EP3542037A1 - Verfahren zum betreiben eines abgasnachbehandlungssystems einer brennkraftmaschine, abgasnachbehandlungssystem für eine brennkraftmaschine und brennkraftmaschine mit einem solchen abgasnachbehandlungssystem - Google Patents
Verfahren zum betreiben eines abgasnachbehandlungssystems einer brennkraftmaschine, abgasnachbehandlungssystem für eine brennkraftmaschine und brennkraftmaschine mit einem solchen abgasnachbehandlungssystemInfo
- Publication number
- EP3542037A1 EP3542037A1 EP17808767.2A EP17808767A EP3542037A1 EP 3542037 A1 EP3542037 A1 EP 3542037A1 EP 17808767 A EP17808767 A EP 17808767A EP 3542037 A1 EP3542037 A1 EP 3542037A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- scr catalyst
- catalyst material
- exhaust gas
- exhaust
- internal combustion
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
Classifications
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
- F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL-COMBUSTION ENGINES
- F01N3/00—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust
- F01N3/08—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous
- F01N3/10—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust
- F01N3/18—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust characterised by methods of operation; Control
- F01N3/20—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust characterised by methods of operation; Control specially adapted for catalytic conversion
- F01N3/206—Adding periodically or continuously substances to exhaust gases for promoting purification, e.g. catalytic material in liquid form, NOx reducing agents
- F01N3/2066—Selective catalytic reduction [SCR]
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
- F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL-COMBUSTION ENGINES
- F01N11/00—Monitoring or diagnostic devices for exhaust-gas treatment apparatus
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
- F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL-COMBUSTION ENGINES
- F01N11/00—Monitoring or diagnostic devices for exhaust-gas treatment apparatus
- F01N11/002—Monitoring or diagnostic devices for exhaust-gas treatment apparatus the diagnostic devices measuring or estimating temperature or pressure in, or downstream of the exhaust apparatus
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
- F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL-COMBUSTION ENGINES
- F01N3/00—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust
- F01N3/08—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous
- F01N3/10—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust
- F01N3/18—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust characterised by methods of operation; Control
- F01N3/20—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust characterised by methods of operation; Control specially adapted for catalytic conversion
- F01N3/206—Adding periodically or continuously substances to exhaust gases for promoting purification, e.g. catalytic material in liquid form, NOx reducing agents
- F01N3/208—Control of selective catalytic reduction [SCR], e.g. by adjusting the dosing of reducing agent
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
- F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL-COMBUSTION ENGINES
- F01N9/00—Electrical control of exhaust gas treating apparatus
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
- F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL-COMBUSTION ENGINES
- F01N9/00—Electrical control of exhaust gas treating apparatus
- F01N9/005—Electrical control of exhaust gas treating apparatus using models instead of sensors to determine operating characteristics of exhaust systems, e.g. calculating catalyst temperature instead of measuring it directly
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F02—COMBUSTION ENGINES; HOT-GAS OR COMBUSTION-PRODUCT ENGINE PLANTS
- F02B—INTERNAL-COMBUSTION PISTON ENGINES; COMBUSTION ENGINES IN GENERAL
- F02B37/00—Engines characterised by provision of pumps driven at least for part of the time by exhaust
- F02B37/12—Control of the pumps
- F02B37/16—Control of the pumps by bypassing charging air
- F02B37/162—Control of the pumps by bypassing charging air by bypassing, e.g. partially, intake air from pump inlet to pump outlet
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F02—COMBUSTION ENGINES; HOT-GAS OR COMBUSTION-PRODUCT ENGINE PLANTS
- F02B—INTERNAL-COMBUSTION PISTON ENGINES; COMBUSTION ENGINES IN GENERAL
- F02B37/00—Engines characterised by provision of pumps driven at least for part of the time by exhaust
- F02B37/12—Control of the pumps
- F02B37/18—Control of the pumps by bypassing exhaust from the inlet to the outlet of turbine or to the atmosphere
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
- F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL-COMBUSTION ENGINES
- F01N2510/00—Surface coverings
- F01N2510/06—Surface coverings for exhaust purification, e.g. catalytic reaction
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
- F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL-COMBUSTION ENGINES
- F01N2550/00—Monitoring or diagnosing the deterioration of exhaust systems
- F01N2550/02—Catalytic activity of catalytic converters
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
- F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL-COMBUSTION ENGINES
- F01N2560/00—Exhaust systems with means for detecting or measuring exhaust gas components or characteristics
- F01N2560/02—Exhaust systems with means for detecting or measuring exhaust gas components or characteristics the means being an exhaust gas sensor
- F01N2560/021—Exhaust systems with means for detecting or measuring exhaust gas components or characteristics the means being an exhaust gas sensor for measuring or detecting ammonia NH3
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
- F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL-COMBUSTION ENGINES
- F01N2560/00—Exhaust systems with means for detecting or measuring exhaust gas components or characteristics
- F01N2560/02—Exhaust systems with means for detecting or measuring exhaust gas components or characteristics the means being an exhaust gas sensor
- F01N2560/026—Exhaust systems with means for detecting or measuring exhaust gas components or characteristics the means being an exhaust gas sensor for measuring or detecting NOx
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
- F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL-COMBUSTION ENGINES
- F01N2560/00—Exhaust systems with means for detecting or measuring exhaust gas components or characteristics
- F01N2560/06—Exhaust systems with means for detecting or measuring exhaust gas components or characteristics the means being a temperature sensor
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
- F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL-COMBUSTION ENGINES
- F01N2590/00—Exhaust or silencing apparatus adapted to particular use, e.g. for military applications, airplanes, submarines
- F01N2590/08—Exhaust or silencing apparatus adapted to particular use, e.g. for military applications, airplanes, submarines for heavy duty applications, e.g. trucks, buses, tractors, locomotives
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
- F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL-COMBUSTION ENGINES
- F01N2610/00—Adding substances to exhaust gases
- F01N2610/02—Adding substances to exhaust gases the substance being ammonia or urea
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
- F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL-COMBUSTION ENGINES
- F01N2610/00—Adding substances to exhaust gases
- F01N2610/14—Arrangements for the supply of substances, e.g. conduits
- F01N2610/1453—Sprayers or atomisers; Arrangement thereof in the exhaust apparatus
- F01N2610/146—Control thereof, e.g. control of injectors or injection valves
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
- F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL-COMBUSTION ENGINES
- F01N2900/00—Details of electrical control or of the monitoring of the exhaust gas treating apparatus
- F01N2900/04—Methods of control or diagnosing
- F01N2900/0416—Methods of control or diagnosing using the state of a sensor, e.g. of an exhaust gas sensor
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
- F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL-COMBUSTION ENGINES
- F01N2900/00—Details of electrical control or of the monitoring of the exhaust gas treating apparatus
- F01N2900/04—Methods of control or diagnosing
- F01N2900/0418—Methods of control or diagnosing using integration or an accumulated value within an elapsed period
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
- F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL-COMBUSTION ENGINES
- F01N2900/00—Details of electrical control or of the monitoring of the exhaust gas treating apparatus
- F01N2900/06—Parameters used for exhaust control or diagnosing
- F01N2900/14—Parameters used for exhaust control or diagnosing said parameters being related to the exhaust gas
- F01N2900/1402—Exhaust gas composition
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
- F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL-COMBUSTION ENGINES
- F01N2900/00—Details of electrical control or of the monitoring of the exhaust gas treating apparatus
- F01N2900/06—Parameters used for exhaust control or diagnosing
- F01N2900/14—Parameters used for exhaust control or diagnosing said parameters being related to the exhaust gas
- F01N2900/1404—Exhaust gas temperature
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02T—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO TRANSPORTATION
- Y02T10/00—Road transport of goods or passengers
- Y02T10/10—Internal combustion engine [ICE] based vehicles
- Y02T10/12—Improving ICE efficiencies
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02T—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO TRANSPORTATION
- Y02T10/00—Road transport of goods or passengers
- Y02T10/10—Internal combustion engine [ICE] based vehicles
- Y02T10/40—Engine management systems
Definitions
- the invention relates to a method for operating an exhaust aftertreatment system of an internal combustion engine, an exhaust aftertreatment system for an internal combustion engine and an internal combustion engine with such an exhaust aftertreatment system.
- the invention is based on the object, a method for operating a
- Exhaust after-treatment system of an internal combustion engine an exhaust aftertreatment system for a Brenril aftmaschine and an internal combustion engine with such
- the object is achieved in particular by a method for operating a
- Exhaust after-treatment system of an internal combustion engine in which during operation of the exhaust aftertreatment system at least one operating parameter is detected, in connection with an oxidation state of an SCR catalyst material of the Exhaust after-treatment system is, wherein depending on the at least one operating parameter at least one reoxidation measure for reoxidation of the SCR catalyst material is initiated.
- at least one operating parameter is detected, in connection with an oxidation state of an SCR catalyst material of the Exhaust after-treatment system is, wherein depending on the at least one operating parameter at least one reoxidation measure for reoxidation of the SCR catalyst material is initiated.
- Reoxidation measure can be initiated depending on the at least one operating parameter at least one measure that prevents a progressive or further reduction of the catalyst material.
- a reduction of the nitrogen oxide conversion rate on the SCR catalyst material can now be counteracted in an advantageous manner if an oxidation state of the SCR catalyst material is monitored by means of the at least one operating parameter, wherein at least one reoxidation measure for reoxidation of the SCR catalyst material is initiated as a function of this operating parameter and / or at least one further reduction of the SCR catalyst material is prevented.
- the catalyst material can preferably be actively regenerated and its conversion rate can be increased again, or the trend towards a lower conversion rate can at least be stopped. This in turn allows the use of smaller, less expensive and space-saving SCR catalysts and / or a vote with the one
- Exhaust after-treatment system used internal combustion engine towards higher nitrogen oxide emissions and thus at the same time to a higher efficiency.
- Limit values applicable to nitrogen oxide emissions can nevertheless be met due to the increased or at least not further decreasing conversion rate of the SCR catalyst material.
- the increased efficiency of the internal combustion engine again has a fuel-saving effect.
- the at least one reoxidation measure and / or the at least one measure for preventing further reduction is initiated, in particular, if the at least one operating parameter indicates an oxidation state of the SCR catalyst material which reduces a-preferably, in a predetermined manner-reduced, conversion of nitrogen oxides at the SCR catalyst. Catalyst material has the consequence.
- the SCR catalyst material can be reoxidized as needed and thus regenerated.
- such a measure can first be requested only by initiating it and only then carried out if operational and / or motor boundary conditions favor the success of the measure. Under an initiation of a measure can therefore be understood that this is started immediately, or that the measure is requested and started with a delay or a time offset to their request.
- Oxidation state of a surface of the SCR catalyst material understood. It turns out that common SCR catalyst materials are typically present in an oxidized state, for example vanadium pentoxide, wherein oxygen atoms arranged on the surface of the SCR catalyst material contribute to the catalysis of the reduction of nitrogen oxides. As the SCR catalyst material is reduced, such oxygen atoms are removed, decreasing the catalytic efficiency of the SCR catalyst material.
- common SCR catalyst materials are typically present in an oxidized state, for example vanadium pentoxide, wherein oxygen atoms arranged on the surface of the SCR catalyst material contribute to the catalysis of the reduction of nitrogen oxides. As the SCR catalyst material is reduced, such oxygen atoms are removed, decreasing the catalytic efficiency of the SCR catalyst material.
- an exhaust gas temperature - in particular upstream of the SCR catalyst material, preferably immediately upstream of the same, or on the SCR catalyst material - is detected.
- an operating time preferably measured since a last reoxidation measure or since a start of the internal combustion engine - is detected as the at least one operating parameter. It is also possible that an operating time of the internal combustion engine is detected in a specific operating state or in a specific map range.
- Reoxidation measure can be done so far in particular temperature and / or time-controlled. It shows that a reduction of the SCR catalyst material, especially at high Exhaust gas temperatures and / or longer operating times, especially at high load points, especially at full load occurs.
- the exhaust gas temperature operating time integral to be detected as the at least one operating parameter. In that sense it comes for one
- Operating time and the exhaust temperature together define an operating history, which determines the overall oxidation state.
- a temporally integrally reacted nitrogen oxide freight that is, a total amount of nitrogen oxide supplied to the SCR catalyst material over an integration time and reacted thereon, or an integrally metered amount of reducing agent, the is called one over one
- the at least one operating parameter is a
- the nitrogen oxide concentration and / or the reducing agent concentration is / are particularly preferably detected immediately downstream of the SCR catalyst material.
- the reducing agent used is preferably ammonia, so that in particular an ammonia concentration is detected, preferably immediately downstream of the SCR catalyst material.
- Nitrogen concentration and the ammonia concentration are indicators of an oxidation state of the SCR catalyst material, in particular because a high
- Nitrogen concentration on the one hand - as well as a high reducing agent concentration - can promote a reduction of the catalyst material as a competing reaction to the reduction of nitrogen oxides, with a high nitrogen oxide concentration also speaks for a reduced nitrogen oxide conversion rate of the SCR catalyst material.
- a total nitrogen oxide concentration of nitrogen monoxide and nitrogen dioxide is determined with a nitrogen oxide sensor upstream of the SCR catalyst material, wherein a
- Reducing agent concentration in particular an ammonia concentration downstream of the SCR catalyst material with a reducing agent sensor, in particular a
- Ammonia sensor is determined. According to one embodiment of the invention, it is provided that the at least one operating parameter is compared with a predetermined threshold value, wherein the at least one reoxidation measure and / or the at least one measure for
- Operating parameter reaches or exceeds the predetermined threshold.
- the threshold may be an exhaust temperature threshold, an operating time threshold, an exhaust gas temperature operating time integral threshold, a threshold for integral nitrogen oxide load, a threshold for integral reductant level, a nitric oxide concentration threshold, and / or a reductant concentration threshold.
- “Exceeding” is used here in a general sense to exceed the predetermined threshold, depending on the definition of the operating parameter on the one hand, and the threshold on the other hand, exceeding or exceeding the predetermined threshold by the operating parameter Reduction of the SCR catalyst material, so that in this case the initiation of a measure to prevent further reduction and / or the implementation of a Reoxidationscooptes is useful.
- a value of 400 ° C. can be used as threshold value for the exhaust gas temperature.
- at least one hour to at most 10 hours, preferably 4 hours, can be used as the operating time threshold.
- the at least one measure for preventing further reduction and / or the at least one reoxidation measure is initiated when the at least one operating parameter reaches or exceeds the predetermined threshold value for a predetermined period of time. This may take into account the aspect that the reduction of the SCR catalyst material progresses particularly unfavorably when the threshold is reached or exceeded for a longer time.
- Threshold not reached or exceeded It is possible that from one predetermined pause length, the detected time is reset and re-detected in a subsequent renewed exceeding or reaching the predetermined threshold by the at least one operating parameter. This takes into account the fact that in the breaks a regeneration of the SCR catalyst material without active reoxidation measure is possible.
- the oxidation state and / or a nitrogen oxide conversion value of the SCR catalyst material is / are calculated by means of a catalyst reaction model.
- the catalyst reaction model is supplied with the at least one operating parameter as an input variable.
- the at least one measure for preventing further reduction and / or the at least one reoxidation measure is initiated depending on the oxidation state determined by the catalyst reaction model and / or the nitrogen oxide conversion value determined by the catalyst reaction model.
- a nitrogen oxide conversion value is in particular an absolute nitrogen oxide conversion, in particular an absolute nitrogen oxide conversion rate, or alternatively a reduction of a
- Catalyst reaction models are basically known, for example from the following references:
- Oxidation state of the SCR catalyst material include extended. A model resulting in this way can then be deduced from the operating history of the
- a model-based control strategy for controlling to a specific catalyst age is described.
- a control strategy can be created for the oxidation state of the SCR catalyst material, this being independent of the catalyst age.
- Reoxidation measure a reducing agent metering in an exhaust path of the
- Exhaust aftertreatment system upstream of the SCR catalyst material - preferably temporarily limited - is reduced. This may be done, for example, for a time required to achieve a thermally steady state of the SCR catalyst material throughout the catalyst.
- the reduction of the reducing agent metering can be carried out, for example, for at least one minute to at most 60 minutes, preferably for 15 minutes.
- This measure may, for example, be combined with an operating time threshold such that the reduction of the reducing agent dosage is carried out for approximately 15 minutes, if previously a continuous steady-state operation above a certain one
- Exhaust gas temperature threshold for particular at least one hour to a maximum of 10 hours, preferably for 4 hours, is determined.
- the at least one measure for preventing further reduction and / or the at least one reoxidation measure is preferably one Oxygen concentration in the exhaust gas raised upstream of the SCR catalyst material. By a higher oxygen content in the exhaust gas, the reoxidation of the SCR catalyst material can be promoted.
- the exhaust gas temperature upstream of the SCR catalyst material is preferably lowered. A lower temperature in the exhaust gas, the reoxidation of the SCR catalyst material can be promoted.
- the at least one measure for preventing further reduction and / or as the at least one reoxidation measure is preferably one
- Nitrogen oxide concentration in the exhaust gas upstream of the SCR catalyst material is reduced. This measure has the effect, in particular, that a
- Reducing agent metering control reduces the dosage of the reducing agent when less nitrogen oxide is present in the exhaust gas upstream of the SCR catalyst material. Furthermore, a reduction in the nitrogen monoxide concentration in the region of the SCR catalyst material leads to a suppression of the oxidation of nitrogen monoxide
- Nitrogen dioxide as a competing reaction for the reoxidation of the SCR catalyst material.
- the nitrogen oxide concentration in the exhaust gas can also flankierend to the reduction of
- Reductant metering be performed to meet predetermined nitrogen oxide limits for the nitrogen oxide emission even at reduced reducing agent dosage.
- the oxygen concentration in the exhaust gas upstream of the SCR catalyst material is increased and / or the exhaust gas temperature is lowered by changing a setting position of a turbine bypass path adjusting device for a bypass path of an exhaust gas turbocharger upstream of the SCR catalyst material.
- a turbine bypass path adjusting device may preferably be designed as a so-called wastegate, and comprise a valve device or an exhaust gas flap. If the turbine bypass path adjusting device is closed further or completely, more exhaust gas is conducted via the exhaust gas turbocharger turbine, so that at the same time the power of an exhaust gas turbocharger active with the exhaust gas turbocharger turbine Increased compressor and more combustion air is promoted in a combustion chamber of the internal combustion engine. This results in a higher combustion air-fuel ratio in the
- Bypass path of an exhaust gas turbocharger compressor which is preferably arranged in the charging path of an exhaust aftertreatment system having the engine is changed.
- the compressor bypass path adjusting device in particular for a
- Charge air intake can be opened so that the compressor is blown around.
- the efficiency of the exhaust gas turbocharger can be increased in certain operating ranges, especially if otherwise a compressor pumps would occur.
- the beneficial effect on the combustion air-fuel ratio by the increased efficiency exceeds the negative effect of the compressor-Umblasung.
- the exhaust gas temperature can be lowered at the same time and the nitrogen oxide concentration in the exhaust gas can be reduced.
- the nitrogen oxide concentration in the exhaust gas upstream of the SCR catalyst material is reduced by a
- Exhaust aftertreatment system associated internal combustion engine is increased. As a result, in particular, the combustion chamber temperature can be lowered, and the nitrogen oxide emission can be reduced.
- the nitrogen oxide concentration in the exhaust gas upstream of the SCR catalyst material is reduced by a
- Combustion center in the combustion chamber of the exhaust aftertreatment system associated internal combustion engine is changed. This can be done in particular via a
- Shifting of an ignition timing can be effected.
- Combustion focus position is / are in particular shifted so that the nitrogen oxide emissions are reduced, for example by adjusting the ignition timing to late.
- the object is also solved by an exhaust aftertreatment system for a
- Internal combustion engine which has an exhaust path, wherein in the
- the exhaust aftertreatment system further includes a reductant dosing device configured to operate
- the reducing agent may in particular be ammonia or an ammonia precursor product, in particular a urea-water solution.
- Exhaust gas aftertreatment system further comprises at least one detection device, which is configured to detect at least one operating parameter that is related to an oxidation state of an SCR catalyst material of the SCR catalytic converter.
- the exhaust gas aftertreatment system has a control device which is set up to at least one measure for the at least one operating parameter depending on the at least one operating parameter
- the at least one detection device may in particular be an exhaust-gas temperature sensor, an operating-time detection means, an exhaust-gas temperature operating-time integral-detection means, a nitrogen oxide sensor and / or a reducing-agent sensor, in particular an ammonia sensor.
- the exhaust-gas aftertreatment system it is possible for the exhaust-gas aftertreatment system to have a nitrogen oxide sensor and / or an exhaust-gas temperature sensor upstream of the SCR catalytic converter.
- the exhaust gas aftertreatment system downstream of the SCR catalytic converter to have a reducing agent sensor, in particular an ammonia sensor, and / or a nitrogen oxide sensor, and / or a temperature sensor.
- At least one predetermined threshold value is preferably stored in the control device with which the at least one operating parameter is compared in order to be dependent on the comparison to initiate at least one measure to prevent further reduction and / or the at least one Reoxidationsmotherookie.
- a catalyst reaction model is deposited in the control device, to which the at least one operating parameter can be supplied as an input variable, wherein the at least one measure for preventing further reduction and / or the at least one reoxidation measure depends on an oxidation state determined by the catalyst reaction model and / or a nitrogen oxide conversion value determined by the catalyst reaction model.
- the control device is preferably with the reducing agent metering device
- control device is preferably set up to control a turbine bypass path setting device and / or a compressor bypass path setting device of an internal combustion engine having the exhaust gas aftertreatment system, wherein it is preferably operatively connected to at least one of these devices.
- the control device is additionally or alternatively preferably set up to a
- Embodiments has. In connection with the internal combustion engine, in particular, the advantages that already in connection with the method and with the
- the internal combustion engine preferably has an exhaust gas turbocharger with an exhaust gas turbocharger turbine in an exhaust path of the exhaust aftertreatment system - preferably upstream of the SCR catalyst - and an exhaust gas turbocharger compressor in a charging path of
- exhaust gas turbocharger turbine is preferably associated with a bypass path and a turbine bypass path adjusting device, wherein the
- Exhaust gas turbocharger compressors are preferably associated with a bypass path and a compressor bypass path adjusting device, wherein the control device of the
- Exhaust after-treatment system preferred with the turbine bypass path actuator and / or is operatively connected to the compressor bypass path control device for the control thereof.
- the internal combustion engine preferably has an exhaust gas recirculation device which is set up for recirculating exhaust gas into a combustion chamber of the internal combustion engine, wherein the
- Control device of the exhaust aftertreatment system preferably with the
- Exhaust gas recirculation device is operatively connected to set an exhaust gas recirculation rate.
- control device is preferably set up to a
- control device of the exhaust aftertreatment system is a control unit of the internal combustion engine, in particular an engine control unit of the same, or that the
- control device of the exhaust aftertreatment system in the control unit in particular the engine control unit, the internal combustion engine is integrated. But it is also possible that the exhaust aftertreatment system is assigned a separate control device.
- the internal combustion engine is preferably designed as a reciprocating engine. It is possible that the internal combustion engine is arranged to drive a passenger car, a truck or a commercial vehicle. In a preferred embodiment, the internal combustion engine is the drive in particular heavy land or water vehicles, such as mine vehicles, trains, the internal combustion engine in a
- Locomotive or a railcar is used, or by ships. It is also possible to use the internal combustion engine to drive a defense vehicle, for example a tank.
- An exemplary embodiment of the internal combustion engine is preferably also stationary, for example, for stationary power supply in emergency operation,
- the internal combustion engine in this case preferably drives a generator. Also a stationary application of
- Internal combustion engine for driving auxiliary equipment such as fire pumps on oil rigs
- an application of the internal combustion engine in the field of promoting fossil raw materials and in particular fuels, for example oil and / or gas possible.
- the internal combustion engine is also possible to use the internal combustion engine in the industrial sector or in the field of construction, for example in a construction or construction machine, for example in a crane or an excavator.
- the internal combustion engine is preferably as Diesel engine, as a gasoline engine, as a gas engine for operation with natural gas, biogas, special gas or other suitable gas formed.
- the internal combustion engine is designed as a gas engine, it is suitable for use in a cogeneration plant for stationary power generation.
- the exhaust aftertreatment system is preferably configured to carry out a method according to one of the previously described embodiments.
- the internal combustion engine is preferably configured to carry out at least one of the previously described
- Figure 1 is a schematic representation of an embodiment of an internal combustion engine with an exhaust aftertreatment system
- Figure 2 is a schematic representation of an embodiment of a method for
- FIG. 1 shows a schematic representation of an exemplary embodiment of an internal combustion engine 1 with an exhaust gas aftertreatment system 3, which has an exhaust gas path 5, wherein in the exhaust gas path 5 an SCR catalytic converter 7 is arranged, which contains an SCR catalytic converter.
- Reductant metering device 9 which is adapted for metering a reducing agent, in particular ammonia or an ammonia precursor product, in particular a urea-water solution, in the exhaust path 5 upstream of the SCR catalyst 7.
- the exhaust aftertreatment system 3 also has at least one
- Detection device 11 here a plurality of detection devices 11, for detecting at least one operating parameter, in particular for detecting a plurality of operating parameters, wherein the at least one operating parameter is associated with an oxidation state of the SCR catalyst material of the SCR catalyst 7.
- the exhaust gas aftertreatment system 3 has a control device 13, which is set up, depending on the at least one operating parameter, at least one measure for preventing further reduction of the SCR catalyst material and / or initiate at least one reoxidation measure for the reoxidation of the SCR catalyst material.
- a reduction of a nitrogen oxide conversion rate of the SCR catalyst 7 due to a reduction of the SCR catalyst material can be avoided or reversed, in particular by regenerating the SCR catalyst material regularly or as needed by reoxidation.
- detection means 1 1 for detecting operating parameters are here in particular an exhaust gas temperature sensor 15 and a nitrogen oxide sensor 17 - both in the exhaust path 5 upstream of the SCR catalyst 7 - provided, as a further detection means 1 1, a reducing agent sensor 19, in particular an ammonia sensor in which exhaust path 5 is located downstream of the SCR catalyst 7.
- the control device 13 has
- an operation time detecting means so that an operating time of
- the control device 13 is in particular operatively connected to the reducing agent metering device 9 as well as to the various detection devices 11.
- the internal combustion engine 1 also has an exhaust gas turbocharger 21, which has a
- the exhaust gas turbocharger turbine 23 is arranged in the exhaust path 5 of the internal combustion engine 1, wherein the exhaust gas turbocharger compressor 25 in a charging path 27 of the
- Internal combustion engine 1 is arranged.
- the turbocharger turbine 23 is a turbine bypass path 29 having a
- Turbine bypass path adjusting device 31 assigned via the - depending on a
- Position of the turbine bypass path adjusting device 31, in particular as a wastegate may be formed - a certain proportion of exhaust gas can be passed around the exhaust gas turbocharger turbine 23 around.
- the exhaust gas turbocharger compressor 25 is a compressor bypass path 33 with a
- compressor bypass path control device 35 Associated with compressor bypass path control device 35, wherein along the charging path 27 flowing charge air depending on a parking position of the compressor bypass path adjusting device 35 on the exhaust gas turbocharger compressor 25 over, and in particular from a high pressure side of the exhaust gas turbocharger compressor 25 can be returned to a low pressure side thereof, which also as Charge air extraction or blowing of the
- Exhaust gas turbocharger compressor 25 is designated.
- a proportion of the charge air removed or blown is adjustable by changing the setting position of the turbine bypass path adjusting device 35.
- the internal combustion engine 1 also has an exhaust gas recirculation device 37, here in the form of an exhaust gas recirculation path 39, wherein in the exhaust gas recirculation path 39 an exhaust gas recirculation path
- Adjusting device 41 in particular in the form of an exhaust gas recirculation flap, is arranged, by means of which an exhaust gas recirculation rate, that is a proportion of recirculated into the charging path 27 from the exhaust path 5 exhaust gas, is adjustable.
- an exhaust gas recirculation rate that is a proportion of recirculated into the charging path 27 from the exhaust path 5 exhaust gas.
- the control device 13 is connected to the turbine bypass path adjusting device 31, the
- Fig. 2 shows a schematic representation of an embodiment of a method for
- a first step S1 during operation of the exhaust aftertreatment system 3 at least one operating parameter is detected which is associated with an oxidation state of an SCR catalyst material of the SCR catalyst 7 stands.
- the at least one detected operating parameter is evaluated, in particular with regard to the oxidation state of the SCR catalyst material.
- a third step S3 depending on the at least one operating parameter, in particular depending on the oxidation state of the SCR catalyst material, which was determined based on the at least one operating parameter in the second step S2, at least one measure for preventing further reduction of the SCR catalyst material and / or at least one Reoxidations£worm initiated for reoxidation of the SCR catalyst material.
- the at least one operating parameter preferably an exhaust gas temperature, an operating time, an exhaust gas temperature operating time integral, a temporally integrally reacted nitrogen oxide freight, a temporally integrally metered amount of reducing agent, a
- the at least one operating parameter is compared with a predetermined and preferably stored in the control device 13 threshold, the measure for
- Prevent further reduction and / or the Reoxidationselftes is initiated when the at least one operating parameter reaches or exceeds the predetermined threshold, or if the at least one operating parameter of the predetermined
- Threshold reaches or exceeds for a predetermined period of time.
- a catalyst reaction model is preferably stored, wherein the oxidation state of the SCR catalyst material and / or a nitrogen oxide conversion value of the SCR catalyst material is determined by means of the catalyst reaction model, wherein the catalyst reaction model, the at least one operating parameter supplied as input wherein the at least one measure for preventing further reduction and / or the at least one reoxidation measure is initiated depending on the oxidation state determined by the catalyst reaction model and / or the nitrogen oxide conversion value.
- At least one measure to prevent further reduction and / or the at least one Reoxidationsssenwort is preferably a reducing agent dosage in reduces the exhaust gas path 5 of the exhaust aftertreatment system 3 upstream of the SCR catalyst 7, raises an oxygen concentration in the exhaust gas upstream of the SCR catalyst 7, lowers the exhaust gas temperature upstream of the SCR catalyst 7, and / or decreases a nitrogen oxide concentration in the exhaust gas upstream of the SCR catalyst 7 ,
- the oxygen concentration is preferably increased and / or the exhaust gas temperature is lowered by changing the setting position of the turbine bypass path adjusting device 31, and / or by changing the setting position of the compressor bypass path adjusting device 35.
- the nitrogen oxide concentration in the exhaust gas is preferably reduced by increasing the exhaust gas recirculation rate, in particular by means of the exhaust gas recirculation setting device 41, and / or by changing a combustion center position in at least one combustion chamber of the internal combustion engine 1.
- the control device 13 is preferably operatively connected to an ignition device or an injector for the direct injection of a fuel into the combustion chamber in order to set an ignition timing can.
- Internal combustion engine 1 stronger in terms of efficiency and thus can be optimized fuel-efficient, with associated, higher nitrogen oxide emissions are compensated by the higher or at least not reduced conversion rate of the SCR catalyst 7.
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- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Combustion & Propulsion (AREA)
- Mechanical Engineering (AREA)
- General Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Health & Medical Sciences (AREA)
- Toxicology (AREA)
- Analytical Chemistry (AREA)
- Exhaust Gas After Treatment (AREA)
Abstract
Description
Claims
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE102016222801.3A DE102016222801B4 (de) | 2016-11-18 | 2016-11-18 | Verfahren zum Betreiben eines Abgasnachbehandlungssystems einer Brennkraftmaschine, Abgasnachbehandlungssystem für eine Brennkraftmaschine und Brennkraftmaschine mit einem solchen Abgasnachbehandlungssystem |
| PCT/EP2017/001282 WO2018091129A1 (de) | 2016-11-18 | 2017-11-03 | Verfahren zum betreiben eines abgasnachbehandlungssystems einer brennkraftmaschine, abgasnachbehandlungssystem für eine brennkraftmaschine und brennkraftmaschine mit einem solchen abgasnachbehandlungssystem |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| EP3542037A1 true EP3542037A1 (de) | 2019-09-25 |
Family
ID=60574512
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| EP17808767.2A Withdrawn EP3542037A1 (de) | 2016-11-18 | 2017-11-03 | Verfahren zum betreiben eines abgasnachbehandlungssystems einer brennkraftmaschine, abgasnachbehandlungssystem für eine brennkraftmaschine und brennkraftmaschine mit einem solchen abgasnachbehandlungssystem |
Country Status (5)
| Country | Link |
|---|---|
| US (1) | US20200271032A1 (de) |
| EP (1) | EP3542037A1 (de) |
| CN (1) | CN109952419A (de) |
| DE (1) | DE102016222801B4 (de) |
| WO (1) | WO2018091129A1 (de) |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| AT524012B1 (de) * | 2020-07-03 | 2022-10-15 | Avl List Gmbh | Gasbetriebene Brennkraftmaschine und Abgasreinigung hierfür |
| CN112983597A (zh) * | 2021-04-23 | 2021-06-18 | 潍柴动力股份有限公司 | 一种燃气发动机后处理系统 |
Family Cites Families (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE10020100A1 (de) * | 2000-04-22 | 2001-10-31 | Dmc2 Degussa Metals Catalysts | Verfahren und Katalysator zur Reduktion von Stickoxiden |
| DE602005001922T2 (de) * | 2004-12-18 | 2007-12-06 | Haldor Topsoe A/S | Verfahren zur Regelung der Zugabe eines Reduktionsmittels in das Abgas einer Brennkraftmaschine |
| US7526950B2 (en) * | 2007-01-31 | 2009-05-05 | Ford Global Technologies, Llc | Emission control diagnostic system and method |
| US8635853B2 (en) * | 2008-01-25 | 2014-01-28 | Caterpillar Inc. | Exhaust reduction system having oxygen and temperature control |
| US8474248B2 (en) | 2009-05-06 | 2013-07-02 | Detroit Diesel Corporation | Model based method for selective catalyst reducer urea dosing strategy |
| US8869513B2 (en) * | 2012-04-19 | 2014-10-28 | GM Global Technology Operations LLC | Exhaust diagnostic control system and method with NH3 depletion cleansing |
| US9238984B2 (en) * | 2014-02-03 | 2016-01-19 | Caterpillar, Inc. | Exhaust emission prediction system and method |
| JP6102907B2 (ja) * | 2014-12-26 | 2017-03-29 | トヨタ自動車株式会社 | 排気浄化装置の劣化診断装置 |
| JP6102908B2 (ja) * | 2014-12-26 | 2017-03-29 | トヨタ自動車株式会社 | 排気浄化装置の劣化診断装置 |
| JP6123822B2 (ja) * | 2015-02-13 | 2017-05-10 | トヨタ自動車株式会社 | 排気浄化装置の劣化診断装置 |
| DE102015004063A1 (de) * | 2015-03-28 | 2016-03-10 | Mtu Friedrichshafen Gmbh | Anordnung und Verfahren |
-
2016
- 2016-11-18 DE DE102016222801.3A patent/DE102016222801B4/de not_active Expired - Fee Related
-
2017
- 2017-11-03 US US16/461,958 patent/US20200271032A1/en not_active Abandoned
- 2017-11-03 WO PCT/EP2017/001282 patent/WO2018091129A1/de not_active Ceased
- 2017-11-03 CN CN201780071298.7A patent/CN109952419A/zh active Pending
- 2017-11-03 EP EP17808767.2A patent/EP3542037A1/de not_active Withdrawn
Also Published As
| Publication number | Publication date |
|---|---|
| WO2018091129A1 (de) | 2018-05-24 |
| CN109952419A (zh) | 2019-06-28 |
| DE102016222801B4 (de) | 2019-12-24 |
| US20200271032A1 (en) | 2020-08-27 |
| DE102016222801A1 (de) | 2018-05-24 |
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