EP3310890B1 - Stable bleaching composition - Google Patents
Stable bleaching composition Download PDFInfo
- Publication number
- EP3310890B1 EP3310890B1 EP15731726.4A EP15731726A EP3310890B1 EP 3310890 B1 EP3310890 B1 EP 3310890B1 EP 15731726 A EP15731726 A EP 15731726A EP 3310890 B1 EP3310890 B1 EP 3310890B1
- Authority
- EP
- European Patent Office
- Prior art keywords
- hypohalite
- composition
- alkyl
- weight
- bleaching composition
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- 239000000203 mixture Substances 0.000 title claims description 228
- 238000004061 bleaching Methods 0.000 title claims description 73
- -1 alkali metal salts Chemical class 0.000 claims description 55
- 125000000217 alkyl group Chemical group 0.000 claims description 44
- 239000004744 fabric Substances 0.000 claims description 44
- 239000000049 pigment Substances 0.000 claims description 44
- 239000007844 bleaching agent Substances 0.000 claims description 31
- 239000004094 surface-active agent Substances 0.000 claims description 28
- 239000007788 liquid Substances 0.000 claims description 27
- 238000000034 method Methods 0.000 claims description 23
- 229910052783 alkali metal Inorganic materials 0.000 claims description 21
- 229910019142 PO4 Inorganic materials 0.000 claims description 20
- 235000021317 phosphate Nutrition 0.000 claims description 20
- 239000003381 stabilizer Substances 0.000 claims description 15
- 230000003139 buffering effect Effects 0.000 claims description 11
- 239000003945 anionic surfactant Substances 0.000 claims description 10
- 150000001412 amines Chemical class 0.000 claims description 9
- 150000001768 cations Chemical class 0.000 claims description 7
- 230000003287 optical effect Effects 0.000 claims description 7
- 239000003093 cationic surfactant Substances 0.000 claims description 6
- 125000001301 ethoxy group Chemical group [H]C([H])([H])C([H])([H])O* 0.000 claims description 6
- QCDWFXQBSFUVSP-UHFFFAOYSA-N 2-phenoxyethanol Chemical compound OCCOC1=CC=CC=C1 QCDWFXQBSFUVSP-UHFFFAOYSA-N 0.000 claims description 5
- RBTKNAXYKSUFRK-UHFFFAOYSA-N heliogen blue Chemical group [Cu].[N-]1C2=C(C=CC=C3)C3=C1N=C([N-]1)C3=CC=CC=C3C1=NC([N-]1)=C(C=CC=C3)C3=C1N=C([N-]1)C3=CC=CC=C3C1=N2 RBTKNAXYKSUFRK-UHFFFAOYSA-N 0.000 claims description 5
- 229960005323 phenoxyethanol Drugs 0.000 claims description 5
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 4
- 239000002736 nonionic surfactant Substances 0.000 claims description 4
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims description 4
- 230000000087 stabilizing effect Effects 0.000 claims description 4
- 239000002888 zwitterionic surfactant Substances 0.000 claims description 4
- 229910006146 SO3M1 Inorganic materials 0.000 claims description 3
- 150000003013 phosphoric acid derivatives Chemical class 0.000 claims description 3
- 125000002572 propoxy group Chemical group [*]OC([H])([H])C(C([H])([H])[H])([H])[H] 0.000 claims description 3
- 150000003856 quaternary ammonium compounds Chemical group 0.000 claims description 3
- 150000003467 sulfuric acid derivatives Chemical class 0.000 claims description 3
- 150000001638 boron Chemical class 0.000 claims description 2
- 150000004649 carbonic acid derivatives Chemical class 0.000 claims description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 2
- 239000004417 polycarbonate Chemical class 0.000 claims description 2
- 229920000515 polycarbonate Chemical class 0.000 claims description 2
- 150000004760 silicates Chemical class 0.000 claims description 2
- 125000005402 stannate group Chemical class 0.000 claims description 2
- 239000004698 Polyethylene Substances 0.000 description 26
- 239000004615 ingredient Substances 0.000 description 23
- 239000011734 sodium Substances 0.000 description 20
- 239000002738 chelating agent Substances 0.000 description 19
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 18
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 18
- 239000010452 phosphate Substances 0.000 description 17
- 229910052708 sodium Inorganic materials 0.000 description 17
- WQYVRQLZKVEZGA-UHFFFAOYSA-N hypochlorite Chemical compound Cl[O-] WQYVRQLZKVEZGA-UHFFFAOYSA-N 0.000 description 16
- 150000001875 compounds Chemical class 0.000 description 14
- HZNQSWJZTWOTKM-UHFFFAOYSA-N 2,3,4-trimethoxybenzoic acid Chemical compound COC1=CC=C(C(O)=O)C(OC)=C1OC HZNQSWJZTWOTKM-UHFFFAOYSA-N 0.000 description 13
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 13
- 239000003599 detergent Substances 0.000 description 12
- 239000007800 oxidant agent Substances 0.000 description 12
- 230000006641 stabilisation Effects 0.000 description 12
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 11
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 11
- 239000002253 acid Substances 0.000 description 11
- 239000000975 dye Substances 0.000 description 11
- 239000011591 potassium Substances 0.000 description 11
- 229910052700 potassium Inorganic materials 0.000 description 11
- 239000000047 product Substances 0.000 description 11
- 238000011105 stabilization Methods 0.000 description 11
- 150000003839 salts Chemical class 0.000 description 10
- IMQLKJBTEOYOSI-GPIVLXJGSA-N Inositol-hexakisphosphate Chemical compound OP(O)(=O)O[C@H]1[C@H](OP(O)(O)=O)[C@@H](OP(O)(O)=O)[C@H](OP(O)(O)=O)[C@H](OP(O)(O)=O)[C@@H]1OP(O)(O)=O IMQLKJBTEOYOSI-GPIVLXJGSA-N 0.000 description 9
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 9
- IMQLKJBTEOYOSI-UHFFFAOYSA-N Phytic acid Natural products OP(O)(=O)OC1C(OP(O)(O)=O)C(OP(O)(O)=O)C(OP(O)(O)=O)C(OP(O)(O)=O)C1OP(O)(O)=O IMQLKJBTEOYOSI-UHFFFAOYSA-N 0.000 description 9
- 239000000467 phytic acid Substances 0.000 description 9
- 235000002949 phytic acid Nutrition 0.000 description 9
- 229940068041 phytic acid Drugs 0.000 description 9
- 235000019832 sodium triphosphate Nutrition 0.000 description 9
- 239000007789 gas Substances 0.000 description 8
- 229910052751 metal Inorganic materials 0.000 description 8
- 239000002184 metal Substances 0.000 description 8
- 238000005406 washing Methods 0.000 description 8
- 150000007513 acids Chemical class 0.000 description 7
- 239000003795 chemical substances by application Substances 0.000 description 7
- 238000000354 decomposition reaction Methods 0.000 description 7
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 6
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 6
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 6
- ZMANZCXQSJIPKH-UHFFFAOYSA-N Triethylamine Chemical compound CCN(CC)CC ZMANZCXQSJIPKH-UHFFFAOYSA-N 0.000 description 6
- 150000001340 alkali metals Chemical class 0.000 description 6
- 239000010949 copper Substances 0.000 description 6
- 229910052802 copper Inorganic materials 0.000 description 6
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 6
- 238000003860 storage Methods 0.000 description 6
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 5
- 230000032683 aging Effects 0.000 description 5
- 150000007942 carboxylates Chemical class 0.000 description 5
- 239000000243 solution Substances 0.000 description 5
- 229910021653 sulphate ion Inorganic materials 0.000 description 5
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 4
- CPELXLSAUQHCOX-UHFFFAOYSA-M Bromide Chemical compound [Br-] CPELXLSAUQHCOX-UHFFFAOYSA-M 0.000 description 4
- QUSNBJAOOMFDIB-UHFFFAOYSA-N Ethylamine Chemical compound CCN QUSNBJAOOMFDIB-UHFFFAOYSA-N 0.000 description 4
- 239000004115 Sodium Silicate Substances 0.000 description 4
- 230000008901 benefit Effects 0.000 description 4
- 238000004140 cleaning Methods 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- 150000004820 halides Chemical class 0.000 description 4
- UEZVMMHDMIWARA-UHFFFAOYSA-M phosphonate Chemical compound [O-]P(=O)=O UEZVMMHDMIWARA-UHFFFAOYSA-M 0.000 description 4
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 4
- 229910052911 sodium silicate Inorganic materials 0.000 description 4
- 238000010186 staining Methods 0.000 description 4
- VKFFEYLSKIYTSJ-UHFFFAOYSA-N tetraazanium;phosphonato phosphate Chemical compound [NH4+].[NH4+].[NH4+].[NH4+].[O-]P([O-])(=O)OP([O-])([O-])=O VKFFEYLSKIYTSJ-UHFFFAOYSA-N 0.000 description 4
- BCMCBBGGLRIHSE-UHFFFAOYSA-N 1,3-benzoxazole Chemical compound C1=CC=C2OC=NC2=C1 BCMCBBGGLRIHSE-UHFFFAOYSA-N 0.000 description 3
- YGUMVDWOQQJBGA-VAWYXSNFSA-N 5-[(4-anilino-6-morpholin-4-yl-1,3,5-triazin-2-yl)amino]-2-[(e)-2-[4-[(4-anilino-6-morpholin-4-yl-1,3,5-triazin-2-yl)amino]-2-sulfophenyl]ethenyl]benzenesulfonic acid Chemical compound C=1C=C(\C=C\C=2C(=CC(NC=3N=C(N=C(NC=4C=CC=CC=4)N=3)N3CCOCC3)=CC=2)S(O)(=O)=O)C(S(=O)(=O)O)=CC=1NC(N=C(N=1)N2CCOCC2)=NC=1NC1=CC=CC=C1 YGUMVDWOQQJBGA-VAWYXSNFSA-N 0.000 description 3
- PIICEJLVQHRZGT-UHFFFAOYSA-N Ethylenediamine Chemical compound NCCN PIICEJLVQHRZGT-UHFFFAOYSA-N 0.000 description 3
- WMFOQBRAJBCJND-UHFFFAOYSA-M Lithium hydroxide Chemical compound [Li+].[OH-] WMFOQBRAJBCJND-UHFFFAOYSA-M 0.000 description 3
- 241000530268 Lycaena heteronea Species 0.000 description 3
- 101710194948 Protein phosphatase PhpP Proteins 0.000 description 3
- 230000002378 acidificating effect Effects 0.000 description 3
- 229910052784 alkaline earth metal Inorganic materials 0.000 description 3
- 125000003342 alkenyl group Chemical group 0.000 description 3
- 150000001450 anions Chemical class 0.000 description 3
- 125000003118 aryl group Chemical group 0.000 description 3
- 125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 description 3
- 239000006227 byproduct Substances 0.000 description 3
- 125000004432 carbon atom Chemical group C* 0.000 description 3
- 230000015556 catabolic process Effects 0.000 description 3
- 238000006731 degradation reaction Methods 0.000 description 3
- 238000010790 dilution Methods 0.000 description 3
- 239000012895 dilution Substances 0.000 description 3
- 125000000118 dimethyl group Chemical group [H]C([H])([H])* 0.000 description 3
- 239000006081 fluorescent whitening agent Substances 0.000 description 3
- 238000009472 formulation Methods 0.000 description 3
- 229910052742 iron Inorganic materials 0.000 description 3
- 150000002739 metals Chemical class 0.000 description 3
- 229910052757 nitrogen Inorganic materials 0.000 description 3
- HWGNBUXHKFFFIH-UHFFFAOYSA-I pentasodium;[oxido(phosphonatooxy)phosphoryl] phosphate Chemical compound [Na+].[Na+].[Na+].[Na+].[Na+].[O-]P([O-])(=O)OP([O-])(=O)OP([O-])([O-])=O HWGNBUXHKFFFIH-UHFFFAOYSA-I 0.000 description 3
- 239000002689 soil Substances 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- UNXRWKVEANCORM-UHFFFAOYSA-I triphosphate(5-) Chemical compound [O-]P([O-])(=O)OP([O-])(=O)OP([O-])([O-])=O UNXRWKVEANCORM-UHFFFAOYSA-I 0.000 description 3
- 125000004178 (C1-C4) alkyl group Chemical group 0.000 description 2
- MPNXSZJPSVBLHP-UHFFFAOYSA-N 2-chloro-n-phenylpyridine-3-carboxamide Chemical compound ClC1=NC=CC=C1C(=O)NC1=CC=CC=C1 MPNXSZJPSVBLHP-UHFFFAOYSA-N 0.000 description 2
- 125000000954 2-hydroxyethyl group Chemical group [H]C([*])([H])C([H])([H])O[H] 0.000 description 2
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonia chloride Chemical compound [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 description 2
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical class [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 2
- QDHHCQZDFGDHMP-UHFFFAOYSA-N Chloramine Chemical class ClN QDHHCQZDFGDHMP-UHFFFAOYSA-N 0.000 description 2
- 244000060011 Cocos nucifera Species 0.000 description 2
- 235000013162 Cocos nucifera Nutrition 0.000 description 2
- DBVJJBKOTRCVKF-UHFFFAOYSA-N Etidronic acid Chemical compound OP(=O)(O)C(O)(C)P(O)(O)=O DBVJJBKOTRCVKF-UHFFFAOYSA-N 0.000 description 2
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 2
- XYFCBTPGUUZFHI-UHFFFAOYSA-N Phosphine Chemical compound P XYFCBTPGUUZFHI-UHFFFAOYSA-N 0.000 description 2
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 2
- 239000005708 Sodium hypochlorite Substances 0.000 description 2
- 238000002835 absorbance Methods 0.000 description 2
- 230000001133 acceleration Effects 0.000 description 2
- 239000003513 alkali Substances 0.000 description 2
- 229910000272 alkali metal oxide Inorganic materials 0.000 description 2
- 150000003863 ammonium salts Chemical class 0.000 description 2
- 125000000129 anionic group Chemical group 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 125000002091 cationic group Chemical group 0.000 description 2
- 239000003518 caustics Substances 0.000 description 2
- NEHMKBQYUWJMIP-UHFFFAOYSA-N chloromethane Chemical compound ClC NEHMKBQYUWJMIP-UHFFFAOYSA-N 0.000 description 2
- XCJYREBRNVKWGJ-UHFFFAOYSA-N copper(II) phthalocyanine Chemical compound [Cu+2].C12=CC=CC=C2C(N=C2[N-]C(C3=CC=CC=C32)=N2)=NC1=NC([C]1C=CC=CC1=1)=NC=1N=C1[C]3C=CC=CC3=C2[N-]1 XCJYREBRNVKWGJ-UHFFFAOYSA-N 0.000 description 2
- ZRKZFNZPJKEWPC-UHFFFAOYSA-N decylamine-N,N-dimethyl-N-oxide Chemical compound CCCCCCCCCC[N+](C)(C)[O-] ZRKZFNZPJKEWPC-UHFFFAOYSA-N 0.000 description 2
- 230000000249 desinfective effect Effects 0.000 description 2
- HPNMFZURTQLUMO-UHFFFAOYSA-N diethylamine Chemical compound CCNCC HPNMFZURTQLUMO-UHFFFAOYSA-N 0.000 description 2
- XPPKVPWEQAFLFU-UHFFFAOYSA-J diphosphate(4-) Chemical compound [O-]P([O-])(=O)OP([O-])([O-])=O XPPKVPWEQAFLFU-UHFFFAOYSA-J 0.000 description 2
- 235000011180 diphosphates Nutrition 0.000 description 2
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 2
- 230000002209 hydrophobic effect Effects 0.000 description 2
- 150000002500 ions Chemical class 0.000 description 2
- 229910052744 lithium Inorganic materials 0.000 description 2
- 230000003647 oxidation Effects 0.000 description 2
- 238000007254 oxidation reaction Methods 0.000 description 2
- 229940048084 pyrophosphate Drugs 0.000 description 2
- 239000002516 radical scavenger Substances 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- SUKJFIGYRHOWBL-UHFFFAOYSA-N sodium hypochlorite Chemical compound [Na+].Cl[O-] SUKJFIGYRHOWBL-UHFFFAOYSA-N 0.000 description 2
- 230000002195 synergetic effect Effects 0.000 description 2
- QEMXHQIAXOOASZ-UHFFFAOYSA-N tetramethylammonium Chemical compound C[N+](C)(C)C QEMXHQIAXOOASZ-UHFFFAOYSA-N 0.000 description 2
- LWIHDJKSTIGBAC-UHFFFAOYSA-K tripotassium phosphate Chemical compound [K+].[K+].[K+].[O-]P([O-])([O-])=O LWIHDJKSTIGBAC-UHFFFAOYSA-K 0.000 description 2
- 230000002087 whitening effect Effects 0.000 description 2
- BHMLFPOTZYRDKA-IRXDYDNUSA-N (2s)-2-[(s)-(2-iodophenoxy)-phenylmethyl]morpholine Chemical compound IC1=CC=CC=C1O[C@@H](C=1C=CC=CC=1)[C@H]1OCCNC1 BHMLFPOTZYRDKA-IRXDYDNUSA-N 0.000 description 1
- 125000000008 (C1-C10) alkyl group Chemical group 0.000 description 1
- 125000006273 (C1-C3) alkyl group Chemical group 0.000 description 1
- 125000006527 (C1-C5) alkyl group Chemical group 0.000 description 1
- QLAJNZSPVITUCQ-UHFFFAOYSA-N 1,3,2-dioxathietane 2,2-dioxide Chemical compound O=S1(=O)OCO1 QLAJNZSPVITUCQ-UHFFFAOYSA-N 0.000 description 1
- 125000000355 1,3-benzoxazolyl group Chemical group O1C(=NC2=C1C=CC=C2)* 0.000 description 1
- HYZJCKYKOHLVJF-UHFFFAOYSA-N 1H-benzimidazole Chemical compound C1=CC=C2NC=NC2=C1 HYZJCKYKOHLVJF-UHFFFAOYSA-N 0.000 description 1
- VKZRWSNIWNFCIQ-UHFFFAOYSA-N 2-[2-(1,2-dicarboxyethylamino)ethylamino]butanedioic acid Chemical compound OC(=O)CC(C(O)=O)NCCNC(C(O)=O)CC(O)=O VKZRWSNIWNFCIQ-UHFFFAOYSA-N 0.000 description 1
- HECHAOUMONWDAO-UHFFFAOYSA-N 2-[4-[2-[4-(triazol-2-yl)phenyl]ethenyl]phenyl]triazole Chemical class C=1C=C(N2N=CC=N2)C=CC=1C=CC(C=C1)=CC=C1N1N=CC=N1 HECHAOUMONWDAO-UHFFFAOYSA-N 0.000 description 1
- PADNTDFLHBNUCL-UHFFFAOYSA-N 2-[4-[4-(3-sulfo-1-benzofuran-2-yl)phenyl]phenyl]-1-benzofuran-3-sulfonic acid Chemical group O1C2=CC=CC=C2C(S(O)(=O)=O)=C1C(C=C1)=CC=C1C(C=C1)=CC=C1C1=C(S(=O)(=O)O)C2=CC=CC=C2O1 PADNTDFLHBNUCL-UHFFFAOYSA-N 0.000 description 1
- CJAZCKUGLFWINJ-UHFFFAOYSA-N 3,4-dihydroxybenzene-1,2-disulfonic acid Chemical class OC1=CC=C(S(O)(=O)=O)C(S(O)(=O)=O)=C1O CJAZCKUGLFWINJ-UHFFFAOYSA-N 0.000 description 1
- QWZHDKGQKYEBKK-UHFFFAOYSA-N 3-aminochromen-2-one Chemical class C1=CC=C2OC(=O)C(N)=CC2=C1 QWZHDKGQKYEBKK-UHFFFAOYSA-N 0.000 description 1
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 1
- KWIUHFFTVRNATP-UHFFFAOYSA-N Betaine Natural products C[N+](C)(C)CC([O-])=O KWIUHFFTVRNATP-UHFFFAOYSA-N 0.000 description 1
- LSNNMFCWUKXFEE-UHFFFAOYSA-M Bisulfite Chemical compound OS([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-M 0.000 description 1
- BTBUEUYNUDRHOZ-UHFFFAOYSA-N Borate Chemical class [O-]B([O-])[O-] BTBUEUYNUDRHOZ-UHFFFAOYSA-N 0.000 description 1
- UYNKVBYVIGUBMK-UHFFFAOYSA-N CC.OOP(=O)OP(O)=O Chemical compound CC.OOP(=O)OP(O)=O UYNKVBYVIGUBMK-UHFFFAOYSA-N 0.000 description 1
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- ZKQDCIXGCQPQNV-UHFFFAOYSA-N Calcium hypochlorite Chemical compound [Ca+2].Cl[O-].Cl[O-] ZKQDCIXGCQPQNV-UHFFFAOYSA-N 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 1
- XXAXVMUWHZHZMJ-UHFFFAOYSA-N Chymopapain Chemical compound OC1=CC(S(O)(=O)=O)=CC(S(O)(=O)=O)=C1O XXAXVMUWHZHZMJ-UHFFFAOYSA-N 0.000 description 1
- RPNUMPOLZDHAAY-UHFFFAOYSA-N Diethylenetriamine Chemical compound NCCNCCN RPNUMPOLZDHAAY-UHFFFAOYSA-N 0.000 description 1
- ROSDSFDQCJNGOL-UHFFFAOYSA-N Dimethylamine Chemical group CNC ROSDSFDQCJNGOL-UHFFFAOYSA-N 0.000 description 1
- MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
- KWIUHFFTVRNATP-UHFFFAOYSA-O N,N,N-trimethylglycinium Chemical compound C[N+](C)(C)CC(O)=O KWIUHFFTVRNATP-UHFFFAOYSA-O 0.000 description 1
- BCXBKOQDEOJNRH-UHFFFAOYSA-N NOP(O)=O Chemical class NOP(O)=O BCXBKOQDEOJNRH-UHFFFAOYSA-N 0.000 description 1
- RXTCWPTWYYNTOA-UHFFFAOYSA-N O=P1OCCCCCO1 Chemical compound O=P1OCCCCCO1 RXTCWPTWYYNTOA-UHFFFAOYSA-N 0.000 description 1
- 239000004435 Oxo alcohol Substances 0.000 description 1
- ABLZXFCXXLZCGV-UHFFFAOYSA-N Phosphorous acid Chemical class OP(O)=O ABLZXFCXXLZCGV-UHFFFAOYSA-N 0.000 description 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
- 229920002257 Plurafac® Polymers 0.000 description 1
- 240000008042 Zea mays Species 0.000 description 1
- 235000005824 Zea mays ssp. parviglumis Nutrition 0.000 description 1
- 235000002017 Zea mays subsp mays Nutrition 0.000 description 1
- FENRSEGZMITUEF-ATTCVCFYSA-E [Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].OP(=O)([O-])O[C@@H]1[C@@H](OP(=O)([O-])[O-])[C@H](OP(=O)(O)[O-])[C@H](OP(=O)([O-])[O-])[C@H](OP(=O)(O)[O-])[C@H]1OP(=O)([O-])[O-] Chemical compound [Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].OP(=O)([O-])O[C@@H]1[C@@H](OP(=O)([O-])[O-])[C@H](OP(=O)(O)[O-])[C@H](OP(=O)([O-])[O-])[C@H](OP(=O)(O)[O-])[C@H]1OP(=O)([O-])[O-] FENRSEGZMITUEF-ATTCVCFYSA-E 0.000 description 1
- YDONNITUKPKTIG-UHFFFAOYSA-N [Nitrilotris(methylene)]trisphosphonic acid Chemical compound OP(O)(=O)CN(CP(O)(O)=O)CP(O)(O)=O YDONNITUKPKTIG-UHFFFAOYSA-N 0.000 description 1
- LSYVCAOPFHHUHM-UHFFFAOYSA-N [hydroxy-[hydroxy-[hydroxy(phosphonooxy)phosphoryl]oxyphosphoryl]oxyphosphoryl] phosphono hydrogen phosphate Chemical compound OP(O)(=O)OP(O)(=O)OP(O)(=O)OP(O)(=O)OP(O)(=O)OP(O)(O)=O LSYVCAOPFHHUHM-UHFFFAOYSA-N 0.000 description 1
- 239000012190 activator Substances 0.000 description 1
- 125000001931 aliphatic group Chemical group 0.000 description 1
- 150000001336 alkenes Chemical class 0.000 description 1
- 125000005055 alkyl alkoxy group Chemical group 0.000 description 1
- 150000003973 alkyl amines Chemical class 0.000 description 1
- 125000002877 alkyl aryl group Chemical group 0.000 description 1
- 125000006177 alkyl benzyl group Chemical group 0.000 description 1
- 125000005211 alkyl trimethyl ammonium group Chemical group 0.000 description 1
- 125000002947 alkylene group Chemical group 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- 235000019270 ammonium chloride Nutrition 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 150000003851 azoles Chemical class 0.000 description 1
- 229910052788 barium Inorganic materials 0.000 description 1
- RFRXIWQYSOIBDI-UHFFFAOYSA-N benzarone Chemical compound CCC=1OC2=CC=CC=C2C=1C(=O)C1=CC=C(O)C=C1 RFRXIWQYSOIBDI-UHFFFAOYSA-N 0.000 description 1
- SRSXLGNVWSONIS-UHFFFAOYSA-M benzenesulfonate Chemical compound [O-]S(=O)(=O)C1=CC=CC=C1 SRSXLGNVWSONIS-UHFFFAOYSA-M 0.000 description 1
- JBIROUFYLSSYDX-UHFFFAOYSA-M benzododecinium chloride Chemical compound [Cl-].CCCCCCCCCCCC[N+](C)(C)CC1=CC=CC=C1 JBIROUFYLSSYDX-UHFFFAOYSA-M 0.000 description 1
- 229960003237 betaine Drugs 0.000 description 1
- 229910021538 borax Inorganic materials 0.000 description 1
- 238000005282 brightening Methods 0.000 description 1
- 239000011575 calcium Substances 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 229910000019 calcium carbonate Inorganic materials 0.000 description 1
- ZFXVRMSLJDYJCH-UHFFFAOYSA-N calcium magnesium Chemical compound [Mg].[Ca] ZFXVRMSLJDYJCH-UHFFFAOYSA-N 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 239000004464 cereal grain Substances 0.000 description 1
- 150000004697 chelate complex Chemical class 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000000460 chlorine Substances 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- 238000009833 condensation Methods 0.000 description 1
- 230000005494 condensation Effects 0.000 description 1
- 238000011109 contamination Methods 0.000 description 1
- 235000005822 corn Nutrition 0.000 description 1
- CDJGWBCMWHSUHR-UHFFFAOYSA-M decyl(triethyl)azanium;chloride Chemical compound [Cl-].CCCCCCCCCC[N+](CC)(CC)CC CDJGWBCMWHSUHR-UHFFFAOYSA-M 0.000 description 1
- 239000007857 degradation product Substances 0.000 description 1
- 150000004985 diamines Chemical class 0.000 description 1
- IKJFYINYNJYDTA-UHFFFAOYSA-N dibenzothiophene sulfone Chemical compound C1=CC=C2S(=O)(=O)C3=CC=CC=C3C2=C1 IKJFYINYNJYDTA-UHFFFAOYSA-N 0.000 description 1
- 229910001882 dioxygen Inorganic materials 0.000 description 1
- PMPJQLCPEQFEJW-GNTLFSRWSA-L disodium;2-[(z)-2-[4-[4-[(z)-2-(2-sulfonatophenyl)ethenyl]phenyl]phenyl]ethenyl]benzenesulfonate Chemical compound [Na+].[Na+].[O-]S(=O)(=O)C1=CC=CC=C1\C=C/C1=CC=C(C=2C=CC(\C=C/C=3C(=CC=CC=3)S([O-])(=O)=O)=CC=2)C=C1 PMPJQLCPEQFEJW-GNTLFSRWSA-L 0.000 description 1
- YJHDFAAFYNRKQE-YHPRVSEPSA-L disodium;5-[[4-anilino-6-[bis(2-hydroxyethyl)amino]-1,3,5-triazin-2-yl]amino]-2-[(e)-2-[4-[[4-anilino-6-[bis(2-hydroxyethyl)amino]-1,3,5-triazin-2-yl]amino]-2-sulfonatophenyl]ethenyl]benzenesulfonate Chemical compound [Na+].[Na+].N=1C(NC=2C=C(C(\C=C\C=3C(=CC(NC=4N=C(N=C(NC=5C=CC=CC=5)N=4)N(CCO)CCO)=CC=3)S([O-])(=O)=O)=CC=2)S([O-])(=O)=O)=NC(N(CCO)CCO)=NC=1NC1=CC=CC=C1 YJHDFAAFYNRKQE-YHPRVSEPSA-L 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- JRBPAEWTRLWTQC-UHFFFAOYSA-N dodecylamine Chemical compound CCCCCCCCCCCCN JRBPAEWTRLWTQC-UHFFFAOYSA-N 0.000 description 1
- SYELZBGXAIXKHU-UHFFFAOYSA-N dodecyldimethylamine N-oxide Chemical compound CCCCCCCCCCCC[N+](C)(C)[O-] SYELZBGXAIXKHU-UHFFFAOYSA-N 0.000 description 1
- 239000003995 emulsifying agent Substances 0.000 description 1
- 239000006260 foam Substances 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 125000000623 heterocyclic group Chemical group 0.000 description 1
- 229920001903 high density polyethylene Polymers 0.000 description 1
- 239000004700 high-density polyethylene Substances 0.000 description 1
- 125000001183 hydrocarbyl group Chemical group 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 125000001165 hydrophobic group Chemical group 0.000 description 1
- 239000003752 hydrotrope Substances 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 description 1
- CUILPNURFADTPE-UHFFFAOYSA-N hypobromous acid Chemical class BrO CUILPNURFADTPE-UHFFFAOYSA-N 0.000 description 1
- GEOVEUCEIQCBKH-UHFFFAOYSA-N hypoiodous acid Chemical class IO GEOVEUCEIQCBKH-UHFFFAOYSA-N 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 230000003993 interaction Effects 0.000 description 1
- 239000002085 irritant Substances 0.000 description 1
- 231100000021 irritant Toxicity 0.000 description 1
- 238000005304 joining Methods 0.000 description 1
- 229910052745 lead Inorganic materials 0.000 description 1
- 239000007791 liquid phase Substances 0.000 description 1
- LWXVCCOAQYNXNX-UHFFFAOYSA-N lithium hypochlorite Chemical compound [Li+].Cl[O-] LWXVCCOAQYNXNX-UHFFFAOYSA-N 0.000 description 1
- 239000011777 magnesium Substances 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- YZQBYALVHAANGI-UHFFFAOYSA-N magnesium;dihypochlorite Chemical compound [Mg+2].Cl[O-].Cl[O-] YZQBYALVHAANGI-UHFFFAOYSA-N 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 229910021645 metal ion Inorganic materials 0.000 description 1
- JZMJDSHXVKJFKW-UHFFFAOYSA-M methyl sulfate(1-) Chemical compound COS([O-])(=O)=O JZMJDSHXVKJFKW-UHFFFAOYSA-M 0.000 description 1
- VXBSKVAMQMBCCA-UHFFFAOYSA-M methyl sulfate;trimethyl(tetradecyl)azanium Chemical compound COS([O-])(=O)=O.CCCCCCCCCCCCCC[N+](C)(C)C VXBSKVAMQMBCCA-UHFFFAOYSA-M 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- PXHVJJICTQNCMI-UHFFFAOYSA-N nickel Substances [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 1
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- 238000004806 packaging method and process Methods 0.000 description 1
- 229940055076 parasympathomimetics choline ester Drugs 0.000 description 1
- 239000002304 perfume Substances 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 239000011574 phosphorus Substances 0.000 description 1
- 229910000073 phosphorus hydride Inorganic materials 0.000 description 1
- IEQIEDJGQAUEQZ-UHFFFAOYSA-N phthalocyanine Chemical group N1C(N=C2C3=CC=CC=C3C(N=C3C4=CC=CC=C4C(=N4)N3)=N2)=C(C=CC=C2)C2=C1N=C1C2=CC=CC=C2C4=N1 IEQIEDJGQAUEQZ-UHFFFAOYSA-N 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 229920000768 polyamine Polymers 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- SATVIFGJTRRDQU-UHFFFAOYSA-N potassium hypochlorite Chemical compound [K+].Cl[O-] SATVIFGJTRRDQU-UHFFFAOYSA-N 0.000 description 1
- CHWRSCGUEQEHOH-UHFFFAOYSA-N potassium oxide Chemical compound [O-2].[K+].[K+] CHWRSCGUEQEHOH-UHFFFAOYSA-N 0.000 description 1
- 229910001950 potassium oxide Inorganic materials 0.000 description 1
- 159000000001 potassium salts Chemical class 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 230000002028 premature Effects 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 238000002203 pretreatment Methods 0.000 description 1
- DNXIASIHZYFFRO-UHFFFAOYSA-N pyrazoline Chemical compound C1CN=NC1 DNXIASIHZYFFRO-UHFFFAOYSA-N 0.000 description 1
- 125000001453 quaternary ammonium group Chemical group 0.000 description 1
- 150000003248 quinolines Chemical class 0.000 description 1
- 150000003254 radicals Chemical class 0.000 description 1
- 150000003333 secondary alcohols Chemical class 0.000 description 1
- 238000002791 soaking Methods 0.000 description 1
- 229910000029 sodium carbonate Inorganic materials 0.000 description 1
- FQENQNTWSFEDLI-UHFFFAOYSA-J sodium diphosphate Chemical compound [Na+].[Na+].[Na+].[Na+].[O-]P([O-])(=O)OP([O-])([O-])=O FQENQNTWSFEDLI-UHFFFAOYSA-J 0.000 description 1
- 229940045998 sodium isethionate Drugs 0.000 description 1
- NVIFVTYDZMXWGX-UHFFFAOYSA-N sodium metaborate Chemical compound [Na+].[O-]B=O NVIFVTYDZMXWGX-UHFFFAOYSA-N 0.000 description 1
- 229910001948 sodium oxide Inorganic materials 0.000 description 1
- 229940083982 sodium phytate Drugs 0.000 description 1
- 229940048086 sodium pyrophosphate Drugs 0.000 description 1
- 235000010339 sodium tetraborate Nutrition 0.000 description 1
- LADXKQRVAFSPTR-UHFFFAOYSA-M sodium;2-hydroxyethanesulfonate Chemical compound [Na+].OCCS([O-])(=O)=O LADXKQRVAFSPTR-UHFFFAOYSA-M 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 230000003019 stabilising effect Effects 0.000 description 1
- PJANXHGTPQOBST-UHFFFAOYSA-N stilbene Chemical class C=1C=CC=CC=1C=CC1=CC=CC=C1 PJANXHGTPQOBST-UHFFFAOYSA-N 0.000 description 1
- 150000003462 sulfoxides Chemical class 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 125000004434 sulfur atom Chemical group 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 239000000271 synthetic detergent Substances 0.000 description 1
- 239000000979 synthetic dye Substances 0.000 description 1
- 235000019818 tetrasodium diphosphate Nutrition 0.000 description 1
- 239000001577 tetrasodium phosphonato phosphate Substances 0.000 description 1
- 150000003852 triazoles Chemical class 0.000 description 1
- GETQZCLCWQTVFV-UHFFFAOYSA-N trimethylamine Chemical compound CN(C)C GETQZCLCWQTVFV-UHFFFAOYSA-N 0.000 description 1
- BSVBQGMMJUBVOD-UHFFFAOYSA-N trisodium borate Chemical compound [Na+].[Na+].[Na+].[O-]B([O-])[O-] BSVBQGMMJUBVOD-UHFFFAOYSA-N 0.000 description 1
- ASTWEMOBIXQPPV-UHFFFAOYSA-K trisodium;phosphate;dodecahydrate Chemical class O.O.O.O.O.O.O.O.O.O.O.O.[Na+].[Na+].[Na+].[O-]P([O-])([O-])=O ASTWEMOBIXQPPV-UHFFFAOYSA-K 0.000 description 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
- 239000002023 wood Substances 0.000 description 1
- 238000004394 yellowing prevention Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/395—Bleaching agents
- C11D3/3956—Liquid compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/83—Mixtures of non-ionic with anionic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/86—Mixtures of anionic, cationic, and non-ionic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/88—Ampholytes; Electroneutral compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/88—Ampholytes; Electroneutral compounds
- C11D1/94—Mixtures with anionic, cationic or non-ionic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2003—Alcohols; Phenols
- C11D3/2006—Monohydric alcohols
- C11D3/2034—Monohydric alcohols aromatic
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2068—Ethers
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/395—Bleaching agents
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/40—Dyes ; Pigments
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/40—Dyes ; Pigments
- C11D3/42—Brightening agents ; Blueing agents
Definitions
- the present invention relates to bleaching compositions, in particular to hypohalite bleaching compositions which can be used to treat various surfaces.
- Bleach-containing compositions for bleaching various surfaces are well known in the art.
- those relying on bleaching by hypohalite bleach, such as hypochlorite are often preferred, mainly for bleaching performance reasons.
- hypohalite bleach composition often faced stability problems.
- an objective of bleach manufacturers has always been to obtain a bleach product that is chemically and physically stable over time, for example, over periods of storage.
- hypohalite bleach-containing compositions it is often desirable to add further ingredients, such as dyes or pigments, to hypohalite bleach-containing compositions in order to improve the aesthetics of such compositions.
- further ingredients such as dyes or pigments
- coloured bleaching compositions are particularly preferred compositions.
- the distinct appearance of the composition facilitates it's recognition by consumers, thereby reducing potential misuse or consumption of a potentially irritant composition.
- hypohalite bleach-containing compositions A drawback associated with coloured hypohalite bleach-containing compositions is that pigments and/or dyes, present herein, are decomposed by the bleach. Indeed, hypohalite bleaches are oxidising agents and pigments and dyes are very prone to attacks. In some cases such compounds can even be completely decomposed by such oxidising agents.
- oxidizing agents of the bleaching composition may also cause degradation of optical brighteners present in the composition to increase whitening performances of the same.
- hypohalite-containing composition comprising a pigment and/or a brightener, in which this compound is chemically stable and wherein the cleaning performances of the composition are maintained.
- hypohalite bleach-containing compositions it is known in the art to add a stabilising agent to hypohalite bleach-containing compositions in order to prevent, or at least reduce, the decomposition of further ingredients, in particular pigments and/or dye, present in such compositions.
- EP-A-0668345 and EP-A-1001010 relates to bleaching compositions comprising a hypohalite bleach and a radical scavenger.
- stabilization systems and especially radical scavengers, are capable of stabilising further ingredients, it has been found that pigments and/or dyes are still particularly prone to attacks by hypohalite bleaches and hence are extremely difficult to be stably incorporated into bleaching compositions comprising the known stabilization systems.
- EP 2112218 discloses the use of trimethoxy benzoic acid (TMBA) or a salt thereof as stabilizer of pigments and/or dyes in hypohalite bleach-containing composition.
- TMBA trimethoxy benzoic acid
- TMBA is able to stabilize also the Brightener 49, which is rapidly oxidised by the hypochlorite.
- Brightener 49 which is rapidly oxidised by the hypochlorite.
- TMBA is an expensive chemical, then a cheaper and more efficient substitute of TMBA would be really attractive.
- JP2006077199 teaching the use of a compound of formula R 2 -O-(R 3 CHCH 2 O) s -H, such as phenoxyethanol, to stabilize a synthetic dyes in a bleaching composition containing a hypohalite, an alkali agent, an alkali metal salt of sulfonic acid.
- a compound of formula R 2 -O-(R 3 CHCH 2 O) s -H such as phenoxyethanol
- the composition containing phenoxyethanol although stable, causes staining of the hard surfaces to which it is applied when the dye is a copper phtalocyanine pigment.
- compositions according to claim 1 uses of compound of formula (I) according to claim 10 or 11 and a process of treating a surface according to claim 12 are provided.
- the bleaching compositions herein described are formulated as liquid compositions, including gel and paste form.
- the bleaching compositions are, preferably, but not necessarily, formulated as aqueous compositions.
- Preferred liquid bleaching compositions of the present invention are aqueous and therefore, preferably, may comprise water, more preferably may comprise water in an amount of from 60% to 98%, even more preferably of from 80% to 96% and most preferably 85% to 97% by weight of the total composition.
- compositions of the present invention typically do not undergo more than 36% loss of available oxidising agent after 10 days of storage at 50°C ⁇ 0.5°C and more preferably not more than 32%.
- the percentage of loss of available chlorine (%AvCl) may be measured using the method described, for instance, in “ Analyses des Eaux et Extraits de Javel” by "Lachner syndicalerance de L'eau de Javel et des building connexes", pages 9-10 (1984 ). Said method consists in measuring the available oxidising agent in the fresh compositions, i.e. just after they are made, and in the same compositions after 5 days at 50°C.
- compositions according to the present claims 1 and 10 are alkaline compositions.
- the pH of the liquid compositions herein is from 10.5 to 14 when measured at 25°C. It is in this alkaline range that the optimum stability and performance of the composition as well as fabric whiteness and/or safety are obtained.
- compositions herein may comprise an acid or a source of alkalinity to adjust the pH as appropriate.
- Suitable sources of alkalinity are the caustic alkalis such as sodium hydroxide, potassium hydroxide and/or lithium hydroxide, and/or the alkali metal oxides such as sodium and/or potassium oxide.
- a preferred source of alkalinity is a caustic alkali, more preferably sodium hydroxide and/or potassium hydroxide.
- Typical levels of such sources of alkalinity, when present, are of from 0.1% to 2% by weight, preferably from 0.5% to 1.5% by weight of the composition.
- the bleaching compositions of the present invention comprise a hypohalite bleach.
- Suitable hypohalite bleaches may be provided by a variety of sources, including bleaches that lead to the formation of positive halide ions and/or hypohalite ions, as well as bleaches that are organic based sources of halides, such as chloroisocyanurates.
- hypohalite bleaches for use herein include the alkali metal and alkaline earth metal hypochlorites, hypobromites, hypoiodites, chlorinated trisodium phosphate dodecahydrates, potassium and sodium dichloroisocyanurates, potassium and sodium trichlorocyanurates, N-chloroimides, N-chloroamides, N-chloroamines and chlorohydantoins.
- said hypohalite bleach is an alkali metal and/or alkaline earth metal hypochlorite.
- said hypohalite bleach is an alkali metal and/or alkaline earth metal hypochlorite selected from the group consisting of sodium hypochlorite, potassium hypochlorite, magnesium hypochlorite, lithium hypochlorite and calcium hypochlorite, and mixtures thereof. Even more preferably, said hypohalite bleach is sodium hypochlorite.
- the liquid bleaching compositions herein comprise hypohalite bleach such that the content of active halide (for hypochlorite : AvCl2) in the composition is of from 0.01% to 15% by weight, more preferably from 0.1% to 10% by weight, even more preferably from 0.5% to 7% by weight and most preferably from 1% to 6% by weight of the composition.
- active halide for hypochlorite : AvCl2
- the bleaching compositions of the present claim 1 comprises a surfactant system.
- Said surfactant system may be present in the compositions herein in amounts of at least 0.01% by weight, preferably from 0.5% to 50% by weight, more preferably from 0.5% to 30% by weight and even more preferably from 0.5% to 10% by weight of the composition.
- the amount of surfactant must be superior to 0.5% in order to avoid staining of surfaces.
- the surfactant system for use herein is selected from the group consisting of:
- Suitable anionic surfactants for use in the compositions herein include water-soluble salts or acids of the formula ROSO 3 M wherein R preferably is a C 10 -C 24 hydrocarbyl, preferably linear or branched alkyl having a C 10 -C 20 alkyl component, more preferably a C 12 -C 18 linear or branched alkyl, and M is H or a cation, e.g., an alkali metal cation (e.g., sodium, potassium, lithium), or ammonium or substituted ammonium (e.g., methyl-, dimethyl-, and trimethyl ammonium cations and quaternary ammonium cations, such as tetramethyl-ammonium and dimethyl piperdinium cations and quaternary ammonium cations derived from alkylamines such as ethylamine, diethylamine, triethylamine, and mixtures thereof, and the like).
- R preferably is a
- Suitable anionic surfactants for use herein are water-soluble salts or acids of the formula (II) R 3 O(A) m SO 3 M 1 (II) wherein R 3 is an unsubstituted C 6 -C 24 linear or branched alkyl group having a C 6 -C 24 alkyl component, preferably a C 10 -C 20 linear or branched alkyl, more preferably C 12 -C 18 linear or branched alkyl, A is an ethoxy or propoxy unit, m is greater than zero, typically between about 0.5 and about 30, more preferably between about 0.5 and about 5, and M 1 is H or a cation which can be, for example, a metal cation (e.g., sodium, potassium, lithium, calcium, magnesium, etc.), ammonium or substituted-ammonium cation.
- R 3 is an unsubstituted C 6 -C 24 linear or branched alkyl group having a C 6 -C 24 alkyl component
- Alkyl ethoxylated sulfates as well as alkyl propoxylated sulfates are contemplated herein.
- Specific examples of substituted ammonium cations include methyl-, dimethyl-, trimethyl-ammonium and quaternary ammonium cations, such as tetramethyl-ammonium, dimethyl piperdinium and cations derived from alkanolamines such as ethylamine, diethylamine, triethylamine, mixtures thereof, and the like.
- Exemplary surfactants are C 12 -C 18 alkyl polyethoxylate(1.0)sulfate, C 12 -C 18 E(1.0)sulfate, C 12 -C 18 alkyl polyethoxylate(2.25)sulfate, C 12 -C 18 E(2.25)sulfate, C 12 -C 18 alkyl polyethoxylate(3.0)sulfate, C 12 -C 18 E(3.0)sulfate, and C 12 -C 18 alkyl polyethoxylate(4.0)sulfate, C 12 -C 18 E(4.0)sulfate, wherein the counterion is conveniently selected from sodium and potassium.
- the surfactant system used is an anionic surfactant system, namely alkyl alkoxy (preferably ethoxy) sulphate alone for example alkyl (ethoxy) 3 sulphate (AE3S) or in combination with a co-surfactant, preferably a C 2 -C 10 alkyl sulphate and/or a C 8 -C 22 alkyl or aryl sulphonate like C 8 -C 22 benzene sulphonate and/or another alkyl alkoxy sulphate apart the 3 ethoxylated one.
- AE3S alkyl alkoxy
- co-surfactant preferably a C 2 -C 10 alkyl sulphate and/or a C 8 -C 22 alkyl or aryl sulphonate like C 8 -C 22 benzene sulphonate and/or another alkyl alkoxy sulphate apart the 3 ethoxylated one.
- compositions according to the present invention have a viscosity between 25 cps and 1500 cps, preferably between 50 cps and 200 cps, depending of the ratio between AE3S and the co-surfactant, when measured with a Rheometer like Carri-med CSL2-100 ® at the following viscosity parameters: angle: 1°58, gap: 60, diameter: 4.0 cm, iner.: 63.60 at a temperature of 25°C and a shear rate of 30 1/sec.
- Suitable anionic surfactants for use herein are water-soluble salts or acids of the formula (III) R 4 O(A) m CH 2 COOM 1 (III) wherein R 4 is an unsubstituted C 6 -C 24 linear or branched alkyl group having a C 6 -C 24 alkyl component, preferably a C 10 -C 20 linear or branched alkyl, more preferably C 12 -C 18 linear or branched alkyl, A is an ethoxy or propoxy unit, m is greater than zero, typically between about 0.5 and about 30, more preferably between about 0.5 and about 5, and M 1 is as defined above.
- Alkyl ethoxylated carboxylates as well as alkyl propoxylated carboxylates are contemplated herein.
- Exemplary surfactants are C 12 -C 18 alkyl ethoxylated (2.0) carboxylate, C 12 -C 18 alkyl ethoxylated (5.0) carboxylate, C 12 -C 18 alkyl ethoxylated(7.0)carboxylate, wherein the counterion is conveniently selected from sodium and potassium.
- anionic surfactants useful for detersive purposes can also be used herein.
- the anionic surfactant may be selected in the group consisting of alkyl sulphates, alkyl ether sulphates, sarcosinates, taurates, ether carboxylate, alkyl ethoxylated sulphates, alkyl propoxylated sulfates or their mixtures.
- Suitable nonionic surfactants for use herein are capped nonionic ethoxylated surfactants according to the formula (IV): R 5 (OR 6 ) n OR 7 (IV) wherein R 5 is a C 8 -C 18 linear or branched alkyl or alkenyl group, aryl group, alkaryl group, preferably, R 5 is a C 10 -C 15 alkyl or alkenyl group, more preferably a C 10 -C 15 alkyl group; R 6 is a C 2 -C 10 linear or branched alkyl group, preferably a C 4 group; R 7 is a C 1 -C 10 alkyl or alkenyl group, preferably a C 1 -C 5 alkyl group, and n is an integer ranging in the range of from 1 to 20, preferably from 1 to 10, more preferably from 1 to 5; or mixtures thereof.
- surfactants are commercially available from BASF under the trade name Plurafac ® , from HOECHST under the trade name Genapol ® or from ICI under the trade name Symperonic ® .
- Preferred capped nonionic ethoxylated surfactant of the above formula are those commercially available under the tradename Genapol ® L 2.5 NR from Hoechst, and Symperonic ® LF/CS 1100 from ICI.
- nonionic surfactants for use herein include a class of compounds which may be broadly defined as compounds produced by the condensation of alkylene oxide groups (hydrophilic in nature) with an organic hydrophobic compound, which may be branched or linear aliphatic (e.g. Guerbet or secondary alcohol) or alkyl aromatic in nature.
- the length of the hydrophilic or polyoxyalkylene radical which is condensed with any particular hydrophobic group can be readily adjusted to yield a water-soluble compound having the desired degree of balance between hydrophilic and hydrophobic elements.
- Suitable zwitterionic surfactants for use herein are that include the amine oxides corresponding to the formula (V): R 8 R 9 R 10 N ⁇ O (V) wherein R 8 is a primary alkyl group containing 6-24 carbons, preferably 10-18 carbons, and wherein Rg and R 10 are, each, independently, an alkyl group containing 1 to 6 carbon atoms.
- the arrow in the formula is a conventional representation of a semi-polar bond.
- the preferred amine oxides are those in which the primary alkyl group has a straight chain in at least most of the molecules, generally at least 70%, preferably at least 90% of the molecules, and the amine oxides which are especially preferred are those in which R contains 10-18 carbons and R 8 and R 9 are both methyl.
- Exemplary of the preferred amine oxides are the N-decyldimethylamine oxide, N-dodecyl dimethylamine oxide, the corresponding amine oxides in which one or both of the methyl groups are replaced with ethyl or 2-hydroxyethyl groups and mixtures thereof.
- a most preferred amine oxide for use herein is N-decyldimethylamine oxide.
- Suitable zwitterionic surfactants for the purpose of the invention are the phosphine or sulfoxide surfactants of formula (VI): R 11 R 12 R 13 A ⁇ O (VI) wherein A is phosphorus or sulfur atom, R 11 is a primary alkyl group containing 6-24 carbons, preferably 10-18 carbons, and wherein R 12 and R 13 are, each, independently selected from methyl, ethyl and 2-hydroxyethyl.
- the arrow in the formula is a conventional representation of a semi-polar bond.
- Suitable surfactants with multiple charges for use herein are zwitterionic detergents that comprise the betaine and betaine-like detergents wherein the molecule contains both basic and acidic groups which form an inner salt giving the molecule both cationic and anionic hydrophilic groups over a broad range of pH values.
- Some common examples of these detergents are described in U.S. Pat. Nos. 2082275 , 2702279 and 2255082 .
- Amphoteric and ampholytic detergents which can be either cationic or anionic depending upon the pH of the system are represented by detergents such as dodecylbetaalanine, N-alkyltaurines such as the one prepared by reacting dodecylamine with sodium isethionate according to the teaching of U.S. Pat. No. 2658072 , N-higher alkylaspartic acids such as those produced according to the teaching of U.S. Pat. No. 2438091 , and the products sold under the trade name "Miranol", and described in U.S. Pat. No. 2,528,378 . Additional synthetic detergents and listings of their commercial sources can be found in McCutcheon's Detergents and Emulsifiers, North American Ed. 1980.
- Suitable zwitterionic detergents for use herein comprise quaternary amine (or diamine) alkyl ether sulfate of formula (VII): R 14 [N(A m SO 3 M 1 ) 4 ] n (VII) wherein R 14 is an unsubstituted C 2 -C 24 linear or branched alkyl group having a C 4 -C 24 alkyl component, preferably a C 4 -C 20 linear or branched alkyl, more preferably C 4 -C 18 linear or branched alkyl, and A, m and M1 are as defined above, in particular, m is typically between about 0.5 and about 50, more preferably between about 5 and about 30.
- Quaternary diamine alkyl ether sulfates as well as quaternary amine alkyl ether sulfates are contemplated herein.
- Exemplary surfactants are Lutensit z96 form BASF ® .
- Cationic surfactants suitable for use in compositions of the present invention are those having a long-chain hydrocarbyl group.
- cationic surfactants include the ammonium surfactants such as alkyltrimethylammonium halogenides, and those surfactants having the formula (VIII): [R 15 OR 16 ) y ][R 17 (OR 16 ) y ] 2 R 18 N + X - (VIII) wherein R 15 is an alkyl or alkyl benzyl group having from 8 to 18 carbon atoms in the alkyl chain, each R 16 is selected from the group consisting of -CH 2 CH 2 -, -CH 2 CH(CH 3 ), -CH 2 CH 2 CH 2 -, and mixtures thereof; each R 17 is selected from the group consisting of C1-C4 alkyl, benzyl ring structures formed by joining the two R 17 groups, and hydrogen when y is not 0; R 18 is the same as R 17 or is an alkyl chain wherein the
- Quaternary ammonium surfactant suitable for the present invention has the formula (IX):
- Highly preferred cationic surfactants are the water-soluble quaternary ammonium compounds useful in the present composition having the formula : R 25 R 26 R 27 R 28 N + X - (i)
- compositions of the present invention comprise a stabilizer of formula (I): R 1 -O-(R 2 CHCH 2 O) s -H (I) wherein R 1 is a phenyl group, R 2 represents a hydrogen atom and s represents an integer from 1 to 2.
- the stabilizer of formula (I) is phenoxyethanol.
- the bleaching composition herein may comprise from 0.001% to 5%, preferably from 0.005% to 3.0% and more preferably from 0.03% to 2.0% by weight of the total composition of said stabilizer of formula (I).
- compositions of the present invention may comprise at least one metal-phthalocyanine pigment.
- the presence of a pigment in the composition of the present invention is essential to provide a colored bleaching composition.
- the metal, in the metal-phthalocyanine pigment can be any metal with which phthalocyanine forms a metal chelate complex, such as Cu, Ni, Mg, Pt, Al, Co, Pb, Ba.
- the metal-phthalocyanine pigments contained in the bleaching composition of the present invention is a copper-phthalocyanine pigment.
- the pigment used in the present invention herein is a blue or green copper phthalocyanine pigment.
- Blue copper phtalocyanine is commercially available under the tradename Dye Pigmosol Blue 15 ® , from BASF; Direct Blue 86 (commercially available under the tradename Iragon Blue DBL86 ® from Clariant); Pigment Blue 15:1 (commercially available under the tradename Disperse Blue 69-007 ® from BASF); and Pigment Blue 15:3 (commercially available under the tradename Hostafine Blue B2G ® from Clariant).
- the pigment, or mixture thereof, is present in the compositions of the present claim 1 at levels of from 0.0005% to 0.005% and preferably from 0.0005% to 0.003% by weight.
- compositions according to the present invention may also comprise a brightener or mixture thereof.
- the brightener has to be stable to the hypohalite bleach.
- the brighteners may be desired herein to further enhance the whiteness performance of the compositions herein.
- Brighteners are compounds which have the ability to fluorescent by absorbing ultraviolet wave-lengths of light and re-emitting visible light. Brighteners, also referred to as fluorescent whitening agent (FWA), have been extensively described in the art, see for instance EP-A-0265041 , EP-A-0322564 , EP-A-0317979 or " Fluorescent whitening agents" by A.K. Sarkar, published by MERROW, especially page 71-72 .
- FWA fluorescent whitening agent
- optical brighteners which may be useful in the present invention can be classified into subgroups, which include, but are not necessarily limited to, derivatives of stilbene, pyrazoline, coumarin, carboxylic acid, methinecyanines, dibenzothiophene-5,5-dioxide, azoles, 5- and 6-membered ring heterocycles, and other miscellaneous agents. Examples of such brighteners are disclosed in " The Production and Application of Fluorescent Brightening Agents", M. Zahradnik, Published by John Wiley & Sons, New York (1982 ). Further optical brighteners which may also be used in the present invention include naphthlimide, benzoxazole, benzofuran, benzimidazole and any mixtures thereof.
- optical brighteners which are useful in the present compositions are those identified in U.S. Patent 4,790,856 . These brighteners include the PHORWHITE ® series of brighteners from Verona. Other brighteners disclosed in this reference include: Tinopal-UNPA ® , Tinopal CBS ® and Tinopal 5BM ® available from Ciba-Geigy; Artic White CC ® and Artic White CWD ® ; the 2-(4-styryl-phenyl)-2H-naptho[1,2-d]triazoles; 4,4'-bis(1,2,3-triazol-2-yl)-stilbenes; 4,4'-bis(styryl)bisphenyls; and the aminocoumarins.
- brighteners useful in the present invention include the polycyclic oxazole derivatives such as benzo-oxazole derivatives, or mixtures thereof and particularly preferred herein the benzo-oxazole derivatives.
- An example of such a brightener is benzoxazole,2,2'-(thiophenaldyl)bis having the following formula C 18 H 10 N 2 O 2 S, commercially available from Ciba-Geigy under the trade name Tinopal SOP ® .
- This brightener is almost insoluble in water, i.e. it has a solubility being lower than 1 gram per liter.
- Another example of such a brightener is bis(sulfobenzofuranyl)biphenyl, commercially available from Ciba-Geigy under the trade name Tinopal PLC ® .
- compositions according to the present claim 1 comprise from 0.005% to 0.5% by weight of the total composition of a brightener or mixture thereof, preferably preferably from 0.005% to 0.3% and most preferably from 0.008% to 0.1% by weight.
- compositions of the present invention may comprise an alkali metal salt of silicate. Indeed, when this ingredient is present in the composition according to the present invention a synergetic effect on stability of the pigment and of the oxidising agent is obtained.
- alkali metal salt of silicate it is meant herein an alkali metal salt of silicate or polysilicates, or mixtures thereof.
- the preferred alkali metal salt of silicate to be used herein is sodium silicate.
- Preferred compositions of the present invention comprise from 0.005% to 5% by weight of the total composition of an alkali metal salt of silicate, preferably from 0.01 % to 2% and more preferably from 0.05% to 1%.
- alkali metal salt of silicate such as sodium silicate
- alkali metal salt of silicate such as sodium silicate
- alkali metal salts of silicate such as sodium silicate
- pigments such as copper-phthalocyanine when decomposed by oxidizing agent, release free metal ion, such as copper, which results in the acceleration of hypohalite decomposition.
- a further advantage of the bleaching compositions according to the present invention is that they show excellent bleaching performances upon storage. The cleaning performances of the bleaching composition are therefore maintained.
- compositions of the present invention according to claim 1, the presence of a pH buffering component is compulsory.
- the presence of a pH buffering component in the compositions of the present invention further contributes to the stability of these compositions, effective whiteness performance as well as to the fabric safety.
- the pH buffering component allows to control the alkalinity in the bleaching solution, i.e. maintain the pH of the bleaching solution at a pH of at least 7.5, preferably at least 8, and more preferably at least 8.5 for a longer period of time starting from the moment at which the dilution is completed (e.g. when the bleaching composition of the present invention is diluted in the bleaching solution at a dilution level of 500:1 (water: composition)).
- the pH buffering component may also contribute to stability of the bleachunstable ingredients herein.
- the pH buffering component ensures that the pH of the composition is buffered to a pH value ranging from 7.5 to 13, preferably from 8 to 12, more preferably from 8.5 to 11.5 after the composition has been diluted into 1 to 500 times its weight of water.
- Suitable pH buffering components for use herein are selected from the group consisting of alkali metal salts of carbonates, polycarbonates, sesquicarbonates, silicates, polysilicates, boron salts, phosphates, stannates, alluminates and mixtures thereof. More preferably alkali metal salts of carbonate, silicate and borate.
- the preferred alkali metal salts for use herein are sodium and potassium.
- pH buffering components are selected from the group consisting of sodium carbonate, sodium silicate, sodium borate, sodium metaborate and mixtures thereof.
- the raw materials involved in the preparation of hypohalite bleaches usually contain by-products, e.g. calcium carbonate resulting in an amount of up to 0.4% by weight of by-product within the hypohalite composition. However, at such amount, the by-product will not have the buffering action defined above.
- by-products e.g. calcium carbonate resulting in an amount of up to 0.4% by weight of by-product within the hypohalite composition.
- the by-product will not have the buffering action defined above.
- Liquid bleaching compositions of the invention may contain a mixture of inorganic alkaline compounds, preferably a mixture of at least an hydroxide and at least a carbonate.
- Liquid bleaching compositions herein may contain an amount of pH buffering component of from 0.5% to 9% by weight, preferably from 0.5% to 5% by weight, and more preferably in an amount of from 0.6% to 3% by weight of the composition.
- compositions according to the present invention may optionally also comprise a chelating agent as an optional ingredient.
- Suitable chelating agents may be any of those known to those skilled in the art such as the ones selected from the group comprising phosphonate chelating agents, phosphate chelating agents, polyfunctionally-substituted aromatic chelating agents, ethylenediamine N,N'- disuccinic acids, or mixtures thereof.
- Chelating agents may be desired in the compositions of the present invention, preferably phosphate chelating agents like phytic acid, as they further contribute to the benefit delivered by the stabilizer herein by further improving the stability of the brighteners, thus delivering effective whiteness performance in any laundry application upon ageing of the compositions, i.e. after prolonged periods of storage.
- Suitable phosphonate chelating agents for use herein may include alkali metal ethane 1-hydroxy diphosphonates (HEDP), alkylene poly (alkylene phosphonate), as well as amino phosphonate compounds, including amino aminotri(methylene phosphonic acid) (ATMP), nitrilo trimethylene phosphonates (NTP), ethylene diamine tetra methylene phosphonates, and diethylene triamine penta methylene phosphonates (DTPMP).
- the phosphonate compounds may be present either in their acid form or as salts of different cations on some or all of their acid functionalities.
- Preferred phosphonate chelating agents to be used herein are diethylene triamine penta methylene phosphonate (DTPMP) and ethane 1-hydroxy diphosphonate (HEDP). Such phosphonate chelating agents are commercially available from Monsanto under the trade name REQUEST ® .
- Suitable phosphate chelating agents for use in the compositions of the present invention are described in EP-A-0 867 502 in the section titled "The Phosphate ingredient", such ingredients are specifically incorporated herein by reference, especially for their fabric whitening benefit (i.e., yellowing prevention effect) and/or fabric safety benefit. All phosphate ingredients described in EP-A-0 867 502 in the section titled "The Phosphate ingredient” are suitable for use herein.
- Preferred phosphate chelating agents for use herein are linear phosphate ingredients, wherein R in the formula in the section titled "The Phosphate ingredient" of EP-A-0867502 is M and wherein n is 1 (pyrophosphate) or n is 2 (tripolyphosphate (STPP)), most preferably wherein n is 2.
- R in the formula in the section titled "The Phosphate ingredient" of EP-A-0867502 is M and wherein n is 1 (pyrophosphate) or n is 2 (tripolyphosphate (STPP)), most preferably wherein n is 2.
- M is Sodium.
- preferred phosphate chelating agents for use in the compositions of the present invention are pyrophosphate and/or tripolyphosphate (STPP), more preferably Na phosphate and/or Na tripolyphosphate (STPP).
- Phytic acid which is particularly suitable for use herein, is a hexa-phosphoric acid that occurs naturally in the seeds of many cereal grains, generally in the form of the insoluble calcium-magnesium salt. It may also be derived from corn steep liquor. Commercial grade phytic acid is commercially available from J. T. Baker Co., e.g. as a 40% aqueous solution. It is intended that the present invention covers the acidic form of phytic acid as well as alkali metal salt derivatives thereof, particularly sodium or potassium salts thereof. Sodium phytate is available from Jonas Chemical Co (Brooklyn, N.Y.).
- the phytic acid component exists primarily as the ionized salt in the liquid compositions herein even if it is added in its acidic form. Mixtures of such salts of phytic acid are also covered.
- Polyfunctionally-substituted aromatic chelating agents may also be useful in the compositions herein. See U.S. patent 3812044, issued May 21, 1974, to Connor et al .
- Preferred compounds of this type in acid form are dihydroxydisulfobenzenes such as 1,2-dihydroxy-3,5-disulfobenzene.
- a preferred biodegradable chelating agent for use herein is ethylene diamine N,N'-disuccinic acid, or alkali metal, or alkaline earth, ammonium or substitutes ammonium salts thereof or mixtures thereof.
- Ethylenediamine N,N'-disuccinic acids, especially the (S,S) isomer have been extensively described in US patent 4704233, November 3, 1987, to Hartman and Perkins .
- Ethylenediamine N,N'-disuccinic acids is, for instance, commercially available under the tradename ssEDDS ® from Palmer Research Laboratories.
- Particularly preferred chelating agents for use herein are phosphate chelating agents like sodium pyrophosphate, sodium tripolyphosphate, phytic acid, and mixtures thereof.
- compositions herein comprise up to 10%, preferably from 0.01% to 5% by weight, more preferably from 0.03% to 2% by weight of the composition of a chelating agent or mixture thereof.
- a further optional ingredient of the present composition is a builder.
- Highly preferred builder compounds for use in the present invention are water-soluble phosphate builders.
- Specific examples of water-soluble phosphate builders are the alkali metal tripolyphosphates, sodium, potassium and ammonium pyrophosphate, sodium and potassium and ammonium pyrophosphate, sodium and potassium orthophosphate, sodium polymeta/phosphate in which the degree of polymerisation ranges from 6 to 21, and salts of phytic acid.
- water-soluble phosphate builders are the alkali metal tripolyphosphates, sodium, potassium and ammonium pyrophosphate, sodium and potassium and ammonium pyrophosphate, sodium and potassium orthophosphate, sodium polymeta/phosphate in which the degree of polymerization ranges from 6 to 21, and salts of phytic acid.
- the bleaching compositions herein may further comprise a variety of optional ingredients such as bleach activators, soil suspenders, soil suspending polyamine polymers, polymeric soil release agents, foam reducing systems/agents, catalysts, dye transfer agents, perfumes, hydrotropes and solvents.
- optional ingredients such as bleach activators, soil suspenders, soil suspending polyamine polymers, polymeric soil release agents, foam reducing systems/agents, catalysts, dye transfer agents, perfumes, hydrotropes and solvents.
- the bleaching composition can be used to treat surfaces.
- surfaces include, but are not limited to, hard-surfaces typically found in houses like kitchens, bathrooms, or in car interiors, e.g., tiles, walls, floors, chrome, glass, smooth vinyl, any plastic, plastified wood, table top, sinks, cooker tops, dishes, sanitary fittings such as sinks, showers, shower curtains, wash basins, WCs and the like, as well as fabrics including clothes, curtains, drapes, bed linens, bath linens, table cloths, sleeping bags, tents, upholstered furniture and the like, and carpets.
- Inanimate surfaces also include household appliances including, but not limited to, refrigerators, freezers, washing machines, automatic dryers, ovens, microwave ovens, dishwashers and so on.
- treating a surface it is meant herein bleaching and/or disinfecting said surfaces as the compositions of the present invention comprise a hypohalite bleach and cleaning, i.e. removing various types of stains from the surfaces.
- the present invention also encompasses a process of treating (e.g. bleaching) a fabric, as the inanimate surface.
- a fabric is contacted with a composition according to the present invention.
- pretreatment mode where a liquid bleaching composition, as defined herein, is applied neat onto said fabrics before the fabrics are rinsed, or washed and then rinsed, or in a "soaking mode” where a liquid bleaching composition, as defined herein, is first diluted in an aqueous bath and the fabrics are immersed and soaked in the bath, before they are rinsed, or in a "through the wash mode", where a liquid bleaching composition, as defined herein, is added on top of a wash liquor formed by dissolution or dispersion of a typical laundry detergent. It is also essential in both cases, that the fabrics be rinsed after they have been contacted with said composition, before said composition has completely dried off.
- the processes of treating surfaces fabrics according to the present invention delivers effective whiteness performance and/or effective stain removal performance avoiding staining of the treated surface upon ageing of the compositions.
- compositions according to the present invention are preferably contacted to fabrics in a liquid form. Indeed, by "in a liquid form”, it is meant herein the liquid compositions according to the present invention per se in neat or diluted form.
- compositions according to the present invention are typically used in diluted form in a laundry operation.
- in diluted form it is meant herein that the compositions for the bleaching of fabrics according to the present invention may be diluted by the user, preferably with water. Such dilution may occur for instance in hand laundry applications as well as by other means such as in a washing machine.
- Said compositions can be diluted up to 500 times, preferably from 5 to 200 times and more preferably from 10 to 80 times.
- the process of bleaching fabrics according to the present invention comprises the steps of first contacting a fabrics with a bleaching composition according to the present invention, in its diluted form, then allowing said fabrics to remain in contact with said composition, for a period of time sufficient to bleach said fabrics, typically 1 to 60 minutes, preferably 5 to 30 minutes, then rinsing said fabrics with water. If said fabrics are to be washed, i.e., with a conventional composition comprising at least one surface active agent, said washing may be conducted together with the bleaching of said fabrics by contacting said fabrics at the same time with a bleaching composition according to the present invention, or said washing may be conducted before or after that said fabrics have been bleached.
- said process allows to bleach fabrics and optionally to wash fabrics with a detergent composition comprising at least one surface active agent before the step of contacting said fabrics with said bleaching composition and/or in the step where said fabrics are contacted with said bleaching composition and/or after the step where said fabrics are contacted with the bleaching composition and before the rinsing step and/or after the rinsing step.
- the process of bleaching fabrics comprises the step of contacting fabrics with a liquid bleaching composition according to the present invention, in its neat form, of allowing said fabrics to remain in contact with said bleaching composition for a period of time sufficient to bleach said fabrics, typically 5 seconds to 30 minutes, preferably 1 minute to 10 minutes and then rinsing said fabrics with water. If said fabrics are to be washed, i.e., with a conventional composition comprising at least one surface active agent, said washing may be conducted before or after said fabrics have been bleached.
- the level of hypohalite bleach is from 0.01% to 6%, preferably from 0.1% to 5%, more preferably from 0.3% to 4.5% and most preferably from 1.0% to 4.0%.
- the present invention provides liquid hypohalite bleach-containing compositions that may be applied neat onto a fabric to bleach, despite a standing prejudice against using hypochlorite-containing compositions neat on fabrics.
- the bleaching pre-treatment operation may also be followed by the diluted bleaching process as described herein before either in bucket (hand operation) or in a washing machine.
- the present invention also encompasses a process of treating a hard-surface, as the inanimate surface.
- a composition as defined herein, is contacted with the hard-surfaces to be treated.
- the present invention also encompasses a process of treating a hard-surface with a composition, as defined herein, wherein said process comprises the step of applying said composition to said hard-surface, preferably only soiled portions thereof, and optionally rinsing said hard-surface.
- composition as defined herein, may be applied to the surface to be treated in its neat form or in its diluted form typically up to 200 times their weight of water, preferably into 80 to 2 times their weight of water, and more preferably 60 to 2 times.
- compositions of the present invention are easy to rinse and provide good shine characteristics on the treated surfaces.
- hard-surfaces it is understood any hard-surfaces as mentioned herein before as well as dishes.
- compositions are made by mixing the listed ingredients in the listed proportions (weight percent unless otherwise specified).
- compositions of Table I were tested in a Rapid Aging Test (RAT) for 10 days at 50°C.
- RAT Rapid Aging Test
- Rapid Aging Test has been performed storing 100 mL of sample at 50°C ( ⁇ 0.5°C) into a ventilated oven.
- the bottles used for the test were 100 mL square bottle with plug cap in HDPE.
- the stabilization of the pigment (Blue copper phtalocyanine) by 2-PE is better with respect to TMBA at the same concentration of 0.10% (composition I vs composition II in table 2).
- concentration II vs composition IV in table 2 increases, but also the loss of AvCl increases, probably due to the oxidation of the same 2-PE.
- concentration II vs composition V in table 2 slightly reduces the stabilization of the pigment (composition II vs composition V in table 2), but also decrease the loss of AvCl.
- Amine oxide are suitable surfactants for these systems(compositions XXII, XXIII and XIV of table I), but it is worth to note that a level of surfactant lower than 0.5 % w/w causes the pigment to stain the surfaces where the product is used (see composition XXIII).
- compositions VII-XII Analogue trends about pigment and AvCl were observed when the samples were prepared with the Br49 (compositions VII-XII). Moreover, the stabilization of the brightener by 2-PE is better in comparison with TMBA at the same concentration of 0.10% (composition VIII vs composition VII in table 2). Increasing the level of 2-PE, the stabilization of Br49 increases (composition VIII vs compositions IX-XII in table 2). The stabilization of the brightener provided by 0.10% of TMBA is comparable with the one obtained with 0.066% of 2-PE (composition VII vs composition XI in Table 2).
- hypochlorite-containing formulations develops molecular oxygen as main degradation product of the oxidant.
- This reaction is catalytically enhanced by metal impurities which are usually present in water, such as copper and iron.
- metal impurities which are usually present in water, such as copper and iron.
- This phenomenon is very relevant for bleach products, because large values of gas evolution rate may cause bulging of bottles, which would cause drawbacks in terms of aesthetics and safety of the packaging. For this reason, GER is a key parameter for the assessment of the robustness of new formulations.
- composition I and II were tested also with a contamination of Iron (500 ppb) and copper (250 ppb), which was added on top of the product.
- the product already contains about 200 ppb of iron and 200 ppb of copper coming from raw materials.
- composition II Table 3
- Table 3 GER ((mLO2/(500mL*day)) Day 0 Day 1 Day 3 Day 7 Day 10 Day 14
- Composition I TMBA 0.10%) 1.0 1.7 1.8 1.3 1.3 0.47 Composition II (2-PE 0.10%) 1.7 0.7 1.3 1.0 1.0 0.59 Composition I (TMBA 0.10%)+ metals 9.6 9.0 8.0 7.4 11.2 12.22 Composition II (2-PE 0.10%) + metals 6.0 5.4 4.6 3.6 4.6 4.01
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PCT/IB2015/054669 WO2016207691A1 (en) | 2015-06-22 | 2015-06-22 | Stable bleaching composition |
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EP (1) | EP3310890B1 (ru) |
ES (1) | ES2940468T3 (ru) |
PT (1) | PT3310890T (ru) |
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US2702279A (en) | 1955-02-15 | Detergent compositions having | ||
US2082275A (en) | 1934-04-26 | 1937-06-01 | Gen Aniline Works Inc | Substituted betaines |
US2255082A (en) | 1938-01-17 | 1941-09-09 | Gen Aniline & Film Corp | Capillary active compounds and process of preparing them |
US2438091A (en) | 1943-09-06 | 1948-03-16 | American Cyanamid Co | Aspartic acid esters and their preparation |
US2528378A (en) | 1947-09-20 | 1950-10-31 | John J Mccabe Jr | Metal salts of substituted quaternary hydroxy cycloimidinic acid metal alcoholates and process for preparation of same |
US2658072A (en) | 1951-05-17 | 1953-11-03 | Monsanto Chemicals | Process of preparing amine sulfonates and products obtained thereof |
US3812044A (en) | 1970-12-28 | 1974-05-21 | Procter & Gamble | Detergent composition containing a polyfunctionally-substituted aromatic acid sequestering agent |
US4790856A (en) | 1984-10-17 | 1988-12-13 | Colgate-Palmolive Company | Softening and anti-static nonionic detergent composition with sulfosuccinamate detergent |
US4764302A (en) | 1986-10-21 | 1988-08-16 | The Clorox Company | Thickening system for incorporating fluorescent whitening agents |
US4704233A (en) | 1986-11-10 | 1987-11-03 | The Procter & Gamble Company | Detergent compositions containing ethylenediamine-N,N'-disuccinic acid |
DE3852380D1 (de) | 1987-11-26 | 1995-01-19 | Ciba Geigy Ag | Stabile, optische Aufheller enthaltende Waschmittel. |
EP0322564B1 (de) | 1987-12-23 | 1994-06-15 | Ciba-Geigy Ag | Stabile, optische Aufheller enthaltende Waschmittel |
JP2663180B2 (ja) * | 1989-10-26 | 1997-10-15 | ライオン株式会社 | 粘度低下防止剤及び該防止剤を含有する液体漂白剤組成物 |
EP0668345B1 (en) | 1994-02-22 | 2001-12-12 | The Procter & Gamble Company | Hypochlorite bleaching compositions |
ES2231852T3 (es) | 1997-03-27 | 2005-05-16 | THE PROCTER & GAMBLE COMPANY | Composiciones blanqueantes. |
ATE239779T1 (de) | 1998-11-11 | 2003-05-15 | Procter & Gamble | Bleichmittelzusammensetzungen |
JP4191118B2 (ja) * | 2004-09-13 | 2008-12-03 | ライオン株式会社 | 漂白剤組成物 |
JP2008214545A (ja) * | 2007-03-06 | 2008-09-18 | Lion Corp | 液体洗浄剤組成物 |
EP2112218B1 (en) | 2008-04-25 | 2011-08-17 | The Procter & Gamble Company | Colored bleaching composition |
US8449626B2 (en) * | 2009-11-11 | 2013-05-28 | The Procter & Gamble Company | Cleaning method |
CN104250590A (zh) * | 2013-06-28 | 2014-12-31 | 青岛康泰鑫环保科技有限公司 | 一种无磷低泡洗衣粉 |
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- 2015-06-22 WO PCT/IB2015/054669 patent/WO2016207691A1/en active Application Filing
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WO2016207691A1 (en) | 2016-12-29 |
PT3310890T (pt) | 2023-03-03 |
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