EP3475099B1 - Procédé de fabrication d'un produit de sécurité ou de valeur comprenant un élément de sécurité diffractif - Google Patents

Procédé de fabrication d'un produit de sécurité ou de valeur comprenant un élément de sécurité diffractif Download PDF

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Publication number
EP3475099B1
EP3475099B1 EP17777503.8A EP17777503A EP3475099B1 EP 3475099 B1 EP3475099 B1 EP 3475099B1 EP 17777503 A EP17777503 A EP 17777503A EP 3475099 B1 EP3475099 B1 EP 3475099B1
Authority
EP
European Patent Office
Prior art keywords
adhesive
latent
hot
reactive
security
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
EP17777503.8A
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German (de)
English (en)
Other versions
EP3475099A1 (fr
Inventor
Per KRÜGER
Michael Knebel
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Bundesdruckerei GmbH
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Bundesdruckerei GmbH
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
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Publication date
Application filed by Bundesdruckerei GmbH filed Critical Bundesdruckerei GmbH
Publication of EP3475099A1 publication Critical patent/EP3475099A1/fr
Application granted granted Critical
Publication of EP3475099B1 publication Critical patent/EP3475099B1/fr
Active legal-status Critical Current
Anticipated expiration legal-status Critical

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Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B42BOOKBINDING; ALBUMS; FILES; SPECIAL PRINTED MATTER
    • B42DBOOKS; BOOK COVERS; LOOSE LEAVES; PRINTED MATTER CHARACTERISED BY IDENTIFICATION OR SECURITY FEATURES; PRINTED MATTER OF SPECIAL FORMAT OR STYLE NOT OTHERWISE PROVIDED FOR; DEVICES FOR USE THEREWITH AND NOT OTHERWISE PROVIDED FOR; MOVABLE-STRIP WRITING OR READING APPARATUS
    • B42D25/00Information-bearing cards or sheet-like structures characterised by identification or security features; Manufacture thereof
    • B42D25/40Manufacture
    • B42D25/45Associating two or more layers
    • B42D25/465Associating two or more layers using chemicals or adhesives
    • B42D25/47Associating two or more layers using chemicals or adhesives using adhesives
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B41PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41MPRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
    • B41M3/00Printing processes to produce particular kinds of printed work, e.g. patterns
    • B41M3/006Patterns of chemical products used for a specific purpose, e.g. pesticides, perfumes, adhesive patterns; use of microencapsulated material; Printing on smoking articles
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B42BOOKBINDING; ALBUMS; FILES; SPECIAL PRINTED MATTER
    • B42DBOOKS; BOOK COVERS; LOOSE LEAVES; PRINTED MATTER CHARACTERISED BY IDENTIFICATION OR SECURITY FEATURES; PRINTED MATTER OF SPECIAL FORMAT OR STYLE NOT OTHERWISE PROVIDED FOR; DEVICES FOR USE THEREWITH AND NOT OTHERWISE PROVIDED FOR; MOVABLE-STRIP WRITING OR READING APPARATUS
    • B42D25/00Information-bearing cards or sheet-like structures characterised by identification or security features; Manufacture thereof
    • B42D25/30Identification or security features, e.g. for preventing forgery
    • B42D25/328Diffraction gratings; Holograms
    • GPHYSICS
    • G09EDUCATION; CRYPTOGRAPHY; DISPLAY; ADVERTISING; SEALS
    • G09FDISPLAYING; ADVERTISING; SIGNS; LABELS OR NAME-PLATES; SEALS
    • G09F3/00Labels, tag tickets, or similar identification or indication means; Seals; Postage or like stamps
    • G09F3/02Forms or constructions
    • G09F3/0291Labels or tickets undergoing a change under particular conditions, e.g. heat, radiation, passage of time
    • G09F3/0292Labels or tickets undergoing a change under particular conditions, e.g. heat, radiation, passage of time tamper indicating labels
    • GPHYSICS
    • G09EDUCATION; CRYPTOGRAPHY; DISPLAY; ADVERTISING; SEALS
    • G09FDISPLAYING; ADVERTISING; SIGNS; LABELS OR NAME-PLATES; SEALS
    • G09F3/00Labels, tag tickets, or similar identification or indication means; Seals; Postage or like stamps
    • G09F3/02Forms or constructions
    • G09F3/0291Labels or tickets undergoing a change under particular conditions, e.g. heat, radiation, passage of time
    • G09F3/0294Labels or tickets undergoing a change under particular conditions, e.g. heat, radiation, passage of time where the change is not permanent, e.g. labels only readable under a special light, temperature indicating labels and the like
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B41PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41MPRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
    • B41M3/00Printing processes to produce particular kinds of printed work, e.g. patterns
    • B41M3/14Security printing

Definitions

  • the invention relates to a method for producing a security or valuable product with a carrier substrate made of paper and a diffractive security element which is connected directly to the carrier substrate via an adhesive layer.
  • the invention also relates to a security product or product of value produced by the method.
  • Security or value products such as personal documents, access control cards, vehicle documents, banknotes, postage stamps, tax codes, VISA, tickets or bank cards, usually have defined security features that are intended to make counterfeiting difficult or even impossible.
  • the security features that can be recognized by humans can be subdivided into optical, haptic and acoustic security features.
  • the security or value documents relevant in connection with the present invention have an optical security feature.
  • the security or value documents carry diffractive security elements.
  • the microstructures include grids, mostly in the form of surface reliefs, which change incident light through diffraction. This creates various effects such as two or three-dimensional images, kinematic effects or color changes.
  • the different types of DOVID differ in their image resolution, brightness and animation properties. Examples include holograms and kinegrams.
  • diffractive security elements such as holograms, kinegrams and alphagrams are used, which are glued to a paper carrier substrate with a hot melt adhesive.
  • forgeries occur time and again with these security features, in which, for example, kinegrams are completely detached by heating the hot melt adhesive or the use of solvents and are used for forgeries can be reused.
  • an indicator can be incorporated into the adhesive (e.g. rhodamine), which triggers a color reaction when manipulated with solvents such as ethanol and acetone. This chemical reaction creates a colored reaction product that penetrates the carrier substrate, usually paper, and / or discolors the security element.
  • rhodamines are classified as potentially carcinogenic, mutagenic and ecotoxic.
  • DE 10 2008 052 572 A1 describes a security or value document with a core layer which contains electronic components or diffractive security elements embedded in a polymer matrix.
  • Polymer layers are applied by lamination to the top and bottom of the security or value document.
  • a protective layer made of a polymeric material is provided between the polymer layers and the core layer.
  • the core layer, the protective layers and the outer polymer layers are bonded to one another as a composite, a latently reactive adhesive being used, which enables a material bond between the respective polymeric materials of the layers.
  • a security element for bonding to a substrate such as a value document having at least one bonding surface coated with at least one adhesive layer and the adhesive containing at least one powdery antiblocking agent as a component, the antiblocking agent being exposed to heat and / or radiation and / or mechanical action can be activated and, after activation, is able to enter into a chemical reaction with a component of the adhesive and / or with itself.
  • thermoplastic plastic film on the side of the thermoplastic plastic film on which the electromechanical transducer or transducers are located, a further thermoplastic plastic film is placed on or one or more further thermoplastic plastic films are placed under the film stack and the film stack is then laminated.
  • the WO 2010/072339 A2 teaches a method for producing a security element and a transfer film, in particular a hot stamping film, for transferring one or more multilayer bodies onto a target substrate.
  • the DE 10 2010 035 889 A1 relates to a method for producing a security element, in which a stack of foils is laminated to a laminate by means of pressure and heat and the security document is separated from the laminate, the third foil having no printing layer and at least one security thread over before the foils are brought together to form a stack of foils a Holtmelt adhesive is applied to the third film.
  • the invention is based on the knowledge that a connection of the security element and substrate by means of a latently reactive adhesive can prevent manipulation by detaching the security element.
  • the latently reactive adhesive is introduced into the hot melt adhesive matrix or is present separately in sections.
  • the latently reactive adhesive is activated during the application process and creates a permanent chemical bond between the substrate and the security element. A full-surface detachment is made more difficult or completely prevented because manipulation of the security element causes cohesive destruction of the paper and security element, which makes reconstruction of the security feature almost impossible.
  • the process sequence according to the invention is basically designed in such a way that the joining process is subject to a differentiated temperature regime, in which temperatures prevail in a first phase which only enable the hot melt adhesive to be processed for a specific purpose. Only when the security element is fixed in the intended area of the substrate with the aid of the hot melt adhesive is the temperature increased in a second phase in such a way that the latently reactive adhesive is activated and the desired (additional) chemical bond takes place. The temperature in the second phase must always be specified so that the hot melt adhesive used in the application is not thermally damaged.
  • the application temperature is understood to mean the processing temperature of the adhesive recommended by the manufacturer. If the manufacturer specifies a temperature range, the lower limit is decisive. If different temperature specifications from one manufacturer are known for one and the same adhesive, the most recent specification from this manufacturer is decisive. In the event that different manufacturers specify different processing temperatures for exactly the same adhesive composition, the application temperature is the lowest temperature specification. If there is no information about the processing temperatures of the hot melt adhesives, the application temperature for hot melt adhesives is the glass transition temperature of the base polymer. Anything is missing Information on the processing temperatures of the latent-reactive adhesives, the application temperature for latent-reactive adhesives is the temperature at which at least 90% of the functionalities required to cure the adhesive are consumed within a time window of 15 minutes. In the case of a latently reactive adhesive based on a surface-deactivated di- or polyisocyanate and at least one isocyanate-reactive polymer, for example, the degradation of isocyanate functionality over time would be decisive.
  • the application temperature T a1 of the hot melt adhesive is in the range from 45 to 245 ° C, in particular in the range from 55 to 145 ° C
  • the application temperature T a2 of the latent reactive adhesive is in the range from 50 to 250 ° C , especially in the range from 60 to 150 ° C. If the application temperatures T a1 and T a2 are in the range mentioned, it is ensured that neither the substrate material nor the diffractive security element are thermally damaged during the joining step. Independently or in combination thereof, it is preferred if the application temperature T a2 of the latent-reactive adhesive is at least 5 ° C. above the application temperature T a1 of the hot-melt adhesive.
  • the application temperature T a2 of the latently reactive adhesive is 5 ° C. to 40 ° C., particularly preferably 10 ° C. to 20 ° C., above the application temperature T a1 of the hot melt adhesive. This ensures that a material connection between the carrier substrate and the security element by the latent-reactive adhesive does not take place until after it has been placed and that the adhesive properties of the latent-reactive adhesive do not hinder the processing beforehand.
  • Latent-reactive adhesives for the purposes of the invention are adhesive compositions which can be stored at room temperature and which cure by themselves at higher temperatures through the formation of covalent bonds.
  • an adhesive composition based on a combination of a surface-deactivated di- or polyisocyanate and at least one isocyanate-reactive polymer is preferably used as the latently reactive adhesive. It can also be a latently reactive hot melt adhesive, in particular if a mixture with the (non-latently reactive) hot melt adhesive is used.
  • latently reactive adhesives suitable for the purposes of the invention can be found EP 2 712 879 A1 remove.
  • the latently reactive hot melt adhesive composition described there comprises a mixture of polymers which are in the melting temperature and the number of functionalities present that can in principle react with an isocyanate group.
  • the composition also contains a surface-deactivated di- or polyisocyanate.
  • EP 0 598 973 B1 describes a process for the production of reactive enamel masses. These consist of a polymer that is solid at room temperature but meltable with isocyanate-reactive groups and a premix of a solid isocyanate and a deactivating agent. The melt is applied in layers to carrier materials so that the deactivated isocyanate and polymer layers are not mixed. Above 40 ° C, these layers can be liquefied and reshaped. They harden between 100 ° C and 120 ° C.
  • EP 1 231 232 B1 describes a reactive one-component hot-melt adhesive which is solid at room temperature and which comprises an isocyanate which is liquid or solid at room temperature, an isocyanate-reactive polymer which is solid at room temperature and a polymer which is inert towards isocyanate groups.
  • This adhesive is non-adhesive at room temperature and only becomes adhesive when heated to temperatures between 60 ° C and 160 ° C.
  • a suitable latent-reactive adhesive can be EP 0 922 720 A1 remove.
  • the use of an aqueous dispersion which contains at least one surface-deactivated polyisocyanate and at least one isocyanate-reactive polymer for the production of storage-stable, latently reactive layers or powders is described.
  • Hotmelts also known as hotmelts
  • Hotmelts are solvent-free and more or less solid products at room temperature that are applied to the adhesive surface when they are hot and create a firm bond when they cool down.
  • Hotmelt adhesives are purely physically setting adhesives, i.e. the already finished adhesive is introduced into the adhesive joint, which has been converted into a workable form by heating and solidifies again when it cools. This group of adhesives is based on various basic chemicals.
  • the preferred hot melt adhesive is an adhesive composition with a base polymer selected from the group comprising polyamides (PA), polyethylene (PE), amorphous polyalphaolefins (APAO), ethylene vinyl acetate copolymers (EVAC), polyester elastomers (TPE-E), polyurethane elastomers ( TPE-U), copolyamide elastomers (TPE-A) and vinylpyrrolidone / vinyl acetate copolymers are used, especially when a mixture with the latently reactive adhesive is used.
  • a base polymer selected from the group comprising polyamides (PA), polyethylene (PE), amorphous polyalphaolefins (APAO), ethylene vinyl acetate copolymers (EVAC), polyester elastomers (TPE-E), polyurethane elastomers ( TPE-U), copolyamide elastomers (TPE-A) and vinylpyrrolidone / vinyl acetate copolymers are used
  • hot melt adhesive and latently reactive adhesive preferably 100 parts by weight of the hot melt adhesive are mixed with 5 to 50 parts by weight of the latently reactive adhesive.
  • the hot melt adhesive and the latently reactive adhesive are present separately from one another in sections and sections with the latent reactive adhesive are applied before sections with the hot melt adhesive. Since the application temperature of the hot-melt adhesive is lower than the application temperature of the latent-reactive adhesive, the subsequent application of the hot-melt adhesive does not activate the adhesion of the latent-reactive adhesive. As a result, more functionalities are available for the later covalent attachment to the substrate and the security element.
  • the ratio of the total area of all sections of the hot-melt adhesive to the total area of all sections of the latent-reactive adhesive is preferably 20: 1 to 2: 1.
  • the latent-reactive adhesive is preferably applied by means of screen printing.
  • a further aspect of the invention lies in the provision of a security or valuable product, in particular a security or valuable document, with a substrate, preferably made of paper, and a diffractive security element that is connected directly to the carrier substrate by means of an adhesive layer, the security or product of value is produced by the process described above. Accordingly, the latently reactive adhesive is cured and covalently bonded to the substrate and security element.
  • Valuable and / or security products in the sense of the invention include, for example, passports, identity cards, driver's licenses, access control cards or other ID cards, vehicle registration documents, vehicle documents, visas, checks, means of payment, in particular banknotes, company IDs, credentials, membership cards, gift or shopping vouchers, waybills, Tax stamps, postage stamps, tickets, (game) chips, certificates or adhesive labels (e.g. for product security).
  • the mixture is applied at a temperature that corresponds to the application temperature of the hot melt adhesive.
  • the hot glue mixture in the glue joint is quickly applied to the back of aluminum foil applied kinegram and then increased the temperature to the application temperature of the latent-reactive adhesive.
  • FIG. 2 represents a sectional view through a further variant of the security or valuable product 100 according to the invention - likewise in a highly schematic manner.
  • the security or valuable product 100 can be produced as follows: In a first partial step, first sections 34 of the joining area are coated on a carrier substrate 10 made of paper by means of screen printing with a latent-reactive adhesive with an application temperature of about 80 ° C. Approx. 15% of the total area of the adhesive joint is coated.
  • the remaining second sections 32 are filled with a hot-melt adhesive with an application temperature of approximately 60 ° C., the temperature corresponding to the processing temperature recommended by the manufacturer.
  • a kinegram is then quickly applied to the back of the aluminum foil and the temperature is increased to the application temperature of the latent-reactive adhesive.

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  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Theoretical Computer Science (AREA)
  • Physics & Mathematics (AREA)
  • General Physics & Mathematics (AREA)
  • Pest Control & Pesticides (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Toxicology (AREA)
  • Manufacturing & Machinery (AREA)
  • Adhesives Or Adhesive Processes (AREA)
  • Credit Cards Or The Like (AREA)
  • Adhesive Tapes (AREA)

Claims (8)

  1. Procédé destiné à fabriquer un produit de sécurité ou de valeur (100) pourvu d'un substrat (10) en papier et d'un élément de sécurité diffractif (20) qui est relié directement audit substrat (10) au moyen d'une couche de colle (30), comprenant les étapes suivantes :
    (i) l'application d'une colle thermofusible et d'une colle à réactivité latente a) sur une partie du substrat (10) qui est prévue pour l'élément de sécurité (20) et/ou b) sur l'élément de sécurité (20), l'opération consistant soit à appliquer un mélange constitué de colle thermofusible et de colle à réactivité latente, soit à appliquer par zones la colle thermofusible et la colle à réactivité latente séparément l'une de l'autre, et une température d'application Ta1 de la colle thermofusible étant inférieure à une température d'application Ta2 de la colle à réactivité latente, et la température T1 pendant l'application étant choisie telle que Ta1 ≤ T1 < Ta2 ;
    (ii) la mise en place de l'élément de sécurité (20) sur le substrat (10) ; et
    (iii) l'augmentation de la température à une température T2, où T2 ≥ Ta2.
  2. Procédé selon la revendication 1, lors duquel la température d'application Ta1 de la colle thermofusible se situe dans une plage comprise entre 45 °C et 245 °C et la température d'application Ta2 de la colle à réactivité latente se situe dans une plage comprise entre 50 °C et 250 °C.
  3. Procédé selon la revendication 1 ou 2, lors duquel la température d'application Ta2 de la colle à réactivité latente se situe au moins 5 °C au-dessus de la température d'application Ta1 de la colle thermofusible.
  4. Procédé selon l'une quelconque des revendications précédentes, lors duquel la colle à réactivité latente utilisée est une composition adhésive basée sur une combinaison entre un di- ou polyisocyanate désactivé en surface et au moins un polymère réactif avec des isocyanates.
  5. Procédé selon l'une quelconque des revendications précédentes, lors duquel la colle thermofusible utilisée est une composition adhésive comprenant un polymère de base sélectionné parmi le groupe comprenant des polyamides (PA), du polyéthylène (PE), des polyalphaoléfines amorphes (APAO), des copolymères d'éthylène-acétate de vinyle (EVAC), des élastomères de polyester (TPE-E), des élastomères de polyuréthane (TPE-U), des élastomères de copolyamide (TPE-A) et des copolymères de vinylpyrrolidone et d'acétate de vinyle.
  6. Procédé selon l'une quelconque des revendications précédentes, lors duquel la colle thermofusible et la colle à réactivité latente se présentent séparément l'une de l'autre de manière à former différentes parties, et des parties (34) avec la colle à réactivité latente sont appliquées avant des parties (32) avec la colle thermofusible.
  7. Procédé selon la revendication 6, lors duquel l'application de la colle à réactivité latente est réalisée par sérigraphie.
  8. Produit de sécurité ou de valeur (100) pourvu d'un substrat (10) en papier et d'un élément de sécurité diffractif (20) qui est relié directement audit substrat (10) au moyen d'une couche de colle (30), ledit produit étant fabriqué conformément à un procédé selon la revendication 1.
EP17777503.8A 2016-09-20 2017-09-15 Procédé de fabrication d'un produit de sécurité ou de valeur comprenant un élément de sécurité diffractif Active EP3475099B1 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE102016117674.5A DE102016117674A1 (de) 2016-09-20 2016-09-20 Verfahren zur Herstellung eines Sicherheits- oder Wertprodukts mit einem diffraktiven Sicherheitselement
PCT/EP2017/073237 WO2018054765A1 (fr) 2016-09-20 2017-09-15 Procédé de fabrication d'un produit de sécurité ou de valeur comprenant un élément de sécurité diffractif

Publications (2)

Publication Number Publication Date
EP3475099A1 EP3475099A1 (fr) 2019-05-01
EP3475099B1 true EP3475099B1 (fr) 2021-12-15

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EP17777503.8A Active EP3475099B1 (fr) 2016-09-20 2017-09-15 Procédé de fabrication d'un produit de sécurité ou de valeur comprenant un élément de sécurité diffractif

Country Status (3)

Country Link
EP (1) EP3475099B1 (fr)
DE (1) DE102016117674A1 (fr)
WO (1) WO2018054765A1 (fr)

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE102019120049A1 (de) * 2019-07-24 2021-01-28 Bundesdruckerei Gmbh Verfahren und Schmelzklebstoff zur Herstellung eines aus mehreren Schichten bestehenden Wert- oder Sicherheitsdokumentes sowie Wert- oder Sicherheitsdokument
DE102021000890A1 (de) 2021-02-19 2022-08-25 Giesecke+Devrient Currency Technology Gmbh Sicherheitselement und Verfahren zu seiner Herstellung

Family Cites Families (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE4022584A1 (de) 1990-07-16 1992-01-23 Kurz Leonhard Fa Verfahren zur festlegung einer dekorschicht auf einem substrat sowie hierzu geeignete praegefolie
KR100276573B1 (ko) 1992-06-15 2000-12-15 엡뇌터 아게 반응성 고온용융물을 제조하기 위한 방법 및 혼합물
EP0598973A1 (fr) 1992-11-26 1994-06-01 The Procter & Gamble Company Composition de nettoyage liquide pour tous usages
PT922720E (pt) 1997-12-11 2002-01-30 Bayer Ag Processo para a preparacao e utilizacao de camadas ou pos reactivos latentes estaveis a armazenagem de poliisocianatos solidos desactivados superficialmente e polimeros de dispersao com grupos funcionais
DE10106630A1 (de) 2001-02-12 2002-08-22 Jowat Lobers U Frank Gmbh & Co Selbsttragendes reaktives Schmelzklebeelement und seine Verwendung
DE102007044482A1 (de) 2007-09-18 2009-03-19 Giesecke & Devrient Gmbh Sicherheitselement mit Tamper Evident-Effekt
DE102007054046A1 (de) * 2007-11-13 2009-06-18 Bayer Materialscience Ag Latentreaktive Klebstoffe für Identifikations-Dokumente
DE102008052572A1 (de) 2008-10-21 2010-04-29 Bayer Materialscience Ag Latent-reaktiv verklebte TPU/PC-Schichtstoffe
DE102008062149B3 (de) * 2008-12-16 2010-04-29 Ovd Kinegram Ag Verfahren zur Herstellung eines Sicherheitselements sowie Transferfolie
DE102009031877A1 (de) * 2008-12-23 2010-07-01 Giesecke & Devrient Gmbh Sicherheitselement mit verbessertem Heißsiegelklebstoff
DE102010035889B4 (de) * 2010-08-30 2021-11-11 Bundesdruckerei Gmbh Wert- und/oder Sicherheitsdokument und Verfahren zu dessen Herstellung
EP2455228A1 (fr) * 2010-11-18 2012-05-23 Bayer Material Science AG Document de sécurité et/ou de valeur contenant un convertisseur électromécanique
EP2712879B1 (fr) 2012-09-28 2018-02-14 Collano Adhesives AG Composition de colle à fondre à réaction latente

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DE102016117674A1 (de) 2018-03-22
EP3475099A1 (fr) 2019-05-01
WO2018054765A1 (fr) 2018-03-29

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