EP3472285A1 - (c8-10)-alkylamidoalkylbétaïne comme substance active anti-froissage - Google Patents
(c8-10)-alkylamidoalkylbétaïne comme substance active anti-froissageInfo
- Publication number
- EP3472285A1 EP3472285A1 EP16810387.7A EP16810387A EP3472285A1 EP 3472285 A1 EP3472285 A1 EP 3472285A1 EP 16810387 A EP16810387 A EP 16810387A EP 3472285 A1 EP3472285 A1 EP 3472285A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- washing
- formula
- cleaning agent
- carbon atoms
- agent according
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/88—Ampholytes; Electroneutral compounds
- C11D1/90—Betaines
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/88—Ampholytes; Electroneutral compounds
- C11D1/94—Mixtures with anionic, cationic or non-ionic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/38—Products with no well-defined composition, e.g. natural products
- C11D3/386—Preparations containing enzymes, e.g. protease or amylase
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
- D06M13/325—Amines
- D06M13/342—Amino-carboxylic acids; Betaines; Aminosulfonic acids; Sulfo-betaines
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
- D06M13/402—Amides imides, sulfamic acids
- D06M13/405—Acylated polyalkylene polyamines
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
- D06M13/46—Compounds containing quaternary nitrogen atoms
- D06M13/461—Quaternised amin-amides from polyamines or heterocyclic compounds or polyamino-acids
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/22—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aromatic compounds
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
- D06M2200/20—Treatment influencing the crease behaviour, the wrinkle resistance, the crease recovery or the ironing ease
Definitions
- the present invention relates to a washing or cleaning agent for textiles, which has ce-alkylamidoalkylbetain as Antiknitterwirkstoff and a special additional surfactant combination and the use of Cs-io-Alkylamidoalkylbetain as Antiknitterwirkstoff for textiles.
- Ironing is a very annoying task, according to consumer surveys. So far, it has not yet been possible to develop a detergent that improves the surface smoothness of clothing after washing to the extent that the ironing is unnecessary.
- alkylamidoalkylbetaines improves the cleaning performance of such spots (enzyme-selective spots) whose removal is improved by the use of enzymes (in particular of protease).
- Alkylamidopropylbetaine (abbreviated APB) as surfactants for cosmetic purposes and as a cleaning agent and is based on the low irritant effect of Cs / ioAPB.
- APB Alkylamidopropylbetaine
- DE 2926479 B1 discloses the preparation C6-C18 Alkylamidopropylbetainen.
- cocoalkylamidoalkylbetaine it is not apparent from the prior art that the surface smoothness of the textile during the washing process, as well as the cleaning performance of enzyme-selective stains, can be improved by using cocoalkylamidoalkylbetaine.
- the object underlying the invention is achieved by a washing or cleaning agent for textiles comprising
- R is a, preferably linear, alkyl radical having 7, 8 or 9 carbon atoms
- n 2, 3, 4, 5 or 6 (in particular 3) and
- R 2 and R 3 are identical or different alkyl radicals having 1 to 3 carbon atoms, preferably methyl,
- R is C-NH (CH 2 ) n N + (R 2 ) (R 3 ) CH 2 COO- (II)
- R is a, preferably linear, alkyl radical having 10 to 30 carbon atoms
- n 2, 3, 4, 5 or 6 (in particular 3) and
- R 2 and R 3 are identical or different alkyl radicals having 1 to 3 carbon atoms, preferably methyl, the weight ratio of C 3-10 -alkylamido (C 2-6) alkylbetaine of formula (I) to C 3 -oalkylamido ( C 2-6) -alkylbetain of the formula (II) greater than 1, preferably greater than 2, more preferably greater than 4, even more preferably greater than 10, most preferably greater than 20.
- the cocoidoamido (C 2-6) -alkylbetaines of the formula (I) are used in a total amount of from 0.01 1% by weight to 35% by weight, in particular from 0.01 1 wt .-% to 10 wt .-%, are included. All amounts stated in connection with the detergents or cleaners described herein are, unless stated otherwise, by weight in each case based on the total weight of the washing or cleaning agent. Furthermore, such quantities, which relate to at least one component, always refer to the
- At least one anionic surfactant based on the total amount of anionic surfactants contained in the composition.
- washing or cleaning agents thereof containing as betaine of the formula (I) those which are selected from at least one compound of the formula (I-a)
- R is -C-NH (CH 2 ) 3 -N + -CH 2 COO- (Ia)
- R is a, preferably linear, alkyl radical having 7, 8 or 9 carbon atoms.
- alkylamidopropyl betaines of the formula (I) or (I-a) are preferably selected from linear C 8 or C 10 alkylamidopropyl betaine, i.
- Caprylamidopropyl betaine N- (3-octanoyl) aminopropyl) -N-carboxymethyl-N, N-dimethyl-1-propanaminium
- Capramidopropylbetaine N- (3-decanoyl) aminopropyl) -N-carboxymethyl-N, N-dimethyl-1-propanaminium
- Such a betaine blend is commercially available, for example, as Tegotens® B 810 from Evonik Industries.
- betaines of the formula (I-a) are a selection criterion, it is again very particularly preferred that if betaine of the formula (II-a) is contained,
- R is a, preferably linear, alkyl radical having 10 to 30 carbon atoms
- R 2 and R 3 are identical or different alkyl radicals having 1 to 3 carbon atoms, preferably methyl, the weight ratio of betaine of the formula (Ia) to be contained betaine of formula (II-a) greater than 1, preferably greater than 2, particularly preferably greater than 4 , most preferably greater than 10, most preferably greater than 20.
- the indication of the number of carbon atoms not only refers to the carbon atoms of the alkyl chain but also includes the carbonyl carbon atom of the amide group.
- the situation is different when a concrete structural formula (see formulas (I), (I-a), (II), (II-a)) is shown.
- the radical R relates exclusively to the carbon atoms of the alkyl chain.
- the detergents or cleaners of the invention do not comprise cocoamidopropylbetaine.
- Cocoamidopropyl betaine is a mixture of Cs-ds
- Alkylamidopropyl betaine as EP071 1545 B1 discloses. This means that in certain embodiments, the short chain alkylamidopropyl betaines are not
- Cocoamidopropyl betaine come.
- washing or cleaning agents according to the invention contain, in addition to at least one
- Compound of the formula (I) (in particular of the formula (I-a)) additionally at least one
- Alkylbenzenesulfonate as anionic surfactant.
- the at least one alkyl benzene sulfonate is a linear or branched Ce-19 alkyl benzene sulfonate, preferably a C9-13 linear alkyl benzene sulfonate (LAS).
- the amount of alkylbenzenesulfonate is 2 wt% to 60 wt%, 2 wt% to 40 wt%, 2 wt% to 25 wt%, 5 wt% to 20%, 7% to 18%, 9% to 16%, 1 to 14%, 2.5%, by weight to 20 wt .-%, 2.5 wt .-% to 18 wt .-% or 5 wt .-% to 18 wt .-% based on the total weight of the detergent or cleaning agent.
- the at least one alkyl benzene sulfonate is a C9-13 alkyl benzene sulfonate (LAS).
- Suitable alkylbenzenesulfonates are preferably selected from linear or branched alkylbenzenesulfonates of the formula
- a particularly preferred representative is sodium dodecylbenzylsulfonate.
- the washing or cleaning agent according to the invention contains at least one further surfactant selected from anionic surfactant, nonionic surfactant or mixtures thereof. This surfactant is of course different from the compounds of formulas (I) and (I-a).
- anionic surfactants for example, those of the sulfonate type and sulfates are used.
- surfactants of the sulfonate type preferably olefinsulfonates, i. Mixtures of alkene and hydroxyalkanesulfonates and disulfonates, as obtained for example from Ci2-i8 monoolefins with terminal or internal double bond by sulfonation with gaseous sulfur trioxide and subsequent alkaline or acid hydrolysis of the sulfonation, into consideration.
- Alkanesulfonates which are obtained from C 12 -alkanes, for example by sulfochlorination or sulfoxidation with subsequent hydrolysis or neutralization, are also suitable.
- esters of ⁇ -sulfo fatty acids e.g. the ⁇ -sulfonated methyl esters of hydrogenated coconut, palm kernel or tallow fatty acids suitable.
- Alk (en) ylsulfates are the alkali metal and in particular the sodium salts of
- Sulfuric acid half esters of C 12 -18 fatty alcohols for example from coconut fatty alcohol,
- alk (en) ylsulfates of said chain length which contain a synthetic, produced on a petrochemical basis straight-chain alkyl radical, which have an analogous degradation behavior as the adequate compounds based on oleochemical raw materials.
- Ci2-Ci6-alkyl sulfates and Ci2-Ci5-alkyl sulfates and C14-C15-alkyl sulfates are preferred.
- the washing or cleaning agent according to the invention particularly preferably contains
- Sulfuric acid monoesters of ethoxylated with 1 to 6 moles of ethylene oxide straight or branched C7-2i alcohols such as 2-methyl-branched C9-n-alcohols having an average of 3.5 moles of ethylene oxide (EO) or Ci2-i8 fatty alcohols having 1 to 4 EO.
- EO ethylene oxide
- Ci2-i8 fatty alcohols having 1 to 4 EO.
- Alkyl ether sulfates are selected from at least one compound of the formula
- R is a linear or branched, substituted or unsubstituted alkyl radical, preferably a linear, unsubstituted alkyl radical, more preferably a fatty alcohol radical.
- Preferred radicals R are selected from decyl, undecyl, dodecyl, tridecyl, tetradecyl, pentadecyl, hexadecyl, heptadecyl, octadecyl, nonadecyl, eicosyl radicals and mixtures thereof, where the representatives with even number of carbon atoms are preferred.
- radicals R are derived from C 12-18 fatty alcohols, for example coconut fatty alcohol, tallow fatty alcohol, lauryl, myristyl, cetyl or stearyl alcohol or C 10 -C 20 oxo alcohols.
- AO represents an ethylene oxide (EO) or propylene oxide (PO) moiety, preferably an ethylene oxide moiety.
- EO ethylene oxide
- PO propylene oxide
- the index n stands for an integer from 1 to 50, preferably from 1 to 20 and especially from 2 to 10. Most preferably, n stands for the numbers 2, 3, 4, 5, 6, 7 or 8.
- X stands for a monovalent cation or the nth part of an n-valent cation, the alkali metal ions are preferred, and Na + or K + including Na, with Na + being extremely preferred.
- Other cations X + can be selected from NhV,
- the alkyl ether sulfate may be selected from
- Degree of ethoxylation represents a statistical average that may be an integer or a fractional number for a particular product.
- the indicated degrees of alkoxylation represent statistical averages, which may be an integer or a fractional number for a particular product.
- Preferred alkoxylates / ethoxylates have a narrow homolog distribution (narrow rank ethoxylates, NRE).
- anionic surfactants does not mean soaps
- the detergents according to the invention may comprise soaps, but they are not included in the scope of the present invention as anionic surfactants.
- anionic surfactants are the freedom from formulation no conditions to be observed in the way. It is only to be considered that soaps are not counted among the anionic surfactants. It is very particularly preferred according to the invention when the detergent or cleaning agent as additional surfactant (i) at least one linear C9-13 alkylbenzenesulfonate and (ii) at least one alkyl ether sulfate of the formula
- R is -O- (AO) n -SO 3 - X + in which R is a linear or branched, substituted or unsubstituted alkyl radical (preferably R radicals are derived from C 12-18 fatty alcohols, for example coconut fatty alcohol, tallow fatty alcohol, lauryl , Myristyl, cetyl or stearyl alcohol or C10-C20 oxo alcohols), AO represents an ethylene oxide (EO) or propylene oxide (PO) grouping, (preferably an ethylene oxide grouping), the subscript n represents an integer of 1 to 50 (preferably from 2 to 10.
- n is the numbers 2, 3, 4, 5, 6, 7 or 8
- X is a monovalent cation or the nth part of an n-valent cation (Preferred are the alkali metal ions and below Na + or K + , with Na + being highly preferred.) Further cations X + can be selected from NhV, V Zn 2+ , V 2 Mg 2+ , 1 ⁇ Ca 2+ , 1 ⁇ Mn 2+ , and their mixtures).
- soaps come as additional ingredients of detergents or cleaning agents into consideration.
- Suitable are saturated fatty acid soaps, such as the salts of lauric acid, myristic acid, palmitic acid, stearic acid, hydrogenated erucic acid and behenic acid, and in particular of natural fatty acids, e.g. Coconut, palm kernel or tallow fatty acids, derived soap mixtures.
- anionic surfactants as well as soaps may be present in the form of their sodium, potassium or ammonium salts and as soluble salts of organic bases, such as mono-, di- or triethanolamine.
- the anionic surfactants and soaps are preferably present in the form of their monoethanolammonium, sodium, potassium or magnesium salts, in particular in the form of the sodium salts.
- Anionic surfactants i. in particular alkylbenzenesulfonates and alkyl ether sulfates, are preferably present in the washing or cleaning agent to a certain proportion by weight, namely with 3 to 25 wt .-% based on the total weight of the washing or
- Detergent formulation Preference is given to amounts of from 5 to 20% by weight of anionic surfactants, based on the total weight of the detergent formulation. Regardless of whether the detergent contains one or more of the anionic surfactants, the amounts given refer to the total amount of all anionic surfactants contained in the detergent.
- the detergents or cleaning agents further comprise soaps, preferably 0, 1 to 5 wt .-% soaps. Preferably, the washing or cleaning agents have no soaps.
- the washing or cleaning agents according to the invention preferably contain as additional surfactant, at least one nonionic surfactant.
- the inventive detergent or cleaning agent as an additional surfactant at least one anionic surfactant and at least one nonionic surfactant.
- the nonionic surfactants used are preferably alkoxylated, advantageously ethoxylated, in particular primary, alcohols having preferably 8 to 18 carbon atoms and on average 1 to 12 moles of ethylene oxide (EO) per mole of alcohol, in which the alcohol radical can be linear or preferably methyl-branched in the 2-position or linear and methyl-branched radicals in the mixture can contain, as they are usually present in Oxoalkoholresten.
- alcohol ethoxylates having linear radicals of alcohols of native origin having 12 to 18 carbon atoms, e.g. from coconut, palm, tallow or oleyl alcohol, and on average from 2 to 8 EO per mole of alcohol.
- the preferred ethoxylated alcohols include, for example, C 12-14 alcohols with 3 EO or 4 EO, Cg-n-alcohol with 7 EO, cis-is alcohols with 3 EO, 5 EO, 7 EO or 8 EO, C 12-18 Alcohols with 3 EO, 5 EO or 7 EO and mixtures of these, such as mixtures of C12-14 alcohol with 3 EO and Ci2-is-alcohol with 5 EO.
- the degrees of ethoxylation given represent statistical means which, for a particular product, may be an integer or a fractional number.
- Preferred alcohol ethoxylates have a narrow homolog distribution (narrow rank ethoxylates, NRE).
- fatty alcohols with more than 12 EO can also be used. Examples include tallow fatty alcohol with 14 EO, 25 EO, 30 EO or 40 EO.
- nonionic surfactants used either as the sole nonionic surfactant or in combination with other nonionic surfactants are alkoxylated, preferably ethoxylated or ethoxylated and propoxylated fatty acid alkyl esters, preferably having from 1 to 4 carbon atoms in the alkyl chain, especially fatty acid methyl esters.
- alkyl polyglycosides Another class of nonionic surfactants that can be used to advantage are the alkyl polyglycosides (APG).
- APG alkyl polyglycosides
- Usable alkylpolyglycosides satisfy the general formula RO (G) z , in which R is a linear or branched, in particular in the 2-position methyl-branched, saturated or unsaturated, aliphatic radical having 8 to 22, preferably 12 to 18 carbon atoms and G is the Is a symbol which represents a glycose unit having 5 or 6 C atoms, preferably glucose.
- the glycosidation degree z is between 1, 0 and 4.0, preferably between 1, 0 and 2.0 and in particular between 1, 1 and 1, 4.
- Nonionic surfactants of the amine oxide type for example N-cocoalkyl-N, N-dimethylamine oxide and N-tallowalkyl-N, N-dihydroxyethylamine oxide, and the fatty acid alkanolamides may also be suitable.
- the amount of these nonionic surfactants is preferably not more than that of the ethoxylated fatty alcohols, especially not more than half thereof. It is inventively preferred if the washing or cleaning agent has a total surfactant content of 5.0 to 80.0 wt .-%, in particular from 8.0 to 65 wt .-%, each based on the weight of said agent.
- the agent according to the invention in particular liquid washing or liquid cleaning agents, preferably contains water. It is preferred that the inventive compositions more than 5 wt .-%, preferably more than 15 wt .-% and particularly preferably more than 25 wt .-%, water.
- non-aqueous solvents may be added to the compositions according to the invention.
- Suitable non-aqueous solvents include mono- or polyhydric alcohols, alkanolamines or glycol ethers, provided that they are miscible with water in the specified concentration range.
- the solvents are preferably selected from ethanol, n-propanol, i-propanol, butanols, glycol, propanediol, butanediol, methylpropanediol, glycerol, diglycol, propyldiglycol, butyldiglycol, hexyleneglycol, ethylene glycol methyl ether, ethylene glycol ethyl ether,
- Ethylene glycol propyl ether ethylene glycol mono-n-butyl ether, diethylene glycol methyl ether, diethylene glycol ethyl ether, propylene glycol methyl ether, propylene glycol ethyl ether,
- Propylene glycol propyl ether dipropylene glycol monomethyl ether, dipropylene glycol monoethyl ether, methoxytriglycol, ethoxytriglycol, butoxytriglycol, 1-butoxyethoxy-2-propanol, 3-methyl-3-methoxybutanol, propylene glycol t-butyl ether, di-n-octyl ether and mixtures of these solvents.
- the inventive compositions if they contain more than 15 wt .-% water, an alcohol, especially ethanol and / or glycerol, in amounts between 0.5 and 5 wt .-%.
- compositions according to the invention can likewise be present in a water-poor form.
- the washing or cleaning agents are in the form of a liquid and have water in a total amount of preferably less than 15 wt .-% (in particular 1, 0 to 14.99 wt .-%), particularly preferably less than 10 wt .-%, (in particular 1, 0 to 9.99 wt .-%), each based on the weight of the composition on.
- each of the low-water compositions is in each case based on the total weight of the liquid composition a total amount of
- anionic surfactant at least one C9-i 3-alkylbenzenesulfonate is contained, and
- nonionic surfactant containing as nonionic surfactant at least one alkoxylated alcohol having 8 to 18 carbon atoms and on average 4 to 12 moles of ethylene oxide (EO) per mole of alcohol, contain.
- EO ethylene oxide
- water-poor compositions according to the invention can be present in pre-portioned form, wherein the washing or cleaning agent according to the invention is filled into a water-soluble coating of water-soluble material and thus can be part of a water-soluble packaging. If the washing or cleaning agent according to the invention is packaged in a water-soluble casing, it is preferred that the content of water is less than 10% by weight, based on the total agent, and that anionic surfactants, if present, are present in the form of their ammonium salts ,
- the water solubility of the material can be determined using one in a square frame
- the cover is preferably made of a water-soluble film.
- This film may according to the invention preferably have a thickness of at most 150 ⁇ (more preferably of at most 120 ⁇ ).
- preferred casings are made of a water-soluble film and have a thickness of at most 150 ⁇ m (more preferably of at most 120 ⁇ m, very particularly preferably of not more than 90 ⁇ m).
- Such water-soluble portions may be obtained either by methods of vertical
- VFFS Form hypoxialversiegelns
- thermoforming method can be produced.
- the thermoforming process generally includes forming a first layer of water-soluble film material to form at least one protrusion for receiving at least one composition therein, filling the composition into the respective protrusion, covering the composition-filled protrusions with a second layer of water-soluble one Film material and sealing the first and second layers together at least around the protrusions.
- the water-soluble material preferably contains at least one water-soluble polymer.
- the water-soluble material preferably contains a water-soluble film material selected from polymers or polymer blends.
- the wrapper may be formed of one or two or more layers of the water-soluble film material.
- the water-soluble film material of the first layer and the further layers, if present, may be the same or different. It is preferable that the water-soluble material is polyvinyl alcohol or a
- Suitable water-soluble films as the water-soluble material are preferably based whose molecular weight CMO each in the range of 10,000 to 1,000,000 on a polyvinyl alcohol or a polyvinyl alcohol copolymer, preferably from 20,000 to 500,000 gmol ⁇ particularly preferably gmol 30,000 to 100,000 gmor and in particular from 40,000 to 80,000 "Polyl alcohol is usually produced by hydrolysis of polyvinyl acetate, since the direct route of synthesis is not possible.The same applies to polyvinyl alcohol copolymers which are prepared from polyvinyl acetate copolymers.
- at least one layer of the water-soluble material comprises a polyvinyl alcohol, its degree of hydrolysis 70 to 100 mol%, preferably 80 to 90 mol%, particularly preferably 81 to 89 mol% and in particular 82 to 88 mol%.
- the film material suitable as water-soluble material may additionally be added polymers selected from the group comprising acrylic acid-containing polymers, polyacrylamides, oxazoline polymers, polystyrene sulfonates, polyurethanes, polyesters, polyether polylactic acid, and / or mixtures of the above polymers.
- Preferred polyvinyl alcohol copolymers include, in addition to vinyl alcohol, dicarboxylic acids as further monomers.
- Suitable dicarboxylic acids are itaconic acid, malonic acid, succinic acid and
- polyvinyl alcohol copolymers include, in addition to vinyl alcohol, an ethylenically unsaturated carboxylic acid, its salt or its esters.
- Such polyvinyl alcohol copolymers particularly preferably contain, in addition to vinyl alcohol, acrylic acid, methacrylic acid, acrylates, methacrylates or mixtures thereof.
- Suitable water-soluble films for use as a water-soluble material are films sold under the name Monosol M8630 by MonoSol LLC.
- Other suitable films include films called Solublon® PT, Solublon® KA, Solublon® KC or
- Solublon® KL from Aicello Chemical Europe GmbH or the films VF-HP from Kuraray, or HiTorrent SH2312 from Nippon Gohsei.
- the detergents or cleaning agents may of course contain conventional ingredients of such agents.
- the washing or cleaning agent may contain other ingredients that further improve the performance and / or aesthetic properties of the detergent.
- the washing or cleaning agent preferably additionally contains one or more substances from the group of enzymes, bleaching agents, bleach activators, complexing agents, builders, electrolytes, non-aqueous
- Solvents pH adjusters, perfumes, perfume carriers, fluorescers, optical brighteners, dyes, speckies, hydrotropes, silicone oils, antiredeposition agents, grayness inhibitors, anti-shrinkage agents, crease inhibitors, color transfer inhibitors, antimicrobial agents, germicides, fungicides, antioxidants, preservatives, corrosion inhibitors, antistatic agents, bittering agents, Ironing aids, repellents and impregnating agents, swelling and anti-slip agents, softening components and UV absorbers.
- the compositions may nevertheless comprise speckles having soap components.
- the composition has soaps only in the speckles.
- Useful organic builder substances are, for example, the polycarboxylic acids which can be used in the form of their sodium salts, polycarboxylic acids meaning those carboxylic acids which carry more than one acid function.
- these are citric acid,
- Preferred salts are the salts of polycarboxylic acids such as citric acid, adipic acid, succinic acid, glutaric acid, tartaric acid, sugar acids and mixtures thereof.
- the acids themselves can also be used.
- the acids typically also have the property of an acidifying component and thus serve, for example, in US Pat
- Granules according to the invention also for adjusting a lower and milder pH of detergents or cleaners.
- citric acid, succinic acid, glutaric acid, adipic acid, gluconic acid and any desired mixtures of these can be mentioned here.
- polymeric polycarboxylates are suitable, these are for example the
- Alkali metal salts of polyacrylic acid or polymethacrylic acid for example, those having a molecular weight of 500 to 70,000 g / mol. This substance class has already been discussed in detail described above.
- the (co) polymeric polycarboxylates can be used either as a powder or as an aqueous solution.
- the content of (co) polymeric polycarboxylates in the compositions is preferably 0.5 to 20% by weight, in particular 3 to 10% by weight.
- the polymers may also contain allylsulfonic acids, such as, for example, in EP-B-0 727 448 allyloxybenzenesulfonic acid and methallylsulfonic acid, as a monomer.
- allylsulfonic acids such as, for example, in EP-B-0 727 448 allyloxybenzenesulfonic acid and methallylsulfonic acid
- biodegradable polymers of more than two different monomer units for example those which, according to DE-A-43 00 772, as monomers, salts of acrylic acid and maleic acid and vinyl alcohol or vinyl alcohol derivatives or according to DE-C-42 21 381 contain as monomers, salts of acrylic acid and 2-alkylallylsulfonic acid and sugar derivatives.
- copolymers are those which are described in the German patent applications DE-A-43 03 320 and DE-A-44 17 734 and preferably have as monomers acrolein and acrylic acid / acrylic acid salts or acrolein and vinyl acetate.
- polymeric aminodicarboxylic acids, their salts or their precursors are particularly preferred.
- polyaspartic acids or their salts and derivatives which is disclosed in the German patent application DE-A-195 40 086, that they also have a bleach-stabilizing effect in addition to cobuilder properties.
- polyacetals which can be obtained by reacting dialdehydes with polyolcarboxylic acids which have 5 to 7 C atoms and at least 3 hydroxyl groups, for example as described in European Patent Application EP-A-0 280 223.
- Preferred polyacetals are obtained from dialdehydes such as glyoxal, glutaraldehyde, terephthalaldehyde and mixtures thereof and from polyol carboxylic acids such as gluconic acid and / or glucoheptonic acid.
- organic builder substances are dextrins, for example oligomers or polymers of carbohydrates, which can be obtained by partial hydrolysis of starches.
- the hydrolysis can be carried out by customary, for example acid or enzyme catalyzed processes.
- they are hydrolysis products with middle
- a polysaccharide with a dextrose equivalent (DE) in the range from 0.5 to 40, in particular from 2 to 30 is preferred, DE being a common measure of the reducing action of a polysaccharide compared to dextrose, which has a DE of 100 , is.
- DE dextrose equivalent
- Both maltodextrins with a DE of between 3 and 20 and dry glucose syrups with a DE of between 20 and 37 and also so-called yellow dextrins and white dextrins with relatively high molecular weights in the range from 2000 to 30 000 g / mol are useful.
- a preferred dextrin is described in British Patent Application 94 19 091.
- the oxidized derivatives of such dextrins are their reaction products with oxidizing agents which are capable of at least one alcohol function of the saccharide ring to oxidize the carboxylic acid function.
- oxidizing agents capable of at least one alcohol function of the saccharide ring to oxidize the carboxylic acid function.
- Such oxidized dextrins and processes for their preparation are described, for example, in European Patent Applications EP-A-0 232 202, EP-A-0 427 349, EP-A-0 472 042 and EP-A-0 542 496 and International Patent Applications WO 92 WO-A-93/16110, WO-A-94/28030, WO-A-95/07303, WO-A-95/12619 and WO-A-95 / 20608 known.
- an oxidized oligosaccharide according to the German patent application DE-A-196 00 018.
- a product oxidized on Ce of the saccharide ring may be particularly advantageous
- Ethylenediamine disuccinate are other suitable cobuilders.
- Ethylenediamine-N, N '- disuccinate (EDDS) whose synthesis is described for example in US 3,158,615, preferably in the form of its sodium or magnesium salts.
- EDDS Ethylenediamine-N, N '- disuccinate
- glycerol disuccinates and glycerol trisuccinates as described, for example, in US Pat. Nos. 4,524,009, 4,639,325, in European
- organic cobuilders are, for example, acetylated hydroxycarboxylic acids or their salts, which may optionally also be present in lactone form and which have at least 4 carbon atoms and at least one hydroxyl group and a maximum of two
- Such co-builders are used, for example, in the international
- phosphonates are, in particular, hydroxyalkane or aminoalkanephosphonates.
- Hydroxyalkane phosphonates are the 1-hydroxyethane-1,1-diphosphonate (HEDP) of particular importance as co-builders. It is preferably used as the sodium salt, the
- Aminoalkanephosphonates are preferably ethylenediaminetetramethylenephosphonate (EDTMP), diethylenetriaminepentamethylenephosphonate (DTPMP) and their higher homologs. They are preferably used in the form of the neutral-reacting sodium salts, for example as the hexasodium salt of EDTMP or as the hepta- and octa-sodium salt of DTPMP.
- the builder used here is preferably HEDP from the class of phosphonates.
- the aminoalkanephosphonates also have a pronounced heavy metal binding capacity.
- agents also contain bleach
- aminoalkanephosphonates in particular DTPMP
- mixtures of the phosphonates mentioned all compounds capable of forming complexes with alkaline earth ions can be used as co-builders.
- a preferred inorganic builder is fine crystalline, synthetic and bound water-containing zeolite.
- the finely crystalline, synthetic and bound water-containing zeolite used is preferably zeolite A and / or P.
- zeolite X and mixtures of A, X and / or P, for example a cocrystal of zeolites A and X are also suitable.
- the zeolite can be used as a spray-dried powder or as undried, still moist from their production, stabilized suspension used.
- the zeolite may contain minor additions of nonionic surfactants as stabilizers, for example 1 to 3 wt .-%, based on zeolite, of ethoxylated C12-Ci8 fatty alcohols having 2 to 5 ethylene oxide groups, Ci2 -Ci4 fatty alcohols with 4 to 5
- Suitable zeolites have an average particle size of less than 10 ⁇ (volume distribution, measuring method: Coulter Counter) and preferably contain 18 to 22 wt .-%, in particular 20 to 22 wt .-% of bound water.
- zeolites are contained in the premix in amounts of from 10 to 94.5% by weight, it being particularly preferred that zeolites are present in amounts of from 20 to 70, in particular from 30 to 60% by weight.
- Suitable partial substitutes for zeolites are phyllosilicates of natural and synthetic origin.
- Such layered silicates are known, for example, from the patent applications DE-A-23 34 899, EP-A-0 026 529 and DE-A-35 26 405. Their usability is not on a special one
- NaMSixOx + iyH20 where M is sodium or hydrogen, x is a number from 1.9 to 4 and y is a number from 0 to 20 and preferred values for x are 2, 3 or 4, are suitable for the substitution of zeolites or phosphates ,
- Such crystalline layered silicates are described, for example, in European Patent Application EP-A-0 164 514.
- Preferred crystalline layered silicates of the formula given are those in which M is sodium and x assumes the values 2 or 3. In particular, both ⁇ - and ⁇ -sodium disilicates Na2Si205'yH20 are preferred.
- the preferred builders also include amorphous sodium silicates having a modulus of Na2 ⁇ : S1O2 of from 1: 2 to 1: 3.3, preferably from 1: 2 to 1: 2.8, and more preferably from 1: 2 to 1: 2.6 , which are delay-delayed and have secondary washing properties.
- the dissolution delay compared to conventional amorphous sodium silicates may have been caused in various ways, for example by surface treatment, compounding, compaction / densification or by overdrying.
- the term "amorphous” is also understood to mean "X-ray amorphous". This means that the silicates are present X-ray diffraction experiments do not give sharp X-ray reflections, as they are typical for crystalline substances, but at best one or more maxima of the scattered
- diffraction maxima This is to be interpreted as meaning that the products have microcrystalline regions of size 10 to a few hundred nm, with values of up to max. 50 nm and in particular up to max. 20 nm are preferred.
- Such so-called X-ray amorphous silicates which also have a dissolution delay compared to the conventional water glasses are
- compacted / compacted amorphous silicates particularly preferred are compacted / compacted amorphous silicates, compounded amorphous silicates and overdried X-ray amorphous silicates, wherein in particular the overdried silicates preferably also occur as a carrier in the granules according to the invention or are used as carriers in the process according to the invention.
- phosphates as builders are possible, unless such use should not be avoided for environmental reasons.
- Particularly suitable are the sodium salts of orthophosphates, pyrophosphates and in particular tripolyphosphates.
- Their content is generally not more than 25 wt .-%, preferably not more than 20 wt .-%, each based on the finished agent.
- tripolyphosphates even in small amounts up to a maximum of 10% by weight, based on the finished composition, in combination with other builder substances lead to a synergistic improvement in the secondary washing power.
- the washing or cleaning agent further comprises at least one enzyme.
- Suitable enzymes are the enzymes previously mentioned as additives.
- enzyme granules are contained in a proportion of 4 to 15 wt .-%, preferably from 7 to 12 wt .-%, each based on 100 wt .-% of the total washing or cleaning agent.
- the at least one enzyme is present as granules.
- the detergents or cleaners according to the invention preferably contain enzymes in
- the enzymes are in a total amount of 0.001 to 4 wt .-%, more preferably from 0.01 to 3 wt .-%, even more preferably from 0.05 to 1, 25 wt .-% and particularly preferably from 0.2 to 1, 0 wt .-% in these detergents or cleaning agents.
- enzymes known from the state of the art for textile treatment are suitable as enzyme for use as an additive.
- it is one or more enzymes which can develop a catalytic activity as an additive of a detergent, in particular a protease, amylase, lipase, cellulase, hemicellulase, mannanase, pectin-splitting enzyme, tannase, xylanase, xanthanase, .beta.-glucosidase, Carrageenase, perhydrolase, oxidase,
- a detergent in particular a protease, amylase, lipase, cellulase, hemicellulase, mannanase, pectin-splitting enzyme, tannase, xylanase, xanthanase, .beta.-glucosidase, Carrageenase, perhydrolase
- Oxidoreductase and mixtures thereof Preferred hydrolytic enzymes include, in particular, proteases, amylases, in particular ⁇ -amylases, cellulases, lipases,
- Hemicellulases in particular pectinases, mannanases, ß-glucanases, and mixtures thereof.
- Proteases, amylases, cellulases and / or lipases and mixtures thereof are particularly preferred, and proteases are particularly preferred.
- These enzymes are basically of natural origin; Starting from the natural molecules, improved variants are available for use in detergents or cleaning agents, which are preferably used accordingly.
- subtilisin type those of the subtilisin type are preferable.
- these are the subtilisins BPN 'and Carlsberg, the protease PB92, the subtilisins 147 and 309, the alkaline protease from Bacillus lentus, subtilisin DY and the enzymes thermitase, proteinase K and the subtilases, but not the subtilisins in the narrower sense Proteases TW3 and TW7.
- Subtilisin Carlsberg in a developed form under the trade names Alcalase ® from Novozymes A / S, Bagsvaerd, Denmark.
- the subtilisins 147 and 309 are sold under the trade names Esperase ®, or Savinase ® from Novozymes. From the protease from Bacillus lentus DSM 5483 derived under the name BLAP ® protease variants derived. Other usable proteases are, for example, under the trade names Durazym ®, relase ®, Everlase® ®, Nafizym ®, Natalase ®, Kannase® ® and Ovozyme ® from Novozymes, the ® under the trade names Purafect ®, Purafect ® OxP, Purafect Prime, Excellase ® and Properase.RTM ® from Genencor, that under the
- amylases which can be used according to the invention are the ⁇ -amylases from Bacillus licheniformis, B. amyloliquefaciens or B. stearothermophilus and their further developments improved for use in detergents or cleaners.
- the enzyme from B. licheniformis is available from Novozymes under the name Termamyl ® and from Genencor under the name Purastar® ® ST.
- Development products of this a-amylase are available from Novozymes under the trade names Duramyl ® and Termamyl ® ultra, from Genencor under the name Purastar® ® OxAm and from Daiwa Seiko Inc., Tokyo, Japan, as Keistase ®.
- the ⁇ -amylase from B. amyloliquefaciens is marketed by Novozymes under the name BAN ®, and variants derived from the amylase from B. stearothermophilus under the names BSG ® and Novamyl ®, likewise from Novozymes. Furthermore, for this purpose, the ⁇ -amylase from Bacillus sp. A 7-7 (DSM 12368) and the cyclodextrin glucanotransferase (CGTase) from B. agaradherens (DSM 9948). Likewise, fusion products of all the molecules mentioned can be used.
- lipases or cutinases which can be used according to the invention, which are contained in particular because of their triglyceride-cleaving activities, but also in order to generate in situ peracids from suitable precursors, are the lipases which are originally obtainable from Humicola lanuginosa (Thermomyces lanuginosus) or further developed, in particular those with the amino acid exchange D96L. They are sold, for example, by Novozymes under the trade names Lipolase ®, Lipolase Ultra ®, LipoPrime® ®, Lipozyme® ® and Lipex ®.
- the cutinases can be used, which were originally isolated from Fusarium solani pisi and Humicola insolens.
- Lipases which are likewise useful are sold by Amano under the names Lipase CE® , Lipase P® , Lipase B® or Lipase CES® , Lipase AKG® , Bacillus sp.
- Lipase® , Lipase AP® , Lipase M- AP® and Lipase AML® are available.
- the lipases or cutinases can be used, the initial enzymes were originally isolated from Pseudomonas mendocina and Fusarium solanii.
- cellulases may be present as pure enzymes, as enzyme preparations or in the form of mixtures in which the individual components advantageously complement each other in terms of their various performance aspects.
- performance aspects include in particular the contributions of the cellulase to the primary washing performance of the agent (cleaning performance), to the secondary washing performance of the agent (antiredeposition effect or grayness inhibition) Avivage (fabric effect) or for the exercise of a "stone washed" effect
- EC Endoglucanase
- Carezyme ® are based on the 50 kD EG, or the 43 kD EG from H. insolens DSM 1800. Further commercial products of this company are Cellusoft ® , Renozyme ® and
- Celluclean ® Also usable are for example the 20 kD EG Melanocarpus, which are available from AB Enzymes, Finland, under the trade names Ecostone ® and Biotouch ®. Further commercial products from AB Enzymes are Econase® ® and ECOPULP ®. Other suitable cellulases are from Bacillus sp. CBS 670.93 and CBS 669.93, those derived from Bacillus sp. CBS 670.93 from the company Genencor under the trade name Puradax ® is available. Further commercial products of the company Genencor are "Genencor detergent cellulase L" and lndiAge ® Neutra.
- variants of these enzymes obtainable by point mutations can be used according to the invention.
- Particularly preferred cellulases are Thielavia terrestris cellulase variants, cellulases from melanocarpus, in particular melanocarpus albomyces, cellulases of the EGIII type from Trichoderma reesei or variants obtainable therefrom.
- hemicellulases include, for example, mannanases, xanthan lyases, xanthanases, xyloglucanases, xylanases,
- Pullulanases pectin-cleaving enzymes and ⁇ -glucanases.
- the recovered from Bacillus subtilis .beta.-glucanase is available under the name Cereflo ® from Novozymes.
- particularly preferred hemicellulases are mannanases, which ® example, under the trade name Man Away ® by the company Novozymes or Purabrite of the
- pectin-destroying enzymes in the context of the present invention are also counted enzymes with the designations pectinase, pectate lyase, pectin esterase, pectin methoxylase, pectin methoxylase, pectin methyl esterase, pectase, pectin methyl esterase, pectin esterase, pectin-pectin hydrolase, pectin-polymerase, endopolygalacturonase, pectolase, pectin hydrolase, pectin-polygalacturonase, Endo-polygalacturonase, poly-a-1, 4-galacturonide glycanohydrolase, endogalacturonase, endo-D-galacturonase, galacturan 1, 4-a-galacturonidase, exopolygalacturonase, poly (galacturonate) hydrolase
- suitable enzymes for example, under the name Gamanase ®, Pektinex AR ®, X-Pect ® or Pectaway ® by the company Novozymes, UF under the name Rohapect ®, Rohapect TPL ®, Rohapect PTE100 ®, Rohapect MPE ®, Rohapect MA available plus HC, Rohapect DA12L ®, Rohapect 10L ®, Rohapect B1 L ® by the company AB Enzymes and under the name Pyrolase® ® by the company Diversa Corp., San Diego, CA, United States. Of all these enzymes, particular preference is given to those which have been stabilized per se with respect to oxidation in a comparatively stable manner or, for example, via point mutagenesis.
- a bleaching agent can serve all substances by oxidation, reduction or adsorption
- Dyes destroy or absorb and thereby discolor materials. These include, among others, hypohalite-containing bleach, hydrogen peroxide, perborate, percarbonate,
- Peroxoacetic acid diperoxoazelaic acid, diperoxododecanedioic acid and oxidative enzyme systems.
- Detergents additionally contain one or more of the above additionally mentioned substances, in particular those from the groups of bleach activators, pH adjusters, perfumes,
- Perfume carriers fluorescers, dyes, silicone oils, anti redeposition agents, optical brighteners, grayness inhibitors and color transfer inhibitors. Suitable agents are known in the art.
- the washing or cleaning agent according to the invention preferably has a pH (20 ° C.) in the basic range, ie greater than 7, in particular in the range from greater than 7 to 14, preferably from 7.5 to 12, in particular from 8 to 10 ,
- the washing or cleaning agents according to the invention may be present in solid form (for example as a powder, as extruded particles, as agglomerates or as granules) or as a liquid.
- organic solvents may also be present in the compositions.
- it is monohydric or polyhydric alcohols having 1 to 4 carbon atoms.
- Preferred alcohols in such agents are ethanol, 1, 2-propanediol, glycerol and mixtures of these alcohols.
- such agents contain from 2 to 12% by weight of such alcohols.
- the agents can have different states of aggregation.
- the detergents or cleaners are liquid or gel-like agents.
- washing or cleaning processes ie in particular processes for cleaning textiles, are generally distinguished by the fact that cleaning-active substances are applied to the items to be cleaned in one or more process steps and washed off after the action time, or that the items to be cleaned are otherwise mixed with a washing or Cleaning agent or a solution of this agent is treated.
- temperatures of up to 95 ° C or less, 90 ° C or less, 60 ° C or less, 50 ° C or less, 40 ° C or less , 30 ° C or less or 20 ° C or less. These temperatures are based on the temperatures used in the washing or cleaning steps.
- the present invention relates to a process for reducing wrinkles in fabrics during laundering, characterized by reacting a betaine of formula (I) or (Ia) as described in the present application, and in particular as a component a washing or cleaning agent (in particular a washing or cleaning agent of the first subject of the invention) brings into contact with the textile.
- a washing or cleaning process comprises the process steps:
- Detergent which includes laundry softener to incorporate stable. At the same time as cleaning, textiles are finished with the Antiknitterwirkstoff.
- washing or cleaning agent either directly with the textiles in manual cleaning or first to prepare an aqueous solution of the washing or cleaning agent (wash liquor) and bring this wash with the textile in contact.
- wash liquor a washing or cleaning agent
- the object underlying the present invention is achieved by the use of at least one betaine of the formula (I) or (Ia), as described in the present application, as anti-crease agent for textiles. Surprisingly It has been shown that the betaines described lead to the desired effect.
- Textiles made of polyester / cotton blended fabric were washed with a liquid detergent (formulation 1, comparative example) and once with the liquid detergent according to formulation 1 with addition of 1, 0 wt .-% active substance Cs / do-Alkylamidopropylbetain (formulation 2, according to the invention), as well as with a washing powder (formulation 3, comparative example) and once with the washing powder according to formulation 4 with the addition of 0.75% by weight of active substance Cs / oalkylamidopropylbetaine (formulation 4: according to the invention).
- the different fabrics were washed separately at 40 ° C (in the Easy Care program) in a standard washing machine from Miele. There were 5 washes done.
- Enzymes (protease, 0.4% 0.4% 0.4 0.4 amylase, cellulase,
- the frictional resistance after washing was determined. This test method is used to determine the resistance that opposes a textile surface rubbing by a friction body.
- a Zwick Z010 was used for the measurement.
- the Teflon friction body was centered at the end of the test sample. By starting the tensile tester, the friction body was moved to the other end of the test sample. The distance traveled was then included in a force / length change diagram.
- Polyester / cotton blended fabric (65% by weight of polyester, 35% by weight of cotton)
- the tissues treated with the formulations according to the invention show less resistance than the unwashed tissues, whereas with conventional detergents a significantly greater force is necessary. This indicates a high resistance, more creases and less smooth fibers of the tissues.
- Cs / OO alkylamidopropyl betaines according to the invention a reduced wrinkling of tissue as well as a simpler ironing is thus possible.
- Measurement 1 is carried out as described in point A 2.1 on the non-ironed sample (blended fabric and cotton) (static friction).
- Measurement 2 is carried out as described in point A 2.1 on the already ironed sample (cotton) (dynamic friction).
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- Chemical & Material Sciences (AREA)
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- Life Sciences & Earth Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
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- Textile Engineering (AREA)
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Abstract
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE102016201295.9A DE102016201295A1 (de) | 2016-01-28 | 2016-01-28 | C8-10-Alkylamidoalkylbetain als Antiknitterwirkstoff |
PCT/EP2016/081039 WO2017129310A1 (fr) | 2016-01-28 | 2016-12-14 | (c8-10)-alkylamidoalkylbétaïne comme substance active anti-froissage |
Publications (1)
Publication Number | Publication Date |
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EP3472285A1 true EP3472285A1 (fr) | 2019-04-24 |
Family
ID=57544458
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
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EP16810387.7A Withdrawn EP3472285A1 (fr) | 2016-01-28 | 2016-12-14 | (c8-10)-alkylamidoalkylbétaïne comme substance active anti-froissage |
Country Status (3)
Country | Link |
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EP (1) | EP3472285A1 (fr) |
DE (1) | DE102016201295A1 (fr) |
WO (1) | WO2017129310A1 (fr) |
Family Cites Families (35)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3158615A (en) | 1960-07-20 | 1964-11-24 | Union Carbide Corp | Stabilized polymerizable vinyl pyridines |
ZA734721B (en) | 1972-07-14 | 1974-03-27 | Procter & Gamble | Detergent compositions |
DE2926479C2 (de) | 1979-06-30 | 1981-10-08 | Th. Goldschmidt Ag, 4300 Essen | Verfahren zur Herstellung von Betainen |
EP0026529B2 (fr) | 1979-09-29 | 1992-08-19 | THE PROCTER & GAMBLE COMPANY | Compositions détergentes |
US4524009A (en) | 1984-01-31 | 1985-06-18 | A. E. Staley Manufacturing Company | Detergent builder |
CA1238917A (fr) | 1984-01-31 | 1988-07-05 | Vivian B. Valenty | Adjuvant pour detergent |
DE3413571A1 (de) | 1984-04-11 | 1985-10-24 | Hoechst Ag, 6230 Frankfurt | Verwendung von kristallinen schichtfoermigen natriumsilikaten zur wasserenthaertung und verfahren zur wasserenthaertung |
US4639325A (en) | 1984-10-24 | 1987-01-27 | A. E. Staley Manufacturing Company | Detergent builder |
DE3526405A1 (de) | 1985-07-24 | 1987-02-05 | Henkel Kgaa | Schichtsilikate mit beschraenktem quellvermoegen, verfahren zu ihrer herstellung und ihre verwendung in wasch- und reinigungsmitteln |
FR2597473B1 (fr) | 1986-01-30 | 1988-08-12 | Roquette Freres | Procede d'oxydation de di-, tri-, oligo- et polysaccharides en acides polyhydroxycarboxyliques, catalyseur mis en oeuvre et produits ainsi obtenus. |
DE3706036A1 (de) | 1987-02-25 | 1988-09-08 | Basf Ag | Polyacetale, verfahren zu deren herstellung aus dialdehyden und polyolcarbonsaeuren und verwendung der polyacetale |
ATE124960T1 (de) | 1989-11-10 | 1995-07-15 | Tno | Verfahren zur herstellung von polydicarboxysacchariden. |
IT1249883B (it) | 1990-08-13 | 1995-03-30 | Ferruzzi Ricerca & Tec | Agenti sequestranti del calcio a base di carboidrati ossidati e loro impiego come builder per detergenti |
IT1245063B (it) | 1991-04-12 | 1994-09-13 | Ferruzzi Ricerca & Tec | Procedimento per l'ossidazione di carboidrati |
DE4134914A1 (de) | 1991-10-23 | 1993-04-29 | Henkel Kgaa | Wasch- und reinigungsmittel mit ausgewaehlten builder-systemen |
ATE166362T1 (de) | 1991-11-14 | 1998-06-15 | Procter & Gamble | C6/c2-c3 oxidierte stärke als waschmittelbestandteil |
DE4221381C1 (de) | 1992-07-02 | 1994-02-10 | Stockhausen Chem Fab Gmbh | Pfropf-Copolymerisate von ungesättigten Monomeren und Zuckern, Verfahren zu ihrer Herstellung und ihre Verwendung |
DE4203923A1 (de) | 1992-02-11 | 1993-08-12 | Henkel Kgaa | Verfahren zur herstellung von polycarboxylaten auf polysaccharid-basis |
JPH05339896A (ja) | 1992-06-03 | 1993-12-21 | Arakawa Chem Ind Co Ltd | 紙用サイズ剤および紙サイジング方法 |
DE4300772C2 (de) | 1993-01-14 | 1997-03-27 | Stockhausen Chem Fab Gmbh | Wasserlösliche, biologisch abbaubare Copolymere auf Basis von ungesättigten Mono- und Dicarbonsäuren, Verfahren zu ihrer Herstellung und ihre Verwendung |
DE4303320C2 (de) | 1993-02-05 | 1995-12-21 | Degussa | Waschmittelzusammensetzung mit verbessertem Schmutztragevermögen, Verfahren zu dessen Herstellung und Verwendung eines geeigneten Polycarboxylats hierfür |
DE4317519A1 (de) | 1993-05-26 | 1994-12-01 | Henkel Kgaa | Herstellung von Polycarboxylaten auf Polysaccharid-Basis |
NL194919C (nl) | 1993-09-07 | 2003-07-04 | Tno | Werkwijze voor het oxideren van koolhydraten. |
NL9301905A (nl) | 1993-11-04 | 1995-06-01 | Inst Voor Agrotech Onderzoek | Werkwijze voor het oxideren van koolhydraten. |
DE4400024A1 (de) | 1994-01-03 | 1995-07-06 | Henkel Kgaa | Silikatische Builder und ihre Verwendung in Wasch- und Reinigungsmitteln sowie Mehrstoffgemische für den Einsatz auf diesem Sachgebiet |
DE4402051A1 (de) | 1994-01-25 | 1995-07-27 | Henkel Kgaa | Gerüststoff für Wasch- oder Reinigungsmittel |
DE4402851A1 (de) | 1994-01-31 | 1995-08-03 | Henkel Kgaa | Wirbelschicht-Oxidationsverfahren zur Herstellung von Polycarboxylaten auf Polysaccharid-Basis |
DE4417734A1 (de) | 1994-05-20 | 1995-11-23 | Degussa | Polycarboxylate |
EP0704523A1 (fr) * | 1994-09-30 | 1996-04-03 | The Procter & Gamble Company | Compositions pour éviter le transfert de colorant contenant des bétaines |
DE4439642C1 (de) | 1994-11-07 | 1996-01-11 | Goldschmidt Ag Th | Milde, wäßrige, tensidische Zubereitungen für kosmetische Zwecke und Reinigungsmittel |
US5547612A (en) | 1995-02-17 | 1996-08-20 | National Starch And Chemical Investment Holding Corporation | Compositions of water soluble polymers containing allyloxybenzenesulfonic acid monomer and methallyl sulfonic acid monomer and methods for use in aqueous systems |
DE19540086A1 (de) | 1995-10-27 | 1997-04-30 | Henkel Kgaa | Verwendung von polymeren Aminodicarbonsäuren in Waschmitteln |
DE19600018A1 (de) | 1996-01-03 | 1997-07-10 | Henkel Kgaa | Waschmittel mit bestimmten oxidierten Oligosacchariden |
DE102004051010A1 (de) * | 2004-10-20 | 2005-06-23 | Clariant Gmbh | Flüssigwaschmittel enthaltend anionische Tenside und Farbfixiermittel |
RU2650684C2 (ru) * | 2014-02-20 | 2018-04-17 | Хенкель Аг Унд Ко. Кгаа | Моющее или чистящее средство с улучшенной способностью к вспениванию при высоком уровне загрязнений |
-
2016
- 2016-01-28 DE DE102016201295.9A patent/DE102016201295A1/de not_active Withdrawn
- 2016-12-14 WO PCT/EP2016/081039 patent/WO2017129310A1/fr active Application Filing
- 2016-12-14 EP EP16810387.7A patent/EP3472285A1/fr not_active Withdrawn
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WO2017129310A1 (fr) | 2017-08-03 |
DE102016201295A1 (de) | 2017-08-03 |
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