EP3556480B1 - Leveler cleaning sheets and related methods - Google Patents

Leveler cleaning sheets and related methods Download PDF

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Publication number
EP3556480B1
EP3556480B1 EP18167519.0A EP18167519A EP3556480B1 EP 3556480 B1 EP3556480 B1 EP 3556480B1 EP 18167519 A EP18167519 A EP 18167519A EP 3556480 B1 EP3556480 B1 EP 3556480B1
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EP
European Patent Office
Prior art keywords
adhesive layer
leveler
cleaning sheet
ferrous
adhesive
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EP18167519.0A
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German (de)
French (fr)
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EP3556480A1 (en
Inventor
Erwin Tomsin
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Nitto Belgium NV
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Nitto Belgium NV
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Publication date
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Priority to EP18167519.0A priority Critical patent/EP3556480B1/en
Priority to PCT/EP2019/059832 priority patent/WO2019201942A1/en
Publication of EP3556480A1 publication Critical patent/EP3556480A1/en
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B08CLEANING
    • B08BCLEANING IN GENERAL; PREVENTION OF FOULING IN GENERAL
    • B08B7/00Cleaning by methods not provided for in a single other subclass or a single group in this subclass
    • B08B7/0028Cleaning by methods not provided for in a single other subclass or a single group in this subclass by adhesive surfaces
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B21MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
    • B21DWORKING OR PROCESSING OF SHEET METAL OR METAL TUBES, RODS OR PROFILES WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
    • B21D1/00Straightening, restoring form or removing local distortions of sheet metal or specific articles made therefrom; Stretching sheet metal combined with rolling
    • B21D1/02Straightening, restoring form or removing local distortions of sheet metal or specific articles made therefrom; Stretching sheet metal combined with rolling by rollers

Definitions

  • the present invention relates to the use of a leveler cleaning sheet for cleaning the rolls of a leveler machine, such as the work rolls of a tension leveler, for example.
  • the invention relates to a method of manufacturing a leveler cleaning sheet and to leveler cleaning sheets produced by said method.
  • Leveler machines are widely applied for the processing of materials into flat shapes. For example, a leveler arrangement using multiple rolls may be used to process metal coils into flat sheets by application of high pressure (see Fig. 1 ).
  • FIGS. 2A to 2D show a roll with typical contaminations, which generally appear as dark spots ( Fig. 2A ), which, when magnified, may be identified as metal ( Fig. 2B ), cloth and wood ( Fig. 2C ) and dust ( Fig. 2D ) contaminants.
  • the present inventors found that using a leveler cleaning sheet comprising specific configuration and adhesive properties enables inexpensive, efficient, and simple in-line cleaning of leveler machine rolls.
  • the present invention in accordance with claim 1, therefore relates to the use of a leveler cleaning sheet cleaning one or more rolls of a leveler machine, comprising contacting a leveler cleaning sheet with at least a part of the curved surface of the one or more rolls to enable cleaning by rotation of the one or more rolls; the leveler cleaning sheet comprising a substrate and a first adhesive layer provided over the substrate, and the surface of first adhesive layer contacting at least a part of the curved surface of the one or more rolls; wherein the first adhesive layer exhibits an adhesion to ferrous or non-ferrous metals of higher than 10 cN/20mm.
  • the leveler cleaning sheet comprises a second adhesive layer between the substrate and the first adhesive layer and in contact with the substrate, and a carrier layer between the first and the second adhesive layers; and wherein the adhesion to ferrous or non-ferrous metals of the second adhesive layer is higher than that of the first adhesive layer.
  • a further aspect of the present invention in accordance with claim 8, relates to a method of manufacturing a leveler cleaning sheet, comprising the steps of: providing a double-sided adhesive tape comprising a first adhesive layer, a second adhesive layer, a carrier layer between the first and the second adhesive layers, and an optional release liner in contact with the first adhesive layer; adhering the surface of the second adhesive layer to a substrate to provide the leveler cleaning sheet, wherein the first adhesive layer exhibits an adhesion to ferrous or non-ferrous metals of higher than 10 cN/20mm, and wherein the adhesion to ferrous or non-ferrous metals of the second adhesive layer is higher than that of the first adhesive layer.
  • a leveler cleaning sheet comprising: a double-sided adhesive tape comprising a first adhesive layer, a second adhesive layer, a carrier layer between the first and the second adhesive layers, and an optional release liner in contact with the first adhesive layer; wherein the surface of the second adhesive layer is adhered to a substrate; wherein the first adhesive layer exhibits an adhesion to ferrous or non-ferrous metals in the range of from 50 cN/20mm to 600 cN/20mm, and wherein the adhesion to ferrous or non-ferrous metals of the second adhesive layer is higher than that of the first adhesive layer.
  • the present invention in accordance with claim 1, relates to the use of a leveler cleaning sheet cleaning one or more rolls of a leveler machine, comprising contacting a leveler cleaning sheet with at least a part of the curved surface of the one or more rolls to enable cleaning by rotation of the one or more rolls; the leveler cleaning sheet comprising a substrate and a first adhesive layer provided over the substrate, and the surface of first adhesive layer contacting at least a part of the curved surface of the one or more rolls; wherein the first adhesive layer exhibits an adhesion to ferrous or non-ferrous metals of higher than 10 cN/20mm.
  • the leveler machine is generally not particularly limited as long as comprises work rolls supported by backup bearings, and may include flatteners, shape correction levelers and tension levelers, for example.
  • the leveler machine is a tension leveler, which is usually configured to pull a strip (made of metals or alloys, such as hot rolled steel, cold rolled steel, stainless steel, aluminum, or copper, or of non-metallic specialized materials) beyond its yield point (i.e. the point on stress-strain curve which indicates the limit of elastic behavior and the beginning of plastic behavior) both by elongating and bending the strip over a series of work rolls in order to permanently eliminate edge wave and center buckle and correct excessive crossbow and coil set.
  • a tension leveler which is usually configured to pull a strip (made of metals or alloys, such as hot rolled steel, cold rolled steel, stainless steel, aluminum, or copper, or of non-metallic specialized materials) beyond its yield point (i.e. the point on stress-strain curve which indicates the limit of elastic behavior and the beginning of plastic behavior
  • FIG. 1 An exemplary processing line for the leveling of a metal coil and for the production of flat metal sheets is illustrated in Fig. 1 .
  • a metal coil provided on a coil car (1) is fed through an uncoiler (2) and a triple roll-assembly (3), followed by a rewind shirr (4).
  • the trimmed metal foil After passing a trimmer (5), which cuts the metal foil to a predetermined width, the trimmed metal foil enters the leveling machine (6) comprising a multiplicity of rolls (see dashed line marking), while the scrap material exiting the trimmer (5) is wound on a scrap winder (7).
  • the leveled material is then conveyed to a shirr machine (9), wherein the metal foil is cut into flat sheets with predetermined length and collected as finished goods (10).
  • the leveler cleaning sheet is inserted into the leveler machine and passed through the running machine, preferably under normal leveling conditions. Accordingly, the rolls do not have to be removed or made accessible as in manual cleaning operations and necessary adjustments may be kept at a minimum.
  • the line speed of the leveler 0.5 to 2 m/min, preferably to 0.7 to 1.3 m/min.
  • other line speeds may also be selected by the skilled artisan depending on the desired cleaning performance and the available time for the cleaning operation.
  • passing the sheet through the leveler once is sufficient for effective cleaning. Accordingly, the actual duration of the cleaning process is remarkably shortened and takes less than one minute for most tension levelers, typically around 20 seconds. In comparison to most conventional techniques, the production loss is therefore significantly reduced.
  • the leveler roll gap may be suitably adjusted by the skilled artisan depending on the thickness of the roll cleaning sheet.
  • the leveler cleaning sheet used in the method according to the first embodiment of the present invention may be configured according to cleaning sheet (20a) shown in Fig. 3A , comprising a substrate (21) and a first adhesive layer (22).
  • the used leveler cleaning sheet comprises one or more further layers between the substrate and the first adhesive layer, for instance a second adhesive layer (23) according to the cleaning sheet (20b) depicted in Fig. 3B
  • a leveler cleaning sheet according to Fig. 3C is used the sheet (20c) comprising a second adhesive layer (23) between the substrate (21) and the first adhesive layer (22) and in contact with the substrate (21), and a carrier layer (24) between the first and the second adhesive layers (22) and (23).
  • a double-sided pressure-sensitive adhesive tape comprising the first adhesive layer, the second adhesive layer, and the carrier layer between the first and the second adhesive layers, to the substrate in order to provide the leveler cleaning sheet.
  • the step of adhering the surface of the second adhesive layer to a substrate may be performed manually or mechanically, e.g. by a lamination device.
  • the adhesion to ferrous or non-ferrous metals of the second adhesive layer is higher than that of the first adhesive layer in order to prevent delamination of the double-sided adhesive tape from the substrate during contact of the first substrate with the one or more rolls to be cleaned.
  • the leveler roll gap may be suitably adjusted by the skilled artisan depending on the thickness and the rigidity of the roll cleaning sheet.
  • an efficient in-line cleaning method is provided, which is simultaneously inexpensive and environment-friendly, especially when compared to solvent-based cleaning methods.
  • the method enables efficient cleaning of the rolls with a single pass of the cleaning sheet through the leveler, which remarkably accelerates the cleaning process and thus dramatically improves production efficiency.
  • the properties and compositions of the leveler cleaning sheet including the first adhesive layer and the substrate, as well as the optional carrier layer and the optional second adhesive layer will be further described in conjunction with the second embodiment below, including preferred embodiments thereof. Overall, it will be appreciated that the preferred features of the first and second embodiments specified above may be combined in any combination, except for combinations where at least some of the features are mutually exclusive.
  • the present invention in accordance with claim 8, relates to a method of manufacturing a leveler cleaning sheet, comprising the steps of: providing a double-sided adhesive tape comprising a first adhesive layer, a second adhesive layer, a carrier layer between the first and the second adhesive layers, and an optional release liner in contact with the first adhesive layer; adhering the surface of the second adhesive layer to a substrate to provide the leveler cleaning sheet, wherein the first adhesive layer exhibits an adhesion to ferrous or non-ferrous metals of higher than 10 cN/20mm, and wherein the adhesion to ferrous or non-ferrous metals of the second adhesive layer is higher than that of the first adhesive layer.
  • the initial step of method of manufacturing a leveler cleaning sheet according to the present invention lies in the provision of a double-sided adhesive tape in accordance to Fig. 3D , comprising a first adhesive layer (22), a second adhesive layer (23), a carrier layer (24) between the first adhesive layer (22) and the second adhesive layer (23), and an optional release liner (25) in contact with the first adhesive layer (22).
  • a double-sided adhesive tape in accordance to Fig. 3D , comprising a first adhesive layer (22), a second adhesive layer (23), a carrier layer (24) between the first adhesive layer (22) and the second adhesive layer (23), and an optional release liner (25) in contact with the first adhesive layer (22).
  • Such double-sided adhesive tapes (20d) may be manufactured from scratch or may be suitably selected from commercially available products.
  • the "adhesion to ferrous or non-ferrous metals”, as used herein, denotes the peel adhesion property on a clean and dry surface made of a ferrous or non-ferrous metal, which may include surfaces of metals and metal alloys, such as steel, for example. While not being limited thereto, in a preferred embodiment of the present invention, the wording "adhesion to ferrous or non-ferrous metals", as used herein, denotes the peel adhesion on BA steel determined according to EN 1939.
  • the first adhesive layer exhibits an adhesion to ferrous or non-ferrous metals in the range of from 10 to 600 cN/20mm, further preferably in the range of from 50 to 500 cN/20mm, especially preferably in the range of from 100 to 450 cN/20mm, and most preferably in the range of from 150 to 400 cN/20mm, at which particularly advantageous roll cleaning efficiencies are achieved.
  • Suitable formulations for manufacturing the first and second adhesive layers with the above-cited adhesion properties will be known to the skilled artisan and are not particularly limited.
  • exemplary adhesive formulations for the first adhesive layer may include acrylate-based, rubber-based, urethane-based, silicone-based adhesive formulations and combinations of two or more thereof, preferably at contents of 50 wt.-% to 100 wt.-%, more preferably at contents of 60 wt.-% to 98 wt.-% by weight, such as from 70 wt.-% to 95 wt.-%, or from 80 wt.-% to 93 wt.-%, for example, each based on the total weight of the first adhesive layer.
  • the first adhesive layer comprises an acrylic pressure-sensitive adhesive.
  • the acrylic pressure-sensitive adhesive preferably comprises a (meth)acrylic polymer as the main component (e.g. at a content of 50% by weight or more of the acrylic pressure-sensitive adhesive).
  • the (meth)acrylic polymer may be selected from a block copolymer, an alternating copolymer, and a graft copolymer, for example.
  • the (meth)acrylic polymer may be prepared by polymerization of one or more C 1 -C 18 -alkyl (meth)acrylate monomers.
  • the (meth)acrylic polymer may also include other monomers copolymerizable with alkyl (meth)acrylate, e.g. for introducing a crosslinking site into the acrylic polymer or enhancing an aggregating ability of the acrylic polymer.
  • the copolymerizable monomer component may be used solely or in combination of two or more thereof.
  • the ratio of the alkyl(meth)acrylate to the total amount of the monomer components constituting the acrylic polymer is desirably 50% by weight or more.
  • Exemplary urethane-based adhesive formulations include, but are not limited to polyisocyanate compounds (e.g. diphenylmethane diisocyanate, tolylene diisocyanate, hexamethylene diisocyanate) reacted with polyols (e.g. polyether polyols, polyester polyols, polycarbonate polyols, polycaprolactone polyols, etc.).
  • polyisocyanate compounds e.g. diphenylmethane diisocyanate, tolylene diisocyanate, hexamethylene diisocyanate
  • polyols e.g. polyether polyols, polyester polyols, polycarbonate polyols, polycaprolactone polyols, etc.
  • Exemplary rubber-based adhesive formulations include, but are not limited to natural rubbers or synthetic rubber-based adhesives (such as adhesives based on SBS, SBR, SEPS, SIS, SEBS, polyisobutylene, and/or butyl rubber, for example).
  • polymer-based adhesives including polymerization types (anionic, cationic or radical polymerization; solution, emulsification, mass, and suspension polymerization) and reaction conditions, are well-known in the art and may be appropriately selected by the skilled artisan depending on the used starting materials (i.e. monomers).
  • polymerization types anionic, cationic or radical polymerization; solution, emulsification, mass, and suspension polymerization
  • reaction conditions are well-known in the art and may be appropriately selected by the skilled artisan depending on the used starting materials (i.e. monomers).
  • the first adhesive layer may comprise further additives, which may be appropriately selected by the skilled artisan from known materials, including but not limited to tackifiers (e.g. tackifying resins including one or more of rosin-based tackifying resins, terpene-based tackifying resins, hydrocarbon-based tackifying resins, epoxy-based tackifying resins, polyamide-based tackifying resins, elastomer-based tackifying resins, phenol-based tackifying resins, and/or ketone-based tackifying resins, for example), crosslinking agents (e.g.
  • tackifiers e.g. tackifying resins including one or more of rosin-based tackifying resins, terpene-based tackifying resins, hydrocarbon-based tackifying resins, epoxy-based tackifying resins, polyamide-based tackifying resins, elastomer-based tackifying resins,
  • isocyanate-based crosslinking agents epoxy-based crosslinking agents, oxazolidine-based crosslinking agents, aziridine-based crosslinking agents, melamine-based crosslinking agents, peroxide-based crosslinking agents, urea-based crosslinking agents, metal alkoxide-based crosslinking agents, metal chelate-based crosslinking agents, metal salt-based crosslinking agents, carbodiimide-based crosslinking agents, and/or amine-based crosslinking agents; preferably used at (total) contents of 0.1 to 20 wt.-% based on total weight of the adhesive layer), plasticizers, polymerization inhibitors, emulsifiers, pH buffering agents, foam inhibitors, stabilizers, anti-aging agents, UV-absorbers, antioxidants, anticorrosion-agents, light stabilizers, peeling regulators, softening agents, fillers, colorants (pigment, dye, etc.), surfactants, antistatic agents, and the like.
  • the adhesion of the second adhesive layer to ferrous or non-ferrous metals is not particularly limited as long as it is higher than that of the first adhesive layer.
  • the adhesion to ferrous or non-ferrous metals of the first adhesive layer is preferably less than 30%, more preferably less than 25% of that of the second adhesive layer.
  • the adhesion to ferrous or non-ferrous metals of the first adhesive layer is higher than 4%, more preferably higher than 6% of that of the second adhesive layer.
  • the adhesion to ferrous or non-ferrous metals of the second adhesive layer is in the range of from 800 to 2100 cN/20mm, further preferably 1000 to 2000 cN/20mm, more preferably 1200 to 1800 cN/20 mm, most preferably 1400 to 1650 cN/20mm.
  • Working within these ranges effectively prevents delamination, while still allowing the double-sided tape to be easily removed after the cleaning process, thereby enabling the substrate to be reused for multiple roll cleaning operations.
  • the material constituting the second adhesive layer is not particularly limited and may be suitably selected depending on its adhesion properties on ferrous or non-ferrous metals.
  • the second adhesive layer comprises an acrylic pressure-sensitive adhesive.
  • the second adhesive layer comprises a (meth)acrylic polymer as the main component (e.g. at a content of 50% by weight or more of the acrylic pressure-sensitive adhesive) according to the above description of the first adhesive layer.
  • the acrylic pressure-sensitive adhesive used in the second adhesive layer is prepared by polymerizing a monomer composition comprising primarily an alkyl (meth)acrylate (e.g. a C 1 -C 18 -alkyl (meth)acrylate) and one or more modifying monomer(s) copolymerizable with the alkyl (meth)acrylate.
  • hydroxyl group-containing monomers including hydroxyethyl (meth)acrylate, 2-hydroxypropyl (meth)acrylate, 4-hydroxybutyl (meth)acrylate, 6-hydroxyhexyl (meth)acrylate, 8-hydroxyoctyl (meth)acrylate, 12-hydroxylauryl (meth)acrylate, N-methylol(meth)acrylamide, vinyl alcohol, allyl alcohol, 2-hydroxyethyl vinyl ether, 4-hydroxybutyl vinyl ether, diethyleneglycol monovinyl ether, for example), carboxyl group-containing monomers ((meth)acrylic acid, carboxyl ethyl (meth)acrylate, itaconic acid, maleic acid, fumaric acid, etc.), styrene-based monomers (such as styrene or styrene derivatives comprising alkyl, halogen, or haloalkyl groups, for example), cyano group-
  • epoxy group-containing monomers e.g. glycidyl (meth)acrylate
  • amide group-containing monomers e.g. (meth)acrylamide
  • imide group-containing monomers e.g. N-cyclohexyl maleimide
  • vinyl ethers and vinyl esters e.g. vinyl propionate
  • the carrier layer (24) is composed of materials that may be suitably selected by the skilled artisan, including polymers, metals, nonwoven fabrics, paper and combinations thereof, for example.
  • the carrier layer comprises a polymer, such as a polyester (e.g. polyethylene terephthalate (PET), polybutylene terephthalate, polyethylene naphthalate etc.), polyamide (aliphatic or aromatic polyamides, for example) and/or polyolefin (polyethylene, polypropylene, polybutylene, etc.).
  • PET polyethylene terephthalate
  • polybutylene terephthalate polyethylene naphthalate etc.
  • polyamide aliphatic or aromatic polyamides, for example
  • polyolefin polyethylene, polypropylene, polybutylene, etc.
  • a carrier layer comprising a polyester-based material is particularly preferred, as it allows easy lamination and use of rolls of double-sided adhesive tapes, as opposed to being limited to the application of sheets.
  • the carrier layer may further contain additives, such as antioxidants, UV-absorbing agents, antistatic agents, light stabilizers, fillers, colorants etc.
  • additives such as antioxidants, UV-absorbing agents, antistatic agents, light stabilizers, fillers, colorants etc.
  • the carrier layer may be composed of a single layer or of multiple layers having different compositions.
  • the thickness of the carrier layer may be suitably selected by the skilled artisan. Preferable thicknesses range from 1 ⁇ m to 1000 ⁇ m. Particularly preferred is a carrier layer thickness of from 50 ⁇ m to 250 ⁇ m, which enables easy die-cutting of the resulting cleaning sheet and renders it stable towards film burrs.
  • the optional release liner may be suitably selected from materials known in the art. Examples thereof include, but are not limited to siliconized paper, PE-coated paper, siliconized PE-coated paper, PET, PP, etc.
  • the double-adhesive tape used in the present invention may be provided with a release liner on both the first and the second adhesive layers. In case two release liners are used, they may be identical or different.
  • the leveler cleaning sheet may be prepared on-site, by adhering the double-sided adhesive tape on the chosen substrate (in which case a release liner has preferably been also provided on the first adhesive layer, which may facilitate the handling for the operation personnel) or before delivery to the customer for easier application.
  • the method of the second embodiment further comprises the step of winding the cleaning sheet into a roll form, wherein the substrate contacts the first adhesive layer, and the substrate is preferably on the outside surface of the roll.
  • a configuration significantly facilitates the handling and the cleaning operation for the operating personnel, and further enables the insertion using a coil car, similarly to the process shown in Fig, 1 .
  • no release liner on the first adhesive layer is necessary, so that the manufacturing costs may be further reduced.
  • the roll is provided with perforations in parallel to the roll axis.
  • the cleaning sheet may comprise a release liner having larger dimensions than the double-sided adhesive tape.
  • the width of release liner may extend beyond the surface of the double-sided adhesive tape on at least one side thereof (for example, at one or both edges in width direction if wound on a roll, by selecting a higher release liner width relative to the width double-sided adhesive tape).
  • FIGs 4A to 4H An exemplary manual application of such a cleaning sheet roll is illustrated in Figures 4A to 4H , including the steps of unrolling (an optionally pre-perforated) roll ( Figs. 4A and 4B ), tearing off (if perforated) or cutting the roll ( Figs. 4C and 4D ), manually applying the thus obtained sheet onto the roll material surface ( Fig. 4E ), optionally with a scraping tool ( Fig. 4F ), and removing the top release liner from the sheet ( Figs. 4G and 4H ), which may be further facilitated by providing the cleaning sheet with dry-edges at the side of the sheet (e.g. by dimensioning the top release liner larger than the double-sided adhesive tape).
  • the total thickness of the double-sided adhesive tape without the optional release liner(s) is preferably in a range of from 1 ⁇ m to 5 mm, further preferably in a range of from 5 ⁇ m to 500 ⁇ m, as may be determined according to EN 1942, for example.
  • the double-sided pressure-sensitive adhesive tape exhibits a static shear of 10 mm/3h or less, more preferably of 5 mm/3h or less, further preferably of 2 mm/3h or less, which may be determined according to EN 1943.
  • the double-sided adhesive tape may comprise further layers between the first and second adhesive layers beside of the carrier layer.
  • the double-sided adhesive tape may comprise one or more adhesive layers and/or carrier-type layers between the carrier layer and one of the first and second adhesive layers.
  • a three layer-configuration consisting of a first adhesive layer, a second adhesive layer and a carrier layer between and in contact with the first and the second adhesive layers (as well as one or two optional release liner(s) on the surface(s) of the adhesive layer(s)) is preferable.
  • the substrate comprised in any of the above-described cleaning sheets may be suitably selected by the skilled artisan depending on the desired properties of the cleaning sheets and may be composed of a single layer or multiple layers with different compositions. It is important to note that the material constituting the substrate of the leveler cleaning sheet is not particularly limited as long as it is able to withstand the mechanical forces exerted by the leveler. For instance, the substrate may differ from the strip material for which the leveling process has been set up. As exemplary materials, metals (e.g. iron, copper, aluminum, zinc), alloys (e.g.
  • the substrate may comprise a metal, an alloy, or a polymer.
  • the substrate material is selected from a material having a density of less than 3 kg/dm 3 , such as aluminum or polymer-based materials, for example, since such light-weight materials may be easily handled by a single operator as opposed to steel sheets, for example.
  • Polymer-based materials including, but not limited to polyamide or PTFE and derivatives thereof, are particularly preferred.
  • the method of the second embodiment enables facilitated and inexpensive production of a leveler cleaning sheet with excellent roll cleaning performance.
  • the present invention in accordance with claim 10, relates to a leveler cleaning sheet.
  • the leveler cleaning sheet comprises: a first adhesive layer, a second adhesive layer, a carrier layer between the first and the second adhesive layers, and a substrate in contact with the second adhesive layer to a substrate to provide the leveler cleaning sheet, wherein the first adhesive layer exhibits an adhesion to ferrous or non-ferrous metals in the range of from 50 cN/20mm to 600 cN/20mm, and wherein the adhesion to ferrous or non-ferrous metals of the second adhesive layer is higher than that of the first adhesive layer.
  • An exemplary configuration is shown in Fig. 3C .
  • the cleaning sheet is wound into a roll and further preferably comprises perforations in parallel to the roll axis. which significantly facilitates the handling of the cleaning sheet and the roll cleaning procedure so as to be executable by a single person (see Figs. 4A to 4H ), and also allows for installation in a coil car in the feed section of leveler machines.
  • a release liner having larger dimensions than the double-sided adhesive tape may be provided.
  • the width of release liner may extend beyond the surface of the double-sided adhesive tape on one or both sides of the wound roll (e.g.
  • a leveler cleaning sheet with a configuration according to Fig. 3C was prepared by manually laminating multiple double-sided adhesive tapes (Nitto Double Coated Tape 61390; tape thickness without liner: 0.090 mm; adhesion to non-ferrous and ferrous metal surfaces: 1500 cN/20mm (open side), 350 cN/20mm (closed side); carrier: 0.012 mm transparent polyester) at the open sides onto a cleaned metallic substrate sheet (width: 1524 mm).
  • the thus obtained leveler cleaning sheet was passed through a tension leveler machine having a working roll (width: 1600 mm) contaminated with metal, dust and other dirt particles due to the metal sheet leveling under typical conditions, at a line speed of approximately 1 m/min.
  • the cleaning sheet Upon exiting the leveler, the cleaning sheet was visually inspected (see Fig. 3 ).
  • the photograph in Fig. 5 shows that nearly all dirt particles on the working roll effectively adhered to the layer of the leveler cleaning sheet corresponding to the first adhesive layer within one or a few revolution(s) of the working roll. As is indicated by the dashed line, the cleaning efficiency may be easily judged based on the visual appearance of the cleaning sheet.
  • Fig. 6A The cleaning test according to Example 1 was repeated, with the exception that A3-shaped Nitto Double Coated Tape 61390 was manually applied onto the substrate in the arrangement shown in Fig. 6A .
  • the visual appearance of the cleaning sheet exiting the leveler machine is depicted in Fig. 6B .
  • major dirt particles effectively adhered to the layer of the leveler cleaning sheet corresponding to the first adhesive layer.
  • the leveler was opened and the cleaning performance was evaluated based on the appearance of the working roll.
  • Fig. 7 is a photograph of the opened leveler, which shows that the part of the working roll that contacted the cleaning sheet (right hand side) has been effectively cleaned when compared to the uncleaned area of the working roll (left hand side).
  • the method according to the present invention effectively and quickly cleans the contaminated rolls of a leveler machine, enables simple and cost-effective cleaning operation, and allows the leveler operator to easily assess the degree of contamination of the working rolls.

Landscapes

  • Cleaning In General (AREA)
  • Adhesive Tapes (AREA)

Description

    FIELD OF INVENTION
  • The present invention relates to the use of a leveler cleaning sheet for cleaning the rolls of a leveler machine, such as the work rolls of a tension leveler, for example.
  • In addition, the invention relates to a method of manufacturing a leveler cleaning sheet and to leveler cleaning sheets produced by said method.
  • BACKGROUND OF THE INVENTION
  • Leveler machines are widely applied for the processing of materials into flat shapes. For example, a leveler arrangement using multiple rolls may be used to process metal coils into flat sheets by application of high pressure (see Fig. 1).
  • A general problem observed in tension leveling processes is that contaminants (metal particles, paper powder, felt particles, abrasive metal oxides (Al2O3), and other foreign materials) may stick to the work and backup rolls during leveler operation and collect thereon until they generate marks and dents in the resulting leveled sheet, cause undesired vibration in the leveling machine and reduce the yield and/or quality of the leveled material. Figures 2A to 2D show a roll with typical contaminations, which generally appear as dark spots (Fig. 2A), which, when magnified, may be identified as metal (Fig. 2B), cloth and wood (Fig. 2C) and dust (Fig. 2D) contaminants.
  • In view of the above, a number of different methods have been proposed to minimize or eliminate the formation of marks and dents in the leveled strip by regular roll cleaning procedures, including off-line cleaning of the rolls after removal from the leveler. Another method includes cleaning of the work rolls in the deactivated leveler, for example by inserting a cleaning pad into the roll nip and manually rotating the roll to wipe foreign materials off of its surface, or by washing the rolls with a solvent spray.
  • Since these methods are time-consuming and often require highly qualified operating personnel to be conducted effectively, efforts have been made to develop in-line processes, wherein the cleaning operation is performed while running the leveler machine. For example, US 2007-180879 A1 discloses the implementation of a scraping device for continuous cleaning of work rolls. While this method reduces losses in production time, it is relatively expensive, particularly when cleaning of more than two rolls is desired, and requires additional maintenance. Other methods include passing a strip of fabric (e.g. felt) which is soaked in or sprayed with organic solvent, such as petroleum hydrocarbon or cellulose thinner, through the leveler machine, thereby wiping the surface of the back-up rolls and removing contaminating particles (see EP 0 715 551 B1 or WO 95/06529 , for example). However, felt cleaning requires at least about 30 minutes per cleaning step and the cleaning efficiency is difficult to judge. Last but not least, the use of organic solvents raises concerns from an environmental point of view.
  • In addition, conventional methods using cleaning sheets often have the problem that the cleaning preparation and operation steps are difficult or even impossible to perform by a single operator.
  • Therefore, it remains desirable to provide an efficient in-line cleaning method, which is simultaneously inexpensive, environment-friendly, improves production efficiency, and which may be conducted by a leveler operator in a simple manner. In addition, it is desirable to provide a high quality leveler cleaning sheet which may be produced easily and used for the aforementioned method.
    Cleaning sheets for the cleaning of semiconductor wafers, substrates for flat panel displays, compact diss, and MR heads are disclosed in EP 1 942 519 A1 . JP H03 165902 A discloses an adhesive belt system for removing dust from carrier rolls used for a continuous conveying system as a replacement for brushing or polishing devices. WO 2010/023807 A1 discloses a panel with a cleaning function for glass, plastic and ceramic substrates. A coating line cleaning apparatus is disclosed in GB 2532255 A .
  • SUMMARY OF THE INVENTION
  • The present invention solves these objects with the subject matter of the claims as defined herein. The advantages of the present invention will be further explained in detail in the section below and further advantages will become apparent to the skilled artisan upon consideration of the invention disclosure.
  • The present inventors found that using a leveler cleaning sheet comprising specific configuration and adhesive properties enables inexpensive, efficient, and simple in-line cleaning of leveler machine rolls.
  • Generally speaking, the present invention, in accordance with claim 1, therefore relates to the use of a leveler cleaning sheet cleaning one or more rolls of a leveler machine, comprising contacting a leveler cleaning sheet with at least a part of the curved surface of the one or more rolls to enable cleaning by rotation of the one or more rolls; the leveler cleaning sheet comprising a substrate and a first adhesive layer provided over the substrate, and the surface of first adhesive layer contacting at least a part of the curved surface of the one or more rolls; wherein the first adhesive layer exhibits an adhesion to ferrous or non-ferrous metals of higher than 10 cN/20mm. Optionally, the leveler cleaning sheet comprises a second adhesive layer between the substrate and the first adhesive layer and in contact with the substrate, and a carrier layer between the first and the second adhesive layers; and wherein the adhesion to ferrous or non-ferrous metals of the second adhesive layer is higher than that of the first adhesive layer.
  • A further aspect of the present invention, in accordance with claim 8, relates to a method of manufacturing a leveler cleaning sheet, comprising the steps of: providing a double-sided adhesive tape comprising a first adhesive layer, a second adhesive layer, a carrier layer between the first and the second adhesive layers, and an optional release liner in contact with the first adhesive layer; adhering the surface of the second adhesive layer to a substrate to provide the leveler cleaning sheet, wherein the first adhesive layer exhibits an adhesion to ferrous or non-ferrous metals of higher than 10 cN/20mm, and wherein the adhesion to ferrous or non-ferrous metals of the second adhesive layer is higher than that of the first adhesive layer.
  • Another aspect of the present invention, in accordance to claim 10, is a leveler cleaning sheet comprising: a double-sided adhesive tape comprising a first adhesive layer, a second adhesive layer, a carrier layer between the first and the second adhesive layers, and an optional release liner in contact with the first adhesive layer; wherein the surface of the second adhesive layer is adhered to a substrate; wherein the first adhesive layer exhibits an adhesion to ferrous or non-ferrous metals in the range of from 50 cN/20mm to 600 cN/20mm, and wherein the adhesion to ferrous or non-ferrous metals of the second adhesive layer is higher than that of the first adhesive layer.
  • Preferred embodiments of the leveler cleaning sheets according to the present invention and the related methods of the present invention are described in the following description and the claims.
  • BRIEF DESCRIPTION OF THE DRAWINGS
    • FIG. 1 shows an exemplary leveling process using a metal coil.
    • FIG. 2A shows a contaminated roll surface.
    • FIG. 2B is a magnified view of a part of Fig. 2A, showing metal contaminations.
    • FIG. 2C is a magnified view of a part of Fig. 2A, showing cloth and wood contaminations.
    • FIG. 2D is a magnified view of a part of Fig. 2A, showing dust contaminations.
    • FIG. 3A illustrates the exemplary configuration of a leveler cleaning sheet as used in the present invention.
    • FIG. 3B illustrates the exemplary configuration of a leveler cleaning sheet comprising two adhesive layers as used in the present invention.
    • FIG. 3C illustrates the exemplary configuration of a leveler cleaning sheet according to the present invention.
    • FIG. 3D illustrates the exemplary configuration of a double-sided tape as used in the present invention.
    • FIGS. 4A to 4H illustrate an exemplary manual application of a cleaning sheet provided in roll form, according to an embodiment of the present invention.
    • FIG. 5 is a photograph of a cleaning sheet that has been passed through a leveler machine according to Example 1 of the present invention.
    • FIG. 6A is a photograph of the cleaning sheet according to Example 2 before insertion into leveler.
    • FIG. 6B is a photograph of the cleaning sheet according to Example 2 after cleaning operation.
    • FIG. 7 is a photograph of an opened leveler showing uncleaned and cleaned parts of a working roll.
    DETAILED DESCRIPTION OF THE INVENTION
  • For a more complete understanding of the present invention, reference is now made to the following description of the illustrative embodiments thereof.
  • Leveler Roll Cleaning Method
  • In a first embodiment, the present invention, in accordance with claim 1, relates to the use of a leveler cleaning sheet cleaning one or more rolls of a leveler machine, comprising contacting a leveler cleaning sheet with at least a part of the curved surface of the one or more rolls to enable cleaning by rotation of the one or more rolls; the leveler cleaning sheet comprising a substrate and a first adhesive layer provided over the substrate, and the surface of first adhesive layer contacting at least a part of the curved surface of the one or more rolls; wherein the first adhesive layer exhibits an adhesion to ferrous or non-ferrous metals of higher than 10 cN/20mm.
  • The leveler machine is generally not particularly limited as long as comprises work rolls supported by backup bearings, and may include flatteners, shape correction levelers and tension levelers, for example. Preferably, the leveler machine is a tension leveler, which is usually configured to pull a strip (made of metals or alloys, such as hot rolled steel, cold rolled steel, stainless steel, aluminum, or copper, or of non-metallic specialized materials) beyond its yield point (i.e. the point on stress-strain curve which indicates the limit of elastic behavior and the beginning of plastic behavior) both by elongating and bending the strip over a series of work rolls in order to permanently eliminate edge wave and center buckle and correct excessive crossbow and coil set.
  • An exemplary processing line for the leveling of a metal coil and for the production of flat metal sheets is illustrated in Fig. 1. Herein, a metal coil provided on a coil car (1) is fed through an uncoiler (2) and a triple roll-assembly (3), followed by a rewind shirr (4). After passing a trimmer (5), which cuts the metal foil to a predetermined width, the trimmed metal foil enters the leveling machine (6) comprising a multiplicity of rolls (see dashed line marking), while the scrap material exiting the trimmer (5) is wound on a scrap winder (7). Via a feeder (8), the leveled material is then conveyed to a shirr machine (9), wherein the metal foil is cut into flat sheets with predetermined length and collected as finished goods (10).
  • In order to perform the cleaning operation according to the present invention by contacting a leveler cleaning sheet with at least a part of the curved surface of the one or more rolls of the leveler, the leveler cleaning sheet is inserted into the leveler machine and passed through the running machine, preferably under normal leveling conditions. Accordingly, the rolls do not have to be removed or made accessible as in manual cleaning operations and necessary adjustments may be kept at a minimum.
  • During the cleaning operation, it is recommended to set the line speed of the leveler to 0.5 to 2 m/min, preferably to 0.7 to 1.3 m/min. However, other line speeds may also be selected by the skilled artisan depending on the desired cleaning performance and the available time for the cleaning operation. In view of the properties of the used cleaning sheet (which will be explained in further detail below), passing the sheet through the leveler once is sufficient for effective cleaning. Accordingly, the actual duration of the cleaning process is remarkably shortened and takes less than one minute for most tension levelers, typically around 20 seconds. In comparison to most conventional techniques, the production loss is therefore significantly reduced.
  • The leveler roll gap may be suitably adjusted by the skilled artisan depending on the thickness of the roll cleaning sheet.
  • In general, the leveler cleaning sheet used in the method according to the first embodiment of the present invention may be configured according to cleaning sheet (20a) shown in Fig. 3A, comprising a substrate (21) and a first adhesive layer (22). However, it may be preferable that the used leveler cleaning sheet comprises one or more further layers between the substrate and the first adhesive layer, for instance a second adhesive layer (23) according to the cleaning sheet (20b) depicted in Fig. 3B
  • In a preferred embodiment, a leveler cleaning sheet according to Fig. 3C is used the sheet (20c) comprising a second adhesive layer (23) between the substrate (21) and the first adhesive layer (22) and in contact with the substrate (21), and a carrier layer (24) between the first and the second adhesive layers (22) and (23). Such a configuration may be easily achieved by adhering a double-sided pressure-sensitive adhesive tape comprising the first adhesive layer, the second adhesive layer, and the carrier layer between the first and the second adhesive layers, to the substrate in order to provide the leveler cleaning sheet. The step of adhering the surface of the second adhesive layer to a substrate may be performed manually or mechanically, e.g. by a lamination device.
  • In general, if a second adhesive layer is used in the abovementioned configurations, the adhesion to ferrous or non-ferrous metals of the second adhesive layer is higher than that of the first adhesive layer in order to prevent delamination of the double-sided adhesive tape from the substrate during contact of the first substrate with the one or more rolls to be cleaned.
  • The leveler roll gap may be suitably adjusted by the skilled artisan depending on the thickness and the rigidity of the roll cleaning sheet.
  • Accordingly, an efficient in-line cleaning method is provided, which is simultaneously inexpensive and environment-friendly, especially when compared to solvent-based cleaning methods. Last but not least, the method enables efficient cleaning of the rolls with a single pass of the cleaning sheet through the leveler, which remarkably accelerates the cleaning process and thus dramatically improves production efficiency.
  • The properties and compositions of the leveler cleaning sheet including the first adhesive layer and the substrate, as well as the optional carrier layer and the optional second adhesive layer will be further described in conjunction with the second embodiment below, including preferred embodiments thereof. Overall, it will be appreciated that the preferred features of the first and second embodiments specified above may be combined in any combination, except for combinations where at least some of the features are mutually exclusive.
  • Manufacturing Methods for Leveler Cleaning Sheets
  • In a second embodiment, the present invention, in accordance with claim 8, relates to a method of manufacturing a leveler cleaning sheet, comprising the steps of: providing a double-sided adhesive tape comprising a first adhesive layer, a second adhesive layer, a carrier layer between the first and the second adhesive layers, and an optional release liner in contact with the first adhesive layer; adhering the surface of the second adhesive layer to a substrate to provide the leveler cleaning sheet, wherein the first adhesive layer exhibits an adhesion to ferrous or non-ferrous metals of higher than 10 cN/20mm, and wherein the adhesion to ferrous or non-ferrous metals of the second adhesive layer is higher than that of the first adhesive layer.
  • The initial step of method of manufacturing a leveler cleaning sheet according to the present invention lies in the provision of a double-sided adhesive tape in accordance to Fig. 3D, comprising a first adhesive layer (22), a second adhesive layer (23), a carrier layer (24) between the first adhesive layer (22) and the second adhesive layer (23), and an optional release liner (25) in contact with the first adhesive layer (22). Such double-sided adhesive tapes (20d) may be manufactured from scratch or may be suitably selected from commercially available products.
  • It is to be noted that the "adhesion to ferrous or non-ferrous metals", as used herein, denotes the peel adhesion property on a clean and dry surface made of a ferrous or non-ferrous metal, which may include surfaces of metals and metal alloys, such as steel, for example. While not being limited thereto, in a preferred embodiment of the present invention, the wording "adhesion to ferrous or non-ferrous metals", as used herein, denotes the peel adhesion on BA steel determined according to EN 1939.
  • In preferred embodiments from the viewpoint of balancing roll cleaning efficiency and applicability, the first adhesive layer exhibits an adhesion to ferrous or non-ferrous metals in the range of from 10 to 600 cN/20mm, further preferably in the range of from 50 to 500 cN/20mm, especially preferably in the range of from 100 to 450 cN/20mm, and most preferably in the range of from 150 to 400 cN/20mm, at which particularly advantageous roll cleaning efficiencies are achieved.
  • Suitable formulations for manufacturing the first and second adhesive layers with the above-cited adhesion properties will be known to the skilled artisan and are not particularly limited.
  • For instance, exemplary adhesive formulations for the first adhesive layer may include acrylate-based, rubber-based, urethane-based, silicone-based adhesive formulations and combinations of two or more thereof, preferably at contents of 50 wt.-% to 100 wt.-%, more preferably at contents of 60 wt.-% to 98 wt.-% by weight, such as from 70 wt.-% to 95 wt.-%, or from 80 wt.-% to 93 wt.-%, for example, each based on the total weight of the first adhesive layer.
  • In a preferred embodiment, the first adhesive layer comprises an acrylic pressure-sensitive adhesive. The acrylic pressure-sensitive adhesive preferably comprises a (meth)acrylic polymer as the main component (e.g. at a content of 50% by weight or more of the acrylic pressure-sensitive adhesive). The (meth)acrylic polymer may be selected from a block copolymer, an alternating copolymer, and a graft copolymer, for example.
  • While not being limited thereto, the (meth)acrylic polymer may be prepared by polymerization of one or more C1-C18-alkyl (meth)acrylate monomers. As examples thereof, methyl (meth)acrylate, ethyl (meth)acrylate, n-butyl (meth)acrylate, s-butyl (meth)acrylate, t-butyl (meth)acrylate, isobutyl (meth)acrylate, 2-ethylhexyl (meth)acrylate, n-octyl (meth)acrylate, isooctyl (meth)acrylate, isodecyl (meth)acrylate, n-tridecyl (meth)acrylate, and n-tetradecyl (meth)acrylate may be mentioned. The (meth)acrylic polymer may also include other monomers copolymerizable with alkyl (meth)acrylate, e.g. for introducing a crosslinking site into the acrylic polymer or enhancing an aggregating ability of the acrylic polymer. The copolymerizable monomer component may be used solely or in combination of two or more thereof. In this regard, the ratio of the alkyl(meth)acrylate to the total amount of the monomer components constituting the acrylic polymer is desirably 50% by weight or more.
  • Exemplary urethane-based adhesive formulations include, but are not limited to polyisocyanate compounds (e.g. diphenylmethane diisocyanate, tolylene diisocyanate, hexamethylene diisocyanate) reacted with polyols (e.g. polyether polyols, polyester polyols, polycarbonate polyols, polycaprolactone polyols, etc.).
  • Exemplary rubber-based adhesive formulations include, but are not limited to natural rubbers or synthetic rubber-based adhesives (such as adhesives based on SBS, SBR, SEPS, SIS, SEBS, polyisobutylene, and/or butyl rubber, for example).
  • Methods for the preparation of polymer-based adhesives, including polymerization types (anionic, cationic or radical polymerization; solution, emulsification, mass, and suspension polymerization) and reaction conditions, are well-known in the art and may be appropriately selected by the skilled artisan depending on the used starting materials (i.e. monomers).
  • The first adhesive layer may comprise further additives, which may be appropriately selected by the skilled artisan from known materials, including but not limited to tackifiers (e.g. tackifying resins including one or more of rosin-based tackifying resins, terpene-based tackifying resins, hydrocarbon-based tackifying resins, epoxy-based tackifying resins, polyamide-based tackifying resins, elastomer-based tackifying resins, phenol-based tackifying resins, and/or ketone-based tackifying resins, for example), crosslinking agents (e.g. isocyanate-based crosslinking agents, epoxy-based crosslinking agents, oxazolidine-based crosslinking agents, aziridine-based crosslinking agents, melamine-based crosslinking agents, peroxide-based crosslinking agents, urea-based crosslinking agents, metal alkoxide-based crosslinking agents, metal chelate-based crosslinking agents, metal salt-based crosslinking agents, carbodiimide-based crosslinking agents, and/or amine-based crosslinking agents; preferably used at (total) contents of 0.1 to 20 wt.-% based on total weight of the adhesive layer), plasticizers, polymerization inhibitors, emulsifiers, pH buffering agents, foam inhibitors, stabilizers, anti-aging agents, UV-absorbers, antioxidants, anticorrosion-agents, light stabilizers, peeling regulators, softening agents, fillers, colorants (pigment, dye, etc.), surfactants, antistatic agents, and the like.
  • The adhesion of the second adhesive layer to ferrous or non-ferrous metals is not particularly limited as long as it is higher than that of the first adhesive layer. However, in order to more effectively prevent delamination of the double-sided adhesive during the cleaning operation, the adhesion to ferrous or non-ferrous metals of the first adhesive layer is preferably less than 30%, more preferably less than 25% of that of the second adhesive layer. As a lower limit, it may be preferred that the adhesion to ferrous or non-ferrous metals of the first adhesive layer is higher than 4%, more preferably higher than 6% of that of the second adhesive layer.
  • In preferred embodiments, the adhesion to ferrous or non-ferrous metals of the second adhesive layer is in the range of from 800 to 2100 cN/20mm, further preferably 1000 to 2000 cN/20mm, more preferably 1200 to 1800 cN/20 mm, most preferably 1400 to 1650 cN/20mm. Working within these ranges effectively prevents delamination, while still allowing the double-sided tape to be easily removed after the cleaning process, thereby enabling the substrate to be reused for multiple roll cleaning operations.
  • As with the first adhesive layer, the material constituting the second adhesive layer is not particularly limited and may be suitably selected depending on its adhesion properties on ferrous or non-ferrous metals.
  • In a preferred embodiment, the second adhesive layer comprises an acrylic pressure-sensitive adhesive. Further preferably, the second adhesive layer comprises a (meth)acrylic polymer as the main component (e.g. at a content of 50% by weight or more of the acrylic pressure-sensitive adhesive) according to the above description of the first adhesive layer. Especially preferably, the acrylic pressure-sensitive adhesive used in the second adhesive layer is prepared by polymerizing a monomer composition comprising primarily an alkyl (meth)acrylate (e.g. a C1-C18-alkyl (meth)acrylate) and one or more modifying monomer(s) copolymerizable with the alkyl (meth)acrylate. As examples of such modifying monomers, hydroxyl group-containing monomers (including hydroxyethyl (meth)acrylate, 2-hydroxypropyl (meth)acrylate, 4-hydroxybutyl (meth)acrylate, 6-hydroxyhexyl (meth)acrylate, 8-hydroxyoctyl (meth)acrylate, 12-hydroxylauryl (meth)acrylate, N-methylol(meth)acrylamide, vinyl alcohol, allyl alcohol, 2-hydroxyethyl vinyl ether, 4-hydroxybutyl vinyl ether, diethyleneglycol monovinyl ether, for example), carboxyl group-containing monomers ((meth)acrylic acid, carboxyl ethyl (meth)acrylate, itaconic acid, maleic acid, fumaric acid, etc.), styrene-based monomers (such as styrene or styrene derivatives comprising alkyl, halogen, or haloalkyl groups, for example), cyano group-containing monomers (e. g. acrylonitrile), epoxy group-containing monomers (e.g. glycidyl (meth)acrylate), amide group-containing monomers (e.g. (meth)acrylamide), imide group-containing monomers (e.g. N-cyclohexyl maleimide), vinyl ethers and vinyl esters (e.g. vinyl propionate) may be mentioned.
  • The carrier layer (24) is composed of materials that may be suitably selected by the skilled artisan, including polymers, metals, nonwoven fabrics, paper and combinations thereof, for example. Preferably, the carrier layer comprises a polymer, such as a polyester (e.g. polyethylene terephthalate (PET), polybutylene terephthalate, polyethylene naphthalate etc.), polyamide (aliphatic or aromatic polyamides, for example) and/or polyolefin (polyethylene, polypropylene, polybutylene, etc.). In terms of processability, a carrier layer comprising a polyester-based material is particularly preferred, as it allows easy lamination and use of rolls of double-sided adhesive tapes, as opposed to being limited to the application of sheets.
  • The carrier layer may further contain additives, such as antioxidants, UV-absorbing agents, antistatic agents, light stabilizers, fillers, colorants etc.. Also, the carrier layer may be composed of a single layer or of multiple layers having different compositions.
  • The thickness of the carrier layer may be suitably selected by the skilled artisan. Preferable thicknesses range from 1 µm to 1000 µm. Particularly preferred is a carrier layer thickness of from 50 µm to 250 µm, which enables easy die-cutting of the resulting cleaning sheet and renders it stable towards film burrs.
  • The optional release liner may be suitably selected from materials known in the art. Examples thereof include, but are not limited to siliconized paper, PE-coated paper, siliconized PE-coated paper, PET, PP, etc. As is understood, the double-adhesive tape used in the present invention may be provided with a release liner on both the first and the second adhesive layers. In case two release liners are used, they may be identical or different.
  • In general, the leveler cleaning sheet may be prepared on-site, by adhering the double-sided adhesive tape on the chosen substrate (in which case a release liner has preferably been also provided on the first adhesive layer, which may facilitate the handling for the operation personnel) or before delivery to the customer for easier application.
  • In an especially preferred embodiment, the method of the second embodiment further comprises the step of winding the cleaning sheet into a roll form, wherein the substrate contacts the first adhesive layer, and the substrate is preferably on the outside surface of the roll. Such a configuration significantly facilitates the handling and the cleaning operation for the operating personnel, and further enables the insertion using a coil car, similarly to the process shown in Fig, 1. Also, no release liner on the first adhesive layer is necessary, so that the manufacturing costs may be further reduced. In further preferred embodiments, the roll is provided with perforations in parallel to the roll axis. In addition, the cleaning sheet may comprise a release liner having larger dimensions than the double-sided adhesive tape. For instance, the width of release liner may extend beyond the surface of the double-sided adhesive tape on at least one side thereof (for example, at one or both edges in width direction if wound on a roll, by selecting a higher release liner width relative to the width double-sided adhesive tape).
  • An exemplary manual application of such a cleaning sheet roll is illustrated in Figures 4A to 4H, including the steps of unrolling (an optionally pre-perforated) roll (Figs. 4A and 4B), tearing off (if perforated) or cutting the roll (Figs. 4C and 4D), manually applying the thus obtained sheet onto the roll material surface (Fig. 4E), optionally with a scraping tool (Fig. 4F), and removing the top release liner from the sheet (Figs. 4G and 4H), which may be further facilitated by providing the cleaning sheet with dry-edges at the side of the sheet (e.g. by dimensioning the top release liner larger than the double-sided adhesive tape).
  • The total thickness of the double-sided adhesive tape without the optional release liner(s) is preferably in a range of from 1 µm to 5 mm, further preferably in a range of from 5 µm to 500 µm, as may be determined according to EN 1942, for example.
  • In preferred embodiments, the double-sided pressure-sensitive adhesive tape exhibits a static shear of 10 mm/3h or less, more preferably of 5 mm/3h or less, further preferably of 2 mm/3h or less, which may be determined according to EN 1943.
  • It will be understood that the double-sided adhesive tape may comprise further layers between the first and second adhesive layers beside of the carrier layer. For example, the double-sided adhesive tape may comprise one or more adhesive layers and/or carrier-type layers between the carrier layer and one of the first and second adhesive layers. However, a three layer-configuration consisting of a first adhesive layer, a second adhesive layer and a carrier layer between and in contact with the first and the second adhesive layers (as well as one or two optional release liner(s) on the surface(s) of the adhesive layer(s)) is preferable.
  • The substrate comprised in any of the above-described cleaning sheets may be suitably selected by the skilled artisan depending on the desired properties of the cleaning sheets and may be composed of a single layer or multiple layers with different compositions. It is important to note that the material constituting the substrate of the leveler cleaning sheet is not particularly limited as long as it is able to withstand the mechanical forces exerted by the leveler. For instance, the substrate may differ from the strip material for which the leveling process has been set up. As exemplary materials, metals (e.g. iron, copper, aluminum, zinc), alloys (e.g. hot rolled steel, cold rolled steel, stainless steel), polymers and combinations thereof may be suitably selected by the skilled artisan depending on the desired properties of the cleaning sheets and may be composed of a single layer or multiple layers with different compositions. In preferred embodiments, the substrate may comprise a metal, an alloy, or a polymer. In a further preferred embodiment, the substrate material is selected from a material having a density of less than 3 kg/dm3, such as aluminum or polymer-based materials, for example, since such light-weight materials may be easily handled by a single operator as opposed to steel sheets, for example. Polymer-based materials, including, but not limited to polyamide or PTFE and derivatives thereof, are particularly preferred.
  • Accordingly, the method of the second embodiment enables facilitated and inexpensive production of a leveler cleaning sheet with excellent roll cleaning performance.
  • Leveler Cleaning Sheet
  • In a third embodiment, the present invention, in accordance with claim 10, relates to a leveler cleaning sheet. Specifically, the leveler cleaning sheet comprises: a first adhesive layer, a second adhesive layer, a carrier layer between the first and the second adhesive layers, and a substrate in contact with the second adhesive layer to a substrate to provide the leveler cleaning sheet, wherein the first adhesive layer exhibits an adhesion to ferrous or non-ferrous metals in the range of from 50 cN/20mm to 600 cN/20mm, and wherein the adhesion to ferrous or non-ferrous metals of the second adhesive layer is higher than that of the first adhesive layer. An exemplary configuration is shown in Fig. 3C.
  • In a specifically preferred embodiment, the cleaning sheet is wound into a roll and further preferably comprises perforations in parallel to the roll axis. which significantly facilitates the handling of the cleaning sheet and the roll cleaning procedure so as to be executable by a single person (see Figs. 4A to 4H), and also allows for installation in a coil car in the feed section of leveler machines. Such a configuration represents a major improvement over conventional adhesive-based cleaning sheets which typically employ stiff materials not suitable for roll winding. Independently or in combination therewith, a release liner having larger dimensions than the double-sided adhesive tape may be provided. For example, the width of release liner may extend beyond the surface of the double-sided adhesive tape on one or both sides of the wound roll (e.g. by selecting a higher release liner width relative to the width double-sided adhesive tape, or by providing the release liner with flap portion extending beyond the surface of the double-sided adhesive tape, for example), which enables the operator to quickly remove the release liner from the adhesive surface without contacting the adhesive portion, thereby preventing lift-up and formation of wrinkles at the edges of the cleaning sheet.
  • Other preferred properties and compositions of the layers constituting the leveler cleaning sheet according to the third embodiment of the present invention are further described in conjunction with the second embodiment above.
  • Overall, it will be appreciated that the preferred features of the first and second embodiments specified above may be combined in any combination, except for combinations where at least some of the features are mutually exclusive.
  • EXAMPLES Example 1
  • In an initial test, a leveler cleaning sheet with a configuration according to Fig. 3C was prepared by manually laminating multiple double-sided adhesive tapes (Nitto Double Coated Tape 61390; tape thickness without liner: 0.090 mm; adhesion to non-ferrous and ferrous metal surfaces: 1500 cN/20mm (open side), 350 cN/20mm (closed side); carrier: 0.012 mm transparent polyester) at the open sides onto a cleaned metallic substrate sheet (width: 1524 mm).
  • The thus obtained leveler cleaning sheet was passed through a tension leveler machine having a working roll (width: 1600 mm) contaminated with metal, dust and other dirt particles due to the metal sheet leveling under typical conditions, at a line speed of approximately 1 m/min.
  • Upon exiting the leveler, the cleaning sheet was visually inspected (see Fig. 3). The photograph in Fig. 5 shows that nearly all dirt particles on the working roll effectively adhered to the layer of the leveler cleaning sheet corresponding to the first adhesive layer within one or a few revolution(s) of the working roll. As is indicated by the dashed line, the cleaning efficiency may be easily judged based on the visual appearance of the cleaning sheet.
  • Example 2
  • The cleaning test according to Example 1 was repeated, with the exception that A3-shaped Nitto Double Coated Tape 61390 was manually applied onto the substrate in the arrangement shown in Fig. 6A. The visual appearance of the cleaning sheet exiting the leveler machine is depicted in Fig. 6B. As is shown in Fig. 6B, major dirt particles effectively adhered to the layer of the leveler cleaning sheet corresponding to the first adhesive layer. In addition, the leveler was opened and the cleaning performance was evaluated based on the appearance of the working roll. Fig. 7 is a photograph of the opened leveler, which shows that the part of the working roll that contacted the cleaning sheet (right hand side) has been effectively cleaned when compared to the uncleaned area of the working roll (left hand side).
  • Accordingly, it is demonstrated that the method according to the present invention effectively and quickly cleans the contaminated rolls of a leveler machine, enables simple and cost-effective cleaning operation, and allows the leveler operator to easily assess the degree of contamination of the working rolls.
  • Once given the above disclosure, many other features, modifications, and improvements will become apparent to the skilled artisan. The scope of the invention is delimited by the appended claims.
  • REFERENCE NUMERALS
  • 1
    coil car
    2
    uncoiler
    3
    triple roll assembly
    4
    rewind shirr
    5
    trimmer
    6
    leveler
    7
    scrap winder
    8
    feeder
    9
    shirr machine
    10
    finished goods
    20a / 20b / 20c
    cleaning sheet
    20d
    double-sided adhesive tape
    21
    substrate
    22
    first adhesive layer
    23
    second adhesive layer
    24
    carrier layer
    25
    release liner

Claims (16)

  1. Use of a leveler cleaning sheet (20a; 20b; 20c) for cleaning one or more rolls of a leveler machine, comprising contacting the leveler cleaning sheet (20a; 20b; 20c) with at least a part of the curved surface of the one or more rolls to enable cleaning by rotation of the one or more rolls;
    wherein the leveler cleaning sheet (20a; 20b; 20c) comprises a substrate (21) and a first adhesive layer (22) provided over the substrate (21), and the surface of first adhesive layer (22) contacts at least a part of the curved surface of the one or more rolls; and
    wherein the first adhesive layer (22) exhibits an adhesion to ferrous or non-ferrous metals of higher than 10 cN/20mm.
  2. Use according to claim 1, wherein the leveler cleaning sheet (20a; 20b; 20c) comprises a second adhesive layer (23) between the substrate and the first adhesive layer (22) and in contact with the substrate (21), and a carrier layer (24) between the first and the second adhesive layers (22; 23); and wherein the adhesion to ferrous or non-ferrous metals of the second adhesive layer (23) is higher than that of the first adhesive layer (22).
  3. Use according to claim 2, further comprising the steps of:
    adhering a double-sided pressure-sensitive adhesive tape comprising a first adhesive layer (22), a second adhesive layer (23), a carrier layer (24) between the first and the second adhesive layers (22; 23), to a substrate (21) in order to provide the leveler cleaning sheet (20a; 20b; 20c).
  4. Use according to any of claims 2 or 3, wherein the adhesion to ferrous or non-ferrous metals of the first adhesive layer (22) is less than 25% of that of the second adhesive layer (23).
  5. Use according to any of claims 2 to 4, wherein the first adhesive layer (22) comprises an acrylic pressure-sensitive adhesive.
  6. Use according to any of claims 1 to 4, wherein the first adhesive layer (22) exhibits an adhesion to ferrous or non-ferrous metals in the range of from 100 to 450 cN/20mm, and the second adhesive layer (23), if present, exhibits an adhesion to ferrous or non-ferrous metals in the range of from 1000 to 2000 cN/20mm.
  7. Use according to any of claims 1 to 6, wherein the substrate (21) comprises a metal, an alloy, or a polymer.
  8. Method of manufacturing a leveler cleaning sheet (20a; 20b; 20c), comprising the steps of:
    providing a double-sided adhesive tape comprising a first adhesive layer (22), a second adhesive layer (23), a carrier layer (24) between the first and the second adhesive layers (22; 23), and an optional release liner (25) in contact with the first adhesive layer (22); and
    adhering the surface of the second adhesive layer (23) to a substrate to provide the leveler cleaning sheet (20a; 20b; 20c);
    wherein the first adhesive layer (22) exhibits an adhesion to ferrous or non-ferrous metals of higher than 10 cN/20mm, and
    wherein the adhesion to ferrous or non-ferrous metals of the second adhesive layer (23) is higher than that of the first adhesive layer (22).
  9. Method of manufacturing a leveler cleaning sheet (20a; 20b; 20c) according to claim 8, further comprising the step of winding the cleaning sheet (20a; 20b; 20c) into a roll, wherein the substrate is in contact with the first adhesive layer (22).
  10. Leveler cleaning sheet (20a; 20b; 20c), comprising:
    a double-sided adhesive tape comprising a first adhesive layer (22), a second adhesive layer (23), a carrier layer (24) between the first and the second adhesive layers (22; 23), and an optional release liner (25) in contact with the first adhesive layer (22);
    wherein the surface of the second adhesive layer (23) is adhered to a substrate (21);
    wherein the first adhesive layer (22) exhibits an adhesion to ferrous or non-ferrous metals in the range of from 50 cN/20mm to 600 cN/20 mm, and
    wherein the adhesion to ferrous or non-ferrous metals of the second adhesive layer (23) is higher than that of the first adhesive layer (22).
  11. Leveler cleaning sheet (20a; 20b; 20c) according to claim 10, wherein the cleaning sheet (20a; 20b; 20c) is wound into a roll and optionally comprises perforations in parallel to the roll axis.
  12. Leveler cleaning sheet (20a; 20b; 20c) according to claims 10 or 11, wherein the cleaning sheet (20a; 20b; 20c) comprises a release liner (25) having larger dimensions that the double-sided adhesive tape.
  13. Leveler cleaning sheet (20a; 20b; 20c) according to any of claims 10 to 12, wherein the first adhesive layer (22) exhibits an adhesion to ferrous or non-ferrous metals in the range of from 100 to 450 cN/20mm, and the second adhesive layer (23) exhibits an adhesion to ferrous or non-ferrous metals in the range of from 1000 to 2000 cN/20mm.
  14. Leveler cleaning sheet (20a; 20b; 20c) according to any of claims 10 to 13, wherein the first adhesive layer (22) comprises an acrylic pressure-sensitive adhesive.
  15. Leveler cleaning sheet (20a; 20b; 20c) according to any of claims 10 to 14, wherein the substrate (21) comprises a metal, an alloy, or a polymer.
  16. Leveler cleaning sheet (20a; 20b; 20c) according to any of claims 10 to 15, wherein the substrate (21) comprises a polymer.
EP18167519.0A 2018-04-16 2018-04-16 Leveler cleaning sheets and related methods Active EP3556480B1 (en)

Priority Applications (2)

Application Number Priority Date Filing Date Title
EP18167519.0A EP3556480B1 (en) 2018-04-16 2018-04-16 Leveler cleaning sheets and related methods
PCT/EP2019/059832 WO2019201942A1 (en) 2018-04-16 2019-04-16 Leveler cleaning sheets and related methods

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
EP18167519.0A EP3556480B1 (en) 2018-04-16 2018-04-16 Leveler cleaning sheets and related methods

Publications (2)

Publication Number Publication Date
EP3556480A1 EP3556480A1 (en) 2019-10-23
EP3556480B1 true EP3556480B1 (en) 2023-05-31

Family

ID=62067347

Family Applications (1)

Application Number Title Priority Date Filing Date
EP18167519.0A Active EP3556480B1 (en) 2018-04-16 2018-04-16 Leveler cleaning sheets and related methods

Country Status (2)

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EP (1) EP3556480B1 (en)
WO (1) WO2019201942A1 (en)

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111438228B (en) * 2020-05-12 2021-10-26 徐子敏 Working method of leveling and correcting device for steel coil winding

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH03165902A (en) * 1989-11-24 1991-07-17 Kawasaki Steel Corp Method for removing dust which is stuck on carrier roll
US5255549A (en) * 1992-06-10 1993-10-26 The Monarch Machine Tool Company Tension leveler roll cleaning system and method
WO2007049462A1 (en) * 2005-10-25 2007-05-03 Nitto Denko Corporation Cleaning sheet, transfer member provided with cleaning function, and method for cleaning substrate processing apparatus
US7637132B2 (en) 2006-02-06 2009-12-29 Butech Bliss Work roll scraper for roller levelers
JP5148413B2 (en) * 2008-08-29 2013-02-20 日東電工株式会社 Panel with cleaning function and substrate processing apparatus cleaning method using the same
GB2532255B (en) * 2014-11-13 2020-04-29 Itw Ltd Line cleaner

Also Published As

Publication number Publication date
EP3556480A1 (en) 2019-10-23
WO2019201942A1 (en) 2019-10-24

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