EP3478809A1 - Solvent composition and process for removal of asphalt and other contaminant materials - Google Patents
Solvent composition and process for removal of asphalt and other contaminant materialsInfo
- Publication number
- EP3478809A1 EP3478809A1 EP17821281.7A EP17821281A EP3478809A1 EP 3478809 A1 EP3478809 A1 EP 3478809A1 EP 17821281 A EP17821281 A EP 17821281A EP 3478809 A1 EP3478809 A1 EP 3478809A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- solvent composition
- solvent
- composition
- cationic surfactant
- contaminant material
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
- 239000002904 solvent Substances 0.000 title claims abstract description 195
- 239000000203 mixture Substances 0.000 title claims abstract description 157
- 239000000463 material Substances 0.000 title claims abstract description 81
- 239000000356 contaminant Substances 0.000 title claims abstract description 79
- 238000000034 method Methods 0.000 title claims abstract description 39
- 239000010426 asphalt Substances 0.000 title description 24
- IAZDPXIOMUYVGZ-UHFFFAOYSA-N Dimethylsulphoxide Chemical compound CS(C)=O IAZDPXIOMUYVGZ-UHFFFAOYSA-N 0.000 claims abstract description 38
- 239000003093 cationic surfactant Substances 0.000 claims abstract description 34
- 239000000010 aprotic solvent Substances 0.000 claims abstract description 28
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims abstract description 13
- 239000002270 dispersing agent Substances 0.000 claims description 18
- SZXQTJUDPRGNJN-UHFFFAOYSA-N dipropylene glycol Chemical compound OCCCOCCCO SZXQTJUDPRGNJN-UHFFFAOYSA-N 0.000 claims description 16
- KBWINQAOGFKEEX-UHFFFAOYSA-M 2-[1-ethyl-2-(16-methylheptadecyl)-4,5-dihydroimidazol-1-ium-1-yl]ethanol;ethyl sulfate Chemical compound CCOS([O-])(=O)=O.OCC[N+]1(CC)CCN=C1CCCCCCCCCCCCCCCC(C)C KBWINQAOGFKEEX-UHFFFAOYSA-M 0.000 claims description 7
- 150000003242 quaternary ammonium salts Chemical class 0.000 claims description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 16
- 239000003085 diluting agent Substances 0.000 description 14
- 229930195733 hydrocarbon Natural products 0.000 description 13
- 150000002430 hydrocarbons Chemical class 0.000 description 13
- SECXISVLQFMRJM-UHFFFAOYSA-N N-Methylpyrrolidone Chemical compound CN1CCCC1=O SECXISVLQFMRJM-UHFFFAOYSA-N 0.000 description 12
- 238000012360 testing method Methods 0.000 description 11
- 230000008901 benefit Effects 0.000 description 10
- 238000004090 dissolution Methods 0.000 description 10
- 239000004215 Carbon black (E152) Substances 0.000 description 9
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 8
- 239000000047 product Substances 0.000 description 7
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 6
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 description 6
- 238000013019 agitation Methods 0.000 description 6
- 238000013459 approach Methods 0.000 description 6
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 6
- 238000002156 mixing Methods 0.000 description 6
- -1 etc.) Substances 0.000 description 5
- 239000003921 oil Substances 0.000 description 5
- 238000012545 processing Methods 0.000 description 5
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 4
- 239000010779 crude oil Substances 0.000 description 4
- 239000003960 organic solvent Substances 0.000 description 4
- LPXPTNMVRIOKMN-UHFFFAOYSA-M sodium nitrite Chemical compound [Na+].[O-]N=O LPXPTNMVRIOKMN-UHFFFAOYSA-M 0.000 description 4
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 3
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 3
- 238000004140 cleaning Methods 0.000 description 3
- 238000001816 cooling Methods 0.000 description 3
- 150000002148 esters Chemical class 0.000 description 3
- 238000002474 experimental method Methods 0.000 description 3
- 239000000295 fuel oil Substances 0.000 description 3
- 239000003345 natural gas Substances 0.000 description 3
- 238000005507 spraying Methods 0.000 description 3
- 238000011179 visual inspection Methods 0.000 description 3
- KBPLFHHGFOOTCA-UHFFFAOYSA-N 1-Octanol Chemical compound CCCCCCCCO KBPLFHHGFOOTCA-UHFFFAOYSA-N 0.000 description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 2
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 2
- 239000000654 additive Substances 0.000 description 2
- 150000001298 alcohols Chemical class 0.000 description 2
- 125000003118 aryl group Chemical group 0.000 description 2
- 239000003225 biodiesel Substances 0.000 description 2
- 238000009835 boiling Methods 0.000 description 2
- 239000003575 carbonaceous material Substances 0.000 description 2
- 239000000571 coke Substances 0.000 description 2
- 230000002950 deficient Effects 0.000 description 2
- 239000002283 diesel fuel Substances 0.000 description 2
- 238000004821 distillation Methods 0.000 description 2
- LQZZUXJYWNFBMV-UHFFFAOYSA-N dodecan-1-ol Chemical compound CCCCCCCCCCCCO LQZZUXJYWNFBMV-UHFFFAOYSA-N 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 239000000839 emulsion Substances 0.000 description 2
- 239000012530 fluid Substances 0.000 description 2
- WSFSSNUMVMOOMR-UHFFFAOYSA-N formaldehyde Natural products O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 2
- 238000007710 freezing Methods 0.000 description 2
- 230000008014 freezing Effects 0.000 description 2
- 239000001257 hydrogen Substances 0.000 description 2
- 229910052739 hydrogen Inorganic materials 0.000 description 2
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 2
- 239000003208 petroleum Substances 0.000 description 2
- 238000007790 scraping Methods 0.000 description 2
- 235000010288 sodium nitrite Nutrition 0.000 description 2
- 239000011269 tar Substances 0.000 description 2
- 238000005303 weighing Methods 0.000 description 2
- VBICKXHEKHSIBG-UHFFFAOYSA-N 1-monostearoylglycerol Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCC(O)CO VBICKXHEKHSIBG-UHFFFAOYSA-N 0.000 description 1
- RFVNOJDQRGSOEL-UHFFFAOYSA-N 2-hydroxyethyl octadecanoate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCCO RFVNOJDQRGSOEL-UHFFFAOYSA-N 0.000 description 1
- LZZYPRNAOMGNLH-UHFFFAOYSA-M Cetrimonium bromide Chemical compound [Br-].CCCCCCCCCCCCCCCC[N+](C)(C)C LZZYPRNAOMGNLH-UHFFFAOYSA-M 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
- 241000207199 Citrus Species 0.000 description 1
- JDRSMPFHFNXQRB-CMTNHCDUSA-N Decyl beta-D-threo-hexopyranoside Chemical compound CCCCCCCCCCO[C@@H]1O[C@H](CO)C(O)[C@H](O)C1O JDRSMPFHFNXQRB-CMTNHCDUSA-N 0.000 description 1
- 241000196324 Embryophyta Species 0.000 description 1
- YNAVUWVOSKDBBP-UHFFFAOYSA-N Morpholine Chemical class C1COCCN1 YNAVUWVOSKDBBP-UHFFFAOYSA-N 0.000 description 1
- 241000779819 Syncarpia glomulifera Species 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 125000005210 alkyl ammonium group Chemical group 0.000 description 1
- OGBUMNBNEWYMNJ-UHFFFAOYSA-N batilol Chemical class CCCCCCCCCCCCCCCCCCOCC(O)CO OGBUMNBNEWYMNJ-UHFFFAOYSA-N 0.000 description 1
- 238000006065 biodegradation reaction Methods 0.000 description 1
- 239000006227 byproduct Substances 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 230000003197 catalytic effect Effects 0.000 description 1
- 235000020971 citrus fruits Nutrition 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 235000009508 confectionery Nutrition 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 238000011109 contamination Methods 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 229940073499 decyl glucoside Drugs 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- 239000003599 detergent Substances 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 1
- 238000004945 emulsification Methods 0.000 description 1
- 229930195729 fatty acid Natural products 0.000 description 1
- 239000000194 fatty acid Substances 0.000 description 1
- 150000004665 fatty acids Chemical class 0.000 description 1
- 230000009969 flowable effect Effects 0.000 description 1
- 230000004907 flux Effects 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 239000012634 fragment Substances 0.000 description 1
- 239000003502 gasoline Substances 0.000 description 1
- 229930182478 glucoside Natural products 0.000 description 1
- 229940075529 glyceryl stearate Drugs 0.000 description 1
- 229940100242 glycol stearate Drugs 0.000 description 1
- 150000002334 glycols Chemical class 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 125000000623 heterocyclic group Chemical group 0.000 description 1
- 150000002460 imidazoles Chemical class 0.000 description 1
- GJRQTCIYDGXPES-UHFFFAOYSA-N iso-butyl acetate Natural products CC(C)COC(C)=O GJRQTCIYDGXPES-UHFFFAOYSA-N 0.000 description 1
- FGKJLKRYENPLQH-UHFFFAOYSA-M isocaproate Chemical compound CC(C)CCC([O-])=O FGKJLKRYENPLQH-UHFFFAOYSA-M 0.000 description 1
- OQAGVSWESNCJJT-UHFFFAOYSA-N isovaleric acid methyl ester Natural products COC(=O)CC(C)C OQAGVSWESNCJJT-UHFFFAOYSA-N 0.000 description 1
- 150000002576 ketones Chemical class 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 231100000053 low toxicity Toxicity 0.000 description 1
- 239000010687 lubricating oil Substances 0.000 description 1
- PSZYNBSKGUBXEH-UHFFFAOYSA-M naphthalene-1-sulfonate Chemical compound C1=CC=C2C(S(=O)(=O)[O-])=CC=CC2=C1 PSZYNBSKGUBXEH-UHFFFAOYSA-M 0.000 description 1
- CTQNGGLPUBDAKN-UHFFFAOYSA-N o-dimethylbenzene Natural products CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 1
- 235000011837 pasties Nutrition 0.000 description 1
- 239000001739 pinus spp. Substances 0.000 description 1
- 229920000059 polyethylene glycol stearate Polymers 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 239000001294 propane Substances 0.000 description 1
- 238000005086 pumping Methods 0.000 description 1
- 150000003222 pyridines Chemical class 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- 238000004064 recycling Methods 0.000 description 1
- 238000005201 scrubbing Methods 0.000 description 1
- 239000010802 sludge Substances 0.000 description 1
- SFVFIFLLYFPGHH-UHFFFAOYSA-M stearalkonium chloride Chemical compound [Cl-].CCCCCCCCCCCCCCCCCC[N+](C)(C)CC1=CC=CC=C1 SFVFIFLLYFPGHH-UHFFFAOYSA-M 0.000 description 1
- 229940057981 stearalkonium chloride Drugs 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 229940036248 turpentine Drugs 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B08—CLEANING
- B08B—CLEANING IN GENERAL; PREVENTION OF FOULING IN GENERAL
- B08B3/00—Cleaning by methods involving the use or presence of liquid or steam
- B08B3/04—Cleaning involving contact with liquid
- B08B3/08—Cleaning involving contact with liquid the liquid having chemical or dissolving effect
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/38—Cationic compounds
- C11D1/62—Quaternary ammonium compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2093—Esters; Carbonates
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/43—Solvents
-
- C11D2111/20—
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2068—Ethers
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/34—Organic compounds containing sulfur
- C11D3/3445—Organic compounds containing sulfur containing sulfino groups, e.g. dimethyl sulfoxide
Definitions
- This invention relates to the field of industrial facility cleanup and more specifically to the disaggregation and subsequent removal of asphalt and other contaminant materials from industrial equipment.
- contaminant materials such as asphalt, heavy asphaltenic materials, hydrogen-deficient carbonaceous materials, coke, tar, and the like may be produced as byproducts. These contaminant materials may contaminate vessels, tanks, or other types of industrial equipment. The contamination of industrial equipment may lead to problems such as increased downtime or poor processing results.
- Such conventional approaches may provide various drawbacks. For instance, citrus- derived water products may form emulsions and thus may require emulsion breakers. Water-based products may require extensive separatory effort if any of the hydrocarbons are to be recovered for recycling processes. Additionally, some water-based products may also require a solvent pretreatment to initiate the dissolution of the contaminant materials. Petroleum fractions may be highly flammable and also not easily rinsable with water. Freezing and scraping methods may require additional workers and may only be used in vessels that are accessible to and are safe for those workers. Finally, many of these same approaches are not biodegradable. The lack of biodegradability limits not only the applications for which an approach may be used, but also the operation sites in which it may be used.
- a method for removing contaminant material from industrial equipment comprising: providing a solvent composition comprising methyl soyate, an aprotic solvent (i.e., dimethyl sulfoxide), an additional solvent, and a cationic surfactant; contacting the contaminant material with the solvent composition; and allowing the solvent composition to react with the contaminant material such that at least a portion of the contaminant material is no longer attached to the industrial equipment.
- a solvent composition comprising: providing a solvent composition comprising methyl soyate, an aprotic solvent (i.e., dimethyl sulfoxide), an additional solvent, and a cationic surfactant; contacting the contaminant material with the solvent composition; and allowing the solvent composition to react with the contaminant material such that at least a portion of the contaminant material is no longer attached to the industrial equipment.
- a solvent composition comprising: methyl soyate, an aprotic solvent (i.e., dimethyl sulfoxide), an additional solvent, and a cationic surfactant.
- a solvent composition comprises a mixture of three solvents and a cationic surfactant.
- the first solvent is methyl soyate.
- the second solvent is an aprotic solvent (i.e., dimethyl sulfoxide).
- the third solvent may be any solvent suitable for maintaining the cationic surfactant in solution (e.g., alcohols, esters, ketones, and the like).
- the solvent composition may disaggregate and/or dissolve contaminant materials from industrial equipment in industrial facilities (e.g., oil refineries, natural gas processing plants, petrochemical facilities, port terminals, and the like).
- the solvent composition may be used to remove a contaminant material from any industrial equipment used in industrial facilities including vessels, tanks, vacuum towers, heat exchangers, piping, distillation columns, and the like.
- contaminant materials to be removed may include any contaminant material produced, stored, transported, or the like during the process of crude oil refinement, natural gas processing, hydrocarbon transport, hydrocarbon processing, hydrocarbon cleanup, and the like.
- examples of contaminant materials include asphalt, heavy asphaltenic materials, hydrogen-deficient carbonaceous materials, coke, tar, heavy oil deposits, hydrocarbon sludge, lube oil, the like, or any combinations thereof.
- the contaminant materials are contacted with the solvent composition, such that the contaminant materials are disaggregated and/or dissolved and may then be subsequently removed from industrial equipment.
- Embodiments of the solvent composition comprise the solvent methyl soyate (MESO).
- MESO is a biodegradable long-chain esterified fatty acid.
- the solvent composition may have any wt.% of MESO suitable for disaggregating and/or dissolving contaminant materials such that at least a portion of a contaminant material may be removed from industrial equipment. For instance, the contaminant material may be removed from the surface of industrial equipment.
- the solvent composition has between about 20.0 wt. % MESO and about 40.0 wt. % MESO, alternatively between about 25.0 wt. % MESO and about 35.0 wt. % MESO.
- the MESO may comprise about 30.0 wt. % of the solvent composition. With the benefit of this disclosure, one of ordinary skill in the art will be able to select an appropriate amount of MESO for a chosen application.
- Embodiments of the solvent composition comprise an aprotic solvent.
- Aprotic solvents include any solvents that neither donate protons nor accept protons.
- Aprotic solvents include dimethyl sulfoxide (DMSO), N-methylpyrrolidone (NMP), dimethyl formamide, benzene, or any combinations thereof.
- the aprotic solvent is DMSO.
- the aprotic solvent is DMSO and does not include any or substantially any NMP, benzene, and/or dimethyl formamide.
- the solvent composition may have any wt. % of aprotic solvent suitable for disaggregating and/or dissolving contaminant materials such that at least a portion of a contaminant material may be removed from industrial equipment.
- the solvent composition has between about 20.0 wt.% aprotic solvent (i.e., DMSO) and about 50.0 wt. % aprotic solvent (i.e., DMSO), alternatively between about 25.0 wt.% aprotic solvent (i.e., DMSO) and about 35.0 wt. % aprotic solvent (i.e., DMSO).
- the aprotic solvent i.e., DMSO
- Embodiments of the solvent composition comprise a third solvent (TS).
- the third solvent may be any solvent, or combination of solvents, suitable for maintaining the cationic surfactant in solution and/or for lowering the surface tension of the solvent composition. Without limitation, the third solvent facilitates the contaminant material removal process.
- the TS may be an alcohol, an ester, ether, the like, or any combinations thereof.
- the alcohol may include dipropylene glycol, propylene glycol, simple alcohols ranging from C 8 to Ci 8 (e.g., octanol, dodecanol), the like, or any combinations thereof.
- the ester may include ethyl acetate, isobutyl acetate, glycol esters (e.g., glycol stearate, monoglycerides such as glyceryl stearate, and the like), the like, or any combinations thereof.
- the ether may include a glycol such as dipropylene glycol, or an alkyl glucoside such as decyl glucoside, the like or any combinations thereof.
- the TS is dipropylene glycol.
- the TS in addition to maintaining the cationic surfactant in solution, possesses a high boiling point, low toxicity, biodegradability, or any combinations thereof.
- the solvent composition may have any wt. % of the TS suitable for maintaining the cationic surfactant in solution and/or lowering the surface tension of the solvent composition, which without limitation facilitates the contaminant removal process.
- the solvent composition has between about 20.0 wt. % TS and about 40.0 wt. % TS, alternatively between about 25.0 wt. % TS and about 35.0 wt. % TS.
- the TS may comprise about 30.0 wt. % of the solvent composition.
- Embodiments of the solvent composition comprise a cationic surfactant.
- the cationic surfactant may be any cationic surfactant or combination of cationic surfactants suitable for use in the solvent composition.
- the cationic surfactant may be a quaternary ammonium salt such as an imidazole derivative.
- the cationic surfactant include heterocycles (e.g., isostearyl ethylimidazolinium ethosulfate (ISES), and the like), alkyl-substituted pyridines, morpholinium salts, alkyl ammonium salts (e.g., cetyl trimethylammonium bromide, stearalkonium chloride, dimethyldioctadecylammonim chloride, and the like), the like, or any combinations thereof.
- the cationic surfactant is ISES.
- the solvent composition may have any wt.
- the cationic surfactant may have detergent properties such as disaggregation and emulsification.
- the solvent composition has between about 4.0 wt. % cationic surfactant and about 12.0 wt. % cationic surfactant, alternatively between about 6.0 wt. % cationic surfactant and about 10.0 wt. % cationic surfactant.
- the cationic surfactant may comprise about 8.0 wt. % of the solvent composition.
- the solvent composition may comprise a dispersant.
- the dispersant may be any dispersant suitable for preventing the settling of any components in the solvent composition.
- suitable dispersants include, without limitation, sulfonated- formaldehyde-based dispersants, polycarboxylated ether dispersants, naphthalene sulfonate dispersants, the like, or any combinations thereof.
- the solvent composition may have any wt. % of the dispersant suitable for preventing the settling of any of the solvent composition components. In an embodiment, the solvent composition has between about 1 wt. % dispersant and about 10 wt. % dispersant, alternatively between about 2 wt.
- the dispersant may comprise about 3 wt. % of the solvent composition.
- the solvent composition may be prepared by mixing the MESO, aprotic solvent (i.e., DMSO), and the TS together prior to the addition of the cationic surfactant.
- aprotic solvent i.e., DMSO
- mixing the MESO, the aprotic solvent, and the TS prior to the addition of the cationic surfactant may improve mixability.
- the MESO, aprotic solvent, and the TS may be mixed together in any order.
- the solvent composition may be stored until desired for use.
- the dispersant may be added to the solvent composition at any time during preparation of the solvent composition.
- the solvent composition may be prepared under any suitable conditions. In embodiments, the solvent composition may be prepared at ambient temperature and pressure.
- the solvent composition may be diluted with a diluent.
- the diluent may comprise any suitable diluent that may dilute the solvent composition.
- the diluent may comprise diesel fuel, biodiesel fuel, fuel oil, heavy aromatic naphtha, light sweet crude oil, water, the like, or any combinations thereof. Without being limited by theory, the diluent may decrease the potency of the solvent composition, but not otherwise affect the efficacy.
- the solvent composition has from about 1 wt. % to about 99 wt. % diluent, alternatively from about 80 wt. % to about 90 wt.
- the solvent composition has about 95 wt. % diluent, alternatively about 99 vvt. % diluent.
- a contaminant material removal process comprises contacting the contaminant materials and/or the industrial equipment with the solvent composition.
- the solvent composition is introduced into the vessel.
- the solvent composition may be introduced into the vessel by any suitable means such that the solvent composition contacts the contaminant materials disposed therein.
- the solvent composition is introduced into the vessel by being poured, pumped, injected, or the like, or any combinations thereof.
- the solvent composition may be poured onto the contaminated portion of the industrial equipment, or the contaminated portion of the industrial equipment may be submerged in the solvent composition such that the solvent composition contacts the contaminant materials disposed thereon.
- the contaminant material removal process may include the addition of heat to the solvent composition.
- the heat may be added by any suitable means such as by steam, heated coils, the like, or any combinations thereof.
- the solvent composition is heated to a temperature between about ambient temperature and the flash point of the diluent.
- Solvents containing light cycle oil as diluent can be heated between 100°F and about 160°F, and further alternatively between about 120°F and about 150°F.
- the heat may be applied to the solvent composition prior to the solvent composition contacting a contaminant material or concurrently while the solvent composition is contacting a contaminant material.
- the solvent composition is agitated when disposed in industrial equipment such as a vessel.
- the heat is added to facilitate the disaggregation and/or dissolution process between the solvent composition and the contaminant materials.
- the contaminant material removal process may include the addition of agitation to the solvent composition.
- Agitation of the solvent composition may be accomplished by any suitable means such as by stirring, shaking, pumping, the like, or any combinations thereof.
- the agitation may be applied to the solvent composition prior to the solvent composition contacting a contaminant material or concurrently while the solvent composition is contacting a contaminant material.
- the agitation is added to facilitate the disaggregation and/or dissolution process between the solvent composition and the contaminant materials.
- the solvent composition may be both agitated and heated as described above.
- the solvent composition may be disposed in the industrial equipment for any suitable period of time to allow the solvent composition in contact with the contaminant material to remove at least a portion of the contaminant material from the industrial equipment (i.e., disaggregated or dissolved).
- the length of the time frame may be dictated by the amount that the solvent composition is diluted.
- the time frame is from about one minute to about three weeks.
- the time frame is from about one hour to about forty-eight hours.
- the time frame is from about one hour to about twelve hours.
- the solvent composition may be introduced to industrial equipment in amounts to provide sufficient solvent composition to successfully remove at least a portion of the contaminant materials from the surfaces on which the contaminant materials are disposed. In embodiments, this amount is an amount sufficient for the solvent composition to contact the contaminant materials for an amount of time sufficient to disaggregate and/or dissolve the contaminant materials.
- the solvent composition may be introduced to industrial equipment in an amount in relation to the contaminant material (i.e., weight ratio of solvent composition to contaminant material) between about 100:1 weight ratio and about a 1 :1 weight ratio, alternatively between about a 10:1 weight ratio and about a 1 :1 weight ratio.
- the solvent composition to contaminant material ratio may comprise about a 50: 1 weight ratio, alternatively about a 20:1 weight ratio, and further alternatively about a 5:1 weight ratio.
- the contaminant materials may reside in the solvent composition and may therefore be fluid and/or flowable within the solvent composition.
- the contaminant materials residing within the solvent composition may be removed from the industrial equipment by any suitable means.
- the solvent composition is pumped, poured, or the like, or any combinations thereof from the industrial equipment along with the solvent composition.
- the surface that was contaminated by a contaminant material may be cleaned after the contaminant material has been contacted by the solvent composition.
- cleaning the surface may remove additional particulates and/or residue of the contaminant material.
- the cleaning may be accomplished by any suitable methods such as rinsing, spraying, scrubbing, and the like.
- Rinsing and/or spraying may be accomplished by any suitable method including rinsing and/or spraying with water, aqueous surfactant solutions, hydrocarbon solvents, or any combinations thereof.
- the contaminant materials may be recovered and/or recycled.
- the process of recovery and/or recycle may comprise transferring the disaggregated and/or dissolved contaminant materials to a high temperature and high pressure oven (e.g., a coker unit) to "crack" the heavy hydrocarbons into small usable fragments.
- a catalytic cracker uses high temperature and a catalyst to crack hydrocarbons into smaller pieces. Such a process may reduce contaminant materials to smaller usable hydrocarbons such that they may be recycled for further processing and use.
- the solvent composition may be biodegradable as defined by the Operation for Economic Co-Operation and Development (OECD) Biodegradation Test 301D.
- An example embodiment of a biodegradable solvent composition includes about 30.0 wt. % MESO, about 32.0 wt. % aprotic solvent (i.e., DMSO), about 30.0 wt. % dipropylene glycol (i.e. the TS), and about 8.0 wt. % ISES (i.e. the cationic surfactant).
- the solvent composition may be used in conjunction with other products used to treat industrial equipment for contaminant materials or otherwise unwanted materials.
- the solvent composition may be used to treat contaminant materials concurrently with a sodium nitrite solution used to treat sour water. Examples of sodium nitrite solutions are disclosed in U.S. Patent No. 8,702,994 issued on April 22, 2014, the entirety of which is incorporated herein by reference.
- the solvent composition may be used in conjunction with other organic solvents and/or organic solvent additives to dissolve and/or soften contaminant materials and the like.
- Examples include the organic solvent Rezyd-X ® , a registered trademark of United Laboratories International, LLC; the organic solvent additive HOB ® , a registered trademark of United Laboratories International, LLC; Zyme-Flow ® UN657, a registered trademark of United Laboratories International, LLC; Zyme-Ox ® Plus Z50, a registered trademark of United Laboratories International, LLC; the like; or any combinations thereof.
- a first solvent composition was prepared by mixing the aprotic solvent dimethyl sulfoxide with methyl soyate, dipropylene glycol and isostearyl ethylimidazolinium ethosulfate.
- a second solvent composition was prepared by mixing N-methylpyrrolidone, methyl soyate, dipropylene glycol and isostearyl ethylimidazolinium ethosulfate. Both compositions have the same proportions.
- a solvent composition was prepared with the following mix of components.
- the solvent composition was diluted to a strength of 5% by the addition of diesel fuel.
- the contaminant material chosen for testing was a piece of asphalt obtained from a refinery tank. Two equal sized portions of the asphalt, each comprising the same weight of 1 g, were added to two clear vials such that the asphalt was affixed to the bottom of the vials. 3mL of the HAN solution were added to one vial, and 3 ml of the 5% solvent composition in diesel were added to the other vial. This amount was sufficient to completely submerge the asphalt sample in each vial. Both vials were then placed on a hot plate and heated over a three hour period to temperatures ranging from between 155°F and 175°F.
- a solvent composition was prepared with the following mix of components.
- the solvent composition was split into two samples. Sample 1 was diluted to a strength of 5% by the addition of biodiesel. Sample 2 was diluted to a strength of 5% by the addition of fuel oil.
- the contaminant material chosen for testing was a piece of a hydrocarbon deposit obtained from an underground vessel in a refineiy. This vessel was submerged such that it would only be possible to apply limited heat and no agitation to any solvent composition pumped within. Two equal sized portions of the hydrocarbon deposit, each comprising the same weight of 2 g, were added to two clear vials such that the hydrocarbon deposit was affixed to the bottom of the vials.
- the following example is to illustrate the effectiveness of the solvent composition on various sources of asphalt samples.
- the first sample was collected from a crude oil distillation unit (CDU) as asphalt flux and the second sample was collected from a propane de-asphalting unit (PDA).
- CDU crude oil distillation unit
- PDA propane de-asphalting unit
- the first sample was observed to have a pasty consistency.
- the second sample was hardened and required a sharp tool to separate for weighing and testing.
- Two solvents were used in the experiment, Rezyd-X ® which is a solvent system available from United Laboratories International, LLC and the solvent of the present application comprising MESO, NMP, dipropylene glycol, and ISES.
- VTB hardened vacuum tower bottoms
- the solvents tested were Rezyd-X ® and HOB ® which are both available from United Laboratories International, LLC as well as the solvent of the present application comprising MESO, NMP, dipropylene glycol, and ISES.
- Each solvent was dissolved in light cycle oil (LCO) at 2% by volume.
- LCO light cycle oil
- a sample of VTB was added to three vials and a measured amount of diluted solvent was added to each. The samples were placed in a water bath set at 120 °F. Each sample as intermittently agitated to promote mixing. The results of the experiment are presented in Table 8.
- An aqueous boilout test was performed with the same vacuum tower bottoms as in the previous test.
- a sample of VTB was mixed with an aliquot of water and a measured volume solvent comprising MESO, NMP, Dipropylene Glycol, and ISES.
- the samples were placed in a water bath at 180 °F.
- the first test comprised a 3% by volume solution of solvent in water. There was no observable dissolution after several hours.
- a second test comprised a 6% by volume solution of solvent in water. There was no observable dissolution after several hours.
- compositions and methods are described in terms of “comprising,” “containing,” or “including” various components or steps, the compositions and methods can also “consist essentially of or “consist of the various components and steps.
- indefinite articles “a” or “an,” as used in the claims, are defined herein to mean one or more than one of the element that it introduces.
- ranges from any lower limit may be combined with any upper limit to recite a range not explicitly recited, as well as, ranges from any lower limit may be combined with any other lower limit to recite a range not explicitly recited, in the same way, ranges from any upper limit may be combined with any other upper limit to recite a range not explicitly recited.
- any numerical range with a lower limit and an upper limit is disclosed, any number and any included range falling within the range are specifically disclosed.
- every range of values (of the form, "from about a to about b,” or, equivalently, “from approximately a to b,” or, equivalently, “from approximately a-b") disclosed herein is to be understood to set forth every number and range encompassed within the broader range of values even if not explicitly recited.
- every point or individual value may serve as its own lower or upper limit combined with any other point or individual value or any other lower or upper limit, to recite a range not explicitly recited. [0051] Therefore, the present invention is well adapted to attain the ends and advantages mentioned as well as those that are inherent therein.
Abstract
Description
Claims
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
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US15/198,597 US11946021B2 (en) | 2014-03-22 | 2016-06-30 | Solvent composition and process for removal of asphalt and other contaminant materials |
PCT/US2017/040073 WO2018005847A1 (en) | 2016-06-30 | 2017-06-29 | Solvent composition and process for removal of asphalt and other contaminant materials |
Publications (2)
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EP3478809A1 true EP3478809A1 (en) | 2019-05-08 |
EP3478809A4 EP3478809A4 (en) | 2020-03-04 |
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JP (2) | JP7007353B2 (en) |
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US11053464B2 (en) | 2014-03-22 | 2021-07-06 | United Laboratories International, Llc | Solvent composition and process for removal of asphalt and other contaminant materials |
US11946021B2 (en) | 2014-03-22 | 2024-04-02 | United Laboratories International, Llc | Solvent composition and process for removal of asphalt and other contaminant materials |
US11441103B2 (en) | 2017-01-16 | 2022-09-13 | United Laboratories International, Llc | Solvent composition and process for cleaning contaminated industrial equipment |
EP4225495A1 (en) * | 2020-10-06 | 2023-08-16 | United Laboratories International, LLC | Solvent system for cleaning low-temperature fixed-bed reactor catalyst in situ |
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US6479445B1 (en) | 1997-05-23 | 2002-11-12 | Huntsman Petrochemical Corporation | Paint stripping compositions |
US6395103B1 (en) * | 1997-05-23 | 2002-05-28 | Huntsman Petrochemical Corporation | Degreasing compositions |
US6281189B1 (en) * | 1998-12-03 | 2001-08-28 | Elisha Technologies Co Llc | Soyate containing compositions |
US6191087B1 (en) * | 1999-09-03 | 2001-02-20 | Vertec Biosolvents, Llc | Environmentally friendly solvent |
CN1729284A (en) * | 2002-10-21 | 2006-02-01 | 联合能源公司 | Cleaning compositions for oil-gas wells, well lines, casings, equipment, storage tanks, etc., and method of use |
WO2006042316A1 (en) * | 2004-10-12 | 2006-04-20 | Pantheon Chemical, Inc | Composition for cleaning and degreasing, system for using the composition, and methods of forming and using the composition |
US20080139437A1 (en) * | 2006-11-10 | 2008-06-12 | Power John W | Ether-containing paint removing composition |
US8695707B2 (en) * | 2009-06-16 | 2014-04-15 | Schlumberger Technology Corporation | Asphaltene removal composition and methods |
US8828917B2 (en) * | 2010-08-12 | 2014-09-09 | Segetis, Inc. | Carboxy ester ketal removal compositions, methods of manufacture, and uses thereof |
US8481474B1 (en) * | 2012-05-15 | 2013-07-09 | Ecolab Usa Inc. | Quaternized alkyl imidazoline ionic liquids used for enhanced food soil removal |
US11053464B2 (en) * | 2014-03-22 | 2021-07-06 | United Laboratories International, Llc | Solvent composition and process for removal of asphalt and other contaminant materials |
US11946021B2 (en) * | 2014-03-22 | 2024-04-02 | United Laboratories International, Llc | Solvent composition and process for removal of asphalt and other contaminant materials |
WO2015168658A1 (en) * | 2014-05-02 | 2015-11-05 | Amyris, Inc. | Solvent compositions based on dihydrofarnesene |
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2017
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BR112019000036A2 (en) | 2019-04-16 |
AU2017290352A1 (en) | 2019-02-14 |
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CO2019000948A2 (en) | 2019-04-30 |
AU2021277674A1 (en) | 2022-01-20 |
MX2019000244A (en) | 2019-09-18 |
CA3046619A1 (en) | 2018-01-04 |
ECSP19006820A (en) | 2019-04-30 |
CL2018003898A1 (en) | 2019-03-01 |
KR20190026781A (en) | 2019-03-13 |
JP2019523343A (en) | 2019-08-22 |
PH12019550016A1 (en) | 2019-11-04 |
ZA201900583B (en) | 2021-04-28 |
WO2018005847A1 (en) | 2018-01-04 |
JP2022058510A (en) | 2022-04-12 |
AU2024200899A1 (en) | 2024-03-07 |
JP7399991B2 (en) | 2023-12-18 |
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