EP3452639A1 - Structure à empilements disposés en rangées et procédé pour pile à combustible à haute température - Google Patents

Structure à empilements disposés en rangées et procédé pour pile à combustible à haute température

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Publication number
EP3452639A1
EP3452639A1 EP16722263.7A EP16722263A EP3452639A1 EP 3452639 A1 EP3452639 A1 EP 3452639A1 EP 16722263 A EP16722263 A EP 16722263A EP 3452639 A1 EP3452639 A1 EP 3452639A1
Authority
EP
European Patent Office
Prior art keywords
stacks
cell system
fuel
feed
stack
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
EP16722263.7A
Other languages
German (de)
English (en)
Inventor
Kim ÅSTRÖM
Vesa Kyyhkynen
Hulda AMINOFF
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Convion Oy
Original Assignee
Convion Oy
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Convion Oy filed Critical Convion Oy
Publication of EP3452639A1 publication Critical patent/EP3452639A1/fr
Withdrawn legal-status Critical Current

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Classifications

    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/24—Grouping of fuel cells, e.g. stacking of fuel cells
    • H01M8/249—Grouping of fuel cells, e.g. stacking of fuel cells comprising two or more groupings of fuel cells, e.g. modular assemblies
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B1/00—Electrolytic production of inorganic compounds or non-metals
    • C25B1/01—Products
    • C25B1/02—Hydrogen or oxygen
    • C25B1/04—Hydrogen or oxygen by electrolysis of water
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B15/00—Operating or servicing cells
    • C25B15/08—Supplying or removing reactants or electrolytes; Regeneration of electrolytes
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B9/00—Cells or assemblies of cells; Constructional parts of cells; Assemblies of constructional parts, e.g. electrode-diaphragm assemblies; Process-related cell features
    • C25B9/70—Assemblies comprising two or more cells
    • C25B9/73—Assemblies comprising two or more cells of the filter-press type
    • C25B9/77—Assemblies comprising two or more cells of the filter-press type having diaphragms
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/04—Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids
    • H01M8/04007—Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids related to heat exchange
    • H01M8/04014—Heat exchange using gaseous fluids; Heat exchange by combustion of reactants
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/04—Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids
    • H01M8/04007—Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids related to heat exchange
    • H01M8/04067—Heat exchange or temperature measuring elements, thermal insulation, e.g. heat pipes, heat pumps, fins
    • H01M8/04074—Heat exchange unit structures specially adapted for fuel cell
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/04—Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids
    • H01M8/04082—Arrangements for control of reactant parameters, e.g. pressure or concentration
    • H01M8/04089—Arrangements for control of reactant parameters, e.g. pressure or concentration of gaseous reactants
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/04—Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids
    • H01M8/04082—Arrangements for control of reactant parameters, e.g. pressure or concentration
    • H01M8/04201—Reactant storage and supply, e.g. means for feeding, pipes
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/18—Regenerative fuel cells, e.g. redox flow batteries or secondary fuel cells
    • H01M8/184—Regeneration by electrochemical means
    • H01M8/186—Regeneration by electrochemical means by electrolytic decomposition of the electrolytic solution or the formed water product
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/24—Grouping of fuel cells, e.g. stacking of fuel cells
    • H01M8/241—Grouping of fuel cells, e.g. stacking of fuel cells with solid or matrix-supported electrolytes
    • H01M8/2425—High-temperature cells with solid electrolytes
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/24—Grouping of fuel cells, e.g. stacking of fuel cells
    • H01M8/2465—Details of groupings of fuel cells
    • H01M8/2484—Details of groupings of fuel cells characterised by external manifolds
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B9/00—Cells or assemblies of cells; Constructional parts of cells; Assemblies of constructional parts, e.g. electrode-diaphragm assemblies; Process-related cell features
    • C25B9/70—Assemblies comprising two or more cells
    • C25B9/73—Assemblies comprising two or more cells of the filter-press type
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/10—Fuel cells with solid electrolytes
    • H01M8/12—Fuel cells with solid electrolytes operating at high temperature, e.g. with stabilised ZrO2 electrolyte
    • H01M2008/1293—Fuel cells with solid oxide electrolytes
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30—Hydrogen technology
    • Y02E60/36—Hydrogen production from non-carbon containing sources, e.g. by water electrolysis
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30—Hydrogen technology
    • Y02E60/50—Fuel cells
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P70/00—Climate change mitigation technologies in the production process for final industrial or consumer products
    • Y02P70/50—Manufacturing or production processes characterised by the final manufactured product

Definitions

  • Fuel cell's by means of which energy of fuel, for example biogas, is directly converted to electricity via a chemical reaction in an environmentally friendly process, are promising future energy conversion devices.
  • Fuel cell as presented in fig 1, comprises an anode side 100 and a cathode side 102 and an electrolyte material 104 between them.
  • SOFCs solid oxide fuel cells
  • oxygen 106 is fed to the cathode side 102 and it is reduced to a negative oxygen ion by receiving electrons from the cathode.
  • the negative oxygen ion goes through the electrolyte material 104 to the anode side 100 where it reacts with fuel 108 producing water and also typically carbon dioxide (CO2).
  • Anode 100 and cathode 102 are connected through an external electric circuit 111 comprising a load 110 for the fuel cell withdrawing electrical energy out of the system.
  • the fuel cells also produce heat to the reactant exhaust streams.
  • SOFC device can utilize as fuel for example natural gas, bio gas, methanol or other compounds containing hydrocarbons.
  • SOFC device in figure 2 comprises more than one, typically plural of fuel cells in stack formation 103 (SOFC stack). Each fuel cell comprises anode 100 and cathode 102 structure as presented in figure 1. Part of the used fuel can be recirculated in feedback arrangement 109 through each anode.
  • SOFC device in fig 2 also comprises a fuel heat exchanger 501 and a reformer 107.
  • Reformer 107 is a device that converts the fuel such as for example natural gas to a composition suitable for fuel cells, for example to a composition containing hydrogen and methane, carbon dioxide, carbon monoxide and inert gases.
  • a reformer it is though not necessary to have a reformer.
  • inert gases are purge gases or part of purge gas compounds used in fuel cell technology.
  • nitrogen is a typical inert gas used as purge gas in fuel cell technology.
  • Purge gases are not necessarily elemental and they can be also compound gases.
  • measurement means 115 such as fuel flow meter, current meter and temperature meter
  • Part of the gas used at anodes 100 may be recirculated through anodes in feedback arrangement 109 and the other part of the gas is exhausted 114 from the anodes 100.
  • electrolysis operating mode solid oxide electrolysis cells (SOEC)
  • SOEC solid oxide electrolysis cells
  • the reaction is reversed, i.e. heat, as well as electrical energy from a source 110, are supplied to the cell where water and often also carbon dioxide are reduced in the cathode side forming oxygen ions, which move through the electrolyte material to the anode side where oxidation reaction takes place.
  • the electrodes are typically named anode and cathode based on the fuel cell operating mode, whereas in purely SOEC applications the oxygen electrode may be named the anode, and the reactant electrode as the cathode.
  • Solid Oxide Fuel Cell (SOFC) and Solid Oxide Electrolyzer (SOE) stacks commonly here referred as solid oxide cell stack, where the flow direction of the cathode gas relative to the anode gas internally in each cell as well as the flow directions of the gases between adjacent cells, are combined through different cell layers of the stack. Further, the cathode gas or the anode gas or both can pass through more than one cell before it is
  • a plurality of gas streams can be split or merged after passing a primary cell and before passing a secondary cell. These combinations serve to increase the current density and minimize the thermal gradients across the cells and the whole stack.
  • a solid oxide fuel cell (SOFC) device is an electrochemical conversion device that produces electricity directly from oxidizing fuel. Advantages of SOFC device include high efficiencies, long term stability, low emissions, and cost. The main disadvantage is the high operating temperature which results in long start up times and both mechanical and chemical compatibility issues.
  • the anode electrode of solid oxide fuel cell (SOFC) typically contains significant amounts of nickel that is vulnerable to form nickel oxide if the atmosphere is not reducing. If nickel oxide formation is severe, the
  • SOFC systems typically require purge gas, i.e. safety gas, containing reductive agents (such as hydrogen diluted with inert such as nitrogen) during the start-up and shut-down in order to prevent the fuel cell's anode electrodes from oxidation.
  • purge gas i.e. safety gas
  • reductive agents such as hydrogen diluted with inert such as nitrogen
  • the amount of purge gas has to be minimized because an extensive amount of, e.g. pressurized gas containing hydrogen, are expensive and problematic as space-requiring components.
  • High temperature fuel cell systems typically contain several fuel cell stacks within one or more insulation enclosures.
  • the fuel cell stacks themselves as well as any flanges and sealing surfaces used within the fuel supply lines shall be regarded as potential sources of fuel leakage to their surroundings.
  • the temperature of the surroundings is typically above the self-ignition temperatures of gaseous fuels that are used. Therefore, the traditional approach for dealing with the leakages has been to place all potential sources of leakage within an air or exhaust stream taking care that air is always available in excess amounts to combust any leaking fuel.
  • This approach requires a gas tight enclosure suitable for the pressure level of the air/exhaust stream and large enough to contain all fuel manifolding with non-welded connections (i.e.
  • methods to minimize differences in operating conditions include passive means such as use of symmetry, guide vanes and flow restrictors for flow homogenization as well as active means such as means for stack-wise or stack group-wise flow or loading control.
  • passive means such as use of symmetry, guide vanes and flow restrictors for flow homogenization as well as active means such as means for stack-wise or stack group-wise flow or loading control.
  • active means such as means for stack-wise or stack group-wise flow or loading control.
  • a combination of several methods is typically used. The strive to achieve as even operating conditions as possible places constraints on the system layout and typically becomes a decisive factor in the choice of fuel cell or
  • electrolysis system geometries In high temperature fuel cell systems significant complexity and cost is typically related to interfaces and boundaries such as gas, electricity and mechanical support feedthroughs between a hot and a cold compartment. Where a connection between a hot and a cold structure needs to be made such as passing a hot pipe through a gas-tight cold wall, management of heat loss and thermomechanical stresses becomes an issue which typically require costly and/or space consuming arrangements. Also, transfer pipes between different hot components may need support from cold structures and thermomechanical compensators. Therefore, minimization of hot-cold feedthroughs and transfer pipes is desirable. By integration of components this can be achieved. In prior art embodiments, various designs integrating burners, reformer(s) and heat exchangers are presented.
  • BoP balance of plant
  • components in the balance of plant such as reformers, burners, heat exchangers, ejectors, blowers and valves.
  • the interfacing to these typically introduces asymmetry in an otherwise symmetric arrangement.
  • distribution pipes undergoing heat exchange in a row configuration introduces differences in flow temperatures of different flow branches along the distribution common rail. Pressure losses and dynamic pressures in distribution pipes of reasonable size furthermore introduce pressure differences between flow branches supplying different stacks or groups of stacks.
  • the temperature change of reactant supply pipes running along the row configuration changes the thermal radiation field experienced by different stacks in the flow configurations. All of these phenomena introduce variations in operation conditions of stacks, which affect their performance and lifetime. To avoid harmful effects of such variations, appropriate safety margins need to be applied on global operating parameters to assure that allowed limits are not locally exceeded.
  • Flow deviations in flow between branches can be reduced by designing sufficient pressure drop in flow branches such that pressure drops within branches dominate over pressure drops within the distribution arrangement. However, if such a distribution arrangement involves differences in heat-up or cooldown of reactants diverting to different flow branches, such
  • Flow restrictor elements placed in the outlet streams of stacks are most effective in balancing flows as the temperatures at the outlet tend to have smaller differences than at inlets in case of asymmetric feeds.
  • large pressure drops as a means for compensating of otherwise uneven flow distribution increases system parasitic losses and particularly increase the requirements for reactant circulation arrangements.
  • additional pressure drops can severely reduce the performance of the recirculation(s).
  • Flow restriction elements are also sensitive to manufacturing tolerances.
  • the object of the present invention is to achieve a cell system with improved flow and temperature balance conditions and with improved conditions.
  • This is achieved by a stack arrangement of high temperature fuel cell system or electrolysis cell system, each cell in the cell system comprising an anode side, a cathode side, and an electrolyte between the anode side and the cathode side, the cell system comprising the cells in cell stacks.
  • the arrangement comprises the stacks arranged in row arrangement, wherein the stacks are arranged side by side at least in two rows, and the
  • the arrangement comprises air feed-in ducting for feeding air to the stacks, the ducting having air inlet ends, which are conveyed to a sealed air feed space, which is formed between the stack rows having at least two sides of the air feed space enclosed by the stacks themselves, and the arrangement comprises a fuel feed-in common rail, a fuel feed-in ducting and individual feed-in channeling for feeding fuel to the stacks, and at least one radiative heat transfer compensation element along at least one of the fuel feed-in common rail, the fuel feed-in ducting, the individual feed-in channeling and the air feed-in ducting, means for performing flow and temperature balanced air feed-in flows for the stacks, and means for performing flow balanced fuel flows in the cell system.
  • the focus of the invention is also a method of high temperature fuel cell system or electrolysis cell system.
  • the method is arranged cell stacks in row arrangement so that the stacks are arranged side by side at least in two rows, is fed air to the stacks by an air feed-in ducting having air inlet ends, which are conveyed to a sealed air feed space, which is formed between the stack rows having at least two sides of the air feed space enclosed by the stacks themselves, and in the method is fed fuel to the stacks by a feed-in common rail, a fuel feed-in ducting and individual feed-in channeling, is performed radiative heat transfer compensation along at least one of the fuel feed-in common rail, the fuel feed-in ducting, the individual feed-in
  • the channeling and the air feed-in ducting is performed flow and temperature balanced air feed-in flows for the stacks, and is performed flow balanced fuel flows in the cell system.
  • the invention is based on an air feed-in ducting having air inlet ends, which are conveyed to a sealed air feed space, for feeding air to the stacks, which are arranged side by side at least in two rows.
  • the sealed air feed space is formed between the stack rows having at least two sides of the air feed space enclosed by the stacks themselves.
  • the invention is further based on radiative heat transfer compensation along at least one of the fuel feed-in common rail, the fuel feed-in ducting, the individual feed-in channeling and the air feed-in ducting, and performing flow and temperature balanced air feed-in flows for the stacks, and performing flow balanced fuel flows in the cell system.
  • the benefit of the invention is that a compact and economically beneficial fuel cell or electrolysis cell system can be built. Also functionality of the cell system can be improved, because sealing problems can be at least partly eliminated.
  • Figure 1 presents a single fuel cell structure.
  • Figure 2 presents an example of a SOFC device.
  • Figure 3 presents an exemplary stack arrangement of high temperature cell system according to the present invention.
  • Figure 4 presents the stack row formation according to the present invention. Detailed description of the invention
  • Solid oxide fuel cells can have multiple geometries.
  • the planar geometry (Fig 1) is the typical sandwich type geometry employed by most types of fuel cells, where the electrolyte 104 is sandwiched in between the electrodes, anode 100 and cathode 102.
  • SOFCs can also be made in tubular geometries where for example either air or fuel is passed through the inside of the tube and the other gas is passed along the outside of the tube. This can be also arranged so that the gas used as fuel is passed through the inside of the tube and air is passed along the outside of the tube.
  • Other geometries of SOFCs include modified planar cells (MPC or MPSOFC), where a wave-like structure replaces the traditional flat configuration of the planar cell. Such designs are promising, because they share the advantages of both planar cells (low resistance) and tubular cells.
  • typical fuels are natural gas (mainly methane), different biogases (mainly nitrogen and/or carbon dioxide diluted methane), and other higher hydrocarbon containing fuels or alcohols.
  • Methane and higher hydrocarbons need to be reformed either in the reformer 107 (Fig 2) before entering the fuel cell stacks 103 or (partially) internally within the stacks 103.
  • the reforming reactions require certain amount of water, and additional water is also needed to prevent possible carbon formation (coking) caused by higher hydrocarbons.
  • This water can be provided internally by circulating the anode gas exhaust flow, because water is produced in excess amounts in fuel cell reactions, and/or said water can be provided with an auxiliary water feed (e.g. direct fresh water feed or circulation of exhaust condensate).
  • anode recirculation arrangement also part of the unused fuel and diluents in anode gas are fed back to the process, whereas in auxiliary water feed arrangement only additive to the process is water.
  • stacks are arranged in at least one row configuration with respect to feeds such that deviations in operating conditions of individual stacks are essentially zero despite of the asymmetry in feeds and despite lack of isolation on distribution pipes. Close to zero deviations are achieved by feeding air to the stack rows in a back and forth formation with flow and temperature balanced outlets for stacks, and by having branch-specific pressure drop elements in fuel feed branches and by using at least one heat transfer enhancement element along fuel feed-in common rails.
  • the means for performing flow and temperature balanced air feed-in flows for the stacks 103 can also be accomplished e.g. by perforated pipes.
  • Stacks are arranged in towers and towers further side by side in rows such that between every pair of two rows is formed an essentially cuboid shaped air inlet space in which stack air inlets (and intermediate seals) constitute the at least two largest faces of said cuboid space and air feed structures constitute two of the remaining faces.
  • said clearances can be filled with e.g. ceramic blocks or fibers, sealing gaskets or a combination thereof.
  • perforated curved, e.g. U- shaped tubes or straight tubes with a common header in both ends can be used to facilitate a zig-zag air feed pattern in a back and forth arrangement.
  • Tubes facilitating an even flow and temperature profile to the stack air inlets can also be arranged coaxially.
  • stack air inlet faces constitute over 50% of the total area of the cuboid boundaries.
  • the stack rows can be contained in an isolated gas tight enclosure whose inner volume at least partially constitutes a cathode outlet passage.
  • An afterburner can be located internally or externally to said enclosure.
  • post-oxidation of unspent fuel leaving the fuel system can be arranged at multiple locations within said enclosure. A part or all of the unspent fuel leaving the fuel system can also be extracted for e.g. hydrogen generation.
  • Fuel supply pipes are located inside said cathode outlet passage section and along said rows of adjacent stack towers. Said supply pipings include at least one heat transfer enhancement element and at least one pressure drop structure within each stack row. The at least one heat transfer enhancement elements are placed within fuel feed pipes asymmetrically with respect to stack rows to
  • Heat transfer enhancement elements can be e.g. plates or corrugated structures inside pipes, fins or deformations on the pipe surface.
  • a heat transfer enhancement element can also function as a pressure drop element and different geometries can be used at different locations to achieve to optimize heat transfer vs. pressure drop.
  • Pressure drop elements can consist of various pipe inserts, orifices and holes along reactant supply structures.
  • flow branches to individual stack groups along a row configuration include multiple bends, providing inherent flexibility and thus allowing for minimization of need of bellows.
  • the space between each two stack tower rows can be the air outlet space and air inlet can be located on the outside, inside the insulated gas tight vessel.
  • Fuel piping can be arranged within the air inlet or outlet space or between said spaces e.g. underneath or above the stack row.
  • Fuel common railing can be arranged as part of the structures supporting and feeding fuel to the stacks (manifolds). Manifolds can be tower specific, common for two adjacent or for two opposite facing stack towers, or common for four or more towers.
  • Manifolds can be placed at the middle of a tower, at one end or at both ends with separate manifolds for inlet and outlet fuel. In a high tower configuration it is possible to have multiple manifolds at different heights of the stack tower to facilitate even fuel flow.
  • the air feed arrangement according to the present invention can include means to mix controllable amounts of cold air to the heated air inlet streams of different stack groups allowing for compensating differences in temperatures, currents or flows. Similarly, means to inject small amounts of surplus fuel to different flow branches can be provided as compensation means.
  • Stacks typically require external compression to be applied at least during operation. Compression can be arranged by springs by applying pressure or in some cases by applying weight on stack towers.
  • the compression counterforce can be transferred through cold structures such as through an air sealing enclosure or using rods or plates running partially through a hot environment.
  • manifold can serve as a force distribution plate for single or multiple stack towers for the runtime compression and/or transfer
  • isolation can be located in various and multiple parts of the stack-system interface such as between the stack and manifold, along gas feed pipes and support structures, in relation to seals, integral to the stack or integrated with thermal isolation.
  • Isolation elements can be various seals of low electrical conductivity, discrete ceramic parts, various fibers or a combination thereof.
  • the system can include means to monitor the isolation strength during runtime.
  • compensation elements can comprise flow restrictions (including holes in a pipe or wall), heat transfer enhancing elements etc.
  • the arrangement according to the present invention can be e.g. an arrangement comprising air and fuel feed-in pipings, i.e. ductings, which both have flows in horizontal flows in opposing directions in any cross section with air channel in the middle.
  • the cell system can be a fuel cell system or an electrolysis cell system.
  • Each cell in the cell system comprises an anode side 100, a cathode side 102, and an electrolyte 104 between the anode side and the cathode side.
  • the cell system comprises the cells in cell stacks 103.
  • the stack arrangement comprises the stacks 103 arranged in row arrangement, wherein the stacks are arranged side by side at least in two rows, and the arrangement comprises air feed-in ducting 120 for feeding air to the stacks 103.
  • the ducting has air inlet ends 130, which are conveyed to a sealed air feed space 132, which is formed between the stack 103 rows having at least two sides of the air feed space enclosed by the stacks themselves.
  • Flexible material can be used to seal the space between adjacent stacks 103 and to compensate for dimensional tolerances.
  • Said flexible material can also be electrically isolating material.
  • a material combination can be used, in which one material is flexible and the other material is electrically isolating. Flexibility is not necessary, if tolerances for material(s) are large enough.
  • the stack arrangement comprises a fuel feed-in common rail 133, a fuel feed-in ducting 122 and individual feed-in channeling 131 for feeding fuel to the stacks 103, and at least one radiative heat transfer compensation element 134 along at least one of the fuel feed-in common rail 133, the fuel feed-in ducting 122 and the individual feed-in channeling 131.
  • the radiative heat transfer compensation element 134 can be for example an insert element for reduction of hydraulic diameter, for improvement of convective heat transfer or for enhancement of turbulence. Similar heat transfer compensation element 134 can also be applicable for air feed-in ductings 120 according to the present invention.
  • the radiative heat transfer compensation element 134 can be a branch -specific compensation element in order to provide uniform inlet temperatures between the reactant ducting branches.
  • the stack arrangement further comprises means 135 for performing flow and temperature balanced air feed-in flows for the stacks 103.
  • the means 135 can be accomplished e.g. by a back and forth arrangement 135a (figure 3).
  • the means 135 for performing flow and temperature balanced air feed-in flows for the stacks 103 can also be accomplished e.g. by perforated pipes.
  • flow balancing elements providing pressure drop are placed in all parallel branches except the at least one with the lowest flow in an unbalanced situation. Thus, the overall pressure loss increment due to the balancing is essentially zero.
  • the stack arrangement according to the present invention presented in figures 3 and 4 further comprises means 137 for performing flow and temperature balanced fuel flows in the cell system.
  • the means 137 can comprise at least one heat transfer element 142 for each stack 103 row being placed asymmetrically with respect to flow direction and the row.
  • the means 137 for performing flow and temperature balanced reactant flows can also comprise a stack group specific radiative heat transfer compensation element 134 in which pipe length, hydraulic diameter and/or pressure drop characteristic is stack specific to compensate for pressure and temperature differences in the fuel feed-in common rail 133. In other words at least one of pipe length, hydraulic diameter and pressure drop characteristic can be chosen according to each stack to compensate for pressure and temperature differences in the fuel feed-in common rail 133.
  • the radiative heat transfer compensation element 134 arrangement can comprise curved pipes structures 140 in fuel feed-in side or in air feed-in side or in both of them.
  • radiation heat transfer compensation elements can through different kinds of wall temperature management arrangements be utilized to provide a uniform heat radiation environment for all fuel cell stacks.
  • the common rail structures according to the present invention make the stack arrangement robust and minimize the maldistribution of flows due to leakages and bypassing flows since excess local flows are removed evenly from several parallel branches.
  • the stack arrangement according to the present invention can comprise an afterburner for performing burning of residual gas from the anode side 100.
  • the arrangement can comprise an air heater, which is accommodated to the air feed space 132.
  • the air heater can preferably be placed in conjunction with the air distribution between the stacks 103, providing heat by both convection and radiation.
  • the heater can be e.g. an electrical heater or a burner arrangement or a combination of them.
  • insert element(s) 134 can be utilized insert element(s) 134 to accomplish non-uniform thermal isolation.
  • Pipe inserts 134 are preferably designed to have as high a view factor as possible with respect to the pipe or duct surface whose wall is to be thermally balanced.
  • pipe inserts can preferably be coated with engineered emissivity characteristic or catalytic properties to act e.g. as reformer or trap for impurities.
  • selection of the material combination of pipe and insert elements 134 can have different coefficients of thermal expansion, and thus the stack arrangement can be designed to compensate for thermal movements in structures.
  • balancing of relative proportions of radiative and convective heat transfer can improve non-uniform thermal isolation over an extended operating window.
  • linear and quadratic pressure drop characteristic can be balanced in pressure loss elements to significantly extend the operating window.
  • Simplification of radiative heat transfer structures through reduced symmetry requirements with respect to sources of radiation also enables non-uniform thermal isolation in the embodiments according to the present invention.
  • Different kind of heat radiation transfer methods can be performed simultaneously inside the piping.

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Electrochemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Sustainable Development (AREA)
  • Sustainable Energy (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Manufacturing & Machinery (AREA)
  • General Chemical & Material Sciences (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Combustion & Propulsion (AREA)
  • Fuel Cell (AREA)
  • Inorganic Chemistry (AREA)

Abstract

Un objet de l'invention est un agencement empilé d'un système de cellule d'électrolyse ou d'un système de pile à combustible à haute température, chaque cellule dans le système de pile/cellule comprenant un côté anode (100), un côté cathode (102) et un électrolyte (104) entre le côté anode et le côté cathode, le système de pile/cellule comprenant les piles/cellules dans des empilements de cellules (103). L'agencement comprend les empilements (103) disposés en rangées, les piles étant disposées côte à côte suivant au moins deux rangées, et l'agencement comprend une conduite d'alimentation en air (120) pour alimenter en air les empilements (103), les conduites ayant des extrémités d'entrée d'air (130) qui sont acheminées jusqu'à un espace d'alimentation en air étanche (132) formé entre les rangées d'empilements (103), deux côtés au moins de l'espace d'alimentation en air étant renfermés par les empilements eux-mêmes. L'agencement comprend un rail commun d'alimentation en carburant (133), une conduite d'alimentation en carburant (122) et un système de canalisation d'alimentation individuelle (131) pour alimenter en carburant les empilements (103), et au moins un élément de compensation de transfert de chaleur radiatif (134) le long d'au moins l'un du rail commun d'alimentation en carburant (133), de la conduite d'alimentation en carburant (122), du système de canalisation d'alimentation individuelle (131) et de la conduite d'alimentation en air (120), des moyens (135) pour générer des flux d'alimentation en air équilibrés en termes de débit et de température pour les empilements (103), et des moyens (137) pour générer des flux de carburant équilibrés en termes de débit dans le système de pile/cellule.
EP16722263.7A 2016-05-02 2016-05-02 Structure à empilements disposés en rangées et procédé pour pile à combustible à haute température Withdrawn EP3452639A1 (fr)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
PCT/FI2016/050280 WO2017191353A1 (fr) 2016-05-02 2016-05-02 Structure à empilements disposés en rangées et procédé pour pile à combustible à haute température

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EP (1) EP3452639A1 (fr)
KR (1) KR20190003665A (fr)
CN (1) CN109415828A (fr)
WO (1) WO2017191353A1 (fr)

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CN110391441B (zh) * 2018-04-18 2021-07-02 国家能源投资集团有限责任公司 固体氧化物燃料电池组和电池系统
WO2021115538A1 (fr) 2019-12-10 2021-06-17 Sunfire Gmbh Ensemble pile à oxyde solide
CN115398038A (zh) * 2020-04-16 2022-11-25 旭化成株式会社 电解系统及其使用方法
WO2024075214A1 (fr) * 2022-10-05 2024-04-11 日産自動車株式会社 Système de pile à combustible stationnaire

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Publication number Priority date Publication date Assignee Title
US5298341A (en) * 1992-08-20 1994-03-29 Cerramatec, Inc. Multiple stack ion conducting devices
US5480738A (en) * 1994-02-04 1996-01-02 Ceramatec, Inc. Fuel cell module
US7160642B2 (en) * 2003-10-30 2007-01-09 Hewlett-Packard Development Company, L.P. Fuel cell stack assembly and method of fabrication
JP2009301849A (ja) * 2008-06-12 2009-12-24 Toyota Motor Corp 燃料電池スタック
FI20105962A (fi) * 2010-09-17 2012-03-18 Waertsilae Finland Oy Menetelmä ja järjestely anodioksidoinnin välttämiseksi
WO2015015046A1 (fr) * 2013-07-31 2015-02-05 Convion Oy Disposition et procédé pour pile à haute température

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WO2017191353A1 (fr) 2017-11-09
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