EP3369836A1 - Method for manufacturing hot-dip galvanized steel sheet - Google Patents
Method for manufacturing hot-dip galvanized steel sheet Download PDFInfo
- Publication number
- EP3369836A1 EP3369836A1 EP16859230.1A EP16859230A EP3369836A1 EP 3369836 A1 EP3369836 A1 EP 3369836A1 EP 16859230 A EP16859230 A EP 16859230A EP 3369836 A1 EP3369836 A1 EP 3369836A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- zone
- soaking zone
- gas
- hot
- steel strip
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 238000000034 method Methods 0.000 title claims abstract description 33
- 229910001335 Galvanized steel Inorganic materials 0.000 title claims abstract description 17
- 239000008397 galvanized steel Substances 0.000 title claims abstract description 17
- 238000004519 manufacturing process Methods 0.000 title description 2
- 229910000831 Steel Inorganic materials 0.000 claims abstract description 106
- 238000002791 soaking Methods 0.000 claims abstract description 106
- 239000010959 steel Substances 0.000 claims abstract description 106
- 238000010438 heat treatment Methods 0.000 claims abstract description 54
- 238000001816 cooling Methods 0.000 claims abstract description 45
- 239000011248 coating agent Substances 0.000 claims abstract description 37
- 238000000576 coating method Methods 0.000 claims abstract description 37
- 238000005246 galvanizing Methods 0.000 claims abstract description 36
- 238000000137 annealing Methods 0.000 claims abstract description 33
- 230000001590 oxidative effect Effects 0.000 claims abstract description 19
- 238000005275 alloying Methods 0.000 claims description 37
- 238000005259 measurement Methods 0.000 claims description 11
- 230000002349 favourable effect Effects 0.000 abstract description 12
- 239000007789 gas Substances 0.000 description 153
- 238000002485 combustion reaction Methods 0.000 description 12
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 12
- 230000007423 decrease Effects 0.000 description 10
- 239000012528 membrane Substances 0.000 description 9
- 238000011144 upstream manufacturing Methods 0.000 description 9
- 239000000203 mixture Substances 0.000 description 6
- 230000003647 oxidation Effects 0.000 description 6
- 238000007254 oxidation reaction Methods 0.000 description 6
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 5
- 230000007547 defect Effects 0.000 description 5
- 230000001965 increasing effect Effects 0.000 description 5
- 230000003247 decreasing effect Effects 0.000 description 4
- 238000009826 distribution Methods 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- 239000012510 hollow fiber Substances 0.000 description 4
- 239000012535 impurity Substances 0.000 description 4
- 238000009833 condensation Methods 0.000 description 3
- 230000005494 condensation Effects 0.000 description 3
- 238000010586 diagram Methods 0.000 description 3
- 238000011156 evaluation Methods 0.000 description 3
- 239000002737 fuel gas Substances 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- PXGOKWXKJXAPGV-UHFFFAOYSA-N Fluorine Chemical compound FF PXGOKWXKJXAPGV-UHFFFAOYSA-N 0.000 description 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 2
- 239000004642 Polyimide Substances 0.000 description 2
- 229910045601 alloy Inorganic materials 0.000 description 2
- 239000000956 alloy Substances 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 229910052731 fluorine Inorganic materials 0.000 description 2
- 239000011737 fluorine Substances 0.000 description 2
- 239000001257 hydrogen Substances 0.000 description 2
- 229910052739 hydrogen Inorganic materials 0.000 description 2
- 230000001939 inductive effect Effects 0.000 description 2
- 229910052757 nitrogen Inorganic materials 0.000 description 2
- 229920001721 polyimide Polymers 0.000 description 2
- 238000010583 slow cooling Methods 0.000 description 2
- 210000004894 snout Anatomy 0.000 description 2
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 229910001566 austenite Inorganic materials 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 239000000567 combustion gas Substances 0.000 description 1
- 238000004891 communication Methods 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 238000001514 detection method Methods 0.000 description 1
- 229910001873 dinitrogen Inorganic materials 0.000 description 1
- 238000003618 dip coating Methods 0.000 description 1
- 238000010304 firing Methods 0.000 description 1
- 230000005484 gravity Effects 0.000 description 1
- 230000006698 induction Effects 0.000 description 1
- 238000007689 inspection Methods 0.000 description 1
- 239000003014 ion exchange membrane Substances 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 238000003825 pressing Methods 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 230000000717 retained effect Effects 0.000 description 1
- 230000001932 seasonal effect Effects 0.000 description 1
- 230000000007 visual effect Effects 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
Images
Classifications
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- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D1/00—General methods or devices for heat treatment, e.g. annealing, hardening, quenching or tempering
- C21D1/74—Methods of treatment in inert gas, controlled atmosphere, vacuum or pulverulent material
- C21D1/76—Adjusting the composition of the atmosphere
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- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D9/00—Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor
- C21D9/52—Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor for wires; for strips ; for rods of unlimited length
- C21D9/54—Furnaces for treating strips or wire
- C21D9/56—Continuous furnaces for strip or wire
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- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D9/00—Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor
- C21D9/52—Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor for wires; for strips ; for rods of unlimited length
- C21D9/54—Furnaces for treating strips or wire
- C21D9/56—Continuous furnaces for strip or wire
- C21D9/561—Continuous furnaces for strip or wire with a controlled atmosphere or vacuum
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- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D9/00—Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor
- C21D9/52—Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor for wires; for strips ; for rods of unlimited length
- C21D9/54—Furnaces for treating strips or wire
- C21D9/56—Continuous furnaces for strip or wire
- C21D9/573—Continuous furnaces for strip or wire with cooling
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- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
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- C23C2/003—Apparatus
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- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C2/00—Hot-dipping or immersion processes for applying the coating material in the molten state without affecting the shape; Apparatus therefor
- C23C2/003—Apparatus
- C23C2/0038—Apparatus characterised by the pre-treatment chambers located immediately upstream of the bath or occurring locally before the dipping process
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- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C2/00—Hot-dipping or immersion processes for applying the coating material in the molten state without affecting the shape; Apparatus therefor
- C23C2/003—Apparatus
- C23C2/0038—Apparatus characterised by the pre-treatment chambers located immediately upstream of the bath or occurring locally before the dipping process
- C23C2/004—Snouts
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- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C2/00—Hot-dipping or immersion processes for applying the coating material in the molten state without affecting the shape; Apparatus therefor
- C23C2/02—Pretreatment of the material to be coated, e.g. for coating on selected surface areas
- C23C2/022—Pretreatment of the material to be coated, e.g. for coating on selected surface areas by heating
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- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C2/00—Hot-dipping or immersion processes for applying the coating material in the molten state without affecting the shape; Apparatus therefor
- C23C2/02—Pretreatment of the material to be coated, e.g. for coating on selected surface areas
- C23C2/022—Pretreatment of the material to be coated, e.g. for coating on selected surface areas by heating
- C23C2/0222—Pretreatment of the material to be coated, e.g. for coating on selected surface areas by heating in a reactive atmosphere, e.g. oxidising or reducing atmosphere
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- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C2/00—Hot-dipping or immersion processes for applying the coating material in the molten state without affecting the shape; Apparatus therefor
- C23C2/02—Pretreatment of the material to be coated, e.g. for coating on selected surface areas
- C23C2/022—Pretreatment of the material to be coated, e.g. for coating on selected surface areas by heating
- C23C2/0224—Two or more thermal pretreatments
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- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C2/00—Hot-dipping or immersion processes for applying the coating material in the molten state without affecting the shape; Apparatus therefor
- C23C2/04—Hot-dipping or immersion processes for applying the coating material in the molten state without affecting the shape; Apparatus therefor characterised by the coating material
- C23C2/06—Zinc or cadmium or alloys based thereon
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- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C2/00—Hot-dipping or immersion processes for applying the coating material in the molten state without affecting the shape; Apparatus therefor
- C23C2/26—After-treatment
- C23C2/261—After-treatment in a gas atmosphere, e.g. inert or reducing atmosphere
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- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C2/00—Hot-dipping or immersion processes for applying the coating material in the molten state without affecting the shape; Apparatus therefor
- C23C2/26—After-treatment
- C23C2/28—Thermal after-treatment, e.g. treatment in oil bath
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- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C2/00—Hot-dipping or immersion processes for applying the coating material in the molten state without affecting the shape; Apparatus therefor
- C23C2/26—After-treatment
- C23C2/28—Thermal after-treatment, e.g. treatment in oil bath
- C23C2/29—Cooling or quenching
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- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C2/00—Hot-dipping or immersion processes for applying the coating material in the molten state without affecting the shape; Apparatus therefor
- C23C2/34—Hot-dipping or immersion processes for applying the coating material in the molten state without affecting the shape; Apparatus therefor characterised by the shape of the material to be treated
- C23C2/36—Elongated material
- C23C2/40—Plates; Strips
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- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C2/00—Hot-dipping or immersion processes for applying the coating material in the molten state without affecting the shape; Apparatus therefor
- C23C2/50—Controlling or regulating the coating processes
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/02—Ferrous alloys, e.g. steel alloys containing silicon
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/04—Ferrous alloys, e.g. steel alloys containing manganese
Definitions
- the present disclosure relates to a method of producing a hot-dip galvanized steel sheet using a continuous hot-dip galvanizing apparatus that includes: an annealing furnace in which a heating zone, a soaking zone, and a cooling zone are arranged in this order; and a hot-dip galvanizing line adjacent to the cooling zone.
- the galvannealed steel sheet is produced by, after heat-annealing the steel sheet as the base material at a temperature of about 600 °C to 900 °C in a reducing atmosphere or a non-oxidizing atmosphere, hot-dip galvanizing the steel sheet and further heat-alloying the galvanized coating.
- Si in the steel is an oxidizable element, and is selectively oxidized in a typically used reducing atmosphere or non-oxidizing atmosphere and concentrated in the surface of the steel sheet to form an oxide.
- This oxide decreases wettability with molten zinc in the galvanizing process, and causes non-coating.
- Si concentration in the steel With an increase of the Si concentration in the steel, wettability decreases rapidly and non-coating occurs frequently. Even in the case where non-coating does not occur, there is still a problem of poor coating adhesion.
- Si in the steel is selectively oxidized and concentrated in the surface of the steel sheet, a significant alloying delay arises in the alloying process after the hot-dip galvanizing, leading to considerably lower productivity.
- JP 2010-202959 A (PTL 1) describes the following method. With use of a direct fired furnace (DFF), the surface of a steel sheet is oxidized and then the steel sheet is annealed in a reducing atmosphere to internally oxidize Si and prevent Si from being concentrated in the surface of the steel sheet, thus improving the wettability and adhesion of the hot-dip galvanized coating.
- DFF direct fired furnace
- the reducing annealing after heating may be performed by a conventional method (dew point: -30 °C to -40 °C).
- WO 2007/043273 A1 (PTL 2) describes the following technique.
- annealing is performed under the following conditions to internally oxidize Si and prevent Si from being concentrated in the surface of the steel sheet: heating or soaking the steel sheet at a steel sheet temperature in the range of at least 300 °C by indirect heating; setting the atmosphere inside the furnace in each zone to an atmosphere of 1 vol% to 10 vol% hydrogen with the balance being nitrogen and incidental impurities; setting the steel sheet end-point temperature during heating in the upstream heating zone to 550 °C or more and 750 °C or less and the dew point in the upstream heating zone to less than -25 °C; setting the dew point in the subsequent downstream heating zone and soaking zone to -30 °C or more and 0 °C or less; and setting
- JP 2009-209397 A (PTL 3) describes the following technique. While measuring the dew point of furnace gas, the supply and discharge positions of furnace gas are changed depending on the measurement to control the dew point of the gas in the reducing furnace to be in the range of more than -30 °C and 0 °C or less, thus preventing Si from being concentrated in the surface of the steel sheet.
- the heating furnace may be any of a direct fired furnace (DFF), a non-oxidizing furnace (NOF), and a radiant tube, but a radiant tube is preferable as it produces significantly advantageous effects.
- the coating adhesion after the reduction is favorable, the amount of Si internally oxidized tends to be insufficient, and Si in the steel causes the alloying temperature to be higher than typical temperature by 30 °C to 50 °C, as a result of which the tensile strength of the steel sheet decreases. If the oxidation amount is increased to ensure a sufficient amount of Si internally oxidized, oxide scale attaches to rolls in the annealing furnace, inducing pressing flaws, i.e. pick-up defects, in the steel sheet. The means for simply increasing the oxidation amount is therefore not applicable.
- the structure of a continuous hot-dip galvanizing apparatus 100 used in a method of producing a hot-dip galvanized steel sheet according to one of the disclosed embodiments is described first, with reference to FIG. 1 .
- the continuous hot-dip galvanizing apparatus 100 includes: an annealing furnace 20 in which a heating zone 10, a soaking zone 12, and cooling zones 14 and 16 are arranged in this order; a hot-dip galvanizing bath 22 as a hot-dip galvanizing line adjacent to the cooling zone 16; and an alloying line 23 adjacent to the hot-dip galvanizing bath 22.
- the heating zone 10 includes a first heating zone 10A (upstream heating zone) and a second heating zone 10B (downstream heating zone).
- the cooling zone includes a first cooling zone 14 (rapid cooling zone) and a second cooling zone 16 (slow cooling zone).
- a snout 18 connected to the second cooling zone 16 has its tip immersed in the hot-dip galvanizing bath 22, thus connecting the annealing furnace 20 and the hot-dip galvanizing bath 22.
- a steel strip P is introduced from a steel strip introduction port in the lower part of the first heating zone 10A into the first heating zone 10A.
- One or more hearth rolls are arranged in the upper and lower parts in each of the zones 10, 12, 14, and 16.
- the steel strip P is conveyed vertically a plurality of times inside the corresponding predetermined zone in the annealing furnace 20, forming a plurality of passes. While FIG. 1 illustrates an example of having 10 passes in the soaking zone 12, 2 passes in the first cooling zone 14, and 2 passes in the second cooling zone 16, the numbers of passes are not limited to such, and may be set as appropriate depending on the processing condition.
- the steel strip P is not folded back but changed in direction at the right angle to move to the next zone.
- the steel strip P is thus annealed in the annealing furnace 20 by being conveyed through the heating zone 10, the soaking zone 12, and the cooling zones 14 and 16 in this order.
- Adjacent zones in the annealing furnace 20 communicate through a communication portion connecting the upper parts or lower parts of the respective zones.
- the first heating zone 10A and the second heating zone 10B communicate through a throat (restriction portion) connecting the upper parts of the respective zones.
- the second heating zone 10B and the soaking zone 12 communicate through a throat connecting the lower parts of the respective zones.
- the soaking zone 12 and the first cooling zone 14 communicate through a throat connecting the lower parts of the respective zones.
- the first cooling zone 14 and the second cooling zone 16 communicate through a throat connecting the lower parts of the respective zones.
- the height of each throat may be set as appropriate. To enhance the independence of the atmosphere in each zone, the height of each throat is preferably as low as possible.
- the gas in the annealing furnace 20 flows from downstream to upstream in the furnace, and is discharged from the steel strip introduction port in the lower part of the first heating zone 10A.
- the second heating zone 10B is a direct fired furnace (DFF).
- the DFF may be a well-known DFF.
- a plurality of burners are distributed on the inner wall of the direct fired furnace in the second heating zone 10B so as to face the steel strip P, although not illustrated in FIG. 1 .
- the plurality of burners are divided into a plurality of groups, and the combustion rate and the air ratio in each group are independently controllable.
- Combustion exhaust gas in the second heating zone 10B is supplied into the first heating zone 10A, and the steel strip P is preheated by the heat of the gas.
- the combustion rate is a value obtained by dividing the amount of fuel gas actually introduced into a burner by the amount of fuel gas of the burner under its maximum combustion load.
- the combustion rate at the time of combustion by the burner under its maximum combustion load is 100 %.
- the combustion rate is preferably adjusted to 30 % or more.
- the air ratio is a value obtained by dividing the amount of air actually introduced into a burner by the amount of air necessary for complete combustion of fuel gas.
- the heating burners in the second heating zone 10B are divided into four groups (#1 to #4), and the three groups (#1 to #3) upstream in the steel sheet traveling direction are made up of oxidizing burners, and the last group (#4) is made up of reducing burners.
- the air ratio of the oxidizing burners and the air ratio of the reducing burners are independently controllable.
- the air ratio of the oxidizing burners is preferably adjusted to 0.95 or more and 1.5 or less.
- the air ratio of the reducing burners is preferably adjusted to 0.5 or more and less than 0.95.
- the temperature in the second heating zone 10B is preferably adjusted to 800 °C to 1200 °C.
- the soaking zone 12 is capable of indirectly heating the steel strip P using a radiant tube (RT) (not illustrated) as heating means.
- the average temperature Tr (°C) in the soaking zone 12 is measured by a thermocouple inserted into the soaking zone.
- the average temperature Tr (°C) in the soaking zone 12 is preferably adjusted to 700 °C to 900 °C.
- Reducing gas or non-oxidizing gas is supplied into the soaking zone 12.
- the reducing gas H 2 -N 2 mixed gas is typically used.
- An example is gas (dew point: about -60 °C) having a composition containing 1 vol% to 20 vol% H 2 with the balance being N 2 and incidental impurities.
- An example of the non-oxidizing gas is gas (dew point: about -60 °C) having a composition containing N 2 and incidental impurities.
- the reducing gas or non-oxidizing gas supplied into the soaking zone 12 has two forms, namely, humidified gas and dry gas.
- dry gas is reducing gas or non-oxidizing gas having a dew point of about -60 °C to -50 °C and not humidified by a humidifying device.
- humidity gas is gas humidified by a humidifying device to a dew point of 0 °C to 30 °C.
- the humidified gas when producing a high tensile strength steel sheet having a chemical composition containing 0.2 mass% or more Si, it is preferable to supply the humidified gas to the soaking zone 12 in addition to the dry gas, in order to increase the dew point in the soaking zone.
- FIG. 2 is a schematic diagram illustrating a system of supplying the humidified gas and the dry gas to the soaking zone 12.
- the humidified gas is supplied through three systems, namely, humidified gas supply ports 42A, 42B, and 42C, humidified gas supply ports 44A, 44B, and 44C, and humidified gas supply ports 46A, 46B, and 46C.
- a gas distribution device 24 feeds part of the reducing gas or non-oxidizing gas (dry gas) to a humidifying device 26.
- the remaining part passes through a dry gas pipe 32 as dry gas, and is supplied into the soaking zone 12 from dry gas supply ports 48A, 48B, 48C, and 48D.
- the positions and number of dry gas supply ports are not limited, and may be determined as appropriate based on various conditions.
- a plurality of dry gas supply ports are provided at the same height position.
- the dry gas supply ports are preferably distributed evenly in the steel strip traveling direction.
- the gas humidified in the humidifying device 26 is distributed into the three systems by a humidified gas distribution device 30, passes through respective humidified gas pipes 36, and is supplied into the soaking zone 12 from the humidified gas supply ports 42A, 42B, and 42C, the humidified gas supply ports 44A, 44B, and 44C, and the humidified gas supply ports 46A, 46B, and 46C.
- a humidified gas supply port is provided at each of one or more locations in each of four sections obtained by dividing the soaking zone 12 into halves in the vertical direction and dividing the soaking zone 12 into halves in the entry-delivery direction. This enables uniform dew point control for the whole soaking zone 12.
- Reference sign 38 is a humidified gas flowmeter
- reference sign 40 is a humidified gas dew point meter. Since the dew point of the humidified gas can change due to slight dew condensation in the humidified gas pipes 34 and 36 or the like, the dew point meters 40 are desirably located immediately before the humidified gas supply ports 42, 44, and 46.
- the humidifying device 26 includes a humidifying module having a fluorine or polyimide hollow fiber membrane, flat membrane, or the like. Dry gas flows inside the membrane, whereas pure water adjusted to a predetermined temperature in a circulating constant-temperature water bath 28 circulates outside the membrane.
- the fluorine or polyimide hollow fiber membrane or flat membrane is a type of ion exchange membrane with affinity for water molecules.
- the dry gas is humidified to the same dew point as the set water temperature, thus achieving highly accurate dew point control.
- the dew point of the humidified gas can be controlled to any value in the range of 5 °C to 50 °C.
- the pressure in the annealing furnace varies frequently depending on the combustion condition in the heating zone 10 and the cooling fan operating condition in the cooling zones 14 and 16. If the furnace pressure is excessively high, an excessive force acts on the furnace wall, which can damage the annealing furnace. If the furnace pressure is excessively low, oxygen outside the annealing furnace enters into the soaking zone 12 or the combustion gas in the heating zone 10 flows into the soaking zone 12, thus adversely affecting the steel sheet quality. Hence, such control that changes the flow rate of the gas supplied into the soaking zone 12 is typically performed so as to suppress the variation of the furnace pressure and preferably keep the furnace pressure constant.
- the conventional control method changes not only the flow rate of the dry gas but also the flow rate of the humidified gas. Consequently, the amount of moisture supplied into the soaking zone by the humidified gas varies.
- the soaking zone 12 needs to be constantly supplied with a necessary amount of moisture in terms of inducing internal oxidation of Si or Mn in the steel strip. If the flow rate of the humidified gas is decreased in order to suppress the variation of the furnace pressure, the amount of moisture supplied into the soaking zone 12 tends to become insufficient. This causes the dew point in the soaking zone 12 to fall below the lower limit of the appropriate range. As a result, partial non-coating occurs and degrades the coating appearance. Besides, in the operation that also involves alloying treatment, the alloying temperature tends to increase, making it impossible to obtain the desired tensile strength.
- the variation range of the amount of moisture supplied into the soaking zone is defined as (M max - M min )/M max , where M max is a maximum amount of moisture under the same operation condition and M min is a minimum amount of moisture under the same operation condition.
- the amount of moisture can be calculated according to the below-mentioned Formula (2).
- the dew point of the humidified gas is kept constant to control the variation range of its flow rate to 20 % or less.
- the amount of moisture M (g/min) introduced into the soaking zone 12 by the humidified gas needs to be adjusted depending on the volume of the soaking zone and the width and sheet passing speed of the steel strip P passing through the soaking zone 12.
- Setting the flow rate and dew point of the humidified gas so that the amount of moisture M (g/min) supplied into the soaking zone 12 by the humidified gas satisfies the following Formula (1) is effective in obtaining favorable coating appearance: 40 + Vf W ⁇ 0.9 S + 4 / 90 ⁇ M ⁇ 60 + Vf W ⁇ 0.9 S + 4 / 90
- Vf is the volume (m 3 ) of the soaking zone 12
- W is the width (m) of the steel strip P passing through the soaking zone 12
- S is the sheet passing speed (m/s) of the steel strip P.
- the volume Vf of the soaking zone 12 is substantially a constant.
- the width W and sheet passing speed S of the steel strip P passing through the soaking zone 12 increase or in the case where one of the width W and the sheet passing speed S is constant and the other one of the width W and the sheet passing speed S increases, the area of the steel strip in contact with the gas in the soaking zone 12 per unit time increases. Accordingly, the amount of moisture by the humidified gas is increased based on Formula (1).
- the amount of moisture by the humidified gas needs to be decreased based on Formula (1).
- the amount of moisture by the humidified gas is adjusted based on Formula (1). In any case, it is desirable to adjust the flow rate and dew point of the humidified gas so as to satisfy Formula (1), before the dew point in the soaking zone 12 changes as a result of a change in the operation condition.
- the flow rate Vm of the humidified gas supplied into the soaking zone 12 is not limited as long as the aforementioned control is performed, but is generally maintained in the range of 100 to 400 (Nm 3 /hr).
- the flow rate of the dry gas supplied into the soaking zone 12 is not limited, but is generally maintained in the range of 10 to 300 (Nm 3 /hr).
- a dew point measurement port 50 is located in a region of upper 1/2 of the soaking zone 12 in the height direction.
- the vicinity of each humidified gas supply port is a region where the dew point is locally high, and therefore is not suitable for dew point measurement.
- the dew point measurement port 50 is preferably located 1 m or more away from the position of each humidified gas supply port and 1 m or more away from the inner wall position of the soaking zone facing each of the supply ports.
- the cooling zones 14 and 16 cool the steel strip P.
- the steel strip P is cooled to about 480 °C to 530 °C in the first cooling zone 14, and cooled to about 470 °C to 500 °C in the second cooling zone 16.
- the cooling zones 14 and 16 are also supplied with the aforementioned reducing gas or non-oxidizing gas.
- the supply of the dry gas to the cooling zones 14 and 16 is not limited, but the dry gas is preferably supplied from introduction ports in two or more locations in the height direction and two or more locations in the longitudinal direction so that the dry gas is evenly introduced into the cooling zones.
- the total gas flow rate Qcd of the dry gas supplied into the cooling zones 14 and 16 is measured by a gas flowmeter (not illustrated) provided in the pipe.
- the total gas flow rate Qcd is not limited, but is set to about 200 to 1000 (Nm 3 /hr).
- the variation of the pressure in the annealing furnace may be suppressed by adjusting only the flow rate of the dry gas supplied into the soaking zone, but is preferably suppressed by also adjusting the flow rate of the dry gas supplied into the cooling zones.
- the hot-dip galvanizing bath 22 can be used to apply a hot-dip galvanized coating onto the steel strip P discharged from the second cooling zone 16.
- the hot-dip galvanizing may be performed according to a usual method.
- the alloying line 23 can be used to heat-alloy the galvanized coating applied on the steel strip P.
- the alloying treatment may be performed according to a usual method.
- the alloying temperature is kept from being high, thus preventing a decrease in tensile strength of the produced galvannealed steel sheet.
- the alloying line 23 and the alloying treatment by the alloying line 23 are not essential in the present disclosure. The effect of obtaining favorable coating appearance can be achieved even in the case of not performing alloying treatment.
- the steel strip P subjected to annealing and hot-dip galvanizing is not limited, but the advantageous effects according to the present disclosure can be effectively achieved in the case where the steel strip has a chemical composition containing 0.2 mass% or more Si, i.e. in the case of high tensile strength steel.
- the continuous hot-dip galvanizing apparatus illustrated in FIGS. 1 and 2 was used to anneal each steel strip whose chemical composition is listed in Table 1 under each annealing condition listed in Table 2, and then hot-dip galvanize and alloy the steel strip.
- Steel sample ID A and steel sample ID B are both high tensile strength steels.
- time denotes the time elapsed from the operation start, where the type, sheet thickness, and sheet width of the passing steel strip and the operation condition of the continuous hot-dip galvanizing apparatus were changed with the passage of time as listed in Table 2.
- a DFF was used as the second heating zone.
- the heating burners were divided into four groups (#1 to #4) where the three groups (#1 to #3) upstream in the steel sheet traveling direction were made up of oxidizing burners and the last group (#4) was made up of reducing burners, and the air ratios of the oxidizing burners and reducing burners were set to the values listed in Table 2.
- the length of each group in the steel sheet traveling direction was 4 m.
- a RT furnace having a volume Vr of 700 m 3 was used as the soaking zone.
- the average temperature Tr in the soaking zone was set to the value listed in Table 2.
- gas dew point: -50 °C
- Part of the dry gas was humidified by a humidifying device having 10 hollow fiber membrane-type humidifying modules, to prepare humidified gas. Dry gas of 500 L/min at the maximum and circulating water of 20 L/min at the maximum were flown in each module.
- a common circulating constant-temperature water bath capable of supplying pure water of 200 L/min in total was used for each module.
- the dry gas supply ports and the humidified gas supply ports were arranged at the positions illustrated in FIG. 2 .
- the dew point of the humidified gas was kept constant and the variation range of the flow rate of the humidified gas was limited to 20 % or less, as listed in Table 2.
- the furnace pressure was kept constant by adjusting the flow rate of the dry gas supplied into the soaking zone and the cooling zone.
- the field “dew point” of the soaking zone indicates the dew point in the soaking zone measured at the position of the dew point measurement port 50 in FIG. 2 .
- the field “dew point of vicinity of humidified gas supply port” indicates the dew point in the soaking zone measured at a position of 80 cm away from the humidified gas supply port 40B in FIG. 2 .
- the field “dew point of humidified gas” indicates the dew point measured by the humidified gas dew point meter 40 in FIG. 2 .
- the dry gas (dew point: -50 °C) was supplied into the first and second cooling zones from their lowermost parts with the flow rate listed in Table 2.
- the temperature of the molten bath was set to 460 °C, the A1 concentration in the molten bath was set to 0.130 %, and the coating weight was adjusted to 50 g/m 2 per surface by gas wiping.
- the line speed was set to 1.0 m/s to 2.0 m/s, with the change of the sheet thickness.
- alloying treatment was performed in an induction heating-type alloying furnace so that the coating alloying degree (Fe content) was 10 % to 13 %.
- the alloying temperature in the treatment is listed in Table 2.
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Abstract
Description
- The present disclosure relates to a method of producing a hot-dip galvanized steel sheet using a continuous hot-dip galvanizing apparatus that includes: an annealing furnace in which a heating zone, a soaking zone, and a cooling zone are arranged in this order; and a hot-dip galvanizing line adjacent to the cooling zone.
- In recent years, the demand for high tensile strength steel sheets which contribute to more lightweight structures and the like is increasing in the fields of automobiles, household appliances, building products, etc. As high tensile strength steel materials, for example, it is known that a steel sheet with favorable hole expandability can be produced by containing Si in steel, and a steel sheet with favorable ductility where retained austenite (γ) forms easily can be produced by containing Si or Al in steel.
- However, in the case of producing a galvannealed steel sheet using, as a base material, a high tensile strength steel sheet containing a large amount of Si (particularly, 0.2 mass% or more), the following problem arises. The galvannealed steel sheet is produced by, after heat-annealing the steel sheet as the base material at a temperature of about 600 °C to 900 °C in a reducing atmosphere or a non-oxidizing atmosphere, hot-dip galvanizing the steel sheet and further heat-alloying the galvanized coating.
- Here, Si in the steel is an oxidizable element, and is selectively oxidized in a typically used reducing atmosphere or non-oxidizing atmosphere and concentrated in the surface of the steel sheet to form an oxide. This oxide decreases wettability with molten zinc in the galvanizing process, and causes non-coating. With an increase of the Si concentration in the steel, wettability decreases rapidly and non-coating occurs frequently. Even in the case where non-coating does not occur, there is still a problem of poor coating adhesion. Besides, if Si in the steel is selectively oxidized and concentrated in the surface of the steel sheet, a significant alloying delay arises in the alloying process after the hot-dip galvanizing, leading to considerably lower productivity.
- In view of such problems, for example,
JP 2010-202959 A -
WO 2007/043273 A1 (PTL 2) describes the following technique. In a continuous annealing and hot-dip coating method that uses an annealing furnace having an upstream heating zone, a downstream heating zone, a soaking zone, and a cooling zone arranged in this order and a hot-dip molten bath, annealing is performed under the following conditions to internally oxidize Si and prevent Si from being concentrated in the surface of the steel sheet: heating or soaking the steel sheet at a steel sheet temperature in the range of at least 300 °C by indirect heating; setting the atmosphere inside the furnace in each zone to an atmosphere of 1 vol% to 10 vol% hydrogen with the balance being nitrogen and incidental impurities; setting the steel sheet end-point temperature during heating in the upstream heating zone to 550 °C or more and 750 °C or less and the dew point in the upstream heating zone to less than -25 °C; setting the dew point in the subsequent downstream heating zone and soaking zone to -30 °C or more and 0 °C or less; and setting the dew point in the cooling zone to less than -25 °C. PTL 2 also describes humidifying mixed gas of nitrogen and hydrogen and introducing it into the downstream heating zone and/or the soaking zone. -
JP 2009-209397 A -
- PTL 1:
JP 2010-202959 A - PTL 2:
WO 2007/043273 A1 - PTL 3:
JP 2009-209397 A - However, with the method described in PTL 1, although the coating adhesion after the reduction is favorable, the amount of Si internally oxidized tends to be insufficient, and Si in the steel causes the alloying temperature to be higher than typical temperature by 30 °C to 50 °C, as a result of which the tensile strength of the steel sheet decreases. If the oxidation amount is increased to ensure a sufficient amount of Si internally oxidized, oxide scale attaches to rolls in the annealing furnace, inducing pressing flaws, i.e. pick-up defects, in the steel sheet. The means for simply increasing the oxidation amount is therefore not applicable.
- With the method described in PTL 2, since the heating or soaking in the upstream heating zone, downstream heating zone, and soaking zone is performed by indirect heating, the oxidation of the surface of the steel sheet like that by direct firing in PTL 1 is unlikely to occur, and the internal oxidation of Si is insufficient as compared with PTL 1. The problem of an increase in alloying temperature is therefore more serious. Moreover, not only the amount of moisture brought into the furnace varies depending on the external air temperature change or the steel sheet type, but also the dew point of the mixed gas tends to vary depending on the external air temperature change, making it difficult to stably control the dew point in the optimal dew point range. Due to such large dew point variation, surface defects such as non-coating occur even within the aforementioned dew point ranges and temperature ranges. The production of stable products is therefore difficult.
- With the method described in PTL 3, although the use of a DFF in the heating furnace may enable the oxidation of the surface of the steel sheet, stably controlling the dew point in a high dew point range of -20 °C to 0 °C in the aforementioned control range is difficult because humidified gas is not actively supplied to the annealing furnace. Besides, in the case where the dew point increases, the dew point in the upper part of the furnace tends to be high. For example, while a dew point meter in the lower part of the furnace indicates 0 °C, the atmosphere in the upper part of the furnace has a high dew point of +10 °C or more. Operating the furnace in such a state for a long time has been found to cause pick-up defects.
- It could therefore be helpful to provide a method of producing a hot-dip galvanized steel sheet whereby favorable coating appearance can be obtained with high coating adhesion even in the case of hot-dip galvanizing a steel strip whose Si content is 0.2 mass% or more.
- We provide the following:
- [1] A method of producing a hot-dip galvanized steel sheet using a continuous hot-dip galvanizing apparatus that includes: an annealing furnace in which a heating zone, a soaking zone, and a cooling zone are arranged in the stated order; and a hot-dip galvanizing line adjacent to the cooling zone, the method comprising: annealing a steel strip by conveying the steel strip through the heating zone, the soaking zone, and the cooling zone in the stated order inside the annealing furnace; and applying a hot-dip galvanized coating onto the steel strip discharged from the cooling zone, using the hot-dip galvanizing line, wherein reducing gas or non-oxidizing gas is supplied into the soaking zone, the reducing gas or the non-oxidizing gas including: humidified gas humidified by a humidifying device; and dry gas not humidified by the humidifying device, and while a width and a sheet passing speed of the steel strip passing through the soaking zone are constant, a variation of pressure in the annealing furnace is suppressed by adjusting a flow rate of the dry gas, and a variation range of an amount of moisture supplied into the soaking zone by the humidified gas is limited to 20 % or less.
- [2] The method of producing a hot-dip galvanized steel sheet according to [1], wherein a flow rate and a dew point of the humidified gas are set so that an amount of moisture M supplied into the soaking zone by the humidified gas and expressed in g/min satisfies the following Formula (1):
- [3] The method of producing a hot-dip galvanized steel sheet according to [2], wherein when at least one of the width and the sheet passing speed of the steel strip passing through the soaking zone varies, the flow rate and the dew point of the humidified gas are changed so that the amount of moisture M expressed in g/min satisfies the Formula (1).
- [4] The method of producing a hot-dip galvanized steel sheet according to any one of [1] to [3], wherein a dew point in the soaking zone measured at a dew point measurement port provided in the soaking zone is controlled to -25 °C or more and 0 °C or less, the dew point measurement port being provided in a region of upper 1/2 of the soaking zone in a height direction, and located 1 m or more away from a position of a supply port of the humidified gas provided in the soaking zone and 1 m or more away from an inner wall position of the soaking zone facing the supply port.
- [5] The method of producing a hot-dip galvanized steel sheet according to any one of [1] to [4], wherein the heating zone includes a direct fired furnace, the continuous hot-dip galvanizing apparatus includes an alloying line adjacent to the hot-dip galvanizing line, and the method further comprises heat-alloying the galvanized coating applied on the steel strip, using the alloying line.
- With the disclosed method of producing a hot-dip galvanized steel sheet, it is possible to obtain favorable coating appearance with high coating adhesion even in the case of hot-dip galvanizing a steel strip whose Si content is 0.2 mass% or more.
- In the accompanying drawings:
-
FIG. 1 is a sectional diagram illustrating the structure of a continuous hot-dip galvanizingapparatus 100 according to one of the disclosed embodiments; and -
FIG. 2 is a schematic diagram illustrating a system of supplying humidified gas and dry gas to a soakingzone 12 inFIG. 1 . - The structure of a continuous hot-dip galvanizing
apparatus 100 used in a method of producing a hot-dip galvanized steel sheet according to one of the disclosed embodiments is described first, with reference toFIG. 1 . The continuous hot-dip galvanizingapparatus 100 includes: anannealing furnace 20 in which aheating zone 10, asoaking zone 12, andcooling zones bath 22 as a hot-dip galvanizing line adjacent to thecooling zone 16; and analloying line 23 adjacent to the hot-dip galvanizingbath 22. In this embodiment, theheating zone 10 includes afirst heating zone 10A (upstream heating zone) and asecond heating zone 10B (downstream heating zone). The cooling zone includes a first cooling zone 14 (rapid cooling zone) and a second cooling zone 16 (slow cooling zone). Asnout 18 connected to thesecond cooling zone 16 has its tip immersed in the hot-dip galvanizingbath 22, thus connecting the annealingfurnace 20 and the hot-dip galvanizingbath 22. - A steel strip P is introduced from a steel strip introduction port in the lower part of the
first heating zone 10A into thefirst heating zone 10A. One or more hearth rolls are arranged in the upper and lower parts in each of thezones furnace 20, forming a plurality of passes. WhileFIG. 1 illustrates an example of having 10 passes in thesoaking zone 12, 2 passes in thefirst cooling zone 14, and 2 passes in thesecond cooling zone 16, the numbers of passes are not limited to such, and may be set as appropriate depending on the processing condition. At some hearth rolls, the steel strip P is not folded back but changed in direction at the right angle to move to the next zone. The steel strip P is thus annealed in the annealingfurnace 20 by being conveyed through theheating zone 10, thesoaking zone 12, and thecooling zones - Adjacent zones in the annealing
furnace 20 communicate through a communication portion connecting the upper parts or lower parts of the respective zones. In this embodiment, thefirst heating zone 10A and thesecond heating zone 10B communicate through a throat (restriction portion) connecting the upper parts of the respective zones. Thesecond heating zone 10B and the soakingzone 12 communicate through a throat connecting the lower parts of the respective zones. The soakingzone 12 and thefirst cooling zone 14 communicate through a throat connecting the lower parts of the respective zones. Thefirst cooling zone 14 and thesecond cooling zone 16 communicate through a throat connecting the lower parts of the respective zones. The height of each throat may be set as appropriate. To enhance the independence of the atmosphere in each zone, the height of each throat is preferably as low as possible. The gas in theannealing furnace 20 flows from downstream to upstream in the furnace, and is discharged from the steel strip introduction port in the lower part of thefirst heating zone 10A. - In this embodiment, the
second heating zone 10B is a direct fired furnace (DFF). The DFF may be a well-known DFF. A plurality of burners are distributed on the inner wall of the direct fired furnace in thesecond heating zone 10B so as to face the steel strip P, although not illustrated inFIG. 1 . Preferably, the plurality of burners are divided into a plurality of groups, and the combustion rate and the air ratio in each group are independently controllable. Combustion exhaust gas in thesecond heating zone 10B is supplied into thefirst heating zone 10A, and the steel strip P is preheated by the heat of the gas. - The combustion rate is a value obtained by dividing the amount of fuel gas actually introduced into a burner by the amount of fuel gas of the burner under its maximum combustion load. The combustion rate at the time of combustion by the burner under its maximum combustion load is 100 %. When the combustion load is low, the burner cannot maintain a stable combustion state. Accordingly, the combustion rate is preferably adjusted to 30 % or more.
- The air ratio is a value obtained by dividing the amount of air actually introduced into a burner by the amount of air necessary for complete combustion of fuel gas. In this embodiment, the heating burners in the
second heating zone 10B are divided into four groups (#1 to #4), and the three groups (#1 to #3) upstream in the steel sheet traveling direction are made up of oxidizing burners, and the last group (#4) is made up of reducing burners. The air ratio of the oxidizing burners and the air ratio of the reducing burners are independently controllable. The air ratio of the oxidizing burners is preferably adjusted to 0.95 or more and 1.5 or less. The air ratio of the reducing burners is preferably adjusted to 0.5 or more and less than 0.95. The temperature in thesecond heating zone 10B is preferably adjusted to 800 °C to 1200 °C. - In this embodiment, the soaking
zone 12 is capable of indirectly heating the steel strip P using a radiant tube (RT) (not illustrated) as heating means. The average temperature Tr (°C) in the soakingzone 12 is measured by a thermocouple inserted into the soaking zone. The average temperature Tr (°C) in the soakingzone 12 is preferably adjusted to 700 °C to 900 °C. - Reducing gas or non-oxidizing gas is supplied into the soaking
zone 12. As the reducing gas, H2-N2 mixed gas is typically used. An example is gas (dew point: about -60 °C) having a composition containing 1 vol% to 20 vol% H2 with the balance being N2 and incidental impurities. An example of the non-oxidizing gas is gas (dew point: about -60 °C) having a composition containing N2 and incidental impurities. - In this embodiment, the reducing gas or non-oxidizing gas supplied into the soaking
zone 12 has two forms, namely, humidified gas and dry gas. Here, "dry gas" is reducing gas or non-oxidizing gas having a dew point of about -60 °C to -50 °C and not humidified by a humidifying device. Meanwhile, "humidified gas" is gas humidified by a humidifying device to a dew point of 0 °C to 30 °C. - For example, when producing a high tensile strength steel sheet having a chemical composition containing 0.2 mass% or more Si, it is preferable to supply the humidified gas to the soaking
zone 12 in addition to the dry gas, in order to increase the dew point in the soaking zone. On the other hand, for example when producing an ordinary steel sheet (tensile strength of about 270 MPa), it is preferable to supply only the dry gas to the soakingzone 12 without supplying humidified gas. -
FIG. 2 is a schematic diagram illustrating a system of supplying the humidified gas and the dry gas to the soakingzone 12. The humidified gas is supplied through three systems, namely, humidifiedgas supply ports gas supply ports gas supply ports FIG. 2 , agas distribution device 24 feeds part of the reducing gas or non-oxidizing gas (dry gas) to ahumidifying device 26. The remaining part passes through adry gas pipe 32 as dry gas, and is supplied into the soakingzone 12 from drygas supply ports - The positions and number of dry gas supply ports are not limited, and may be determined as appropriate based on various conditions. Preferably, a plurality of dry gas supply ports are provided at the same height position. Moreover, the dry gas supply ports are preferably distributed evenly in the steel strip traveling direction.
- The gas humidified in the
humidifying device 26 is distributed into the three systems by a humidifiedgas distribution device 30, passes through respective humidifiedgas pipes 36, and is supplied into the soakingzone 12 from the humidifiedgas supply ports gas supply ports gas supply ports - The positions and number of humidified gas supply ports are not limited, and may be determined as appropriate based on various conditions. Preferably, a humidified gas supply port is provided at each of one or more locations in each of four sections obtained by dividing the soaking
zone 12 into halves in the vertical direction and dividing the soakingzone 12 into halves in the entry-delivery direction. This enables uniform dew point control for the whole soakingzone 12.Reference sign 38 is a humidified gas flowmeter, andreference sign 40 is a humidified gas dew point meter. Since the dew point of the humidified gas can change due to slight dew condensation in the humidifiedgas pipes dew point meters 40 are desirably located immediately before the humidified gas supply ports 42, 44, and 46. - The
humidifying device 26 includes a humidifying module having a fluorine or polyimide hollow fiber membrane, flat membrane, or the like. Dry gas flows inside the membrane, whereas pure water adjusted to a predetermined temperature in a circulating constant-temperature water bath 28 circulates outside the membrane. The fluorine or polyimide hollow fiber membrane or flat membrane is a type of ion exchange membrane with affinity for water molecules. When moisture content differs between the inside and outside of the hollow fiber membrane, a force for equalizing the moisture content difference emerges and, with this force as a driving force, moisture transmits through the membrane and moves toward the part with lower moisture content. The temperature of dry gas varies with seasonal or daily air temperature change. In this humidifying device, however, heat exchange is possible by ensuring a sufficient contact area between gas and water through the vapor permeable membrane. Accordingly, regardless of whether the dry gas temperature is higher or lower than the circulating water temperature, the dry gas is humidified to the same dew point as the set water temperature, thus achieving highly accurate dew point control. The dew point of the humidified gas can be controlled to any value in the range of 5 °C to 50 °C. When the dew point of the humidified gas is higher than the pipe temperature, there is a possibility that dew condensation occurs in the pipe and dew condensation water enters directly into the furnace. The humidified gas pipe is therefore heated/heat-retained to be not less than the dew point of the humidified gas and not less than the external air temperature. - Regardless of whether or not the humidified gas is supplied into the soaking
zone 12, the pressure in the annealing furnace varies frequently depending on the combustion condition in theheating zone 10 and the cooling fan operating condition in thecooling zones zone 12 or the combustion gas in theheating zone 10 flows into the soakingzone 12, thus adversely affecting the steel sheet quality. Hence, such control that changes the flow rate of the gas supplied into the soakingzone 12 is typically performed so as to suppress the variation of the furnace pressure and preferably keep the furnace pressure constant. In the operation of supplying both the humidified gas and the dry gas to the soakingzone 12, the conventional control method changes not only the flow rate of the dry gas but also the flow rate of the humidified gas. Consequently, the amount of moisture supplied into the soaking zone by the humidified gas varies. - However, the soaking
zone 12 needs to be constantly supplied with a necessary amount of moisture in terms of inducing internal oxidation of Si or Mn in the steel strip. If the flow rate of the humidified gas is decreased in order to suppress the variation of the furnace pressure, the amount of moisture supplied into the soakingzone 12 tends to become insufficient. This causes the dew point in the soakingzone 12 to fall below the lower limit of the appropriate range. As a result, partial non-coating occurs and degrades the coating appearance. Besides, in the operation that also involves alloying treatment, the alloying temperature tends to increase, making it impossible to obtain the desired tensile strength. If the flow rate of the humidified gas is increased in order to suppress the variation of the furnace pressure, the amount of moisture supplied into the soakingzone 12 tends to become excessive, as a result of which roll pick-up occurs. Such roll pick-up causes flaws on the steel strip surface, and degrades the coating appearance. - It is therefore important in this embodiment that, while the width and sheet passing speed of the steel strip passing through the soaking
zone 12 are constant (hereafter also referred to as "under the same operation condition"), the variation of the pressure in the annealing furnace is suppressed by adjusting the flow rate of the dry gas, and the amount of moisture supplied into the soakingzone 12 by the humidified gas is kept as constant as possible, specifically, the variation range of the amount of moisture is limited to 20 % or less. This contributes to favorable coating appearance. Moreover, in the operation that also involves alloying treatment, a decrease in tensile strength can be prevented by decreasing the alloying temperature. Here, "the variation range of the amount of moisture" supplied into the soaking zone is defined as (Mmax - Mmin)/Mmax, where Mmax is a maximum amount of moisture under the same operation condition and Mmin is a minimum amount of moisture under the same operation condition. The amount of moisture can be calculated according to the below-mentioned Formula (2). - How the variation range of the amount of moisture is limited to 20 % or less is not limited. As an example, the dew point of the humidified gas is kept constant to control the variation range of its flow rate to 20 % or less. In the case where a plurality of humidified gas supply ports are provided as in this embodiment, it is preferable to keep both the flow rate of the humidified gas from each supply port and the total flow rate of the humidified gas as constant as possible (e.g. 20 % or less).
- The amount of moisture M (g/min) introduced into the soaking
zone 12 by the humidified gas needs to be adjusted depending on the volume of the soaking zone and the width and sheet passing speed of the steel strip P passing through the soakingzone 12. As a result of keen examination, we discovered that setting the flow rate and dew point of the humidified gas so that the amount of moisture M (g/min) supplied into the soakingzone 12 by the humidified gas satisfies the following Formula (1) is effective in obtaining favorable coating appearance:zone 12, W is the width (m) of the steel strip P passing through the soakingzone 12, and S is the sheet passing speed (m/s) of the steel strip P. - When at least one of the width W and sheet passing speed S of the steel strip P passing through the soaking
zone 12 varies, it is effective to change the flow rate and dew point of the humidified gas so that the amount of moisture M (g/min) satisfies Formula (1). - The volume Vf of the soaking
zone 12 is substantially a constant. In the case where the width W and sheet passing speed S of the steel strip P passing through the soakingzone 12 increase or in the case where one of the width W and the sheet passing speed S is constant and the other one of the width W and the sheet passing speed S increases, the area of the steel strip in contact with the gas in the soakingzone 12 per unit time increases. Accordingly, the amount of moisture by the humidified gas is increased based on Formula (1). In the case where the width W and sheet passing speed S of the steel strip P passing through the soakingzone 12 decrease or in the case where one of the width W and the sheet passing speed S is constant and the other one of the width W and the sheet passing speed S decreases, on the other hand, the amount of moisture by the humidified gas needs to be decreased based on Formula (1). In the case where one of the width W and the sheet passing speed S increases and the other one of the width W and the sheet passing speed S decreases, too, the amount of moisture by the humidified gas is adjusted based on Formula (1). In any case, it is desirable to adjust the flow rate and dew point of the humidified gas so as to satisfy Formula (1), before the dew point in the soakingzone 12 changes as a result of a change in the operation condition. -
- The flow rate Vm of the humidified gas supplied into the soaking
zone 12 is not limited as long as the aforementioned control is performed, but is generally maintained in the range of 100 to 400 (Nm3/hr). The flow rate of the dry gas supplied into the soakingzone 12 is not limited, but is generally maintained in the range of 10 to 300 (Nm3/hr). - Water vapor has a lower specific gravity than nitrogen gas, and so tends to accumulate in the upper part in the soaking
zone 12. Hence, a dewpoint measurement port 50 is located in a region of upper 1/2 of the soakingzone 12 in the height direction. The vicinity of each humidified gas supply port is a region where the dew point is locally high, and therefore is not suitable for dew point measurement. Accordingly, the dewpoint measurement port 50 is preferably located 1 m or more away from the position of each humidified gas supply port and 1 m or more away from the inner wall position of the soaking zone facing each of the supply ports. It is also preferable to control the flow rate of the humidified gas so that the dew point in the soakingzone 12 measured at the dewpoint measurement port 50 is maintained at -25 °C or more and 0 °C or less. This contributes to favorable coating appearance. Moreover, in the operation that also involves alloying treatment, a decrease in tensile strength can be prevented by decreasing the alloying temperature. - In this embodiment, the
cooling zones first cooling zone 14, and cooled to about 470 °C to 500 °C in thesecond cooling zone 16. - The
cooling zones cooling zones cooling zones - The hot-
dip galvanizing bath 22 can be used to apply a hot-dip galvanized coating onto the steel strip P discharged from thesecond cooling zone 16. The hot-dip galvanizing may be performed according to a usual method. - The alloying
line 23 can be used to heat-alloy the galvanized coating applied on the steel strip P. The alloying treatment may be performed according to a usual method. In this embodiment, the alloying temperature is kept from being high, thus preventing a decrease in tensile strength of the produced galvannealed steel sheet. Note that the alloyingline 23 and the alloying treatment by the alloyingline 23 are not essential in the present disclosure. The effect of obtaining favorable coating appearance can be achieved even in the case of not performing alloying treatment. - The steel strip P subjected to annealing and hot-dip galvanizing is not limited, but the advantageous effects according to the present disclosure can be effectively achieved in the case where the steel strip has a chemical composition containing 0.2 mass% or more Si, i.e. in the case of high tensile strength steel.
- The continuous hot-dip galvanizing apparatus illustrated in
FIGS. 1 and2 was used to anneal each steel strip whose chemical composition is listed in Table 1 under each annealing condition listed in Table 2, and then hot-dip galvanize and alloy the steel strip. Steel sample ID A and steel sample ID B are both high tensile strength steels. In Table 2, "time" denotes the time elapsed from the operation start, where the type, sheet thickness, and sheet width of the passing steel strip and the operation condition of the continuous hot-dip galvanizing apparatus were changed with the passage of time as listed in Table 2. - A DFF was used as the second heating zone. The heating burners were divided into four groups (#1 to #4) where the three groups (#1 to #3) upstream in the steel sheet traveling direction were made up of oxidizing burners and the last group (#4) was made up of reducing burners, and the air ratios of the oxidizing burners and reducing burners were set to the values listed in Table 2. The length of each group in the steel sheet traveling direction was 4 m.
- A RT furnace having a volume Vr of 700 m3 was used as the soaking zone. The average temperature Tr in the soaking zone was set to the value listed in Table 2. As dry gas, gas (dew point: -50 °C) having a composition containing 15 vol% H2 with the balance being N2 and incidental impurities was used. Part of the dry gas was humidified by a humidifying device having 10 hollow fiber membrane-type humidifying modules, to prepare humidified gas. Dry gas of 500 L/min at the maximum and circulating water of 20 L/min at the maximum were flown in each module. A common circulating constant-temperature water bath capable of supplying pure water of 200 L/min in total was used for each module. The dry gas supply ports and the humidified gas supply ports were arranged at the positions illustrated in
FIG. 2 . - Eight types of steel strips different from each other in any of steel sample ID, sheet thickness, and sheet width were passed as listed in Table 2. The first half (time 0:00 to 0:55) corresponds to Comparative Examples, and the latter half (time 0:55 to 1:50) corresponds to Examples. In detail, in the sheet passing in the first half, the flow rate of the dry gas supplied into the soaking zone, the flow rate of the humidified gas supplied into the soaking zone, and the flow rate of the dry gas supplied into the cooling zone were varied as listed in Table 2, to keep the furnace pressure constant. In the sheet passing in the latter half, while the type, width, and sheet passing speed of the steel strip passing through the soaking zone were constant, the dew point of the humidified gas was kept constant and the variation range of the flow rate of the humidified gas was limited to 20 % or less, as listed in Table 2. The furnace pressure was kept constant by adjusting the flow rate of the dry gas supplied into the soaking zone and the cooling zone.
- In Table 2, the field "dew point" of the soaking zone indicates the dew point in the soaking zone measured at the position of the dew
point measurement port 50 inFIG. 2 . The field "dew point of vicinity of humidified gas supply port" indicates the dew point in the soaking zone measured at a position of 80 cm away from the humidified gas supply port 40B inFIG. 2 . The field "dew point of humidified gas" indicates the dew point measured by the humidified gasdew point meter 40 inFIG. 2 . - The dry gas (dew point: -50 °C) was supplied into the first and second cooling zones from their lowermost parts with the flow rate listed in Table 2.
- The temperature of the molten bath was set to 460 °C, the A1 concentration in the molten bath was set to 0.130 %, and the coating weight was adjusted to 50 g/m2 per surface by gas wiping. The line speed was set to 1.0 m/s to 2.0 m/s, with the change of the sheet thickness. After the hot-dip galvanizing, alloying treatment was performed in an induction heating-type alloying furnace so that the coating alloying degree (Fe content) was 10 % to 13 %. The alloying temperature in the treatment is listed in Table 2.
- The evaluation of the coating appearance was conducted through inspection by an optical surface defect meter (detection of non-coating defects or roll pick-up flaws of ϕ0.5 or more) and visual determination of alloying unevenness. Samples that passed in all criteria were rated as "Good", samples that had a low degree of alloying unevenness were rated as "Fair", and samples that failed in at least one of the criteria were rated as "Poor". The results are listed in Table 2.
- In addition, the tensile strength of a galvannealed steel sheet produced under each condition was measured. Steel sample ID A of high tensile strength steel was rated as "pass" when the tensile strength was 590 MPa or more, and steel sample ID B of high tensile strength steel was rated as "pass" when the tensile strength was 980 MPa or more. The results are listed in Table 2.
- In Comparative Examples, in the case where the dew point in the soaking zone was less than -25 °C, the coating appearance degraded due to partial non-coating, and also the tensile strength was rated as "fail" with an increase in alloying temperature. In the case where the dew point in the soaking zone was more than 0 °C, roll pick-up occurred, and caused flaws on the steel strip surface, resulting in degraded coating appearance. In time periods of 0:20, 0:35, and 0:45, the amount of moisture satisfied Formula (1), but the variation of the amount of moisture from the preceding or succeeding time period was significant and the dew point was outside the range of -25 °C to 0 °C, so that a low degree of alloying unevenness was seen.
- In Examples, a predetermined amount of moisture was able to be stably supplied even when the total gas flow rate in the soaking zone changed, so that the surface appearance was favorable throughout the length and width of the coil, and desired tensile characteristics were obtained. In time periods of 1:20 to 2:00 in which the variation of the amount of moisture was limited to 20 % or less, Formula (1) was satisfied, and the dew point was controlled to -25 °C to 0 °C, especially high tensile strength and surface appearance were obtained stably.
Table 1 (mass%) Steel ID C Si Mn P S A 0.08 0.25 1.5 0.03 0.001 B 0.11 1.5 2.7 0.01 0.001 - With the disclosed method of producing a hot-dip galvanized steel sheet, favorable coating appearance with high coating adhesion can be obtained even in the case of hot-dip galvanizing a steel strip whose Si content is 0.2 mass% or more. Moreover, when further performing alloying treatment, the alloying temperature can be kept from becoming high, thus preventing a decrease in tensile strength of the produced galvannealed steel sheet.
-
- 100 continuous hot-dip galvanizing apparatus
- 10 heating zone
- 10A first heating zone (upstream)
- 10B second heating zone (downstream, direct fired furnace)
- 12 soaking zone
- 14 first cooling zone (rapid cooling zone)
- 16 second cooling zone (slow cooling zone)
- 18 snout
- 20 annealing furnace
- 22 hot-dip galvanizing bath
- 23 alloying line
- 24 dry gas distribution device
- 26 humidifying device
- 28 circulating constant-temperature water bath
- 30 humidified gas distribution device
- 32 dry gas pipe
- 34, 36 humidified gas pipe
- 38 humidified gas flowmeter
- 40 humidified gas dew point meter
- 42A, 42B, 42C humidified gas supply port
- 44A, 44B, 44C humidified gas supply port
- 46A, 46B, 46C humidified gas supply port
- 48A, 48B, 48C, 48D dry gas supply port
- 50 dew point measurement port
- 52A upper hearth roll
- 52B lower hearth roll
- P steel strip
Claims (5)
- A method of producing a hot-dip galvanized steel sheet using a continuous hot-dip galvanizing apparatus that includes: an annealing furnace in which a heating zone, a soaking zone, and a cooling zone are arranged in the stated order; and a hot-dip galvanizing line adjacent to the cooling zone, the method comprising:annealing a steel strip by conveying the steel strip through the heating zone, the soaking zone, and the cooling zone in the stated order inside the annealing furnace; andapplying a hot-dip galvanized coating onto the steel strip discharged from the cooling zone, using the hot-dip galvanizing line,wherein reducing gas or non-oxidizing gas is supplied into the soaking zone, the reducing gas or the non-oxidizing gas including: humidified gas humidified by a humidifying device; and dry gas not humidified by the humidifying device, andwhile a width and a sheet passing speed of the steel strip passing through the soaking zone are constant, a variation of pressure in the annealing furnace is suppressed by adjusting a flow rate of the dry gas, and a variation range of an amount of moisture supplied into the soaking zone by the humidified gas is limited to 20 % or less.
- The method of producing a hot-dip galvanized steel sheet according to claim 1,
wherein a flow rate and a dew point of the humidified gas are set so that an amount of moisture M supplied into the soaking zone by the humidified gas and expressed in g/min satisfies the following Formula (1): - The method of producing a hot-dip galvanized steel sheet according to claim 2,
wherein when at least one of the width and the sheet passing speed of the steel strip passing through the soaking zone varies, the flow rate and the dew point of the humidified gas are changed so that the amount of moisture M expressed in g/min satisfies the Formula (1). - The method of producing a hot-dip galvanized steel sheet according to any one of claims 1 to 3,
wherein a dew point in the soaking zone measured at a dew point measurement port provided in the soaking zone is controlled to -25 °C or more and 0 °C or less, the dew point measurement port being provided in a region of upper 1/2 of the soaking zone in a height direction, and located 1 m or more away from a position of a supply port of the humidified gas provided in the soaking zone and 1 m or more away from an inner wall position of the soaking zone facing the supply port. - The method of producing a hot-dip galvanized steel sheet according to any one of claims 1 to 4,
wherein the heating zone includes a direct fired furnace,
the continuous hot-dip galvanizing apparatus includes an alloying line adjacent to the hot-dip galvanizing line, and
the method further comprises
heat-alloying the galvanized coating applied on the steel strip, using the alloying line.
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JP2015211121A JP6439654B2 (en) | 2015-10-27 | 2015-10-27 | Method for producing hot-dip galvanized steel sheet |
PCT/JP2016/003631 WO2017072989A1 (en) | 2015-10-27 | 2016-08-05 | Method for manufacturing hot-dip galvanized steel sheet |
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EP (1) | EP3369836B1 (en) |
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WO2023286501A1 (en) * | 2021-07-14 | 2023-01-19 | Jfeスチール株式会社 | Method for producing hot-dip galvanized steel sheet |
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JPS61217531A (en) * | 1985-03-22 | 1986-09-27 | Kawasaki Steel Corp | Cooling method for steel strip |
JPH089737B2 (en) * | 1989-05-24 | 1996-01-31 | 日本鋼管株式会社 | Direct-fire type hard-type continuous annealing furnace and its operating method |
KR101011897B1 (en) * | 2005-10-14 | 2011-02-01 | 신닛뽄세이테쯔 카부시키카이샤 | Method of continous annealing/hot-dipping of steel sheet containing silicon and apparatus for continuous annealing/hot-dipping |
JP5338087B2 (en) * | 2008-03-03 | 2013-11-13 | Jfeスチール株式会社 | Method for producing hot-dip galvanized steel sheet with excellent plating properties and continuous hot-dip galvanizing equipment |
JP5720084B2 (en) | 2009-03-06 | 2015-05-20 | Jfeスチール株式会社 | Continuous hot dip galvanizing apparatus and method for producing hot dip galvanized steel sheet |
CN102453792B (en) * | 2010-10-26 | 2013-07-17 | 宝山钢铁股份有限公司 | Method and equipment for controlling furnace pressure of continuous annealing furnace |
DE102011051731B4 (en) * | 2011-07-11 | 2013-01-24 | Thyssenkrupp Steel Europe Ag | Process for the preparation of a flat steel product provided by hot dip coating with a metallic protective layer |
JP5505461B2 (en) * | 2012-05-24 | 2014-05-28 | Jfeスチール株式会社 | Continuous annealing furnace for steel strip, continuous annealing method for steel strip, continuous hot dip galvanizing equipment and method for manufacturing hot dip galvanized steel strip |
EP3112493B1 (en) * | 2014-02-25 | 2022-12-14 | JFE Steel Corporation | Method for controlling dew point of reduction furnace, and reduction furnace |
JP6020605B2 (en) * | 2015-01-08 | 2016-11-02 | Jfeスチール株式会社 | Method for producing galvannealed steel sheet |
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KR102072560B1 (en) | 2020-02-03 |
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JP2017082278A (en) | 2017-05-18 |
CN108138297A (en) | 2018-06-08 |
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JP6439654B2 (en) | 2018-12-19 |
EP3369836B1 (en) | 2019-10-09 |
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