EP3562623A1 - Abrasive article and method of use - Google Patents

Abrasive article and method of use

Info

Publication number
EP3562623A1
EP3562623A1 EP17832573.4A EP17832573A EP3562623A1 EP 3562623 A1 EP3562623 A1 EP 3562623A1 EP 17832573 A EP17832573 A EP 17832573A EP 3562623 A1 EP3562623 A1 EP 3562623A1
Authority
EP
European Patent Office
Prior art keywords
article
abrasive
backing
tie coat
coat
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
EP17832573.4A
Other languages
German (de)
French (fr)
Inventor
Christopher J. Carter
Martin YALE
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
3M Innovative Properties Co
Original Assignee
3M Innovative Properties Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 3M Innovative Properties Co filed Critical 3M Innovative Properties Co
Publication of EP3562623A1 publication Critical patent/EP3562623A1/en
Withdrawn legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B24—GRINDING; POLISHING
    • B24D—TOOLS FOR GRINDING, BUFFING OR SHARPENING
    • B24D3/00—Physical features of abrasive bodies, or sheets, e.g. abrasive surfaces of special nature; Abrasive bodies or sheets characterised by their constituents
    • B24D3/001—Physical features of abrasive bodies, or sheets, e.g. abrasive surfaces of special nature; Abrasive bodies or sheets characterised by their constituents the constituent being used as supporting member
    • B24D3/002—Flexible supporting members, e.g. paper, woven, plastic materials
    • B24D3/004—Flexible supporting members, e.g. paper, woven, plastic materials with special coatings
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B24—GRINDING; POLISHING
    • B24D—TOOLS FOR GRINDING, BUFFING OR SHARPENING
    • B24D3/00—Physical features of abrasive bodies, or sheets, e.g. abrasive surfaces of special nature; Abrasive bodies or sheets characterised by their constituents
    • B24D3/007—Physical features of abrasive bodies, or sheets, e.g. abrasive surfaces of special nature; Abrasive bodies or sheets characterised by their constituents the constituent being used as bonding agent between different parts of an abrasive tool
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B24—GRINDING; POLISHING
    • B24D—TOOLS FOR GRINDING, BUFFING OR SHARPENING
    • B24D11/00—Constructional features of flexible abrasive materials; Special features in the manufacture of such materials
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B24—GRINDING; POLISHING
    • B24D—TOOLS FOR GRINDING, BUFFING OR SHARPENING
    • B24D2203/00—Tool surfaces formed with a pattern
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B24—GRINDING; POLISHING
    • B24D—TOOLS FOR GRINDING, BUFFING OR SHARPENING
    • B24D3/00—Physical features of abrasive bodies, or sheets, e.g. abrasive surfaces of special nature; Abrasive bodies or sheets characterised by their constituents
    • B24D3/02—Physical features of abrasive bodies, or sheets, e.g. abrasive surfaces of special nature; Abrasive bodies or sheets characterised by their constituents the constituent being used as bonding agent
    • B24D3/20—Physical features of abrasive bodies, or sheets, e.g. abrasive surfaces of special nature; Abrasive bodies or sheets characterised by their constituents the constituent being used as bonding agent and being essentially organic
    • B24D3/28—Resins or natural or synthetic macromolecular compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B24—GRINDING; POLISHING
    • B24D—TOOLS FOR GRINDING, BUFFING OR SHARPENING
    • B24D3/00—Physical features of abrasive bodies, or sheets, e.g. abrasive surfaces of special nature; Abrasive bodies or sheets characterised by their constituents
    • B24D3/34—Physical features of abrasive bodies, or sheets, e.g. abrasive surfaces of special nature; Abrasive bodies or sheets characterised by their constituents characterised by additives enhancing special physical properties, e.g. wear resistance, electric conductivity, self-cleaning properties
    • B24D3/346—Physical features of abrasive bodies, or sheets, e.g. abrasive surfaces of special nature; Abrasive bodies or sheets characterised by their constituents characterised by additives enhancing special physical properties, e.g. wear resistance, electric conductivity, self-cleaning properties utilised during polishing, or grinding operation

Definitions

  • the present invention relates to abrasive articles and methods of using the same for polishing. More particularly, it relates to an abrasive article having a water-softenable tie coat.
  • the preparation of automotive paint surfaces following repair after accident or other damage typically involves a multistage process. This process is initiated by de- nibbing the paint applied to the surface during the repair with a relatively coarse PI 500 abrasive disc. The de-nibbed surface is then refined using a series of increasingly fine grade abrasive discs (typically P3000 and P6000 or JIS2500 and JIS6000), followed by a cutting compound and finally a polish.
  • abrasive discs typically P3000 and P6000 or JIS2500 and JIS6000
  • a coated abrasive article having
  • tie coat is liquid-softenable such that the tie coat maintains the flexible backing in a substantially rigid state when the tie coat is dry and allows the backing to flex when the tie coat is in its softened state.
  • This aspect of the invention delivers advantages as follows.
  • the article When the tie coat is in its dry state, the article is able to deliver a high cut rate due to the tie coat maintaining the rigidity of the backing.
  • the aggressiveness of the cut achieved is reduced due the increased conformity of the backing.
  • the increased conformability allows article more readily to conform to the surface of the paint finish.
  • a further advantage is that the only action required by the user to initiate the change in state is to add liquid, for example water. No change of abrasive article or other tooling is required to alter the cut performance of the abrasive article. This reduces the need for the user to implement multiple abrasive changes to remove dust nibs and restore paint to its original finish.
  • the invention allows the use of a random orbital sander to achieve both cut and finish since the cut achieved when using a conventional abrasive article with a flexible backing on a rotary polisher can be achieved with the abrasive article in its dry state in use on a random orbital sander. This reduces the requirement to use not only multiple abrasive discs but also the requirement to use multiple powered devices in order to restore paint to its original finish.
  • the tie coat is a hydrogel.
  • the tie coat contains an acrylol morpholine oxide UV-curable monomer.
  • the backing is a non-woven web or foam.
  • the backing is a thermoplastic web.
  • the abrasive coat comprises a cured abrasive slurry containing a plurality of abrasives particles,
  • abrasive slurry is soluble such that it retains the abrasive particles on the backing when in its solid state, and releases the abrasive particles from the backing during the process of dissolution to a dissolved state.
  • This aspect of the invention delivers advantages as follows.
  • the article When the abrasive slurry is in its dry state, the article is able to deliver a high cut rate due to the surface texture of the cured abrasive slurry abrading the paint surface.
  • the surface texture of the slurry breaks down allowing the slurry to deliver a high finish to the paint surface.
  • This is advantageous since the only action required by the user to initiate the change in state is to add liquid, for example water. No change of abrasive article or other tooling is required. This eliminates the need for the user to implement multiple abrasive changes to remove dust nibs and restore paint to its original finish.
  • the abrasive slurry is a UV light cured abrasive slurry.
  • this feature of the abrasive article allows surface features to be cured in the surface of the abrasive article which assist in delivering high cut when the abrasive article is in its dry state.
  • the abrasive slurry dissolves into a polishing compound upon dissolution by a liquid.
  • the liquid is a surfactant or emulsion or, more preferably, water.
  • the cured undissolved slurry has a surface texture comprising geometric forms.
  • the cured undissolved slurry has a surface texture comprising polygons.
  • the abrasive particles are formed of vermiculite, alumina or silicon carbide, preferably alumina.
  • a method of abrading a work piece including the steps of:
  • tie coat is liquid-softenable such that the tie coat maintains the flexible backing in a substantially rigid state when the tie coat is dry and allows the backing to flex when the tie coat is in its softened state
  • the method includes the step of:
  • Figure 1 shows an abrasive article in the form of an abrasive disc 10.
  • the disc 10 is suitable for mounting on a rotary polisher or random orbital sander although it is conceivable within the scope of the invention that the abrasive article could be used for other forms of abrasive work.
  • the disc 10 has a backing 12 with first and second opposed major surfaces 14, 16.
  • the first major surface 14 carries a tie coat 18.
  • An abrasive coat 20 is positioned on the tie coat 18.
  • the backing 12 is formed of a non- woven thermoplastic web comprising an open, lofty, three-dimensional structure of fibers bonded to one another at their mutual contact points. Such non- woven backings are well known in the art.
  • the backing 12 is a foam backing and other forms of backing are conceivable within the scope of the invention.
  • the backing material whether non-woven or foam, is flexible so as to offer a degree of compliance to the abrasive disc 10 when wet as will be described in further detail below.
  • the tie coat 18 serves two principal purposes. Firstly, it improves the adhesion of the abrasive coat 20 to the backing and secondly it provides a degree of control over the rigidity of the backing 12. As described above, the backing 12 is inherently flexible.
  • the process of UV-curing the tie coat 18 on the backing hardens the tie coat 18 which then maintains the backing 12 in a rigid state despite its inherent flexibility. This rigidity is maintained until such time as the tie coat 18 comes into contact with water (or other liquid such as an emulsion or surfactant) at which point the tie coat 18 softens.
  • the tie coat 18 contains an acrylol morpholine oxide UV-curable monomer which has a high glass transition temperature, is very hard when dry but is water-soluble in its cured linear polymer form. This solubility allows the tie coat 18 (and thereby the backing 12 to which the tie coat 18 is adhered) to transition from rigid when dry to flexible when wet.
  • the abrasive coat 20 is formed of a UV-curable abrasive slurry which contains a plurality of abrasive particles.
  • the abrasive particles in this embodiment are Alumina 5 ⁇ or Alumina 14 ⁇ although other suitable minerals fall within the scope of the invention.
  • the slurry is cast into a micro-replicated tooling to form a structured abrasive once cured. This process generates a geometric surface texture on the abrasive article in the form of polygons 22.
  • the abrasive coat 20 (by way of the polygons 22) delivers aggressive cut as the tips of the polygons abrade the workpiece.
  • the abrasive slurry like the tie coat 18 described above, contains acrylol morpholine oxide (also referred to as ACMO) which enables the abrasive slurry to dissolve upon contact with water.
  • ACMO acrylol morpholine oxide
  • the addition of water to the abrasive disc 10 causes the aggressive polygons to soften and break up. This reduces the cut of the abrasive article and increases the finish.
  • the small abrasive particles Al in the range of 5 to 14 um
  • the small abrasive particles are freed resulting in the abrasive slurry dissolving into a polishing compound which delivers a high finish to the workpiece.
  • Curing was achieved in a two stage process with the tie coat being cured before application and curing of the abrasive slurry.

Landscapes

  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Polishing Bodies And Polishing Tools (AREA)

Abstract

A coated abrasive article (10) having a flexible backing (12) and an abrasive coat (20) attached to the backing (12) by a tie coat (18), wherein the tie coat (18) is liquid-softenable such that the tie coat (18) maintains the flexible backing (12) in a substantially rigid state when the tie coat (18) is dry and allows the backing (12) to flex when the tie coat (18) is in its softened state.

Description

ABRASIVE ARTICLE AND METHOD OF USE
The present invention relates to abrasive articles and methods of using the same for polishing. More particularly, it relates to an abrasive article having a water-softenable tie coat.
The preparation of automotive paint surfaces following repair after accident or other damage typically involves a multistage process. This process is initiated by de- nibbing the paint applied to the surface during the repair with a relatively coarse PI 500 abrasive disc. The de-nibbed surface is then refined using a series of increasingly fine grade abrasive discs (typically P3000 and P6000 or JIS2500 and JIS6000), followed by a cutting compound and finally a polish.
As a result it is common for the operative to have to change the abrasive disk multiple times during the paint rectification process. This adds complexity and cost to the process as time is spent changing tooling rather than working on the surface to be repaired.
Furthermore it is recognised that abrasive articles with flexible backings have the disadvantage of lower cut unless a powerful rotary polisher is used. Instead a stiffer product must be used on slower random orbital sanders but at the expense of surface finish.
It is an object of the invention to at least mitigate some of the problems set out above.
According to a first aspect of the invention there is provided a coated abrasive article having
a flexible backing and an abrasive coat attached to the backing by a tie coat, wherein the tie coat is liquid-softenable such that the tie coat maintains the flexible backing in a substantially rigid state when the tie coat is dry and allows the backing to flex when the tie coat is in its softened state.
This aspect of the invention delivers advantages as follows. When the tie coat is in its dry state, the article is able to deliver a high cut rate due to the tie coat maintaining the rigidity of the backing. However, when the tie coat is in its softened state following the application of liquid to the abrasive article the aggressiveness of the cut achieved is reduced due the increased conformity of the backing. The increased conformability allows article more readily to conform to the surface of the paint finish. A further advantage is that the only action required by the user to initiate the change in state is to add liquid, for example water. No change of abrasive article or other tooling is required to alter the cut performance of the abrasive article. This reduces the need for the user to implement multiple abrasive changes to remove dust nibs and restore paint to its original finish.
Furthermore, the invention allows the use of a random orbital sander to achieve both cut and finish since the cut achieved when using a conventional abrasive article with a flexible backing on a rotary polisher can be achieved with the abrasive article in its dry state in use on a random orbital sander. This reduces the requirement to use not only multiple abrasive discs but also the requirement to use multiple powered devices in order to restore paint to its original finish.
Preferably, the tie coat is a hydrogel.
Preferably, the tie coat contains an acrylol morpholine oxide UV-curable monomer.
Preferably, the backing is a non-woven web or foam.
More preferably, the backing is a thermoplastic web.
Preferably, the abrasive coat comprises a cured abrasive slurry containing a plurality of abrasives particles,
wherein the abrasive slurry is soluble such that it retains the abrasive particles on the backing when in its solid state, and releases the abrasive particles from the backing during the process of dissolution to a dissolved state.
This aspect of the invention delivers advantages as follows. When the abrasive slurry is in its dry state, the article is able to deliver a high cut rate due to the surface texture of the cured abrasive slurry abrading the paint surface. However, when the abrasive slurry is in its dissolved state, the surface texture of the slurry breaks down allowing the slurry to deliver a high finish to the paint surface. This is advantageous since the only action required by the user to initiate the change in state is to add liquid, for example water. No change of abrasive article or other tooling is required. This eliminates the need for the user to implement multiple abrasive changes to remove dust nibs and restore paint to its original finish.
Furthermore, there is a synergistic advantage to the softening of the tie coat and the dissolution of the abrasive slurry upon the addition of liquid. The flexibility in the backing delivered by the softening of the tie coat acts to improve the effectiveness of the dissolved slurry in delivering high finish to the workpiece since the article is more readily able to conform to the shape of the workpiece.
Preferably, the abrasive slurry is a UV light cured abrasive slurry.
Advantageously this feature of the abrasive article allows surface features to be cured in the surface of the abrasive article which assist in delivering high cut when the abrasive article is in its dry state.
Preferably, the abrasive slurry dissolves into a polishing compound upon dissolution by a liquid.
Preferably, the liquid is a surfactant or emulsion or, more preferably, water.
Preferably, the cured undissolved slurry has a surface texture comprising geometric forms.
More preferably, the cured undissolved slurry has a surface texture comprising polygons.
Preferably, the abrasive particles are formed of vermiculite, alumina or silicon carbide, preferably alumina.
According to a second aspect of the invention there is provided a method of abrading a work piece, the method including the steps of:
providing a coated abrasive article having
a flexible backing and an abrasive coat attached to the backing by a tie coat, wherein the tie coat is liquid-softenable such that the tie coat maintains the flexible backing in a substantially rigid state when the tie coat is dry and allows the backing to flex when the tie coat is in its softened state,
the method including the further steps of:
applying a liquid to the article to soften the tie coat,
abrading the work piece.
Preferably, the method includes the step of:
abrading the work piece with the article in a dry state prior to adding the liquid.
Figure 1 shows an abrasive article in the form of an abrasive disc 10. The disc 10 is suitable for mounting on a rotary polisher or random orbital sander although it is conceivable within the scope of the invention that the abrasive article could be used for other forms of abrasive work. The disc 10 has a backing 12 with first and second opposed major surfaces 14, 16. The first major surface 14 carries a tie coat 18. An abrasive coat 20 is positioned on the tie coat 18. The backing 12 is formed of a non- woven thermoplastic web comprising an open, lofty, three-dimensional structure of fibers bonded to one another at their mutual contact points. Such non- woven backings are well known in the art. In an alternative embodiment the backing 12 is a foam backing and other forms of backing are conceivable within the scope of the invention. The backing material, whether non-woven or foam, is flexible so as to offer a degree of compliance to the abrasive disc 10 when wet as will be described in further detail below.
The tie coat 18 serves two principal purposes. Firstly, it improves the adhesion of the abrasive coat 20 to the backing and secondly it provides a degree of control over the rigidity of the backing 12. As described above, the backing 12 is inherently flexible.
However, the process of UV-curing the tie coat 18 on the backing hardens the tie coat 18 which then maintains the backing 12 in a rigid state despite its inherent flexibility. This rigidity is maintained until such time as the tie coat 18 comes into contact with water (or other liquid such as an emulsion or surfactant) at which point the tie coat 18 softens. This has two effects. Firstly, the tie coat 18 no longer maintains the backing 12 in a rigid state allowing the adhesive disc 10 to adopt a degree of compliance. This reduces the aggression of the cut of the abrasive disc 10. Secondly, the tie coat permits a degree of movement in the abrasive coat 20 which further reduces the aggression of the cut.
The tie coat 18 contains an acrylol morpholine oxide UV-curable monomer which has a high glass transition temperature, is very hard when dry but is water-soluble in its cured linear polymer form. This solubility allows the tie coat 18 (and thereby the backing 12 to which the tie coat 18 is adhered) to transition from rigid when dry to flexible when wet.
The abrasive coat 20 is formed of a UV-curable abrasive slurry which contains a plurality of abrasive particles. The abrasive particles in this embodiment are Alumina 5 μπι or Alumina 14 μπι although other suitable minerals fall within the scope of the invention. The slurry is cast into a micro-replicated tooling to form a structured abrasive once cured. This process generates a geometric surface texture on the abrasive article in the form of polygons 22. When the abrasive disc 10 is dry, the abrasive coat 20 (by way of the polygons 22) delivers aggressive cut as the tips of the polygons abrade the workpiece.
However, the abrasive slurry, like the tie coat 18 described above, contains acrylol morpholine oxide (also referred to as ACMO) which enables the abrasive slurry to dissolve upon contact with water. Thus, the addition of water to the abrasive disc 10 causes the aggressive polygons to soften and break up. This reduces the cut of the abrasive article and increases the finish. As the dissolution continues the small abrasive particles (Alumina in the range of 5 to 14 um) are freed resulting in the abrasive slurry dissolving into a polishing compound which delivers a high finish to the workpiece.
Tie Coat Formulation Example 1
Abrasive Coat Formulation Example 1
Abrasive Coat Formulation Example 2
Abrasive Coat Formulation Example 3
Curing was achieved in a two stage process with the tie coat being cured before application and curing of the abrasive slurry.

Claims

Claims:
1. A coated abrasive article having
a flexible backing and an abrasive coat attached to the backing by a tie coat, wherein the tie coat is liquid-softenable such that the tie coat maintains the flexible backing in a substantially rigid state when the tie coat is dry and allows the backing to flex when the tie coat is in its softened state.
2. The article of claim 1 wherein the tie coat is a hydrogel.
3. The article of claim 2 wherein the tie coat contains an acrylol morpholine oxide UV-curable monomer.
4. The article of claim 1 wherein the backing is a non-woven web or foam.
5. The article of claim 4 wherein the backing is a thermoplastic web.
6. The article of any preceding claim wherein the abrasive coat comprises a cured abrasive slurry containing a plurality of abrasives particles,
wherein the abrasive slurry is soluble such that it retains the abrasive particles on the backing when in its solid state, and releases the abrasive particles from the backing during the process of dissolution to a dissolved state.
7. The article of claim 6 wherein the abrasive slurry is a UV light cured abrasive slurry.
8. The article of claim 7 wherein the slurry dissolves into a polishing compound upon activation by liquid.
9. The article of claim 1 and/or 8 wherein the liquid is water.
10. The article of claim 6 wherein the cured undissolved slurry has a surface texture comprising geometric forms.
11. The article of claim 10 wherein the geometric forms are polygons.
12. The article of claim 6 wherein the abrasive particles are formed of vermiculite, alumina or silicon carbide, preferably of alumina.
13. A method of abrading a work piece, the method including the steps of:
providing a coated abrasive article having
a flexible backing and an abrasive coat attached to the backing by a tie coat, wherein the tie coat is liquid-softenable such that the tie coat maintains the flexible backing in a substantially rigid state when the tie coat is dry and allows the backing to flex when the tie coat is in its softened state,
the method including the further steps of:
applying a liquid to the article to soften the tie coat,
abrading the work piece.
14. The method of claim 13 wherein the method includes the step of:
abrading the work piece with the article in a dry state prior to adding the liquid.
EP17832573.4A 2016-12-30 2017-12-27 Abrasive article and method of use Withdrawn EP3562623A1 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
GBGB1622439.6A GB201622439D0 (en) 2016-12-30 2016-12-30 Abrasive article and method of use
PCT/IB2017/058433 WO2018122742A1 (en) 2016-12-30 2017-12-27 Abrasive article and method of use

Publications (1)

Publication Number Publication Date
EP3562623A1 true EP3562623A1 (en) 2019-11-06

Family

ID=58412326

Family Applications (1)

Application Number Title Priority Date Filing Date
EP17832573.4A Withdrawn EP3562623A1 (en) 2016-12-30 2017-12-27 Abrasive article and method of use

Country Status (5)

Country Link
US (1) US20200023493A1 (en)
EP (1) EP3562623A1 (en)
CN (1) CN110139729A (en)
GB (1) GB201622439D0 (en)
WO (1) WO2018122742A1 (en)

Family Cites Families (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE3151925A1 (en) * 1981-12-30 1983-07-07 Bayer Ag, 5090 Leverkusen Elastic grinding materials based on polyurethane-urea gels and a process for their preparation
US4652275A (en) * 1985-08-07 1987-03-24 Minnesota Mining And Manufacturing Company Erodable agglomerates and abrasive products containing the same
US5700302A (en) * 1996-03-15 1997-12-23 Minnesota Mining And Manufacturing Company Radiation curable abrasive article with tie coat and method
US20090061744A1 (en) * 2007-08-28 2009-03-05 Rajeev Bajaj Polishing pad and method of use
US7232364B2 (en) * 2005-02-04 2007-06-19 3M Innovative Properties Company Abrasive cleaning article and method of making
US8038750B2 (en) * 2007-07-13 2011-10-18 3M Innovative Properties Company Structured abrasive with overlayer, and method of making and using the same
WO2009088606A2 (en) * 2007-12-31 2009-07-16 3M Innovative Properties Company Plasma treated abrasive article and method of making same
JP5555453B2 (en) * 2008-07-24 2014-07-23 スリーエム イノベイティブ プロパティズ カンパニー Abrasive product, method for producing and using the same
CN101704224B (en) * 2009-11-06 2011-05-04 南京航空航天大学 Solidified abrasive grinding and polishing pad with transition layer and bonding layer
CN103282458B (en) * 2011-01-06 2015-05-13 积水化成品工业株式会社 Composition for adhesive hydrogel and use thereof

Also Published As

Publication number Publication date
CN110139729A (en) 2019-08-16
US20200023493A1 (en) 2020-01-23
GB201622439D0 (en) 2017-02-15
WO2018122742A1 (en) 2018-07-05

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