EP3268307A4 - Chromium-free water-gas shift catalyst and process for making the same - Google Patents

Chromium-free water-gas shift catalyst and process for making the same Download PDF

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Publication number
EP3268307A4
EP3268307A4 EP16762388.3A EP16762388A EP3268307A4 EP 3268307 A4 EP3268307 A4 EP 3268307A4 EP 16762388 A EP16762388 A EP 16762388A EP 3268307 A4 EP3268307 A4 EP 3268307A4
Authority
EP
European Patent Office
Prior art keywords
chromium
making
same
free water
gas shift
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
EP16762388.3A
Other languages
German (de)
English (en)
French (fr)
Other versions
EP3268307A1 (en
Inventor
Christopher Holt
Paul Matter
Michael BEACHY
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
pH Matter LLC
Original Assignee
pH Matter LLC
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by pH Matter LLC filed Critical pH Matter LLC
Priority claimed from PCT/US2016/021473 external-priority patent/WO2016145023A1/en
Publication of EP3268307A1 publication Critical patent/EP3268307A1/en
Publication of EP3268307A4 publication Critical patent/EP3268307A4/en
Withdrawn legal-status Critical Current

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Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/74—Iron group metals
    • B01J23/745—Iron
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/02—Boron or aluminium; Oxides or hydroxides thereof
    • B01J21/04—Alumina
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/002—Mixed oxides other than spinels, e.g. perovskite
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/72—Copper
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/61—Surface area
    • B01J35/613—10-100 m2/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/61—Surface area
    • B01J35/615—100-500 m2/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/03—Precipitation; Co-precipitation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/08—Heat treatment
    • B01J37/082—Decomposition and pyrolysis
    • B01J37/088—Decomposition of a metal salt
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
    • C01B3/06—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of inorganic compounds containing electro-positively bound hydrogen, e.g. water, acids, bases, ammonia, with inorganic reducing agents
    • C01B3/12—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of inorganic compounds containing electro-positively bound hydrogen, e.g. water, acids, bases, ammonia, with inorganic reducing agents by reaction of water vapour with carbon monoxide
    • C01B3/16—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of inorganic compounds containing electro-positively bound hydrogen, e.g. water, acids, bases, ammonia, with inorganic reducing agents by reaction of water vapour with carbon monoxide using catalysts
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2523/00—Constitutive chemical elements of heterogeneous catalysts
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/02—Processes for making hydrogen or synthesis gas
    • C01B2203/0283—Processes for making hydrogen or synthesis gas containing a CO-shift step, i.e. a water gas shift step
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/10—Catalysts for performing the hydrogen forming reactions
    • C01B2203/1041—Composition of the catalyst
    • C01B2203/1047—Group VIII metal catalysts
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Combustion & Propulsion (AREA)
  • Inorganic Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Catalysts (AREA)
EP16762388.3A 2015-03-10 2016-03-09 Chromium-free water-gas shift catalyst and process for making the same Withdrawn EP3268307A4 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US201562130649P 2015-03-10 2015-03-10
PCT/US2016/021473 WO2016145023A1 (en) 2015-03-10 2016-03-09 Chromium-free water-gas shift catalyst and process for making the same

Publications (2)

Publication Number Publication Date
EP3268307A1 EP3268307A1 (en) 2018-01-17
EP3268307A4 true EP3268307A4 (en) 2018-07-25

Family

ID=60389449

Family Applications (1)

Application Number Title Priority Date Filing Date
EP16762388.3A Withdrawn EP3268307A4 (en) 2015-03-10 2016-03-09 Chromium-free water-gas shift catalyst and process for making the same

Country Status (2)

Country Link
EP (1) EP3268307A4 (zh)
CN (1) CN107406252A (zh)

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108479785A (zh) * 2018-04-16 2018-09-04 深圳市国能环保科技有限公司 一种高温水煤气变换反应用催化剂及其制造方法

Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4402745A (en) * 1981-04-27 1983-09-06 Marko Materials, Inc. New iron-aluminum-copper alloys which contain boron and have been processed by rapid solidification process and method
US4590324A (en) * 1985-03-11 1986-05-20 Amoco Corporation Dehydrogenation of alkylaromatics
EP0296734A1 (en) * 1987-06-22 1988-12-28 Imperial Chemical Industries Plc Copper catalyst for carbon oxide conversion
WO2001074484A2 (en) * 2000-03-31 2001-10-11 The Regents Of The University Of Michigan Transition metal carbides, nitrides and borides and their oxygen containing analogs useful as water gas shift catalysts
WO2004043583A2 (en) * 2002-11-11 2004-05-27 Conocophillips Company Improved supports for high surface area catalysts
WO2008141827A1 (en) * 2007-05-23 2008-11-27 Saudi Basic Industries Corporation Process of oxidative dehydrogenation using a boria-alumina catalyst
EP2826561A1 (en) * 2012-03-13 2015-01-21 Benefuel Inc. Solid acid catalyst, method for manufacturing same, and method for manufacturing a fatty acid alkyl ester using same

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6969505B2 (en) * 2002-08-15 2005-11-29 Velocys, Inc. Process for conducting an equilibrium limited chemical reaction in a single stage process channel
WO2006138485A1 (en) * 2005-06-15 2006-12-28 The Ohio State University Catalyst for hydrogen production from water gas shift reaction
CN101518737A (zh) * 2009-03-26 2009-09-02 上海大学 用于富氢燃气中水煤气反应变换一氧化碳的催化剂及其制备方法

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4402745A (en) * 1981-04-27 1983-09-06 Marko Materials, Inc. New iron-aluminum-copper alloys which contain boron and have been processed by rapid solidification process and method
US4590324A (en) * 1985-03-11 1986-05-20 Amoco Corporation Dehydrogenation of alkylaromatics
EP0296734A1 (en) * 1987-06-22 1988-12-28 Imperial Chemical Industries Plc Copper catalyst for carbon oxide conversion
WO2001074484A2 (en) * 2000-03-31 2001-10-11 The Regents Of The University Of Michigan Transition metal carbides, nitrides and borides and their oxygen containing analogs useful as water gas shift catalysts
WO2004043583A2 (en) * 2002-11-11 2004-05-27 Conocophillips Company Improved supports for high surface area catalysts
WO2008141827A1 (en) * 2007-05-23 2008-11-27 Saudi Basic Industries Corporation Process of oxidative dehydrogenation using a boria-alumina catalyst
EP2826561A1 (en) * 2012-03-13 2015-01-21 Benefuel Inc. Solid acid catalyst, method for manufacturing same, and method for manufacturing a fatty acid alkyl ester using same

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
CLIVE BARNETT: "HYDROGENATION OF ALIPHATIC NITRILES OVER TRANSITION METAL BORIDES", INDUSTRIAL AND ENGINEERING CHEMISTRY: PRODUCT RESEARCH AND DEVELOPMENT,, vol. 8, no. 2, June 1969 (1969-06-01), pages 145 - 149, XP001278811 *
See also references of WO2016145023A1 *

Also Published As

Publication number Publication date
CN107406252A (zh) 2017-11-28
EP3268307A1 (en) 2018-01-17

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