EP3423607B1 - Échangeur de chaleur incorporant un alliage d'aluminium laminé - Google Patents
Échangeur de chaleur incorporant un alliage d'aluminium laminé Download PDFInfo
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- EP3423607B1 EP3423607B1 EP17705918.5A EP17705918A EP3423607B1 EP 3423607 B1 EP3423607 B1 EP 3423607B1 EP 17705918 A EP17705918 A EP 17705918A EP 3423607 B1 EP3423607 B1 EP 3423607B1
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- heat exchanger
- aluminium alloy
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- exchanger according
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- 229910000838 Al alloy Inorganic materials 0.000 title claims description 56
- 239000000956 alloy Substances 0.000 claims description 60
- 229910045601 alloy Inorganic materials 0.000 claims description 59
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 18
- 229910052782 aluminium Inorganic materials 0.000 claims description 18
- 239000004411 aluminium Substances 0.000 claims description 18
- 239000000203 mixture Substances 0.000 claims description 10
- 239000012535 impurity Substances 0.000 claims description 9
- 229910052748 manganese Inorganic materials 0.000 claims description 6
- 229910052804 chromium Inorganic materials 0.000 claims description 5
- 229910052726 zirconium Inorganic materials 0.000 claims description 5
- 229910052802 copper Inorganic materials 0.000 claims description 3
- 229910052742 iron Inorganic materials 0.000 claims description 3
- 238000005219 brazing Methods 0.000 description 29
- 238000005260 corrosion Methods 0.000 description 13
- 230000007797 corrosion Effects 0.000 description 13
- 239000010410 layer Substances 0.000 description 10
- 239000000463 material Substances 0.000 description 10
- 238000000265 homogenisation Methods 0.000 description 8
- 239000003921 oil Substances 0.000 description 6
- 238000005275 alloying Methods 0.000 description 5
- 238000005266 casting Methods 0.000 description 5
- 230000000694 effects Effects 0.000 description 5
- 230000007774 longterm Effects 0.000 description 5
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- 238000010438 heat treatment Methods 0.000 description 4
- 238000004519 manufacturing process Methods 0.000 description 4
- 238000005096 rolling process Methods 0.000 description 4
- 230000002411 adverse Effects 0.000 description 3
- 230000015572 biosynthetic process Effects 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- 239000002245 particle Substances 0.000 description 3
- 239000000758 substrate Substances 0.000 description 3
- 229910052725 zinc Inorganic materials 0.000 description 3
- 238000005253 cladding Methods 0.000 description 2
- 239000000470 constituent Substances 0.000 description 2
- 238000010276 construction Methods 0.000 description 2
- 239000011229 interlayer Substances 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 238000002844 melting Methods 0.000 description 2
- 230000008018 melting Effects 0.000 description 2
- 230000008569 process Effects 0.000 description 2
- 229910052710 silicon Inorganic materials 0.000 description 2
- 229910052720 vanadium Inorganic materials 0.000 description 2
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 229910002551 Fe-Mn Inorganic materials 0.000 description 1
- 101000993059 Homo sapiens Hereditary hemochromatosis protein Proteins 0.000 description 1
- 229910019752 Mg2Si Inorganic materials 0.000 description 1
- MKPXGEVFQSIKGE-UHFFFAOYSA-N [Mg].[Si] Chemical group [Mg].[Si] MKPXGEVFQSIKGE-UHFFFAOYSA-N 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 238000004378 air conditioning Methods 0.000 description 1
- AZDRQVAHHNSJOQ-UHFFFAOYSA-N alumane Chemical group [AlH3] AZDRQVAHHNSJOQ-UHFFFAOYSA-N 0.000 description 1
- 230000000712 assembly Effects 0.000 description 1
- 238000000429 assembly Methods 0.000 description 1
- 229910052796 boron Inorganic materials 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 238000005097 cold rolling Methods 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 238000009749 continuous casting Methods 0.000 description 1
- 239000002826 coolant Substances 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 239000012792 core layer Substances 0.000 description 1
- 230000003628 erosive effect Effects 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 238000005098 hot rolling Methods 0.000 description 1
- 229910052738 indium Inorganic materials 0.000 description 1
- 238000005304 joining Methods 0.000 description 1
- 239000000155 melt Substances 0.000 description 1
- 230000005012 migration Effects 0.000 description 1
- 238000013508 migration Methods 0.000 description 1
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- 238000004881 precipitation hardening Methods 0.000 description 1
- 238000007670 refining Methods 0.000 description 1
- 238000005057 refrigeration Methods 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
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- 239000006104 solid solution Substances 0.000 description 1
- 238000009718 spray deposition Methods 0.000 description 1
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- 229910052718 tin Inorganic materials 0.000 description 1
- 230000009466 transformation Effects 0.000 description 1
- LEONUFNNVUYDNQ-UHFFFAOYSA-N vanadium atom Chemical compound [V] LEONUFNNVUYDNQ-UHFFFAOYSA-N 0.000 description 1
Images
Classifications
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C21/00—Alloys based on aluminium
- C22C21/06—Alloys based on aluminium with magnesium as the next major constituent
- C22C21/08—Alloys based on aluminium with magnesium as the next major constituent with silicon
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C21/00—Alloys based on aluminium
- C22C21/06—Alloys based on aluminium with magnesium as the next major constituent
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C21/00—Alloys based on aluminium
- C22C21/10—Alloys based on aluminium with zinc as the next major constituent
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C21/00—Alloys based on aluminium
- C22C21/12—Alloys based on aluminium with copper as the next major constituent
- C22C21/14—Alloys based on aluminium with copper as the next major constituent with silicon
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C21/00—Alloys based on aluminium
- C22C21/12—Alloys based on aluminium with copper as the next major constituent
- C22C21/16—Alloys based on aluminium with copper as the next major constituent with magnesium
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C21/00—Alloys based on aluminium
- C22C21/12—Alloys based on aluminium with copper as the next major constituent
- C22C21/18—Alloys based on aluminium with copper as the next major constituent with zinc
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22F—CHANGING THE PHYSICAL STRUCTURE OF NON-FERROUS METALS AND NON-FERROUS ALLOYS
- C22F1/00—Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working
- C22F1/04—Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working of aluminium or alloys based thereon
- C22F1/043—Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working of aluminium or alloys based thereon of alloys with silicon as the next major constituent
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F28—HEAT EXCHANGE IN GENERAL
- F28F—DETAILS OF HEAT-EXCHANGE AND HEAT-TRANSFER APPARATUS, OF GENERAL APPLICATION
- F28F21/00—Constructions of heat-exchange apparatus characterised by the selection of particular materials
- F28F21/08—Constructions of heat-exchange apparatus characterised by the selection of particular materials of metal
- F28F21/081—Heat exchange elements made from metals or metal alloys
- F28F21/084—Heat exchange elements made from metals or metal alloys from aluminium or aluminium alloys
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F28—HEAT EXCHANGE IN GENERAL
- F28D—HEAT-EXCHANGE APPARATUS, NOT PROVIDED FOR IN ANOTHER SUBCLASS, IN WHICH THE HEAT-EXCHANGE MEDIA DO NOT COME INTO DIRECT CONTACT
- F28D9/00—Heat-exchange apparatus having stationary plate-like or laminated conduit assemblies for both heat-exchange media, the media being in contact with different sides of a conduit wall
- F28D9/0031—Heat-exchange apparatus having stationary plate-like or laminated conduit assemblies for both heat-exchange media, the media being in contact with different sides of a conduit wall the conduits for one heat-exchange medium being formed by paired plates touching each other
- F28D9/0043—Heat-exchange apparatus having stationary plate-like or laminated conduit assemblies for both heat-exchange media, the media being in contact with different sides of a conduit wall the conduits for one heat-exchange medium being formed by paired plates touching each other the plates having openings therein for circulation of at least one heat-exchange medium from one conduit to another
- F28D9/005—Heat-exchange apparatus having stationary plate-like or laminated conduit assemblies for both heat-exchange media, the media being in contact with different sides of a conduit wall the conduits for one heat-exchange medium being formed by paired plates touching each other the plates having openings therein for circulation of at least one heat-exchange medium from one conduit to another the plates having openings therein for both heat-exchange media
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F28—HEAT EXCHANGE IN GENERAL
- F28F—DETAILS OF HEAT-EXCHANGE AND HEAT-TRANSFER APPARATUS, OF GENERAL APPLICATION
- F28F2275/00—Fastening; Joining
- F28F2275/04—Fastening; Joining by brazing
Definitions
- the invention relates to a brazed heat exchanger comprising various components and at least one component being made from the rolled 6xxx-series aluminium alloy product according to this invention.
- the invention relates further to the use of the rolled aluminium alloy in a heat exchanger.
- Heat exchangers and other similar equipment such as condensers, evaporators and the like for use in car coolers, air conditioning systems, industrial cooling systems, etc. usually comprise a number of heat exchange tubes arranged in parallel between two headers, each tube joined at either end to one of the headers. Corrugated fins are disposed in an airflow clearance between adjacent heat exchange tubes and are brazed to the respective tubes. These various components are commonly joined to each other done by brazing.
- a brazing filler metal or brazing alloy, or a composition producing a brazing alloy upon heating is applied to at least one portion of the substrate to be brazed. After the substrate parts are assembled, they are heated until the brazing metal or brazing alloy melts. The melting point of the brazing material is lower than the melting point of the aluminium substrate or aluminium core sheet.
- Brazing sheet products find wide applications in heat exchangers and other similar equipment.
- Conventional brazing products have a core of rolled sheet, typically an aluminium alloy of the 3xxx-series, having on at least one surface of the core sheet an aluminium clad layer (also known as an aluminium cladding layer).
- the aluminium clad layer is commonly made of a 4xxx-series alloy comprising silicon in an amount in the range of 4% to 20%, and preferably in the range of about 6% to 14%.
- the aluminium clad layer may be coupled or bonded to the core alloy in various ways known in the art, for example by means of roll bonding, cladding spray-forming or semi-continuous or continuous casting processes.
- These aluminium clad layers have a liquidus temperature typically in the range of about 540°C to 615°C.
- brazing sheet products Although commercially sold brazing sheet products have predominantly a core alloy based on a 3xxx-series aluminium alloys, there are commercially available brazing sheet products having a heat-treatable 6xxx-series aluminium alloy as core alloy. These 6xxx-series alloys can be used also base plate of a heat exchanger or for manufacturing headers or side plates of a heat exchanger. Within the 6xxx-series alloys the alloys AA6101, AA6151, AA6951, AA6060, AA6061, and AA6063 can be found. A list of the key alloying elements of these alloys is given in Table 1. Table 1.
- Alloy composition in wt.% of several prior art rolled aluminium alloys used in heat exchangers and as registered with the Aluminium Association.
- Alloy Element Mg Si Fe Cu Mn Cr AA6101 0.35-0.8 0.30-0.70 ⁇ 0.50 ⁇ 0.10 ⁇ 0.03 ⁇ 0.03 AA6151 0.45-0.8 0.6-1.2 ⁇ 1.0 ⁇ 0.35 ⁇ 0.20 0.15-0.35 AA6951 0.40-0.8 0.20-0.50 ⁇ 0.8 0.15-0.40 ⁇ 0.10 - AA6060 0.35-0.6 0.30-0.6 0.10-0.30 ⁇ 0.10 ⁇ 0.10 ⁇ 0.05 AA6061 0.8-1.2 0.40-0.8 ⁇ 0.7 0.15-0.40 ⁇ 0.15 0.04-0.35 AA6063 0.45-0.9 0.20-0.6 ⁇ 0.35 ⁇ 0.10 ⁇ 0.10 ⁇ 0.10 ⁇ 0.10 ⁇ 0.10 ⁇ 0.10
- aluminium alloy designations and temper designations refer to the Aluminium Association designations in Aluminium Standards and Data and the Registration Records, as published by the Aluminium Association in 2015 and are well known to the person skilled in the art.
- the temper designations are laid down in European standard EN515.
- the term "about" when used to describe a compositional range or amount of an alloying addition means that the actual amount of the alloying addition may vary from the nominal intended amount due to factors such as standard processing variations as understood by those skilled in the art.
- up to and “up to about”, as employed herein, explicitly includes, but is not limited to, the possibility of zero weight-percent of the particular alloying component to which it refers.
- up to 0.3% Ti may include an alloy having no Ti.
- a brazed heat exchanger incorporating at least one component made from a rolled 6xxx-series aluminium alloy having a composition, and wherein the rolled 6xxx-series aluminium alloy has a composition of: Si 0.2% to 1.3%, Mg 0.40% to 1.3%, Cu up to 0.80%, Fe 0.05% to 1.0%, Mn 0.05% to 0.70%, optionally one or two elements selected from the group of 0.05-0.35% Zr and 0.04-0.35% Cr, Zn up to 0.25%, Ti up to 0.25%, balance unavoidable impurities and aluminium, and wherein the Fe/Mn ratio is ⁇ 1.90.
- the rolled 6xxx-series aluminium alloy forms one of the components forming a base plate, a header or a side support of plate thickness 1-12mm of a heat exchanger device and the rolled aluminium alloy used provides a good balance in post-braze mechanical properties and enhanced corrosion resistance, in particular after long term exposure at elevated temperatures, for example for 1,000 hours at 150°C, reflecting long term use of such a heat exchanger device. This would also allow some down-gauging of the heat exchanger component made from this 6xxx-series alloy.
- the purposive combined addition of Mg and Si strengthens the aluminium alloy due to precipitation hardening of elemental Si and Mg 2 Si formed under the co-presence of Mg.
- the Si content should be at least 0.20%, and preferably at least 0.25%.
- a preferred upper-limit for the Si content is about 0.8%, and more preferably about 0.60%, and more preferably about 0.55%.
- the presence of Si enhances also the formability.
- the Mg content should be at least 0.40% to provide sufficient strength to the rolled product.
- a preferred upper-limit for the Mg content is about 0.9%, and more preferably about 0.8%.
- Fe is not a desired component of the aluminium alloy, but its presence is normally unavoidable.
- the Fe-content should not exceed 1.0%, and a preferred upper-limit is about 0.8%, and more preferably about 0.50%.
- a preferred range is 0.05% to about 0.40%, and more preferably from about 0.10% to about 0.40%, because alloys containing less Fe are more expensive.
- At least 0.05% Mn must be present.
- at least 0.08% Mn is present, and more preferably >0.10% Mn.
- a preferred upper-limit is about 0.50%, and more preferably about 0.40%.
- the Fe/Mn ratio is being controlled and the Fe/Mn-ratio should not exceed 1.90, and preferably does not exceed 1.80, and more preferably does not exceed 1.75.
- a preferred lower-limit for the Fe-Mn ratio is about 0.7.
- Cu may increase the post-braze strength of the aluminium alloy, but its presence should not exceed 0.80%. It is preferred that the Cu-level does not exceed about 0.4%. Cu levels above about 0.4% may rise to a reduced post-braze corrosion resistance of products incorporating the aluminium alloy according to the invention.
- Ti may be present up to about 0.25% to act as a grain refining additive during the casting of an ingot of the aluminium alloy of the invention. Additional Ti may be added, for example due to their presence in scrap material, in order to increase the strength of the core alloy by solubility hardening.
- the total amount of Ti present in the alloy should preferably not exceed about 0.20%, but preferably is less than about 0.12%. A preferred lower limit for the Ti addition is about 0.01%.
- Ti can be added as a sole element or with either boron or carbon as known in the art serving as a casting aid, for grain size control.
- the Zn content in the aluminium alloy is present as a tolerable impurity element of less than about 0.25%, and preferably should be present at the lower-end of this range, e.g. less than about 0.15%, and more preferably less than about 0.10%, to maintain corrosion resistance at desired levels.
- one or two dispersoid forming elements selected from the group consisting of about 0.05% to about 0.35% Zr and about 0.04% to about 0.35% Cr can be added to further improve the strength of the aluminium alloy product in the post-braze condition.
- a more preferred Zr level is in the range of about 0.05% to about 0.20%, and more preferably in a range of about 0.06% to about 0.15%.
- a more preferred Cr level is in the range of about 0.05% to about 0.20%, and more preferably in a range of about 0.06% to about 0.25%.
- the total combined amount of all the dispersoid forming alloying elements Zr and Cr does not exceed about 0.35% to avoid the formation of coarse constituent particles in particular when combined with a relative high Fe content in combination with the purposive addition of Mn.
- Coarse constituent particles may have an adverse effect on formability and they may hinder further down-gauging of the product form and they can have an adverse effect on the corrosion resistance.
- the aluminium alloy it has no purposive addition of vanadium such that, if present, it is at a level of less than about 0.05%, and more preferably less than about 0.03%, such that the aluminium alloy is substantially free from V.
- substantially free or “essentially free” is meant that no purposeful addition was made to the chemical composition but that due to impurities and/or leaking from contact with manufacturing equipment, trace quantities of V may nevertheless find their way into the alloy product. For example, less than about 0.02% is an example of a trace quantity.
- the aluminium alloy may have 0% V.
- the aluminium alloy may contain normal and inevitable impurities, typically each ⁇ 0.05% and the total ⁇ 0.2%, and the balance is made by aluminium.
- the 6xxx-series core alloy has a composition consisting of, in wt.%: Si 0.2% to 1.3%, Mg 0.40% to 1.3%, Cu up to 0.80%, Fe 0.05% to 1.0%, Mn 0.05% to 0.70%, optionally one or two elements selected from the group 0.05%-0.35% Zr and 0.04%-0.35% Cr, Zn up to 0.25%, Ti up to 0.25%, balance unavoidable impurities and aluminium, and wherein the Fe/Mn ratio is ⁇ 1.90, and with preferred narrower alloy compositions are herein described.
- the rolled 6xxx-series aluminium alloy is employed as a bare or non-clad rolled product in the heat exchanger such that in use the outer-face of the aluminium alloy is exposed to the corrosive environment, in particular as a so-called base plate where the heat exchanger apparatus is brazed onto.
- the thickness of rolled 6xxx-series alloy is in a range of about 1 mm to 12 mm.
- the rolled 6xxx-series aluminium alloy has a first side and a second side, and at least one clad layer applied on the first side or the second side. There can be provided a clad layer on both the first side and the second side.
- the at least one clad layer can be a 1xxx-series, e.g. AA1050, or a 7xxx-series alloy to provide sacrificial protection of the 6xxx-series alloy.
- a suitable 7xxx-series alloy would have a Zn-content of up to about 3%, and would include an AA7072-series alloy.
- the clad material could also be made from a brazing material and preferably made of a 4xxx-series aluminium alloy. Typical alloys within this series are AA4343, AA4045, AA4047, AA4004, AA4104, AA4147, or some near compositional variants thereof.
- the 4xxx-series alloy may further contain one or more selected from the group consisting of Zn, In, and Sn, in a concentration tailored to effect a desired electrochemical potential within and adjacent to a brazing joint.
- the rolled 6xxx-series alloy can be in the form of a brazing sheet material wherein the 6xxx-series alloy forms the core alloy material and at least one side is clad with a brazing material, preferably a 4xxx-series alloy.
- a brazing sheet material would be used for manufacturing a brazed tube as one of the components of the heat exchanger.
- the 6xxx-series core alloy and the clad brazing material are separated by an interliner or an interlayer, such that the core is bonded to an interliner, and the interliner is, in turn, bonded to the 4xxx-series alloy.
- This structure minimizes localized corrosion, promotes good brazeability, reduces liquid film migration, and, by suitable selection of the interliner alloy, enhances corrosion resistance, such that the interliner alloy sacrificially protects the underlying core alloy.
- An example of a suitable interliner would be an 1xxx- or 3xxx-series alloy, or a 1xxx- or 3xxx-series alloy with a purposive addition of Zn below about 3%, or a purposive addition of In below about 1%.
- brazing sheet product there is proved a core alloy bonded on both sides to an interliner, and each interliner is, in turn, bonded to a 4xxx-series alloy.
- an outerliner or waterside liner bonded on one side of the core alloy and a clad brazing material bonded to the other side of the core alloy.
- an interliner between the 6xxx-series core alloy and the clad brazing material.
- the outerliner would generally be of an alloy tailored to provide high corrosion resistance or even corrosion combined with erosion resistance in the environment to which that face of the sheet is exposed.
- An example of a suitable outerliner would be an aluminium alloy having a purposive addition of Zn up to about 3%, such as for example an AA7072-series alloy.
- the thickness of the core layer (in percent compared to the total thickness of the brazing sheet product) of the brazing sheet is preferably in a range of about 60% to 90%
- the thickness of the interliner or interlayer or outerliner or waterside liner (in percent compared to the total thickness of the brazing sheet product) is preferably in a range of about 5% to 25%
- the thickness of the clad brazing layer is preferably (in percent compared to the total thickness of the brazing sheet) in a range of about 4% to 15%.
- the thickness of the 6xxx-series core alloy at final clad composite gauge can be as little as about 80 microns to as much as about 5 mm.
- the one component made from the rolled 6xxx-series alloys forms a base plate, a header or a side support of a heat exchanger.
- the thickness of rolled 6xxx-series alloy is in a range of about 1 mm to 12 mm.
- the one component made from the rolled 6xxx-series alloys forms a base plate of a heat exchanger, more preferably of an oil cooler.
- the rolled 6xxx-series aluminium product is preferably provided in a fully-annealed "O" temper or an "F” temper or in an "H” temper, i.e. in an H1 or H2 temper.
- An H1 temper means that the alloy product is strain hardened.
- An H2 temper means that the alloy product is strain hardened and partially annealed.
- the alloy part may be strain hardened in accordance with typical H1X or H2X temper practices, where X is a whole number from 0 to 9, e.g. H12 or H24 temper.
- the rolled aluminium alloy used in the heat exchanger according to this invention is being cast into rolling feedstock, for example by means of DC-casting or continuous strip casting, and thereafter preferably homogenized prior to being down gauged by means of rolling to final gauge, for example by hot rolling and optionally also by cold rolling.
- rolling feedstock for example by means of DC-casting or continuous strip casting
- homogenized prior to being down gauged by means of rolling to final gauge, for example by hot rolling and optionally also by cold rolling.
- a homogenization heat-treatment assists in converting any ⁇ -AlFeSi to the less harmful ⁇ -AlFeSi form, preferably below 10 ⁇ m long and with 90% below 5 ⁇ m.
- the purposive addition of Mn acts to accelerate the ⁇ - to ⁇ -AlFeSi transformation in particular during homogenization so that the resulting homogenized ingot results in an increased post-braze corrosion resistance when used as a core alloy for a brazing sheet product or when used as base plate, a header or a side support of a heat exchanger.
- the as-cast rolling ingot is also homogenized to bring favourably the soluble secondary magnesium-silicon phases into suitable form.
- the homogenisation heat-treatment involves heating the ingot for at least about 2 hours, and more preferably at least about 6 hours.
- a preferred upper-limit for the homogenisation soaking time is about 48 hours, and more preferably about 24 hours.
- a longer homogenisation time is not disadvantageous, but is not required and only serves to raise the costs of production.
- Homogenisation is preferably performed at a temperature of 525°C or more using one or more homogenisation steps, more preferably at least one homogenisation step is performed at a temperature range of 540°C to 600°C.
- the heat-up rates that can be applied are those which are regular in the art.
- the aluminium alloy is homogenised for at least about 6 hours and preferably less than about 20 hours at a temperature range of about 550°C to about 600°C.
- the present invention also relates to the use or a method of use of the rolled 6xxx-series aluminium alloy as described herein, either as a bare product or having at least one clad layer on one of its sides, for use in a heat exchanger.
- the alloy forms a base plate, a header or a side support of said heat exchanger.
- the heat exchanger is a radiator, an oil cooler, an inter cooler, a heater core, an evaporator, a charge air cooler, or a condenser or similar applications and assemblies which are produced by joining brazing sheets for forming a compact assembly, mainly for the purpose of exchanging heat.
- the rolled 6xxx-series aluminium alloy is particularly useful for high performance, light weight, automotive heat exchangers but could be used for other brazed applications including but not limited to refrigeration and HVAC.
- FIG. 1 showing a drawing of the construction of a stacked plate oil cooler in a partially exploded illustration.
- FIG. 1 shows schematically an example of the construction of a stacked plate oil cooler 1 which is constructed from a multiplicity of stacking plates 2 and metal turbulence plates 3 (turbulence inserts) arranged between said stacking plates 2.
- the stacked plate oil cooler 1 is closed off by means of a base plate 4 and a cover plate 5.
- An intermediate metal plate 6 is inserted between the uppermost metal turbulence plate 3 and the cover plate 5.
- Connections for the oil and a liquid coolant are arranged in the relative thick base plate 4, but cannot be seen or are not illustrated in this FIG. 1 .
- the cover plate 5 is closed; it has, in this embodiment, stamped impressions 10, 12.
- the base plate 4 can be made of the rolled 6xxx-series aluminium alloy according to the invention providing a good balance in post-braze mechanical properties and enhanced corrosion resistance, in particular after long term exposure at elevated temperatures, for example for 1,000 hours at 150°C, reflecting long term use of such a heat exchanger device.
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- Thermal Sciences (AREA)
- General Engineering & Computer Science (AREA)
- Crystallography & Structural Chemistry (AREA)
- Heat-Exchange Devices With Radiators And Conduit Assemblies (AREA)
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Claims (18)
- Échangeur de chaleur incorporant au moins un composant fait à partir d'un alliage d'aluminium laminé de la série 6xxx ayant une composition, en pourcentage en poids, de
Si 0,2 % à 1,3 %, Mg 0,40 % à 1,3 %, Cu jusqu'à 0,80 %, Fe 0,05 % à 1,0 %, Mn 0,05 % à 0,70 %, Zn jusqu'à 0,25 %, Ti jusqu'à 0,25 %,
dans lequel le rapport Fe/Mn est < 1,90, et dans lequel ledit au moins un composant fait à partir de l'alliage d'aluminium laminé de la série 6xxx a une épaisseur dans une plage de 1 mm à 12 mm et forme une plaque de base, un collecteur, ou un support latéral de l'échangeur de chaleur. - Échangeur de chaleur selon la revendication 1, dans lequel l'alliage d'aluminium laminé de la série 6xxx a une teneur en Fe au maximum de 0,8 %, et de préférence au maximum de 0,50 %.
- Échangeur de chaleur selon l'une quelconque des revendications 1 et 2, dans lequel l'alliage d'aluminium laminé de la série 6xxx a une teneur en Mn au maximum de 0,50 %, et de préférence au maximum de 0,40 %.
- Échangeur de chaleur selon l'une quelconque des revendications 1 à 3, dans lequel l'alliage d'aluminium laminé de la série 6xxx a une teneur en Si au maximum de 0,80 %, et de préférence au maximum de 0,60 %.
- Échangeur de chaleur selon l'une quelconque des revendications 1 à 4, dans lequel l'alliage d'aluminium laminé de la série 6xxx a une teneur en Mg qui ne dépasse pas 0,1 %, et de préférence pas 0,8 %.
- Échangeur de chaleur selon l'une quelconque des revendications 1 à 5, dans lequel l'alliage d'aluminium laminé de la série 6xxx a une teneur en Cu allant jusqu'à 0,4 %.
- Échangeur de chaleur selon l'une quelconque des revendications 1 à 5, dans lequel l'alliage d'aluminium laminé de la série 6xxx a été homogénéisé.
- Échangeur de chaleur selon la revendication 7, dans lequel l'alliage central de la série 6xxx a été homogénéisé pendant une période allant jusqu'à 48 heures à une température dans une plage de 525° C à 600° C, de préférence dans une plage de température de 540° C à 600° C.
- Échangeur de chaleur selon l'une quelconque des revendications 1 à 8, dans lequel l'alliage d'aluminium laminé de la série 6xxx présente un rapport Fe/Mn < 1,80, et de préférence < 1,75.
- Échangeur de chaleur selon l'une quelconque des revendications 1 à 9, dans lequel l'alliage d'aluminium laminé de la série 6xxx a un premier côté et un second côté, et au moins une couche de revêtement sur le premier côté ou sur le second côté.
- Échangeur de chaleur selon la revendication 10, dans lequel ladite au moins une couche de revêtement est réalisée en un alliage sélectionné parmi le groupe comprenant les alliages d'aluminium des séries 1xxx, 4xxx, et 7xxx.
- Échangeur de chaleur selon l'une quelconque des revendications 1 à 9, dans lequel l'alliage d'aluminium laminé de la série 6xxx est dépourvu de revêtement.
- Échangeur de chaleur selon la revendication 1, dans lequel ledit au moins un composant réalisé à partir de l'alliage d'aluminium laminé de la série 6xxx est prévu dans une températion O entièrement recuite.
- Échangeur de chaleur selon la revendication 1, dans lequel ledit au moins un composant réalisé à partir de l'alliage d'aluminium laminé de la série 6xxx est prévu dans une températion H1X ou une températion H2X.
- Échangeur de chaleur selon la revendication 1, dans lequel ledit au moins un composant réalisé à partir de l'alliage d'aluminium laminé de la série 6xxx est prévu dans une températion F.
- Échangeur de chaleur selon l'une quelconque des revendications 1 à 15, dans lequel échangeur de chaleur est un échangeur de chaleur automobile.
- Échangeur de chaleur selon l'une quelconque des revendications 1 à 16, dans lequel l'échangeur de chaleur est un radiateur, un condenseur, un évaporateur, un refroidisseur d'huile, un refroidisseur intermédiaire, un refroidisseur à charge d'air ou un noyau chauffant.
- Utilisation d'un aluminium laminé ayant une épaisseur dans la plage de 1 mm à 12 mm tel que défini dans l'une quelconque des revendications 1 à 15 à titre de composant dans un échangeur de chaleur, à titre de plaque de base, de collecteur ou de support latéral dans ledit échangeur de chaleur.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP16157787 | 2016-02-29 | ||
PCT/EP2017/054141 WO2017148788A1 (fr) | 2016-02-29 | 2017-02-23 | Alliage en aluminium laminé pour échangeurs de chaleur |
Publications (2)
Publication Number | Publication Date |
---|---|
EP3423607A1 EP3423607A1 (fr) | 2019-01-09 |
EP3423607B1 true EP3423607B1 (fr) | 2019-12-18 |
Family
ID=55451066
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
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EP17705918.5A Revoked EP3423607B1 (fr) | 2016-02-29 | 2017-02-23 | Échangeur de chaleur incorporant un alliage d'aluminium laminé |
Country Status (4)
Country | Link |
---|---|
US (1) | US20210033358A1 (fr) |
EP (1) | EP3423607B1 (fr) |
CN (1) | CN109072357B (fr) |
WO (1) | WO2017148788A1 (fr) |
Families Citing this family (12)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN109072357B (zh) | 2016-02-29 | 2020-09-01 | 爱励轧制产品德国有限责任公司 | 包含轧制铝合金的热交换器 |
FR3080058B1 (fr) * | 2018-04-16 | 2023-05-12 | Constellium Neuf Brisach | Tole de brasage multicouche |
CA3094898C (fr) * | 2018-05-22 | 2022-08-23 | Aleris Rolled Products Germany Gmbh | Echangeur de chaleur brase |
FR3096450B1 (fr) * | 2019-05-21 | 2022-05-20 | Valeo Systemes Thermiques | Echangeur de chaleur monobloc comprenant au moins deux blocs d’échange de chaleur comportant chacun un chemin de circulation d’un fluide réfrigérant et un chemin de circulation d’un liquide caloporteur |
SE544093C2 (en) * | 2019-05-21 | 2021-12-21 | Alfa Laval Corp Ab | Plate heat exchanger, and a method of manufacturing a plate heat exchanger |
JP7282468B2 (ja) * | 2019-10-04 | 2023-05-29 | Maアルミニウム株式会社 | アルミニウムブレージングシートおよびアルミニウム部材のフラックスフリーろう付方法 |
EP3842561B1 (fr) * | 2019-12-23 | 2022-08-17 | Novelis Koblenz GmbH | Procédé de fabrication d'un produit laminé en alliage d'aluminium |
CN111041294B9 (zh) * | 2019-12-31 | 2021-03-12 | 辽宁忠旺集团有限公司 | 具有高长期热稳定性的6系低合金成分及其制备方法 |
CN111996421B (zh) * | 2020-08-31 | 2021-09-21 | 包头常铝北方铝业有限责任公司 | 热交换器用铝合金复合板带箔及其制备方法与应用 |
CN115679165A (zh) * | 2021-07-28 | 2023-02-03 | 宝山钢铁股份有限公司 | 一种半导体设备用6系铝合金板材及制造方法 |
CN114231807A (zh) * | 2021-12-15 | 2022-03-25 | 江苏胜翔轻合金科技有限公司 | 应用于换热器的铝合金材料及其制备方法 |
FR3134584A1 (fr) | 2022-04-19 | 2023-10-20 | Constellium Neuf-Brisach | Echangeur de chaleur à base d’un alliage d’aluminium obtenu par brasage |
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JPH0673480A (ja) | 1992-08-26 | 1994-03-15 | Furukawa Alum Co Ltd | アルミニウムブレージングシート |
US5302342A (en) | 1989-11-17 | 1994-04-12 | Honda Giken Kogyo Kabushiki Kaisha | Aluminum alloy for heat exchangers |
EP1795294A1 (fr) | 2005-12-08 | 2007-06-13 | Furukawa-Sky Aluminum Corp. | Procédé de fabrication d'une feuille de brasage |
DE102008034031A1 (de) | 2007-07-19 | 2009-02-12 | Denso Corp., Kariya-shi | Aluminiumlegierungs-Lötblech mit hoher Festigkeit sowie ein Herstellungsverfahren dafür |
WO2017148788A1 (fr) | 2016-02-29 | 2017-09-08 | Aleris Rolled Products Germany Gmbh | Alliage en aluminium laminé pour échangeurs de chaleur |
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JP3505825B2 (ja) * | 1994-11-28 | 2004-03-15 | 三菱アルミニウム株式会社 | ろう付け後に高い疲労強度を保持するAl合金製熱交換器フィン材 |
EP1111077A1 (fr) * | 1999-12-24 | 2001-06-27 | ALUMINIUM RHEINFELDEN GmbH | Alliage d'aluminium à partir de ferailles et alliage de moulage ainsi produit |
SE0101570A0 (en) * | 2001-05-03 | 2002-11-04 | Sapa Heat Transfer Ab | High strength aluminium tube material |
EP1430988B1 (fr) * | 2001-09-28 | 2013-11-20 | Furukawa-Sky Aluminum Corporation | Technique de brasage d'un materiau en aluminium ou en alliage d'aluminium et feuille de brasage en alliage d'aluminium |
JP4107931B2 (ja) * | 2001-09-28 | 2008-06-25 | 古河スカイ株式会社 | アルミニウム又はアルミニウム合金材のろう付け方法およびアルミニウム合金製ブレージングシート |
FR2862984B1 (fr) * | 2003-11-28 | 2006-11-03 | Pechiney Rhenalu | Bande en alliage d'aluminium pour brasage |
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2017
- 2017-02-23 CN CN201780009825.1A patent/CN109072357B/zh not_active Expired - Fee Related
- 2017-02-23 US US16/071,294 patent/US20210033358A1/en not_active Abandoned
- 2017-02-23 EP EP17705918.5A patent/EP3423607B1/fr not_active Revoked
- 2017-02-23 WO PCT/EP2017/054141 patent/WO2017148788A1/fr active Application Filing
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JPH0673480A (ja) | 1992-08-26 | 1994-03-15 | Furukawa Alum Co Ltd | アルミニウムブレージングシート |
EP1795294A1 (fr) | 2005-12-08 | 2007-06-13 | Furukawa-Sky Aluminum Corp. | Procédé de fabrication d'une feuille de brasage |
DE102008034031A1 (de) | 2007-07-19 | 2009-02-12 | Denso Corp., Kariya-shi | Aluminiumlegierungs-Lötblech mit hoher Festigkeit sowie ein Herstellungsverfahren dafür |
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Also Published As
Publication number | Publication date |
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WO2017148788A1 (fr) | 2017-09-08 |
CN109072357B (zh) | 2020-09-01 |
CN109072357A (zh) | 2018-12-21 |
EP3423607A1 (fr) | 2019-01-09 |
US20210033358A1 (en) | 2021-02-04 |
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