EP3137577B1 - Method for obtaining crude oil products - Google Patents

Method for obtaining crude oil products Download PDF

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Publication number
EP3137577B1
EP3137577B1 EP15717936.7A EP15717936A EP3137577B1 EP 3137577 B1 EP3137577 B1 EP 3137577B1 EP 15717936 A EP15717936 A EP 15717936A EP 3137577 B1 EP3137577 B1 EP 3137577B1
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Prior art keywords
stream
crude oil
quench
streams
distillation
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EP15717936.7A
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German (de)
French (fr)
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EP3137577A1 (en
Inventor
Heinz Zimmermann
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Linde GmbH
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Linde GmbH
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Priority claimed from DE102014006326.7A external-priority patent/DE102014006326A1/en
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    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G55/00Treatment of hydrocarbon oils, in the absence of hydrogen, by at least one refining process and at least one cracking process
    • C10G55/02Treatment of hydrocarbon oils, in the absence of hydrogen, by at least one refining process and at least one cracking process plural serial stages only
    • C10G55/04Treatment of hydrocarbon oils, in the absence of hydrogen, by at least one refining process and at least one cracking process plural serial stages only including at least one thermal cracking step
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G70/00Working-up undefined normally gaseous mixtures obtained by processes covered by groups C10G9/00, C10G11/00, C10G15/00, C10G47/00, C10G51/00
    • C10G70/04Working-up undefined normally gaseous mixtures obtained by processes covered by groups C10G9/00, C10G11/00, C10G15/00, C10G47/00, C10G51/00 by physical processes
    • C10G70/041Working-up undefined normally gaseous mixtures obtained by processes covered by groups C10G9/00, C10G11/00, C10G15/00, C10G47/00, C10G51/00 by physical processes by distillation
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G47/00Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G69/00Treatment of hydrocarbon oils by at least one hydrotreatment process and at least one other conversion process
    • C10G69/02Treatment of hydrocarbon oils by at least one hydrotreatment process and at least one other conversion process plural serial stages only
    • C10G69/06Treatment of hydrocarbon oils by at least one hydrotreatment process and at least one other conversion process plural serial stages only including at least one step of thermal cracking in the absence of hydrogen
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G9/00Thermal non-catalytic cracking, in the absence of hydrogen, of hydrocarbon oils
    • C10G9/002Cooling of cracked gases
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G9/00Thermal non-catalytic cracking, in the absence of hydrogen, of hydrocarbon oils
    • C10G9/34Thermal non-catalytic cracking, in the absence of hydrogen, of hydrocarbon oils by direct contact with inert preheated fluids, e.g. with molten metals or salts
    • C10G9/36Thermal non-catalytic cracking, in the absence of hydrogen, of hydrocarbon oils by direct contact with inert preheated fluids, e.g. with molten metals or salts with heated gases or vapours
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/40Characteristics of the process deviating from typical ways of processing
    • C10G2300/4006Temperature
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/40Characteristics of the process deviating from typical ways of processing
    • C10G2300/4012Pressure

Definitions

  • the invention relates to a process for the production of crude oil products.
  • Crude oil is first desalinated in known refinery processes and, after heating, subjected to fractional distillation at atmospheric pressure (hereinafter referred to as atmospheric distillation). The remaining so-called atmospheric residue is fed to a vacuum distillation.
  • atmospheric distillation fractional distillation at atmospheric pressure
  • the object of the invention is to improve corresponding methods and devices and in particular to increase the yield of high-grade crude oil products.
  • a steam cracking furnace is therefore a structural unit used for steam cracking in which identical or comparable reaction conditions are present.
  • a steam cracking plant may comprise one or more cracking furnaces.
  • a fission gas stream is understood here to mean a gaseous stream which is formed from the effluent of one or more cracking furnaces.
  • the cracked gas stream also referred to as cracker effluent
  • a quench cooler such as a transfer line exchanger (TLE) with cooling water and then in a second quenching step, i. Mix with a liquid hydrocarbon stream, cooled.
  • TLE transfer line exchanger
  • the first cooling step ie the cooling of the quenching gas with cooling water, for example in the quench cooler
  • quenching the cooling of the quenching gas with cooling water
  • the second cooling step may therefore also be referred to as oil quench for better distinctness.
  • quench effluent The stream formed by combining the cracked gas stream with the liquid stream used for quenching is referred to herein as quench effluent.
  • quench effluent comprises all of the liquid stream used for quenching and compounds derived from the cracked gas stream which are reduced at most by corresponding reaction products due to the quench.
  • the mass flow of the quench effluent corresponds to the sum of the mass flow of the liquid stream used for quenching and the mass flow of the cracked gas stream, It is therefore explicitly not the product of a separation or deposition process.
  • the quench effluent is present immediately after the union of the quench liquid stream and the split gas stream.
  • the invention proposes a process for recovering crude oil products in which a gaseous stream is formed by evaporation from a stream of crude oil and the gaseous stream is subjected at least in part to a steam cracking process.
  • a split gas flow is generated.
  • Corresponding methods are for example from US 2008/0221378 A1 and the WO 2010/117401 A1 known.
  • At least part of the gaseous stream formed during the evaporation of the crude oil may be supplied to one or more cracking furnaces alone or after being combined with one or more further streams, for example one or more recycle streams. If several cracking furnaces are present, they can also be charged with different currents. As is generally known, the charging of the cracking furnaces takes place in each case after the addition of water vapor.
  • the resulting cracked gas stream is at least partially quenched to give a quench effluent stream with a liquid hydrocarbon stream.
  • the present invention proposes to use a fraction of the crude oil stream which remains liquid during the evaporation of the crude oil stream, at least in part to form the liquid hydrocarbon stream used for quenching, wherein the liquid hydrocarbon stream used for quenching is poor or free of components which originate from the Quenchabstrom or a stream formed from the Quenchabstrom were separated. Further, the quench effluent is obtained by quenching with the liquid hydrocarbon stream at a temperature ranging from 0 to 250 ° C.
  • the liquid hydrocarbon stream used for quenching is not formed using a recycle stream and no quenching cycle is used as it is conventional method is known.
  • a quenching cycle of a conventional method for example, a so-called oil column with two sections arranged one above the other is used.
  • the quench oil is given up at the top of the lower section.
  • a lower portion of the lower portion of the cracked gas stream is fed and sent towards the Quenchöl.
  • the gap gas stream contained heavy compounds are dissolved or suspended in the quench oil and the gap gas stream is cooled simultaneously.
  • the quench oil with the optionally dissolved or suspended therein compounds is withdrawn from the bottom of the oil column, optionally treated, and returned to the head of the lower portion of the oil column again.
  • pyrolysis gasoline is abandoned, which is separated in a downstream water quench and also partially circulated.
  • the disadvantage of conventional quench circuits is the aging of the quench oil. Due to the frequent contacts with the hot cleavage gas stream, the initially low-viscosity compounds are polymerized and the formation of soot and tar or other tough, high-boiling compounds occurs. The quench oil must therefore be replaced regularly and replaced by fresh quench oil conventionally. The aged quench oil is practically worthless.
  • the liquid hydrocarbon stream used for quenching is poor in or free of components separated from the quench effluent or stream formed from the quench effluent, undergoing little or no aging because the products contained therein are not recycled Connections come into contact with the gap gas flow just once. This one-time contact does not lead to aging reactions and the corresponding compounds can be converted into product fractions which can still be used profitably.
  • the split gas stream exits the radiation zone of the cracking furnace (s) at a temperature of typically 750 to 875 ° C.
  • the collapsed gas stream should be cooled as quickly as possible to avoid further reaction of the compounds formed, for example polymer formation. If the above-mentioned linear coolers are used, they perform a considerable part of the cooling of the cracked gas stream.
  • the split gas flow occurs conventionally still with a temperature of about 230 ° C in the oil column and leaves it at a temperature of about 100 ° C. The majority of the heat is dissipated by the quench oil.
  • the temperature of the quenching gas is reduced from a temperature value in a first temperature range to a temperature value in a second temperature range, wherein the temperature value in the second temperature range is about 130 ° C lower than the temperature value in the first temperature range .
  • the temperature difference between the temperature values is significantly higher.
  • the current obtained is therefore still at a very high temperature, which requires a further quench before further processing.
  • the temperature of the quench gas in the prequench decreases from a temperature value in a first temperature range to a temperature value in a second temperature range, wherein the temperature value in the second temperature range is at most 111 ° C lower than the temperature value in the first temperature range.
  • the temperature value in the second temperature range is at least 649 ° C.
  • the quench effluent is obtained at a temperature which is in a temperature range of 0 to 250 ° C.
  • the temperature can be in particular in a temperature range of 50 to 200 ° C or from 50 to 150 ° C, ie at a temperature which is also achieved in a conventional oil column, and allows direct processing of Quenchabstroms.
  • the cracked gas stream before it is quenched with the liquid hydrocarbon stream, for example by means of a linear cooler, has already been cooled to a temperature which is 50 to 200 ° C, for example 100 to 150 ° C, above the temperature of Quenchabstr oms and, for example, corresponds to the typical inlet temperatures into an oil column in a conventional process.
  • the invention makes it possible in this particularly preferred embodiment to dispense with the use of further quench oil, in particular an oil circuit.
  • further quench oil in particular an oil circuit.
  • the Quenchabstrom contains a considerable proportion of finely divided oil droplets from the quenching liquid stream and heavy components (oils, tars and the like), it is first freed in conventional steam cracking process in a so-called oil column of corresponding components. Only downstream of the oil column, a corresponding stream of the known separation stages for recovering the hydrocarbon products from the cracking gas can be supplied.
  • the present invention is based on the idea of dispensing with a corresponding oil column and of further processing the quench effluent, for example as in conventional crude oil processing. This is possible because, by quenching with the remaining liquid in the evaporation of the crude oil stream, or a corresponding part thereof, in the Quenchabstrom only those (heavier) components are included, as they are found in conventional crude oil streams, the atmospheric distillation be subjected.
  • liquid hydrocarbon stream used for quenching only once for quenching.
  • a great advantage of the proposed method is therefore that no oil circuit is required for the quench, in which the oil (ie, the liquid hydrocarbon stream conventionally used for quenching) usually ages very much by chemical reactions, in particular significantly increases in viscosity, and thereby loses value. In the context of the present invention, such aging reactions do not play a role for the reasons explained.
  • Another advantage that results from not using an oil circuit is that, for example, the conventionally provided heat recovery from the cracking gas eliminated by consuming heat ashtray in the oil circuit and the heat can be fed via the Quenchabstrom directly another consumer. The heat can be used, for example, for (pre) heating the streams used in the atmospheric distillation. Also, the remaining in the evaporation of the crude oil stream liquid fraction can be cooled before use, with its heat can be transferred to other streams.
  • At least part of the quench effluent is used to form a separation insert, which is separated by distillation together with another stream of crude oil to obtain distillation effluents.
  • This distillative separation is advantageously carried out initially in a distillation column for fractional distillation at atmospheric distillation, as it is also used in a conventional refinery.
  • the atmospheric distillation may be followed by a vacuum distillation in a distillation column equipped therefor. All streams (cuts, fractions) formed in the distillation (for example, atmospheric distillation and / or vacuum distillation) are referred to herein as distillation effluents.
  • the separation insert may be formed from the quench effluent in any manner, but always contains hydrocarbons having one, two, three, four and more carbon atoms and / or hydrocarbons contained in the quench effluent, for example hydrocarbons formed by hydrogenation or further reactions after quenching. These are, for example, methane, ethane, ethylene, acetylene, propane, propylene and methylacetylene and saturated and unsaturated hydrocarbons having four carbon atoms.
  • the mentioned "education" of the separation insert for example, by separating a partial flow, combining with another stream or chemical and / or physical reacting done.
  • the separation insert advantageously contains hydrocarbons previously contained in the quench liquid hydrocarbon stream or compounds formed from such hydrocarbons. These are typically hydrocarbons with more than ten or 20 and for example up to 30 or more carbon atoms. Such hydrocarbons thus need not advantageously be separated from the Quenchabstrom but are supplied in accordance with an advantageous embodiment of the method, in particular unchanged a common distillative separation together with the second crude oil stream.
  • an embodiment is proposed in which a common distillative separation of the Quenchabstroms is made together with the second crude oil stream.
  • a full integration into a refinery is achieved, for example, by the Quenchabstrom is completely supplied to an atmospheric distillation in a correspondingly equipped distillation column together with the second crude oil stream.
  • the quench effluent together with the liquid hydrocarbon stream used for quenching can be transferred to a corresponding distillation column in which the usual crude oil fractions are recovered.
  • the compounds contained in the liquid hydrocarbon stream used for quenching pass into the respective fractions, for example the vacuum gas oil or the atmospheric gas oil, according to their boiling point. Separate separation of the compounds contained in the liquid hydrocarbon stream used for quenching in the manner of a conventional oil column is therefore not required.
  • a water quench is also eliminated since pyrolysis gasoline also passes into the corresponding fractions of the crude oil distillation, namely the gasoline fractions.
  • a separate compression of Quenchabstroms is also not required.
  • the method can therefore be realized with significantly lower expenditure on equipment than a method of the prior art, as for example in the US 2009/0050523 A1 and in which only heavy fractions separated from a cracked gas in a conventional manner are fed to a refinery process.
  • the method of the invention not obvious, because in the US 2009/0050523 A1 used Quenchöl- and pyrolysis gasoline cycle requires a separation of quench oil and pyrolysis gasoline. It is therefore not possible to transfer corresponding compounds in a quench effluent to a common separation with a second crude oil stream.
  • the same applies with respect to a method, as for example in the US 2007/0055087 A1 is shown.
  • the US 2010/0320119 A1 discloses a process in which a quench effluent is fed to a primary fraction to give different streams. Because the US 2010/0320119 A1 However, explicitly teaches to prepare a tar stream from the primary fractionation and use in a Quenchölniklauf, here prohibits the feed of a second crude oil stream in the primary fractionation, because this would make it impossible to obtain the tar stream through the additionally fed crude oil components.
  • the present invention proposes, in an advantageous embodiment, to process the separation insert formed using the Quenchabstroms, like conventional crude oil streams, first in an atmospheric distillation.
  • the products of the steam cracking process such as ethylene and other light hydrocarbons, pass into the top stream of the distillation column.
  • the classical sections of the crude oil stream (and the liquid stream used for quenching) can be produced in this distillation column.
  • the oil column conventionally used in a steam cracking process and the distillation column used for atmospheric distillation in a conventional refinery process are functionally combined.
  • the products of the steam cracking process withdrawn from the top or from the top of the atmospheric distillation column may be subjected, together with corresponding light products from the crude oil stream, if present, to the post-cracking gas separation steps usually following the oil column of a steam cracking process.
  • a water wash in which the naphtha which may possibly still be contained in a corresponding stream is deposited in liquid form.
  • hydrocarbons having one to four carbon atoms typically remain in the gas phase.
  • the resulting in the column for atmospheric distillation further distillation effluents are composed of heavier hydrocarbons, which originate mainly from the uncleaved crude oil or the liquid used for quenching. These are, for example, so-called atmospheric gas oil (English: Atmospheric Gas Oil, AGO) and the mentioned atmospheric residues.
  • atmospheric gas oil English: Atmospheric Gas Oil, AGO
  • the separation of the fractions provided as recycle streams can be carried out, for example, in the customary separation devices which are provided in the context of the present invention, similar to conventional steam-splitting processes. Separate separation of corresponding light fractions, as conventionally carried out in a refinery, can therefore be dispensed with. Such light fractions, because they can be fed to the steam cracking process as recycle streams, need not be stored in tanks as in conventional refinery plants. As also explained below, the compounds contained in corresponding streams can also be at least partially further implemented.
  • the measures according to the invention provide the advantage that it is possible to dispense with an oil column, and that no pyrolysis oil and no pyrolysis gasoline are produced as separate products.
  • the compounds which conventionally pass into the pyrolysis oil and the pyrolysis gasoline are found again in the use of the process according to the invention in the corresponding distillation effluents (for example from the atmospheric distillation and the vacuum distillation).
  • the process according to the invention can also be configured by recycling all distillation effluents which are not desired as products, such that production of typical refinery products such as gasoline, diesel, heating oil etc. no longer occurs.
  • the said components may be used, for example after appropriate treatment such as hydrotreats or (mild) hydrocracking, together or separately, as an insert for the steam cracking process.
  • appropriate treatment such as hydrotreats or (mild) hydrocracking
  • ethylene, propylene, butadiene, aromatics and high-pressure steam or electricity can be obtained from the crude oil used.
  • This variant proves to be extremely economical.
  • the method according to the invention can be flexibly adapted to the respective requirements of corresponding compounds.
  • the present invention further enables a particularly effective utilization of the waste heat generated in a steam cracking process.
  • This can first be used to preheat the crude oil stream, the vaporized portion of which is then subjected to the steam cracking process.
  • Further waste heat may, for example, also be used to heat the further stream of crude oil, which is then fed to the distillation column for atmospheric distillation.
  • the quench cooler can be integrated into a corresponding heat recovery circuit, for example, by steam generated there is used to heat the crude oil stream.
  • the separation by distillation of the separating insert formed using the Quenchabstroms together with the other crude oil is carried out, as explained, advantageously initially at atmospheric pressure and then in vacuo, so that recourse to known methods of refinery technology for distillation can be used and appropriate processes for the treatment of the distillation effluents can be used.
  • distillation effluents or streams derived therefrom may also be at least partially subjected to the steam cracking process.
  • diverted streams can be formed in each case by branching off a partial stream, combining with other streams, chemically or physically reacting at least some components in appropriate streams, heating, cooling, evaporating, condensing, etc.
  • corresponding derived streams can be formed by hydrocracking.
  • the distillation effluents if appropriate after prior further separation and / or treatment, are partially or fully catalytically hydrogenated and at least partially cracked.
  • undesired unsaturated hydrocarbons can be converted to saturated hydrocarbons and reacted again to form value products in the steam cracking process.
  • the recycled streams may in particular be hydrotreated and / or hydrocracked atmospheric gas oil (English: Atmospheric Gasoil, AGO) and treated by hydrotreatment and / or hydrocracked vacuum gas oil (Vacuum Gasoil, VGO), ie distillation residues from atmospheric distillation or Act vacuum distillation.
  • Suitable recycling streams are also unsaturated hydrocarbons having two to four carbon atoms and / or hydrocarbons having five to eight carbon atoms in question. Naphtha can also be used again in corresponding steam cracking processes.
  • a plant for recovering crude oil products which is adapted to form a gaseous stream from a crude oil stream by evaporation and to subject the gaseous stream at least in part to a steam cracking process, may be arranged such that in the steam cracking process, a cracked gas stream is generated at least in part to quench a Quenchabstroms with a liquid hydrocarbon stream can be quenched.
  • Means may be provided which are adapted to use, at least in part, a portion of the crude oil stream remaining on evaporation of the crude oil stream to form the liquid hydrocarbon stream used for quenching.
  • the quench liquid hydrocarbon stream is lean or free of components separated from the quench effluent or stream formed from the quench effluent stream. Further, the quench effluent is obtained by quenching with the liquid hydrocarbon stream at a temperature ranging from 0 to 250 ° C.
  • the plant comprises at least one distillation column adapted for fractional distillation at atmospheric pressure and means adapted to supply to said distillation column a separation insert formed using at least a portion of the quench effluent and another crude stream.
  • means are furthermore provided which are set up to at least partially subject the distillation effluents or streams derived therefrom formed in this distillation column to the steam cracking process.
  • FIG. 1 is a plant for the production of crude oil products shown schematically in a partial view and designated 100 in total.
  • the plant 100 supplied crude oil a is divided into two crude oil streams b and c.
  • the crude oil stream b is preheated in a convection zone of one or more cracking furnaces 1 and transferred to an evaporation tank 2.
  • a proportion of the crude oil stream b evaporating in the evaporation vessel 2 is conducted as stream d after mixing with steam through the radiation zone of the cracking furnace 1 or furnaces, a gap gas e being obtained.
  • the cracked gas e is cooled in a quench cooler 3 and then quenched in a quench device 4 with a portion of the crude oil stream b remaining liquid in the evaporation tank 2, here illustrated with stream f.
  • a separating insert formed from the quenching stream g (without a separate name) is transferred to a distillation column 5 for fractional atmospheric distillation, into which the crude oil stream c is also fed.
  • the distillation column 5 is operated in a conventional manner, so that in this example, an atmospheric residue h and an atmospheric gas oil i are obtained.
  • a stream k is withdrawn containing light products from the cracking furnace (s) 1 and the crude oil stream c.
  • a water scrubber 6 By mixing water (not shown) in a water scrubber 6, a water-naphtha mixture is separated from the stream k and transferred as stream I into a decanter 7. In this a water flow m and a naphtha flow n is obtained.
  • gaseous remaining fractions which are essentially hydrocarbons having one to four carbon atoms, are withdrawn as stream o and fed to a decomposition part, which may be formed in a known manner.
  • a decomposition part for example, first a separation of methane and / or methane and ethane can be carried out (so-called Demethanizer First or Deethanizer First method).
  • FIG. 2 is the plant 100 in an expanded view, ie as an enlarged section of an entire plant 100, illustrated and designated 200 in total.
  • a vacuum residue p is obtained from an atmospheric residue withdrawn as stream h from the distillation column 5 in a distillation column 8 equipped for vacuum distillation, which is fired in a device 9 and used to obtain energy, here indicated by arrow q can be.
  • a correspondingly processed stream s can be returned to the steam cracking process or into one or more cracking furnaces 1.
  • the atmospheric gas oil which can be treated in a hydrogenation unit 11 and subsequently recycled as stream t into the steam cracking process.
  • aromatics can be separated in an aromatic extraction unit 12 and carried out as stream v from the plant. A remaining portion may be re-subjected as stream w to the steam cracking process.
  • the already explained stream o which predominantly has hydrocarbons having one to four carbon atoms, can be converted into a C4 decomposition part 13, in which the product streams indicated here overall with x, for example ethylene, propylene and butadiene, can be separated off.
  • a methane stream y can be carried out from the plant and / or used for heating. Not obtained as product streams x Hydrocarbons can be recycled as stream z in the steam cracking process.

Description

Die Erfindung betrifft ein Verfahren zur Gewinnung von Rohölprodukten.The invention relates to a process for the production of crude oil products.

Stand der TechnikState of the art

Rohöl wird in bekannten Raffinerieverfahren zunächst entsalzt und nach Erwärmung einer fraktionierten Destillation bei Atmosphärendruck (nachfolgend als atmosphärische Destillation bezeichnet) unterworfen. Der verbleibende sogenannte atmosphärische Rückstand wird einer Vakuumdestillation zugeführt.Crude oil is first desalinated in known refinery processes and, after heating, subjected to fractional distillation at atmospheric pressure (hereinafter referred to as atmospheric distillation). The remaining so-called atmospheric residue is fed to a vacuum distillation.

Nicht sämtliche der bei der atmosphärischen Destillation und der Vakuumdestillation gewonnenen Fraktionen sind jedoch gewinnbringend nutzbar. Ein Teil der darin enthaltenen Verbindungen kann daher beispielsweise katalytisch umgesetzt und auf diese Weise aufgewertet werden. Dies gelingt jedoch nicht immer vollständig. Auch eine thermische Umsetzung von Rohölkomponenten durch Dampfspalten (engl. Steam Cracking) ist bekannt.However, not all of the fractions obtained in atmospheric distillation and vacuum distillation are profitable. A part of the compounds contained therein can therefore be catalytically converted, for example, and upgraded in this way. However, this does not always succeed completely. A thermal conversion of crude oil components by steam cracking (engl. Steam Cracking) is also known.

Die Erfindung stellt sich die Aufgabe, entsprechende Verfahren und Vorrichtungen zu verbessern und insbesondere die Ausbeute an hochwertigen Rohölprodukten zu erhöhen.The object of the invention is to improve corresponding methods and devices and in particular to increase the yield of high-grade crude oil products.

Offenbarung der ErfindungDisclosure of the invention

Diese Aufgabe wird durch ein Verfahren mit den Merkmalen des Patentanspruchs 1 gelöst. Ausgestaltungen sind Gegenstand der jeweiligen Unteransprüche sowie der nachfolgenden Beschreibung.This object is achieved by a method having the features of patent claim 1. Embodiments are the subject of the respective subclaims and the following description.

Zu den nachfolgend verwendeten Begriffen und zu technischen Details der eingesetzten Verfahren sei auf einschlägige Fachliteratur verwiesen (siehe beispielsweise Zimmermann, H. und Walzl, R.: Ethylene, In: Ullmann's Encyclopedia of Industrial Chemistry, Weinheim: Wiley-VCH, Onlinepublikation 2007, DOI: 10.1002/14356007.a10_045.pub2 , sowie Irion, W.W. und Neuwirth, O.S.: Oil Refining, In: Ullmann's Encyclopedia of Industrial Chemistry, Weinheim: Wiley-VCH, Onlinepublikation 2000, DOI: 10.1002/14356007.a18_051 ).Reference should be made to the relevant technical literature for the terms used below and technical details of the methods used (see, for example, US Pat Zimmermann, H. and Walzl, R .: Ethylene, In: Ullmann's Encyclopedia of Industrial Chemistry, Weinheim: Wiley-VCH, Online Publication 2007, DOI: 10.1002 / 14356007.a10_045.pub2 , such as Irion, WW and Neuwirth, OS: Oil Refining, In: Ullmann's Encyclopedia of Industrial Chemistry, Weinheim: Wiley-VCH, Online Publication 2000, DOI: 10.1002 / 14356007.a18_051 ).

Verfahren zum Dampfspalten (engl. Steam Cracking) werden in der Regel mittels Rohrreaktoren durchgeführt, deren Reaktionsrohre, die sogenannten Coils, einzeln oder gruppenweise unter gleichen oder unterschiedlichen Bedingungen betrieben werden können. Unter gleichen oder vergleichbaren Bedingungen betriebene Reaktionsrohre oder Gruppen von Reaktionsrohren, aber auch unter einheitlichen Bedingungen betriebene Rohrreaktoren insgesamt, werden nachfolgend jeweils als Spaltöfen bezeichnet. Ein Spaltofen ist im hier verwendeten Sprachgebrauch also eine zum Dampfspalten verwendete bauliche Einheit, in der gleiche oder vergleichbare Reaktionsbedingungen vorliegen. Eine Anlage zum Dampfspalten kann einen oder mehrere Spaltöfen umfassen.Steam cracking processes are generally carried out by means of tube reactors whose reaction tubes, the so-called coils, can be operated individually or in groups under the same or different conditions. Reaction tubes operated under identical or comparable conditions or groups of reaction tubes, but also tube reactors operated under uniform conditions, are referred to below as "cracking furnaces". In the language used here, a cracking furnace is therefore a structural unit used for steam cracking in which identical or comparable reaction conditions are present. A steam cracking plant may comprise one or more cracking furnaces.

Unter einem Spaltgasstrom wird hier ein gasförmiger Strom verstanden, der aus dem Abstrom eines oder mehrerer Spaltöfen gebildet wird. Der Spaltgasstrom (engl. auch als Cracker Effluent bezeichnet) wird in einem ersten Abkühlschritt typischerweise in einem Spaltgaskühler, beispielsweise einem Linearkühler (engl. Transfer Line Exchanger, TLE) mit Kühlwasser und anschließend in einem zweiten Abkühlschritt durch Quenchen, d.h. Mischen mit einem flüssigen Kohlenwasserstoffstrom, abgekühlt.A fission gas stream is understood here to mean a gaseous stream which is formed from the effluent of one or more cracking furnaces. The cracked gas stream (also referred to as cracker effluent) in a first cooling step is typically quenched in a quench cooler, such as a transfer line exchanger (TLE) with cooling water and then in a second quenching step, i. Mix with a liquid hydrocarbon stream, cooled.

In der Fachliteratur wird bisweilen auch der erste Abkühlschritt, d.h. die Abkühlung des Spaltgases mit Kühlwasser, beispielsweise in dem Spaltgaskühler, als Quenchen bezeichnet. In diesem ersten Abkühlschritt wird das Spaltgas jedoch nur indirekt abgekühlt und nicht, wie in dem zweiten Abkühlschritt, mit einem flüssigen Kohlenwasserstoffstrom vermischt. Der zweite Abkühlschritt kann der besseren Unterscheidbarkeit halber daher auch als Ölquench bezeichnet werden. Der durch die Vereinigung des Spaltgasstroms mit dem zum Quenchen verwendeten flüssigen Strom gebildete Strom wird hier als Quenchabstrom bezeichnet. Der "Quenchabstrom" umfasst sämtliche aus dem zum Quenchen verwendeten flüssigen Strom und aus dem Spaltgasstrom stammenden Verbindungen, die allenfalls um entsprechende Reaktionsprodukte aufgrund des Quenchs reduziert sind. Insbesondere entspricht der Massenstrom des Quenchabstroms der Summe aus dem Massenstrom des zum Quenchen verwendeten flüssigen Stroms und dem Massenstrom des Spaltgasstroms, er ist also explizit nicht das Produkt eines Trenn- oder Abscheidungsprozesses. Der Quenchabstrom liegt unmittelbar nach der Vereinigung des zum Quenchen verwendeten flüssigen Stroms und des Spaltgasstroms vor.In the literature sometimes the first cooling step, ie the cooling of the quenching gas with cooling water, for example in the quench cooler, is referred to as quenching. However, in this first cooling step, the cracked gas is only indirectly cooled and not mixed, as in the second cooling step, with a liquid hydrocarbon stream. The second cooling step may therefore also be referred to as oil quench for better distinctness. The stream formed by combining the cracked gas stream with the liquid stream used for quenching is referred to herein as quench effluent. The "quench effluent" comprises all of the liquid stream used for quenching and compounds derived from the cracked gas stream which are reduced at most by corresponding reaction products due to the quench. In particular, the mass flow of the quench effluent corresponds to the sum of the mass flow of the liquid stream used for quenching and the mass flow of the cracked gas stream, It is therefore explicitly not the product of a separation or deposition process. The quench effluent is present immediately after the union of the quench liquid stream and the split gas stream.

Vorteile der ErfindungAdvantages of the invention

Die Erfindung schlägt ein Verfahren zur Gewinnung von Rohölprodukten vor, bei dem aus einem Rohölstrom durch Verdampfen ein gasförmiger Strom gebildet und der gasförmige Strom zumindest zum Teil einem Dampfspaltverfahren unterworfen wird. In dem Dampfspaltverfahren wird ein Spaltgasstrom erzeugt. Entsprechende Verfahren sind beispielsweise aus der US 2008/0221378 A1 und der WO 2010/117401 A1 bekannt.The invention proposes a process for recovering crude oil products in which a gaseous stream is formed by evaporation from a stream of crude oil and the gaseous stream is subjected at least in part to a steam cracking process. In the steam cracking process, a split gas flow is generated. Corresponding methods are for example from US 2008/0221378 A1 and the WO 2010/117401 A1 known.

Im Rahmen der vorliegenden Erfindung kann zumindest ein Teil des bei der Verdampfung des Rohöls gebildeten gasförmigen Stroms alleine oder nach Vereinigung mit einem oder mehreren weiteren Strömen, beispielsweise einem oder mehreren Recycleströmen, einem oder mehreren Spaltöfen zugeführt werden. Sind mehrere Spaltöfen vorhanden, können diese auch mit unterschiedlichen Strömen beschickt werden. Wie allgemein bekannt, erfolgt die Beschickung der Spaltöfen dabei jeweils nach Zugabe von Wasserdampf.In the context of the present invention, at least part of the gaseous stream formed during the evaporation of the crude oil may be supplied to one or more cracking furnaces alone or after being combined with one or more further streams, for example one or more recycle streams. If several cracking furnaces are present, they can also be charged with different currents. As is generally known, the charging of the cracking furnaces takes place in each case after the addition of water vapor.

Der erhaltene Spaltgasstrom wird zumindest zum Teil unter Erhalt eines Quenchabstroms mit einem flüssigen Kohlenwasserstoffstrom gequencht. Die vorliegende Erfindung schlägt dabei vor, einen bei dem Verdampfen des Rohölstroms flüssig verbleibenden Anteil des Rohölstroms zumindest zum Teil zur Bildung des zum Quenchen eingesetzten flüssigen Kohlenwasserstoffstroms zu verwenden, wobei der zum Quenchen eingesetzte flüssige Kohlenwasserstoffstrom arm an oder frei von Komponenten ist, die aus dem Quenchabstrom oder einem aus dem Quenchabstrom gebildeten Strom abgetrennt wurden. Ferner wird der Quenchabstrom durch das Quenchen mit dem flüssigen Kohlenwasserstoffstrom bei einer Temperatur erhalten, die in einem Temperaturbereich von 0 bis 250 °C liegt.The resulting cracked gas stream is at least partially quenched to give a quench effluent stream with a liquid hydrocarbon stream. The present invention proposes to use a fraction of the crude oil stream which remains liquid during the evaporation of the crude oil stream, at least in part to form the liquid hydrocarbon stream used for quenching, wherein the liquid hydrocarbon stream used for quenching is poor or free of components which originate from the Quenchabstrom or a stream formed from the Quenchabstrom were separated. Further, the quench effluent is obtained by quenching with the liquid hydrocarbon stream at a temperature ranging from 0 to 250 ° C.

Mit anderen Worten wird im Rahmen der vorliegenden Erfindung der zum Quenchen verwendete flüssige Kohlenwasserstoffstrom nicht unter Verwendung eines Recyclestroms gebildet und es kommt kein Quenchkreislauf zum Einsatz, wie er aus herkömmlichen Verfahren bekannt ist. In einem Quenchkreislauf eines herkömmlichen Verfahrens wird beispielsweise eine sogenannte Ölsäule mit zwei übereinander angeordneten Abschnitten eingesetzt. Das Quenchöl wird am Kopf des unteren Abschnitts aufgegeben. In einen unteren Bereich des unteren Abschnitts wird der Spaltgasstrom eingespeist und dem Quenchöl entgegengeschickt. In dem Spaltgasstrom enthaltene schwere Verbindungen werden dabei in dem Quenchöl gelöst oder suspendiert und der Spaltgasstrom wird gleichzeitig abgekühlt. Das Quenchöl mit den darin ggf. gelösten oder suspendierten Verbindungen wird aus dem Sumpf der Ölsäule abgezogen, ggf. aufbereitet, und erneut zum Kopf des unteren Abschnitts der Ölsäule zurückgeführt. In einem oberen Bereich der Ölsäule wird Pyrolysebenzin aufgegeben, das in einem nachgeschalteten Wasserquench abgetrennt und ebenfalls teilweise im Kreis gefahren wird.In other words, in the present invention, the liquid hydrocarbon stream used for quenching is not formed using a recycle stream and no quenching cycle is used as it is conventional method is known. In a quenching cycle of a conventional method, for example, a so-called oil column with two sections arranged one above the other is used. The quench oil is given up at the top of the lower section. In a lower portion of the lower portion of the cracked gas stream is fed and sent towards the Quenchöl. In the gap gas stream contained heavy compounds are dissolved or suspended in the quench oil and the gap gas stream is cooled simultaneously. The quench oil with the optionally dissolved or suspended therein compounds is withdrawn from the bottom of the oil column, optionally treated, and returned to the head of the lower portion of the oil column again. In an upper region of the oil column pyrolysis gasoline is abandoned, which is separated in a downstream water quench and also partially circulated.

Nachteilig an herkömmlichen Quenchkreisläufen ist jedoch die Alterung des Quenchöls. Aufgrund der häufigen Kontakte mit dem heißen Spaltgasstrom werden die zunächst niedrig viskosen Verbindungen polymerisiert und es kommt zur Bildung von Ruß und Teer bzw. anderer zäher, schwersiedender Verbindungen. Das Quenchöl muss daher herkömmlicherweise regelmäßig ausgetauscht und durch frisches Quenchöl ersetzt werden. Das gealterte Quenchöl ist praktisch wertlos. Im Gegensatz dazu ist der zum Quenchen verwendete flüssige Kohlenwasserstoffstrom dadurch, dass er arm an oder frei von Komponenten ist, die aus dem Quenchabstrom oder einem aus dem Quenchabstrom gebildeten Strom abgetrennt wurden, kaum oder keinen Alterungsprozessen unterworfen, weil die in ihm enthaltenen, nicht recycelten Verbindungen nur genau einmal mit dem Spaltgasstrom in Kontakt kommen. Durch diesen einmaligen Kontakt kommt es nicht zu Alterungsreaktionen und die entsprechenden Verbindungen können in Produktfraktionen überführt werden, die sich noch gewinnbringend nutzen lassen.However, the disadvantage of conventional quench circuits is the aging of the quench oil. Due to the frequent contacts with the hot cleavage gas stream, the initially low-viscosity compounds are polymerized and the formation of soot and tar or other tough, high-boiling compounds occurs. The quench oil must therefore be replaced regularly and replaced by fresh quench oil conventionally. The aged quench oil is practically worthless. In contrast, the liquid hydrocarbon stream used for quenching is poor in or free of components separated from the quench effluent or stream formed from the quench effluent, undergoing little or no aging because the products contained therein are not recycled Connections come into contact with the gap gas flow just once. This one-time contact does not lead to aging reactions and the corresponding compounds can be converted into product fractions which can still be used profitably.

Der Spaltgasstrom verlässt die Strahlungszone des oder der Spaltöfen bei einer Temperatur von typischerweise 750 bis 875 °C. Der S paltgasstrom sollte zur Vermeidung einer Weiterreaktion der gebildeten Verbindungen, beispielsweise einer Polymerbildung, so rasch wie möglich abgekühlt werden. Werden die eingangs erwähnten Linearkühler eingesetzt, führen diese einen beträchtlichen Teil der Abkühlung des Spaltgasstroms durch. Wie in dem eingangs zitierten Artikel " Ethylene" in Ullmann's Encyclopedia of Industrial Chemistry erwähnt , tritt der Spaltgasstrom herkömmlicherweise noch mit einer Temperatur von ca. 230 °C in die Ölsäule ein und verlässt diese bei einer Temperatur von ca. 100 °C. Der überwiegende Anteil der Wärme wird dabei durch das Quenchöl abgeführt. Beim Einsatz eines entsprechenden herkömmlichen Ölquenchs wird also die Temperatur des Spaltgases von einem Temperaturwert in einem ersten Temperaturbereich auf einen Temperaturwert in einem zweiten Temperaturbereich verringert, wobei der Temperaturwert in dem zweiten Temperaturbereich um ca. 130 °C niedriger liegt als der Temperaturwert in dem ersten Temperaturbereich. Bei Verfahren ohne Einsatz eines Linearkühlers ist der Temperaturunterschied zwischen den Temperaturwerten deutlich höher.The split gas stream exits the radiation zone of the cracking furnace (s) at a temperature of typically 750 to 875 ° C. The collapsed gas stream should be cooled as quickly as possible to avoid further reaction of the compounds formed, for example polymer formation. If the above-mentioned linear coolers are used, they perform a considerable part of the cooling of the cracked gas stream. As in the article cited above " Ethylene "in Ullmann's Encyclopedia of Industrial Chemistry , the split gas flow occurs conventionally still with a temperature of about 230 ° C in the oil column and leaves it at a temperature of about 100 ° C. The majority of the heat is dissipated by the quench oil. When using a corresponding conventional oil quench so the temperature of the quenching gas is reduced from a temperature value in a first temperature range to a temperature value in a second temperature range, wherein the temperature value in the second temperature range is about 130 ° C lower than the temperature value in the first temperature range , In processes without the use of a linear cooler, the temperature difference between the temperature values is significantly higher.

Aus der US 2008/0221378 A1 ist ein Verfahren bekannt, bei dem ein nicht verdampfter Anteil eines Rohölstroms für einen Vorquench eines Spaltgasstroms verwendet wird, der durch Dampfspalten eines verdampften Anteils des Rohölstroms erhalten wurde. Der Vorquench wird vorgenommen, um in dem nicht verdampften Anteil enthaltene, aber noch spaltbare Komponenten durch die Wärme des Spaltgasstroms zu spalten. Die Zugabe des nicht verdampften Anteils zu dem Spaltgasstroms im Rahmen des Vorquenchs erfolgt daher bei noch hoher Temperatur des Spaltgasstroms, typischerweise bei 760 bis 929°C. Gleichzeitig wird durch den Vorquench die Temperatur des Spaltgasstroms nur geringfügig reduziert, nämlich um typischerweise nicht mehr als 111 °C. Stromab des Vorquenchs liegt der erhaltene Strom daher bei noch sehr hoher Temperatur vor, die vor der Weiterverarbeitung einen weiteren Quench erforderlich macht. Mit anderen Worten wird also in dem Verfahren gemäß der US 2008/0221378 A1 die Temperatur des Spaltgases bei dem Vorquench von einem Temperaturwert in einem ersten Temperaturbereich auf einen Temperaturwert in einem zweiten Temperaturbereich verringert, wobei der Temperaturwert in dem zweiten Temperaturbereich um höchstens 111 °C niedriger liegt als der Temperaturwert in dem ersten Temperaturbereich. Der Temperaturwert in dem zweiten Temperaturbereich liegt dabei bei mindestens 649 °C.From the US 2008/0221378 A1 For example, a method is known in which an unvaporized portion of a crude oil stream is used for a pre-quench of a cracked gas stream obtained by steam cracking a vaporized portion of the crude oil stream. The pre-quench is made to cleave, but still cleavable components contained in the non-evaporated portion by the heat of the cracked gas stream. The addition of the unevaporated fraction to the cracked gas stream in the course of the pre-quenching therefore takes place at a still high temperature of the cracked gas stream, typically at 760 to 929 ° C. At the same time, the pre-quench reduces the temperature of the cracked gas stream only slightly, namely by typically not more than 111 ° C. Downstream of the pre-quenching, the current obtained is therefore still at a very high temperature, which requires a further quench before further processing. In other words, in the method according to the US 2008/0221378 A1 the temperature of the quench gas in the prequench decreases from a temperature value in a first temperature range to a temperature value in a second temperature range, wherein the temperature value in the second temperature range is at most 111 ° C lower than the temperature value in the first temperature range. The temperature value in the second temperature range is at least 649 ° C.

Im Gegensatz dazu wird durch das erfindungsgemäße Quenchen mit dem flüssigen Kohlenwasserstoffstrom der Quenchabstrom, wie erwähnt, bei einer Temperatur erhalten, die in einem Temperaturbereich von 0 bis 250 °C liegt. Die Temperatur kann insbesondere in einem Temperaturbereich von 50 bis 200 °C oder von 50 bis 150 °C liegen, also bei einer Temperatur, die auch in einer herkömmlichen Ölsäule erzielt wird, und die eine direkte Weiterverarbeitung des Quenchabstroms ermöglicht.In contrast, by quenching with the liquid hydrocarbon stream according to the invention, the quench effluent, as mentioned, is obtained at a temperature which is in a temperature range of 0 to 250 ° C. The temperature can be in particular in a temperature range of 50 to 200 ° C or from 50 to 150 ° C, ie at a temperature which is also achieved in a conventional oil column, and allows direct processing of Quenchabstroms.

Vorteilhafterweise ist in diesem Fall der Spaltgasstrom, bevor er mit dem flüssigen Kohlenwasserstoffstrom gequencht wird, beispielsweise mittels eines Linearkühlers, bereits auf eine Temperatur abgekühlt worden, die 50 bis 200 °C, beispielsweise 100 bis 150 °C, oberhalb der Temperatur des Quenchabstr oms liegt und beispielsweise der typischen Eintrittstemperaturen in eine Ölsäule in einem herkömmlichen Verfahren entspricht. Die Erfindung ermöglicht es in dieser besonders bevorzugten Ausführungsform, auf die Verwendung weiteren Quenchöls, insbesondere einen Ölkreislauf, zu verzichten. Hierzu besteht ausgehend von der US 2008/0221378 A1 kein Anlass, denn diese lehrt, dass eine hohe Temperatur des Spaltgasstroms erforderlich ist, um in dem nicht verdampften Anteil des Rohölstroms enthaltene Verbindungen zu spalten. Durch einen einfachen Quench auf niedrige Temperaturen mittels dieses nicht verdampften Anteils würden jedoch entsprechende Spaltungsreaktionen zum Stillstand gebracht und eine nennenswerte Spaltausbeute wäre nicht erzielbar. Daher ist hier zwingend auch eine hohe Temperatur des Abstroms des Vorquenchs, und damit ein weiterer Quench in Form eines Ölkreislaufs, erforderlich.Advantageously, in this case, the cracked gas stream, before it is quenched with the liquid hydrocarbon stream, for example by means of a linear cooler, has already been cooled to a temperature which is 50 to 200 ° C, for example 100 to 150 ° C, above the temperature of Quenchabstr oms and, for example, corresponds to the typical inlet temperatures into an oil column in a conventional process. The invention makes it possible in this particularly preferred embodiment to dispense with the use of further quench oil, in particular an oil circuit. For this purpose, starting from the US 2008/0221378 A1 no reason, because it teaches that a high temperature of the cracked gas stream is required to crack compounds contained in the unevaporated portion of the crude oil stream. However, by a simple quench to low temperatures by means of this non-vaporized portion, corresponding cleavage reactions would be halted and a significant gap yield would not be achievable. Therefore, a high temperature of the effluent of the pre-quenching, and thus another quench in the form of an oil circuit, is mandatory here.

Da der Quenchabstrom einen beträchtlichen Anteil fein verteilter Öltröpfchen aus dem zum Quenchen verwendeten flüssigen Strom und schwer siedende Komponenten (Öle, Teere und dergleichen) enthält, wird er in herkömmlichen Dampfspaltverfahren zunächst in einer sogenannten Ölsäule von entsprechenden Komponenten befreit. Erst stromab der Ölsäule kann ein entsprechender Strom den bekannten Trennstufen zur Gewinnung der Kohlenwasserstoffprodukte aus dem Spaltgas zugeführt werden.Since the Quenchabstrom contains a considerable proportion of finely divided oil droplets from the quenching liquid stream and heavy components (oils, tars and the like), it is first freed in conventional steam cracking process in a so-called oil column of corresponding components. Only downstream of the oil column, a corresponding stream of the known separation stages for recovering the hydrocarbon products from the cracking gas can be supplied.

Die vorliegende Erfindung beruht nun auf der Idee, auf eine entsprechende Ölsäule zu verzichten und den Quenchabstrom beispielsweise wie in der herkömmlichen Rohölverarbeitung auch weiter zu verarbeiten. Dies ist möglich, weil durch das Quenchen mit dem bei der Verdampfung des Rohölstroms flüssig verbleibenden Anteil, oder einem entsprechenden Teil hiervon, in dem Quenchabstrom nur solche (schwereren) Komponenten enthalten sind, wie sie sich auch in herkömmlichen Rohölströmen wiederfinden, die der atmosphärischen Destillation unterworfen werden.The present invention is based on the idea of dispensing with a corresponding oil column and of further processing the quench effluent, for example as in conventional crude oil processing. This is possible because, by quenching with the remaining liquid in the evaporation of the crude oil stream, or a corresponding part thereof, in the Quenchabstrom only those (heavier) components are included, as they are found in conventional crude oil streams, the atmospheric distillation be subjected.

Im Gegensatz zu herkömmlichen Verfahren, in denen ein Quenchölkreislauf vorgesehen ist, wird im Rahmen der vorliegenden Erfindung also der zum Quenchen verwendete flüssige Kohlenwasserstoffstrom nur einmal zum Quenchen verwendet.In contrast to conventional methods in which a Quenchölkreislauf is provided, so used in the present invention, the liquid hydrocarbon stream used for quenching only once for quenching.

Ein großer Vorteil des vorgeschlagenen Verfahrens besteht daher darin, dass für den Quench kein Ölkreislauf benötigt wird, in dem das Öl (also der herkömmlicherweise für das Quenchen verwendete flüssige Kohlenwasserstoffstrom) durch chemische Reaktionen üblicherweise sehr stark altert, insbesondere deutlich an Viskosität zunimmt, und dadurch stark an Wert verliert. Im Rahmen der vorliegenden Erfindung spielen solche Alterungsreaktionen aus den erläuterten Gründen keine Rolle. Ein weiterer Vorteil, der sich aus dem Verzicht auf einen Ölkreislauf ergibt, ist der, dass beispielsweise die herkömmlicherweise vorgesehene Wärmerückgewinnung aus dem Spaltgas durch aufwendige Wärmetascher im Ölkreislauf entfällt und die Wärme über den Quenchabstrom direkt einem anderen Verbraucher zugeführt werden kann. Die Wärme kann beispielsweise zum (Vor-)Heizen der in der atmosphärischen Destillation eingesetzten Ströme verwendet werden. Auch der bei der Verdampfung des Rohölstroms verbleibende flüssige Anteil kann vor seiner Verwendung abgekühlt werden, wobei seine Wärme auch auf andere Ströme übertragen werden kann.A great advantage of the proposed method is therefore that no oil circuit is required for the quench, in which the oil (ie, the liquid hydrocarbon stream conventionally used for quenching) usually ages very much by chemical reactions, in particular significantly increases in viscosity, and thereby loses value. In the context of the present invention, such aging reactions do not play a role for the reasons explained. Another advantage that results from not using an oil circuit, is that, for example, the conventionally provided heat recovery from the cracking gas eliminated by consuming heat ashtray in the oil circuit and the heat can be fed via the Quenchabstrom directly another consumer. The heat can be used, for example, for (pre) heating the streams used in the atmospheric distillation. Also, the remaining in the evaporation of the crude oil stream liquid fraction can be cooled before use, with its heat can be transferred to other streams.

Mit besonderem Vorteil wird daher im Rahmen der vorliegenden Erfindung zumindest ein Teil des Quenchabstroms zur Bildung eines Trenneinsatzes verwendet, der zusammen mit einem weiteren Rohölstrom unter Erhalt von Destillationsabströmen destillativ aufgetrennt wird. Diese destillative Auftrennung erfolgt vorteilhafterweise zunächst in einer zur fraktionierten Destillation bei Atmosphärendruck eingerichteten Destillationssäule, wie sie auch in einer herkömmlichen Raffinerieanlage verwendet wird. Der atmosphärischen Destillation kann sich eine Vakuumdestillation in einer hierfür eingerichteten Destillationssäule anschließen. Alle bei der Destillation (beispielsweise der atmosphärischen Destillation und/oder der Vakuumdestillation) gebildeten Ströme (Schnitte, Fraktionen) werden hier als Destillationsabströme bezeichnet.With particular advantage, therefore, in the context of the present invention, at least part of the quench effluent is used to form a separation insert, which is separated by distillation together with another stream of crude oil to obtain distillation effluents. This distillative separation is advantageously carried out initially in a distillation column for fractional distillation at atmospheric distillation, as it is also used in a conventional refinery. The atmospheric distillation may be followed by a vacuum distillation in a distillation column equipped therefor. All streams (cuts, fractions) formed in the distillation (for example, atmospheric distillation and / or vacuum distillation) are referred to herein as distillation effluents.

Der Trenneinsatz kann aus dem Quenchabstrom auf beliebige Weise gebildet werden, enthält jedoch immer in dem Quenchabstrom enthaltene Kohlenwasserstoffe mit einem, zwei, drei, vier und mehr Kohlenstoffatomen und/oder aus derartigen Kohlenwasserstoffen, beispielsweise durch Hydrieren oder Weiterreaktionen nach dem Quenchen gebildete Kohlenwasserstoffe. Es handelt sich hierbei beispielsweise um Methan, Ethan, Ethylen, Acetylen, Propan, Propylen und Methylacetylen und um gesättigte und ungesättigte Kohlenwasserstoffe mit vier Kohlenstoffatomen. Die angesprochene "Bildung" des Trenneinsatzes kann beispielsweise durch Abtrennen eines Teilstroms, Vereinigen mit einem weiteren Strom oder chemisches und/oder physikalisches Umsetzen erfolgen.The separation insert may be formed from the quench effluent in any manner, but always contains hydrocarbons having one, two, three, four and more carbon atoms and / or hydrocarbons contained in the quench effluent, for example hydrocarbons formed by hydrogenation or further reactions after quenching. These are, for example, methane, ethane, ethylene, acetylene, propane, propylene and methylacetylene and saturated and unsaturated hydrocarbons having four carbon atoms. The mentioned "education" of the separation insert, for example, by separating a partial flow, combining with another stream or chemical and / or physical reacting done.

Ferner enthält der Trenneinsatz vorteilhafterweise Kohlenwasserstoffe, die zuvor in dem zum Quenchen verwendeten flüssigen Kohlenwasserstoffstrom enthalten waren, oder aus solchen Kohlenwasserstoffen gebildete Verbindungen. Hierbei handelt es sich typischerweise um Kohlenwasserstoffe mit mehr als zehn oder 20 und beispielsweise bis zu 30 oder mehr Kohlenstoffatomen. Derartige Kohlenwasserstoffe brauchen also vorteilhafterweise nicht aus dem Quenchabstrom abgetrennt zu werden sondern werden gemäß einer vorteilhaften Ausgestaltung des Verfahrens insbesondere unverändert einer gemeinsamen destillativen Trennung zusammen mit dem zweiten Rohölstrom zugeführt.Further, the separation insert advantageously contains hydrocarbons previously contained in the quench liquid hydrocarbon stream or compounds formed from such hydrocarbons. These are typically hydrocarbons with more than ten or 20 and for example up to 30 or more carbon atoms. Such hydrocarbons thus need not advantageously be separated from the Quenchabstrom but are supplied in accordance with an advantageous embodiment of the method, in particular unchanged a common distillative separation together with the second crude oil stream.

Mit anderen Worten wird eine Ausführungsform vorgeschlagen, in der eine gemeinsame destillative Trennung des Quenchabstroms zusammen mit dem zweiten Rohölstrom vorgenommen wird. Hierdurch wird, wie auch nachfolgend erläutert, eine Vollintegration in eine Raffinerie erzielt, beispielsweise indem der Quenchabstrom vollständig einer atmosphärischen Destillation in einer entsprechend eingerichteten Destillationssäule zusammen mit dem zweiten Rohölstrom zugeführt wird. Dies ermöglicht es, auf separate Abtrenneinrichtungen für Kohlenwasserstoffe in dem Dampfspaltstrom bzw. dem Quenchabstrom zu verzichten. Beispielsweise kann der Quenchabstrom zusammen mit dem zum Quenchen verwendeten flüssigen Kohlenwasserstoffstrom in eine entsprechende Destillationssäule überführt werden, in der die üblichen Rohölfraktionen gewonnen werden. Die in dem zum Quenchen verwendeten flüssigen Kohlenwasserstoffstrom enthaltenen Verbindungen gehen entsprechend ihrem Siedepunkt in die jeweiligen Fraktionen, beispielsweise das Vakuumgasöl oder das atmosphärische Gasöl, über. Eine separate Abtrennung der in dem zum Quenchen verwendeten flüssigen Kohlenwasserstoffstrom enthaltenen Verbindungen nach Art einer herkömmlichen Ölsäule ist damit nicht erforderlich. Auch ein Wasserquench entfällt, da Pyrolysebenzin ebenfalls in die entsprechenden Fraktionen der Rohöldestillation übergeht, nämlich die Benzinfraktionen. Eine separate Verdichtung des Quenchabstroms ist ebenfalls nicht erforderlich.In other words, an embodiment is proposed in which a common distillative separation of the Quenchabstroms is made together with the second crude oil stream. As a result, as explained below, a full integration into a refinery is achieved, for example, by the Quenchabstrom is completely supplied to an atmospheric distillation in a correspondingly equipped distillation column together with the second crude oil stream. This makes it possible to dispense with separate separation means for hydrocarbons in the steam gap stream or the Quenchabstrom. For example, the quench effluent together with the liquid hydrocarbon stream used for quenching can be transferred to a corresponding distillation column in which the usual crude oil fractions are recovered. The compounds contained in the liquid hydrocarbon stream used for quenching pass into the respective fractions, for example the vacuum gas oil or the atmospheric gas oil, according to their boiling point. Separate separation of the compounds contained in the liquid hydrocarbon stream used for quenching in the manner of a conventional oil column is therefore not required. A water quench is also eliminated since pyrolysis gasoline also passes into the corresponding fractions of the crude oil distillation, namely the gasoline fractions. A separate compression of Quenchabstroms is also not required.

Das Verfahren lässt sich daher mit deutlich geringerem apparativem Aufwand verwirklichen als ein Verfahren des Standes der Technik, wie es beispielsweise in der US 2009/0050523 A1 beschrieben ist, und bei dem lediglich in herkömmlicher Weise aus einem Spaltgas abgetrennte schwere Fraktionen einem Raffinerieprozess zugeführt werden. Ausgehend von der US 2009/0050523 A1 ist das erfindungsgemäße Verfahren nicht naheliegend, denn der in der US 2009/0050523 A1 verwendete Quenchöl- und Pyrolysebenzinkreislauf erfordert eine Abtrennung von Quenchöl und Pyrolysebenzin. Entsprechende Verbindungen in einem Quenchabstrom in eine gemeinsame Trennung mit einem zweiten Rohölstrom zu überführen verbietet sich daher hier. Entsprechendes gilt auch bezüglich eines Verfahrens, wie es beispielsweise in der US 2007/0055087 A1 gezeigt ist. Die US 2010/0320119 A1 offenbart ein Verfahren, bei dem ein Quenchabstrom einer Primärfraktionierung unter Erhalt unterschiedlicher Ströme zugeführt wird. Da die US 2010/0320119 A1 jedoch explizit lehrt, einen Teerstrom aus der Primärfraktionierung aufzubereiten und in einem Quenchölkreislauf einzusetzen, verbietet sich hier die Einspeisung eines zweiten Rohölstroms in die Primärfraktionierung, denn dieser würde die Gewinnung des Teerstroms durch die zusätzlich eingespeisten Rohölkomponenten unmöglich machen.The method can therefore be realized with significantly lower expenditure on equipment than a method of the prior art, as for example in the US 2009/0050523 A1 and in which only heavy fractions separated from a cracked gas in a conventional manner are fed to a refinery process. Starting from the US 2009/0050523 A1 is the method of the invention not obvious, because in the US 2009/0050523 A1 used Quenchöl- and pyrolysis gasoline cycle requires a separation of quench oil and pyrolysis gasoline. It is therefore not possible to transfer corresponding compounds in a quench effluent to a common separation with a second crude oil stream. The same applies with respect to a method, as for example in the US 2007/0055087 A1 is shown. The US 2010/0320119 A1 discloses a process in which a quench effluent is fed to a primary fraction to give different streams. Because the US 2010/0320119 A1 However, explicitly teaches to prepare a tar stream from the primary fractionation and use in a Quenchölkreislauf, here prohibits the feed of a second crude oil stream in the primary fractionation, because this would make it impossible to obtain the tar stream through the additionally fed crude oil components.

Mit anderen Worten schlägt die vorliegende Erfindung in einer vorteilhaften Ausgestaltung vor, den unter Verwendung des Quenchabstroms gebildeten Trenneinsatz, wie herkömmliche Rohölströme auch, zunächst in einer atmosphärischen Destillation zu bearbeiten. Bei der atmosphärischen Destillation gehen die Produkte des Dampfspaltverfahrens, beispielsweise Ethylen und andere leichte Kohlenwasserstoffe, in den Kopfstrom der Destillationssäule über. Gleichzeitig können in dieser Destillationssäule die klassischen Schnitte des Rohölstroms (und des zum Quenchen verwendeten flüssigen Stroms) erzeugt werden.In other words, the present invention proposes, in an advantageous embodiment, to process the separation insert formed using the Quenchabstroms, like conventional crude oil streams, first in an atmospheric distillation. In atmospheric distillation, the products of the steam cracking process, such as ethylene and other light hydrocarbons, pass into the top stream of the distillation column. At the same time, the classical sections of the crude oil stream (and the liquid stream used for quenching) can be produced in this distillation column.

Im Rahmen dieser bevorzugten Ausführungsform der vorliegenden Erfindung werden also die herkömmlicherweise in einem Dampfspaltverfahren eingesetzte Ölsäule und die in einem herkömmlichen Raffinerieprozess eingesetzte Destillationssäule zur atmosphärischen Destillation funktionell zusammengelegt. Die vom Kopf oder aus einem oberen Bereich der Säule zur atmosphärischen Destillation abgezogenen Produkte des Dampfspaltverfahrens können zusammen mit entsprechenden leichten Produkten aus dem Rohölstrom, soweit vorhanden, den üblicherweise der Ölsäule eines Dampfspaltverfahrens nachgeschalteten Schritten zur Aufbereitung des Spaltgases unterworfen werden.In the context of this preferred embodiment of the present invention, therefore, the oil column conventionally used in a steam cracking process and the distillation column used for atmospheric distillation in a conventional refinery process are functionally combined. The products of the steam cracking process withdrawn from the top or from the top of the atmospheric distillation column may be subjected, together with corresponding light products from the crude oil stream, if present, to the post-cracking gas separation steps usually following the oil column of a steam cracking process.

Beispielsweise kann hierbei zunächst eine Wasserwäsche eingesetzt werden, in der das in einem entsprechenden Strom ggf. noch enthaltene Naphtha in flüssiger Form abgeschieden wird. Nach der Wasserwäsche verbleiben typischerweise Kohlenwasserstoffe mit einem bis vier Kohlenstoffatomen in der Gasphase. Diese können anschließend bekannten Trennsequenzen (Demethanizer First, Deethanizer First usw.; zu Details sei auf die zitierte Fachliteratur verwiesen) unterworfen werden.For example, in this case, first of all a water wash can be used, in which the naphtha which may possibly still be contained in a corresponding stream is deposited in liquid form. After washing with water, hydrocarbons having one to four carbon atoms typically remain in the gas phase. These can then be subjected to known separation sequences (Demethanizer First, Deethanizer First, etc., for details, see the cited technical literature).

Die in der Säule zur atmosphärischen Destillation anfallenden weiteren Destillationsabströme setzen sich aus schwereren Kohlenwasserstoffen zusammen, die überwiegend aus dem ungespaltenen Rohöl bzw. dem zum Quenchen verwendeten flüssigen Strom stammen. Hierbei handelt es sich beispielsweise um sogenanntes atmosphärisches Gasöl (engl. Atmospheric Gas Oil, AGO) und die erwähnten atmosphärischen Rückstände.The resulting in the column for atmospheric distillation further distillation effluents are composed of heavier hydrocarbons, which originate mainly from the uncleaved crude oil or the liquid used for quenching. These are, for example, so-called atmospheric gas oil (English: Atmospheric Gas Oil, AGO) and the mentioned atmospheric residues.

Weitere Vorteile können erzielt werden, wenn bestimmte, beispielsweise in dem Spaltgas oder in dem weiteren Rohölstrom enthaltene, Kohlenwasserstoffe erneut dem Dampfspaltverfahren unterworfen werden. Derartige, dem Dampfspaltverfahren erneut unterworfene Ströme werden als Recycleströme bezeichnet. Recycleströme können vereinigt und gemeinsam oder getrennt voneinander, ggf. zusammen mit Frischeinsätzen, gleichen oder unterschiedlichen Spaltöfen zugeführt werden. Als Frischeinsatz wird im Rahmen der vorliegenden Erfindung der bereits erläuterte, bei der Verdampfung des Rohölstroms gebildete gasförmige Strom eingesetzt, es können jedoch auch andere, von der Anlagengrenze zugeführte Ströme eingesetzt werden.Further advantages can be achieved if certain hydrocarbons, for example contained in the cracked gas or in the further crude oil stream, are again subjected to the steam cracking process. Such streams subjected to the steam cracking process are referred to as recycle streams. Recycled streams can be combined and fed together or separately, possibly together with fresh inserts, identical or different cracking furnaces. As a fresh use of the present invention, the already explained, formed in the evaporation of the crude oil stream gaseous stream is used, but it can also be used other, supplied from the plant boundary streams.

Die Abtrennung der als Recycleströme vorgesehenen Fraktionen kann beispielsweise in den üblichen Trenneinrichtungen, die im Rahmen der vorliegenden Erfindung ähnlich wie in herkömmlichen Dampfspaltverfahren vorgesehen sind, erfolgen. Auf eine separate Abtrennung entsprechender leichter Anteile, wie sie herkömmlicherweise in einer Raffinerie erfolgt, kann daher verzichtet werden. Derartige leichte Anteile müssen, weil sie dem Dampfspaltverfahren als Recycleströme zugeführt werden können, nicht wie in herkömmlichen Raffinerieanlagen in Tanks gespeichert werden. Wie auch nachfolgend noch erläutert, können die in entsprechenden Strömen enthaltenen Verbindungen auch zumindest teilweise weiter umgesetzt werden.The separation of the fractions provided as recycle streams can be carried out, for example, in the customary separation devices which are provided in the context of the present invention, similar to conventional steam-splitting processes. Separate separation of corresponding light fractions, as conventionally carried out in a refinery, can therefore be dispensed with. Such light fractions, because they can be fed to the steam cracking process as recycle streams, need not be stored in tanks as in conventional refinery plants. As also explained below, the compounds contained in corresponding streams can also be at least partially further implemented.

Insgesamt ergibt sich durch die erfindungsgemäßen Maßnahmen der Vorteil, dass auf eine Ölsäule verzichtet werden kann, und dass kein Pyrolyseöl und kein Pyrolysebenzin als separate Produkte anfallen. Die herkömmlicherweise in das Pyrolyseöl und das Pyrolysebenzin übergehenden Verbindungen finden sich beim Einsatz des erfindungsgemäßen Verfahrens in den entsprechenden Destillationsabströmen (beispielsweise aus der atmosphärischen Destillation und der Vakuumdestillation) wieder.Overall, the measures according to the invention provide the advantage that it is possible to dispense with an oil column, and that no pyrolysis oil and no pyrolysis gasoline are produced as separate products. The compounds which conventionally pass into the pyrolysis oil and the pyrolysis gasoline are found again in the use of the process according to the invention in the corresponding distillation effluents (for example from the atmospheric distillation and the vacuum distillation).

Das erfindungsgemäße Verfahren kann durch die Rückführung aller nicht als Produkte erwünschter Destillationsabströme auch derart ausgestaltet werden, dass es nicht mehr zur Produktion typischer Raffinerieprodukte wie Benzin, Diesel, Heizöl etc. kommt. Die genannten Komponenten können, beispielsweise nach entsprechender Behandlung wie Hydrotreaten oder (mildem) Hydrocracken, gemeinsam oder getrennt voneinander, als Einsatz für das Dampfspaltverfahren verwendet werden. In einem solchen Fall können aus dem eingesetzten Rohöl beispielsweise ausschließlich Ethylen, Propylen, Butadien, Aromaten und Hochdruckdampf bzw. Elektrizität gewonnen werden. Diese Variante erweist sich als ausgesprochen wirtschaftlich. Das erfindungsgemäße Verfahren kann flexibel an den jeweiligen Bedarf entsprechender Verbindungen angepasst werden.The process according to the invention can also be configured by recycling all distillation effluents which are not desired as products, such that production of typical refinery products such as gasoline, diesel, heating oil etc. no longer occurs. The said components may be used, for example after appropriate treatment such as hydrotreats or (mild) hydrocracking, together or separately, as an insert for the steam cracking process. In such a case, for example, exclusively ethylene, propylene, butadiene, aromatics and high-pressure steam or electricity can be obtained from the crude oil used. This variant proves to be extremely economical. The method according to the invention can be flexibly adapted to the respective requirements of corresponding compounds.

Die vorliegende Erfindung ermöglicht ferner eine besonders effektive Nutzung der in einem Dampfspaltverfahren erzeugten Abwärme. Diese kann zunächst zum Vorwärmen des Rohölstroms verwendet werden, dessen verdampfter Anteil anschließend dem Dampfspaltverfahren unterworfen wird. Weitere Abwärme kann beispielsweise auch zum Erwärmen des weiteren Rohölstroms verwendet werden, der anschließend in die Destillationssäule zur atmosphärischen Destillation eingespeist wird. Insgesamt ergeben sich damit eine vorteilhafte Energieintegration und eine Verringerung der abzuführenden Abwärme. Auch der Spaltgaskühler kann in einen entsprechenden Wärmerückgewinnungskreislauf eingebunden werden, indem beispielsweise dort erzeugter Dampf zur Beheizung des Rohölstroms verwendet wird.The present invention further enables a particularly effective utilization of the waste heat generated in a steam cracking process. This can first be used to preheat the crude oil stream, the vaporized portion of which is then subjected to the steam cracking process. Further waste heat may, for example, also be used to heat the further stream of crude oil, which is then fed to the distillation column for atmospheric distillation. Overall, this results in an advantageous energy integration and a reduction in the dissipated waste heat. Also, the quench cooler can be integrated into a corresponding heat recovery circuit, for example, by steam generated there is used to heat the crude oil stream.

Die destillative Auftrennung des unter Verwendung des Quenchabstroms gebildeten Trenneinsatzes zusammen mit dem weiteren Rohölstrom erfolgt, wie erläutert, vorteilhafterweise zunächst bei Atmosphärendruck und anschließend im Vakuum, so dass zur Destillation auf bekannte Verfahren der Raffinerietechnik zurückgegriffen werden kann und entsprechende Verfahren zur Behandlung der Destillationsabströme weiter genutzt werden können.The separation by distillation of the separating insert formed using the Quenchabstroms together with the other crude oil is carried out, as explained, advantageously initially at atmospheric pressure and then in vacuo, so that recourse to known methods of refinery technology for distillation can be used and appropriate processes for the treatment of the distillation effluents can be used.

Wie bereits erwähnt, können die Destillationsabströme oder hiervon abgeleitete Ströme zumindest zum Teil ebenfalls dem Dampfspaltverfahren unterworfen werden. Abgeleitete Ströme können dabei beispielsweise jeweils durch Abzweigen eines Teilstroms, Vereinigen mit anderen Strömen, chemisches oder physikalisches Umsetzen zumindest einiger Komponenten in entsprechenden Strömen, Erwärmen, Abkühlen, Verdampfen, Kondensieren usw. gebildet werden.As already mentioned, the distillation effluents or streams derived therefrom may also be at least partially subjected to the steam cracking process. In each case, diverted streams can be formed in each case by branching off a partial stream, combining with other streams, chemically or physically reacting at least some components in appropriate streams, heating, cooling, evaporating, condensing, etc.

Mit besonderem Vorteil können entsprechende abgeleitete Ströme durch Hydrocrackverfahren gebildet werden. In derartigen Verfahren werden die Destillationsabströme, gegebenenfalls nach vorheriger weiterer Auftrennung und/oder Aufbereitung, teilweise oder vollständig katalytisch hydriert und zumindest teilweise gecrackt. Auf diese Weise können als Ofeneinsätze unerwünschte ungesättigte Kohlenwasserstoffe zu gesättigten Kohlenwasserstoffen umgewandelt und erneut unter Bildung von Wertprodukten in dem Dampfspaltverfahren umgesetzt werden.With particular advantage corresponding derived streams can be formed by hydrocracking. In such processes, the distillation effluents, if appropriate after prior further separation and / or treatment, are partially or fully catalytically hydrogenated and at least partially cracked. In this way, as furnace inserts, undesired unsaturated hydrocarbons can be converted to saturated hydrocarbons and reacted again to form value products in the steam cracking process.

Bei den Recycleströmen kann es sich insbesondere um durch Hydrotreatment und/oder Hydrocracken behandeltes atmosphärisches Gasöl (engl. Atmospheric Gasoil, AGO) und um durch Hydrotreatment und/oder Hydrocracken behandeltes Vakuumgasöl (Vacuum Gasoil, VGO), also Destillationsrückstände aus der atmosphärischen Destillation oder der Vakuumdestillation handeln. Als Recycleströme kommen ferner ungesättigte Kohlenwasserstoffe mit zwei bis vier Kohlenstoffatomen und/oder Kohlenwasserstoffe mit fünf bis acht Kohlenstoffatomen in Frage. Auch Naphtha kann in entsprechenden Dampfspaltverfahren erneut eingesetzt werden.The recycled streams may in particular be hydrotreated and / or hydrocracked atmospheric gas oil (English: Atmospheric Gasoil, AGO) and treated by hydrotreatment and / or hydrocracked vacuum gas oil (Vacuum Gasoil, VGO), ie distillation residues from atmospheric distillation or Act vacuum distillation. Suitable recycling streams are also unsaturated hydrocarbons having two to four carbon atoms and / or hydrocarbons having five to eight carbon atoms in question. Naphtha can also be used again in corresponding steam cracking processes.

In der destillativen Auftrennung nachgeschalteten Trennstufen, denen Kohlenwasserstoffe mit zwei bis vier Kohlenstoffatomen unterworfen werden, können beispielsweise Verbindungen wie Methan, Ethylen, Propylen, Butadien und/oder Aromaten (Benzol, Toluol und/oder Xylole, zusammengefasst auch als BTX bezeichnet) gewonnen und aus der Anlage ausgeführt werden. Der in der Vakuumdestillation anfallende und nicht weiter nutzbare Vakuumrückstand und/oder das gebildete Methan können zur Energiegewinnung verfeuert werden.In the distillation separation downstream separation stages, which are subjected to hydrocarbons having two to four carbon atoms, for example, compounds such as methane, ethylene, propylene, butadiene and / or aromatics (benzene, toluene and / or xylenes, collectively referred to as BTX) recovered and from the system are running. The vacuum residue obtained in the vacuum distillation and which can no longer be used and / or the methane formed can be burned to produce energy.

Eine Anlage zur Gewinnung von Rohölprodukten, die dafür eingerichtet ist, aus einem Rohölstrom durch Verdampfen einen gasförmigen Strom zu bilden und den gasförmigen Strom zumindest zu einem Teil einen Dampfspaltverfahren zu unterwerfen, kann derart eingerichtet sein, dass in dem Dampfspaltverfahren ein Spaltgasstrom erzeugt wird, der zumindest zum Teil unter Erhalt eines Quenchabstroms mit einem flüssigen Kohlenwasserstoffstrom gequencht werden kann. Es können Mittel vorgesehen sein, die dafür eingerichtet sind, einen bei dem Verdampfen des Rohölstroms flüssig verbleibenden Anteil des Rohölstroms zumindest zum Teil zur Bildung des zum Quenchen verwendeten flüssigen Kohlenwasserstoffstroms zu verwenden. Der zum Quenchen verwendete flüssige Kohlenwasserstoffstrom ist arm an oder frei von Komponenten, die aus dem Quenchabstrom oder einem aus dem Quenchabstrom gebildeten Strom abgetrennt wurden. Ferner wird der Quenchabstrom durch das Quenchen mit dem flüssigen Kohlenwasserstoffstrom bei einer Temperatur erhalten, die in einem Temperaturbereich von 0 bis 250 °C liegt.A plant for recovering crude oil products, which is adapted to form a gaseous stream from a crude oil stream by evaporation and to subject the gaseous stream at least in part to a steam cracking process, may be arranged such that in the steam cracking process, a cracked gas stream is generated at least in part to quench a Quenchabstroms with a liquid hydrocarbon stream can be quenched. Means may be provided which are adapted to use, at least in part, a portion of the crude oil stream remaining on evaporation of the crude oil stream to form the liquid hydrocarbon stream used for quenching. The quench liquid hydrocarbon stream is lean or free of components separated from the quench effluent or stream formed from the quench effluent stream. Further, the quench effluent is obtained by quenching with the liquid hydrocarbon stream at a temperature ranging from 0 to 250 ° C.

Eine derartige Anlage weist sämtliche Mittel auf, die sie zur Durchführung eines erfindungsgemäßen Verfahrens befähigen. Vorteilhafterweise umfasst dieAnlage zumindest eine zur fraktionierten Destillation bei Atmosphärendruck eingerichtete Destillationssäule und Mittel, die dafür eingerichtet sind, dieser Destillationssäule einen unter Verwendung zumindest eines Teils des Quenchabstroms gebildeten Trenneinsatz und einen weiteren Rohölstrom zuzuführen.Such a system has all the means that enable it to carry out a method according to the invention. Advantageously, the plant comprises at least one distillation column adapted for fractional distillation at atmospheric pressure and means adapted to supply to said distillation column a separation insert formed using at least a portion of the quench effluent and another crude stream.

Vorteilhafterweise sind ferner Mittel vorgesehen, die dafür eingerichtet sind, in dieser Destillationssäule gebildete Destillationsabströme oder hiervon abgeleitete Ströme zumindest zum Teil ebenfalls dem Dampfspaltverfahren zu unterwerfen.Advantageously, means are furthermore provided which are set up to at least partially subject the distillation effluents or streams derived therefrom formed in this distillation column to the steam cracking process.

Die Erfindung wird unter Bezugnahme auf die beigefügten Zeichnungen näher erläutert, welche bevorzugte Ausführungsformen der Erfindung zeigen.The invention will be explained in more detail with reference to the accompanying drawings, which show preferred embodiments of the invention.

Kurze Beschreibung der Zeichnungen

Figur 1
zeigt eine Anlage zur Gewinnung von Rohölprodukten in Teilansicht.
Figur 2
zeigt eine Anlage zur Gewinnung von Rohölprodukten in erweiterter Ansicht.
Brief description of the drawings
FIG. 1
shows a plant for the production of crude oil products in partial view.
FIG. 2
shows a plant for the extraction of crude oil products in an expanded view.

In den Figuren sind einander entsprechende Elemente mit identischen Bezugszeichen angegeben und werden nicht wiederholt erläutert. Die jeweils gezeigten Anlagenkomponenten entsprechen gleichzeitig Schritten eines Verfahrens.In the figures, corresponding elements are given identical reference numerals and will not be explained repeatedly. The plant components shown correspond to the same steps of a process.

Ausführungsformen der ErfindungEmbodiments of the invention

In Figur 1 ist eine Anlage zur Gewinnung von Rohölprodukten schematisch in einer Teilansicht dargestellt und insgesamt mit 100 bezeichnet.In FIG. 1 is a plant for the production of crude oil products shown schematically in a partial view and designated 100 in total.

Der Anlage 100 zugeführtes Rohöl a wird in zwei Rohölströme b und c aufgeteilt. Der Rohölstrom b wird in einer Konvektionszone eines oder mehrerer Spaltöfen 1 vorgewärmt und in einen Verdampfungsbehälter 2 überführt. Ein in dem Verdampfungsbehälter 2 verdampfender Anteil des Rohölstroms b wird als Strom d nach Vermischung mit Dampf durch die Strahlungszone des oder der Spaltöfen 1 geführt, wobei ein Spaltgas e erhalten wird.The plant 100 supplied crude oil a is divided into two crude oil streams b and c. The crude oil stream b is preheated in a convection zone of one or more cracking furnaces 1 and transferred to an evaporation tank 2. A proportion of the crude oil stream b evaporating in the evaporation vessel 2 is conducted as stream d after mixing with steam through the radiation zone of the cracking furnace 1 or furnaces, a gap gas e being obtained.

Das Spaltgas e wird in einem Spaltgaskühler 3 gekühlt und anschließend in einer Quencheinrichtung 4 mit einem in dem Verdampfungsbehälter 2 flüssig verbliebenen Anteil des Rohölstroms b, hier mit Strom f veranschaulicht, gequencht. Ein aus dem Quenchabstrom g gebildeter Trenneinsatz (ohne gesonderte Bezeichnung) wird in eine Destillationssäule 5 zur fraktionierten atmosphärischen Destillation überführt, in die auch der Rohölstrom c eingespeist wird.The cracked gas e is cooled in a quench cooler 3 and then quenched in a quench device 4 with a portion of the crude oil stream b remaining liquid in the evaporation tank 2, here illustrated with stream f. A separating insert formed from the quenching stream g (without a separate name) is transferred to a distillation column 5 for fractional atmospheric distillation, into which the crude oil stream c is also fed.

Die Destillationssäule 5 wird in üblicher Weise betrieben, so dass in dieser beispielsweise ein atmosphärischer Rückstand h und ein atmosphärisches Gasöl i erhalten werden. Vom Kopf oder aus einem oberen Bereich der Destillationssäule 5 wird ein Strom k abgezogen, der leichte Produkte aus dem oder den Spaltöfen 1 und dem Rohölstrom c enthält. Durch Beimischen von Wasser (nicht gezeigt) in einem Wasserwäscher 6 wird ein Wasser-Naphtha-Gemisch aus dem Strom k abgeschieden und als Strom I in einen Dekanter 7 überführt. In diesem wird ein Wasserstrom m und ein Naphthastrom n erhalten.The distillation column 5 is operated in a conventional manner, so that in this example, an atmospheric residue h and an atmospheric gas oil i are obtained. From the top of or from an upper portion of the distillation column 5, a stream k is withdrawn containing light products from the cracking furnace (s) 1 and the crude oil stream c. By mixing water (not shown) in a water scrubber 6, a water-naphtha mixture is separated from the stream k and transferred as stream I into a decanter 7. In this a water flow m and a naphtha flow n is obtained.

In dem Wasserwäscher 6 gasförmig verbleibende Anteile, bei denen es sich im wesentlichen um Kohlenwasserstoffe mit einem bis vier Kohlenstoffatomen handelt, werden als Strom o abgezogen und einem Zerlegungsteil zugeführt, der in bekannter Weise ausgebildet sein kann. In einem entsprechenden Zerlegungsteil kann beispielsweise zunächst eine Abtrennung vom Methan und/oder von Methan und Ethan erfolgen (sogenannte Demethanizer First oder Deethanizer First-Verfahren).In the water scrubber 6 gaseous remaining fractions, which are essentially hydrocarbons having one to four carbon atoms, are withdrawn as stream o and fed to a decomposition part, which may be formed in a known manner. In a corresponding decomposition part, for example, first a separation of methane and / or methane and ethane can be carried out (so-called Demethanizer First or Deethanizer First method).

In Figur 2 ist die Anlage 100 in erweiterter Ansicht, d.h. als erweiterter Ausschnitt einer Gesamtanlage 100, veranschaulicht und insgesamt mit 200 bezeichnet. Der in der Figur 1 gezeigte Anlagenteil, also zumindest ein Spaltofen 1 mit den zugehörigen Einrichtungen 2 bis 4 und eine zur fraktionierten atmosphärischen Destillation eingerichtete Destillationssäule 5 mit einem Wasserwäscher 6 und einem zugehörigen Dekanter 7, ist mit 100 bezeichnet.In FIG. 2 is the plant 100 in an expanded view, ie as an enlarged section of an entire plant 100, illustrated and designated 200 in total. The Indian FIG. 1 Plant part shown, so at least one cracking furnace 1 with the associated facilities 2 to 4 and furnished for fractional atmospheric distillation distillation column 5 with a water scrubber 6 and an associated decanter 7, designated 100.

Wie in Figur 2 veranschaulicht, wird aus einem atmosphärischen Rückstand, der als Strom h aus der Destillationssäule 5 abgezogen wird, in einer zur Vakuumdestillation eingerichteten Destillationssäule 8 ein Vakuumrückstand p erhalten, der in einer Einrichtung 9 verfeuert und zur Gewinnung von Energie, hier mit Pfeil q veranschaulicht, verwendet werden kann.As in FIG. 2 1, a vacuum residue p is obtained from an atmospheric residue withdrawn as stream h from the distillation column 5 in a distillation column 8 equipped for vacuum distillation, which is fired in a device 9 and used to obtain energy, here indicated by arrow q can be.

Ein Kopfstrom r aus der Destillationssäule 8, sogenanntes Vakuumgasöl, wird in eine Hydriereinheit 10 überführt, wo der Strom r beispielsweise durch Hydrocracken bearbeitet werden kann. Ein entsprechend bearbeiteter Strom s kann in das Dampfspaltverfahren bzw. in einen oder mehrere Spaltöfen 1 zurückgeführt werden. Entsprechendes gilt auch für den oben erläuterten Strom i, das atmosphärische Gasöl, der in einer Hydriereinheit 11 behandelt und anschließend als Strom t in das Dampfspaltverfahren zurückgeführt werden kann. Aus einem Strom u, der im wesentlichen Kohlenwasserstoffe mit fünf bis acht Kohlenstoffatomen enthält, können in einer Aromatenextraktionseinheit 12 Aromaten abgetrennt und als Strom v aus der Anlage ausgeführt werden. Ein verbleibender Anteil kann als Strom w dem Dampfspaltverfahren erneut unterworfen werden. Der bereits erläuterte Strom o, der überwiegend Kohlenwasserstoffe mit einem bis vier Kohlenstoffatomen aufweist, kann in einen C4-Zerlegungsteil 13 überführt werden, in welchem die hier insgesamt mit x angegebenen Produktströme, beispielsweise Ethylen, Propylen und Butadien, abgetrennt werden können. Ein Methanstrom y kann aus der Anlage ausgeführt und/oder zur Beheizung verwendet werden. Nicht als Produktströme x gewonnene Kohlenwasserstoffe können als Strom z in das Dampfspaltverfahren zurückgeführt werden.A top stream r from the distillation column 8, so-called vacuum gas oil, is transferred to a hydrogenation unit 10, where the stream r can be processed by hydrocracking, for example. A correspondingly processed stream s can be returned to the steam cracking process or into one or more cracking furnaces 1. The same applies to the above-explained stream i, the atmospheric gas oil, which can be treated in a hydrogenation unit 11 and subsequently recycled as stream t into the steam cracking process. From a stream u, which contains substantially hydrocarbons having five to eight carbon atoms, aromatics can be separated in an aromatic extraction unit 12 and carried out as stream v from the plant. A remaining portion may be re-subjected as stream w to the steam cracking process. The already explained stream o, which predominantly has hydrocarbons having one to four carbon atoms, can be converted into a C4 decomposition part 13, in which the product streams indicated here overall with x, for example ethylene, propylene and butadiene, can be separated off. A methane stream y can be carried out from the plant and / or used for heating. Not obtained as product streams x Hydrocarbons can be recycled as stream z in the steam cracking process.

Claims (8)

  1. Process for obtaining crude oil products, in which a gaseous stream (d) is formed by evaporation (2) from a crude oil stream (b) and the gaseous stream (d) is at least partly subjected to a steamcracking process (1), wherein the steamcracking process (1) produces a cracking gas stream (e) which is at least partly quenched with a liquid hydrocarbon stream (f) to obtain a quench output stream (g), characterized in that a proportion (f) that remains in liquid form in the evaporation (2) of the crude oil stream (b) is at least partly used to form the liquid hydrocarbon stream (f) used for quenching, wherein the liquid hydrocarbon stream used for quenching has a low level of or is free of components that have been separated from the quench output stream (g) or a stream formed from the quench output stream (g) and the quench output stream (g) is obtained by quenching with the liquid hydrocarbon stream (f) at a temperature lying in a temperature range of from 0 to 250°C.
  2. Process according to Claim 1, in which a separation feed is formed from at least a portion of the quench output stream (g) and is distillatively separated (5, 8) together with a further crude oil stream (c) to obtain distillation output streams (h, i, k, p, r).
  3. Process according to Claim 2, in which the distillation output streams (h, i, k, p, r) or streams derived therefrom (s, t, w, z) are subjected to the steamcracking process (1) at least partly as recycle streams.
  4. Process according to either of Claims 2 and 3, in which the distillative separation (5, 8) of the separation feed together with the further crude oil stream (c) is effected first at atmospheric pressure (5) and then under reduced pressure (8).
  5. Process according to Claim 3 or 4, in which streams (s, t) derived from at least a portion of the distillation output streams (i, r) at least by catalytic hydrogenation (10, 11) are formed.
  6. Process according to any of Claims 3 to 5, in which atmospheric gas oil (i) treated by catalytic hydrogenation (11), catalytic hydrogenation-treated vacuum gas oil (r), saturated hydrocarbons having two to four carbon atoms (z) and/or hydrocarbons having five to eight carbon atoms (w) are used as recycle streams.
  7. Process according to any of Claims 2 to 6, in which methane, ethylene, propylene and/or butadiene (x) and/or aromatic compounds (v) are obtained.
  8. Process according to any of Claims 2 to 7, in which at least a portion of the distillation output streams (p, y) is burned for energy generation.
EP15717936.7A 2014-04-30 2015-04-28 Method for obtaining crude oil products Active EP3137577B1 (en)

Applications Claiming Priority (3)

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DE102014006326.7A DE102014006326A1 (en) 2014-04-30 2014-04-30 Process and plant for the extraction of crude oil products
EP14003149 2014-09-11
PCT/EP2015/059249 WO2015165920A1 (en) 2014-04-30 2015-04-28 Process and system for obtaining crude oil products

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EP3137577A1 EP3137577A1 (en) 2017-03-08
EP3137577B1 true EP3137577B1 (en) 2018-06-20

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JP (1) JP2017516892A (en)
KR (1) KR20160146767A (en)
CN (1) CN106414672B (en)
AU (1) AU2015254694A1 (en)
BR (1) BR112016025289A2 (en)
HU (1) HUE039685T2 (en)
PH (1) PH12016501983A1 (en)
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CN1847365A (en) * 2005-04-14 2006-10-18 高忠武 Still catalytically cracking process of producing light fuel oil with heavy oil
US7374664B2 (en) 2005-09-02 2008-05-20 Equistar Chemicals, Lp Olefin production utilizing whole crude oil feedstock
US7563357B2 (en) * 2007-01-26 2009-07-21 Exxonmobil Chemical Patents Inc. Process for cracking synthetic crude oil-containing feedstock
US8118996B2 (en) * 2007-03-09 2012-02-21 Exxonmobil Chemical Patents Inc. Apparatus and process for cracking hydrocarbonaceous feed utilizing a pre-quenching oil containing crackable components
US20090050523A1 (en) 2007-08-20 2009-02-26 Halsey Richard B Olefin production utilizing whole crude oil/condensate feedstock and selective hydrocracking
WO2010117402A1 (en) * 2009-03-31 2010-10-14 Equistar Chemicals, Lp Processing of organic acids containing hydrocarbons
US8105479B2 (en) 2009-06-18 2012-01-31 Exxonmobil Chemical Patents Inc. Process and apparatus for upgrading steam cracker tar-containing effluent using steam

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AU2015254694A1 (en) 2016-11-10
US20170051213A1 (en) 2017-02-23
HUE039685T2 (en) 2019-01-28
BR112016025289A2 (en) 2017-08-15
CN106414672B (en) 2018-06-22
PH12016501983A1 (en) 2016-12-19
EP3137577A1 (en) 2017-03-08
KR20160146767A (en) 2016-12-21
JP2017516892A (en) 2017-06-22
RU2016143914A (en) 2018-05-30
US9994781B2 (en) 2018-06-12
CN106414672A (en) 2017-02-15
RU2016143914A3 (en) 2018-10-15
ZA201607160B (en) 2018-05-30
WO2015165920A1 (en) 2015-11-05

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