EP3417098B1 - Nonwoven with an embossed mesh pattern - Google Patents

Nonwoven with an embossed mesh pattern Download PDF

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Publication number
EP3417098B1
EP3417098B1 EP16825393.8A EP16825393A EP3417098B1 EP 3417098 B1 EP3417098 B1 EP 3417098B1 EP 16825393 A EP16825393 A EP 16825393A EP 3417098 B1 EP3417098 B1 EP 3417098B1
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EP
European Patent Office
Prior art keywords
woven fabric
embossed
embossing
pattern
nonwoven
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EP16825393.8A
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German (de)
French (fr)
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EP3417098A1 (en
Inventor
Norbert Weis
Christoph RIEGER
Klaus SCHWOEBEL
Dieter Philipp
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Carl Freudenberg KG
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Carl Freudenberg KG
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Publication date
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Priority to PL16825393T priority Critical patent/PL3417098T3/en
Publication of EP3417098A1 publication Critical patent/EP3417098A1/en
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Classifications

    • DTEXTILES; PAPER
    • D04BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04HMAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H1/00Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
    • D04H1/40Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
    • D04H1/44Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties the fleeces or layers being consolidated by mechanical means, e.g. by rolling
    • D04H1/46Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties the fleeces or layers being consolidated by mechanical means, e.g. by rolling by needling or like operations to cause entanglement of fibres
    • D04H1/48Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties the fleeces or layers being consolidated by mechanical means, e.g. by rolling by needling or like operations to cause entanglement of fibres in combination with at least one other method of consolidation
    • D04H1/485Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties the fleeces or layers being consolidated by mechanical means, e.g. by rolling by needling or like operations to cause entanglement of fibres in combination with at least one other method of consolidation in combination with weld-bonding
    • DTEXTILES; PAPER
    • D04BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04HMAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H1/00Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
    • D04H1/40Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
    • D04H1/54Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties by welding together the fibres, e.g. by partially melting or dissolving
    • D04H1/541Composite fibres, e.g. sheath-core, sea-island or side-by-side; Mixed fibres
    • DTEXTILES; PAPER
    • D04BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04HMAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H1/00Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
    • D04H1/40Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
    • D04H1/54Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties by welding together the fibres, e.g. by partially melting or dissolving
    • D04H1/541Composite fibres, e.g. sheath-core, sea-island or side-by-side; Mixed fibres
    • D04H1/5418Mixed fibres, e.g. at least two chemically different fibres or fibre blends
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06CFINISHING, DRESSING, TENTERING OR STRETCHING TEXTILE FABRICS
    • D06C23/00Making patterns or designs on fabrics
    • D06C23/04Making patterns or designs on fabrics by shrinking, embossing, moiréing, or crêping
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06CFINISHING, DRESSING, TENTERING OR STRETCHING TEXTILE FABRICS
    • D06C2700/00Finishing or decoration of textile materials, except for bleaching, dyeing, printing, mercerising, washing or fulling
    • D06C2700/31Methods for making patterns on fabrics, e.g. by application of powder dye, moiréing, embossing

Definitions

  • the invention relates to a nonwoven fabric with an embossed mesh pattern.
  • the invention further relates to a method for producing such a nonwoven fabric and its use as a wipe for the household, the commercial sector and / or as a wiping material in a mop.
  • Textile fabrics in the form of nonwovens are widely used as wipes and as a wiping material in mops.
  • the fibers in such nonwovens are usually either thermally bonded by fusing existing thermoplastic fibers or by gluing or binding the fibers in by means of applied or incorporated chemical binder systems.
  • JP 60-194160 a thermal Pressing described using heated rollers.
  • the result of this full-surface pressing is thin, less flexible, paper-like and less absorbent fabrics.
  • wet baby wipes can also be partially embossed to increase the strength of the material, but this leads to an increase in the bending moment in the known methods and patterns and thus to an undesirable stiffness of the wipes.
  • the cited document proposes to set a distance of at least half of the nominal fiber length between discrete (individual, unrelated) embossed areas.
  • the embossed area should be between 4% and 8% of the total area.
  • the invention is based on the object of specifying a nonwoven fabric which at the same time meets high requirements with regard to softness, flexibility and durability.
  • the nonwoven fabric should have sufficient absorption properties and, in particular, should enable the production of wipes and wiping materials in mops with the abovementioned properties.
  • the present invention relates to a nonwoven fabric comprising framework fibers and an at least partially fused thermoplastic material, in particular at least partially fused thermoplastic binder fibers, at least the framework fibers being staple fibers, the nonwoven fabric having a thermally embossed mesh pattern consisting of a plurality of intersecting embossing grooves, between which a large number is arranged by embossing elevations, the equivalent diameter of the embossing elevations being less than 50% of the fiber length of the framework fibers, the ratio of the width of the embossing grooves to the thickness of the nonwoven fabric in the region of the embossing elevations being less than or equal to 4/5 and the ratio of the width of the Embossing grooves for the thickness of the nonwoven fabric in the region of the embossing grooves is 0.5 to, characterized in that the proportion of the at least partially fused thermoplastic material is from 5% by weight to 30% by weight.
  • An essential aspect of the nonwoven fabric according to the invention is the presence of a thermally embossed mesh pattern made up of a plurality of intersecting embossing grooves.
  • this network pattern is between the A large number of embossing elevations are arranged in the embossing grooves.
  • the nonwoven fabric is compressed in comparison to the embossing elevations and the thermoplastic material is at least partially fused, which stabilizes the embossed structure.
  • the mesh pattern also has a positive effect on the stability and durability of the nonwoven as a whole.
  • the pattern can be formed over the entire surface or only on partial areas of the nonwoven fabric.
  • the mesh pattern is formed on at least 60%, preferably 70% to 100% and in particular 80% to 100% of the surface of the nonwoven fabric.
  • embossing grooves are arranged and dimensioned such that the equivalent diameter of the embossing elevations is less than 50% of the fiber length of the framework fibers.
  • the term "equivalent diameter of the embossment elevations” means the diameter of the smallest circle that circumscribes (i.e., can be drawn and / or include around) the entire embossment elevation. Rewriting the symbol means that at least two points of the embossing elevation touch the circle tangentially and no section of the embossing elevation intersects the circle to the outside. Of course, a real circle does not have to be drawn or marked on the nonwoven fabric for rewriting. For the purposes of the present invention, equivalent symbol diameters were determined as shown in the Test Methods section below.
  • the ratio of the width of the embossing grooves to the thickness of the nonwoven fabric in the area of the embossed elevations is less than or equal to 4/5 and the ratio the width of the embossing grooves to the thickness of the nonwoven in the area of the embossing grooves is from 0.5 to 2.
  • the width of the embossing grooves is defined as the distance between two turning points W of the transitions of an embossing groove into the adjacent embossing elevations.
  • the width of the embossing grooves was determined as shown in the Test Methods section below.
  • the thickness of the nonwoven fabric in the area of the embossing surveys was measured in accordance with DIN EN ISO 9073-2: 1997 and the thickness of the nonwoven fabric in the area of the embossing grooves as shown below in the section on test methods.
  • the special arrangement and dimensioning of the embossing grooves in relation to the fiber length enables a high proportion of scaffold fibers that have been tied multiple times, for example twice, ie scaffold fibers that are tied at at least two different locations in the compressed area of the embossing grooves.
  • the durability and strength of the nonwoven fabric can be improved and less fiber loss can be achieved when using and washing the nonwoven fabric.
  • the nonwoven fabric according to the invention is surprisingly distinguished by a high degree of flexibility or a low bending moment, which makes the nonwoven fabric extremely supple and, as a result, pleasant to the touch gives.
  • the specific mesh pattern gives the nonwoven a good cleaning performance even for coarse dirt particles.
  • the individual framework fibers are strongly connected to one another in a three-dimensional structure by the thermoplastic material in the embossing grooves, and thus in their mutual position and possibility of movement are limited, but the embossing grooves are just so far apart that the embossed areas can serve as joints to a certain extent, thereby increasing the flexibility of the nonwoven.
  • the equivalent diameter of the embossing elevations is 5% to 50%, more preferably 5% to 40%, even more preferably 7% to 40% and in particular 8% to 30% of the fiber length of the framework fibers .
  • the ratio of the width of the embossing grooves to the thickness of the nonwoven in the region of the embossing elevations is from 4/5 to 1/5, more preferably from 4/5 to 1/3 and in particular from 2/3 to Is 1/3.
  • the ratio of the width of the embossing grooves to the thickness of the nonwoven fabric in the region of the embossing grooves is from 0.5 to 1.5 and in particular from 0.75 to 1.25.
  • the proportion of the surface of the embossed elevations on the total surface of the nonwoven can be adjusted depending on the desired properties of the nonwoven.
  • the fluffiness and absorbency of the nonwoven can be increased by increasing the proportion of the surface of the embossed elevations in the total surface of the nonwoven.
  • the mesh pattern is only present on partial areas of the nonwoven, then only the partial area provided with the mesh pattern is regarded as the total surface of the nonwoven for determining the proportion of the surface of the embossed elevations.
  • the proportion of the surface of the embossed elevations in the total surface of the nonwoven fabric can be determined by coloring the embossed elevations and subsequent optical evaluation, as shown below in the section on the test methods.
  • the proportion of the surface of the embossing grooves in the total surface of the nonwoven fabric is preferably more than 15%, for example from 15% to 45%, more preferably from 20% to 40%.
  • the mesh pattern is only present on partial areas of the nonwoven fabric, only that with is used to determine the proportion of the surface of the embossing grooves Partial area provided with the mesh pattern is regarded as the total surface of the nonwoven.
  • the proportion of the surface of the embossing grooves on the total surface of the nonwoven fabric can also be determined by coloring the embossing elevations and visual evaluation, as shown below in the section on the test methods.
  • the nonwoven contains an at least partially fused thermoplastic material, in particular thermoplastic binding fibers.
  • thermoplastic material can comprise thermoplastic binding particles, in particular binding powder, and / or binding fibers. Binding fibers are preferred according to the invention since they are particularly easy to process and can be distributed homogeneously in the nonwoven fabric.
  • the melting point of the thermoplastic material is advantageously at least 30 ° C, for example from 30 ° C to 150 ° C, more preferably at least 40 ° C, for example from 40 ° C to 150 ° C and in particular at least 45 ° C for example from 45 ° C to 130 ° C below the melting point or decomposition point of the framework fibers.
  • the at least partially fused thermoplastic material enables the embossed mesh pattern and the nonwoven fabric to be stabilized overall.
  • This material can be melted in the manufacture of the nonwoven in a simple manner, for example by using heated embossing rollers.
  • At least partially fused thermoplastic materials which are particularly preferred according to the invention contain polyolefin, in particular polypropylene and / or polyethylene, and also polyester, polyamide, polylactide, and / or mixtures and copolymers thereof.
  • the nonwoven contains structural fibers as a further component. According to their function as framework fibers, these are preferably either not fused or at least significantly less fused compared to the at least partially fused thermoplastic material.
  • the framework fibers are selected from non-thermoplastic materials, for example natural fibers, preferably cellulosic fibers, in particular viscose or cotton fibers and / or mixtures thereof.
  • non-thermoplastic materials for example natural fibers, preferably cellulosic fibers, in particular viscose or cotton fibers and / or mixtures thereof.
  • thermoplastic fibers as framework fibers is also conceivable, provided that their melting point is at a sufficient distance from the melting point of the at least partially fused thermoplastic material. Polyester, polyamide, polylactide fibers and / or mixtures thereof are particularly suitable for this.
  • the framework fibers are staple fibers.
  • staple fibers In contrast to filaments, which at least theoretically have an unlimited length, staple fibers have defined lengths.
  • the average length of the framework fibers is preferably 15 mm to 85 mm, more preferably 20 mm to 60 mm, in particular 25 mm to 55 mm. It has been shown that the combination of the aforementioned fiber lengths and the specific network pattern makes it possible to achieve a double fiber setting and yet to ensure a sufficient amount of unbound fiber surface and free fiber ends in order to achieve a high cleaning performance of the nonwoven.
  • the average titer of the framework fibers is preferably between 0.1 dtex and 2.6 dtex, more preferably from 0.3 dtex to 2.4 dtex, in particular from 0.6 dtex to 2.2 dtex. If there is a mixture of fibers of different titers, fiber titers greater than 6.7 dtex are not taken into account for the determination of the average titre. It has been shown that fibers with the aforementioned fiber titers on the one hand enable a high cleaning line and on the other hand a good hand feel.
  • the basis weight of the nonwoven fabric is preferably in the range between 50 g / m 2 and 300 g / m 2 , more preferably from 100 g / m 2 to 250 g / m 2 , in particular from 120 g / m 2 to 220 g / m 2 . It has been shown that with the above-mentioned basis weights, on the one hand, due to a sufficient volume, a high absorption capacity and, on the other hand, a satisfactory and pleasant flexibility of the nonwoven can be achieved.
  • the volume weight of the area of the nonwoven fabric compressed by the embossing grooves can be calculated from the thickness of the nonwoven fabric in the area of the embossing grooves and from the basis weight of the nonwoven fabric and is preferably less than 0.0005 g / mm 3 , more preferably 0.00015 g / mm 3 to 0.00045 g / mm 3 .
  • the nonwoven fabric In the area of the embossing elevations, the nonwoven fabric has a lower density than in the area of the embossing grooves and is therefore more voluminous and absorbent than in the area of the embossing grooves.
  • the volume weight of the area of the nonwoven fabric which is not compressed by the embossing grooves can be calculated from the thickness of the nonwoven fabric in the area of the embossed elevations and the basis weight of the nonwoven fabric and is preferably less than 0.00015 g / mm 3 , more preferably 0.00008 g / mm 3 to 0.00012 g / mm 3 .
  • the nonwoven fabric according to the invention surprisingly has a low bending moment at least in one direction.
  • This bending moment is preferably less than the bending moment of a nonwoven fabric of the same structure without embossing grooves.
  • the bending moment of a nonwoven according to the invention is preferably less than 90% in at least one direction, more preferably between 70% and 90%, in particular between 75% and 85% of a nonwoven fabric of the same structure without embossing.
  • the nonwoven fabric can be thermally bonded via the at least partially fused thermoplastic material.
  • the partially fused thermoplastic material is at least in the Areas of the embossing grooves.
  • the at least partially fused thermoplastic material is also present in the areas of the embossed elevations, which enables the nonwoven to be further stabilized.
  • the at least partially fused areas can be formed by the embossing process.
  • the nonwoven fabric can also have a bonding agent for bonding, advantageously at least some of the fibers being bound with a bonding agent.
  • a bonding agent for bonding advantageously at least some of the fibers being bound with a bonding agent.
  • Any binder customary for chemical consolidation of textile materials can be used, the binder preferably being selected from the group consisting of an aqueous copolymer dispersion of vinyl acetate and ethylene.
  • nonwoven fabric is also additionally consolidated by needling.
  • the shape of the embossing grooves can be linear or non-linear, for example wavy or zigzag, provided that a network pattern is formed as a result.
  • embossed grooves have interruptions and, for example, form dashed and / or dotted grooves. This can have an advantageous effect on the absorbency of the nonwoven.
  • the mesh pattern is designed as a diamond pattern, honeycomb pattern, fish scale pattern, waffle pattern, linen pattern, and / or butterfly pattern.
  • FIGS Figures 2 and 4 to 6 fish scale pattern shown this is preferred, for example, in FIGS Figures 2 and 4 to 6 fish scale pattern shown.
  • the mesh pattern is preferably aligned such that the embossing grooves run diagonally to the machine direction. This enables the strength values (measured as maximum tensile force) to be homogenized in the longitudinal and transverse directions.
  • the special configuration of the nonwoven fabric according to the invention enables a homogeneous property profile.
  • the MD / CD ratio of the maximum tensile force is preferably more than 0.65, for example from 0.65 to 0.95, more preferably from 0.75 to 0.95. At these ratios, the nonwoven fabric according to the invention has a homogeneous strength profile, which has proven to be favorable in use.
  • the nonwoven fabric can be constructed in one or more layers. It is preferably constructed in one layer. As a result, the embossed mesh pattern can be formed on both sides of the nonwoven in one process step. Delamination is also difficult.
  • the nonwoven fabric according to the invention is outstandingly suitable as a wipe for the household and / or the commercial sector and / or as a wiping material in a mop.
  • Thermal embossing can be carried out in a simple manner, for example by using heated embossing rollers.
  • the solidification preferably takes place at least by means of needling and, if appropriate, additionally by means of binders and / or thermal action, for example using a calender or an oven. It is advantageous with the needling that it can reorient the fibers in the nonwoven and thus enables a further adjustment of the property profile of the nonwoven.
  • the specific mesh pattern can be obtained by suitable selection of the embossing bars on the embossing rollers.
  • Figure 1 shows the schematic view of a section from the cross section of a nonwoven fabric 1 according to the invention with an embossing groove 2 which has a width 3.
  • the nonwoven fabric 1 has a thickness 4.
  • Two embossing elevations 5 and 5 ' adjoin the embossing groove 2 on the left and right. at.
  • the nonwoven fabric 1 has a thickness 6 in each case.
  • Figure 2 shows the schematic view of the top view of a nonwoven fabric 1 according to the invention comprising a multiplicity of embossed elevations 5.
  • the smallest circle, which describes the entire embossed elevation 5, is shown as an example on an embossed elevation 5.
  • the diameter of this circle is the equivalent diameter 7 of this embossing elevation 5.
  • Figure 3 shows a CT image of a section from the cross section of a nonwoven fabric 1 according to the invention.
  • Figure 4 shows a CT image of a detail from the top view of a nonwoven fabric 1 according to the invention.
  • Figure 5 shows an SEM image in 50-fold enlargement of a detail from the top view of a nonwoven fabric 1 according to the invention.
  • Figure 6 shows a further CT image of a detail from the top view of a nonwoven fabric 1 according to the invention.
  • the smallest circle, which circumscribes the entire embossing survey 5, is shown as an example on an embossing survey 5.
  • the diameter of this circle is the equivalent diameter 7 of this embossing elevation 5.
  • the equivalent diameter of the embossing surveys is determined as follows: As a basis, a computed tomography image of the top view of the nonwoven fabric with the entire pattern repetition unit is used.
  • a circular template is used for the embossed surveys in the network pattern in order to measure the diameter of the smallest circle that can circumscribe the complete embossed elevations (i.e. which is drawn around it and enclose it) may) (as described above with reference to the definition of the equivalent diameter of the embossing elevations).
  • the measurement should be accurate within +/- 0.6 mm.
  • the diameter of the circumscription circle is the equivalent diameter of the embossing elevations.
  • the numerical value of the diameter is taken as the average of at least five individual measurements.
  • embossed elevations ie embossed elevations with an equivalent diameter of less than 5% of the fiber length, are not taken into account.
  • a cross-sectional computed tomographic image of the nonwoven fabric is used.
  • the thinnest points are optically determined by at least five embossing grooves (in this case using Volume Graphics VG Studio Max ), and the mean value is formed. This gives the thickness of the nonwoven in the area of the embossing grooves.
  • the thickness of the nonwoven is first determined. This corresponds to the thickness of the nonwoven in the area of the embossed elevations.
  • the arithmetic mean is then calculated from the thickness of the nonwoven in the area of the embossing grooves and the thickness of the nonwoven in the area of the embossing elevations.
  • the resulting value corresponds to the thickness of the nonwoven in the area of the turning points W, which can now be optically drawn in the computed tomography image. If one measures the shortest distance between two turning points W delimiting the same groove, the width of this embossing groove results. This measurement is repeated for at least five embossing grooves and the average is formed.
  • the same is glued flat on a metal plate of the same dimensions (8 x 4 cm) and a total weight of 114 g ⁇ 10 g and circling without additional pressure using a commercially available stamp pad (ten times in and ten times against clockwise).
  • This sample can then be scanned or photographed and evaluated using image processing software (in the present case using Adobe Photoshop ).
  • the proportion of the embossed elevations in the total surface can be determined on a pixel basis by means of the color difference between the colored areas and the non-colored area. There is at least one triple determination.
  • the difference measurement from the total surface and the proportionate area of the embossing elevations gives the proportion of the area of the embossing grooves in the total area of the nonwoven.
  • the thickness of the nonwoven is measured with a precision thickness measuring device with 25 cm 2 test area and 0.5 kPa pre-pressure. At least ten places on the sample are measured and then the mean value is formed.
  • thermoplastic material The determination of the melting point of the thermoplastic material is determined according to the test specification DIN EN ISO 11357-3: 2013.
  • the maximum tensile force is determined according to the test specification DIN EN ISO 9073-3: 1992.
  • the bending length is determined based on the test specification DIN EN ISO 9073-7: 1998.
  • the sample size is 250 x 50 mm. Three individual measurements are carried out and the mean in mm is formed. The smaller the bending length, the lower the bending stiffness.
  • the production takes place in the dry-laying process.
  • a fiber mixture of 50% viscose fibers (1.7 dtex, 50 mm), 30% polyester fibers (0.9 dtex, 38 mm) and 20% polypropylene hot melt adhesive fibers (2.2 dtex, 40 mm) is mixed homogeneously and laid over a carding machine to a pile. After the pile layers have been doubled, they are consolidated by needling before this nonwoven fabric is additionally heat-set in an oven. A nonwoven stretch is also interposed. The subsequent embossing process embosses a fish-scale mesh pattern on the nonwoven.
  • a design print can be applied to the nonwoven fabric before or after the embossing unit.
  • the nonwoven fabric according to the invention has a weight per unit area of 145 g / m 2 , the thickness in the area of the embossing elevations is 1.4 mm, the thickness in the area of the embossing grooves is 0.7 mm.
  • the equivalent diameter of a mesh sample unit is 6.5 mm. This means that the fibers are thermally set on average at at least two points.
  • the ratio of the width of the embossing grooves and the thickness of the nonwoven fabric in the area of the embossing elevations is 1/2, which has a positive effect on the bending stiffness of the Nonwoven affects, as well as the ratio of the width of the embossing grooves and the thickness of the nonwoven in the area of the embossing grooves, which assumes a value of 1 in this advantageous embodiment.
  • a computer tomographic 3D model of the nonwoven fabric was created to measure and calculate the dimensions of the embossing grooves and embossing grooves.
  • the determination of the thickness of the nonwoven in the area of the embossing, the measurement of the weight per unit area of the nonwoven as well as its strength and bending stiffness was carried out according to the above-mentioned test regulations.
  • the special design of the mesh pattern which covers 30% of the total surface (measured by coloring the raised areas and software-based, pixel-based evaluation), leads to a homogenization of the tensile strengths in the longitudinal and transverse directions and, on the other hand, to a reduction in the bending length in at least one direction ( measured in accordance with the test specification DIN EN ISO 9073-7: 1998) to less than 10 mm of the nonwoven.

Description

Technisches GebietTechnical field

Die Erfindung betrifft einen Vliesstoff mit geprägtem Netzmuster. Die Erfindung betrifft ferner ein Verfahren zur Herstellung eines solchen Vliesstoffs sowie seine Verwendung als Wischtuch für den Haushalt, den gewerblichen Bereich und/oder als Wischmaterial in einem Wischmop.The invention relates to a nonwoven fabric with an embossed mesh pattern. The invention further relates to a method for producing such a nonwoven fabric and its use as a wipe for the household, the commercial sector and / or as a wiping material in a mop.

Stand der TechnikState of the art

Textile Flächengebilde in Form von Vliesstoffen werden weit verbreitet als Wischtücher und als Wischmaterial in Wischmops eingesetzt. Zum Erzielen einer höheren Haltbarkeit werden die Fasern in solchen Vliesstoffen in der Regel entweder thermisch gebunden durch Verschmelzen vorhandener thermoplastischer Fasern oder durch Verkleben beziehungsweise Einbinden der Fasern durch auf- oder eingebrachte chemische Bindersysteme.Textile fabrics in the form of nonwovens are widely used as wipes and as a wiping material in mops. To achieve a higher durability, the fibers in such nonwovens are usually either thermally bonded by fusing existing thermoplastic fibers or by gluing or binding the fibers in by means of applied or incorporated chemical binder systems.

Zur weiteren Erhöhung der Bindung und Verbesserung der mechanischen Eigenschaften wird beispielsweise in der JP 60-194160 ein thermisches Zusammenpressen mittels beheizter Walzen beschrieben. Das Ergebnis dieser vollflächigen Verpressung sind allerdings dünne, wenig flexible, papierartige und wenig absorbierende Flächengebilde.To further increase the bond and improve the mechanical properties, for example, in JP 60-194160 a thermal Pressing described using heated rollers. The result of this full-surface pressing, however, is thin, less flexible, paper-like and less absorbent fabrics.

Wie in der EP 1 322 806 B1 beschrieben, können auch feuchte Babypflegetücher mit partieller Prägung versehen werden, um die Festigkeit des Materials zu erhöhen, was aber bei den bekannten Verfahren und Mustern zu einer Erhöhung des Biegemoments und damit zu einer unerwünschten Steifheit der Tücher führt. Um dennoch feuchte Einwegtücher zu erhalten, die die Anforderungen an Weichheit, Voluminität, Absorption und mechanischer Festigkeit erfüllen, wird in der genannten Schrift vorgeschlagen, zwischen diskreten (einzelnen unzusammenhängenden) geprägten Bereichen einen Abstand von mindestens der Hälfte der Nennfaserlänge einzustellen. Zudem soll der geprägte Bereich zwischen 4 % und 8 % der Gesamtfläche betragen.Like in the EP 1 322 806 B1 described, wet baby wipes can also be partially embossed to increase the strength of the material, but this leads to an increase in the bending moment in the known methods and patterns and thus to an undesirable stiffness of the wipes. In order to nevertheless obtain moist disposable wipes that meet the requirements for softness, volume, absorption and mechanical strength, the cited document proposes to set a distance of at least half of the nominal fiber length between discrete (individual, unrelated) embossed areas. In addition, the embossed area should be between 4% and 8% of the total area.

Flexibilität und Festigkeit sind nach dem beschriebenen Stand der Technik gegenläufige Eigenschaften von thermisch verpressten (kalandrierten) Vliesstoffen. Für den Einsatz als mehrfach verwendbare Wischtücher oder als Wischmaterial in Wischmops sind die nach dem Stand der Technik durch Prägung zu erzielenden Kompromisse aus Weichheit und Festigkeit nicht akzeptabel, so dass sich diese anders als im Bereich von feuchten Einwegtüchern bisher nicht durchsetzen konnten.According to the prior art described, flexibility and strength are opposing properties of thermally pressed (calendered) nonwovens. For use as a reusable wipe or as a wiping material in mops, the compromises of softness and strength to be achieved by embossing according to the prior art are not acceptable, so that, unlike in the area of disposable wet wipes, these have so far not been able to prevail.

Der Erfindung liegt vor diesem Hintergrund die Aufgabe zugrunde, einen Vliesstoff anzugeben, welcher zugleich hohe Anforderungen bezüglich Weichheit, Flexibilität und Haltbarkeit erfüllt. Zudem soll sich der Vliesstoff durch ausreichende Absorptionseigenschaften auszeichnen und insbesondere die Herstellung von Wischtüchern und Wischmaterialien in Wischmops mit den vorgenannten Eigenschaften ermöglichen.Against this background, the invention is based on the object of specifying a nonwoven fabric which at the same time meets high requirements with regard to softness, flexibility and durability. In addition, the nonwoven fabric should have sufficient absorption properties and, in particular, should enable the production of wipes and wiping materials in mops with the abovementioned properties.

Darstellung der ErfindungPresentation of the invention

Die vorliegende Erfindung löst die zuvor genannte Aufgabe durch die Merkmale des Patentanspruchs 1.The present invention achieves the aforementioned object by the features of patent claim 1.

Es wurde erkannt, dass bei einer bestimmten Anordnung und Dimensionierung von Prägenuten im Verhältnis zur Faserlänge sowohl die Haltbarkeit eines Vliesstoffs als auch seine Weichheit und Flexibilität erhöht werden kann und dabei die Absorptionsfähigkeit des Vliesstoffs durch die eingebrachten Prägenuten nicht erheblich verringert wird.It was recognized that with a certain arrangement and dimensioning of embossing grooves in relation to the fiber length, the durability of a nonwoven fabric as well as its softness and flexibility can be increased and the absorbent capacity of the nonwoven fabric is not significantly reduced by the embossing grooves introduced.

Ausführung der ErfindungImplementation of the invention

Die vorliegende Erfindung betrifft einen Vliesstoff, umfassend Gerüstfasern und ein zumindest teilweise verschmolzenes thermoplastisches Material, insbesondere zumindest teilweise verschmolzene thermoplastische Bindefasern, wobei zumindest die Gerüstfasern Stapelfasern sind, wobei der Vliesstoff ein thermisch eingeprägtes Netzmuster aus einer Vielzahl sich kreuzender Prägenuten aufweist, zwischen denen eine Vielzahl von Prägeerhebungen angeordnet ist, wobei der äquivalente Durchmesser der Prägeerhebungen kleiner ist als 50 % der Faserlänge der Gerüstfasern, wobei das Verhältnis der Breite der Prägenuten zur Dicke des Vliesstoffs im Bereich der Prägeerhebungen kleiner oder gleich 4/5 ist und wobei das Verhältnis der Breite der Prägenuten zur Dicke des Vliesstoffs im Bereich der Prägenuten 0.5 bis beträgt, dadurch gekennzeichnet, dass der Anteil des zumindest teilweise verschmolzenen thermoplastischen Materials von 5 Gew.-% bis 30 Gew.-% beträgt.The present invention relates to a nonwoven fabric comprising framework fibers and an at least partially fused thermoplastic material, in particular at least partially fused thermoplastic binder fibers, at least the framework fibers being staple fibers, the nonwoven fabric having a thermally embossed mesh pattern consisting of a plurality of intersecting embossing grooves, between which a large number is arranged by embossing elevations, the equivalent diameter of the embossing elevations being less than 50% of the fiber length of the framework fibers, the ratio of the width of the embossing grooves to the thickness of the nonwoven fabric in the region of the embossing elevations being less than or equal to 4/5 and the ratio of the width of the Embossing grooves for the thickness of the nonwoven fabric in the region of the embossing grooves is 0.5 to, characterized in that the proportion of the at least partially fused thermoplastic material is from 5% by weight to 30% by weight.

Ein wesentlicher Aspekt des erfindungsgemäßen Vliesstoffs ist das Vorhandensein eines thermisch eingeprägten Netzmusters aus einer Vielzahl sich kreuzender Prägenuten. In diesem Netzmuster ist zwischen den Prägenuten eine Vielzahl von Prägeerhebungen angeordnet. Im Bereich der Prägenuten ist der Vliesstoff im Vergleich zu den Prägeerhebungen verdichtet und das thermoplastische Material liegt zumindest teilweise verschmolzen vor, wodurch die eingeprägte Struktur stabilisiert wird. Das Netzmuster wirkt sich zudem positiv auf die Stabilität und Haltbarkeit des Vliesstoffs als Ganzes aus. Das Muster kann vollflächig oder lediglich auf Teilbereichen des Vliesstoffs ausgebildet sein. In einer bevorzugten Ausführungsform der Erfindung ist das Netzmuster auf mindestens 60 %, vorzugsweise 70 % bis 100 % und insbesondere 80 % bis 100 % der Oberfläche des Vliesstoffs ausgebildet.An essential aspect of the nonwoven fabric according to the invention is the presence of a thermally embossed mesh pattern made up of a plurality of intersecting embossing grooves. In this network pattern is between the A large number of embossing elevations are arranged in the embossing grooves. In the area of the embossing grooves, the nonwoven fabric is compressed in comparison to the embossing elevations and the thermoplastic material is at least partially fused, which stabilizes the embossed structure. The mesh pattern also has a positive effect on the stability and durability of the nonwoven as a whole. The pattern can be formed over the entire surface or only on partial areas of the nonwoven fabric. In a preferred embodiment of the invention, the mesh pattern is formed on at least 60%, preferably 70% to 100% and in particular 80% to 100% of the surface of the nonwoven fabric.

Ein weiterer wesentlicher Aspekt des erfindungsgemäßen Vliesstoffs besteht darin, dass die Prägenuten so angeordnet und dimensioniert sind, dass der äquivalente Durchmesser der Prägeerhebungen kleiner ist als 50 % der Faserlänge der Gerüstfasern.Another important aspect of the nonwoven fabric according to the invention is that the embossing grooves are arranged and dimensioned such that the equivalent diameter of the embossing elevations is less than 50% of the fiber length of the framework fibers.

Mit dem Begriff "äquivalenter Durchmesser der Prägeerhebungen", wie hierin verwendet, ist der Durchmesser des kleinsten Kreises gemeint, der die gesamte Prägeerhebung umschreibt (d. h. darum gezeichnet werden und/oder diese einschließen kann). Umschreiben des Symbols bedeutet, dass mindestens zwei Punkte der Prägeerhebung den Kreis tangential berühren und kein Abschnitt der Prägeerhebung den Kreis nach außen schneidet. Natürlich muss für ein Umschreiben kein wirklicher Kreis auf dem Vliesstoff gezeichnet oder markiert werden. Für die Zwecke der vorliegenden Erfindung wurden äquivalente Symboldurchmesser bestimmt wie unten im Abschnitt über die Testverfahren gezeigt.As used herein, the term "equivalent diameter of the embossment elevations" means the diameter of the smallest circle that circumscribes (i.e., can be drawn and / or include around) the entire embossment elevation. Rewriting the symbol means that at least two points of the embossing elevation touch the circle tangentially and no section of the embossing elevation intersects the circle to the outside. Of course, a real circle does not have to be drawn or marked on the nonwoven fabric for rewriting. For the purposes of the present invention, equivalent symbol diameters were determined as shown in the Test Methods section below.

Ein weiterer wesentlicher Aspekt des erfindungsgemäßen Vliesstoffs besteht darin, dass das Verhältnis der Breite der Prägenuten zur Dicke des Vliesstoffs im Bereich der Prägeerhebungen kleiner oder gleich 4/5 ist und das Verhältnis der Breite der Prägenuten zur Dicke des Vliesstoffs im Bereich der Prägenuten von 0.5 bis 2 beträgt.Another important aspect of the nonwoven fabric according to the invention is that the ratio of the width of the embossing grooves to the thickness of the nonwoven fabric in the area of the embossed elevations is less than or equal to 4/5 and the ratio the width of the embossing grooves to the thickness of the nonwoven in the area of the embossing grooves is from 0.5 to 2.

Die Breite der Prägenuten ist dabei definiert als der Abstand zwischen zwei Wendepunkten W der Übergänge einer Prägenut in die angrenzenden Prägeerhebungen. Für die Zwecke der vorliegenden Erfindung wurde die Breite der Prägenuten bestimmt wie unten im Abschnitt über die Testverfahren gezeigt. Ferner wurde die Dicke des Vliesstoffs im Bereich der Prägeerhebungen nach der DIN EN ISO 9073-2:1997 gemessen und die Dicke des Vliesstoffs im Bereich der Prägenuten wie unten im Abschnitt über die Testverfahren gezeigt.The width of the embossing grooves is defined as the distance between two turning points W of the transitions of an embossing groove into the adjacent embossing elevations. For the purposes of the present invention, the width of the embossing grooves was determined as shown in the Test Methods section below. Furthermore, the thickness of the nonwoven fabric in the area of the embossing surveys was measured in accordance with DIN EN ISO 9073-2: 1997 and the thickness of the nonwoven fabric in the area of the embossing grooves as shown below in the section on test methods.

Es wurde gefunden, dass bei dieser speziellen Anordnungen und Dimensionierung der Prägenuten in Abstimmung mit der Faserlänge der Gerüstfasern ein sehr gutes Eigenschaftsprofil aus hoher Festigkeit und Abriebbeständigkeit sowie hohem Absorptionsvermögen und Flexibilität des Vliesstoffs erzielt werden kann, was sich vorteilhaft für die Anwendung als Wischtuch und/oder Wischmaterial in einem Wischmop auswirkt.It has been found that with this special arrangement and dimensioning of the embossing grooves in coordination with the fiber length of the framework fibers, a very good property profile can be achieved from high strength and abrasion resistance as well as high absorbency and flexibility of the nonwoven, which is advantageous for use as a wipe and / or wiping material in a mop.

Insbesondere ermöglicht die spezielle Anordnung und Dimensionierung der Prägenuten im Verhältnis zur Faserlänge einen hohen Anteil an mehrfach, beispielsweise zweifach abgebunden Gerüstfasern, d. h. Gerüstfasern, die an mindestens zwei verschiedenen Stellen im verdichteten Bereich der Prägenuten abgebunden sind. Dadurch kann die Haltbarkeit und Festigkeit des Vliesstoffs verbessert und ein geringer Faserverlust bei der Benutzung und Wäsche des Vliesstoffs erzielt werden. Darüber hinaus zeichnet sich der erfindungsgemäße Vliesstoff überraschenderweise durch eine hohe Flexibilität, beziehungsweise ein niedriges Biegemoment, aus, was dem Vliesstoff eine hohe Anschmiegsamkeit und damit einhergehend ein angenehmes Handgefühl verleiht. Ferner verleiht das spezifische Netzmuster dem Vliesstoff eine gute Reinigungsleistung auch für gröbere Schmutzpartikel.In particular, the special arrangement and dimensioning of the embossing grooves in relation to the fiber length enables a high proportion of scaffold fibers that have been tied multiple times, for example twice, ie scaffold fibers that are tied at at least two different locations in the compressed area of the embossing grooves. As a result, the durability and strength of the nonwoven fabric can be improved and less fiber loss can be achieved when using and washing the nonwoven fabric. In addition, the nonwoven fabric according to the invention is surprisingly distinguished by a high degree of flexibility or a low bending moment, which makes the nonwoven fabric extremely supple and, as a result, pleasant to the touch gives. Furthermore, the specific mesh pattern gives the nonwoven a good cleaning performance even for coarse dirt particles.

Ohne sich an die Theorie binden zu wollen wird angenommen, dass bei der spezifischen erfindungsgemäßen Anordnung und Dimensionierung der Prägenuten und Faserlängen die einzelnen Gerüstfasern durch das thermoplastische Material in den Prägenuten zwar stark miteinander in einer dreidimensionalen Struktur verbunden, und damit in ihrer gegenseitigen Lage und Bewegungsmöglichkeit eingeschränkt sind, aber die Prägenuten gerade noch so weit auseinander liegen, dass die geprägten Bereiche gewissermaßen als Gelenke dienen können und dadurch die Flexibilität des Vliesstoffs erhöht wird.Without wishing to be bound by theory, it is assumed that in the specific arrangement and dimensioning of the embossing grooves and fiber lengths according to the invention, the individual framework fibers are strongly connected to one another in a three-dimensional structure by the thermoplastic material in the embossing grooves, and thus in their mutual position and possibility of movement are limited, but the embossing grooves are just so far apart that the embossed areas can serve as joints to a certain extent, thereby increasing the flexibility of the nonwoven.

Durch diesen Effekt wird die Tendenz, dass ein Prägevorgang üblicherweise das Biegemoment der Materialien dramatisch erhöht, überkompensiert. Dennoch wird aufgrund der intensiven Verbindung der Gerüstfasern eine hohe Beständigkeit, Festigkeit und Dimensionsstabilität bei Benutzung und beim Waschen erreicht.This effect overcompensates the tendency that an embossing process usually dramatically increases the bending moment of the materials. Nevertheless, due to the intensive connection of the scaffold fibers, high durability, strength and dimensional stability are achieved during use and during washing.

In praktischen Versuchen hat es sich als besonders günstig erwiesen, wenn der äquivalente Durchmesser der Prägeerhebungen 5 % bis 50 %, noch bevorzugter 5 % bis 40 %, noch bevorzugter 7 % bis 40 % und insbesondere 8 % bis 30 % der Faserlänge der Gerüstfasern beträgt.In practical tests, it has proven to be particularly advantageous if the equivalent diameter of the embossing elevations is 5% to 50%, more preferably 5% to 40%, even more preferably 7% to 40% and in particular 8% to 30% of the fiber length of the framework fibers .

Ferner hat es sich als besonders günstig erwiesen, wenn das Verhältnis der Breite der Prägenuten zur Dicke des Vliesstoffs im Bereich der Prägeerhebungen von 4/5 bis 1/5, noch bevorzugter von 4/5 bis 1/3 und insbesondere von 2/3 bis 1/3 beträgt.Furthermore, it has proven to be particularly favorable if the ratio of the width of the embossing grooves to the thickness of the nonwoven in the region of the embossing elevations is from 4/5 to 1/5, more preferably from 4/5 to 1/3 and in particular from 2/3 to Is 1/3.

Als ebenfalls besonders günstig hat es sich erwiesen, wenn das Verhältnis der Breite der Prägenuten zur Dicke des Vliesstoffs im Bereich der Prägenuten von 0,5 bis 1,5 und insbesondere von 0,75 bis 1,25 beträgt.It has also proven to be particularly favorable if the ratio of the width of the embossing grooves to the thickness of the nonwoven fabric in the region of the embossing grooves is from 0.5 to 1.5 and in particular from 0.75 to 1.25.

Der Anteil der Oberfläche der Prägeerhebungen an der Gesamtoberfläche des Vliesstoffs kann in Abhängigkeit der erwünschten Eigenschaften des Vliesstoffs eingestellt werden. Grundsätzlich kann mit einer Erhöhung des Anteils der Oberfläche der Prägeerhebungen an der Gesamtoberfläche des Vliesstoffs die Flauschigkeit und Saugfähigkeit des Vliesstoffs gesteigert werden. Als vorteilhaft hat sich vor diesem Hintergrund erwiesen, die Gesamtoberfläche der Prägeerhebungen auf mehr als 50 %, vorzugsweise von 55 % bis 85 %, noch bevorzugter von 60 % bis 80 %, bezogen auf die Gesamtoberfläche des Vliesstoffs einzustellen. Für den Fall, dass das Netzmuster lediglich auf Teilbereichen des Vliesstoffs vorliegt, so wird für die Bestimmung des Anteils der Oberfläche der Prägeerhebungen lediglich der mit dem Netzmuster versehene Teilbereich als Gesamtoberfläche des Vliesstoffs angesehen.The proportion of the surface of the embossed elevations on the total surface of the nonwoven can be adjusted depending on the desired properties of the nonwoven. In principle, the fluffiness and absorbency of the nonwoven can be increased by increasing the proportion of the surface of the embossed elevations in the total surface of the nonwoven. Against this background, it has proven to be advantageous to set the total surface area of the embossing elevations to more than 50%, preferably from 55% to 85%, more preferably from 60% to 80%, based on the total surface area of the nonwoven fabric. In the event that the mesh pattern is only present on partial areas of the nonwoven, then only the partial area provided with the mesh pattern is regarded as the total surface of the nonwoven for determining the proportion of the surface of the embossed elevations.

Dabei kann der Anteil der Oberfläche der Prägeerhebungen an der Gesamtoberfläche des Vliesstoffs mittels Einfärbung der Prägeerhebungen und anschließender optischer Auswertung bestimmt werden wie unten im Abschnitt über die Testverfahren gezeigt.The proportion of the surface of the embossed elevations in the total surface of the nonwoven fabric can be determined by coloring the embossed elevations and subsequent optical evaluation, as shown below in the section on the test methods.

Durch ein Erhöhen des Anteils der Oberfläche der Prägenuten an der Gesamtoberfläche des Vliesstoffs kann wiederum die Beständigkeit, Festigkeit und Dimensionsstabilität des Vliesstoffs gesteigert werden. Vor diesem Hintergrund beträgt der Anteil der Oberfläche der Prägenuten an der Gesamtoberfläche des Vliesstoffs vorzugsweise mehr als 15 %, beispielsweise von 15 % bis 45 %, noch bevorzugter von 20 % bis 40 %. Für den Fall, dass das Netzmuster lediglich auf Teilbereichen des Vliesstoffs vorliegt, so wird für die Bestimmung des Anteils der Oberfläche der Prägenuten lediglich der mit dem Netzmuster versehene Teilbereich als Gesamtoberfläche des Vliesstoffs angesehen.By increasing the proportion of the surface of the embossing grooves in the total surface of the nonwoven fabric, the durability, strength and dimensional stability of the nonwoven fabric can be increased. Against this background, the proportion of the surface of the embossing grooves in the total surface of the nonwoven fabric is preferably more than 15%, for example from 15% to 45%, more preferably from 20% to 40%. In the event that the mesh pattern is only present on partial areas of the nonwoven fabric, only that with is used to determine the proportion of the surface of the embossing grooves Partial area provided with the mesh pattern is regarded as the total surface of the nonwoven.

Der Anteil der Oberfläche der Prägenuten an der Gesamtoberfläche des Vliesstoffs kann ebenfalls mittels Einfärbung der Prägeerhebungen und optischer Auswertung bestimmt werden wie unten im Abschnitt über die Testverfahren gezeigt.The proportion of the surface of the embossing grooves on the total surface of the nonwoven fabric can also be determined by coloring the embossing elevations and visual evaluation, as shown below in the section on the test methods.

Erfindungsgemäß enthält der Vliesstoff ein zumindest teilweise verschmolzenes thermoplastisches Material, insbesondere thermoplastische Bindefasern. Hierdurch können die Gerüstfasern im Vliesstoff verfestigt werden. Das thermoplastische Material kann thermoplastische Bindepartikel, insbesondere Bindepulver, und/oder Bindefasern umfassen. Erfindungsgemäß bevorzugt sind Bindefasern, da diese besonders leicht verarbeitbar sind und sich homogen im Vliesstoff verteilen lassen.According to the invention, the nonwoven contains an at least partially fused thermoplastic material, in particular thermoplastic binding fibers. As a result, the framework fibers can be consolidated in the nonwoven. The thermoplastic material can comprise thermoplastic binding particles, in particular binding powder, and / or binding fibers. Binding fibers are preferred according to the invention since they are particularly easy to process and can be distributed homogeneously in the nonwoven fabric.

Um ein einfaches Aufschmelzen des thermoplastischen Materials bei der Herstellung des Vliesstoffs zu ermöglichen, liegt der Schmelzpunkt des thermoplastischen Materials vorteilhafterweise mindestens 30 °C, beispielsweise von 30 °C bis 150 °C, noch bevorzugter mindestens 40 °C beispielsweise von 40 °C bis 150 °C und insbesondere mindestens 45 °C beispielsweise von 45 °C bis 130 °C unterhalb des Schmelzpunkts oder Zersetzungspunkts der Gerüstfasern.In order to allow easy melting of the thermoplastic material in the manufacture of the nonwoven, the melting point of the thermoplastic material is advantageously at least 30 ° C, for example from 30 ° C to 150 ° C, more preferably at least 40 ° C, for example from 40 ° C to 150 ° C and in particular at least 45 ° C for example from 45 ° C to 130 ° C below the melting point or decomposition point of the framework fibers.

Durch das zumindest teilweise verschmolzene thermoplastische Material kann, wie oben erläutert, eine Stabilisierung des geprägten Netzmusters und des Vliesstoffs insgesamt erzielt werden. Das Aufschmelzen dieses Materials bei der Herstellung des Vliesstoffs kann auf einfache Weise, beispielsweise durch die Verwendung beheizter Prägewalzen, erfolgen.As explained above, the at least partially fused thermoplastic material enables the embossed mesh pattern and the nonwoven fabric to be stabilized overall. This material can be melted in the manufacture of the nonwoven in a simple manner, for example by using heated embossing rollers.

Erfindungsgemäß besonders bevorzugte zumindest teilweise verschmolzene thermoplastische Materialien enthalten Polyolefin, insbesondere Polypropylen- und/oder Polyethylen, sowie Polyester, Polyamid, Polylactid, und/oder Gemische und Co-Polymere hiervon.At least partially fused thermoplastic materials which are particularly preferred according to the invention contain polyolefin, in particular polypropylene and / or polyethylene, and also polyester, polyamide, polylactide, and / or mixtures and copolymers thereof.

Um eine ausreichende Stabilisierung des Netzmusters und des Vliesstoffs insgesamt zu erhalten, hat es sich für zweckmäßig erwiesen, den Anteil des zumindest teilweise verschmolzenen thermoplastischen Materials auf erfindungsgemäss von 5 Gew.-% bis 30 Gew.-%, bevorzugt von 15 Gew.-% bis 25 Gew.-%, bezogen auf das Gesamtgewicht des Vliesstoffs, einzustellen. Eine Einstellung auf mehr als 30 % ist nachteilig, da hierbei die Flexibilität des Vliesstoffs in unerwünschter Weise eingeschränkt wird.
Als weitere Komponente enthält der Vliesstoff Gerüstfasern. Diese liegen entsprechend ihrer Funktion als Gerüstfasern vorzugsweise entweder nicht verschmolzen oder zumindest im Vergleich zu dem zumindest teilweise verschmolzenen thermoplastischen Material deutlich weniger verschmolzen vor. In einer bevorzugten Ausführungsform der Erfindung sind die Gerüstfasern ausgewählt aus nicht-thermoplastischen Materialien, beispielsweise natürlichen Fasern, vorzugsweise cellulosischen Fasern, insbesondere Viskose- oder Baumwollfasern und/oder Gemischen hiervon.
Ebenfalls denkbar ist jedoch auch die Verwendung von thermoplastischen Fasern als Gerüstfasern, sofern deren Schmelzpunkt einen ausreichenden Abstand zum Schmelzpunkt des zumindest teilweise verschmolzenen thermoplastischen Materials aufweist. Hierfür eignen sich insbesondere Polyester-, Polyamid-, Polylactidfasern und/oder Gemische hiervon.
In order to obtain sufficient stabilization of the mesh pattern and of the nonwoven fabric overall, it has proven to be expedient to increase the proportion of the at least partially fused thermoplastic material to 5% by weight to 30% by weight, preferably 15% by weight. up to 25% by weight, based on the total weight of the nonwoven. A setting of more than 30% is disadvantageous since the flexibility of the nonwoven fabric is undesirably restricted.
The nonwoven contains structural fibers as a further component. According to their function as framework fibers, these are preferably either not fused or at least significantly less fused compared to the at least partially fused thermoplastic material. In a preferred embodiment of the invention, the framework fibers are selected from non-thermoplastic materials, for example natural fibers, preferably cellulosic fibers, in particular viscose or cotton fibers and / or mixtures thereof.
However, the use of thermoplastic fibers as framework fibers is also conceivable, provided that their melting point is at a sufficient distance from the melting point of the at least partially fused thermoplastic material. Polyester, polyamide, polylactide fibers and / or mixtures thereof are particularly suitable for this.

Erfindungsgemäß besonders bevorzugt ist die Verwendung von Gemischen aus nicht-thermoplastischen und thermoplastischen Fasern als Gerüstfasern, da hierdurch ein besonders gutes Eigenschaftsprofil für den Einsatz als Wischtuch und/oder Wischmaterial in einem Wischmop erzielt werden kann.According to the invention, particular preference is given to the use of mixtures of non-thermoplastic and thermoplastic fibers as framework fibers, since this enables a particularly good property profile to be achieved for use as a wipe and / or wiping material in a mop.

Erfindungsgemäß sind die Gerüstfasern Stapelfasern. Stapelfasern weisen im Unterschied zu Filamenten, die zumindest theoretisch eine unbegrenzte Länge haben, definierte Längen auf. Die mittlere Länge der Gerüstfasern beträgt vorzugsweise 15 mm bis 85 mm, noch bevorzugter 20 mm bis 60 mm, insbesondere 25 mm bis 55 mm. Es hat sich gezeigt, dass es durch die Kombination der vorgenannten Faserlängen und dem spezifischen Netzmuster möglich ist, eine doppelte Faserabbindung zu erzielen und dennoch ausreichend ungebundene Faseroberfläche und freie Faserenden zu gewährleisten, um eine hohe Reinigungsleistung des Vliesstoffs zu erreichen.According to the invention, the framework fibers are staple fibers. In contrast to filaments, which at least theoretically have an unlimited length, staple fibers have defined lengths. The average length of the framework fibers is preferably 15 mm to 85 mm, more preferably 20 mm to 60 mm, in particular 25 mm to 55 mm. It has been shown that the combination of the aforementioned fiber lengths and the specific network pattern makes it possible to achieve a double fiber setting and yet to ensure a sufficient amount of unbound fiber surface and free fiber ends in order to achieve a high cleaning performance of the nonwoven.

Der mittlere Titer der Gerüstfasern liegt vorzugsweise zwischen 0,1 dtex und 2,6 dtex, noch bevorzugter von 0,3 dtex bis 2,4 dtex, insbesondere von 0,6 dtex bis 2,2 dtex. Liegt eine Mischung aus Fasern unterschiedlicher Titer vor, so werden für die Bestimmung des mittleren Titers Fasertiter größer 6,7 dtex nicht berücksichtigt. Es hat sich gezeigt, dass Fasern mit den vorgenannten Fasertitern zum einen eine hohe Reinigungsleitung und zum anderen ein gutes Handgefühl ermöglichen.The average titer of the framework fibers is preferably between 0.1 dtex and 2.6 dtex, more preferably from 0.3 dtex to 2.4 dtex, in particular from 0.6 dtex to 2.2 dtex. If there is a mixture of fibers of different titers, fiber titers greater than 6.7 dtex are not taken into account for the determination of the average titre. It has been shown that fibers with the aforementioned fiber titers on the one hand enable a high cleaning line and on the other hand a good hand feel.

Das Flächengewicht des Vliesstoffs liegt vorzugsweise im Bereich zwischen 50 g/m2 und 300 g/m2, noch bevorzugter von 100 g/m2 bis 250 g/m2, insbesondere von 120 g/m2 bis 220 g/m2. Es hat sich gezeigt, dass bei den vorgenannten Flächengewichten einerseits, aufgrund eines ausreichend vorliegenden Volumens, eine hohe Absorptionsfähigkeit und andererseits eine zufriedenstellende und angenehme Flexibilität des Vliesstoffs erzielt werden kann.The basis weight of the nonwoven fabric is preferably in the range between 50 g / m 2 and 300 g / m 2 , more preferably from 100 g / m 2 to 250 g / m 2 , in particular from 120 g / m 2 to 220 g / m 2 . It has been shown that with the above-mentioned basis weights, on the one hand, due to a sufficient volume, a high absorption capacity and, on the other hand, a satisfactory and pleasant flexibility of the nonwoven can be achieved.

Das Volumengewicht des durch die Prägenuten verdichteten Bereichs des Vliesstoffs kann aus der Dicke des Vliesstoffs im Bereich der Prägenuten und aus dem Flächengewicht des Vliesstoffs berechnet werden und beträgt vorzugsweise weniger als 0,0005 g/mm3, noch bevorzugter von 0,00015 g/mm3 bis 0,00045 g/mm3.The volume weight of the area of the nonwoven fabric compressed by the embossing grooves can be calculated from the thickness of the nonwoven fabric in the area of the embossing grooves and from the basis weight of the nonwoven fabric and is preferably less than 0.0005 g / mm 3 , more preferably 0.00015 g / mm 3 to 0.00045 g / mm 3 .

Im Bereich der Prägeerhebungen weist der Vliesstoff eine geringere Dichte als im Bereich der Prägenuten auf und ist daher voluminöser und saugfähiger als im Bereich der Prägenuten.In the area of the embossing elevations, the nonwoven fabric has a lower density than in the area of the embossing grooves and is therefore more voluminous and absorbent than in the area of the embossing grooves.

Das Volumengewicht des nicht durch die Prägenuten verdichteten Bereichs des Vliesstoffs kann aus der Dicke des Vliesstoffs im Bereich der Prägeerhebungen und dem Flächengewicht des Vliesstoffs berechnet werden und beträgt vorzugsweise weniger als 0,00015 g/mm3, noch bevorzugter von 0,00008 g/mm3 bis 0,00012 g/mm3.The volume weight of the area of the nonwoven fabric which is not compressed by the embossing grooves can be calculated from the thickness of the nonwoven fabric in the area of the embossed elevations and the basis weight of the nonwoven fabric and is preferably less than 0.00015 g / mm 3 , more preferably 0.00008 g / mm 3 to 0.00012 g / mm 3 .

Wie oben erläutert, weist der erfindungsgemäße Vliesstoff überraschenderweise ein geringes Biegemoment zumindest in einer Richtung auf. Dieses Biegemoment ist dabei vorzugsweise geringer als das Biegemoment eines Vliesstoffs gleichen Aufbaus ohne Prägenuten.As explained above, the nonwoven fabric according to the invention surprisingly has a low bending moment at least in one direction. This bending moment is preferably less than the bending moment of a nonwoven fabric of the same structure without embossing grooves.

Das Biegemoment eines erfindungsgemäßen Vliesstoffs liegt in mindestens einer Richtung vorzugsweise bei weniger als 90 %, noch bevorzugter zwischen 70 % und 90 %, insbesondere zwischen 75 % und 85 % eines Vliesstoffs gleichen Aufbaus ohne Prägung.The bending moment of a nonwoven according to the invention is preferably less than 90% in at least one direction, more preferably between 70% and 90%, in particular between 75% and 85% of a nonwoven fabric of the same structure without embossing.

Wie oben erläutert kann der Vliesstoff über das zumindest teilweise verschmolzene thermoplastische Material thermisch verfestigt vorliegen. Dabei liegt das teilweise verschmolzene thermoplastische Material zumindest in den Bereichen der Prägenuten vor. In einer bevorzugten Ausführungsform liegt das zumindest teilweise verschmolzene thermoplastische Material zusätzlich auch in den Bereichen der Prägeerhebungen vor, was eine weitere Stabilisierung des Vliesstoffs ermöglicht. Die Ausbildung der zumindest teilweise verschmolzenen Bereiche kann, wie oben erläutert, durch den Prägevorgang erfolgen. Es kann jedoch auch vorteilhaft sein, eine zusätzliche thermische Verfestigung durchzuführen, bei der das thermoplastische Material zumindest anteilig verschmilzt.As explained above, the nonwoven fabric can be thermally bonded via the at least partially fused thermoplastic material. The partially fused thermoplastic material is at least in the Areas of the embossing grooves. In a preferred embodiment, the at least partially fused thermoplastic material is also present in the areas of the embossed elevations, which enables the nonwoven to be further stabilized. As explained above, the at least partially fused areas can be formed by the embossing process. However, it can also be advantageous to carry out an additional thermal consolidation in which the thermoplastic material melts at least in part.

Zusätzlich zur thermischen Verfestigung kann der Vliesstoff auch ein Bindemittel zur Verfestigung aufweisen, wobei vorteilhafterweise zumindest ein Teil der Fasern mit einem Bindemittel gebunden vorliegt. Es kann dabei jegliches für eine chemische Verfestigung textiler Materialien übliches Bindemittel eingesetzt werden, wobei das Bindemittel vorzugsweise ausgewählt ist aus der Gruppe bestehend aus einer wässrigen Copolymer-Dispersion aus Vinylacetat und Ethylen.In addition to thermal bonding, the nonwoven fabric can also have a bonding agent for bonding, advantageously at least some of the fibers being bound with a bonding agent. Any binder customary for chemical consolidation of textile materials can be used, the binder preferably being selected from the group consisting of an aqueous copolymer dispersion of vinyl acetate and ethylene.

Ebenfalls denkbar ist, dass der Vliesstoff zusätzlich auch durch Vernadelung verfestigt vorliegt.It is also conceivable that the nonwoven fabric is also additionally consolidated by needling.

Die Form der Prägenuten kann linear oder nichtlinear, beispielsweise wellenförmig oder zickzackförmig ausgeführt sein sofern hierdurch ein Netzmuster gebildet wird.The shape of the embossing grooves can be linear or non-linear, for example wavy or zigzag, provided that a network pattern is formed as a result.

Ebenfalls denkbar ist, dass die Prägenuten Unterbrechungen aufweisen und beispielsweise gestrichelte und/oder gepunktete Nuten bilden. Dies kann sich vorteilhaft auf das Absorptionsvermögen des Vliesstoffs auswirken.It is also conceivable that the embossed grooves have interruptions and, for example, form dashed and / or dotted grooves. This can have an advantageous effect on the absorbency of the nonwoven.

In einer vorteilhaften Ausführungsform der Erfindung ist das Netzmuster als Rautenmuster, Bienenwabenmuster, Fischschuppenmuster, Waffelmuster, Leinenmuster, und/oder Schmetterlingsmuster ausgebildet.In an advantageous embodiment of the invention, the mesh pattern is designed as a diamond pattern, honeycomb pattern, fish scale pattern, waffle pattern, linen pattern, and / or butterfly pattern.

Erfindungsgemäß bevorzugt ist das exemplarisch in den Figuren 2 und 4 bis 6 gezeigte Fischschuppenmuster. Vorzugsweise wird das Netzmuster so ausgerichtet, dass die Prägenuten diagonal zur Maschinenlaufrichtung verlaufen. Hierdurch kann eine Homogenisierung der Festigkeitswerte (gemessen als Höchstzugkraft) in Längs- und Querrichtung erzielt werden.According to the invention, this is preferred, for example, in FIGS Figures 2 and 4 to 6 fish scale pattern shown. The mesh pattern is preferably aligned such that the embossing grooves run diagonally to the machine direction. This enables the strength values (measured as maximum tensile force) to be homogenized in the longitudinal and transverse directions.

Die spezielle Ausgestaltung des erfindungsgemäßen Vliesstoffs ermöglicht ein homogenes Eigenschaftsprofil. So beträgt das MD/CD-Verhältnis der Höchstzugkraft vorzugsweise mehr als 0,65, beispielsweise von 0,65 bis 0,95, noch bevorzugter von 0,75 bis 0,95. Bei diesen Verhältnissen zeigt der erfindungsgemäße Vliesstoff ein homogenes Festigkeitsprofil, was sich bei der Anwendung als günstig erweist.The special configuration of the nonwoven fabric according to the invention enables a homogeneous property profile. The MD / CD ratio of the maximum tensile force is preferably more than 0.65, for example from 0.65 to 0.95, more preferably from 0.75 to 0.95. At these ratios, the nonwoven fabric according to the invention has a homogeneous strength profile, which has proven to be favorable in use.

Der Vliesstoff kann ein- oder mehrlagig aufgebaut sein. Vorzugsweise ist er einlagig aufgebaut. Hierdurch kann das geprägte Netzmuster in einem Prozessschritt auf beiden Seiten des Vliesstoffs ausgebildet werden. Ferner ist eine Delamination erschwert.The nonwoven fabric can be constructed in one or more layers. It is preferably constructed in one layer. As a result, the embossed mesh pattern can be formed on both sides of the nonwoven in one process step. Delamination is also difficult.

Der erfindungsgemäße Vliesstoff eignet sich hervorragend als Wischtuch für den Haushalt und/oder den gewerblichen Bereich und/oder als Wischmaterial in einem Wischmop.The nonwoven fabric according to the invention is outstandingly suitable as a wipe for the household and / or the commercial sector and / or as a wiping material in a mop.

Der erfindungsgemäße Vliesstoff kann beispielweise durch ein Verfahren, umfassend folgende Verfahrensschritte, hergestellt werden:

  • Bereitstellen eines Faserflors umfassend Stapelfasern als Gerüstfasern und ein thermoplastisches Material, insbesondere thermoplastische Bindefasern;
  • Verfestigen des Faserflors mittels Vernadelung, Bindemittel und/oder thermischer Beaufschlagung;
  • Thermisches Einprägen eines Netzmusters unter zumindest teilweisem Verschmelzen des thermoplastischen Materials wobei das Netzmuster
    • eine Vielzahl sich kreuzender Prägenuten aufweist, zwischen denen eine Vielzahl von Prägeerhebungen angeordnet ist,
    • der äquivalente Durchmesser der Prägeerhebungen kleiner ist als 50 % der Faserlänge der Gerüstfasern,
    • das Verhältnis der Breite der Prägenuten zur Dicke des Vliesstoffs im Bereich der Prägeerhebungen kleiner oder gleich 4/5 ist,
    • das Verhältnis der Breite der Prägenuten zur Dicke des Vliesstoffs im Bereich der Prägenuten von 0,5 bis 2 liegt.
The nonwoven fabric according to the invention can be produced, for example, by a process comprising the following process steps:
  • Providing a pile of fibers comprising staple fibers as framework fibers and a thermoplastic material, in particular thermoplastic binding fibers;
  • Solidification of the fibrous web by means of needling, binding agents and / or thermal exposure;
  • Thermal embossing of a mesh pattern with at least partial fusion of the thermoplastic material, the mesh pattern
    • has a multiplicity of intersecting embossing grooves, between which a multiplicity of embossing elevations is arranged,
    • the equivalent diameter of the embossing elevations is less than 50% of the fiber length of the framework fibers,
    • the ratio of the width of the embossing grooves to the thickness of the nonwoven in the area of the embossing elevations is less than or equal to 4/5,
    • the ratio of the width of the embossing grooves to the thickness of the nonwoven in the region of the embossing grooves is from 0.5 to 2.

Das thermische Einprägen kann auf einfache Weise, beispielsweise durch die Verwendung beheizter Prägewalzen, erfolgen.Thermal embossing can be carried out in a simple manner, for example by using heated embossing rollers.

Erfindungsgemäß bevorzugt erfolgt das Verfestigen zumindest mittels Vernadelung und ggf. zusätzlich mittels Bindemittel und/oder thermischer Beaufschlagung, beispielsweise mit einem Kalander oder einem Ofen. Vorteilhaft bei der Vernadelung ist, dass diese eine Umorientierung der Fasern im Vliesstoff herbeiführen kann und somit eine weitere Einstellung des Eigenschaftsprofils des Vliesstoffs ermöglicht.According to the invention, the solidification preferably takes place at least by means of needling and, if appropriate, additionally by means of binders and / or thermal action, for example using a calender or an oven. It is advantageous with the needling that it can reorient the fibers in the nonwoven and thus enables a further adjustment of the property profile of the nonwoven.

Dabei kann das spezifische Netzmuster durch geeignete Wahl der Prägestege auf den Prägewalzen erhalten werden.The specific mesh pattern can be obtained by suitable selection of the embossing bars on the embossing rollers.

Kurzbeschreibung der ZeichnungBrief description of the drawing

In der Zeichnung zeigt:

Fig.1
die schematische Ansicht eines Ausschnitts aus dem Querschnitt eines erfindungsgemäßen Vliesstoffs,
Fig.2
die schematische Darstellung der Draufsicht eines erfindungsgemäßen Vliesstoffs, sowie die vergrößerte Ansicht eines Ausschnitts hiervon,
Fig.3
eine CT-Aufnahme eines Ausschnitts aus dem Querschnitt eines erfindungsgemäßen Vliesstoffs,
Fig.4
eine CT-Aufnahme eines Ausschnitts aus der Draufsicht eines erfindungsgemäßen Vliesstoffs,
Fig.5
eine REM-Aufnahme eines Ausschnitts aus der Draufsicht eines erfindungsgemäßen Vliesstoffs,
Fig.6
eine weitere CT-Aufnahme eines Ausschnitts aus der Draufsicht eines erfindungsgemäßen Vliesstoffs.
The drawing shows:
Fig. 1
the schematic view of a section of the cross section of a nonwoven fabric according to the invention,
Fig. 2
2 shows the schematic representation of the top view of a nonwoven fabric according to the invention, as well as the enlarged view of a section thereof,
Fig. 3
a CT image of a section from the cross section of a nonwoven fabric according to the invention,
Fig. 4
1 shows a CT image of a detail from the top view of a nonwoven according to the invention,
Fig. 5
1 is a SEM image of a detail from the top view of a nonwoven fabric according to the invention,
Fig. 6
another CT image of a detail from the top view of a nonwoven fabric according to the invention.

FigurenbeschreibungFigure description

Figur 1 zeigt die schematische Ansicht eines Ausschnitts aus dem Querschnitt eines erfindungsgemäßen Vliesstoffs 1 mit einer Prägenut 2, die eine Breite 3 aufweist. Im Bereich der Prägenut 2 weist der Vliesstoff 1 eine Dicke 4 auf. Links und rechts an die Prägenut 2 grenzen zwei Prägeerhebungen 5 und 5' an. Im Bereich der Prägeerhebungen 5 und 5', weist der Vliesstoff 1 jeweils eine Dicke 6 auf. Figure 1 shows the schematic view of a section from the cross section of a nonwoven fabric 1 according to the invention with an embossing groove 2 which has a width 3. In the area of the embossing groove 2, the nonwoven fabric 1 has a thickness 4. Two embossing elevations 5 and 5 'adjoin the embossing groove 2 on the left and right. at. In the area of the embossed elevations 5 and 5 ', the nonwoven fabric 1 has a thickness 6 in each case.

Figur 2 zeigt die schematische Ansicht der Draufsicht eines erfindungsgemäßen Vliesstoffs 1 umfassend eine Vielzahl von Prägeerhebungen 5. Exemplarisch ist an einer Prägeerhebung 5 der kleinste Kreis dargestellt, der die gesamte Prägeerhebung 5 umschreibt. Der Durchmesser dieses Kreises ist der äquivalente Durchmesser 7 dieser Prägeerhebung 5. Figure 2 shows the schematic view of the top view of a nonwoven fabric 1 according to the invention comprising a multiplicity of embossed elevations 5. The smallest circle, which describes the entire embossed elevation 5, is shown as an example on an embossed elevation 5. The diameter of this circle is the equivalent diameter 7 of this embossing elevation 5.

Figur 3 zeigt eine CT-Aufnahme eines Ausschnitts aus dem Querschnitt eines erfindungsgemäßen Vliesstoffs 1. Figure 3 shows a CT image of a section from the cross section of a nonwoven fabric 1 according to the invention.

Figur 4 zeigt eine CT-Aufnahme eines Ausschnitts aus der Draufsicht eines erfindungsgemäßen Vliesstoffs 1. Figure 4 shows a CT image of a detail from the top view of a nonwoven fabric 1 according to the invention.

Figur 5 zeigt eine REM-Aufnahme in 50-facher Vergrößerung eines Ausschnitts aus der Draufsicht eines erfindungsgemäßen Vliesstoffs 1. Figure 5 shows an SEM image in 50-fold enlargement of a detail from the top view of a nonwoven fabric 1 according to the invention.

Figur 6 zeigt eine weitere CT-Aufnahme eines Ausschnitts aus der Draufsicht eines erfindungsgemäßen Vliesstoffs 1. Exemplarisch ist an einer Prägeerhebung 5 der kleinste Kreis dargestellt, der die gesamte Prägeerhebung 5 umschreibt. Der Durchmesser dieses Kreises ist der äquivalente Durchmesser 7 dieser Prägeerhebung 5. Figure 6 shows a further CT image of a detail from the top view of a nonwoven fabric 1 according to the invention. The smallest circle, which circumscribes the entire embossing survey 5, is shown as an example on an embossing survey 5. The diameter of this circle is the equivalent diameter 7 of this embossing elevation 5.

PrüfverfahrenTest method

Grundsätzlich ist bei der Auswahl der für die Prüfverfahren herangezogenen Bereiche darauf zu achten, dass jeweils repräsentative Ausschnitte mit dem vorherrschenden Muster gewählt werden.When selecting the areas used for the test methods, it is essential to ensure that representative sections with the predominant pattern are selected.

Äquivalenter Durchmesser der PrägeerhebungenEquivalent diameter of the embossing elevations

Der äquivalente Durchmesser der Prägeerhebungen wird wie folgt bestimmt: Als Grundlage wird eine computertomografische Aufnahme der Draufsicht des Vliesstoffes mit der gesamten Muster-Wiederholungseinheit verwendet.The equivalent diameter of the embossing surveys is determined as follows: As a basis, a computed tomography image of the top view of the nonwoven fabric with the entire pattern repetition unit is used.

In der Auswertung (im vorliegenden Fall mittels Volume Graphics VG Studio Max), wird für die Prägeerhebungen im Netzmuster eine Kreisschablone verwendet, um den Durchmesser des kleinsten Kreises zu messen, der die vollständige Prägeerhebungen umschreiben kann (d.h. der darum herum gezeichnet werden und diese einschließen kann) (wie oben mit Bezug auf die Definition des äquivalenten Durchmessers der Prägeerhebungen beschrieben). Die Messung sollte innerhalb von +/- 0,6 mm genau sein. Der Durchmesser des Umschreibungskreises ist der äquivalente Durchmesser der Prägeerhebungen.In the evaluation (in the present case by means of Volume Graphics VG Studio Max ), a circular template is used for the embossed surveys in the network pattern in order to measure the diameter of the smallest circle that can circumscribe the complete embossed elevations (i.e. which is drawn around it and enclose it) may) (as described above with reference to the definition of the equivalent diameter of the embossing elevations). The measurement should be accurate within +/- 0.6 mm. The diameter of the circumscription circle is the equivalent diameter of the embossing elevations.

Nach Bestimmung der äquivalenten Durchmesser der Prägeerhebungen im Netzmuster wird der numerische Wert der Durchmesser als Mittelwert von mindestens fünf Einzelmessungen genommen.After determining the equivalent diameter of the embossing in the mesh pattern, the numerical value of the diameter is taken as the average of at least five individual measurements.

Dabei werden gegebenenfalls vorhandene sehr kleine Prägeerhebungen, d. h. Prägeerhebungen mit einem äquivalenten Durchmesser von unter 5 % der Faserlänge nicht berücksichtigt.Any very small embossed elevations, ie embossed elevations with an equivalent diameter of less than 5% of the fiber length, are not taken into account.

Dicke des Vliesstoffs im Bereich der Prägenuten und Breite der PrägenutenThickness of the nonwoven in the area of the embossing grooves and width of the embossing grooves

Zur Bestimmung der Dicke des Vliesstoffs im Bereich der Prägenuten wird eine computertomografische Aufnahme des Vliesstoffs im Querschnitt herangezogen.To determine the thickness of the nonwoven fabric in the area of the embossing grooves, a cross-sectional computed tomographic image of the nonwoven fabric is used.

Es werden von mindestens fünf Prägenuten die dünnsten Stellen optisch bestimmt (im vorliegenden Fall mittels Volume Graphics VG Studio Max), und der Mittelwert gebildet. Hierdurch erhält man die Dicke des Vliesstoffs im Bereich der Prägenuten.The thinnest points are optically determined by at least five embossing grooves (in this case using Volume Graphics VG Studio Max ), and the mean value is formed. This gives the thickness of the nonwoven in the area of the embossing grooves.

Zur Bestimmung der Breite der Prägenuten wird zunächst die Dicke des Vliesstoffs bestimmt. Diese entspricht der Dicke des Vliesstoffs im Bereich der Prägeerhebungen.To determine the width of the embossing grooves, the thickness of the nonwoven is first determined. This corresponds to the thickness of the nonwoven in the area of the embossed elevations.

Aus der Dicke des Vliesstoffs im Bereich der Prägenuten und der Dicke des Vliesstoffs im Bereich der Prägeerhebungen wird anschließend das arithmetische Mittel berechnet. Der resultierende Wert entspricht der Dicke des Vliesstoffs im Bereich der Wendepunkte W, die in der computertomografischen Aufnahme nun optisch eingezeichnet werden können. Misst man den kürzesten Abstand zweier die gleiche Nut begrenzender Wendepunkte W, so ergibt sich die Breite dieser Prägenut. Diese Messung wird für mindestens fünf Prägenuten wiederholt und der Mittelwert gebildet.The arithmetic mean is then calculated from the thickness of the nonwoven in the area of the embossing grooves and the thickness of the nonwoven in the area of the embossing elevations. The resulting value corresponds to the thickness of the nonwoven in the area of the turning points W, which can now be optically drawn in the computed tomography image. If one measures the shortest distance between two turning points W delimiting the same groove, the width of this embossing groove results. This measurement is repeated for at least five embossing grooves and the average is formed.

Bestimmung des Anteils der Prägeerhebungen und der Prägenuten an der GesamtoberflächeDetermination of the proportion of the embossing surveys and the embossing grooves in the total surface

Zur Bestimmung des Anteils der Prägeerhebungen an der Gesamtoberfläche des Vliesstoffs wird selbiger auf eine Metallplatte gleicher Abmessung (8 x 4 cm) und einem Gesamtgewicht von 114 g ± 10 g flächig geklebt und ohne zusätzlichen Druck über ein handelsübliches Stempelkissen kreisend (zehnmal im und zehnmal gegen den Uhrzeigersinn) bewegt. Dadurch werden die Prägeerhebungen eingefärbt. Diese Probe kann anschließend eingescannt oder fotografiert und mittels Bildbearbeitungssoftware (im vorliegenden Fall mittels Adobe Photoshop) ausgewertet werden. Über den Farbunterschied der eingefärbten Flächen zur nicht eingefärbten Fläche kann dazu der Anteil der Prägeerhebungen an der Gesamtoberfläche pixelbasiert bestimmt werden. Es erfolgt mindestens eine Dreifachbestimmung.To determine the proportion of the embossing surveys on the total surface of the nonwoven, the same is glued flat on a metal plate of the same dimensions (8 x 4 cm) and a total weight of 114 g ± 10 g and circling without additional pressure using a commercially available stamp pad (ten times in and ten times against clockwise). This embosses the embossed areas. This sample can then be scanned or photographed and evaluated using image processing software (in the present case using Adobe Photoshop ). The proportion of the embossed elevations in the total surface can be determined on a pixel basis by means of the color difference between the colored areas and the non-colored area. There is at least one triple determination.

Die Differenzmessung aus Gesamtoberfläche und anteiliger Fläche der Prägeerhebungen ergibt den Anteil der Fläche der Prägenuten an der Gesamtfläche des Vliesstoffs.The difference measurement from the total surface and the proportionate area of the embossing elevations gives the proportion of the area of the embossing grooves in the total area of the nonwoven.

Dicke des VliesstoffsThickness of the nonwoven

Angelehnt an die Prüfvorschrift DIN EN ISO 9073-2:1997 wird die Dicke des Vliesstoffs mit einem Präzisionsdickenmessgerät mit 25 cm2 Prüffläche und 0,5 kPa Vordruck gemessen. Es werden mindestens zehn Stellen der Probe vermessen und anschließend der Mittelwert gebildet.Based on the test specification DIN EN ISO 9073-2: 1997, the thickness of the nonwoven is measured with a precision thickness measuring device with 25 cm 2 test area and 0.5 kPa pre-pressure. At least ten places on the sample are measured and then the mean value is formed.

FlächengewichtBasis weight

Angelehnt an die Prüfvorschrift DIN EN ISO 9073-1:1989 werden für die Bestimmung des Flächengewichts mindestens zehn Proben mit einer Probengröße von 100 mm x 100 mm ausgestanzt, diese Proben gewogen und die Messwerte mit 100 multipliziert. Aus diesen Einzelwerten wird der Mittelwert gebildet.Based on the test specification DIN EN ISO 9073-1: 1989, at least ten samples with a sample size of 100 mm x 100 mm are punched out to determine the basis weight, these samples are weighed and the measured values are multiplied by 100. The mean value is formed from these individual values.

Länge der StapelfasernLength of the staple fibers

Die Einzelfaserlängenmessung erfolgt je nach Fasertype mit dem Ein- oder mit dem Zwei-Pinzetten-Verfahren in Anlehnung an die DIN 53808-1:03. Abweichend zur Prüfnorm beträgt die Anzahl der Messungen n = 50.Depending on the type of fiber, the individual fiber length measurement is carried out using the one or two-tweezers method based on DIN 53808-1: 03. Deviating from the test standard, the number of measurements is n = 50.

Es ist darauf zu achten, dass die Fasern bei der Entnahme aus dem Vliesstoff nicht eingekürzt werden. Dies gilt speziell für thermisch verfestigte und geprägte Vliesstoffe.It is important to ensure that the fibers are not shortened when they are removed from the nonwoven. This applies especially to thermally bonded and embossed nonwovens.

Bestimmung des SchmelzpunktsDetermination of the melting point

Die Bestimmung des Schmelzpunkts des thermoplastischen Materials wird nach der Prüfvorschrift DIN EN ISO 11357-3:2013 bestimmt.The determination of the melting point of the thermoplastic material is determined according to the test specification DIN EN ISO 11357-3: 2013.

Bestimmung der ZugfestigkeitDetermination of tensile strength

Die Bestimmung der Höchstzugkraft erfolgt nach der Prüfvorschrift DIN EN ISO 9073-3:1992.The maximum tensile force is determined according to the test specification DIN EN ISO 9073-3: 1992.

Bestimmung der BiegelängeDetermination of the bending length

Die Bestimmung der Biegelänge erfolgt in Anlehnung an die Prüfvorschrift DIN EN ISO 9073-7:1998. Die Probengröße beträgt 250 x 50 mm. Es werden drei Einzelmessungen durchgeführt und der Mittelwert in mm gebildet. Je geringer die Biegelänge ausfällt, desto geringer ist die Biegesteifigkeit.The bending length is determined based on the test specification DIN EN ISO 9073-7: 1998. The sample size is 250 x 50 mm. Three individual measurements are carried out and the mean in mm is formed. The smaller the bending length, the lower the bending stiffness.

Im Folgenden wird die Erfindung anhand eines Beispiels näher erläutert.The invention is explained in more detail below using an example.

Beispielexample

Bei einem beispielhaften erfindungsgemäßen Vliesstoff erfolgt die Herstellung im Trockenlegeverfahren. Bei dieser Ausführung wird eine Fasermischung aus 50 % Viskosefasern (1,7 dtex, 50 mm), 30 % Polyesterfasern (0,9 dtex, 38 mm) und 20 % Polypropylen-Schmelzklebefasern (2,2 dtex, 40 mm) homogen durchmischt und über eine Krempelmaschine zu einem Flor gelegt. Nach Doublierung der Florlagen erfolgt eine Verfestigung durch Vernadelung, ehe dieser Vliesstoff in einem Ofen zusätzlich thermofixiert wird. Ferner wird eine Vliesstreckung zwischengeschaltet. Der anschließende Prägeprozess prägt ein Netzmuster in Fischschuppenoptik auf den Vliesstoff. Zusätzlich kann vor oder nach der Prägeeinheit ein Designdruck auf den Vliesstoff aufgebracht werden.In an exemplary nonwoven fabric according to the invention, the production takes place in the dry-laying process. In this version, a fiber mixture of 50% viscose fibers (1.7 dtex, 50 mm), 30% polyester fibers (0.9 dtex, 38 mm) and 20% polypropylene hot melt adhesive fibers (2.2 dtex, 40 mm) is mixed homogeneously and laid over a carding machine to a pile. After the pile layers have been doubled, they are consolidated by needling before this nonwoven fabric is additionally heat-set in an oven. A nonwoven stretch is also interposed. The subsequent embossing process embosses a fish-scale mesh pattern on the nonwoven. In addition, a design print can be applied to the nonwoven fabric before or after the embossing unit.

Der erfindungsgemäße Vliesstoff weist ein Flächengewicht von 145 g/m2 auf, die Dicke im Bereich der Prägeerhebungen beträgt 1,4 mm, die Dicke im Bereich der Prägenuten 0,7 mm. Der äquivalente Durchmesser einer Netzmustereinheit liegt bei 6,5 mm. Dies führt dazu, dass die Fasern im Mittel an mindestens zwei Punkten thermisch abgebunden werden. Ferner liegt das Verhältnis aus der Breite der Prägenuten und Dicke des Vliesstoffs im Bereich der Prägeerhebungen bei 1/2, was sich positiv auf die Biegesteifigkeit des Vliesstoffs auswirkt, wie auch das Verhältnis von Breite der Prägenuten und Dicke des Vliesstoffs im Bereich der Prägenuten, welches bei dieser vorteilhaften Ausführung einen Wert von 1 annimmt.The nonwoven fabric according to the invention has a weight per unit area of 145 g / m 2 , the thickness in the area of the embossing elevations is 1.4 mm, the thickness in the area of the embossing grooves is 0.7 mm. The equivalent diameter of a mesh sample unit is 6.5 mm. This means that the fibers are thermally set on average at at least two points. Furthermore, the ratio of the width of the embossing grooves and the thickness of the nonwoven fabric in the area of the embossing elevations is 1/2, which has a positive effect on the bending stiffness of the Nonwoven affects, as well as the ratio of the width of the embossing grooves and the thickness of the nonwoven in the area of the embossing grooves, which assumes a value of 1 in this advantageous embodiment.

Zur Messung und Berechnung der Dimensionen der Prägeerhebungen und Prägenuten wurde ein computertomografisches 3D-Modell des Vliesstoffs erzeugt. Die Bestimmung der Dicke des Vliesstoffs im Bereich der Prägeerhebungen, die Messung des Flächengewichts des Vliesstoffs sowie dessen Festigkeit und Biegesteifigkeit erfolgte nach oben genannten Prüfvorschriften.A computer tomographic 3D model of the nonwoven fabric was created to measure and calculate the dimensions of the embossing grooves and embossing grooves. The determination of the thickness of the nonwoven in the area of the embossing, the measurement of the weight per unit area of the nonwoven as well as its strength and bending stiffness was carried out according to the above-mentioned test regulations.

Die besondere Ausgestaltung des Netzmusters, welche 30 % der Gesamtoberfläche abdeckt (gemessen mittels Einfärbung der erhabenen Bereiche und softwaregestützter, pixelbasierter Auswertung), führt zu einer Homogenisierung der Zugfestigkeiten in Längs- und Querrichtung und zum anderen zu einer Verringerung der Biegelänge in zumindest einer Richtung (gemessen in Anlehnung an die Prüfvorschrift DIN EN ISO 9073-7:1998) auf unter 10 mm des Vliesstoffs.The special design of the mesh pattern, which covers 30% of the total surface (measured by coloring the raised areas and software-based, pixel-based evaluation), leads to a homogenization of the tensile strengths in the longitudinal and transverse directions and, on the other hand, to a reduction in the bending length in at least one direction ( measured in accordance with the test specification DIN EN ISO 9073-7: 1998) to less than 10 mm of the nonwoven.

Durch das Aufbringen des spezifischen Netzmusters wird der Vliesstoff stabiler und flexibler zugleich und eignet sich daher hervorragend als Wischtuch und/oder Wischmaterial in Wischmops.Applying the specific mesh pattern makes the nonwoven more stable and flexible at the same time and is therefore ideal as a wipe and / or wiping material in mops.

Claims (13)

  1. Non-woven fabric (1) comprising structural fibres and an at least partially fused thermoplastic material, in particular at least partially fused thermoplastic bonding fibres, wherein at least the structural fibres are staple fibres, and wherein the non-woven fabric (1) has a thermally embossed mesh pattern from a multiplicity of intersecting embossed grooves (2), a multiplicity of embossed elevations (5) being disposed therebetween, wherein
    - the equivalent diameter (7) of the embossed elevations (5) is less than 50% of the fibre length of the structural fibres;
    - the ratio of the width (3) of the embossed grooves (2) to the thickness (6) of the non-woven fabric in the region of the embossed elevations (5) is less than or equal to 4/5; and
    - the ratio of the width (3) of the embossed grooves (2) to the thickness (4) of the non-woven fabric in the region of the embossed grooves (2) is 0.5 to 2,
    characterized in that the proportion of the at least partially fused thermoplastic material is 5% by weight to 30% by weight.
  2. Non-woven fabric (1) according to Claim 1, characterized in that the proportion of the surface of the embossed grooves (2) in terms of the overall surface of the non-woven fabric (1) comprises more than 15% of the overall area of the non-woven fabric (1) .
  3. Non-woven fabric (1) according to one or a plurality of the preceding claims, characterized in that the structural fibres have a mean length of 15 mm to 85 mm.
  4. Non-woven fabric (1) according to one or a plurality of the preceding claims, characterized in that the structural fibres have a yarn count between 0.1 dtex and 2.6 dtex.
  5. Non-woven fabric (1) according to one or a plurality of the preceding claims, characterized by an area weight between 50 g/m2 and 300 g/m2.
  6. Non-woven fabric (1) according to one or a plurality of the preceding claims, characterized in that at least part of the structural fibres are present as needle-bonded and/or bonded by a bonding agent.
  7. Non-woven fabric (1) according to one or a plurality of the preceding claims, characterized in that the embossed grooves (2) have interruptions.
  8. Non-woven fabric (1) according to one or a plurality of the preceding claims, characterized in that said non-woven fabric (1) is of single-ply construction.
  9. Non-woven fabric (1) according to one or a plurality of the preceding claims, characterized in that the mesh pattern is configured as a diamond pattern, a honeycomb pattern, a fish scale pattern, a waffle pattern, a linen pattern, and/or a butterfly pattern.
  10. Non-woven fabric (1) according to one or a plurality of the preceding claims, characterized by a machine-direction/cross-direction ratio of the maximum tensile force of more than 0.65.
  11. Method for producing a non-woven fabric (1) according to one or a plurality of the preceding claims, comprising the following method steps:
    - providing a fibrous pile comprising staple fibres and a thermoplastic material, in particular thermoplastic bonding fibres;
    - consolidating the fibrous pile by means of needle-bonding, bonding agents, and/or thermal impingement;
    - thermally embossing a mesh pattern while at least partially fusing the thermoplastic material, wherein the mesh pattern
    - has a multiplicity of intersecting embossed grooves (3), a multiplicity of embossed elevations (7) being disposed therebetween;
    - the equivalent diameter of the embossed elevations (7) is less than 50% of the fibre length of the structural fibres;
    - the ratio of the width of the embossed grooves (3) to the thickness of the non-woven fabric (1) in the region of the embossed elevations (6) is less than or equal to 4/5.
  12. Method according to Claim 11, characterized in that the consolidating is performed at least by means of needle-bonding and optionally additionally by means of a bonding agent and/or thermal impingement, for example using a calender or an oven.
  13. Use of a non-woven fabric (1) according to one or a plurality of Claims 1 to 10 as a mopping cloth for the domestic and/or the commercial sector, and/or as mopping material in a mop.
EP16825393.8A 2016-02-17 2016-12-21 Nonwoven with an embossed mesh pattern Active EP3417098B1 (en)

Priority Applications (1)

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PL16825393T PL3417098T3 (en) 2016-02-17 2016-12-21 Nonwoven with an embossed mesh pattern

Applications Claiming Priority (2)

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DE102016001807.0A DE102016001807A1 (en) 2016-02-17 2016-02-17 Nonwoven fabric with embossed net pattern
PCT/EP2016/082087 WO2017140403A1 (en) 2016-02-17 2016-12-21 Nonwoven with an embossed mesh pattern

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EP3417098A1 EP3417098A1 (en) 2018-12-26
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US (1) US11668032B2 (en)
EP (1) EP3417098B1 (en)
KR (1) KR102093116B1 (en)
CN (1) CN108495963B (en)
AU (1) AU2016393382B2 (en)
BR (1) BR112018015275A2 (en)
CA (1) CA3013397C (en)
DE (1) DE102016001807A1 (en)
ES (1) ES2797174T3 (en)
HK (1) HK1252723A1 (en)
MX (1) MX2018009886A (en)
PL (1) PL3417098T3 (en)
RU (1) RU2696641C1 (en)
SG (1) SG11201806953XA (en)
WO (1) WO2017140403A1 (en)

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DE102018114147A1 (en) 2018-06-13 2019-12-19 Adler Pelzer Holding Gmbh Three-dimensional shaped fleece
DE102018123447A1 (en) * 2018-09-24 2020-03-26 Carl Freudenberg Kg Use of a nonwoven fabric for the production of a whale lining
FR3092732B1 (en) * 2019-02-19 2021-06-04 Oreal Manufacturing process of a cosmetic article

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AU2016393382A1 (en) 2018-09-06
KR102093116B1 (en) 2020-04-23
HK1252723A1 (en) 2019-05-31
DE102016001807A1 (en) 2017-08-17
CN108495963B (en) 2021-06-04
CA3013397C (en) 2020-09-01
AU2016393382B2 (en) 2019-11-21
SG11201806953XA (en) 2018-09-27
BR112018015275A2 (en) 2018-12-18
US11668032B2 (en) 2023-06-06
MX2018009886A (en) 2018-11-09
ES2797174T3 (en) 2020-12-01
PL3417098T3 (en) 2020-10-05
RU2696641C1 (en) 2019-08-05
CN108495963A (en) 2018-09-04
KR20180113598A (en) 2018-10-16
EP3417098A1 (en) 2018-12-26
WO2017140403A1 (en) 2017-08-24
CA3013397A1 (en) 2017-08-24
US20210189619A1 (en) 2021-06-24

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