EP3430338A1 - Trenneinrichtung für gewickelte wärmeübertrager zum trennen einer gasförmigen phase von einer flüssigen phase eines zweiphasigen mantelseitig geführten mediums - Google Patents
Trenneinrichtung für gewickelte wärmeübertrager zum trennen einer gasförmigen phase von einer flüssigen phase eines zweiphasigen mantelseitig geführten mediumsInfo
- Publication number
- EP3430338A1 EP3430338A1 EP17712923.6A EP17712923A EP3430338A1 EP 3430338 A1 EP3430338 A1 EP 3430338A1 EP 17712923 A EP17712923 A EP 17712923A EP 3430338 A1 EP3430338 A1 EP 3430338A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- chimney
- roof
- phase
- heat exchanger
- chimneys
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000007791 liquid phase Substances 0.000 title claims abstract description 48
- 239000007792 gaseous phase Substances 0.000 title claims abstract description 38
- 239000012071 phase Substances 0.000 title claims abstract description 27
- 238000000034 method Methods 0.000 claims abstract description 5
- 239000007788 liquid Substances 0.000 claims description 30
- 230000002093 peripheral effect Effects 0.000 claims description 15
- 238000004891 communication Methods 0.000 claims description 5
- 238000000926 separation method Methods 0.000 description 9
- 239000012530 fluid Substances 0.000 description 4
- 230000002051 biphasic effect Effects 0.000 description 3
- 241000237942 Conidae Species 0.000 description 2
- 238000007872 degassing Methods 0.000 description 2
- 206010022000 influenza Diseases 0.000 description 2
- 239000003949 liquefied natural gas Substances 0.000 description 2
- 230000005514 two-phase flow Effects 0.000 description 2
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
- 239000005977 Ethylene Substances 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 230000000977 initiatory effect Effects 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 238000005201 scrubbing Methods 0.000 description 1
- 238000000638 solvent extraction Methods 0.000 description 1
- 125000006850 spacer group Chemical group 0.000 description 1
- 239000006228 supernatant Substances 0.000 description 1
Classifications
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F28—HEAT EXCHANGE IN GENERAL
- F28B—STEAM OR VAPOUR CONDENSERS
- F28B9/00—Auxiliary systems, arrangements, or devices
- F28B9/08—Auxiliary systems, arrangements, or devices for collecting and removing condensate
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F28—HEAT EXCHANGE IN GENERAL
- F28D—HEAT-EXCHANGE APPARATUS, NOT PROVIDED FOR IN ANOTHER SUBCLASS, IN WHICH THE HEAT-EXCHANGE MEDIA DO NOT COME INTO DIRECT CONTACT
- F28D7/00—Heat-exchange apparatus having stationary tubular conduit assemblies for both heat-exchange media, the media being in contact with different sides of a conduit wall
- F28D7/02—Heat-exchange apparatus having stationary tubular conduit assemblies for both heat-exchange media, the media being in contact with different sides of a conduit wall the conduits being helically coiled
- F28D7/024—Heat-exchange apparatus having stationary tubular conduit assemblies for both heat-exchange media, the media being in contact with different sides of a conduit wall the conduits being helically coiled the conduits of only one medium being helically coiled tubes, the coils having a cylindrical configuration
Definitions
- Separating device for wound heat exchanger for separating a gaseous phase from a liquid phase of a two-phase shell-side guided medium
- the invention relates to a wound heat exchanger according to claim 1.
- Such wound heat exchangers are e.g. used in physical scrubbing for acid gas removal (e.g., rectisol process), in ethylene plants, or in liquefied natural gas (LNG) plants.
- acid gas removal e.g., rectisol process
- LNG liquefied natural gas
- Coiled heat exchangers with liquid separators for separating a gaseous phase from a liquid phase are e.g. from DE 10 2012 000 146 A1, EP 2 818 821 A1, DE 10 201 1017030 A1, DE 10 2010 055 452 A1 and DE 10 2004 040 974 A1.
- DE 10 2004 040 974 A1 provides for the use of a baffle plate for degassing the two-phase flow.
- the present invention seeks to provide a wound heat exchanger with a separator that allows a simple way, an improved separation of the gaseous phase of the liquid phase.
- Heat transfer between a biphasic first medium and a second medium comprising: a shell surrounding a shell space and extending along a longitudinal axis, an inlet for admitting the biphasic first medium into the shell space, a shell tube disposed in the shell space having a plurality of tubes for receiving of the second medium helically wound around the longitudinal axis and a separator for separating one
- the separator comprises a liquid phase collecting tray located above the tube bundle, the tray having a plurality of chimneys for separating the two phases, the respective chimney being remote from the tube bundle
- Side of the floor protrudes from the ground is roofed by a roof and opens into a through hole in the bottom, further provided between the respective roof and an upper end of the respective fireplace an inlet opening through which the gaseous phase can flow into the respective chimney, so that in particular the liquid phase can flow away from the respective roof past the respective inlet opening onto the floor, and so that the gaseous phase flows via the inlet opening located below the respective roof into the assigned chimney and from there via the assigned through-opening through the floor uf the tube bundle is feasible.
- the fireplaces can be designed with advantage so that even at high liquid load, the liquid does not over the
- Inlet openings flows into the chimneys and continues to ensure a reliable separation of the two phases.
- a plurality of differing streams or media in particular two or three different streams can be provided on the pipe side, which exchange heat indirectly with the shell-side first medium or current.
- the tubes of the tube bundle can be divided into a corresponding number of tube groups, so that each tube-side (second) medium is assigned a tube group.
- the separating device can also take over the function of the actual liquid distributor.
- the bottom has a plurality of openings through which the liquid phase collected on the floor can rain directly, that is, without a detour via further fluid-carrying components, to the tube bundle.
- a separate liquid distributor may be provided, which is connected to the bottom in FIG.
- Fluid communication is such that the collected on the floor liquid phase can get into the manifold.
- the manifold is configured to distribute the liquid phase onto the tube bundle.
- the liquid phase can be passed through a gap running around the jacket or via pipes into an underlying annular channel with distributor arms.
- the liquid phase can be introduced via a central opening in the core tube and then fed to a distributor in the form of a pressure distributor.
- Such liquid distributors are described in detail, for example, in DE 10 2004 040 974 A1. Other distributors are also conceivable.
- the respective chimney is formed by a circumferential cylindrical wall which extends from an edge region bordering the respective passage opening, so that the respective passage opening of the floor forms an outlet opening of the respective chimney facing downwards towards the tube bundle ,
- the tubes of the tube bundle are wound around or on a core tube of the heat exchanger, which extends along the longitudinal axis of the jacket in the jacket space and is preferably arranged coaxially to this longitudinal axis, wherein preferably the core tube, the load takes up the pipes.
- the individual tubes of the tube bundle are preferably wound in several tube layers on the core tube, wherein the individual tube layers rest on each other via spacers.
- the roof of the respective chimney has a peripheral edge region, with a lower edge pointing downwards, which runs at the level of or below a circumferential as well as upwardly facing end side of the respective chimney, the inlet opening of bounded by respective fireplaces.
- Cylinder axis of the shell of the heat exchanger which preferably runs parallel to the vertical.
- the roof of the respective chimney protrudes perpendicular to the axis of the respective chimney with the peripheral edge region over the associated chimney.
- the peripheral part or edge region of the respective roof which in this way projects beyond the respective chimney or the said cylindrical wall perpendicular to the axis of the respective chimney, is also referred to herein as the projection of the respective roof.
- an internal chimney is arranged in at least one or more or all chimneys (the respective chimneys are then referred to as outdoor fireplaces), which extends through the roof of the respective outer chimney and with a projecting upper portion of the roof of the respective outer chimney, wherein the upper portion of the respective inner chimney has an inlet opening which is in turn covered by a roof of the respective inner chimney, so that the liquid phase from the roof of the respective inner chimney past the respective inlet opening of the inner chimney on the Roof of the assigned outer chimney and from there can flow to the bottom of the separator, and so that the gaseous
- the roof of the respective inner chimney has a peripheral edge region, with a lower edge pointing downwards, which runs at or below a peripheral, upwardly facing end side of the upper section of the respective inner chimney, which is the inlet opening bounded by the respective interior fireplace.
- the separator can be configured in a particularly space-saving manner.
- the separating device can also be arranged in sections of the jacket or jacket space in which the circumference or
- the jacket has a jacket section which surrounds at least part of the partitioning device, in particular at least part of the chimneys, in a cross section perpendicular to the longitudinal axis of the jacket and tapers upwards in the direction of the longitudinal axis and in particular the shape one
- Truncated cone shell has.
- the respective inner chimney extends along the axis of the respective associated outer chimney, in which the respective inner chimney is arranged at least in sections. Furthermore, it is also provided with respect to the roof of the respective inner chimney that this perpendicular to the axis of the respective inner chimney with a
- circumferential edge region protrudes beyond the respective inner chimney, so that in turn a circumferential projection of the roof is formed on the underlying inner chimney.
- the respective inner chimney is arranged coaxially with the respectively associated, outer chimney surrounding the inner chimney.
- the chimneys form a group of first chimneys as well as a group of second chimneys, the second chimneys along their respective axis having a greater height above the ground than the first chimneys.
- the distance of a second chimney to the roof of an adjacent first chimney perpendicular to the axis of the second chimney is smaller than the projection of the roof of the adjacent first chimney.
- first and second chimneys are arranged alternately along the floor, so that preferably between each two adjacent first chimneys, a second chimney or between each two adjacent second chimneys, a first chimney is arranged.
- the object according to the invention is achieved by a method for separating a gaseous phase from a liquid phase of a two-phase first medium and for heat transfer between the first medium and a second medium using a wound heat exchanger according to the invention, wherein the first medium comprises the liquid and the gaseous phase is fed via the inlet into the shell space, wherein the liquid phase, if It impinges on feeding on a roof, flows past the respective inlet opening on the ground, and wherein the liquid phase is collected on the ground and then distributed to the tube bundle, and wherein the gaseous phase via the located below the respective roof inlet opening in the associated fireplace (especially indoor fireplace, outdoor fireplace, first fireplace or second fireplace) initiated and is guided from there through the associated passage opening through the bottom of the tube bundle.
- the first medium comprises the liquid
- the gaseous phase is fed via the inlet into the shell space
- the liquid phase if It impinges on feeding on a roof, flows past the respective inlet opening on the ground, and wherein the liquid phase is collected on the
- the chimneys are designed so that liquid does not flow into the chimneys via the inlet openings even at high liquid loads.
- Figure 1 is a schematic representation of the separation of a liquid from a gaseous phase of a two-phase medium to be distributed to a tube bundle.
- Fig. 2 is a schematic sectional view of an embodiment
- FIG. 3 is a schematic sectional view of another embodiment of a wound heat exchanger according to the invention.
- FIG. 4 is a schematic sectional view of another embodiment of a wound heat exchanger according to the invention.
- Fig. 5 shows an example of a liquid distributor, for distributing the separated with a separator according to the invention liquid
- FIG. 1 shows in a schematic sectional view of the basic task of the distribution of a two-phase first medium M in a wound Heat exchanger 1 represents.
- a separator 2 is used according to the invention, which separates a gaseous phase G of a liquid phase F of the first medium M.
- the liquid phase F and the gaseous phase G are each separately and evenly distributed on the arranged under the separator 2 tube bundle 3 of the wound heat exchanger 1, in which a second medium M 'is performed, so that the two media M, M 'can exchange heat indirectly.
- a number of mediums to be guided separately on the pipe side, which then can exchange heat indirectly with the first medium M.
- Heat exchanger 1 each one preferably at least partially
- Said longitudinal axis z is preferably parallel to the vertical.
- the 2 to 4 has in each case an inlet 7 for introducing the two-phase first medium M into the shell space 6 above a bottom 4 of a separating device 2 which is used to separate the gaseous and liquid phases G, F of the first Medium M is configured so that the two phases F, G can be distributed separately on the tube bundle 3.
- the bottom 4 extends horizontally or perpendicular to the longitudinal axis z and is arranged above the tube bundle 3, wherein it preferably extends over the entire
- Cross-sectional area of the shell space 6 extends perpendicular to the longitudinal axis z and in this case the shell space 6 divided into two sections.
- the bottom 4 preferably serves to collect the liquid phase F and is preferably fluidly connected to a liquid distributor 4a via a suitable flow connection S, wherein the
- Liquid distributor 4a is configured to distribute the liquid phase F on the tube bundle 3, wherein the liquid phase F acts on the tube bundle, for example from above.
- liquid distributor 4a the devices already described above can be used.
- FIG. 5 shows an example Embodiment of a liquid distributor 4a, which can be used with all embodiments of the separating device 2 according to the invention (for example according to FIGS. 2 to 4).
- the bottom 4 of the separator 2 is connected by means of a suitable flow connection S with the core tube 300 of the heat exchanger 1, so that collected on the bottom 4 liquid phase F can get into the core tube 300.
- the liquid distributor 4a according to FIG. 5 now has below the bottom 4a of the separating device 2 and above the tube bundle 3 a plurality of arms 4b which are in fluid communication with the core tube 300 and are designed to distribute the liquid phase F onto the tube bundle 3 which is disposed below the arms 4b.
- the arms 4b extend from the core tube 300
- the separating device 2 itself can also function as a liquid distributor.
- the bottom 4 may have a multiplicity of openings 40a, in particular distributed uniformly over the bottom 4, via which the liquid phase F is then in each case directed onto the tube bundle 3
- the base 4 for separating the two phases F, G of the first medium M has a plurality of passage openings 40 through which the gaseous phase G can be distributed to the tube bundle 3.
- the passage openings 40 each with an associated chimney 50 in flow communication, wherein the respective chimney 50 is preferably formed by a circumferential cylindrical wall 50, which is preferably a closed wall, the no
- the axes L of the chimneys 50 are preferably cylinder axes L, which run parallel to the longitudinal axis z of the heat exchanger 1 or mantle 5.
- the respective chimney 50 further has an inlet opening 51 at an upper end, which is opposite to the respective outlet opening 40 in the direction of the respective axis L and is in each case roofed over by a roof 52, so that a circumferential gap between the respective roof 52 and the below arranged fireplace 50 is formed.
- the liquid phase F which is given from above to the bottom 4 or the separating device 2, can now flow off the respective roof 52 past the respective inlet opening 51 or the respective circumferential gap onto the bottom 4, where it is collected, in order to then move be distributed separately from the gaseous phase G on the tube bundle 3, eg by means of the liquid distributor 4a, which in detail e.g. According to FIG.
- the gaseous phase G can enter the associated chimney 50 via the respective gap or the inlet opening 51 situated below the respective roof 52 and from there via the assigned passage opening or outlet opening 40 through the base 4 the tube bundle 3 is feasible.
- a liquid distributor 4a it is also possible to dispense with a liquid distributor 4a.
- the liquid phase F can be distributed via openings 40a in the bottom 4 on the tube bundle 3.
- the roofs 52 are preferably arranged at the same height in the direction of the longitudinal axis z of the wound heat exchanger 1 or shell 5 and each have a peripheral edge region 52a with a circumferential annular lower edge 52b the longitudinal axis z extends at the level or below a circumferential end face 50a of the respective chimney 50, which borders the inlet opening 51 of the respective chimney 50. It is further provided that the roof 52 of the respective chimney 50 projects perpendicular to the axis L of the respective chimney 50 with the peripheral edge region 52a on the associated chimney 50. This will ensure that after
- FIG. 3 shows a further embodiment of a wound heat exchanger 1 according to the invention, in which the individual chimneys 50, 70 are basically designed in the manner of FIG. 2, with first chimneys 50 being present in contrast to FIG Have height above the floor 4, as second chimneys 70.
- the first and second chimneys 50, 70 are arranged alternately, so that due to the different height of the respective roofs 52,72 a larger number of chimneys 50, 70 per area on the floor. 4 can be arranged. This is particularly clear from the fact that in this arrangement of chimneys 50, 70 of different length, the distance A of a second chimney 70 to the roof 52 of an adjacent first chimney 50 perpendicular to the axis L of the second chimney 70 is smaller than the projection A 'of the roof 52nd of
- FIG. 4 shows a further exemplary embodiment of a wound heat exchanger 1 according to the invention, in which the chimneys 50 are designed in the manner of FIG. 2, wherein an inner chimney 60 is now additionally arranged in the respective chimney 50, which is designed here as an outer chimney extends through the roof 52 of the respective outer chimney 50 and protrudes with an upper portion 63 from the respective roof 52, wherein the upper portion 63 of the respective inner chimney 60 has an inlet opening 61, which in turn is covered by a roof 62 of the respective inner chimney 60, so that again results in a circumferential gap between the respective roof 62 and the inner chimney 60 arranged thereunder.
- an inner chimney 60 is now additionally arranged in the respective chimney 50, which is designed here as an outer chimney extends through the roof 52 of the respective outer chimney 50 and protrudes with an upper portion 63 from the respective roof 52, wherein the upper portion 63 of the respective inner chimney 60 has an inlet opening 61, which in turn is covered by a roof 62 of the respective inner chimney 60, so that again results in
- the internal chimneys 60 may each be formed by a circumferential cylindrical wall 60, which may extend in the respective surrounding outer chimney 50 down to the level of the respective passage opening 40 of the bottom 4, so that a lower outlet opening 41 of the respective inner chimney 60, which faces the tube bundle 3, lies in the opening plane of the respective passage opening 40.
- liquid phase F of a top of the separator 2 and the bottom 4 discontinued first medium M now from the roof 62 of the respective inner chimney 60 at the gap or the inlet opening 61 of the respective inner chimney 60 over on the roof 52 of each associated inconveniencekamins 50 and from there flow to the bottom 4, where it can be collected and redistributed to the tube bundle 3.
- the gaseous phase G can continue to be guided via the annular inlet openings 51 in the respective outer chimney 50 along the coaxial inner chimney 60 via the respective passage or outlet opening 40 on the tube bundle 3, due to the internal chimneys 60 now an additional flow path for the gaseous Phase G per outdoor chimney 50 is present, since the gaseous phase G now also on the below the roof 62 of the respective inner chimney 60 located inlet opening 61 of the respective
- Inner chimney 60 in the respective inner chimney 60 and from there via the outlet opening 41 of the respective inner chimney on the tube bundle 3 can be guided.
- the roof 62 of the respective inner chimney 60 also preferably has a peripheral edge region 62a, with an annular, downwardly pointing lower edge 62b, which is at or below a peripheral, upwardly facing end face 60a of the upper section 63 of FIG respective
- Inner chimney 60 extends, which bounds the inlet opening 61 of the respective inner chimney 60.
Landscapes
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- General Engineering & Computer Science (AREA)
- Physics & Mathematics (AREA)
- Thermal Sciences (AREA)
- Heat-Exchange Devices With Radiators And Conduit Assemblies (AREA)
Abstract
Description
Claims
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP16000628 | 2016-03-16 | ||
PCT/EP2017/025050 WO2017157535A1 (de) | 2016-03-16 | 2017-03-15 | Trenneinrichtung für gewickelte wärmeübertrager zum trennen einer gasförmigen phase von einer flüssigen phase eines zweiphasigen mantelseitig geführten mediums |
Publications (2)
Publication Number | Publication Date |
---|---|
EP3430338A1 true EP3430338A1 (de) | 2019-01-23 |
EP3430338B1 EP3430338B1 (de) | 2019-12-18 |
Family
ID=55646208
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP17712923.6A Active EP3430338B1 (de) | 2016-03-16 | 2017-03-15 | Trenneinrichtung für gewickelte wärmeübertrager zum trennen einer gasförmigen phase von einer flüssigen phase eines zweiphasigen mantelseitig geführten mediums |
Country Status (5)
Country | Link |
---|---|
US (1) | US10982905B2 (de) |
EP (1) | EP3430338B1 (de) |
CN (1) | CN108779961B (de) |
RU (1) | RU2724413C2 (de) |
WO (1) | WO2017157535A1 (de) |
Families Citing this family (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE102018000468A1 (de) * | 2018-01-22 | 2019-07-25 | Linde Aktiengesellschaft | Gewickelter Wärmeübertrager mit Abscheider im Kernrohr |
EP3719433A1 (de) * | 2019-04-02 | 2020-10-07 | Linde GmbH | Regelbarer flüssigkeitsverteiler eines gewickelten wärmeübertragers zur realisierung unterschiedlicher flüssigkeitsbelastungen |
FR3100320B1 (fr) * | 2019-09-02 | 2022-02-18 | Air Liquide | Dispositif de distribution destiné à une colonne de séparation gaz/liquide |
CN113280650B (zh) * | 2021-07-22 | 2021-09-24 | 四川空分设备(集团)有限责任公司 | 气液两相流体均布装置 |
Family Cites Families (13)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5724828A (en) * | 1995-04-21 | 1998-03-10 | Baltimore Aircoil Company, Inc. | Combination direct and indirect closed circuit evaporative heat exchanger with blow-through fan |
RU2081663C1 (ru) * | 1995-11-01 | 1997-06-20 | Закрытое акционерное общество Нефтегазовой компании "Черногорнефтегаз" | Тепломассообменный аппарат |
US6098965A (en) * | 1996-06-04 | 2000-08-08 | Fluor Corporation | Reactor distribution apparatus and quench zone mixing apparatus |
DE102004040974A1 (de) * | 2004-08-24 | 2006-03-02 | Linde Ag | Gewickelter Wärmetauscher |
DE102007019816A1 (de) * | 2007-04-26 | 2008-10-30 | Linde Ag | Sammler-Verteiler-Kombination |
US8517353B2 (en) * | 2010-09-27 | 2013-08-27 | Uop Llc | Apparatus and process for distributing vapor and liquid phases |
DE102010055452A1 (de) | 2010-12-21 | 2012-06-21 | Linde Aktiengesellschaft | Strömungsleitvorrichtung im Einlaufbereich eines abfallenden Flüssigkeitskanals |
DE102011017030A1 (de) | 2011-04-14 | 2012-10-18 | Linde Ag | Wärmetauscher mit Kernrohr und Ringkanal |
DE102012000146A1 (de) | 2012-01-05 | 2013-07-11 | Linde Aktiengesellschaft | Flüssigkeitsverteiler für einen Wärmeübertrager |
DE102012011329A1 (de) * | 2012-06-06 | 2013-12-12 | Linde Aktiengesellschaft | Waschkolonne und Verfahren zum Waschen eines Rohgases |
US9004460B2 (en) * | 2013-06-21 | 2015-04-14 | Praxair Technology, Inc. | Combined collector and distributor |
PL2818821T3 (pl) * | 2013-06-27 | 2016-07-29 | Linde Ag | Nawijany wymiennik ciepła z zasilaniem rury rdzeniowej |
EP3367033A1 (de) * | 2017-02-24 | 2018-08-29 | Linde Aktiengesellschaft | Wärmeübertrager und verfahren zur verteilung einer flüssigen phase in einem wärmeübertrager |
-
2017
- 2017-03-15 WO PCT/EP2017/025050 patent/WO2017157535A1/de active Application Filing
- 2017-03-15 RU RU2018131445A patent/RU2724413C2/ru active
- 2017-03-15 CN CN201780017362.3A patent/CN108779961B/zh active Active
- 2017-03-15 EP EP17712923.6A patent/EP3430338B1/de active Active
- 2017-03-15 US US16/085,028 patent/US10982905B2/en active Active
Also Published As
Publication number | Publication date |
---|---|
CN108779961A (zh) | 2018-11-09 |
CN108779961B (zh) | 2020-05-29 |
RU2018131445A3 (de) | 2020-04-23 |
EP3430338B1 (de) | 2019-12-18 |
RU2018131445A (ru) | 2020-04-16 |
US20190078842A1 (en) | 2019-03-14 |
WO2017157535A1 (de) | 2017-09-21 |
US10982905B2 (en) | 2021-04-20 |
RU2724413C2 (ru) | 2020-06-23 |
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