EP3518887A1 - Verbessert konditionierende haarbehandlungsmittel mit auswaschschutz - Google Patents
Verbessert konditionierende haarbehandlungsmittel mit auswaschschutzInfo
- Publication number
- EP3518887A1 EP3518887A1 EP17749406.9A EP17749406A EP3518887A1 EP 3518887 A1 EP3518887 A1 EP 3518887A1 EP 17749406 A EP17749406 A EP 17749406A EP 3518887 A1 EP3518887 A1 EP 3518887A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- weight
- hair treatment
- hair
- composition according
- preferred
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
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Classifications
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/12—Preparations containing hair conditioners
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/34—Alcohols
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/34—Alcohols
- A61K8/345—Alcohols containing more than one hydroxy group
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
- A61K8/41—Amines
- A61K8/416—Quaternary ammonium compounds
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
- A61K8/44—Aminocarboxylic acids or derivatives thereof, e.g. aminocarboxylic acids containing sulfur; Salts; Esters or N-acylated derivatives thereof
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/49—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing heterocyclic compounds
- A61K8/4906—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing heterocyclic compounds with one nitrogen as the only hetero atom
- A61K8/4913—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing heterocyclic compounds with one nitrogen as the only hetero atom having five membered rings, e.g. pyrrolidone carboxylic acid
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/64—Proteins; Peptides; Derivatives or degradation products thereof
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/64—Proteins; Peptides; Derivatives or degradation products thereof
- A61K8/65—Collagen; Gelatin; Keratin; Derivatives or degradation products thereof
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/73—Polysaccharides
- A61K8/731—Cellulose; Quaternized cellulose derivatives
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/73—Polysaccharides
- A61K8/737—Galactomannans, e.g. guar; Derivatives thereof
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/004—Preparations used to protect coloured hair
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/02—Preparations for cleaning the hair
Definitions
- the invention relates to hair treatment compositions, in particular shampoos and so-called conditioners, with a combination of active ingredients for gentle and effective care of the hair.
- hair treatment compositions in particular shampoos and so-called conditioners
- active ingredients for gentle and effective care of the hair.
- care products affect the natural structure and properties of the hair.
- the wet and dry combability of the hair, the hold and the fullness of the hair can be optimized or the hair can be protected from increased splits following such care treatments.
- the hair is treated with special active ingredients, for example quaternary ammonium salts or special polymers, usually in the form of a rinse.
- special active ingredients for example quaternary ammonium salts or special polymers, usually in the form of a rinse.
- this treatment improves the combability, the hold and the fullness of the hair and reduces the splitting rate.
- multifunctional cosmetic products are known in the prior art.
- these include the so-called “2 in 1" shampoos, which not only cleanse the hair, but also condition it.
- These products are highly appreciated by the consumer because of their product performance, at least one process step, for example, conditioning with a classical hair conditioner; unnecessary.
- the term "undesired change” is understood to mean the fading or bleeding and loss of color brilliance of the hue of the hair as a result of the respective dyeing.Environmental influences and / or sun effects may exacerbate these changes.There is still a need for active ingredients or active ingredient combinations for hair treatment products with good nourishing properties, which also strengthen the adhesion of dyes to the hair fibers and thus preserve the authenticity of the artificially produced hair color, and further develop hair treatment products in this regard.
- the present application was therefore based on the object to provide good skin-friendly and nourishing hair treatment compositions which have excellent foam properties and have a good rinsability with water and also reduce or prevent the washing out of color from dyed hair.
- the nourishing hair treatment products should have a constant conditioning performance regardless of the water quality and in particular fine hair and / or damaged hair and thereby strengthen the hair in their structure and so protect against splits and breakage and improve combability and grip. In addition, they should have a germ-reducing effect.
- a first object of the present invention are hair treatment compositions containing by weight
- R ' is a straight-chain or branched, saturated or unsaturated hydrocarbon radical having 1 to 24 carbon atoms
- R is a protein, a peptide or a protein hydrolyzate means
- X is -C (O) O- or -N + (R '" 2 ) -R' V - or -N (R"')R' V - or -C (O) -N (R V ) R VI - stands,
- Hair treatment compositions for the purposes of the present invention are, for example, hair shampoos, hair conditioners, conditioning shampoos, hairsprays, hair conditioners, hair conditioners, hair wraps, hair tonics, perming solutions, hair dye shampoos, hair dyes, hair fixatives, hair dressings, hairstyling preparations, hair lotions, mousses, hair gels , Hair waxes or their combinations.
- Preferred agents are therefore shampoos, conditioners or hair tonics.
- the hair treatment compositions contain as the first essential ingredient 0.001 to 10 wt .-% of at least one Succinimidylesters.
- Succinimidyl esters are esters of carboxylic acids with (optionally substituted) / V-hydroxysuccinimide (NHS, IUPAC 1-hydroxy-2,5-pyrrolidinedione) and are also referred to as NHS esters.
- Hair treatment compositions which are preferred according to the invention are characterized in that they additionally contain from 0.01 to 10% by weight, preferably from 0.05 to 7.5% by weight, more preferably from 0.1 to 6% by weight, based on the weight of the composition. % and in particular 0.15 to 5% by weight of (one) succinimidyl ester (s) of the formula (III)
- R1 represents -H or an ionic group.
- R is an optionally substituted saturated or unsaturated, linear, branched or cyclic, aliphatic or aromatic hydrocarbon radical having at least 5 C atoms.
- Suitable ionic groups R1 include both anionic groups such as phosphate, phosphonate, phosphinate, sulfate, sulfonate, sulfinate, sulfenate, oxysulfonate, carboxylate groups and cationic groups such as substituted or unsubstituted ammonium groups. Zwitterionic / betainic groups such as carboxybetaine or sulfobetaine groups are also possible.
- R 1 is -H or -OSO 3 " or -SO 3 " or -SO 2 - or -COO " or -NH 3 + or -N (CH 3 ) H 2 + or -N (CH 3 ) 2 H + or -N (CH 3 ) 3 + or -N + (CH 3 ) 2 (CH 2 ) 2-COO- or -N + (CH 3 ) 2 (CH 2 ) 3 -SO 3 -.
- succinimidyl esters to be used according to the invention are described in priority document on pages 4 to 7 with the numbers 1 to 72.
- Very particularly preferred hair treatment compositions according to the invention are characterized in that they contain, based on their weight, from 0.01 to 10% by weight, preferably from 0.05 to 7.5% by weight, more preferably from 0 to 1 to 6% by weight. % and in particular 0, 15 to 5 wt .-% of at least one Succinimidylesters from the group
- X is H, a monovalent cation or the nth part of an n-valent cation
- Hair treatment compositions containing these succinimidyl esters have excellent care properties on both thin and normal hair, provide a significant structure strengthening and prevent the washing and bleeding of chemically colored hair very effectively.
- compositions according to the invention contain from 0.001 to 20% by weight of at least one proteolipid of the formula (I) R ' -XR " (I),
- R ' is a straight-chain or branched, saturated or unsaturated hydrocarbon radical having 1 to 24 carbon atoms
- R is a protein, a peptide or a protein hydrolyzate means
- X is -C (O) O- or -N + (R '" 2 ) -R' V - or -N (R"')R' V - or -C (O) -N (R V ) R VI - stands,
- Preferred cosmetic agents contain - by weight - 0, 01 to 10 wt .-%, preferably 0.02 to 5 wt .-%, particularly preferably 0.05 to 2.5 wt .-%, more preferably 0, 1 to 1 wt .-% and in particular 0, 15 bis 0.5% by weight of proteolipid (s).
- R " in formula (I) represents a peptide or a protein or a protein hydrolyzate
- Preferred radicals R " are oligopeptides which have at least one amino acid sequence Glu-Glu-Glu, where the amino group may be free or protonated and the carboxy groups may be free or deprotonated.
- Oligopeptides in the sense of the present application are acid amide-like linked by peptide bonds condensation products of amino acids comprising at least 3 and a maximum of 25 amino acids.
- the molecular weight of the proteolipid contained in the agents can vary , Preferred cosmetic agents are characterized in that the proteolipid has a molecular weight of from 1000 to 30,000 Da, preferably from 1250 to 25,000 Da, more preferably from 1,500 to 20,000 Da and in particular from 2,000 to 15,000 Da.
- oligopeptides are preferably used, which not only consist of the three glutamic acids, but contain further bound to this sequence amino acids. These additional amino acids are preferably selected from certain amino acids, while certain other agents are less preferred.
- radical R " contains the proteolipids used in the agents tyrosine It is further preferred if the radical R " contains the proteolipids used in the agents leucine.
- radical R "of the proteolipids isoleucine used in the agents contains.
- radical R " contains the proteolipids used in the agents arginine.
- radical R " contains the proteolipids used in the agents valine.As the radical R " in particularly preferred oligopeptides or in the preferred oligopeptides amino acid sequences are described below:
- a particularly preferred oligopeptide additionally contains tyrosine, which is preferably linked via its acid function to the Glu-Glu-Glu sequence.
- Preferred cosmetic agents are therefore characterized in that the oligopeptide contained in the proteolipids of the formula (I) as the radical R "has at least one amino acid sequence Tyr-Glu-Glu-Glu, where the amino group is free or protonated and the carboxy groups are free
- Another particularly preferred oligopeptide additionally contains isoleucine, which is preferably linked to the Glu-Glu-Glu sequence via its amino function, and therefore preferred cosmetic agents are characterized in that in the proteolipids of the formula (I) as Residual R " contained oligopeptide having at least one amino acid sequence Glu-Glu-Glu-Ile, wherein the amino group is free or protonated and the carboxy groups may be free or deprotonated.
- Oligopeptides having both of the aforementioned amino acids are preferred.
- Cosmetic agents are particularly preferred in which the oligopeptide contained in the proteolipids of the formula (I) as the radical R "has at least one amino acid sequence Tyr-Glu-Glu-Ile, where the amino group is free or protonated and the carboxy- Groups may be free or deprotonated.
- oligopeptides additionally contain arginine, which is preferably bound to isoleucine.
- Preferred cosmetic agents are therefore characterized in that the oligopeptide contained in the proteolipids of the formula (I) as the radical R "has at least one amino acid sequence Tyr-Glu-Glu-Glu-Ile-Arg, where the amino groups are free or protonated and the Carboxy groups may be present freely or deprotonated.
- Still further preferred oligopeptides additionally contain valine, which is preferably bound to the arginine.
- Further preferred cosmetic agents are therefore characterized in that the oligopeptide contained in the proteolipids of the formula (I) as the radical R "has at least one amino acid sequence Tyr-Glu-Glu-Glu-Ile-Arg-Val, where the amino groups are free or protonated and the carboxy groups may be present freely or deprotonated.
- Still further preferred oligopeptides additionally contain leucine, which is preferably bound to valine.
- Further preferred cosmetic agents are characterized in that the oligopeptide contained in the proteolipids of the formula (I) as the radical R "has at least one amino acid sequence Tyr-Glu-Glu-Glu-Ile-Arg-Val-Leu, the amino groups being free or protonated and the carboxy groups may be free or deprotonated.
- Particularly preferred oligopeptides additionally contain leucine, which is preferably bound to the tyrosine.
- Further preferred cosmetic agents are characterized in that the oligopeptide contained in the proteolipids of the formula (I) as the radical R " is at least one Amino acid sequence Leu-Tyr-Glu-Glu-Glu-Ile-Arg-Val-Leu, wherein the amino groups are free or protonated and the carboxy groups may be free or deprotonated.
- especially cosmetic agents which contain at least one proteolipid of the formula (I) in which R "has at least one amino acid sequence Leu-Tyr-Glu-Glu-Glu-Ile-Arg-Val-Leu, the amino groups being free or protonated and the carboxy groups may be free or deprotonated.
- the radical R " in formula (I) may be a peptide or a protein or a protein hydrolyzate, with protein hydrolysates being preferred Protein hydrolysates are product mixtures obtained by acid, base or enzymatically catalyzed degradation of proteins (proteins) Protein hydrolysates of both vegetable and animal origin can be used.
- Animal protein hydrolysates are, for example, elastin, collagen, keratin, silk and milk protein protein hydrolysates, which may also be present in the form of salts.
- Such products are, for example, under the trademarks Dehylan ® (BASF SE), Promois® ® (Interorgana) Collapuron ® (BASF SE), Nutrilan® ® (BASF SE), Gelita-Sol ® (German Gelatinefabriken Stoess & Co), Lexein ® ( Inolex) and kerasol tm ® Croda) (marketed.
- Protein hydrolysates of plant origin for example soybean, almond, rice, pea, potato and wheat protein hydrolysates.
- Such products are, for example, under the trademarks Gluadin ® (BASF SE), diamine ® (Diamalt) ® (Inolex) and Crotein ® (Croda) available.
- the radical R " is selected from keratin or keratin hydrolysates
- Preferred cosmetic agents are characterized in that they contain at least one proteolipid of formula (I) in which R " is for keratin or a Keratinhydrolysat stands.
- particularly preferred cosmetic agents are characterized in that they contain at least one proteolipid of the formula (I) in which X represents -N + (CH 3 ) 2-CH 2 -CH (OH) -CH 2 - and R 'represents - ( CH 2 ) i7-CH 3 .
- particularly preferred cosmetic agents are characterized in that they contain at least one proteolipid of the formula (I) in which X is -N + (CH 3) 2 -CH 2 -CH (OH) -CH 2 - and R 'is - (CH 2 ) i i-23-CH 3 .
- preferred cosmetic agents are characterized in that they contain at least one proteolipid of the formula (I) in which X is -C (O) -O- and R 'is - (CH 2 ) 7 -CH 3.
- the agents preferably contain the proteolipid (s) in an amount of from 0.01 to 10.0% by weight and more preferably from 0.05 to 2.0% by weight, based in each case on the weight of the ready-to-use agent ,
- preferred hair treatment compositions according to the invention are characterized in that they contain -0.01 to 15 wt .-%, preferably 0.05 to 10 wt .-%, more preferably 0, 1 to 7.5 wt .-% by weight.
- compositions according to the invention are characterized in that they contain - based on their weight -0, 01 to 15 wt .-%, preferably 0.05 to 10 wt .-%, more preferably 0, 1 to 7.5 wt .-% and in particular 0.15 to 5 wt .-% of at least one proteolipid of the formula (II in which X is -C (O) -O- or -N + (CH 3 ) 2 -CH 2 -CH (OH) -CH 2 - and R 'is - (CH 2 ) n -23-CH 3 , in particular represents - (CH 2 ) i7-CH 3 .
- agents according to the invention may contain amino-functional silicones to further increase the conditioning effects.
- Preferred agents according to the invention contain from 0.001 to 50% by weight of at least one amino-functional silicone.
- Particularly preferred agents according to the invention are characterized in that they contain at least one amino-functional silicone of the formula (Si-IIa)
- n and n are numbers whose sum (m + n) is between 1 and 2000, preferably between 50 and 150, where n preferably values of 0 to 1999 and in particular of 49 to 149 and m preferably values of 1 to 2000 , in particular from 1 to 10 assumes.
- compositions according to the invention which are an amino-functional silicone of the formula (Si-IIb)
- R is -OH, -O-CH3 or a -CH3 group and m
- n1 and n2 are numbers whose sum (m + n1 + n2) is between 1 and 2000, preferably between 50 and 150, wherein the sum (n1 + n2) preferably assumes values from 0 to 1999 and in particular from 49 to 149 and m preferably values from 1 to 2000, in particular from 1 to 10.
- silicones are referred to as amodimethicones according to the INCI declaration.
- the amine number stands for the milliequivalents of amine per gram of the amino-functional silicone. It can be determined by titration and also expressed in mg KOH / g.
- Hair-treatment agents preferred according to the invention are characterized in that, based on their weight, they contain from 0.01 to 20% by weight, preferably from 0.05 to 10% by weight, more preferably from 0.1 to 7.5% by weight and in particular from 0.15 to 5% by weight of amino-functional silicone (s).
- the agents according to the invention contain amino-functional silicone (s) with terminal (r / n) hydroxy group (s).
- pretreatment agents which contain at least one silicone of the formula (Si-V) have proven particularly effective with regard to the desired effects:
- A represents a group -OH, -0-Si (CH 3) 3, -0-Si (CH3) 20H, -0-Si (CH 3) 20ch 3, D is a group of -H, -Si (CH 3 ) 3 , -Si (CH 3 ) 2 OH, -Si (CH 3 ) 2 OCH 3 ,
- n and c are integers between 0 and 1000,
- Hair treatment compositions according to the invention which - based on their weight - 0.01 to 20 wt.%, Preferably 0.01 to 20 wt .-%, preferably 0, 1 to 10 wt .-%, more preferably 0.5 to 7.5 Wt .-% and in particular 0.1 to 5 wt .-% of at least one silicone of the formula (Si-V) contain:
- D is a group -H, -Si (CH 3 ) 3 , -Si (CH 3 ) 2 OH, -Si (CH 3 ) 2 OCH 3 ,
- n and c are integers between 0 and 1000,
- the individual siloxane units having the indices b, c and n are randomly distributed, i. it does not necessarily have to be block copolymers.
- compositions according to the invention which, based on their weight, 0.001 to 20 wt.%, Preferably 0.01 to 10 wt.%, Particularly preferably 0.05 to 7.5 wt.% And in particular 0.5 to 5 wt.% Of at least one 4-morpholinomethyl-substituted silicone containing structural units of the formulas (Si-Via), (Si-Vlb) and (Si-Vlc)
- R 1 is -CH 3 , -OH, -OCH 3 , -O-CH 2 CH 3 , -O-CH 2 CH 2 CH 3 , or -O-CH (CH 3 ) 2 ;
- R 2 is -CH 3 , -OH, or -OCH 3 ,
- Particularly preferred hair treatment compositions according to the invention contain, based on their weight, from 0.001 to 20% by weight, preferably from 0.01 to 10% by weight, particularly preferably from 0.05 to 7.5% by weight and in particular from 0.5 to 5% by weight.
- R 1 is -CH 3 , -OH, -OCH 3 , -O-CH 2 CH 3 , -O-CH 2 CH 2 CH 3 , or -O-CH (CH 3 ) 2 ;
- R2 is -CH 3 , -OH, or -OCH 3 .
- B represents a group -OH, -0-Si (CH 3) 3, -0-Si (CH3) 20H, -0-Si (CH 3) 20ch 3;
- D is a group -H, -Si (CH 3 ) 3, -Si (CH 3 ) 20H, -Si (CH 3 ) 2 OCH 3 ,
- a, b and c independently represent integers between 0 and 1000, with the proviso that a + b + c> 0
- the units a, b, c, m and n are distributed randomly or in blocks in the molecule.
- Structural formula (Si-VI) is intended to illustrate that the siloxane groups n and m do not necessarily have to be bound directly to an end grouping B or D, respectively. Rather, in preferred formulas (Si-VI) a> 0 or b> 0 and in particularly preferred formulas (Si-Vl) a> 0 and c> 0, i. the terminal moiety B or D is preferably attached to a dimethylsiloxy moiety. Also in formula (Si-Vl), the siloxane units a, b, c, m and n are preferably randomly distributed.
- the agents of the invention preferably contain the silicone (s) in the form of an emulsion, more preferably in the form of a microemulsion ,
- Nonionic components which are particularly suitable here are ethoxylates of decanol, undecanol, dodecanol, tridecanol, etc. Ethoxylated tridecanols have proven to be particularly suitable, which are incorporated with particular preference into the compositions according to the invention.
- compositions which are particularly preferred according to the invention are characterized in that they contain 0.00001 to 5% by weight, preferably 0.0001 to 3.5% by weight, particularly preferably 0.001 to 2% by weight, based on their weight preferably 0.01 to 1 wt .-% and in particular 0.1 to 0.5 wt .-% branched, ethoxylated tridecanol (INCI name: Trideceth-5) or o iso-tridecyl-u hydroxypolyglycolether (INCI name: Trideceth -10) or mixtures thereof.
- compositions of the invention may contain other silicone (s) which are not amino functional.
- preferred hair treatment compositions are characterized in that they - based on their weight - 0.01 to 20 wt .-%, preferably 0, 1 to 10 wt .-%, more preferably 0.5 to 7.5 wt .-% and in particular 1 to 5 wt .-% non-amino-functional silicone (s) included. Preferred silicones are described below.
- x is a number from 0 to 100, preferably from 0 to 50, more preferably from 0 to 20 and in particular 0 to 10.
- silicones are called DIMETHICONE according to the INCI nomenclature.
- the following compounds are preferably used as the silicone of the formula Si-I: (CH 3 ) 3 Si-O-Si (CH 3 ) 3 (CH 3 ) 3 Si-O- (CH 3 ) 2 Si-O- Si (CH 3 ) 3 (CH 3 ) 3 Si [O- (CH 3 ) 2 Si] 2 -O-Si (CH 3 ) 3 (CH 3 ) 3 Si [O- (CH 3 ) 2 Si] 3 -0-Si (CH 3 ) 3 (CH 3 ) 3 Si - [0- (CH 3 ) 2 Si] 4 -O-Si (CH 3 ) 3
- (CH 3 ) 3 Si [0- (CH 3 ) 2 Si] is-0-Si (CH 3 ) 3 (CH 3 ) 3 Si [0- (CH 3 ) 2 Si] i 6 -O-Si (CH 3 ) 3 (CH3) 3 Si- [0- (CH 3) 2 Si] i7-0-Si (CH 3) 3 (CH 3) 3 Si- [0- (CH3) 2 Si] i8-0-Si (CH 3) 3
- the hair treatment compositions of the invention may contain surfactant (s).
- surfactant in cleaning compositions (shampoos), in particular anionic surfactants have proven useful, in conditioning compositions, cationic surfactants are often used ingredients; Due to their advantageous properties, amphoteric surfactants are used with particular advantage both in shampoos and in conditioners.
- the hair treatment compositions of the invention may contain at least one anionic surfactant.
- Suitable anionic surfactants and emulsifiers for the compositions according to the invention are all anionic surfactants suitable for use on the human body. These are characterized by a water-solubilizing, anionic group such as. As a carboxylate, sulfate, sulfonate or phosphate group and a lipophilic alkyl group having about 8 to 30 carbon atoms. In addition, glycol or polyglycol ether groups, ester, ether and amide groups and hydroxyl groups may be present in the molecule.
- Preferred hair treatment compositions contain - based on their weight - 0.5 to 20 wt .-%, preferably 0.75 to 15 wt .-%, more preferably 1 to 12 wt .-% and in particular 2 to 10 wt .-% of anionic ( s) surfactant (s).
- Particularly preferred hair treatment compositions according to the invention are characterized in that they contain, based on their weight, from 0.5 to 20% by weight, preferably from 0.75 to 15% by weight, more preferably from 1 to 12% by weight and in particular from 2 to 10 wt .-% alkyl (ether) sulfate of the general formula R- (OCH 2 -CH 2 ) n -OS0 3 X, in which R is a straight-chain or branched, saturated or unsaturated alkyl group having 8 to 24 carbon atoms, n the Number 0 or 1 to 12, and X represents an alkali, alkaline earth, ammonium or alkanolamine ion included.
- the hair treatment compositions of the invention may contain at least one amphoteric surfactant and / or at least one nonionic surfactant.
- Particularly preferred hair treatment compositions according to the invention are characterized in that they contain, based on their weight, from 0.3 to 20% by weight, preferably from 0.5 to 8% by weight, more preferably from 0.75 to 6% by weight and in particular 1 to 5 wt .-% amphoteric surfactant (s) included.
- amphoteric surfactants or as zwitterionic surfactants called surfactants, which have both a negative and a positively charged functional group.
- Particularly preferred hair treatment compositions contain as amphoteric surfactants betaines of the formula (Bet-I)
- R is a straight-chain or branched, saturated or mono- or polyunsaturated alkyl or alkenyl radical having 8 to 24 carbon atoms.
- Cocoamidopropylbetaine Representatives derived from coconut fatty acids, are preferred and are referred to as Cocoamidopropylbetaine. According to the invention, particular preference is given to using surfactants of the formula (Bet-I) which are a mixture of the following representatives:
- hair-treatment compositions according to the invention are preferred which - based on their weight - 0.25 to 8 wt .-%, more preferably 0.5 to 7 wt .-%, more preferably 0.75 to 6.5 wt .-% and in particular 1 to 5.5 wt .-% of surfactant (s) of the formula (Bet-I) included.
- the hair-treatment compositions of the invention may be used with particular preference as amphoteric surfactants betaines of the formula (Bet-II)
- R is a straight-chain or branched, saturated or mono- or polyunsaturated alkyl or alkenyl radical having 8 to 24 carbon atoms.
- surfactants are referred to according to the INCI nomenclature as amphoacetates, wherein the representatives derived from coconut fatty acids are preferred and are referred to as cocoamphoactetates.
- surfactants of this type also always contain betaines of the formula (Bet-I 1a)
- R is a straight-chain or branched, saturated or mono- or polyunsaturated alkyl or alkenyl radical having 8 to 24 carbon atoms and M is a cation.
- surfactants are referred to according to the INCI nomenclature as Amphodiacetate, wherein the representatives derived from coconut fatty acids are preferred and are referred to as Cocoamphodiactetate.
- hair-treatment compositions according to the invention which - based on their weight - 0.25 to 8 wt .-%, more preferably 0.5 to 7 wt .-%, more preferably 0.75 to 6.5 wt .-% and in particular 1 to 5.5 wt .-% of surfactant (s) of the formula (Bet-II) included.
- cosmetic agents according to the invention are preferred in which the radical R in the formulas (Bet-I) and (Bet-II) is selected from
- the hair treatment agents may contain nonionic surfactant (s).
- Hair treatment agents preferred according to the invention contain, based on their weight, 0.3 to 10% by weight, preferably 0.5 to 8% by weight, more preferably 0.75 to 6% by weight and in particular 1 to 5% by weight. % nonionic surfactant (s).
- the hair treatment agents may contain cationic surfactant (s).
- Cationic surfactants of the quaternary ammonium compound type, the esterquats and the amidoamines can be used according to the invention.
- Preferred quaternary ammonium compounds are ammonium halides, in particular chlorides and bromides, such as alkyltrimethylammonium chlorides, dialkyldimethylammonium chlorides and trialkylmethylammonium chlorides.
- the long alkyl chains of these surfactants preferably have 10 to 18 carbon atoms, such as.
- cetyltrimethylammonium chloride stearyltrimethylammonium chloride, distearyldimethylammonium chloride, lauryldimethylammonium chloride, Lauryldimethylbenzylammonium chloride and tricetylmethylammonium chloride.
- Further preferred cationic surfactants are the imidazolium compounds known under the INCI names Quaternium-27 and Quaternium-83.
- Particularly preferred hair treatment compositions according to the invention are characterized in that they contain as cationic care substance - based on their weight - 0.05 to 7.5 wt .-%, preferably 0.1 to 5 wt .-%, particularly preferably 0.2 to 3, 5 wt .-% and in particular 0.25 to 2.5 wt .-% cationic (s) surfactant (s) from the group of quaternary ammonium compounds and / or esterquats and / or amidoamines.
- cationic care substance - based on their weight - 0.05 to 7.5 wt .-%, preferably 0.1 to 5 wt .-%, particularly preferably 0.2 to 3, 5 wt .-% and in particular 0.25 to 2.5 wt .-% cationic (s) surfactant (s) from the group of quaternary ammonium compounds and / or esterquats and / or amidoamines.
- Particularly preferred hair treatment compositions according to the invention are characterized in that, based on the weight of the composition, sis contains -0.05 to 20% by weight, preferably 0 to 1 to 10% by weight, more preferably 0.25 to 8% by weight. and in particular from 0.5 to 7% by weight of cationic surfactant (s), preferably from 0.05 to 20% by weight, preferably from 0.1 to 10% by weight, more preferably from 0.25 to 8% by weight .-% and in particular 0.5 to 7 wt .-% behenyl trimethyl ammonium chloride.
- cationic surfactant preferably from 0.05 to 20% by weight, preferably from 0.1 to 10% by weight, more preferably from 0.25 to 8% by weight .-% and in particular 0.5 to 7 wt .-% behenyl trimethyl ammonium chloride.
- compositions of the invention may contain at least one cationic polymer.
- Cationic polymers increase the care performance of the hair treatment compositions according to the invention (in particular the effectiveness of the hair breakage compositions according to the invention).
- preferred hair treatment agents contain, based on the weight of the composition, 0.01 to 3% by weight, preferably 0.05 to 2% by weight, further preferably 0.1 to 1.5% by weight and in particular 0.15 to 0.8% by weight of cationic polymer (s).
- Cationic polysaccharide polymers are used with particular preference according to the invention as cationic polymers.
- Cationic polysaccharide polymers increase the care performance of the hair treatment compositions according to the invention (in particular the effectiveness of the hair breakage compositions according to the invention).
- Suitable cationic polysaccharide polymers may be selected from cationic cellulose compounds and / or from cationic guar derivatives.
- Particularly preferred hair treatment compositions according to the invention contain as cationic polysaccharide polymer (s) - based on the weight of the composition - 0.01 to 3 wt .-%, preferably 0.05 to 2 wt .-%, more preferably 0.1 to 1, 5 wt .-% and in particular 0.15 to 0.8 wt .-% of at least one polymer from the group of cationic cellulose polymers and / or cationic guar derivatives.
- s cationic polysaccharide polymer
- Cationic cellulose compounds in the sense of the invention are those which carry more than one permanent cationic charge in at least one side chain.
- Cellulose is composed of beta-1, 4-glycosidically linked D-glucopyranose units and forms unbranched, water-insoluble chains.
- side chain of a cellulose chemical substituents are defined which bind to the cellulose skeleton and do not belong to the native cellulose since they have been subsequently introduced, for example, by chemical synthesis. Preference is given to quaternized cellulose polymers derived from hydroxy (C 2 -C 4) -alkylcelluloses, more preferably from hydroxyethylcelluloses.
- Such polymers are known to those skilled in the art and commercially available from various companies. Particularly preferred are the cationic cellulose derivatives known under the INCI names Polyquaternium-4, Polyquaternium-10, Polyquaternium-24, Polyquaternium-67 and / or Polyquaternium-72. Very particular preference is given to polyquaternium-10, polyquaternium-24 and / or polyquaternium-67 and particular preference to polyquaternium-10.
- Preferred hair treatment compositions according to the invention contain as cationic polysaccharide polymer (s) - based on the weight of the composition - 0.01 to 3 wt .-%, preferably 0.05 to 2 wt .-%, more preferably 0.1 to 1, 5 wt .-% and in particular 0, 15 to 0.8 wt .-% of at least one polymer from the group of Polyquaternium-4, Polyquaternium-10, Polyquaternium-24, Polyquaternium-67 and / or Polyquaternium-72.
- s cationic polysaccharide polymer
- Particularly preferred hair treatment compositions according to the invention contain as cationic polysaccharide polymer (s) - based on the weight of the composition - 0.01 to 3 wt .-%, preferably 0.05 to 2 wt .-%, more preferably 0.1 to 1, 5 wt .-% and in particular 0.15 to 0.8 wt .-% Polyquaternium-10.
- Suitable cationic guar derivatives in the context of the invention are cationic hydroxyalkyl guar derivatives, preferably cationic hydroxyethyltrimethylammonium guar and / or cationic hydroxypropyltrimethylammonium guar with average molecular weights between 100,000 and 2,000,000 daltons. Particularly preferred are the cationic guar polymers having a molecular weight (weight average) between 200,000 and 1,600,000 daltons known by the INCI name Guar Hydroxypropyltrimonium Chloride.
- the cationic charge density of these guar polymers is preferably at least 0.4 meq / g, preferably at least 0.5 meq / g and especially at least 0.6 meq / g.
- Their nitrogen content is preferably in the range of 1, 1 to 1, 8 wt .-% (based on their total weight).
- Cationic guar derivatives which are known under the INCI designation Guar Hydroxypropyltrimonium Chloride, are known in the art and available, for example under the trade name Cosmedia Guar ®, N-Hance ® and / or Jaguar ® from different vendors.
- Particularly preferred hair treatment compositions according to the invention contain as cationic polysaccharide polymer (s) - based on the weight of the composition - 0.01 to 3 wt .-%, preferably 0.05 to 2 wt .-%, more preferably 0, 1 to 1, 5 wt .-% and in particular 0, 15 to 0.8 wt .-% guar hydroxypropyltrimonium chlorides.
- preferred hair treatment compositions are characterized in that they - based on the weight of the composition - 0.01 to 3 wt .-%, preferably 0.05 to 2 wt .-%, more preferably 0.1 to 1, 5 wt. % and in particular 0.15 to 0.8% by weight of cationic polymer (s), preferably 0.01 to 3% by weight, preferably 0.05 to 2% by weight, more preferably 0, 1 to 1, 5 wt .-% and in particular 0, 15 to 0.8 wt .-% of at least one polymer from the group of cationic cellulose polymers and / or cationic guar derivatives.
- alpha-substituted aldehydes can further enhance the action of the compositions of the invention. In particular with regard to the inner structural strengthening of the keratin fibers and the prevention of leaching, significant increases in performance are observed.
- composition Based on the weight of the composition - additionally contain from 0.001 to 20 wt .-% of at least one alpha-substituted aldehyde.
- Preferred hair treatment compositions according to the invention are characterized in that they contain, based on their weight, from 0.01 to 10% by weight, preferably from 0.05 to 7.5% by weight, more preferably from 0.1 to 6% by weight and in particular from 0.15 to 5% by weight of alpha-substituted aldehyde (s) of the formula (I)
- Aldehydes which are preferably used according to the invention are described by the numbers 1 to 176 on pages 39 to 42 of the priority document.
- Very particularly preferred hair treatment compositions according to the invention are characterized in that they contain, based on their weight, from 0.01 to 10% by weight, preferably from 0.05 to 7.5% by weight, more preferably from 0 to 1 to 6% by weight. % and in particular 0, 15 to 5 wt .-% of at least one alpha-substituted aldehyde from the group
- Complexing agents can increase the effect of the agents according to the invention even further, in particular complexing agents which are derived from polycarboxylic acids have proved useful.
- complexing agent from the group tetrasodium A /, A / -bis (carboxylatomethyl) -L-glutamate (Tetrasodium Glutamate Diacetate, GLDA), Pentasodium Diethylenetriaminepentaacetate (DTPA), tetrasodium imino disuccinate (IDS ), Tetrasodium ethylenediaminetetraacetate (EDTA), tetrasodium ethylenediamine disuccinic acid (EDDS), trisodium hydroxyethylethylenediaminetriacetic acid (HEDTA).
- DTPA Pentasodium Diethylenetriaminepentaacetate
- IDS tetrasodium imino disuccinate
- EDTA Tetrasodium ethylenediaminetetraacetate
- EDDS tetrasodium ethylenediamine disuccinic acid
- HEDTA trisodium hydroxyethylethylenediaminetri
- Extremely preferred hair treatment compositions according to the invention are characterized in that 0.001 to 20% by weight, preferably 0.005 to 15% by weight, preferably 0.01 to 10% by weight, more preferably 0.05 to 7.5% by weight and in particular 0, based on their weight 1 to 5 wt .-% complexing agent from the group
- the agents according to the invention may contain only one of the three complexing agents mentioned. But it is also possible that the means according to the invention two or all three of the above. Complexing agents, the manganese of all the complexing agents contained in the agents from the o.g. Group within the quantitative range 0.01 to 20 wt .-% is.
- Hair treatment compositions which are preferred according to the invention are characterized in that they contain, based on their weight, from 0.005 to 15% by weight, preferably from 0.01 to 10% by weight, more preferably from 0.05 to 7.5% by weight and in particular from 0 , 1 to 5 wt .-% tetrasodium A /, A / -bis (carboxylatomethyl) - L-glutamate (Tetrasodium Glutamate Diacetate, GLDA) included.
- Hair treatment compositions which are likewise preferred according to the invention are characterized in that they contain, based on their weight, from 0.005 to 15% by weight, preferably from 0.01 to 10% by weight, more preferably from 0.05 to 7.5% by weight and in particular 0, 1 to 5 wt .-% pentasodium Diethylenetriaminepentaacetate (DTPA) included.
- DTPA pentasodium Diethylenetriaminepentaacetate
- Hair treatment compositions which are likewise preferred according to the invention are characterized in that they contain 0.005 to 15% by weight, preferably 0.01 to 10% by weight, based on their weight preferably 0.05 to 7.5 wt .-% and in particular 0, 1 to 5 wt .-% tetrasodium imidisuccinate (IDS) included.
- IDDS tetrasodium imidisuccinate
- DTPA pentasodium diethylenetriaminepentaacetate
- IDMS tetrasodium imino disuccinate
- DTPA pentasodium diethylenetriamine pentaacetate
- IDS tetrasodium imino disuccinate
- preferred hair treatment compositions contain - based on their weight -0, 1 to 5 wt .-% tetrasodium A /, A / -bis (carboxylatomethyl) -L-glutamate (Tetrasodium glutamate diacetates, GLDA) and 0, 1 to 5 wt % Pentasodium diethylenetriaminepentaacetate (DTPA) and 0.1 to 5% by weight tetrasodiumiminodisuccinate (IDS).
- the hair treatment compositions may contain at least one divalent or trivalent metal salt. These lead to an improved washout prevention. To achieve an optimum effect, it is advantageous if the metal salts are present in dissolved form in the compositions according to the invention.
- the hair cleansing and care compositions according to the invention therefore contain water-soluble divalent or trivalent metal salts.
- water-soluble is understood to mean that at 20 ° C. at least 1 g of the respective salt can be completely dissolved in 1 l of water.
- Suitable divalent or trivalent metal salts may be selected from divalent or trivalent organic and / or inorganic salts.
- Particularly suitable cations within these salts may preferably be selected from alkaline earth metal cations and from copper, zinc, iron (II), iron (III) and / or aluminum cations. Very particularly preferred are alkaline earth metal cations and particularly preferably calcium and magnesium cations.
- Particularly suitable organic anions within these salts may preferably be selected from formate, acetate, lactate, succinate, citrate, tartrate, malate, maleate, oxalate and / or glycolate ions. Very particular preference is given to acetate, lactate and / or citrate salts with the abovementioned cations.
- Particularly preferred organic salts are calcium, calcium, calcium, magnesium, magnesium and / or magnesium acetate.
- Particularly suitable inorganic anions within these salts can be selected from halide, sulfate, phosphate and / or carbonate ions. Very particular preference is given to sulfate and / or halide ions, such as chloride and bromide ions.
- Particularly preferred inorganic salts are calcium chloride, calcium sulfate, magnesium chloride and / or magnesium sulfate.
- the proportion by weight of the at least one divalent or trivalent metal salt in the total weight of the hair treatment compositions according to the invention is preferably from 0.01 to 10% by weight, preferably from 0.1 to 7.5% by weight, more preferably from 0.2 to 5% by weight. % and in particular 0.3 to 3 wt .-%.
- preferred hair treatment compositions contain - based on their weight - 0.01 to 10 wt .-%, preferably 0.1 to 7.5 wt .-%, more preferably 0.2 to 5 wt .-% and in particular 0.3 to 3 wt .-% of at least one divalent or trivalent metal salt from the group of organic or inorganic copper, zinc, iron (II), calcium, magnesium, iron (III) and / or aluminum salts.
- the water-soluble salts are particularly preferred. Most particularly preferred within this embodiment are calcium lactate, calcium citrate, calcium acetate, magnesium lactate, magnesium citrate, magnesium acetate, calcium halides, calcium hydroxide, magnesium halides and / or magnesium hydroxide.
- the hair treatment compositions preferably contain the active ingredients described above in a cosmetically acceptable carrier.
- a cosmetically acceptable carrier for the purposes of the invention, this is preferably understood as meaning an aqueous or aqueous-alcoholic carrier.
- the cosmetic carrier preferably contains at least 50% by weight, more preferably at least 60% by weight, particularly preferably at least 70% by weight and especially preferably at least 75% by weight of water.
- the cosmetic carrier may contain 0.01 to 40 wt .-%, preferably 0.05 to 30 wt .-% and in particular 0, 1 to 20 wt .-% of at least one alcohol.
- Suitable alcohols are, for example, ethanol, ethyl diglycol, 1-propanol, 2-propanol, isopropanol, 1,2-propylene glycol, glycerol, diglycerol, triglycerol, 1-butanol, 2-butanol, 1, 2-butanediol, 1, 3-butanediol, 1-pentanol, 2-pentanol, 1, 2-pentanediol, 1, 5-pentanediol, 1, hexanol, 2-hexanol, 1, 2-hexanediol, 1, 6-hexanediol, polyethylene glycols, sorbitol, sorbitan, benzyl alcohol or mixtures thereof alcohols.
- the hair treatment compositions according to the invention it is advantageous if they have a slightly acidic pH.
- compositions according to the invention in a pH range from 4.2 to 5.8 have a particularly good skin tolerance and mildness.
- the hair treatment compositions of the invention preferably have a pH in the range of 4.2 to 5.8, more preferably from 4.3 to 5.6, more preferably from 4.4 to 5.5, most preferably from 4.5 to 5.4, and most preferably from 4.7 to 5.3.
- the hair treatment compositions according to the invention may contain vegetable oils, vegetable butters and / or vegetable waxes. These vegetable oil components give the hair improved combability and manageability and increase hair shine.
- Suitable vegetable oil components include natural (vegetable) oils and / or butters, which commonly contain triglycerides and mixtures of triglycerides.
- Preferred natural oils are coconut oil, (sweet) almond oil, walnut oil, peach kernel oil, apricot kernel oil, argan oil, avocado oil, tea tree oil, soybean oil, sesame oil, sunflower oil, tsubaki oil, evening primrose oil, rice bran oil, palm kernel oil, mango seed oil, marula oil, meadowfoam oil, thistle oil, Macadamia nut oil, grape seed oil, amaranth seed oil, bamboo oil, olive oil, wheat germ oil, pumpkin seed oil, mallow oil, hazelnut oil, safflower oil, canola oil, sasanqua oil, jojoba oil, rambutan oil, cocoa butter and / or shea butter.
- Carnauba waxes, beeswaxes and / or candelilla waxes may be used as suitable natural or vegetable waxes.
- the proportion by weight of the at least one vegetable oil, the vegetable butter and / or the vegetable wax in the total weight of the hair treatment compositions according to the invention is preferably 0.02 to 2.50 wt .-%, more preferably from 0.03 to 2.00 wt .-% , Particularly preferably 0.04 to 1, 50 wt .-% and in particular 0.05 to 1, 00 wt .-%.
- the hair treatment compositions according to the invention may contain at least one further hair-conditioning active agent, which may be selected from the group of US Pat
- Suitable protein hydrolysates are product mixtures which can be obtained by acid, alkaline or enzymatically catalyzed degradation of proteins (proteins).
- Animal protein hydrolysates are, for example, elastin, collagen, keratin, silk and milk protein hydrolysates, which may also be present in the form of salts.
- Such products are, for example, under the trademarks Dehylan ® (Cognis), Promois® ® (Interorgana) Collapuron ® (Cognis), Nutrilan® ® (Cognis), Gelita-Sol ® (German Gelatinefabriken Stoess & Co), Lexein ® (Inolex) and kerasol tm ® (Croda) sold.
- protein hydrolysates of plant origin eg. Soybean, almond, rice, pea, potato and wheat protein hydrolysates.
- Such products are, for example, under the trademarks Gluadin ® (Cognis), diamine ® (Diamalt) ® (Inolex) and Crotein ® (Croda) available.
- cationized protein hydrolysates the protein hydrolyzate on which the animal is based, for example from collagen, milk or keratin, from the plant, for example from wheat, maize, rice, potatoes, soy or almonds, from marine life forms, for example from fish collages or algae, or from biotechnologically derived protein hydrolysates.
- the protein hydrolyzates on which the cationic derivatives are based can be obtained from the corresponding proteins by chemical, in particular alkaline or acid hydrolysis, by enzymatic hydrolysis and / or a combination of both types of hydrolysis.
- the hydrolysis of proteins usually results in a protein hydrolyzate having a molecular weight distribution of about 100 daltons up to several thousand daltons. Preference is given to those cationic protein hydrolyzates whose underlying protein content has a molecular weight of 100 to 25,000 daltons, preferably 250 to 5000 daltons.
- cationic protein hydrolyzates are to be understood as meaning quaternized amino acids and mixtures thereof.
- the quaternization of the protein hydrolyzates or amino acids is often carried out using quaternary ammonium salts such as N, N-dimethyl-N- (n-alkyl) -N- (2-hydroxy-3-chloro-n-propyl) ammonium halides.
- quaternary ammonium salts such as N, N-dimethyl-N- (n-alkyl) -N- (2-hydroxy-3-chloro-n-propyl) ammonium halides.
- the cationic protein hydrolysates may also be further derivatized.
- the proportion by weight of the protein hydrolyzate (s) in the total weight of the hair treatment compositions is preferably from 0.01 to 5% by weight, more preferably from 0.025 to 3% by weight and in particular from 0.05 to 2% by weight.
- Regardless of the source plant, animal, martim, etc. contain protein hydrolysates depending on the degree of hydrolysis of individual amino acids, oligopeptides and possibly polypeptides.
- the hair treatment compositions according to the invention comprise at least one oligopetide which has at least one amino acid sequence Glu-Glu-Glu, where the amino group can be free or protonated and the carboxy groups can be free or deprotonated.
- Preferred hair treatment compositions according to the invention are characterized in that they contain - based on their weight - 0.0001 to 10 wt .-% of at least one oligopeptide having at least one amino acid sequence Glu-Glu-Glu, wherein the amino group is free or protonated and the Carboxy groups may be present freely or deprotonated
- the parenthetized hydrogen atom of the amino group, as well as the parenthetical group of the acid function means that the groups concerned may be present as such (then an oligopeptide having the relevant number of amino acids as shown (see above) Formula 3) or that the amino acid sequence is present in an oligopeptide which comprises further amino acids, depending on where the other amino acid (s) is bound, are the parenthetical components of the above formula by the / the other Replaced amino acid residue (s).
- compositions according to the invention contain - based on their weight - 0.0001 to 10 wt .-% of at least one oligopeptide having at least one amino acid residue Glu-Glu-Glu, ie at least three consecutive glutamic acids.
- Oligopeptides in the sense of the present application are acid amide-like linked by peptide bonds condensation products of amino acids comprising at least 3 and a maximum of 25 amino acids
- the oligopeptide comprises 5 to 15 amino acids, preferably 6 to 13 amino acids, more preferably 7 to 12 amino acids and especially 8, 9 or 10 amino acids.
- the molecular weight of the oligopeptide contained in the agents of the invention may vary.
- Preferred hair treatment agents used according to the invention are characterized in that the oligopeptide has a molecular weight of from 650 to 3000 Da, preferably from 750 to 2500 Da, particularly preferably from 850 to 2000 Da and in particular from 1000 to 1600 Da.
- preferred hair treatment agents are characterized in that the oligopeptide comprises 5 to 15 amino acids, preferably 6 to 13 amino acids, more preferably 7 to 12 amino acids and especially 8, 9 or 10 amino acids and a molecular weight of 650 to 3000 Da, preferably 750 to 2500 Since, more preferably from 850 to 2000 Da and in particular from 1000 to 1600 Da has.
- oligopeptides which do not consist solely of the three glutamic acids but have further amino acids bound to this sequence.
- These other amino acids are preferably selected from certain amino acids, while certain other representatives are less preferred in the present invention.
- oligopeptides used in the agents according to the invention contain no methionine.
- the oligopeptides used in the agents according to the invention contain no cysteine and / or cystine. It is further preferred if the oligopeptides used in the agents according to the invention contain no aspartic acid and / or asparagine. It is further preferred if the oligopeptides used in the agents according to the invention contain no serine and / or threonine. Particularly preferred oligopeptides or amino acid sequences contained in the preferred oligopeptides are described below:
- a particularly preferred oligopeptide additionally contains tyrosine, which is preferably linked via its acid function to the Glu-Glu-Glu sequence.
- Hair treatment compositions which are preferred according to the invention are therefore characterized in that the oligopeptide contained in them has at least one amino acid sequence Tyr-Glu-Glu-Glu, where the amino group may be free or protonated and the carboxy groups may be free or deprotonated.
- Another particularly preferred oligopeptide additionally contains isoleucine, which is preferably linked to the Glu-Glu-Glu sequence via its amino function.
- Hair treatment compositions which are preferred according to the invention are therefore characterized in that the oligopeptide contained in them has at least one amino acid sequence Glu-Glu-Glu-Ile, where the amino- Group free or protonated and the carboxy groups may be free or deprotonated. Oligopeptides which have both the abovementioned amino acids (tyrosine and isoleucine) are preferred according to the invention. Hair treatment compositions according to the invention are particularly preferred in which the oligopeptide present in the hair treatment composition has at least one amino acid sequence Tyr-Glu-Glu-Glu-Ile, where the amino group can be free or protonated and the carboxy groups can be free or deprotonated.
- oligopeptides additionally contain arginine, which is preferably bound to isoleucine
- Hair treatment compositions according to the invention in which the oligopeptide contained in the hair treatment agent has at least one amino acid sequence Tyr-Glu-Glu-Glu-Ile-Arg, where the amino groups are free or protonated and the carboxy groups are free or deprotonated, are particularly preferred.
- Still further preferred oligopeptides additionally contain valine, which is preferably bound to the arginine.
- Further preferred hair treatment compositions according to the invention are characterized in that the oligopeptide contained in the hair treatment agent has at least one amino acid sequence Tyr-Glu-Glu-Glu-Ile-Arg-Val, wherein the amino groups are free or protonated and the carboxy groups are free or deprotonated can.
- Still further preferred oligopeptides additionally contain leucine, which is preferably bound to the valine.
- Further preferred hair treatment compositions according to the invention are characterized in that the oligopeptide contained in the hair treatment agent has at least one amino acid sequence Tyr-Glu-Glu-Glu-Ile-Arg-Val-Leu, wherein the amino groups are free or protonated and the carboxy groups are free or may be present deprotonated.
- oligopeptides additionally contain leucine, which is preferably bound to the tyrosine.
- Further preferred hair treatment compositions according to the invention are characterized in that the oligopeptide contained in the hair treatment agent has at least one amino acid sequence Leu-Tyr-Glu-Glu-Glu-Ile-Arg-Val-Leu, wherein the amino groups are free or protonated and the carboxy groups may be free or deprotonated.
- Preferred hair treatment agents according to the invention are characterized in that at least 0.1% by weight, preferably at least 0.5% by weight, particularly preferably at least 1% by weight, more preferably at least 2.5% by weight, even more preferred at least 5% by weight, and in particular at least 10% by weight, of all the keratinic peptides contained in the composition have the amino acid sequence Glu-Glu-Glu.
- Particularly preferred hair treatment compositions according to the invention are characterized in that at least 0.1% by weight, preferably at least 0.5% by weight, more preferably at least 1% by weight, more preferably at least 2.5% by weight, still further preferably at least 5% by weight and in particular at least 10% by weight of all the keratinic peptides contained in the middle have the amino acid sequence Tyr-Glu-Glu-Glu-Ile.
- Particularly preferred hair treatment compositions according to the invention are characterized in that at least 0.1% by weight, preferably at least 0.5% by weight, more preferably at least 1% by weight, more preferably at least 2.5% by weight, still further preferably at least 5% by weight and in particular at least 10% by weight of all the keratinic peptides contained in the middle have the amino acid sequence Tyr-Glu-Glu-Glu-Ile-Arg-Val-Leu.
- the abovementioned conditions relate to the total content of the agents according to the invention to peptides which originate from keratinic materials.
- oligopeptides of keratinic origin of course, other peptides and / or protenihydrolysates can be used, for example from other native sources.
- the additional use of wheat protein hydrolysates is preferred.
- the proportion by weight of the vitamin (s), vitamin derivative (s), and / or the vitamin precursor (s) in the total weight of the hair treatment agent is preferably from 0.001 to 2% by weight, particularly preferably from 0.005 to 1% by weight and in particular 0, 01 to 0.5 wt .-%.
- the plant extracts may in the hair treatment compositions according to the invention (based on the total weight of the compositions) preferably in an amount of 0.01 to 10 wt .-%, more preferably from 0.05 to 7.5 wt .-% and in particular from 0, 1 be used to 5 wt .-%.
- Glycerin may be added to the hair cleansing and care products separately in an amount of up to 10% by weight (based on the total weight of the composition). However, it may also be part of the aforementioned aqueous-alcoholic carrier.
- hair treatment compositions according to the invention are also suitable for use as antidandruff preparation.
- the total weight of anti-dandruff agents in the total weight of the hair treatment agent may preferably 0.01 to 10 wt .-%, more preferably 0.025 to 7.5 wt .-%, particularly preferably 0.05 to 5 wt .-% and in particular 0.075 to 3 wt. -%.
- Suitable antidandruff active ingredients may be selected from piroctone olamine, climbazole, zinc pyrithione, ketoconazole, salicylic acid, sulfur, selenium sulfide, tar preparations, undecenoic acid derivatives, burdock root extracts, poplar extracts, nettle extracts, walnut shell extracts, birch extracts, willow bark extracts, rosemary extracts and / or arnica extracts.
- the agents of the invention can be formulated as so-called rinse-off products, i. are rinsed out of the hair after a certain exposure time. This exposure time is preferably less than one hour, i. the consumer preferably does not leave the products until the next hair wash in the hair.
- Another object of the present invention is therefore a method for hair treatment in which an agent according to the invention is applied to dry or damp hair, left there for a period of 10 to 300 seconds and then rinsed out.
- compositions according to the invention can also be formulated as so-called leave-on products, ie they are not rinsed out of the hair but left there until the next hair wash.
- Another object of the present invention is therefore a method for hair treatment, in which an agent according to the invention is applied to dry or damp hair and left there until the next hair wash.
- the agents according to the invention lead to a significantly increased strengthening of the inner and outer hair structure.
- Another object of the present invention is therefore the use of agents according to the invention for strengthening the hair structure, in particular the inner hair structure.
- Structural strengthening in the sense of the invention is to be understood as meaning a reduction in the damage of keratinic fibers which has arisen due to the most diverse influences.
- the restoration of natural strength plays an essential role.
- Restructured fibers are characterized for example by an improved gloss, improved grip and easier combing.
- they have an optimized strength and elasticity.
- a successful structure strengthening or restructuring can be physically detected as a melting point increase in comparison to the damaged fiber.
- compositions of the invention also lead to a significantly increased stability of artificial dyeings against the washing out of paint.
- chemically dyed hairs can be washed significantly more frequently with the compositions according to the invention, without the undesired bleeding or color fading occurring.
- Another object of the present invention is therefore the use of agents according to the invention for reducing the washout of color from chemically colored hair.
- succinimidyl esters are used succinimidyl esters:
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- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
- Public Health (AREA)
- Veterinary Medicine (AREA)
- Birds (AREA)
- Epidemiology (AREA)
- Emergency Medicine (AREA)
- Dermatology (AREA)
- Cosmetics (AREA)
Abstract
Description
Claims
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE102016219003.2A DE102016219003A1 (de) | 2016-09-30 | 2016-09-30 | Verbessert konditionierende Haarbehandlungsmittel mit Auswaschschutz |
PCT/EP2017/068603 WO2018059788A1 (de) | 2016-09-30 | 2017-07-24 | Verbessert konditionierende haarbehandlungsmittel mit auswaschschutz |
Publications (1)
Publication Number | Publication Date |
---|---|
EP3518887A1 true EP3518887A1 (de) | 2019-08-07 |
Family
ID=59564153
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP17749406.9A Withdrawn EP3518887A1 (de) | 2016-09-30 | 2017-07-24 | Verbessert konditionierende haarbehandlungsmittel mit auswaschschutz |
Country Status (4)
Country | Link |
---|---|
US (1) | US20200030210A1 (de) |
EP (1) | EP3518887A1 (de) |
DE (1) | DE102016219003A1 (de) |
WO (1) | WO2018059788A1 (de) |
Family Cites Families (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
LU49208A1 (de) * | 1965-07-29 | 1967-01-30 | ||
DE3725030A1 (de) | 1987-07-29 | 1989-02-09 | Henkel Kgaa | Oberflaechenaktive hydroxysulfonate |
DE10356869A1 (de) * | 2003-12-03 | 2005-07-07 | Beiersdorf Ag | Tensidhaltige Zubereitung mit Licochalcon A |
DE102005013438A1 (de) * | 2005-03-21 | 2006-09-28 | Henkel Kgaa | Haarbehandlungs-Kit mit Komplexbildnern |
FR2915376B1 (fr) * | 2007-04-30 | 2011-06-24 | Oreal | Utilisation d'un agent de couplage multi-carbo sites multi-groupements pour proteger la couleur vis-a-vis du lavage de fibres keratiniques teintes artificiellement; procedes de coloration |
WO2008156327A2 (en) * | 2007-06-20 | 2008-12-24 | Lg Household & Health Care Ltd. | Lipid having specific functional group and personal care composition comprising the lipid |
AU2008318490A1 (en) * | 2007-10-31 | 2009-05-07 | Keratec, Ltd. | Keratin derivatives and methods of making the same |
FR2937543B1 (fr) * | 2008-10-27 | 2011-02-25 | Oreal | Utilisation d'un ester de n-hydroxysuccinimidyle pour proteger la couleur vis-a-vis du lavage de fibres keratiniques teintes artificiellement ; procedes de coloration |
DE102009048299A1 (de) * | 2009-10-05 | 2011-06-16 | Henkel Ag & Co. Kgaa | Haarbehandlungsmittel mit Tensid(en) und Proteolipid(en) |
-
2016
- 2016-09-30 DE DE102016219003.2A patent/DE102016219003A1/de not_active Withdrawn
-
2017
- 2017-07-24 WO PCT/EP2017/068603 patent/WO2018059788A1/de unknown
- 2017-07-24 US US16/337,306 patent/US20200030210A1/en not_active Abandoned
- 2017-07-24 EP EP17749406.9A patent/EP3518887A1/de not_active Withdrawn
Also Published As
Publication number | Publication date |
---|---|
DE102016219003A1 (de) | 2018-04-05 |
US20200030210A1 (en) | 2020-01-30 |
WO2018059788A1 (de) | 2018-04-05 |
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