble portion of claim 1 and claim 2 is based, discloses composite fabrics and a method of making composite fabrics.
  • the composite fabrics have smaller yarns spaced between larger yarns, which form channels in the fabric. When resin is applied to the fabric, during lamination, the channels permit faster resin distribution in the fabric.
  • the resin is cured even during the infiltration into the fiber base material and the viscosity thereof increases. Therefore, the thickness of the fiber base material that can be integrally molded without forming an un-infiltrated portion is limited. Accordingly, in the related art, when producing a composite material (thick plate member) having a thick plate portion (a portion having a thickness exceeding a limited thickness), mechanical fastening means, a co-bonding molding method, or the like is used.
  • a method for producing a composite material using the mechanical fastening means includes preparing a plurality of divided members each having a shape obtained by dividing a thick plate member, separately infiltrating resin into the plurality of divided members, curing the resin, and then, mechanically fastening the members with fasteners (for example, rivets).
  • fasteners for example, rivets
  • the resin is infiltrated into each of the plurality of divided members, and therefore, the number of resin infiltration steps increases and the number of parts such as fasteners increases. Therefore, this leads to an increase in manufacturing cost and complication of a manufacturing process.
  • a method for producing a composite material using the co-bonding molding method includes preparing a plurality of divided members each having a shape obtained by dividing a thick plate member, infiltrating resin into one member, and curing the resin, and thereafter, infiltrating resin into the other member, and bonding the other member to one member.
  • the resin is infiltrated into each of the plurality of divided members, and therefore, the number of resin infiltration steps increases, and the bonding treatment of the plurality of divided members is required. Therefore, this leads to an increase in manufacturing cost and complication of a manufacturing process.
  • the present invention has been made in view of the above problems and has an object to easily produce a composite material having a thick plate portion.
  • a method with the features of claim 1 or claim 2 for producing a composite material in which a thermosetting resin is infiltrated into a first fabric and a second fabric made of fiber materials and the first fabric and the second fabric are molded integrally the method including: providing a resin flow path through which the thermosetting resin can flow between the first fabric and the second fabric; and infiltrating the thermosetting resin into the first fabric and the second fabric from surfaces thereof and also from the resin flow path.
  • a groove portion is provided on the surface of the first fabric, and the resin flow path is defined by the groove portion.
  • the groove portion is leveled by applying heat and pressure to the first fabric and the second fabric when curing the thermosetting resin.
  • the groove portion is coated with a thermoplastic resin or starchy glue.
  • the groove portion is formed by performing hot compaction by pressing a member having a concave shape or a convex shape on a surface thereof against the first fabric when shaping the first fabric.
  • the groove portion is formed by performing bagging using a film without disposing a hard material on a surface of a fiber fabric, and then applying pressure and heat, when shaping the first fabric.
  • thermosetting resin infiltration can be performed reliably and promptly, and therefore, even a composite material having a thick plate portion can be integrally molded and easily produced.
  • thermosetting resin can flow in a simple configuration.
  • the influence of the groove portion on the mechanical strength or the like can be reduced.
  • thermosetting resin can flow in a resin infiltration step
  • the groove portion can be easily formed.
  • the groove portion can be easily formed.
  • the method for producing a composite material uses a composite material manufacturing apparatus (reference numeral 1 in Fig. 2 ) and integrally molds a composite material (reference numeral 100 in Fig. 1 ) having a thick plate portion by simultaneously infiltrating resin into a plurality of fiber base materials (reference numerals 101 and 102 in Fig. 2 ).
  • the composite material which is produced by the method for producing a composite material according to this embodiment, and the fiber base material which is used for the production of the composite material will be described with reference to Figs. 1 , 2 , and 3A .
  • the composite material 100 which is produced by the method for producing a composite material according to this embodiment is a skin-stringer member provided with a flat plate-shaped portion (a skin member) and a beam portion (a stringer member) protruding from the surface of the flat plate-shaped portion, and has a thick plate portion 100a whose thickness is partially large.
  • the composite material 100 In the production of the composite material 100, a plurality of (in this embodiment, two) fiber base materials 101 and 102 (refer to Fig. 2 ) are used, and the composite material 100 is produced by simultaneously infiltrating a thermosetting resin into the fiber base materials 101 and 102 and curing the resin.
  • one fiber base material (a first fabric) 101 which is used in the method for producing a composite material according to this embodiment configures the skin member and is formed by laminating fiber materials such as glass fibers or carbon fibers in a flat plate shape.
  • the other fiber base material (a second fabric) 102 which is used in the method for producing a composite material according to this embodiment configures the stringer member, is formed by laminating fiber materials such as glass fibers or carbon fibers in a substantially T-shaped cross section, and is roughly composed of a base portion 102a which is joined to the first fabric 101 and a beam portion 102b protruding from substantially the center of the base portion 102a.
  • a thickness (plate thickness) t 101 of the first fabric 101 and a thickness (plate thickness) t 102a of the base portion 102a in the second fabric 102 are respectively plate thicknesses capable of sufficiently infiltrating resin even by a method for producing a composite material of the related art, and a thickness t 100a of the thick plate portion 100a in the composite material 100 is equivalent to the sum of the plate thickness t 101 and the plate thickness t 102a and is set to a plate thickness into which resin cannot be sufficiently infiltrated by the method for producing a composite material of the related art (refer to Fig. 1 ).
  • the surface (upper surface) of the first fabric 101 is formed in a concave-convex shape, and a plurality of groove portions 101a are formed by the concave-convex shape.
  • the groove portions 101a are provided in a range which is joined to the second fabric 102, and when the first fabric 101 and the second fabric 102 are installed in the composite material manufacturing apparatus 1 in the process of producing the composite material 100, a gap space (a resin flow path) S 101a is defined between the first fabric 101 (the groove portion 101a) and the second fabric 102.
  • the resin flow path S 101a functions as a resin flow path through which a thermosetting resin can flow in a resin infiltration step (described later). Therefore, the groove portion 101a has mechanical strength and heat-resistant strength to the extent that the shape thereof does not collapse in the resin infiltration step (described later), and has a flow path cross section through which the thermosetting resin can flow.
  • the plurality of groove portions 101a are provided to be orthogonal to each other (or intersect each other at a predetermined angle) and be connected to each other (provided to be connected in a grid pattern) on the surface of the first fabric 101 (the joint surface between the first fabric 101 and the second fabric 102).
  • a height (depth) h of the groove portion 101a is set to be 0.2 [mm] or more (h ⁇ 0.2 mm), and a distance (disposition interval) d between the groove portions 101a which are disposed adjacent to each other is set to be less than 30 [mm] (d ⁇ 30 mm) (refer to Fig. 3A ).
  • the composite material manufacturing apparatus 1 which is used in the method for producing a composite material according to this embodiment includes molding tools 11 and 12 for molding the first fabric 101 and the second fabric 102 into the composite material 100.
  • the molding tool (lower mold) 11 which is disposed on the lower side has a surface shape corresponding to the lower surface of the composite material 100 and is made such that the first fabric 101 is placed thereon with a mesh-like resin suction medium 21 interposed therebetween.
  • the molding tool (upper mold) 12 which is disposed on the upper side has a surface shape corresponding to the upper surface of the composite material 100 and is made so as to cover the first fabric 101 and the second fabric 102 placed on the lower mold 11 through mesh-like resin supply media (a first resin supply medium and a second resin supply medium) 22 and 23.
  • predetermined gap spaces (a first resin supply flow path and a second resin supply flow path) S 102a and S 102b are formed between the upper mold 12, and the first fabric 101 and the second fabric 102.
  • the first resin supply flow path S 102a and the second resin supply flow path S 102b function as flow paths through which the thermosetting resin flows in the resin infiltration step (described later) and are each connected to a resin supply device (not shown).
  • the first resin supply flow path S 102a which is formed in the vicinity of the joint portion between the first fabric 101 and the second fabric 102 (the vicinity of an end portion of the base portion 102a in the second fabric 102) communicates with the resin flow path S 101a which is formed between the first fabric 101 and the second fabric 102, and thus, the thermosetting resin which is supplied from the resin supply device (not shown).to the first resin supply flow path S 102a is supplied to the resin flow path S 101a .
  • the composite material manufacturing apparatus 1 includes a vacuum bag film 31 made of nylon, polyester, or the like, and a sealant 32 that seals the gap between the vacuum bag film 31 and the lower mold 11 at the periphery of the vacuum bag film 31.
  • the vacuum bag film 31 is provided with a suction nozzle 41, and a vacuum pump 42 is connected to the suction nozzle 41. Therefore, air in a space (sealed space) S 1 in which the first fabric 101, the second fabric 102, and the upper mold 12 are installed, and which is sealed by the lower mold 11, the vacuum bag film 31, and the sealant 32, is sucked from the suction nozzle 41 by the vacuum pump 42.
  • each of the first fabric 101 and the second fabric 102 is shaped by laminating fiber materials into a predetermined shape (fiber base material shaping step).
  • a member (a covering material or a shaping mold) having a concave-convex shape on the surface thereof is used to transfer the concave-convex shape to the surface of the first fabric 101.
  • this shaping method it is possible to easily obtain the first fabric 101 having the concave-convex shape (the groove portions 101a).
  • a shaping mold 111 having a protrusion portion 111a and a recess portion 111b, as shown in Fig. 4 can be adopted.
  • a large number of recess portions 111b are provided side by side on the surface of the shaping mold 111, and the protrusion portions 111a are provided to be connected in a grid pattern between the recess portions 111b adjacent to each other.
  • the groove portions 101a of the first fabric 101 are formed by the protrusion portions 111a of the shaping mold 111.
  • the groove portions 101a of the first fabric 101 have shapes corresponding to the protrusion portions 111a of the shaping mold 111, that is, shapes connected in a grid pattern on the surface of the first fabric 101.
  • the method of shaping the first fabric 101 is not limited to the method described above, and, for example, a shaping method may be adopted in which a laminate of fiber materials (a fiber fabric) is subjected to bagging by using a familiar film or the like without disposing a hard material (for example, a metal pressure plate or the like) on the surface thereof and heating is then performed while applying vacuum pressure, pressurization by an autoclave, water pressure, or the like.
  • a shaping method may be adopted in which a laminate of fiber materials (a fiber fabric) is subjected to bagging by using a familiar film or the like without disposing a hard material (for example, a metal pressure plate or the like) on the surface thereof and heating is then performed while applying vacuum pressure, pressurization by an autoclave, water pressure, or the like.
  • the first fabric 101 having the concave-convex shape the groove portions 101a
  • the groove portions 101a can be easily obtained by using the concave-convex shape on the surface of the fabric itself.
  • the material that maintains the concave-convex shape (the groove portions 101a) is not limited to the thermoplastic resin and may be any material having a function capable of restraining deformation in an out-of-plane direction, such as starchy glue, for example.
  • thermoplastic resin that provides desired mechanical strength and heat-resistant strength to the concave-convex shape (the groove portions 101a)
  • a thermoplastic resin is used in which a temperature (softening temperature) at which the viscosity thereof is lowered is higher than a thermosetting resin infiltration temperature in the resin infiltration step (described below) and lower than a thermosetting resin curing temperature in the resin curing step (described later).
  • first fabric 101 and the second fabric 102 are installed in the composite material manufacturing apparatus 1, and a thermosetting resin is infiltrated into the first fabric 101 and the second fabric 102 (resin infiltration step).
  • the resin infiltration step is performed by making the sealed space S 1 be in a vacuum state by driving the vacuum pump 42, and supplying a thermosetting resin from the resin supply device (not shown) to the first resin supply flow path S 102a and the second resin supply flow path S 102b (refer to Figs. 2 and 3A ).
  • the thermosetting resin supplied to the first resin supply flow path S 102a and the second resin supply flow path S 102b is diffused by the first resin supply medium 22 and the second resin supply medium 23, respectively, and permeates from the surfaces of the first fabric 101 and the second fabric 102 into the interiors thereof (refer to the dashed arrows in Fig. 2 ).
  • thermosetting resin supplied to the first resin supply flow path S 102a is supplied to the resin flow path S 101a communicating with the first resin supply flow path S 102a and penetrates from the resin flow path S 101a to the interior of the first fabric 101 (refer to the dashed arrows in Fig. 2 ).
  • thermosetting resin infiltration is performed not only from the surfaces of the first fabric 101 and the second fabric 102 respectively provided with the first resin supply medium 22 and the second resin supply medium 23 but also from the resin flow path S 101a between the first fabric 101 and the second fabric 102, whereby the infiltration of the first fabric 101 and the second fabric 102 with the thermosetting resin can be performed reliably and promptly.
  • thermosetting resin infiltrated into the first fabric 101 and the second fabric 102 is thermally cured (resin curing step).
  • the resin curing step is performed by heating the molding tools 11 and 12 by an oven (not shown) and applying pressure so as to press the upper mold 12 against the first fabric 101 and the second fabric 102 on the lower mold 11 (refer to arrows in Fig. 3B ). Therefore, the first fabric 101 and the second fabric 102 are heated and pressurized by the molding tools 11 and 12.
  • thermoplastic resin coated on the first fabric 101 is softened by the heating in the resin curing step, and the concave-convex shape (the groove portions 101a) formed on the first fabric 101 is leveled by the pressurization in the resin curing step.
  • thermosetting resin infiltration can be performed reliably and promptly, and therefore, the composite material 100 having the thick plate portion 100a can be integrally molded.
  • the groove portions 101a are formed by making the surface of the first fabric 101 have a concave-convex shape, and the resin flow paths S 101a are formed between the first fabric 101 and the second fabric 102 by the groove portions 101a.
  • the present invention is not limited to this.
  • a configuration may be adopted in which only a recess portion is formed on the surface (upper surface) of the first fabric and a gap space (a resin flow path) is formed between the first fabric and the second fabric by the recess portion (a groove), and a configuration may be adopted in which only a protrusion portion is formed on the surface of the first fabric and a gap space (a resin flow path) is formed between the first fabric and the second fabric by the protrusion portion (a groove which is formed between protrusion portions).
  • a gap space (a resin flow path) may be formed between the first fabric and the second fabric by making not only the surface (upper surface) of the first fabric but also the surface (lower surface) of the second fabric have a concave-convex shape
  • a gap space (a resin flow path) may be formed between the first fabric and the second fabric by making only the surface (lower surface) of the second fabric have a concave-convex shape (alternatively, by forming a recess portion or a protrusion portion on the surface).
  • the composite material 100 is produced by providing the resin flow path S 101a between two fiber base materials: the first fabric 101 and the second fabric 102.
  • the present invention is not limited to this, and a structure in which fiber base materials are stacked in three or more stages may be integrally molded.
  • the fiber base materials are stacked in three or more stages and are integrally molded, in order to more reliably and promptly perform resin infiltration, it is preferable to provide a gap space between the layers of the respective stages and it is preferable to provide a resin supply flow path that communicates with a gap space between the layers of the respective stages.

Description

    Technical Field
  • The present invention relates to a method for producing a composite material.
    • Background Art
  • A composite material composed of a fiber material such as a glass fiber or a carbon fiber and a resin material is produced by various methods, for example, a VaRTM (Vacuum Assisted Resin Transfer Molding) method.
  • The VaRTM method is to produce a composite material by infiltrating resin into a fiber base material by using vacuum pressure and then curing the infiltrated resin by heating and compressing the fiber base material with the infiltrated resin (refer to, for example, JP 2008- 137 179 A ) .
  • US 2005/070182 A1 , on which the preamble portion of claim 1 and claim 2 is based, discloses composite fabrics and a method of making composite fabrics. The composite fabrics have smaller yarns spaced between larger yarns, which form channels in the fabric. When resin is applied to the fabric, during lamination, the channels permit faster resin distribution in the fabric.
    • Summary of Invention Technical Problem
  • However, the resin is cured even during the infiltration into the fiber base material and the viscosity thereof increases. Therefore, the thickness of the fiber base material that can be integrally molded without forming an un-infiltrated portion is limited. Accordingly, in the related art, when producing a composite material (thick plate member) having a thick plate portion (a portion having a thickness exceeding a limited thickness), mechanical fastening means, a co-bonding molding method, or the like is used.
  • A method for producing a composite material using the mechanical fastening means includes preparing a plurality of divided members each having a shape obtained by dividing a thick plate member, separately infiltrating resin into the plurality of divided members, curing the resin, and then, mechanically fastening the members with fasteners (for example, rivets). However, in such a method for producing a composite material, the resin is infiltrated into each of the plurality of divided members, and therefore, the number of resin infiltration steps increases and the number of parts such as fasteners increases. Therefore, this leads to an increase in manufacturing cost and complication of a manufacturing process.
  • Further, a method for producing a composite material using the co-bonding molding method includes preparing a plurality of divided members each having a shape obtained by dividing a thick plate member, infiltrating resin into one member, and curing the resin, and thereafter, infiltrating resin into the other member, and bonding the other member to one member. However, in such a method for producing a composite material, the resin is infiltrated into each of the plurality of divided members, and therefore, the number of resin infiltration steps increases, and the bonding treatment of the plurality of divided members is required. Therefore, this leads to an increase in manufacturing cost and complication of a manufacturing process.
  • The present invention has been made in view of the above problems and has an object to easily produce a composite material having a thick plate portion.
    • Solution to Problem
  • According to the present invention for solving the above-mentioned problems, there is provided a method with the features of claim 1 or claim 2 for producing a composite material in which a thermosetting resin is infiltrated into a first fabric and a second fabric made of fiber materials and the first fabric and the second fabric are molded integrally, the method including: providing a resin flow path through which the thermosetting resin can flow between the first fabric and the second fabric; and infiltrating the thermosetting resin into the first fabric and the second fabric from surfaces thereof and also from the resin flow path.
  • According to the present invention, a groove portion is provided on the surface of the first fabric, and the resin flow path is defined by the groove portion.
  • According to a preferred first aspect of the present invention, in the method for producing a composite material according to the present invention, the groove portion is leveled by applying heat and pressure to the first fabric and the second fabric when curing the thermosetting resin.
  • According to a preferred second aspect of the present invention, in the method for producing a composite material according to the present invention, the groove portion is coated with a thermoplastic resin or starchy glue.
  • According to the present invention as defined by claim 1, the groove portion is formed by performing hot compaction by pressing a member having a concave shape or a convex shape on a surface thereof against the first fabric when shaping the first fabric.
  • According to the present invention as defined by claim 2, the groove portion is formed by performing bagging using a film without disposing a hard material on a surface of a fiber fabric, and then applying pressure and heat, when shaping the first fabric.
    • Advantageous Effects of Invention
  • According to the method for producing a composite material according to the present invention, the thermosetting resin infiltration can be performed reliably and promptly, and therefore, even a composite material having a thick plate portion can be integrally molded and easily produced.
  • According to the method for producing a composite material according to the present invention, a flow path through which the thermosetting resin can flow can be provided with a simple configuration.
  • According to the method for producing a composite material according to the preferred first aspect of the present invention, the influence of the groove portion on the mechanical strength or the like can be reduced.
  • According to the method for producing a composite material according to the preferred second aspect of the present invention, a flow path through which the thermosetting resin can flow in a resin infiltration step can be reliably secured.
  • According to the method for producing a composite material according to claim 1, the groove portion can be easily formed.
  • According to the method for producing a composite material according to claim 2, the groove portion can be easily formed.
    • Brief Description of Drawings
    • Fig. 1 is an explanatory diagram (schematic perspective view) of a main embodiment of a composite material which is produced by a method for producing a composite material according to the present invention.
    • Fig. 2 is an explanatory diagram (schematic sectional view) showing a structure of a main embodiment of a composite material manufacturing apparatus which is used in the method for producing a composite material according to the present invention.
    • Fig. 3A is an explanatory diagram showing a procedure of a resin infiltration step in the main embodiment of the method for producing a composite material according to the present invention.
    • Fig. 3B is an explanatory diagram showing a procedure of a resin curing step in the main embodiment of the method for producing a composite material according to the present invention.
    • Fig. 4 is an explanatory diagram (schematic perspective view) showing a structure of a main embodiment of a shaping mold which is used in the method for producing a composite material according to the present invention.
    Description of Embodiments
  • Hereinafter, an embodiment of a method for producing a composite material according to the present invention will be described in detail with reference to the accompanying drawings.
    • <Main Embodiment>
  • The method for producing a composite material according to this embodiment uses a composite material manufacturing apparatus (reference numeral 1 in Fig. 2) and integrally molds a composite material (reference numeral 100 in Fig. 1) having a thick plate portion by simultaneously infiltrating resin into a plurality of fiber base materials ( reference numerals 101 and 102 in Fig. 2).
  • The composite material which is produced by the method for producing a composite material according to this embodiment, and the fiber base material which is used for the production of the composite material will be described with reference to Figs. 1, 2, and 3A.
  • As shown in Fig. 1, the composite material 100 which is produced by the method for producing a composite material according to this embodiment is a skin-stringer member provided with a flat plate-shaped portion (a skin member) and a beam portion (a stringer member) protruding from the surface of the flat plate-shaped portion, and has a thick plate portion 100a whose thickness is partially large.
  • In the production of the composite material 100, a plurality of (in this embodiment, two) fiber base materials 101 and 102 (refer to Fig. 2) are used, and the composite material 100 is produced by simultaneously infiltrating a thermosetting resin into the fiber base materials 101 and 102 and curing the resin.
  • As shown in Figs. 1 and 2, one fiber base material (a first fabric) 101 which is used in the method for producing a composite material according to this embodiment configures the skin member and is formed by laminating fiber materials such as glass fibers or carbon fibers in a flat plate shape.
  • The other fiber base material (a second fabric) 102 which is used in the method for producing a composite material according to this embodiment configures the stringer member, is formed by laminating fiber materials such as glass fibers or carbon fibers in a substantially T-shaped cross section, and is roughly composed of a base portion 102a which is joined to the first fabric 101 and a beam portion 102b protruding from substantially the center of the base portion 102a.
  • A thickness (plate thickness) t101 of the first fabric 101 and a thickness (plate thickness) t102a of the base portion 102a in the second fabric 102 are respectively plate thicknesses capable of sufficiently infiltrating resin even by a method for producing a composite material of the related art, and a thickness t100a of the thick plate portion 100a in the composite material 100 is equivalent to the sum of the plate thickness t101 and the plate thickness t102a and is set to a plate thickness into which resin cannot be sufficiently infiltrated by the method for producing a composite material of the related art (refer to Fig. 1).
  • As shown in Fig. 2, the surface (upper surface) of the first fabric 101 is formed in a concave-convex shape, and a plurality of groove portions 101a are formed by the concave-convex shape. The groove portions 101a are provided in a range which is joined to the second fabric 102, and when the first fabric 101 and the second fabric 102 are installed in the composite material manufacturing apparatus 1 in the process of producing the composite material 100, a gap space (a resin flow path) S101a is defined between the first fabric 101 (the groove portion 101a) and the second fabric 102.
  • The resin flow path S101a functions as a resin flow path through which a thermosetting resin can flow in a resin infiltration step (described later). Therefore, the groove portion 101a has mechanical strength and heat-resistant strength to the extent that the shape thereof does not collapse in the resin infiltration step (described later), and has a flow path cross section through which the thermosetting resin can flow.
  • Here, in consideration of the flowability of the thermosetting resin, it is preferable that the plurality of groove portions 101a are provided to be orthogonal to each other (or intersect each other at a predetermined angle) and be connected to each other (provided to be connected in a grid pattern) on the surface of the first fabric 101 (the joint surface between the first fabric 101 and the second fabric 102). Further, in consideration of the flowability of the thermosetting resin, it is preferable that a height (depth) h of the groove portion 101a is set to be 0.2 [mm] or more (h ≥ 0.2 mm), and a distance (disposition interval) d between the groove portions 101a which are disposed adjacent to each other is set to be less than 30 [mm] (d < 30 mm) (refer to Fig. 3A).
  • Next, the configuration of the composite material manufacturing apparatus which is used in the method for producing a composite material according to this embodiment will be described with reference to Fig. 2.
  • As shown in Fig. 2, the composite material manufacturing apparatus 1 which is used in the method for producing a composite material according to this embodiment includes molding tools 11 and 12 for molding the first fabric 101 and the second fabric 102 into the composite material 100.
  • The molding tool (lower mold) 11 which is disposed on the lower side has a surface shape corresponding to the lower surface of the composite material 100 and is made such that the first fabric 101 is placed thereon with a mesh-like resin suction medium 21 interposed therebetween. The molding tool (upper mold) 12 which is disposed on the upper side has a surface shape corresponding to the upper surface of the composite material 100 and is made so as to cover the first fabric 101 and the second fabric 102 placed on the lower mold 11 through mesh-like resin supply media (a first resin supply medium and a second resin supply medium) 22 and 23.
  • Here, predetermined gap spaces (a first resin supply flow path and a second resin supply flow path) S102a and S102b are formed between the upper mold 12, and the first fabric 101 and the second fabric 102. The first resin supply flow path S102a and the second resin supply flow path S102b function as flow paths through which the thermosetting resin flows in the resin infiltration step (described later) and are each connected to a resin supply device (not shown).
  • Here, the first resin supply flow path S102a which is formed in the vicinity of the joint portion between the first fabric 101 and the second fabric 102 (the vicinity of an end portion of the base portion 102a in the second fabric 102) communicates with the resin flow path S101a which is formed between the first fabric 101 and the second fabric 102, and thus, the thermosetting resin which is supplied from the resin supply device (not shown).to the first resin supply flow path S102a is supplied to the resin flow path S101a.
  • Further, the composite material manufacturing apparatus 1 includes a vacuum bag film 31 made of nylon, polyester, or the like, and a sealant 32 that seals the gap between the vacuum bag film 31 and the lower mold 11 at the periphery of the vacuum bag film 31.
  • Further, the vacuum bag film 31 is provided with a suction nozzle 41, and a vacuum pump 42 is connected to the suction nozzle 41. Therefore, air in a space (sealed space) S1 in which the first fabric 101, the second fabric 102, and the upper mold 12 are installed, and which is sealed by the lower mold 11, the vacuum bag film 31, and the sealant 32, is sucked from the suction nozzle 41 by the vacuum pump 42.
  • The procedure of the method for producing a composite material according to this embodiment will be described with reference to Figs. 2, 3A, and 3B.
  • First, each of the first fabric 101 and the second fabric 102 is shaped by laminating fiber materials into a predetermined shape (fiber base material shaping step).
  • In the fiber base material shaping step for the first fabric 101, when hot-compacting a laminate of fiber materials (unidirectional or multidirectional fiber materials or fiber fabric), a member (a covering material or a shaping mold) having a concave-convex shape on the surface thereof is used to transfer the concave-convex shape to the surface of the first fabric 101. According to this shaping method, it is possible to easily obtain the first fabric 101 having the concave-convex shape (the groove portions 101a).
  • Here, as the member having a concave-convex shape on the surface, for example, a shaping mold 111 having a protrusion portion 111a and a recess portion 111b, as shown in Fig. 4, can be adopted. A large number of recess portions 111b are provided side by side on the surface of the shaping mold 111, and the protrusion portions 111a are provided to be connected in a grid pattern between the recess portions 111b adjacent to each other. Therefore, in a case where the shaping mold 111 is used to transfer the concave-convex shape (the protrusion portions 111a and the recess portions 111b) on the surface thereof to the surface of the first fabric 101, the groove portions 101a of the first fabric 101 are formed by the protrusion portions 111a of the shaping mold 111. At this time, the groove portions 101a of the first fabric 101 have shapes corresponding to the protrusion portions 111a of the shaping mold 111, that is, shapes connected in a grid pattern on the surface of the first fabric 101.
  • Of course, the method of shaping the first fabric 101 is not limited to the method described above, and, for example, a shaping method may be adopted in which a laminate of fiber materials (a fiber fabric) is subjected to bagging by using a familiar film or the like without disposing a hard material (for example, a metal pressure plate or the like) on the surface thereof and heating is then performed while applying vacuum pressure, pressurization by an autoclave, water pressure, or the like. According to this shaping method, the first fabric 101 having the concave-convex shape (the groove portions 101a) can be easily obtained by using the concave-convex shape on the surface of the fabric itself.
  • Further, when shaping the first fabric 101 having a concave-convex shape (the groove portions 101a) by the shaping method described above, by coating the surface having the concave-convex shape (the groove portions 101a) with bale-shaped or powder-shaped thermoplastic resin, it is possible to provide desired mechanical strength and heat-resistant strength to the concave-convex shape (the groove portions 101a). Of course, the material that maintains the concave-convex shape (the groove portions 101a) is not limited to the thermoplastic resin and may be any material having a function capable of restraining deformation in an out-of-plane direction, such as starchy glue, for example.
  • As the thermoplastic resin that provides desired mechanical strength and heat-resistant strength to the concave-convex shape (the groove portions 101a), a thermoplastic resin is used in which a temperature (softening temperature) at which the viscosity thereof is lowered is higher than a thermosetting resin infiltration temperature in the resin infiltration step (described below) and lower than a thermosetting resin curing temperature in the resin curing step (described later).
  • Subsequently, the first fabric 101 and the second fabric 102 are installed in the composite material manufacturing apparatus 1, and a thermosetting resin is infiltrated into the first fabric 101 and the second fabric 102 (resin infiltration step).
  • The resin infiltration step is performed by making the sealed space S1 be in a vacuum state by driving the vacuum pump 42, and supplying a thermosetting resin from the resin supply device (not shown) to the first resin supply flow path S102a and the second resin supply flow path S102b (refer to Figs. 2 and 3A). The thermosetting resin supplied to the first resin supply flow path S102a and the second resin supply flow path S102b is diffused by the first resin supply medium 22 and the second resin supply medium 23, respectively, and permeates from the surfaces of the first fabric 101 and the second fabric 102 into the interiors thereof (refer to the dashed arrows in Fig. 2). Further, the thermosetting resin supplied to the first resin supply flow path S102a is supplied to the resin flow path S101a communicating with the first resin supply flow path S102a and penetrates from the resin flow path S101a to the interior of the first fabric 101 (refer to the dashed arrows in Fig. 2).
  • In this manner, the thermosetting resin infiltration is performed not only from the surfaces of the first fabric 101 and the second fabric 102 respectively provided with the first resin supply medium 22 and the second resin supply medium 23 but also from the resin flow path S101a between the first fabric 101 and the second fabric 102, whereby the infiltration of the first fabric 101 and the second fabric 102 with the thermosetting resin can be performed reliably and promptly.
  • Subsequently, the thermosetting resin infiltrated into the first fabric 101 and the second fabric 102 is thermally cured (resin curing step).
  • The resin curing step is performed by heating the molding tools 11 and 12 by an oven (not shown) and applying pressure so as to press the upper mold 12 against the first fabric 101 and the second fabric 102 on the lower mold 11 (refer to arrows in Fig. 3B). Therefore, the first fabric 101 and the second fabric 102 are heated and pressurized by the molding tools 11 and 12.
  • At this time, the thermoplastic resin coated on the first fabric 101 is softened by the heating in the resin curing step, and the concave-convex shape (the groove portions 101a) formed on the first fabric 101 is leveled by the pressurization in the resin curing step.
  • In this manner, by leveling the concave-convex shape (the groove portions 101a) provided in the first fabric 101 and making the surface of the first fabric 101 (the joint surface with the second fabric 102) substantially flat, it is possible to suppress (prevent) a decrease in mechanical strength that can be caused by the influence of the concave-convex shape (curing while the fiber materials are bent).
  • According to the method for producing a composite material according to this embodiment, by providing the resin flow path S101a through which the thermosetting resin can flow between the first fabric 101 and the second fabric 102, and infiltrating the thermosetting resin into the first fabric 101 and the second fabric 102 from the surfaces thereof and also from the resin flow path S101a, the thermosetting resin infiltration can be performed reliably and promptly, and therefore, the composite material 100 having the thick plate portion 100a can be integrally molded.
  • In this embodiment, the groove portions 101a are formed by making the surface of the first fabric 101 have a concave-convex shape, and the resin flow paths S101a are formed between the first fabric 101 and the second fabric 102 by the groove portions 101a. Of course, the present invention is not limited to this.
  • For example, a configuration may be adopted in which only a recess portion is formed on the surface (upper surface) of the first fabric and a gap space (a resin flow path) is formed between the first fabric and the second fabric by the recess portion (a groove), and a configuration may be adopted in which only a protrusion portion is formed on the surface of the first fabric and a gap space (a resin flow path) is formed between the first fabric and the second fabric by the protrusion portion (a groove which is formed between protrusion portions).
  • Further, a gap space (a resin flow path) may be formed between the first fabric and the second fabric by making not only the surface (upper surface) of the first fabric but also the surface (lower surface) of the second fabric have a concave-convex shape, and a gap space (a resin flow path) may be formed between the first fabric and the second fabric by making only the surface (lower surface) of the second fabric have a concave-convex shape (alternatively, by forming a recess portion or a protrusion portion on the surface).
  • It is preferable to provide a groove portion on the surface of one fiber base material and make the surface of the other fiber base material flat. This is because the shape or the like of a gap space can be set only by the shaping of one fiber base material and a uniform gap space can be easily defined. Further, the surface of the other fiber base material is flat, and therefore, in the resin curing step, it is possible to level the concave-convex shape in one fiber base material and easily flatten the surface of the fiber base material.
  • Further, in this embodiment, the composite material 100 is produced by providing the resin flow path S101a between two fiber base materials: the first fabric 101 and the second fabric 102.
  • Of course, the present invention is not limited to this, and a structure in which fiber base materials are stacked in three or more stages may be integrally molded. When the fiber base materials are stacked in three or more stages and are integrally molded, in order to more reliably and promptly perform resin infiltration, it is preferable to provide a gap space between the layers of the respective stages and it is preferable to provide a resin supply flow path that communicates with a gap space between the layers of the respective stages.
    • Reference Signs List
    • 1: composite material manufacturing apparatus
    • 11: molding tool (lower mold)
    • 12: molding tool (upper mold)
    • 21: resin suction medium
    • 22: first resin supply medium
    • 23: second resin supply medium
    • 31: vacuum bag film
    • 32: sealant
    • 41: suction nozzle
    • 42: vacuum pump
    • 100: composite material
    • 100a: thick plate portion in composite material
    • 101: first fabric
    • 101a: groove portion (concave-convex shape) in first fabric
    • 102: second fabric
    • 102a: base portion in second fabric
    • 102b: beam portion in second fabric
    • 111: shaping mold
    • 111a: protrusion portion in shaping mold
    • 111b: recess portion in shaping mold
    • S1: sealed space
    • S101a: resin flow path (gap space)
    • S102a: first resin supply flow path (gap space)
    • S102b: second resin supply flow path (gap space)
    • t100a: thickness of thick plate portion in composite material
    • t101: thickness (plate thickness) of first fabric
    • t102a: thickness (plate thickness) of base portion in second fabric
    • d: disposition interval of groove portions in first fabric
    • h: height (depth) of groove portion in first fabric

Claims (4)

  1. A method for producing a composite material (100) in which a thermosetting resin is infiltrated into a first fabric (101) and a second fabric (102) made of fiber materials and the first fabric (101) and the second fabric (102) are molded integrally, the method comprising:
    providing a resin flow path (S101a) through which the thermosetting resin can flow between the first fabric (101) and the second fabric (102); and
    infiltrating the thermosetting resin into the first fabric (101) and the second fabric (102) from surfaces thereof and also from the resin flow path (S101a),
    wherein a groove portion (101a) is provided on the surface of the first fabric (101), and the resin flow path (S101a) is defined by the groove portion (101a),
    characterized in that
    the groove portion (101a) is formed by performing hot compaction by pressing a member (111) having a concave shape or a convex shape on a surface thereof against the first fabric (101) when shaping the first fabric (101).
  2. A method for producing a composite material (100) in which a thermosetting resin is infiltrated into a first fabric (101) and a second fabric (102) made of fiber materials and the first fabric (101) and the second fabric (102) are molded integrally, the method comprising:
    providing a resin flow path (S101a) through which the thermosetting resin can flow between the first fabric (101) and the second fabric (102); and
    infiltrating the thermosetting resin into the first fabric (101) and the second fabric (102) from surfaces thereof and also from the resin flow path (S101a),
    wherein a groove portion (101a) is provided on the surface of the first fabric (101), and the resin flow path (S101a) is defined by the groove portion (101a),
    characterized in that
    the groove portion (101a) is formed by performing bagging using a film without disposing a hard material on a surface of a fiber fabric, and then applying pressure and heat, when shaping the first fabric (101).
  3. The method for producing a composite material according to claim 1 or 2, wherein the groove portion (101a) is leveled by applying heat and pressure to the first fabric (101) and the second fabric (102) when curing the thermosetting resin.
  4. The method for producing a composite material according to claim 1, 2 or 3, wherein the groove portion (101a) is coated with a thermoplastic resin or starchy glue.
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JP2018022782A JP7114266B2 (en) 2018-02-13 2018-02-13 Composite material manufacturing method and fiber base material
PCT/JP2019/004983 WO2019159926A1 (en) 2018-02-13 2019-02-13 Method for producing composite material, fiber base material, and shaping mold for fiber base material

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WO2019159926A1 (en) 2019-08-22
JP2019136955A (en) 2019-08-22
US20200391455A1 (en) 2020-12-17
JP7114266B2 (en) 2022-08-08
US11707897B2 (en) 2023-07-25
EP3715081A1 (en) 2020-09-30

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