EP3509433A1 - Manufacture of snack food chips - Google Patents

Manufacture of snack food chips

Info

Publication number
EP3509433A1
EP3509433A1 EP17780408.5A EP17780408A EP3509433A1 EP 3509433 A1 EP3509433 A1 EP 3509433A1 EP 17780408 A EP17780408 A EP 17780408A EP 3509433 A1 EP3509433 A1 EP 3509433A1
Authority
EP
European Patent Office
Prior art keywords
dough
starch
corn
containing component
weight
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
EP17780408.5A
Other languages
German (de)
English (en)
French (fr)
Inventor
Ajay Rajeshwar Bhaskar
Helen Charlotte BOODEN
Katherine Margaret SMITH
Daniel VERA NUNEZ
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Frito Lay Trading Co GmbH
Original Assignee
Frito Lay Trading Co GmbH
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Frito Lay Trading Co GmbH filed Critical Frito Lay Trading Co GmbH
Publication of EP3509433A1 publication Critical patent/EP3509433A1/en
Pending legal-status Critical Current

Links

Classifications

    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23LFOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
    • A23L7/00Cereal-derived products; Malt products; Preparation or treatment thereof
    • A23L7/10Cereal-derived products
    • A23L7/117Flakes or other shapes of ready-to-eat type; Semi-finished or partly-finished products therefor
    • A23L7/13Snacks or the like obtained by oil frying of a formed cereal dough
    • AHUMAN NECESSITIES
    • A21BAKING; EDIBLE DOUGHS
    • A21DTREATMENT, e.g. PRESERVATION, OF FLOUR OR DOUGH, e.g. BY ADDITION OF MATERIALS; BAKING; BAKERY PRODUCTS; PRESERVATION THEREOF
    • A21D13/00Finished or partly finished bakery products
    • A21D13/04Products made from materials other than rye or wheat flour
    • A21D13/047Products made from materials other than rye or wheat flour from cereals other than rye or wheat, e.g. rice
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23LFOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
    • A23L29/00Foods or foodstuffs containing additives; Preparation or treatment thereof
    • A23L29/10Foods or foodstuffs containing additives; Preparation or treatment thereof containing emulsifiers
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23LFOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
    • A23L29/00Foods or foodstuffs containing additives; Preparation or treatment thereof
    • A23L29/20Foods or foodstuffs containing additives; Preparation or treatment thereof containing gelling or thickening agents
    • A23L29/206Foods or foodstuffs containing additives; Preparation or treatment thereof containing gelling or thickening agents of vegetable origin
    • A23L29/212Starch; Modified starch; Starch derivatives, e.g. esters or ethers
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23LFOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
    • A23L5/00Preparation or treatment of foods or foodstuffs, in general; Food or foodstuffs obtained thereby; Materials therefor
    • A23L5/10General methods of cooking foods, e.g. by roasting or frying
    • A23L5/11General methods of cooking foods, e.g. by roasting or frying using oil
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23PSHAPING OR WORKING OF FOODSTUFFS, NOT FULLY COVERED BY A SINGLE OTHER SUBCLASS
    • A23P30/00Shaping or working of foodstuffs characterised by the process or apparatus
    • A23P30/10Moulding

Definitions

  • the present invention relates to a method of manufacturing snack food chips, in particular tortilla chips.
  • snack food chips well known.
  • a variety of different snack food chips is known having various shapes and configurations, and compositions.
  • tortilla chips which are composed of a maize-based composition (maize hereinafter being called "corn” in accordance with the terminology used in the United States) which has been formed as a corn masa dough, which is sheeted, cut into individual dough pieces, which are typically triangular in plan (although other shapes are widely known), toasted in an oven and then fried. The fried chips are then seasoned.
  • the masa dough uses fresh corn which has been subject to a nixtamalization process, in which the corn is boiled in an aqueous solution comprising lime, then allowed to soak in the solution and then the corn is washed and ground to produce corn masa.
  • US Patent Application Publication Nos. US 2005/0260314 A 1 and US 2008/0044534 Al disclose a method of making a masa-based dough to produce a fried tortilla chip-like product, in which starch is added to corn masa dough to help control moisture release during frying.
  • the dough ingredients include dry corn masa which is combined with pre-hydration water and mixed to make a pre-hydrated masa, then starches and minor ingredients are mixed with the pre-hydrated masa to form a flour, and then water is added to the flour to make an aerated buoyant masa dough.
  • the added starches are potato starch (pre-gelatinized) and modified starch.
  • tortilla chips which have particular visual characteristics, in particular a chip without any holes extending through the thickness of the chip and a blistered surface which comprises a distribution of small blisters on the surfaces of the chip.
  • the blisters give the tortilla chip a more natural hand-fried appearance as compared to a uniformly flat surface.
  • the blisters should be uniformly distributed over the chip surface, have a regular size distribution and should not be excessively punctured.
  • the chips should not be cracked or have through-holes therein.
  • the oven toasting step is used. This oven toasting step case-hardens the raw dough piece, i.e. creates a hard surface layer while leaving a raw dough composition in the middle of the chip.
  • the surface of the tortilla chip becomes uniformly blistered with an array of surface blisters.
  • the surface blisters are bubble-like voids extending away from the body of the chip, and preferably have a continuous curved wall, which is substantially semi-spherical or semi-ovoid, above the body of the chip.
  • Some blisters may have a punctured wall, but preferably a majority of the blisters, i. e. at least 50% by number, are unpunctured during the manufacturing process.
  • These blisters are formed by steam which is generated by cooking the moisture-containing dough; the steam is formed in the flexible starch matrix and then expands to form the blisters.
  • a masa dough using fresh corn is employed using only a frying step as the cooking step, and does not employ a toasting step, typically the resultant fried chip has an expanded pillow-like structure, i.e. a large central void surrounded by the interconnected peripheral edges of two opposed layers of the tortilla chip, or the tortilla chip does not exhibit any significant blistering.
  • the toasting step is added to form case-hardened surfaces which then are readily able to form blisters in the subsequent frying step.
  • the use of fresh corn and a toasting oven both increase the cost and complexity of the tortilla chip manufacturing line.
  • the present invention aims at least partially to meet those needs.
  • the present invention accordingly provides a method of manufacturing snack food chips, the method comprising the steps of: i. providing a first starch-containing component which comprises a cold water swelling starch, a second starch-containing component which comprises substantially ungelatinized starch, and a third starch-containing component which comprises corn masa flour;
  • a dough from a mixture of the first, second and third starch-containing components and water, wherein the dough comprises from 35 to 75 wt% corn masa flour, from 10 to 40 wt% of the second starch-containing component, and from 5 to 30 wt% of the first starch-containing component, each based upon the weight of dry ingredients of the dough, and the dough comprises from 25 to 35 wt% added water, based on the weight of the dough, wherein the dough is formed at a temperature of up to 30 °C by mixing dry ingredients of the dough with water for a period of from 3 to 60 seconds and the cold water swelling starch forms a gel matrix in the dough;
  • the first, second and third starch- containing components are each dry ingredients and optionally are formed as a dry mixture for forming the dough in step ii.
  • step ii the mixing of dry ingredients of the dough with water is for a period of from 3 to less than 60 seconds.
  • the dough in step ii is formed at a temperature of from 5 to 20 °C, further optionally from 10 to 15 °C.
  • the third starch-containing component further comprises at least one further corn ingredient, the further corn ingredient being selected from fresh corn masa, raw corn flour and cooked corn flour or any mixture of any two or more thereof.
  • the dough does not comprise a fresh corn masa ingredient.
  • the dough comprises from 45 to 70 wt optionally from 50 to 65 wt%, corn masa flour, based upon the weight of the dry ingredients of the dough.
  • the dough comprises from 15 to 30 wt% of the second starch-containing component, based upon the weight of the dry ingredients of the dough.
  • the dough comprises from 20 to 30 wt%, optionally about 25 wt%, of the second starch-containing component, based upon the weight of the dry ingredients of the dough.
  • the second starch-containing component is selected from tapioca starch and corn starch or a mixture thereof and optionally comprises tapioca cook-up starch and/or waxy corn cook-up starch.
  • the cold water swelling starch has a peak viscosity at a temperature of less than 50 °C, when measured by a rapid viscosity analyser (RVA) in excess water having a weight of water which is 3 times the weight of the cold water swelling starch.
  • RVA rapid viscosity analyser
  • cooking step v is carried out to cause the substantially ungelatinized starch in the second starch-containing component to gelatinize, the snack food chips comprising a starch matrix formed from the first and second starch-containing components, and corn masa particles dispersed in the starch matrix.
  • the second starch- containing component gelatinizes to form a continuous flexible starch matrix in which entrapped steam forms bubbles which cause expansion of the continuous flexible starch matrix.
  • the second starch-containing component has a peak viscosity at a temperature of from 50 to 80 °C, optionally from 60 to 70 °C, when measured by a rapid viscosity analyser (RVA) in excess water having a weight of water which is 3 times the weight of the second starch-containing component.
  • RVA rapid viscosity analyser
  • the third starch-containing component has a peak viscosity at a temperature of greater than 80 °C, when measured by a rapid viscosity analyser (RVA) in excess water having a weight of water which is 3 times the weight of the third starch-containing component.
  • RVA rapid viscosity analyser
  • the dough comprises from 5 to 20 wt% of cold water swelling starch in the first starch-containing component, based upon the weight of the dry ingredients of the dough.
  • the dough comprises from 10 to 15 wt%, optionally about 12 wt%, of cold water swelling starch in the first starch-containing component, based upon the weight of the dry ingredients of the dough.
  • the first starch-containing component is selected from a pre-gelatinized cereal flour, a pre-gelatinized starch derivative, or any mixture thereof.
  • the first starch-containing component is at least one pre-gelatinized cereal flour selected from corn, wheat, barley, rice, spelt, or any other grain-derived product, or any mixture thereof.
  • the first starch-containing component is a pre-gelatinized corn flour.
  • the dough further comprises from 5 to 20 wt%, , based upon the weight of the dry ingredients of the dough, of at least one cereal flour selected from wheat, barley, rice, spelt, or any other grain-derived product, or any mixture thereof.
  • the dough comprises from 10 to 15 wt%, based upon the weight of the dry ingredients of the dough, of at least one cereal flour selected from wheat, barley, rice, spelt, or any other grain-derived product, or any mixture thereof.
  • the cooking consists of frying and there is no oven or toasting step prior to the frying step.
  • the dough comprises from 25 to 30 wt added water, based on the weight of the dough.
  • the dough further comprises from 0.2 to 1.5 wt% of an emulsifier which is adapted to bind to free starch, based on the weight of the dough.
  • the emulsifier is a monoglyceride- diglyceride emulsifier comprising a mixture of at least one monoglyceride and at least one diglyceride, optionally the monoglyceride-diglyceride emulsifier comprising or consisting of a food additive having E-number E471.
  • the dough comprises from 0.2 to 0.5 wt% of the emulsifier, based on the weight of the dough.
  • the weight ratio of the added water: emulsifier in the dough is from 25: 1 to 200: 1.
  • the weight ratio of the added water: emulsifier in the dough is from 50: 1 to 150: 1 , optionally from 75: 1 to 125: 1.
  • the corn masa flour has a particle size falling at least partly within the range extending from a fine particle corn masa, in which at most 30 wt% of the fine particle corn masa is retained on a 500 ⁇ sieve and at least 25 wt% of the fine particle corn masa passes through a 250 ⁇ sieve, to a coarse particle corn masa, in which at least 6 wt% of the coarse particle corn masa is retained on an 850 ⁇ sieve and at most 35 wt% of the coarse particle corn masa passes through a 250 ⁇ sieve.
  • the corn masa flour is a mixture of two flours having respective particle sizes, optionally the mixture comprising from 20 to 45 wt%, typically from 30 to 40 wt%, of a first corn masa and from 55 to 80 wt%, typically from 60 to 70 wt%, of a second corn masa, each wt% being based on the weight of the corn masa flour, the first corn masa having a particle size range in which 0 wt% of the first corn masa is retained on a 2000 ⁇ sieve, at most 1 1 wt% of the first corn masa is retained on an 841 ⁇ sieve and at most 32 wt% of the first corn masa passes through a 149 ⁇ sieve, and the second corn masa having a particle size range in which 0 wt% of the second corn masa is retained on a 2000 ⁇ sieve, at most 22 wt% of the second corn masa is retained on an 841 ⁇ sieve and at most 26 wt% of the second corn masa passes through a 149 ⁇ sieve,
  • the dough sheet has a thickness of from 0.6 to 1 mm.
  • step iii the dough sheet is formed in a sheeting apparatus at a linear speed for the sheet of from 20 to 60 linear metres/minute, optionally from 30 to 50 linear metres/minute.
  • the dough pieces are shaped against a mould during frying so that the snack food chips are three-dimensionally shaped with a preset shape.
  • the cooking comprises or consists of frying and the frying temperature is from 160 to 200 °C, optionally from 170 to 190 °C, further optionally about 180 °C.
  • the frying time is from 15 to 30 seconds, optionally from 16 to 25 seconds, further optionally from 18 to 23 seconds.
  • the dough is formed by mixing together the first, second and third starch-containing components to form a dry mix, and then mixing the dry mix with water and a monoglyceride-diglyceride emulsifier to form the dough, wherein the monoglyceride-diglyceride emulsifier comprises a mixture of at least one monoglyceride and at least one diglyceride, optionally the monoglyceride-digl yceride emulsifier comprising or consisting of a food additive having E-number E471.
  • the dry mix has a water content of from 5 to 20 wt% water, optionally from 10 to 12 wt% water, based on the weight of the dry mix.
  • the dry mix when the dry mix is mixed with the water and monoglyceride-diglyceride emulsifier to form the dough the dry mix has a temperature of from 5 to 30 °C, optionally from 5 to 25 °C, and the water has a temperature of from 5 to 15 °C, optionally from 7 to 12 °C, further optionally from 8 to 1 1 °C.
  • the dry mix is mixed with the water, and optional monoglyceride-diglyceride emulsifier, to form the dough for a period of from 3 to 30 seconds, optionally from 5 to 30 seconds.
  • the snack food chips comprise a starch matrix formed from the first and second starch-containing components, and corn masa particles dispersed in the starch matrix.
  • the snack food chip comprises a tortilla chip.
  • more than 90% by number in a random population of 100 of the tortilla chips, more than 90% by number have a continuous wall without through-holes or cracks extending therethrough.
  • the cooking step is carried out to cause the snack food chip to have a plurality of blisters on opposite major surfaces each blister extending outwardly on both opposite major surfaces.
  • the blisters have a mean total number of blisters per cm 2 of the opposite major surfaces of from 0.92 to 1.20, preferably from 1.00 to 1.20, with the blisters having a maximum width of 1.2 mm, optionally wherein for the sample of 6 randomly selected chips, the blisters include a mean total number of blisters having a maximum width of less than 0.5 mm of from 0.63 to 0.83, preferably from 0.68 to 0.78, blisters per cm 2 , and a mean total number of blisters having a maximum width of from 0.5 to 1.2 mm of from 0.25 to 0.43, preferably from 0.30 to 0.38, blisters per cm 2 .
  • the preferred embodiments of the present invention can provide a novel method of manufacturing a snack food chip, in particular a tortilla chip, which can exhibit a controlled level of blistering, in particular a uniform blister distribution over the chip surfaces, without employing a toasting or oven step prior to a frying step, the latter being the cooking step.
  • Preferred embodiments of the present invention can provide that the controlled level of blistering is achieved without using fresh corn on the tortilla chip manufacturing line, i.e. without requiring a nixtamalization step carried out on fresh ground corn immediately prior to forming the dough.
  • some fresh corn masa can be added to provide additional corn flavour and/or texture.
  • the absence of an oven or toasting unit and the absence of a corn soaking unit in the tortilla chip manufacturing line reduces the capital costs and running costs of the manufacturing line. Also, the absence of a corn soaking unit simplifies the tortilla chip manufacturing process.
  • the dough of the preferred embodiments has been found to be cohesive and readily sheetable at high speed and the dough can be formed very quickly, even in a period as low as 3 seconds.
  • the sheetable dough provides that after frying, without requiring a preliminary oven or toasting step, and using a prefabricated commercially available corn mas a flour, the tortilla chips do not exhibit any significant number of cracks or through-holes.
  • the specific dough composition forms a continuous starch network from the initial cold water swelling starch, which has particles of corn masa distributed in the matrix. After cooking the tapioca starch expands and blisters are formed.
  • Such a dough is cohesive and readily sheetable, and in turn permits the formation of a uniform and regular distribution of blisters during the frying process, and the absence of cracks or though-holes in the resultant tortilla chips.
  • the present invention is least partly predicated on the finding by the present inventors that by providing a dough comprising a first starch-containing component which includes cold water swelling starch (for example a pre-gelatinized flour), a second starch-containing component which comprises substantially ungelatinized starch (for example tapioca and/or corn starch, such as cook-up starch), and a third starch-containing component which comprises corn masa flour and other minor ingredients, some of which may be corn-based, the dough can be formed, readily sheeted, cut into pieces and then fried. No toasting step is required and the dough does not need to comprise fresh corn.
  • a prefabricated dried corn masa flour can be employed to provide the entire corn masa component of the tortilla chip. No corn soaking steps are required in the dough and tortilla chip manufacturing lines.
  • the first starch-containing component includes cold water swelling starch which forms a gel matrix for the dough.
  • the cold water swelling starch has a peak viscosity at a temperature of less than 50 °C, when measured by a rapid viscosity analyser (RVA) in excess water having a weight of water which is 3 times the weight of the cold water swelling starch.
  • RVA rapid viscosity analyser
  • This can provide a cohesive sheetable dough that can be formed at a low temperature, for example at about room temperature or lower.
  • the dough is formed at a temperature below the gelation temperature of both the second starch-containing component which comprises substantially ungelatinized starch (for example tapioca and/or corn starch, such as cook-up starch), and the third starch- containing component which comprises corn masa flour.
  • the second starch-containing component has a peak viscosity at a temperature of from 50 to 80 °C, optionally from 60 to 70 °C, when measured by a rapid viscosity analyser (RVA) in excess water having a weight of water which is 3 times the weight of the second starch-containing component.
  • the third starch- containing component has a peak viscosity at a temperature of greater than 80 °C, when measured by a rapid viscosity analyser (RVA) in excess water having a weight of water which is 3 times the weight of the third starch-containing component.
  • the second starch-containing component has a peak RVA viscosity temperature below the peak RVA viscosity temperature of the corn masa
  • the second starch-containing component for example tapioca and/or corn starch, rapidly absorbs water from the dough at the elevated cooking temperature, gelatinizes and expands due to the generation of steam.
  • the second starch-containing component gelatinizes to form a continuous flexible starch matrix in which entrapped steam forms bubbles which cause expansion of the continuous flexible starch matrix.
  • the water absorption of the second starch-containing component occurs preferentiallv to the water absorption of the corn masa of the third starch-containing component, which has a higher peak RVA viscosity temperature, and so the water in the dough is absorbed by the second starch-containing component, leaving the corn masa of the third starch-containing component as particles dispersed throughout the starch matrix and having little or substantially no water absorption in the corn masa.
  • the gelatinization occurs throughout the dough to form an expanded starch matrix together with the first starch-containing component.
  • the expanded matrix forms a typical expanded and crunchy texture associated with tortilla chips.
  • the substantially uniform gelatinization provides a plurality of nucleation sites for steam generation as the dough is rapidly dehydrated during cooking.
  • the steam generated forms a substantially uniform array of a plurality of blisters, of substantially uniform size distribution, on opposite surfaces of the chip.
  • Steam generation does not tend to occur at the corn masa particles, which may otherwise cause a non-uniform blister morphology and may cause local stresses in the matrix which could form through-holes or cracks in the cooked chip.
  • the corn masa remains as particles which are substantially free of absorbed water and so does not form part of the starch matrix, but instead forms a substantially uniform distribution of particles in the matrix.
  • the corn masa particles can provide a tortilla chip taste and crunch to the chip.
  • a sheetable dough can be formed at low temperature and a snack food chip with a corn taste and mouthfeel characteristics, exhibiting a substantially uniform surface blistering and substantially without through-holes or cracks, can be manufactured.
  • the preferred embodiments of the present invention can further provide a method for manufacturing three-dimensionally shaped snack food chips, such as tortilla chips, which exhibit the desired blistering.
  • the shaped tortilla chips can be manufactured at low production costs as well as low capital expenditure.
  • the dough pieces can be shaped by a mould during the frying process.
  • the resultant tortilla chips may have any desired two dimensional plan shape, such as triangular, and any desired three dimensional shape, such as being regularly curved so that a plurality of the tortilla chips are mutually stackable.
  • the method or the present invention may be used to produce a variety of different snack food chip compositions, as well and shapes.
  • the snack food chip may comprise, in addition to corn masa, any cereal-based composition, and may comprise any of, any mixture of, or all of, wheat, barley, rice or any other grain-derived product, as well as any seasoning, either within the cereal-based composition and/or applied as a topical seasoning.
  • the snack food chips may be provided with other product design features to improve eating quality, for example particular flavourings or texturizing components.
  • the snack food chips may be provided in a consumer acceptable retail format, for example a packaging such as a bag or carton, typically hermetically sealed, which is compatible with a retail sales environment.
  • Figure 1 schematically illustrates a process flow of a method for manufacturing snack food chips in accordance with an embodiment of the present invention
  • Figure 2 schematically illustrates a cross-section of a snack food chip in accordance with an embodiment of the present invention
  • Figure 3 is a graph illustrating the variation of viscosity with time during RVA analysis for the first, second and third starch components used in accordance with an embodiment of the present invention.
  • FIG. 1 of the accompanying drawings there is shown a process flow of a method for manufacturing snack food chips, in particular tortilla chips, in accordance with an embodiment of the present invention.
  • a number of starch-containing components are provided. These comprise a first starch-containing component which includes cold water swelling starch, a second starch-containing component which comprises substantially ungelatinized starch, and a third starch-containing component which comprises corn masa flour.
  • the third starch-containing component may optionally further comprise at least one further corn ingredient, the further corn ingredient being selected from fresh corn masa, raw corn flour and cooked corn flour or any mixture of any two or more thereof.
  • the fresh corn masa may be added to enhance the corn taste of the chip, although then the additional fresh corn ingredient needs to be provided in the production line.
  • the corn masa typically has a moisture content of about 50 wt% based on the total weight of the corn masa.
  • the dough does not comprise a fresh corn masa ingredient, because the corn masa flour can provide a good corn taste, and the desired material properties in the dough and chip, and also because the provision of fresh corn can be avoided.
  • the raw corn flour and cooked corn flour can provide some corn taste at lower cost than corn masa and with reduced flavour as compared to corn masa.
  • Such further corn ingredients may, individually or cumulatively, be included in the dough in a weight amount which is less than the weight of the corn masa flour.
  • a dough is formed from a mixture of the first, second and third starch- containing components and added water.
  • the dough is typically formed by mixing together the first, second and third starch-containing components to form a dry mix, and then mixing the dry mix with added water, and preferably an emulsifier, to form the dough.
  • the dough is formed at a temperature of up to 30 °C, optionally from 5 to 20 °C, further optionally from 10 to 15 °C.
  • the dry mix has a moisture content of from 5 to 20 wt% water in the dry ingredients (i.e.
  • the dry mix is mixed with the added water, and optional emulsifier, to form the dough the dry mix has a temperature of from 5 to 30 °C, optionally from 5 to 25 °C, and the added water has a temperature of from 5 to 15 °C, optionally from 7 to 12 °C, further optionally from 8 to 1 1 °C.
  • the dry mix is mixed with the added water and emulsifier to form the dough for a period of from 3 to 30 seconds, typically from 5 to 30 seconds.
  • the dough comprises from 35 to 75 wt% corn masa flour, from 10 to 40 wt% of the second starch-containing component, and from 5 to 30 wt% of the first starch-containing component, each based upon the weight of the dry ingredients of the dough.
  • the cold water swelling starch of the first starch-containing component forms a gel matrix in the dough.
  • the dough preferably comprises from 5 to 20 wt%, more preferably from 10 to 15 wt%, typically about 12 wt%, of cold water swelling starch in the first starch-containing component, based upon the weight of the dry ingredients of the dough.
  • the first starch-containing component is selected from a pre-gelatinized cereal flour, a pre-gelatinized starch derivative, or any mixture thereof.
  • the component including cold water swelling starch may be at least one selected pre-gelatinized cereal flour selected from corn, wheat, barley, rice, spelt, or any other grain-derived product, or any mixture thereof.
  • the component including cold water swelling starch is a pre-gelatinized corn flour.
  • the dough preferably comprises from 15 to 30 wt%, more preferably from 20 to 30 wt%, typically about 25 wt%, of the second starch-containing component, based upon the weight of the dry ingredients of the dough.
  • the second starch-containing component is selected from tapioca starch and corn starch or a mixture thereof and preferably comprises tapioca cook-up starch and/or waxy corn cook-up starch.
  • the dough preferably comprises from 45 to 70 wt%, more preferably from 50 to 65 wt , corn masa flour, based upon the weight of the dry ingredients of the dough.
  • the corn masa flour has a particle size falling at least partly within the range extending from a fine particle corn masa, in which at most 30 wt% of the fine particle corn masa is retained on a 500 ⁇ sieve and at least 25 wt% of the fine particle corn masa passes through a 250 ⁇ sieve, to a coarse particle corn masa, in which at least 6 wt% of the coarse particle corn masa is retained on an 850 ⁇ sieve and at most 35 wt% of the coarse particle corn masa passes through a 250 ⁇ sieve.
  • the corn masa flour is a mixture of two flours having respective particle sizes.
  • the mixture comprises from 20 to 45 wt%, for example from 30 to 40 wt%, of a first corn masa and from 55 to 80 wt%, for example from 60 to 70 wt%, of a second corn masa, each wt% being based on the weight of the corn masa flour.
  • the first corn masa preferably has a particle size range in which 0 wt% of the first corn masa is retained on a 2000 ⁇ sieve, at most 11 wt% of the first corn masa is retained on an 841 ⁇ sieve and at most 32 wt% of the first corn masa passes through a 149 ⁇ sieve
  • the second corn masa preferably has a particle size range in which 0 wt% of the second corn masa is retained on a 2000 ⁇ sieve, at most 22 wt% of the second corn masa is retained on an 841 ⁇ sieve and at most 26 wt% of the second corn masa passes through a 149 ⁇ sieve.
  • the cold water swelling starch has a peak viscosity at a temperature of less than 50 °C.
  • the second starch-containing component has a peak viscosity at a temperature of from 50 to 80 °C, optionally from 60 to 70 °C.
  • the third starch-containing component has a peak viscosity at a temperature of greater than 80 °C. In each case, the viscosity is measured by a rapid viscosity analyser (RVA) in excess water having a weight of water which is 3 times the weight of the third starch-containing component.
  • RVA rapid viscosity analyser
  • Figure 3 is a graph illustrating the variation of viscosity with time during RVA analysis for the first, second and third starch components used in accordance with an embodiment of the present invention.
  • each of (i) the pregelatinized corn flour, (ii) the tapioca starch and (iii) the corn masa flour were individually subjected to RVA analysis.
  • the viscosity (left-hand y axis) was measured over time (x-axis) and the respective sample was subjected to the temperature profile indicated (right-hand y axis).
  • the pregelatinized corn flour has a viscosity peak when the temperature is below 50 °C
  • the tapioca starch has a viscosity peak when the temperature is above 50 °C and below 80 °C
  • the corn mas a flour has a viscosity peak when the temperature is above 80 °C (in fact, the corn masa did not peak even when the temperature profile attained a maximum temperature of 95 °C).
  • Each of these peaks is representative of the gelatinization temperature or peak water absorption of the respective starch.
  • the dough further comprises from 5 to 20 wt%, more preferably from 10 to 15 wt%, based upon the weight of the dry ingredients of the dough, of at least one cereal flour selected from wheat, barley, rice, spelt, or any other grain-derived product, or any mixture thereof.
  • cereal flour selected from wheat, barley, rice, spelt, or any other grain-derived product, or any mixture thereof.
  • Other ingredients known for use in snack food chips, in particular tortilla chips may be incorporated into the dough, typically into the dry mix.
  • the dough does not comprise a fresh corn masa ingredient.
  • the dough preferably comprises from 25 to 35 wt% added water, typically from 25 to 30 wt% added water, based on the weight of the dough.
  • the dough further comprises from 0.2 to 1 .5 wt%, more preferably from 0.2 to 0.5 wt% of an emulsifier, based on the weight of the dough.
  • the weight ratio of the added water: emulsifier in the dough is from 25: 1 to 200: 1, more preferably from 50: 1 to 150: 1 , yet more preferably from 75: 1 to 125: 1.
  • the emulsifier is adapted to bind to free starch and optionally comprises or is a monoglyceride- diglyceride emulsifier comprising a mixture of at least one monoglyceride and at least one diglyceride, optionally the monoglyceride-diglyceride emulsifier comprising or consisting of a food additive having E-number E471.
  • the monoglyceride-diglyceride emulsifier may be added to the dough as a liquid or, less preferably, as a solid, and when added as a liquid is optionally melted (for example at a temperature of about 55 °C) or then mixed with a vegetable oil, such as rapeseed oil or sunflower oil, in particular high oleic acid sunflower oil (HOSO), and the liquid emulsifier/oil mixture is then added to the dough.
  • a vegetable oil such as rapeseed oil or sunflower oil, in particular high oleic acid sunflower oil (HOSO)
  • HOSO high oleic acid sunflower oil
  • the monoglyceride component functions to complex to the free starch, which controls blister formation and the diglyceride component functions to reduce the melting temperature of the monoglyceride-diglyceride emulsifier so that it can more readily be added in the form of a liquid.
  • the monoglyceride component is provided in a concentration which is sufficiently high to control blister formation but not so high that so much free starch has been complexed that there is insufficient free starch remaining in the dough for expansion of the second starch-containing component, for example tapioca starch, to cause expansion of the starch matrix during frying.
  • a dough sheet is formed from the dough and then in a fourth step 8 a plurality of dough pieces are cut from the dough sheet.
  • the dough pieces Preferably, the dough pieces have a thickness of from 0.5 to 1.5 mm, typically from 0.6 to 1 mm.
  • the dough sheet is formed in a sheeting apparatus at a linear speed for the sheet of from 20 to 60 linear metres/minute, optionally from 30 to 50 linear metres/minute.
  • High speed sheeting to form a thin dough sheet is possible because the dough has high cohesiveness, and does not rip, tear or form holes during sheeting. This is a very high speed sheeting operation as compared to the typical manufacture of tortilla chips of similar sheet thickness since traditional tortilla chip dough, including a high proportion of fresh corn masa, has low cohesion, and so linear sheet speeds are typically only 15 linear metres/minute or less.
  • the dough pieces are two-dimensionally pre-shaped, and cut into desired two-dimensional shape and dimensions.
  • the dough pieces are typically substantially planar and flexible.
  • the dough pieces may be regularly shaped, for example being triangular, square, rectangular, elliptical, etc., or be irregularly shaped.
  • the dough pieces have a surface area of from 1000 to 2500 mm 2 and a maximum dimension of from 30 to 100 mm.
  • the dough pieces are cooked to form a plurality of snack food chips.
  • the cooking comprises or consists of frying and the frying temperature is from 160 to 200 °C, optionally from 170 to 190 °C, further optionally about 180 °C.
  • the frying time is from 15 to 30 seconds, optionally from 16 to 25 seconds, further optionally from 18 to 23 seconds.
  • the cooking consists of frying and there is no toasting step prior to the frying step.
  • other cooking techniques apart from frying such as baking, microwaving, etc. may be used instead of frying.
  • the dough pieces may be shaped against a mould during frying so that the snack food chips are three-dimerisionally shaped with a preset shape, for example as disclosed in US-A- 2008/0044534.
  • the snack food chips made according to the present invention may be shaped and dimensioned so as to be suitable for use together with a dip, such as a salsa composition, cream cheese, avocado composition, etc. which are well known in the snack food art.
  • the shaped dough pieces may be conveyed through a proving chamber in which the shaped dough pieces are subjected to controlled temperature and humidity to prove the dough prior to cooking, as is generally known to those skilled in the art of making tortilla chips.
  • the first starch-containing component includes cold water swelling starch which forms a gel matrix for the dough to provide a sheetable dough that can be formed at a low temperature, for example at about room temperature or lower.
  • an emulsifier is present in the dough which is adapted to bind to free starch.
  • the emulsifier comprises or is a monoglyceride-diglyceride emulsifier comprising a mixture of at least one monoglyceride and at least one diglyceride, optionally the monoglyceride-diglyceride emulsifier comprising or consisting of a food additive having E- number E471.
  • the emulsifier can mop up and bind to free starch in the dough. The lower the free starch, the lower the expansion on frying and the lower the blister formation.
  • the monoglyceride-diglyceride emulsifier therefore can control the level of expansion and blistering.
  • the second starch-containing component for example, tapioca starch, is uniformly distributed throughout the starch matrix, which in turn enhances the uniform formation of blisters during cooking.
  • the cold water swelling starch is the only starch component of the first, second and third starch components which absorbs water prior to cooking of the dough.
  • the second, cook-up, starch for example tapioca starch, starts to absorb water because it has a higher peak viscosity RVA temperature than the cold water swelling starch but a lower peak viscosity RVA temperature than the corn masa.
  • the corn masa therefore does not absorb water because the water is preferentially absorbed by the tapioca starch.
  • the dough is cooked, the dough is heated to a temperature above the peak viscosity RVA temperatures of both of the second and third starch-containing components.
  • the second starch-containing component When the second starch-containing component has a peak viscosity RVA temperature below the peak viscosity RVA temperature of the corn masa, the second starch-containing component, for example tapioca and/or corn starch, rapidly absorbs water from the dough at the elevated cooking temperature, gelatinizes and expands in volume due to the generation of steam.
  • the gelatinization of the second starch-containing component occurs preferentially to the viscosity increase of the corn masa of the third starch- containing component, which has a higher peak viscosity RVA temperature, and so the water in the dough is absorbed by the second starch-containing component, leaving the corn masa of the third starch-containing component substantially unincreased in viscosity and with low water absorption.
  • the corn masa forms a substantially uniform distribution of particles in the starch matrix.
  • the corn masa particles can provide a tortilla chip taste and crunch to the chip.
  • the gelatinization occurs throughout the dough to form an expanded starch matrix together with the first starch-containing component.
  • the expanded matrix forms a light and crunchy texture.
  • the substantially uniform gelatinization provides a plurality of nucleation sites for steam generation as the dough is rapidly dehydrated during cooking.
  • the steam generated forms a substantially uniform array of a plurality of blisters, of substantially uniform size distribution, on opposite surfaces of the chip. Steam generation does not tend to occur at the corn masa particles, which may otherwise cause a non-uniform blister morphology and may cause local stresses in the matrix which could form through-holes or cracks in the cooked chip.
  • the resultant snack food chip 20 preferably a tortilla chip, comprises a starch matrix 22 composed of at least one gelatinized and expanded starch, and a plurality of particles 24 distributed in the starch matrix 24.
  • the particles 24 are composed of a third starch-containing component which comprises corn masa which is substantially ungelatinized.
  • the starch matrix 22 forms a continuous wall 26 without through- holes or cracks extending therethrough.
  • the snack food chip 20 has a wall thickness of from 0.5 to 1.5 mm.
  • the snack food chip 20 has having opposite major surfaces 28, 30 which have a plurality of blisters 32 thereon, each blister 32 extending outwardly on both opposite major surfaces 28, 30.
  • the blisters can readily be detected visually using the naked eye, because of their size.
  • the blisters are aesthetically pleasing on the surfaces of a tortilla chip.
  • the maximum width dimension is typically 1.2 mm and the minimum width dimension is typically 0.5 mm (any smaller sized blisters are essentially not visible to the naked eye).
  • the total number of the various sizes of blisters can readily be detected using a 3-D scanner and a blister number per unit area can be calculated. Since each blister extends outwardly on both surfaces, the blister number per unit area is the number per unit area of one surface of the chip.
  • the blisters 32 have a mean total number of blisters per cm 2 of the opposite major surfaces 28, 30 of from 0.92 to 1.20, preferably from 1.00 to 1.20, with the blisters 32 having a maximum width of 1.2 mm.
  • the blisters 32 include a mean total number of blisters 32 having a maximum width of less than 0.5 mm of from 0.63 to 0.83, preferably from 0.68 to 0.78, blisters per cm 2 , and a mean total number of blisters 32 having a maximum width of from 0.5 to 1.2 mm of from 0.25 to 0.43, preferably from 0.30 to 0.38, blisters per cm 2 .
  • more than 90% by number have a continuous wall 26 without through-holes or cracks extending therethrough.
  • Example 1 produced a tortilla chip using the ingredients listed in Table 1.
  • Example 1 as listed in Table 1 the ingredients of the dry mixture, namely the flour components comprising corn masa flour and, as a cold water selling starch, the pregelatinized corn flour, the dry additives comprising tapioca starch, black bean flake and dry sunflower lecithin, were mixed to form a dry mixture.
  • the ingredients of the dry mixture namely the flour components comprising corn masa flour and, as a cold water selling starch, the pregelatinized corn flour, the dry additives comprising tapioca starch, black bean flake and dry sunflower lecithin, were mixed to form a dry mixture.
  • an emulsifier ingredient was formed by melting a monoglyceride-diglyceride emulsifier, in particular E471 , by heating the solid emulsifier at a temperature of 55 °C, and then mixing the molten emulsifier with rapeseed oil.
  • the emulsifier ingredient comprised 50 wt% monoglyceride-diglyceride emulsifier and 50 wt% in rapeseed oil, each based on the weight of the emulsifier ingredient.
  • the dry mixture and the emulsifier ingredient were mixed together with the added water to form a dough.
  • the dry mixture has a temperature of 20 to 25 °C
  • the added water had a temperature of 2 to 10 °C
  • the resultant dough mixture was formed at a temperature of 10 to 15 °C.
  • the dough was mixed for less than 5 seconds.
  • the resultant dough was sheeted through a dough sheeter to a thickness of 0.7 mm.
  • the dough sheet was formed in a sheeting apparatus at a linear speed for the sheet of from 30 to 50 linear metres/minute.
  • the dough sheet was cut into triangular tortilla chip-shaped dough pieces which were then fried in sunflower oil at 185 °C for a period of about 25 seconds, and then topically seasoned.
  • the resultant tortilla chips had a moisture content of 1.5 to 2.0 wt%, based on the total weight of the tortilla chips.
  • the resultant tortilla chips had a crispy and crunchy texture.
  • the opposite surfaces of the tortilla chips had a uniform distribution of blisters.
  • the blisters are formed by steam which is rapidly generated during the frying process. Without being bound by any theory, it is believed that the steam is formed substantially uniformly throughout the dough matrix because the ungelatinized corn masa particles act as initiation points from steam formation. Since there is a uniform distribution of corn masa particles throughout the dough, the steam generation is correspondingly uniform, and a large number of substantially similar-sized blisters is formed on the surfaces of the chip.
  • the pregelatinized corn flour and the tapioca starch provide a starch matrix which is gelatinized in the frying process, and the starch matrix can be substantially uniformly deformed to form the distribution of blisters.
  • the liquid emulsifier in the starch matrix is also believed to assist in achieving a uniform blister distribution and an expanded starch matrix in the resultant tortilla chip.
  • the tortilla chip also did not exhibit any holes or cracks extending through the thickness of the tortilla chip.
  • the tortilla chips had a good corn taste.
  • the corn masa flour was a mixture of two flours having respective particle sizes.
  • the corn masa comprised 65% of finer corn masa flour, the US #2 corn masa flour, and 35% of coarser corn masa flour, the US #9 corn masa flour, each based on the weight of the corn masa flour.
  • the finer corn masa flour had a particle size range in which 0 wt% of the corn masa is retained on a 2000 ⁇ sieve, at most 1 1 wt% of the corn masa is retained on an 841 ⁇ sieve and at most 32 wt% of the corn masa passes through a 149 ⁇ sieve.
  • the coarser corn masa flour had a particle size range in which 0 wt% of the corn masa is retained on a 2000 ⁇ sieve, at most 22 wt% of the corn masa is retained on an 841 ⁇ sieve and at most 26 wt% of the corn masa passes through a 149 ⁇ sieve.
  • the corn masa flour and the liquid emulsifier were both found to control the amount and uniformity of blistering on the surface of the tortilla chips. It was found that increasing the proportion and amount of coarse corn masa flour particles tended to increase the uniformity of blistering and a reduction in the occurrence of individual large blisters. The liquid emulsifier tended to increase the uniformity of blistering on the surface of the tortilla chips.
  • the black bean flake component which is known for use in tortilla chips, was added to provide a distribution of fine back particles in the tortilla chips to provide increases texture and visual contrast.
  • the dry sunflower lecithin was added to assist release of the sheet from the sheeting rolls.
  • Example 2 produced a tortilla chip using the ingredients listed in Table 1. The processing was as set out above for Example 1.
  • the tortilla chip had a good level of blistering, but slightly less uniform, generally larger and with a reduced number per unit area as compared to Example 1. It is believed that the reduced concentration of the coarser corn masa flour led to the reduced blister uniformity in size and distribution.
  • Example 3 produced a tortilla chip using the ingredients listed in Table 1. The processing was as set out above for Example 1. The tortilla chip had a good level of blistering, but less uniform, generally larger and with a reduced number per unit area as compared to Example 1.
  • Example 4 produced a tortilla chip using the ingredients listed in Table 1. The processing was as set out above for Example 1.
  • the tortilla chip had a uniform mid-size blisters, but less uniform, generally larger and with a reduced number per unit area as compared to Example 3. Also, the chip matrix was less expanded as compared to Example 3, which is believed to result from a lower concentration of tapioca starch in the dough.
  • Example 5 produced a tortilla chip using the ingredients listed in Table 1.
  • the processing was as set out above for Example 1.
  • the tortilla chip had some blisters, but reduced as compared to Example 3.
  • the chip matrix was less expanded as compared to Example 3, even with a slightly higher concentration of liquid emulsifier in the dough, which lower expansion is believed to result from a lower water: liquid emulsifier weight ratio of 25: 1 as compared to 33: 1 for Example 3.
  • Comparative Example 1 produced a tortilla chip using the ingredients listed in Table 1. The processing was as set out above for Example 1. The recipe excluded tapioca starch. The tortilla chip had a poorly expanded matrix, which was unacceptable.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Food Science & Technology (AREA)
  • Health & Medical Sciences (AREA)
  • Nutrition Science (AREA)
  • Polymers & Plastics (AREA)
  • Dispersion Chemistry (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Confectionery (AREA)
  • Bakery Products And Manufacturing Methods Therefor (AREA)
EP17780408.5A 2016-10-06 2017-10-06 Manufacture of snack food chips Pending EP3509433A1 (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US201662405007P 2016-10-06 2016-10-06
GB1701530.6A GB2554775B (en) 2016-10-06 2017-01-31 Manufacture of snack food chips
PCT/EP2017/075475 WO2018065573A1 (en) 2016-10-06 2017-10-06 Manufacture of snack food chips

Publications (1)

Publication Number Publication Date
EP3509433A1 true EP3509433A1 (en) 2019-07-17

Family

ID=58462811

Family Applications (1)

Application Number Title Priority Date Filing Date
EP17780408.5A Pending EP3509433A1 (en) 2016-10-06 2017-10-06 Manufacture of snack food chips

Country Status (7)

Country Link
EP (1) EP3509433A1 (es)
CN (1) CN110035666A (es)
AU (1) AU2017339555B2 (es)
CA (1) CA3039315C (es)
GB (1) GB2554775B (es)
MX (1) MX2019004022A (es)
WO (1) WO2018065573A1 (es)

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US10231462B2 (en) 2016-11-15 2019-03-19 Gruma S.A.B. De C.V. Comestible product sheeter and sheeter roller, and method of using the same
CN110024947B (zh) * 2019-05-20 2021-12-28 安徽正宇面粉有限公司 一种保健即食面粉及其生产工艺

Family Cites Families (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0267322A1 (en) * 1985-05-09 1988-05-18 Miles Jamison Willard Method of preparing fried snack products from corn and other cereal flours
US4623548A (en) * 1985-05-09 1986-11-18 Willard Miles J Method for preparing extruded fried snack products from corn and other cereal flours
US4770891A (en) * 1986-01-20 1988-09-13 Willard Miles J Method for preparing sheeted fried snack products
US4931303A (en) * 1988-01-15 1990-06-05 Miles J. Willard Method for controlling the surface bubbling of fabricated snack products
EP0915666B1 (en) * 1996-07-01 2002-09-18 The Procter & Gamble Company Dough compositions
US6217921B1 (en) * 1998-07-24 2001-04-17 The Procter & Gamble Company Coated low-fat and fat-free snack food products and method to prepare the same
US20020018837A1 (en) * 2000-05-27 2002-02-14 Lanner David Arthur Dough for making tortilla chips with controlled surface bubbling
US6572910B2 (en) * 2000-05-27 2003-06-03 The Procter & Gamble Co. Process for making tortilla chips with controlled surface bubbling
US20060034988A1 (en) * 2004-08-16 2006-02-16 Bresnahan Steven A Method for sheeting and processing dough

Also Published As

Publication number Publication date
GB2554775A (en) 2018-04-11
WO2018065573A1 (en) 2018-04-12
GB201701530D0 (en) 2017-03-15
CA3039315A1 (en) 2018-04-12
MX2019004022A (es) 2019-07-08
AU2017339555A1 (en) 2019-05-02
GB2554775B (en) 2020-06-17
CN110035666A (zh) 2019-07-19
AU2017339555B2 (en) 2021-10-21
CA3039315C (en) 2024-06-11

Similar Documents

Publication Publication Date Title
US6491959B1 (en) Production of crispy corn-based snacks having surface bubbles
US5429834A (en) Production of chip-like starch based snacks
US4844919A (en) Concave shaped snack food and process for preparing same
AU603680B2 (en) Extruded starch snack foods and process
US5104673A (en) Extruded starch snack foods
AU768967B2 (en) Process for producing sheetable potato dough from raw potato stock
JP4505458B2 (ja) 米粉組成物
MX2009001246A (es) Composiciones de bocadillos bajos en grasa.
US4950490A (en) Taco shell and method of manufacture
WO2017167644A1 (en) Snack food and manufacture thereof
KR102473568B1 (ko) 분말 베이스 식품의 제조방법 및 이것에 의해 제조된 식품
AU2017339555B2 (en) Manufacture of snack food chips
AU2021245216B2 (en) Snack food chips
AU2017339559B2 (en) Manufacture of snack food chips
EP1249178B1 (en) Process for producing a new appetizer and product by process of the same
JPH0418815B2 (es)
AU2005251705A1 (en) Method for maintaining designed functional shape

Legal Events

Date Code Title Description
STAA Information on the status of an ep patent application or granted ep patent

Free format text: STATUS: UNKNOWN

STAA Information on the status of an ep patent application or granted ep patent

Free format text: STATUS: THE INTERNATIONAL PUBLICATION HAS BEEN MADE

PUAI Public reference made under article 153(3) epc to a published international application that has entered the european phase

Free format text: ORIGINAL CODE: 0009012

STAA Information on the status of an ep patent application or granted ep patent

Free format text: STATUS: REQUEST FOR EXAMINATION WAS MADE

17P Request for examination filed

Effective date: 20190410

AK Designated contracting states

Kind code of ref document: A1

Designated state(s): AL AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HR HU IE IS IT LI LT LU LV MC MK MT NL NO PL PT RO RS SE SI SK SM TR

AX Request for extension of the european patent

Extension state: BA ME

DAV Request for validation of the european patent (deleted)
DAX Request for extension of the european patent (deleted)
STAA Information on the status of an ep patent application or granted ep patent

Free format text: STATUS: EXAMINATION IS IN PROGRESS

17Q First examination report despatched

Effective date: 20200421

STAA Information on the status of an ep patent application or granted ep patent

Free format text: STATUS: EXAMINATION IS IN PROGRESS

STAA Information on the status of an ep patent application or granted ep patent

Free format text: STATUS: EXAMINATION IS IN PROGRESS

P01 Opt-out of the competence of the unified patent court (upc) registered

Effective date: 20230518