EP3472514B1 - Method for operating a waste heat steam generator - Google Patents
Method for operating a waste heat steam generator Download PDFInfo
- Publication number
- EP3472514B1 EP3472514B1 EP16753305.8A EP16753305A EP3472514B1 EP 3472514 B1 EP3472514 B1 EP 3472514B1 EP 16753305 A EP16753305 A EP 16753305A EP 3472514 B1 EP3472514 B1 EP 3472514B1
- Authority
- EP
- European Patent Office
- Prior art keywords
- evaporator
- setpoint
- flow
- bypass line
- steam generator
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 239000002918 waste heat Substances 0.000 title claims description 22
- 238000000034 method Methods 0.000 title claims description 18
- 238000010438 heat treatment Methods 0.000 claims description 17
- 230000001105 regulatory effect Effects 0.000 claims description 10
- 230000001276 controlling effect Effects 0.000 claims description 5
- 238000004781 supercooling Methods 0.000 claims 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 9
- 238000013021 overheating Methods 0.000 description 6
- 230000001052 transient effect Effects 0.000 description 6
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 3
- 230000015572 biosynthetic process Effects 0.000 description 3
- 239000003546 flue gas Substances 0.000 description 3
- 230000001419 dependent effect Effects 0.000 description 2
- 230000006978 adaptation Effects 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 230000018109 developmental process Effects 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 230000010354 integration Effects 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- 230000000630 rising effect Effects 0.000 description 1
- 238000004088 simulation Methods 0.000 description 1
- 238000012549 training Methods 0.000 description 1
Images
Classifications
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F22—STEAM GENERATION
- F22D—PREHEATING, OR ACCUMULATING PREHEATED, FEED-WATER FOR STEAM GENERATION; FEED-WATER SUPPLY FOR STEAM GENERATION; CONTROLLING WATER LEVEL FOR STEAM GENERATION; AUXILIARY DEVICES FOR PROMOTING WATER CIRCULATION WITHIN STEAM BOILERS
- F22D5/00—Controlling water feed or water level; Automatic water feeding or water-level regulators
- F22D5/26—Automatic feed-control systems
- F22D5/34—Applications of valves
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F22—STEAM GENERATION
- F22D—PREHEATING, OR ACCUMULATING PREHEATED, FEED-WATER FOR STEAM GENERATION; FEED-WATER SUPPLY FOR STEAM GENERATION; CONTROLLING WATER LEVEL FOR STEAM GENERATION; AUXILIARY DEVICES FOR PROMOTING WATER CIRCULATION WITHIN STEAM BOILERS
- F22D1/00—Feed-water heaters, i.e. economisers or like preheaters
- F22D1/02—Feed-water heaters, i.e. economisers or like preheaters with water tubes arranged in the boiler furnace, fire tubes, or flue ways
- F22D1/12—Control devices, e.g. for regulating steam temperature
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F22—STEAM GENERATION
- F22D—PREHEATING, OR ACCUMULATING PREHEATED, FEED-WATER FOR STEAM GENERATION; FEED-WATER SUPPLY FOR STEAM GENERATION; CONTROLLING WATER LEVEL FOR STEAM GENERATION; AUXILIARY DEVICES FOR PROMOTING WATER CIRCULATION WITHIN STEAM BOILERS
- F22D5/00—Controlling water feed or water level; Automatic water feeding or water-level regulators
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F24—HEATING; RANGES; VENTILATING
- F24D—DOMESTIC- OR SPACE-HEATING SYSTEMS, e.g. CENTRAL HEATING SYSTEMS; DOMESTIC HOT-WATER SUPPLY SYSTEMS; ELEMENTS OR COMPONENTS THEREFOR
- F24D2200/00—Heat sources or energy sources
- F24D2200/16—Waste heat
Definitions
- the invention relates to a method for operating a waste heat steam generator according to the preamble of claim 1, in particular for load-dependent control of a waste heat steam generator designed according to the forced flow principle.
- From the EP 2 224 164 A1 discloses a method for operating a waste heat steam generator with an evaporator, an economizer with a number of economizer heating surfaces, and a bypass line connected in parallel to a number of economizer heating surfaces on the flow medium side.
- a method is disclosed here with which the formation of a water-steam mixture at the inlet of the evaporator is to be reliably avoided in all load conditions.
- a characteristic parameter for this heat energy supplied to the waste heat steam generator is used to control or regulate the flow rate of the bypass line in order to reduce the flow rate of the bypass line when the parameter increases.
- the flow rate of the bypass line can be adjusted accordingly when the heat energy supplied to the waste heat steam generator is increased and thus before the measurement of an actual change in temperature or subcooling at the inlet of the evaporator. If, in the current operating mode of the waste heat steam generator, the amount of heat supplied to the waste heat steam generator increases, this is linked to an increase in further thermodynamic state variables of the flow medium (such as feed water mass flow, pressure, medium temperatures), which, due to physical principles, is directly associated with an increase in inlet subcooling. Therefore, in such a case, the flow rate of the bypass line should be reduced so that the temperature at the exit of the economizer increases and so the subcooling at the evaporator inlet is decreased.
- the flow medium such as feed water mass flow, pressure, medium temperatures
- the flow rate of the bypass line is advantageously increased in order to adjust the outlet temperature of the economizer in a targeted manner.
- the flow rate can also be regulated as a function of a predetermined subcooling setpoint US 2011/023487 A1 discloses a similar method of operating a heat recovery steam generator.
- the object of the invention is therefore to provide an optimized method for operating a waste heat steam generator.
- FIG 1 initially shows schematically a first embodiment with a control for a waste heat steam generator.
- a flow medium S driven by a pump (not shown in detail), initially flows into a first preheater heating surface or economizer heating surface 10.
- a bypass line 4 branches off.
- a flow control valve 6 is provided, which can be regulated by a controllable motor 8.
- a simple control valve can also be provided, but a fast-reacting control valve enables better adjustment of the subcooling at the evaporator inlet.
- Part of the flow medium S thus flows into the bypass line 4 depending on the position of the flow control valve 6, another part flows through a first economizer heating surface 10 and then another economizer heating surface 14.
- the flow medium is at the outlet of the economizer heating surface 14 at a mixing point 12 from the bypass line 4 and the economizer heating surface 14 before it enters the downstream evaporator 16.
- the economizer heating surfaces 10, 14 and the evaporator 16 are possible on the flue gas side.
- the economizer heating surfaces 10, 14 are connected downstream of the evaporator 16 on the flue gas side, since the economizers carry the comparatively coldest flow medium and should use the residual heat in the flue gas duct, not shown in detail.
- there should be sufficient subcooling at the evaporator inlet i.e. a sufficient difference from the current temperature to the saturation temperature in the evaporator, so that an exclusively liquid flow medium is present. This is the only way to ensure that the flow medium is reliably distributed over the individual evaporator tubes in the evaporator 16.
- a pressure measuring device 20 and a temperature measuring device 22 are provided at this point.
- a subcooling setpoint 26 is initially specified at the evaporator inlet. This can be, for example, 3 K, ie the temperature at the evaporator inlet should be 3 K below the saturation temperature in the evaporator 16.
- a saturation temperature 28 of the evaporator 16 is determined from the pressure determined at the pressure measuring device 20, since this is a direct function of the pressure prevailing in the evaporator 16.
- the flow rate of the bypass line 4 is controlled or regulated as a function of a heat energy characteristic parameter 30 supplied to the waste heat steam generator and as a function of a subcooling setpoint 26 at the inlet of the evaporator 16 and also as a function of a superheating setpoint 110 at the outlet of the evaporator 16.
- the superheating setpoint 110 specifies a setpoint for an outlet temperature of the flow medium at the evaporator 16.
- a pressure measuring device 121 and a temperature measuring device 131 are provided at this point extended regulating and control device 100 'are processed accordingly.
- FIG 1 another feedwater control device SWS for controlling the main feedwater valve 141 is outlined.
- the control takes place here with a corresponding feedwater control device SWS, as it is, for example, already from the WO 2009/150055 A2 is known.
- the pressures ⁇ PS> and ⁇ PD> as well as the temperatures ⁇ TS> and ⁇ TD> before and after the evaporator are tapped, processed accordingly by the feed water control device SWS and then passed on as a control signal ⁇ S> to the motor 142 of the feed water main valve.
- this feed water control is not the subject of the present invention, the controls of the flow control valve 6 of the bypass line and the main feed water valve 141 must be coordinated in their respective control behavior in order to ensure reliable operation of the waste heat steam generator in all load ranges.
- the evaporator flow rate can be temporarily reduced by reducing the evaporator inlet temperature (opening the flow control valve 6 of the bypass line 4) and thus the outlet temperature can be supported.
- the evaporator inlet temperature must be increased (closing the flow control valve 6 of the bypass line 4) in order to counteract an increase in the evaporator outlet temperature by temporarily increasing the evaporator flow rate.
- the maximum evaporator inlet temperature should not be exceeded or the minimum required inlet subcooling should not be undercut.
- the method according to the invention presupposes that the extended regulating and control device 100 ′ is actually able to influence the evaporator inlet temperature in the desired direction. Specifically, this means that for a further reduction in the evaporator inlet temperature, the flow control valve 6 must not already be fully open, while it should not be fully closed for an increase.
- FIG 2 now shows a further detailing of the in FIG 1 shown principle control concept.
- a difference is first formed between the determined overheating at the evaporator outlet and an overheating setpoint 110 and then a change in this difference over time is calculated.
- This is done optimally by using an additional first-order differentiator 151, the input of which is connected to the difference between the setpoint and actual overheating.
- the output of this differentiating element 151 is advantageously multiplied by the time-delayed value 152 of the parameter 30 characteristic of a supplied thermal energy and added to the setpoint value 26 for subcooling. In order not to fall below the required minimum subcooling at the evaporator inlet, this total must also be secured with the desired minimum subcooling 154 via a max selection element 155.
- FIG 3 shows a further embodiment in which the feedwater control valve 141 is arranged in front of the first economizer heating surface 10 and the integration 12 'of the bypass line 4 between the two economizer heating surfaces 10 and 14 is provided.
- the extended regulating and control device 100 now also takes into account in the sense of a classic two-circuit control in comparison to the exemplary embodiment in FIG 2 the time-delayed value 157 of the temperature at the inlet of the economizer 14 determined with the aid of a further measuring device 156.
Description
Die Erfindung betrifft ein Verfahren zum Betreiben eines Abhitzedampferzeugers gemäß dem Oberbegriff des Anspruchs 1, insbesondere zur lastabhängigen Regelung eines nach dem Zwangdurchlaufprinzip ausgebildeten Abhitzedampferzeugers.The invention relates to a method for operating a waste heat steam generator according to the preamble of claim 1, in particular for load-dependent control of a waste heat steam generator designed according to the forced flow principle.
Aus der
Bei der Regelung bzw. Steuerung der Speisewassermenge eines nach dem Zwangdurchlaufprinzip ausgebildeten Abhitzedampferzeugers hat sich herausgestellt, dass sich lastabhängige instationäre Temperaturschwankungen des aus dem Verdampfer austretenden Strömungsmediums ausschließlich mit dem aus der beispielsweise
Aufgabe der Erfindung ist es daher, ein optimiertes Verfahren zum Betreiben eines Abhitzedampferzeugers bereit zu stellen.The object of the invention is therefore to provide an optimized method for operating a waste heat steam generator.
Diese Aufgabe wird mit dem Verfahren mit den Merkmalen des Anspruchs 1 gelöst.This object is achieved with the method having the features of claim 1.
Mit dem erfindungsgemäßen Verfahren können, ohne größeren zusätzlichen Aufwand, auch während eines instationären Betriebs des Abhitzedampferzeugers auftretende Schwankungen der Verdampferaustrittstemperatur effektiv minimiert werden. Konkret bedeutet dies, dass die Bauteilbelastung des Abhitzedampferzeugers bei gegebenen transienten Anforderungen weiter reduziert werden kann oder bei vergleichsweise gleicher Bauteilbelastung die Anlagenflexibilität weiter gesteigert werden kann. Dazu sind bei der aus der
Vorteilhafte Weiterbildungen des erfindungsgemäßen Verfahrens sind den Unteransprüchen zu entnehmen.Advantageous further developments of the method according to the invention can be found in the subclaims.
Die Erfindung soll nun anhand der nachfolgenden Figuren beispielhaft erläutert werden. Es zeigen:
- FIG 1
- schematisch eine erste Ausbildung zur optimierten Regelung,
- FIG 2
- schematisch eine Detaillierung des in
FIG 1 gezeigten Ausführungsbeispiels, - FIG 3
- schematisch ein zweites Ausführungsbeispiel.
- FIG 1
- a schematic of an initial training for optimized control,
- FIG 2
- schematically a detailing of the in
FIG 1 shown embodiment, - FIG 3
- schematically a second embodiment.
Rauchgasseitig sind verschiedene Anordnungen der Economizerheizflächen 10, 14 und des Verdampfers 16 möglich. Üblicherweise sind jedoch die Economizerheizflächen 10, 14 dem Verdampfer 16 rauchgasseitig nachgeschaltet, da die Economizer das vergleichsweise kälteste Strömungsmedium führen und die Restwärme im nicht näher dargestellten Rauchgaskanal nutzen sollen. Um einen reibungslosen Betrieb des Abhitzedampferzeugers zu gewährleisten, sollte am Verdampfereintritt eine ausreichende Unterkühlung, das heißt eine ausreichende Differenz von aktueller Temperatur zur Sättigungstemperatur im Verdampfer vorliegen, so dass ein ausschließlich flüssiges Strömungsmedium vorliegt. Nur so kann sichergestellt werden, dass eine zuverlässige Verteilung des Strömungsmediums auf die einzelnen Verdampferrohre im Verdampfer 16 erfolgt. Zur Regelung der Unterkühlung am Verdampfereintritt sind an dieser Stelle eine Druckmesseinrichtung 20 sowie eine Temperaturmesseinrichtung 22 vorgesehen. Regelungsseitig wird zunächst ein Unterkühlungssollwert 26 am Verdampfereintritt vorgegeben. Dieser kann beispielsweise 3 K betragen, d. h., die Temperatur am Verdampfereintritt soll 3 K unterhalb der Sättigungstemperatur im Verdampfer 16 liegen. Aus dem an der Druckmesseinrichtung 20 ermittelten Druck wird eine Sättigungstemperatur 28 des Verdampfers 16 ermittelt, da diese eine direkte Funktion des im Verdampfer 16 herrschenden Drucks ist. Die aus der
Erfindungsgemäß ist nun eine, gegenüber der aus der
Der Vollständigkeit halber ist in
Vor dem Hintergrund physikalischer Grundlagen resultieren bei einem nach dem Zwangdurchlaufprinzip ausgebildeten Abhitzedampferzeuger schwankende Eintrittstemperaturen in Schwankungen der Austrittstemperatur. Dabei münden fallende Eintrittstemperaturen aufgrund sinkender spezifischer Volumina und dem damit unmittelbar verknüpften Rückgang des Verdampferdurchflusses in steigende Temperaturen beziehungsweise Überhitzungen am Verdampferaustritt. Umgekehrt gilt entsprechendes. Im Allgemeinen ist dies ein unerwünschter Effekt während des instationären Betriebs, der durch geeignet implementierte Gegenmaßnahmen im Regelungskonzept für das Speisewasserhauptventil 141 möglichst kompensiert werden sollte. Aufgrund der heute üblich zur Anwendung kommenden hohen Lastgradienten ist dies allerdings nicht immer ausschließlich durch die Speisewasserregelung möglich. Für eine Verbesserung dieser Situation wird die vorliegende Erfindung herangezogen, die nun aber genau den umgekehrten Weg geht und sich diesen zuvor beschriebenen unerwünschten physikalischen Effekt zu Nutze macht. Dabei wird durch gezielte Manipulation beziehungsweise Veränderung der Verdampfereintrittstemperatur in geeigneter Art und Weise auf Abweichungen der Verdampferaustrittstemperatur zum vorgegebenen Sollwert reagiert, um so Schwankungen der Austrittstemperatur möglichst gering zu halten. Sinkt im instationären Fall beispielsweise die Verdampferaustrittstemperatur unerwünscht stark ab, so kann durch eine Reduzierung der Verdampfereintrittstemperatur (Öffnen des Durchflussregelventils 6 der Bypassleitung 4) der Verdampferdurchfluss temporär reduziert werden und somit die Austrittstemperatur gestützt werden. Für den umgekehrten Fall ist die Verdampfereintrittstemperatur zu erhöhen (Schließen des Durchflussregelventils 6 der Bypassleitung 4), um durch eine temporäre Erhöhung des Verdampferdurchflusses einem Anstieg der Verdampferaustrittstemperatur entgegen zu wirken. Hierbei gilt es jedoch zu beachten, dass vor dem Hintergrund thermohydraulischer Gesichtspunkte eine maximale Verdampfereintrittstemperatur nicht überschritten- bzw. eine minimal geforderte Eintrittsunterkühlung nicht unterschritten werden sollte. Darüber hinaus setzt das erfindungsgemäße Verfahren voraus, dass die erweiterte Regel- und Steuereinrichtung 100' auch tatsächlich in der Lage ist, die Verdampfereintrittstemperatur in die gewünschte Richtung zu beeinflussen. Konkret bedeutet dies, dass für eine weitere Reduzierung der Verdampfereintrittstemperatur das Durchflussregelventil 6 nicht schon bereits vollständig geöffnet sein darf, während es für eine Erhöhung nicht vollständig geschlossen sein sollte. Darüber hinaus ist es besonders vorteilhaft für das hier vorgestellte Verfahren, wenn der um die Economizerheizflächen herumgeführte Nebenstrom nicht bereits vor der letzten Economizerstufe, sondern direkt am Verdampfereintritt dem Hauptstrom des Strömungsmediums wieder beigemischt wird, da nur auf diesem Weg die unter Umständen erforderliche schnelle Änderung der Verdampfereintrittstemperatur gewährleistet werden kann. Die Gefahr einer Einbindung des Bypass Stroms am Verdampfereintritt liegt allerdings in einer möglichen Dampfbildung in der letzten Economizerstufe, was es zu vermeiden gilt. Eine Verlagerung des Speisewasserregelventils vom Eintritt der ersten Economizerstufe (so wie in
Kommt bei einem nach dem Zwangdurchlaufprinzip ausgebildeten Abhitzedampferzeuger das erfindungsgemäße Verfahren zur Anwendung, lassen sich Schwankungen der Überhitzung am Verdampferaustritt wirkungsvoll reduzieren, wie Simulationen eines unterkritischen Verdampferssystems eines solchen zwangdurchströmten Abhitzedampferzeugers gezeigt haben. Die Schwankungen der Verdampferaustrittsüberhitzung belaufen sich dabei ohne Anwendung des hier aufgezeigten Verfahrens auf circa 90K während diese Schwankungen bei Anwendung des erfindungsgemäßen Konzepts auf circa 50K reduziert werden können.If the method according to the invention is used in a waste heat steam generator designed according to the forced flow principle, fluctuations in overheating at the evaporator outlet can be effectively reduced, as simulations of a subcritical evaporator system of such a forced flow waste heat steam generator have shown. The fluctuations in the superheating of the evaporator outlet amount to approximately 90K without using the method shown here, while these fluctuations can be reduced to approximately 50K when using the inventive concept.
Claims (3)
- Method for operating a waste heat steam generator, in particular one designed according to the forced flow principle, comprising an evaporator (16) through which a flow medium flows, an economizer with a number of economizer heating surfaces (10, 14), and a bypass line (4) connected in parallel with a number of economizer heating surfaces (10, 14) on the flow medium side, in which a variable (30) that is characteristic of the heat energy supplied to the waste heat steam generator (1) is used for controlling or regulating the flow rate of the bypass line (4), and wherein the regulation or control of the flow rate of the flow medium through the bypass line (4) is carried out as a function of a supercooling setpoint (26) at the inlet of the evaporator (16),
wherein the regulation or control of the flow rate of the flow medium through the bypass line (4) is additionally carried out as a function of a superheating setpoint (110) at the outlet of the evaporator (16), characterized in that the flow rate of the flow medium through the bypass line (4) is increased when the superheating setpoint (110) is undershot, and the flow rate of the flow medium through the bypass line (4) is lowered when the superheating setpoint (110) is exceeded. - Method according to Claim 1,
wherein the superheating setpoint (110) is predefined as a setpoint for an outlet temperature of the flow medium at the evaporator (16). - Method according to one of Claims 1 to 2, wherein the supercooling setpoint (26) is predefined as a setpoint for an inlet temperature of the flow medium at the evaporator (16).
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
PCT/EP2016/068732 WO2018024340A1 (en) | 2016-08-05 | 2016-08-05 | Method for operating a waste heat steam generator |
Publications (2)
Publication Number | Publication Date |
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EP3472514A1 EP3472514A1 (en) | 2019-04-24 |
EP3472514B1 true EP3472514B1 (en) | 2021-02-24 |
Family
ID=56694118
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
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EP16753305.8A Active EP3472514B1 (en) | 2016-08-05 | 2016-08-05 | Method for operating a waste heat steam generator |
Country Status (8)
Country | Link |
---|---|
US (1) | US10948178B2 (en) |
EP (1) | EP3472514B1 (en) |
JP (1) | JP2019527808A (en) |
KR (1) | KR102245954B1 (en) |
CN (1) | CN109563985B (en) |
CA (1) | CA3032784C (en) |
ES (1) | ES2870673T3 (en) |
WO (1) | WO2018024340A1 (en) |
Families Citing this family (1)
Publication number | Priority date | Publication date | Assignee | Title |
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EP3647657A1 (en) * | 2018-10-29 | 2020-05-06 | Siemens Aktiengesellschaft | Feed water control for forced throughput by-product steam generator |
Family Cites Families (11)
Publication number | Priority date | Publication date | Assignee | Title |
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US3818872A (en) * | 1973-06-29 | 1974-06-25 | Combustion Eng | Economizer bypass for increased furnace wall protection |
JPS56165204U (en) | 1980-05-12 | 1981-12-08 | ||
JPS6291703A (en) | 1985-10-16 | 1987-04-27 | 株式会社日立製作所 | Steaming preventive device for fuel economizer |
JPH0275802A (en) * | 1988-09-13 | 1990-03-15 | Toshiba Corp | Waste heat recovery boiler |
WO2003024559A1 (en) * | 2001-09-14 | 2003-03-27 | Alstom Technology Ltd | Method and device for thermal de-gassing |
EP2255076B1 (en) * | 2008-02-26 | 2015-10-07 | Alstom Technology Ltd | Method for regulating a boiler and control circuit for a boiler |
EP2194320A1 (en) | 2008-06-12 | 2010-06-09 | Siemens Aktiengesellschaft | Method for operating a once-through steam generator and once-through steam generator |
EP2224164A1 (en) * | 2008-11-13 | 2010-09-01 | Siemens Aktiengesellschaft | Method of operating a waste heat steam generator |
DE102010028426A1 (en) * | 2010-04-30 | 2011-11-03 | Siemens Aktiengesellschaft | steam generator |
US10132492B2 (en) * | 2013-10-02 | 2018-11-20 | General Electric Company | System and method for drum level control in a drum of a heat recovery steam generator |
MX2016014151A (en) * | 2014-04-28 | 2017-02-15 | General Electric Technology Gmbh | System and method for fluid medium preheating. |
-
2016
- 2016-08-05 ES ES16753305T patent/ES2870673T3/en active Active
- 2016-08-05 CN CN201680088310.0A patent/CN109563985B/en active Active
- 2016-08-05 KR KR1020197005914A patent/KR102245954B1/en active IP Right Grant
- 2016-08-05 CA CA3032784A patent/CA3032784C/en active Active
- 2016-08-05 JP JP2019506098A patent/JP2019527808A/en active Pending
- 2016-08-05 EP EP16753305.8A patent/EP3472514B1/en active Active
- 2016-08-05 WO PCT/EP2016/068732 patent/WO2018024340A1/en unknown
- 2016-08-05 US US16/314,905 patent/US10948178B2/en active Active
Non-Patent Citations (1)
Title |
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Also Published As
Publication number | Publication date |
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JP2019527808A (en) | 2019-10-03 |
KR102245954B1 (en) | 2021-04-30 |
US20190338944A1 (en) | 2019-11-07 |
CA3032784C (en) | 2020-08-18 |
WO2018024340A1 (en) | 2018-02-08 |
EP3472514A1 (en) | 2019-04-24 |
KR20190031557A (en) | 2019-03-26 |
CN109563985A (en) | 2019-04-02 |
US10948178B2 (en) | 2021-03-16 |
ES2870673T3 (en) | 2021-10-27 |
CN109563985B (en) | 2021-06-25 |
CA3032784A1 (en) | 2018-02-08 |
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