EP3102503B1 - Cartridge and method for producing a cartridge - Google Patents

Cartridge and method for producing a cartridge Download PDF

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Publication number
EP3102503B1
EP3102503B1 EP15712136.9A EP15712136A EP3102503B1 EP 3102503 B1 EP3102503 B1 EP 3102503B1 EP 15712136 A EP15712136 A EP 15712136A EP 3102503 B1 EP3102503 B1 EP 3102503B1
Authority
EP
European Patent Office
Prior art keywords
cartridge
head part
reception chamber
wall
medium
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
EP15712136.9A
Other languages
German (de)
French (fr)
Other versions
EP3102503A1 (en
Inventor
Hayden Turner
Victor Clemens
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Medmix Switzerland AG
Original Assignee
Sulzer Mixpac AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Sulzer Mixpac AG filed Critical Sulzer Mixpac AG
Priority to PL15712136T priority Critical patent/PL3102503T3/en
Publication of EP3102503A1 publication Critical patent/EP3102503A1/en
Application granted granted Critical
Publication of EP3102503B1 publication Critical patent/EP3102503B1/en
Active legal-status Critical Current
Anticipated expiration legal-status Critical

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Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05CAPPARATUS FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05C17/00Hand tools or apparatus using hand held tools, for applying liquids or other fluent materials to, for spreading applied liquids or other fluent materials on, or for partially removing applied liquids or other fluent materials from, surfaces
    • B05C17/005Hand tools or apparatus using hand held tools, for applying liquids or other fluent materials to, for spreading applied liquids or other fluent materials on, or for partially removing applied liquids or other fluent materials from, surfaces for discharging material from a reservoir or container located in or on the hand tool through an outlet orifice by pressure without using surface contacting members like pads or brushes
    • B05C17/00553Hand tools or apparatus using hand held tools, for applying liquids or other fluent materials to, for spreading applied liquids or other fluent materials on, or for partially removing applied liquids or other fluent materials from, surfaces for discharging material from a reservoir or container located in or on the hand tool through an outlet orifice by pressure without using surface contacting members like pads or brushes with means allowing the stock of material to consist of at least two different components
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05CAPPARATUS FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05C17/00Hand tools or apparatus using hand held tools, for applying liquids or other fluent materials to, for spreading applied liquids or other fluent materials on, or for partially removing applied liquids or other fluent materials from, surfaces
    • B05C17/005Hand tools or apparatus using hand held tools, for applying liquids or other fluent materials to, for spreading applied liquids or other fluent materials on, or for partially removing applied liquids or other fluent materials from, surfaces for discharging material from a reservoir or container located in or on the hand tool through an outlet orifice by pressure without using surface contacting members like pads or brushes
    • B05C17/01Hand tools or apparatus using hand held tools, for applying liquids or other fluent materials to, for spreading applied liquids or other fluent materials on, or for partially removing applied liquids or other fluent materials from, surfaces for discharging material from a reservoir or container located in or on the hand tool through an outlet orifice by pressure without using surface contacting members like pads or brushes with manually mechanically or electrically actuated piston or the like
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05CAPPARATUS FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05C17/00Hand tools or apparatus using hand held tools, for applying liquids or other fluent materials to, for spreading applied liquids or other fluent materials on, or for partially removing applied liquids or other fluent materials from, surfaces
    • B05C17/005Hand tools or apparatus using hand held tools, for applying liquids or other fluent materials to, for spreading applied liquids or other fluent materials on, or for partially removing applied liquids or other fluent materials from, surfaces for discharging material from a reservoir or container located in or on the hand tool through an outlet orifice by pressure without using surface contacting members like pads or brushes
    • B05C17/01Hand tools or apparatus using hand held tools, for applying liquids or other fluent materials to, for spreading applied liquids or other fluent materials on, or for partially removing applied liquids or other fluent materials from, surfaces for discharging material from a reservoir or container located in or on the hand tool through an outlet orifice by pressure without using surface contacting members like pads or brushes with manually mechanically or electrically actuated piston or the like
    • B05C17/0116Hand tools or apparatus using hand held tools, for applying liquids or other fluent materials to, for spreading applied liquids or other fluent materials on, or for partially removing applied liquids or other fluent materials from, surfaces for discharging material from a reservoir or container located in or on the hand tool through an outlet orifice by pressure without using surface contacting members like pads or brushes with manually mechanically or electrically actuated piston or the like characterised by the piston driving means
    • B05C17/012Stepwise advancing mechanism, e.g. pawl and ratchets
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B65CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65DCONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
    • B65D83/00Containers or packages with special means for dispensing contents
    • B65D83/0055Containers or packages provided with a flexible bag or a deformable membrane or diaphragm for expelling the contents
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05CAPPARATUS FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05C17/00Hand tools or apparatus using hand held tools, for applying liquids or other fluent materials to, for spreading applied liquids or other fluent materials on, or for partially removing applied liquids or other fluent materials from, surfaces
    • B05C17/005Hand tools or apparatus using hand held tools, for applying liquids or other fluent materials to, for spreading applied liquids or other fluent materials on, or for partially removing applied liquids or other fluent materials from, surfaces for discharging material from a reservoir or container located in or on the hand tool through an outlet orifice by pressure without using surface contacting members like pads or brushes
    • B05C17/00583Hand tools or apparatus using hand held tools, for applying liquids or other fluent materials to, for spreading applied liquids or other fluent materials on, or for partially removing applied liquids or other fluent materials from, surfaces for discharging material from a reservoir or container located in or on the hand tool through an outlet orifice by pressure without using surface contacting members like pads or brushes the container for the material to be dispensed being deformable

Definitions

  • the present invention relates to a cartridge according to the preamble of claim 1 or 2. Furthermore, the invention is directed to a method for manufacturing and in particular in addition to filling such a cartridge.
  • cartridges are often used to store liquid flowable, often pasty or viscous to highly viscous substances and carry out as needed for each application. Examples of such substances are joint sealants, compounds for chemical dowels or chemical anchors, adhesives, pastes or molding compounds in the dental field.
  • these cartridges are made of plastic and are produced in an injection molding process.
  • one-component systems in which the material to be discharged consists of only one component
  • two-component or multi-component systems in which at least two different components are stored in separate chambers of the same cartridge or in separate cartridges, the components being discharged by means of a dynamic or a static mixing device are intimately mixed.
  • examples include two-component adhesive or chemical dowels that cure only after mixing the two components.
  • two-component systems are also used for paints, which are often used for the production of functional protective layers, for example for corrosion protection.
  • the cartridges comprise one (or more) axially displaceable delivery pistons, by the movement of which the material is discharged from the chamber or the chambers.
  • the chambers must have sufficiently thick walls in order to withstand the pressure arising during discharge can.
  • the cartridges must have sufficiently thick walls to be sufficiently diffusion-tight. This is particularly important with regard to storage, in order to effectively prevent the inward diffusion or outward diffusion of the chemical substances and thus a degradation of the cartridge contents. Since such plastic cartridges are usually designed for single use, resulting from both the volume and the mass of a considerable amount of waste, which is particularly disadvantageous from aspects of environmental protection.
  • hoses in which the respective materials are stored. These hoses are then placed in special support or discharge devices to discharge their contents for the particular application.
  • hoses are significantly cheaper than cartridges, especially as regards the volume of waste, they have other disadvantages. It requires much more complex filling devices to fill the hoses and close.
  • their storage is more problematic because hoses are not stable, so special measures or packaging must be provided for storage.
  • the mass of the residual volume in the hose, which can not be discharged is relatively high. Hoses also have the disadvantage that they are very sensitive to mechanical influences, especially against sharp edges or sharp corners.
  • the unfilled cartridges are usually transported by the cartridge manufacturers to the manufacturers of filling materials (media) who then take care of filling the empty cartridges. Even if the unfilled cartridges have a relatively low weight, the costs for transporting the empty cartridges from the cartridge manufacturers to the media manufacturers are relatively high, since the empty cartridges have a relatively large volume and thus a high space requirement during transport. In addition, the storage costs for the empty cartridges are relatively high for both the cartridge manufacturers and the media manufacturers due to the space required. These costs account for a not inconsiderable part of the total manufacturing costs of the cartridges.
  • a cartridge according to the preamble of claims 1 and 2 is known.
  • it In order to empty the entire air contained in the empty cartridge before filling the cartridge, it is first brought into a collapsed state.
  • the rear half of the flexible cartridge wall is invaginated into the front half of the cartridge and then any residual air contained removed by applying a vacuum.
  • the cartridge or receiving chamber which has been screwed together in this way has approximately 50% of the space required by the cartridge or the receiving chamber in the expanded state. Subsequently, the cartridge is filled with the desired material and the filled cartridge stored or delivered in the usual way.
  • this object is achieved with a cartridge having the features of claim 1 or 2 and with a method for producing such a cartridge with the features of claim 7, 14 or 15.
  • the space requirement of a not yet filled cartridge depending on the maximum filling volume of the cartridge, to a fraction, namely less than 30%, in particular less than 25%, preferably less than 20% of the space requirement of a conventional cartridge or the cartridge be reduced in the expanded state.
  • the space requirement of a not yet filled receiving chamber depending on the maximum filling volume of the receiving chamber, to a fraction, namely less than 30%, in particular less than 25%, preferably less than 20% of the space required by the receiving chamber in the expanded state.
  • the knowledge is exploited that the flexible cartridge wall of a collapsing cartridge can be pushed together not only when discharging the filling material from the filled cartridge, but also that a cartridge which has not even been filled can be collapsed in a corresponding manner.
  • the volume of the cartridge or its receiving chamber can be minimized, so that the storage and transport costs can be significantly reduced due to the reduced space requirement. Since the collapsed cartridge can easily be returned to its expanded state at any time, the expansion and the associated increase in the volume of the receiving space are only required when the cartridge is filled with the filling material.
  • the connection between the head part and the cartridge wall can be realized for example by gluing, fusing, welding or by jamming. It is also possible that the head part is molded onto the cartridge wall, in particular at its front end, and thus the head part and the cartridge wall are integrally formed. The end remote from the head part of the cartridge wall is formed closed to form the receiving chamber. In this case, the closed end can be generated directly during the production of the film tube. But it is also possible that this end is initially formed open and is subsequently closed in a further process step. This can be done for example by gluing, crimping, fusing, welding, by clamping, for example by means of a clamping ring or by attaching a separate end element such as an end plate.
  • the design of the cartridge wall as a film on the one hand means a considerable reduction of the waste and the raw materials required for the production and on the other hand brings with it a very high flexibility with regard to the choice of material.
  • the film can be adapted to the specific cartridge content and at the same time represents a very efficient diffusion barrier.
  • the cartridge according to the invention can be inserted into a reusable support cartridge during filling and / or discharging its contents.
  • the film forming the cartridge wall can be designed as a multilayer system, in particular as a composite film.
  • the film may comprise plastic layers and / or metallic layers, in particular one or more aluminum layers.
  • the cartridge wall in the collapsed state of the cartridge, is pushed together in the longitudinal direction of the receiving chamber.
  • the pushing together in the longitudinal direction corresponds to the pushing together of the cartridge wall when discharging the filling compound, so that the cartridge wall does not have to be specially set up in order to allow the pushing together of the unfilled cartridge.
  • the cartridge wall is converted in another way to achieve the collapsed state.
  • the cartridge wall could be deformed transversely and in particular perpendicular to the longitudinal axis of the receiving chamber and in particular pushed together.
  • the cartridge is preferably designed as a one-component cartridge with a receiving chamber or as a multi-component cartridge with a plurality of receiving chambers, in particular as a two-component cartridge with two receiving chambers.
  • the receiving chambers may have a cylindrical shape and, in the case of a multi-component cartridge, be arranged next to one another. It is also possible that the receiving chambers have a different shape from the cylindrical shape and in particular are formed so that they side by side together give a cylindrical shape.
  • each receiving chamber is preferably assigned a separate head part, the outlet of which is in fluid communication with the receiving chamber assigned to it.
  • the receiving chambers is associated with a common common head part, wherein the head part has a plurality of outlets, one of which is in fluid communication with a respective receiving chamber.
  • the head part is molded onto the cartridge wall.
  • the end of the cartridge wall remote from the head part is sealingly closed by a crimping or clamping connection.
  • the originally open end of the tubular cartridge wall can be sealed in this way simple, inexpensive and reliable.
  • the cartridge wall is sealingly and non-detachably connected to the head part in such a way that the cartridge is produced in its expanded state. Only after generating the cartridge in its expanded state, the cartridge wall is pushed together so that the cartridge is transferred to its collapsed state in which the receiving chamber has its minimum volume. This is completely contrary to the previously known procedures for producing a cartridge, in which the empty cartridge is always generated with its maximum filling volume.
  • the end of the cartridge wall remote from the head part is sealingly closed prior to pushing together. This can for example be done directly in the manufacture of the tubular cartridge wall by one end of the cartridge wall is made closed. But it is also possible that the cartridge wall is first produced with two open ends and only at a later time, the remote from the headboard end is closed, as has already been stated above.
  • the cartridge wall is pushed together in the longitudinal direction of the receiving chamber.
  • a predefined pressure is generated in the receiving chamber and the pushing together of the cartridge wall takes place against the pressure.
  • the pressure is reduced gradually and the pressure chosen in particular so high that the cartridge wall when pushed together is folded like a concertina in essence. This ensures a controlled pushing together of the cartridge wall, which in turn allows easy sliding apart of the cartridge wall during filling.
  • the cartridge wall is converted in another way to achieve the collapsed state.
  • the cartridge wall could be deformed transversely and in particular perpendicular to the longitudinal axis of the receiving chamber and in particular pushed together.
  • the medium is filled through the outlet in the head part into the receiving chamber for filling the cartridge. This ensures that the receiving chamber is reliably filled, especially in the area of the outlet with medium.
  • the cartridge wall is pushed apart again by filling the cartridge so that the cartridge is transferred from its collapsed state into a partially expanded state or into its expanded state.
  • the cartridge wall is pushed apart again by filling the cartridge so that the cartridge is transferred from its collapsed state into a partially expanded state or into its expanded state.
  • Fig. 1 shows a designed as a two-component cartridge cartridge 1, which comprises two cylindrical receiving chambers 2, 3.
  • the receiving chambers 2, 3 are bounded in each case by a cartridge wall 4, 5 as well as by a common head part 6, which respectively forms an end-side end of each receiving chamber 2, 3.
  • the two ends 7, 8 of the two cartridge walls 4, 5 which are remote from the head part 6 are in each case to the central axis of the respective receiving chamber 2, 3 brought together and bound together by a respective clamping ring 9, 10 so that the ends 7, 8 are sealed sealing.
  • the head part 6 facing ends 11, 12 are sealingly and permanently connected to the head part 6 by the head part 6 is molded onto the ends 11, 12. While the head part 6 consists of a dimensionally stable plastic, the cartridge walls 4, 5 are designed as a multilayer film, which are rolled and welded in their predominant central region to a cylindrical shape and form together with the head part 6, the cylindrical receiving chambers 2, 3.
  • the head part 6 has two outlets 13, 14, which are connected for filling the receiving chambers 2, 3 with filling material and for discharging the filling material from the receiving chambers 2, 3 with these. Furthermore, a screw cap 15 is provided, through which the outlets 13, 14 are closed together.
  • Fig. 1 are the receiving chambers 2, 3 is not filled with filling material, ie the medium to be discharged, but empty. Nevertheless, the cartridge walls 4, 5, due to the rigidity of the film material used in the Fig. 1 shown substantially cylindrical shape, which represents the expanded state of the cartridge 1 with maximum volume of the receiving chambers 2, 3.
  • the cartridge walls 4, 5 are pushed together before being filled with the medium to be discharged in the longitudinal direction of the receiving chambers 2, 3 until the cartridge is in its collapsed state in which the receiving chambers 2, 3 each have their minimum volume occupies.
  • This collapsed state is in Fig. 2 shown. From the comparison of Fig. 1 and 2 becomes immediately clear that the space requirement of the cartridge 1 and the receiving chambers 2, 3 in the collapsed state is only about 20% of the space required in the expanded state.
  • the pushing together of the cartridge walls 4, 5 can, in particular when screw cap 15 is unscrewed by a discharge device described in more detail below.
  • Fig. 3 shows one opposite the Fig. 1 and 2 slightly modified cartridge 1. The only difference is that in the region of the outlets 13, 14 no screw connection for fastening the screw cap 15, but a bayonet connection for attaching a cap with bayonet closure is provided.
  • the design of the fastening by screwing or by a bayonet connection is not relevant to the present invention.
  • a bayonet attachment in addition to a plugging movement includes an adjoining rotational or screwing, so that in the following for simplicity uniformly the terms "screw” or "ersatz” are used, even if a bayonet attachment of the cap is shown.
  • Fig. 4 shows a discharge device 17, in which the cartridge 1 according to the invention can be used.
  • the discharge device 17 comprises a two-component support cartridge 18, on whose front side two receiving openings 19, 20 are formed for the cartridge 1.
  • the cartridge 1 with its cartridge walls 4, 5 can be pushed into the receiving openings until the head part 6 bears against the end face of the support cartridge 18.
  • the support cartridge 18 can be pivoted together with the inserted cartridge 1 about a pivot axis 21, so that they are inside a housing portion 22 of the discharge 17 comes to rest, as it is in Fig. 6 is shown.
  • the screw lug 16 protrudes through an end opening 23 in the housing portion 22, so that for discharging the present in the receiving chambers 2, 3 medium, a mixer tip, not shown, can be screwed onto the screw boss 16.
  • a ratchet slide 25 at the front end of two plate-shaped feed piston 26, 27 are provided, are displaced in the direction of the front end of the discharge 17, whereby in the receiving chambers 2, 3rd existing filling material discharged through the outlets 13, 14 and then mixed by the mixer tip.
  • Fig. 7 is indicated in a step 1 "production” that can be significantly saved by the design of the cartridge wall as a film manufacturing costs compared to a cartridge with dimensionally stable cartridge wall.
  • step 1 production
  • step 2 storage (empty)
  • step 3 Transport (empty)
  • step 4 filling
  • step 5 transport (filled)

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  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Coating Apparatus (AREA)
  • Containers And Packaging Bodies Having A Special Means To Remove Contents (AREA)
  • Basic Packing Technique (AREA)
  • Packages (AREA)
  • Moulds For Moulding Plastics Or The Like (AREA)
  • Packaging Of Annular Or Rod-Shaped Articles, Wearing Apparel, Cassettes, Or The Like (AREA)
  • Package Specialized In Special Use (AREA)

Description

Die vorliegende Erfindung betrifft eine Kartusche nach dem Oberbegriff des Anspruchs 1 oder 2. Weiterhin ist die Erfindung auf ein Verfahren zum Herstellen und insbesondere zusätzlich zum Befüllen einer solchen Kartusche gerichtet. Im industriellen Bereich, im Bauwesen, beispielsweise von Gebäuden, und auch im Dentalbereich werden häufig Kartuschen eingesetzt, um flüssige fliessfähige, oftmals pastöse oder viskose bis hochviskose Substanzen zu lagern und bei Bedarf für die jeweilige Anwendung auszutragen. Beispiele für solche Substanzen sind Fugendichtmassen, Massen für chemische Dübel oder chemische Anker, Klebstoffe, Pasten oder Abformmassen im Dentalbereich. Üblicherweise sind diese Kartuschen aus Kunststoff gefertigt und werden in einem Spritzgiessverfahren hergestellt.The present invention relates to a cartridge according to the preamble of claim 1 or 2. Furthermore, the invention is directed to a method for manufacturing and in particular in addition to filling such a cartridge. In the industrial sector, in the construction industry, for example of buildings, and also in the dental field cartridges are often used to store liquid flowable, often pasty or viscous to highly viscous substances and carry out as needed for each application. Examples of such substances are joint sealants, compounds for chemical dowels or chemical anchors, adhesives, pastes or molding compounds in the dental field. Usually, these cartridges are made of plastic and are produced in an injection molding process.

Man unterscheidet zwischen Einkomponentensystemen, bei welchen das auszutragende Material nur aus einer Komponente besteht, und Zwei- oder Mehrkomponentensystemen, bei denen mindestens zwei verschiedene Komponenten in separaten Kammern der gleichen Kartusche oder in separaten Kartuschen gelagert werden, wobei die Komponenten beim Austragen mittels einer dynamischen oder einer statischen Mischvorrichtung innig durchmischt werden. Beispiele hierfür sind Zwei-Komponenten-Kleber oder chemische Dübel, die erst nach dem Durchmischen der beiden Komponenten aushärten. Insbesondere im industriellen Bereich werden Zweikomponentensysteme auch für Farben eingesetzt, die oft zur Erzeugung funktioneller Schutzschichten, z.B. zum Korrosionsschutz, verwendet werden.A distinction is made between one-component systems in which the material to be discharged consists of only one component, and two-component or multi-component systems in which at least two different components are stored in separate chambers of the same cartridge or in separate cartridges, the components being discharged by means of a dynamic or a static mixing device are intimately mixed. Examples include two-component adhesive or chemical dowels that cure only after mixing the two components. Especially in the industrial sector, two-component systems are also used for paints, which are often used for the production of functional protective layers, for example for corrosion protection.

Oft ist es so, dass die Kartuschen einen (oder mehrere) axial verschiebbaren Förderkolben umfassen, durch dessen Bewegung das Material aus der Kammer oder den Kammern ausgetragen wird. Es versteht sich, dass dazu die Kammern genügend dicke Wandungen aufweisen müssen, um dem beim Austragen entstehenden Druck standhalten zu können. Zudem müssen die Kartuschen genügend dicke Wandstärken aufweisen, um ausreichend diffusionsdicht zu sein. Dies ist insbesondere im Hinblick auf die Lagerung wichtig, um ein Hineindiffundieren oder ein Herausdiffundieren der chemischen Substanzen und damit eine Degradation des Kartuscheninhalts möglichst wirkungsvoll zu verhindern. Da solche Kunststoffkartuschen in der Regel nur für den Einmalgebrauch ausgelegt sind, resultiert sowohl vom Volumen als auch von der Masse eine erhebliche Abfallmenge, was insbesondere auch unter Aspekten des Umweltschutzes nachteilig ist.It is often the case that the cartridges comprise one (or more) axially displaceable delivery pistons, by the movement of which the material is discharged from the chamber or the chambers. It is understood that for this purpose the chambers must have sufficiently thick walls in order to withstand the pressure arising during discharge can. In addition, the cartridges must have sufficiently thick walls to be sufficiently diffusion-tight. This is particularly important with regard to storage, in order to effectively prevent the inward diffusion or outward diffusion of the chemical substances and thus a degradation of the cartridge contents. Since such plastic cartridges are usually designed for single use, resulting from both the volume and the mass of a considerable amount of waste, which is particularly disadvantageous from aspects of environmental protection.

Eine bekannte Alternative zu den Kunststoffkartuschen stellen Schläuche dar, in denen die jeweiligen Materialien gelagert werden. Diese Schläuche werden dann in spezielle Stütz- oder Austragsvorrichtungen eingelegt, um Ihren Inhalt für die jeweilige Anwendung auszutragen. Zwar sind solche Schläuche insbesondere vom Abfallvolumen her gesehen deutlich günstiger als Kartuschen, sie haben aber andere Nachteile. Es bedarf deutlich aufwändigerer Befüllvorrichtungen, um die Schläuche zu befüllen und zu verschliessen. Zudem ist ihre Lagerung problematischer, denn Schläuche sind nicht stehfähig, sodass für die Lagerung besondere Massnahmen bzw. Verpackungen vorgesehen werden müssen. Auch können Probleme mit der Dichtheit solcher Schläuche auftreten. Zudem ist die Masse des Restvolumens im Schlauch, das nicht ausgetragen werden kann, relativ hoch. Schläuche haben ferner den Nachteil, dass sie sehr empfindlich gegenüber mechanischen Einflüssen sind, insbesondere gegenüber scharfen Kanten oder spitzen Ecken.A known alternative to the plastic cartridges are hoses in which the respective materials are stored. These hoses are then placed in special support or discharge devices to discharge their contents for the particular application. Although such hoses are significantly cheaper than cartridges, especially as regards the volume of waste, they have other disadvantages. It requires much more complex filling devices to fill the hoses and close. In addition, their storage is more problematic because hoses are not stable, so special measures or packaging must be provided for storage. There may also be problems with the tightness of such hoses. In addition, the mass of the residual volume in the hose, which can not be discharged, is relatively high. Hoses also have the disadvantage that they are very sensitive to mechanical influences, especially against sharp edges or sharp corners.

Neben dem Aspekt des Umweltschutzes gewinnt auch das Thema der Nachhaltigkeit zunehmend an Bedeutung. Die Verwendung erneuerbarer Ausgangsmaterialien, die Minimierung des Rohmaterial- und Energieverbrauchs sowie eine möglichst starke Reduzierung des Abfalls sowohl im Hinblick auf die Kartusche an sich als auch auf das in der Kartusche verbleibende Volumen an Restmasse gewinnen zunehmend an Bedeutung.In addition to the aspect of environmental protection, the issue of sustainability is also becoming increasingly important. The use of renewable raw materials, The minimization of raw material and energy consumption and the greatest possible reduction of waste, both with regard to the cartridge per se and to the remaining volume in the cartridge, are becoming increasingly important.

Die unbefüllten Kartuschen werden üblicherweise von den Kartuschenherstellern zu den Herstellern der Füllmaterialien (Medien) transportiert, die dann für das Befüllen der Leerkartuschen Sorge tragen. Auch wenn die unbefüllten Kartuschen ein relativ geringes Gewicht besitzen, sind die Kosten für den Transport der Leerkartuschen von den Kartuschenherstellern zu den Medienherstellern relativ hoch, da die Leerkartuschen ein relativ grosses Volumen und damit einen hohen Platzbedarf beim Transport besitzen. Darüber hinaus sind auch die Lagerkosten für die Leerkartuschen sowohl bei den Kartuschenherstellern als auch bei den Medienherstellern aufgrund des Platzbedarfs relativ hoch. Diese Kosten nehmen einen nicht unerheblichen Teil der Gesamtherstellungskosten der Kartuschen ein.The unfilled cartridges are usually transported by the cartridge manufacturers to the manufacturers of filling materials (media) who then take care of filling the empty cartridges. Even if the unfilled cartridges have a relatively low weight, the costs for transporting the empty cartridges from the cartridge manufacturers to the media manufacturers are relatively high, since the empty cartridges have a relatively large volume and thus a high space requirement during transport. In addition, the storage costs for the empty cartridges are relatively high for both the cartridge manufacturers and the media manufacturers due to the space required. These costs account for a not inconsiderable part of the total manufacturing costs of the cartridges.

Aus der EP 0 992 438 A1 ist eine Kartusche gemäß dem Oberbegriff der Ansprüche 1 und 2 bekannt. Um vor dem Befüllen der Kartusche die gesamte in der leeren Kartusche enthaltene Luft zu entleeren, wird diese zunächst in einen kollabierten Zustand gebracht. Dazu wird die hintere Hälfte der flexiblen Kartuschenwand in die vordere Hälfte der Kartusche hineingestülpt und anschließend noch etwaige enthaltene Restluft durch Anlegen eines Vakuums entfernt. Die derartig zusammengestülpte Kartusche bzw. Aufnahmekammer besitzt ca. 50% des Platzbedarfs der Kartusche bzw. der Aufnahmekammer im expandierten Zustand. Anschließend wird die Kartusche mit dem gewünschten Material befüllt und die befüllte Kartusche in üblicher Weise gelagert bzw. ausgeliefert.From the EP 0 992 438 A1 a cartridge according to the preamble of claims 1 and 2 is known. In order to empty the entire air contained in the empty cartridge before filling the cartridge, it is first brought into a collapsed state. For this purpose, the rear half of the flexible cartridge wall is invaginated into the front half of the cartridge and then any residual air contained removed by applying a vacuum. The cartridge or receiving chamber which has been screwed together in this way has approximately 50% of the space required by the cartridge or the receiving chamber in the expanded state. Subsequently, the cartridge is filled with the desired material and the filled cartridge stored or delivered in the usual way.

Es ist eine Aufgabe der Erfindung, eine Kartusche der eingangs genannten Art sowie ein Verfahren zum Herstellen einer solchen Kartusche vorzuschlagen, mit denen die Gesamtherstellungskosten reduziert werden können.It is an object of the invention to provide a cartridge of the type mentioned above and a method for producing such a cartridge, with which the total manufacturing costs can be reduced.

Erfindungsgemäss wird diese Aufgabe mit einer Kartusche mit den Merkmalen des Anspruchs 1 oder 2 sowie mit einem Verfahren zum Herstellen einer solchen Kartusche mit den Merkmalen des Anspruchs 7, 14 oder 15 gelöst.According to the invention this object is achieved with a cartridge having the features of claim 1 or 2 and with a method for producing such a cartridge with the features of claim 7, 14 or 15.

Mit der Erfindung kann der Platzbedarf einer noch nicht befüllten Kartusche, je nach maximalem Befüllvolumen der Kartusche, auf einen Bruchteil, nämlich auf weniger als 30%, insbesondere weniger als 25%, bevorzugt weniger als 20% des Platzbedarfs einer üblichen Kartusche bzw. der Kartusche im expandierten Zustand reduziert werden. Ebenso kann der Platzbedarf einer noch nicht befüllten Aufnahmekammer, je nach maximalem Befüllvolumen der Aufnahmekammer, auf einen Bruchteil, nämlich auf weniger als 30%, insbesondere weniger als 25%, bevorzugt weniger als 20% des Platzbedarfs der Aufnahmekammer im expandierten Zustand reduziert werden. Erfindungsgemäss wird die Erkenntnis ausgenutzt, dass die flexible Kartuschenwand einer kollabierenden Kartusche nicht nur beim Austragen der Füllmasse aus der befüllten Kartusche zusammengeschoben werden kann, sondern dass auch eine Kartusche, die noch gar nicht befüllt wurde, in entsprechender Weise kollabiert werden kann. Damit kann gleichzeitig das Volumen der Kartusche bzw. deren Aufnahmekammer minimiert werden, so dass die Lager- und Transportkosten aufgrund des verringerten Platzbedarfs deutlich verringert werden können. Da die kollabierte Kartusche jederzeit problemlos wieder in ihren expandierten Zustand überführt werden kann, sind das Expandieren und die damit verbundene Vergrösserung des Volumens des Aufnahmeraums erst erforderlich, wenn die Kartusche mit der Füllmasse befüllt wird. Unter dem Platzbedarf der Kartusche/Aufnahmekammer ist nicht das Innenvolumen der Kartusche/Aufnahmekammer zu verstehen, sondern das Volumen der die Kartusche/Aufnahmekammer umschließenden virtuellen Hülle (konvexe Hülle) bzw. des die Kartusche/Aufnahmekammer umschließenden Raums, der für die Lagerung und/oder den Transport der Kartusche/Aufnahmekammer benötigt wird.With the invention, the space requirement of a not yet filled cartridge, depending on the maximum filling volume of the cartridge, to a fraction, namely less than 30%, in particular less than 25%, preferably less than 20% of the space requirement of a conventional cartridge or the cartridge be reduced in the expanded state. Likewise, the space requirement of a not yet filled receiving chamber, depending on the maximum filling volume of the receiving chamber, to a fraction, namely less than 30%, in particular less than 25%, preferably less than 20% of the space required by the receiving chamber in the expanded state. According to the invention, the knowledge is exploited that the flexible cartridge wall of a collapsing cartridge can be pushed together not only when discharging the filling material from the filled cartridge, but also that a cartridge which has not even been filled can be collapsed in a corresponding manner. Thus, at the same time the volume of the cartridge or its receiving chamber can be minimized, so that the storage and transport costs can be significantly reduced due to the reduced space requirement. Since the collapsed cartridge can easily be returned to its expanded state at any time, the expansion and the associated increase in the volume of the receiving space are only required when the cartridge is filled with the filling material. Under the space required by the cartridge / receiving chamber is not the internal volume of the cartridge / receiving chamber to understand, but the volume of the cartridge / receiving chamber enclosing virtual envelope (convex hull) or the cartridge / receiving chamber enclosing space for storage and / or the transport of the cartridge / receiving chamber is needed.

Die Verbindung zwischen dem Kopfteil und der Kartuschenwand kann beispielsweise durch Verkleben, Verschmelzen, Verschweissen oder durch Verklemmen realisiert sein. Es ist auch möglich, dass das Kopfteil an die Kartuschenwand, insbesondere an deren stirnseitiges Ende, angespritzt ist und somit Kopfteil und Kartuschenwand einstückig ausgebildet sind. Das von dem Kopfteil abgewandte Ende der Kartuschenwand ist zur Bildung der Aufnahmekammer geschlossen ausgebildet. Dabei kann das geschlossene Ende unmittelbar beim Erzeugen des Folienschlauchs erzeugt werden. Es ist aber auch möglich, dass dieses Ende zunächst offen ausgebildet ist und in einem weiteren Verfahrensschritt nachträglich geschlossen wird. Dies kann beispielsweise durch Verkleben, Vercrimpen, Verschmelzen, Verschweissen, durch Verklemmen beispielsweise mittels eines Klemmrings oder durch Anbringen eines separaten Abschlusselements wie einer Endplatte erfolgen.The connection between the head part and the cartridge wall can be realized for example by gluing, fusing, welding or by jamming. It is also possible that the head part is molded onto the cartridge wall, in particular at its front end, and thus the head part and the cartridge wall are integrally formed. The end remote from the head part of the cartridge wall is formed closed to form the receiving chamber. In this case, the closed end can be generated directly during the production of the film tube. But it is also possible that this end is initially formed open and is subsequently closed in a further process step. This can be done for example by gluing, crimping, fusing, welding, by clamping, for example by means of a clamping ring or by attaching a separate end element such as an end plate.

Die Ausgestaltung der Kartuschenwand als Folie bedeutet zum einen eine erhebliche Reduktion des Abfalls und der für die Herstellung benötigten Rohstoffe und bringt zum anderen eine sehr hohe Flexibilität im Hinblick auf die Materialwahl mit sich. Die Folie kann je nach Anwendungsfall an den spezifischen Kartuscheninhalt angepasst werden und stellt gleichzeitig eine sehr effiziente Diffusionssperre dar. Vorzugsweise kann die erfindungsgemässe Kartusche beim Befüllen und/oder beim Austragen ihres Inhalts in eine wiederverwendbare Stützkartusche eingelegt werden. Bevorzugt kann die die Kartuschenwand bildende Folie als Mehrschichtsystem, insbesondere als Verbundfolie ausgestaltet sein. Dabei kann die Folie Kunststoffschichten und/oder metallische Schichten, insbesondere eine oder mehrere Aluminiumschichten, umfassen.The design of the cartridge wall as a film on the one hand means a considerable reduction of the waste and the raw materials required for the production and on the other hand brings with it a very high flexibility with regard to the choice of material. Depending on the application, the film can be adapted to the specific cartridge content and at the same time represents a very efficient diffusion barrier. Preferably, the cartridge according to the invention can be inserted into a reusable support cartridge during filling and / or discharging its contents. Preferably, the film forming the cartridge wall can be designed as a multilayer system, in particular as a composite film. The film may comprise plastic layers and / or metallic layers, in particular one or more aluminum layers.

Nach einer bevorzugten Ausführungsform der Erfindung ist im kollabierten Zustand der Kartusche die Kartuschenwand in Längsrichtung der Aufnahmekammer zusammengeschoben. Dadurch wird automatisch eine Verkürzung der Kartusche erreicht, die einer optimalen Verringerung des Platzbedarfs entspricht. Darüber hinaus entspricht das Zusammenschieben in Längsrichtung dem Zusammenschieben der Kartuschenwand beim Austragen der Füllmasse, so dass die Kartuschenwand nicht speziell eingerichtet werden muss, um auch das Zusammenschieben der unbefüllten Kartusche zu ermöglichen. Grundsätzlich ist es auch denkbar, dass zum Erreichen des kollabierten Zustands die Kartuschenwand in andere Weise umgeformt wird. Beispielsweise könnte die Kartuschenwand quer und insbesondere senkrecht zur Längsachse der Aufnahmekammer verformt und insbesondere zusammengeschoben werden. Dies könnte beispielsweise dadurch erreicht werden, dass in dem unbefüllten Aufnahmeraum ein Unterdruck bzw. ein Vakuum erzeugt wird, durch den ein Zusammenziehen der Kartuschenwand quer zur Längsrichtung der Aufnahmekammer erfolgt. Anschliessend könnte die derart flachgedrückte Kartuschenwand beispielsweise zusammengerollt oder zusammengefaltet werden, um eine Längenverkürzung der Kartusche zu erreichen.According to a preferred embodiment of the invention, in the collapsed state of the cartridge, the cartridge wall is pushed together in the longitudinal direction of the receiving chamber. As a result, a shortening of the cartridge is automatically achieved, which corresponds to an optimal reduction in space requirements. About that In addition, the pushing together in the longitudinal direction corresponds to the pushing together of the cartridge wall when discharging the filling compound, so that the cartridge wall does not have to be specially set up in order to allow the pushing together of the unfilled cartridge. In principle, it is also conceivable that the cartridge wall is converted in another way to achieve the collapsed state. For example, the cartridge wall could be deformed transversely and in particular perpendicular to the longitudinal axis of the receiving chamber and in particular pushed together. This could be achieved, for example, by creating a negative pressure or a vacuum in the unfilled receiving space, through which a contraction of the cartridge wall takes place transversely to the longitudinal direction of the receiving chamber. Subsequently, the thus flattened cartridge wall could, for example, be rolled up or folded in order to achieve a length reduction of the cartridge.

Bevorzugt ist die Kartusche als Einkomponentenkartusche mit einer Aufnahmekammer oder als Mehrkomponentenkartusche mit mehreren Aufnahmekammern, insbesondere als Zweikomponetenkartusche mit zwei Aufnahmekammern, ausgebildet. Insbesondere können die Aufnahmekammern dabei eine zylindrische Form besitzen und im Falle einer Mehrkomponentenkartusche nebeneinander angeordnet sein. Es ist auch möglich, dass die Aufnahmekammern eine von der Zylinderform abweichende Form besitzen und insbesondere so ausgebildet sind, dass sie nebeneinander angeordnet zusammen eine zylindrische Form ergeben.The cartridge is preferably designed as a one-component cartridge with a receiving chamber or as a multi-component cartridge with a plurality of receiving chambers, in particular as a two-component cartridge with two receiving chambers. In particular, the receiving chambers may have a cylindrical shape and, in the case of a multi-component cartridge, be arranged next to one another. It is also possible that the receiving chambers have a different shape from the cylindrical shape and in particular are formed so that they side by side together give a cylindrical shape.

Im Falle einer Mehrkomponentenkartusche ist bevorzugt jeder Aufnahmekammer ein separates Kopfteil zugeordnet, dessen Auslass jeweils mit der ihm zugeordneten Aufnahmekammer in Fluidverbindung steht. Es ist jedoch auch möglich, dass den Aufnahmekammern ein einheitliches gemeinsames Kopfteil zugeordnet ist, wobei das Kopfteil mehrere Auslässe aufweist, von denen jeweils einer in Fluidverbindung mit je einer Aufnahmekammer steht.In the case of a multi-component cartridge, each receiving chamber is preferably assigned a separate head part, the outlet of which is in fluid communication with the receiving chamber assigned to it. However, it is also possible that the receiving chambers is associated with a common common head part, wherein the head part has a plurality of outlets, one of which is in fluid communication with a respective receiving chamber.

Bevorzugt ist das Kopfteil an die Kartuschenwand angespritzt. Dadurch wird eine einstückige Ausbildung und damit eine sehr dichte und stabile Verbindung von Kopfteil und Kartuschenwand erreicht. Vorteilhaft ist das von dem Kopfteil entfernt liegende Ende der Kartuschenwand durch eine Crimp- oder Klemmverbindung dichtend abgeschlossen. Das ursprünglich offene Ende der schlauchförmigen Kartuschenwand kann auf diese Weise einfach, kostengünstig und zuverlässig abgedichtet werden.Preferably, the head part is molded onto the cartridge wall. As a result, a one-piece design and thus a very dense and stable connection of the headboard and cartridge wall is achieved. Advantageously, the end of the cartridge wall remote from the head part is sealingly closed by a crimping or clamping connection. The originally open end of the tubular cartridge wall can be sealed in this way simple, inexpensive and reliable.

Bei dem erfindungsgemässen Verfahren wird zunächst die Kartuschenwand dichtend und unlösbar so mit dem Kopfteil verbunden, dass die Kartusche in ihrem expandierten Zustand erzeugt wird. Erst nach dem Erzeugen der Kartusche in ihrem expandierten Zustand wird die Kartuschenwand so zusammengeschoben, dass die Kartusche in ihren kollabierten Zustand überführt wird, in dem die Aufnahmekammer ihr minimales Volumen besitzt. Dies ist vollkommen konträr zu den bisher bekannten Vorgehensweisen zum Herstellen einer Kartusche, bei denen die Leerkartusche immer mit ihrem maximalen Befüllvolumen erzeugt wird. Erst im Rahmen der vorliegenden Erfindung wurde erkannt, dass das Erzeugen der Leerkartuschen im kollabierten Zustand in erheblichen Kosteneinsparungen bei der Lagerung und beim Transport resultieren kann und dass dennoch problemlos das maximale Befüllvolumen für die gefüllte Kartusche hergestellt werden kann, indem die Kartusche erst unmittelbar vor dem Befüllen bzw. während und insbesondere direkt durch das Befüllen von ihrem kollabierten Zustand in den expandierten Zustand gebracht wird.In the method according to the invention, at first the cartridge wall is sealingly and non-detachably connected to the head part in such a way that the cartridge is produced in its expanded state. Only after generating the cartridge in its expanded state, the cartridge wall is pushed together so that the cartridge is transferred to its collapsed state in which the receiving chamber has its minimum volume. This is completely contrary to the previously known procedures for producing a cartridge, in which the empty cartridge is always generated with its maximum filling volume. It was only within the scope of the present invention that it was recognized that producing the empty cartridges in the collapsed state can result in considerable cost savings during storage and transport, and that, nevertheless, the maximum filling volume for the filled cartridge can be produced without problem by the cartridge being inserted just before the cartridge Filling or during and in particular directly brought by the filling of its collapsed state in the expanded state.

Nach einer bevorzugten Ausführungsform der Erfindung wird vor dem Zusammenschieben das von dem Kopfteil entfernt liegende Ende der Kartuschenwand dichtend verschlossen. Dies kann beispielsweise bereits direkt beim Herstellen der schlauchförmigen Kartuschenwand erfolgen, indem ein Ende der Kartuschenwand geschlossen hergestellt wird. Es ist aber auch möglich, dass die Kartuschenwand zunächst mit zwei offenen Enden herstellt wird und erst zu einem späteren Zeitpunkt das von dem Kopfteil entfernt liegende Ende verschlossen wird, wie es weiter oben bereits ausgeführt wurde.According to a preferred embodiment of the invention, the end of the cartridge wall remote from the head part is sealingly closed prior to pushing together. This can for example be done directly in the manufacture of the tubular cartridge wall by one end of the cartridge wall is made closed. But it is also possible that the cartridge wall is first produced with two open ends and only at a later time, the remote from the headboard end is closed, as has already been stated above.

Vorteilhaft wird die Kartuschenwand in Längsrichtung der Aufnahmekammer zusammengeschoben. Insbesondere ist es dabei bevorzugt, dass in der Aufnahmekammer ein vordefinierter Druck erzeugt wird und das Zusammenschieben der Kartuschenwand gegen den Druck erfolgt. Weiter bevorzugt wird beim Zusammenschieben der Druck nach und nach abgebaut und der Druck insbesondere so hoch gewählt, dass die Kartuschenwand beim Zusammenschieben im Wesentlichen ziehharmonikaartig zusammengefaltet wird. Dadurch ist ein kontrolliertes Zusammenschieben der Kartuschenwand gewährleistet, was wiederum ein problemloses Auseinanderschieben der Kartuschenwand beim Befüllen ermöglicht. Wie bereits beschrieben ist es grundsätzlich auch denkbar, dass zum Erreichen des kollabierten Zustands die Kartuschenwand in andere Weise umgeformt wird. Beispielsweise könnte die Kartuschenwand quer und insbesondere senkrecht zur Längsachse der Aufnahmekammer verformt und insbesondere zusammengeschoben werden.Advantageously, the cartridge wall is pushed together in the longitudinal direction of the receiving chamber. In particular, it is preferred that a predefined pressure is generated in the receiving chamber and the pushing together of the cartridge wall takes place against the pressure. More preferably, when pushed together, the pressure is reduced gradually and the pressure chosen in particular so high that the cartridge wall when pushed together is folded like a concertina in essence. This ensures a controlled pushing together of the cartridge wall, which in turn allows easy sliding apart of the cartridge wall during filling. As already described, it is basically also conceivable that the cartridge wall is converted in another way to achieve the collapsed state. For example, the cartridge wall could be deformed transversely and in particular perpendicular to the longitudinal axis of the receiving chamber and in particular pushed together.

Weiter bevorzugt wird zum Befüllen der Kartusche das Medium durch den Auslass im Kopfteil in die Aufnahmekammer eingefüllt. Dadurch ist gewährleistet, dass die Aufnahmekammer insbesondere im Bereich des Auslasses zuverlässig mit Medium befüllt ist.More preferably, the medium is filled through the outlet in the head part into the receiving chamber for filling the cartridge. This ensures that the receiving chamber is reliably filled, especially in the area of the outlet with medium.

Vorteilhaft wird durch das Befüllen der Kartusche die Kartuschenwand wieder auseinandergeschoben, so dass die Kartusche von ihrem kollabierten Zustand in einen teilexpandierten oder in ihren expandierten Zustand überführt wird. Somit ist für das das Expandieren der Kartusche kein separater Verfahrensschritt erforderlich, da Expandieren und Befüllen in einem gemeinsamen Verfahrensschritt realisiert werden.Advantageously, the cartridge wall is pushed apart again by filling the cartridge so that the cartridge is transferred from its collapsed state into a partially expanded state or into its expanded state. Thus, for the expansion of the cartridge no separate process step is required, since expanding and filling are realized in a common process step.

Die Erfindung wird nachfolgend anhand eines Ausführungsbeispiels unter Bezugnahme auf die Zeichnungen näher beschrieben; in diesen zeigen:

Fig.1
eine erfindungsgemässe Zweikomponentenkartusche in ihrem expandierten Zustand,
Fig. 2
die Kartusche nach Fig.1 in ihrem kollabierten Zustand,
Fig. 3
eine erfindungsgemässe Kartusche ohne Verschlusskappe,
Fig. 4
eine geöffnete Austragvorrichtung für eine erfindungsgemässe Kartusche ohne eingesetzte Kartusche,
Fig. 5
die Austragvorrichtung nach Fig. 4 mit teilweise eingesetzter Kartusche nach Fig. 3,
Fig. 6
die Austragvorrichtung nach den Fig. 4 und 5 mit vollständig eingesetzter, austragsbereiter Kartusche und
Fig. 7
ein schematisches Flussdiagramm der Herstellung und der Verwendung einer erfindungsgemässen Kartusche.
The invention will be described in more detail below with reference to an embodiment with reference to the drawings; in these show:
Fig.1
a two-component cartridge according to the invention in its expanded state,
Fig. 2
the cartridge after Fig.1 in her collapsed state,
Fig. 3
an inventive cartridge without cap,
Fig. 4
an open discharge device for a cartridge according to the invention without inserted cartridge,
Fig. 5
the discharge after Fig. 4 with partially inserted cartridge after Fig. 3 .
Fig. 6
the discharge after the 4 and 5 with fully inserted, ready for use cartridge and
Fig. 7
a schematic flow diagram of the production and use of a cartridge according to the invention.

Fig. 1 zeigt eine als Zweikomponentenkartusche ausgebildete Kartusche 1, die zwei zylindrische Aufnahmekammern 2, 3 umfasst. Die Aufnahmekammern 2, 3 sind jeweils von einer Kartuschenwand 4, 5 sowie von einem gemeinsamen Kopfteil 6 begrenzt, das jeweils ein stirnseitiges Ende jeder Aufnahmekammer 2, 3 bildet. Die beiden von dem Kopfteil 6 entfernt liegenden Enden 7,8 der beiden Kartuschenwände 4, 5 sind jeweils zur Mittelachse der jeweiligen Aufnahmekammer 2, 3 zusammengeführt und durch je einen Klemmring 9, 10 so zusammengebunden, dass die Enden 7, 8 dichtend abgeschlossen sind. Fig. 1 shows a designed as a two-component cartridge cartridge 1, which comprises two cylindrical receiving chambers 2, 3. The receiving chambers 2, 3 are bounded in each case by a cartridge wall 4, 5 as well as by a common head part 6, which respectively forms an end-side end of each receiving chamber 2, 3. The two ends 7, 8 of the two cartridge walls 4, 5 which are remote from the head part 6 are in each case to the central axis of the respective receiving chamber 2, 3 brought together and bound together by a respective clamping ring 9, 10 so that the ends 7, 8 are sealed sealing.

Die dem Kopfteil 6 zugewandten Enden 11, 12 sind mit dem Kopfteil 6 dichtend und unlösbar verbunden, indem das Kopfteil 6 an die Enden 11, 12 angespritzt ist. Während das Kopfteil 6 aus einem formstabilen Kunststoff besteht, sind die Kartuschenwände 4, 5 als Mehrschichtfolie ausgestaltet, die jeweils in ihrem überwiegenden Mittelbereich zu einer zylindrischen Form gerollt und verschweisst sind und zusammen mit dem Kopfteil 6 die zylinderförmigen Aufnahmekammern 2, 3 bilden.The head part 6 facing ends 11, 12 are sealingly and permanently connected to the head part 6 by the head part 6 is molded onto the ends 11, 12. While the head part 6 consists of a dimensionally stable plastic, the cartridge walls 4, 5 are designed as a multilayer film, which are rolled and welded in their predominant central region to a cylindrical shape and form together with the head part 6, the cylindrical receiving chambers 2, 3.

Das Kopfteil 6 besitzt zwei Auslässe 13, 14, die zum Befüllen der Aufnahmekammern 2, 3 mit Füllmasse und zum Austragen der Füllmasse aus den Aufnahmekammern 2, 3 mit diesen verbunden sind. Weiterhin ist eine Schraubkappe 15 vorgesehen, durch die die Auslässe 13, 14 gemeinsam verschlossen sind.The head part 6 has two outlets 13, 14, which are connected for filling the receiving chambers 2, 3 with filling material and for discharging the filling material from the receiving chambers 2, 3 with these. Furthermore, a screw cap 15 is provided, through which the outlets 13, 14 are closed together.

In Fig. 1 sind die Aufnahmekammern 2, 3 noch nicht mit Füllmasse, d.h. dem auszutragenden Medium gefüllt, sondern leer. Trotzdem besitzen die Kartuschenwände 4, 5, aufgrund der Steifigkeit des verwendeten Folienmaterials die in Fig. 1 gezeigte im Wesentlichen zylindrische Form, die den expandierten Zustand der Kartusche 1 mit maximalem Volumen der Aufnahmekammern 2, 3 darstellt.In Fig. 1 are the receiving chambers 2, 3 is not filled with filling material, ie the medium to be discharged, but empty. Nevertheless, the cartridge walls 4, 5, due to the rigidity of the film material used in the Fig. 1 shown substantially cylindrical shape, which represents the expanded state of the cartridge 1 with maximum volume of the receiving chambers 2, 3.

Erfindungsgemäss werden die Kartuschenwände 4, 5 noch vor dem Befüllen mit dem auszutragenden Medium in Längsrichtung der Aufnahmekammern 2, 3 zusammengeschoben, bis die Kartusche ihren kollabierten Zustand, in dem die Aufnahmekammern 2, 3 jeweils ihr minimales Volumen besitzen, einnimmt. Dieser kollabierte Zustand ist in Fig. 2 gezeigt. Aus dem Vergleich der Fig. 1 und 2 wird sofort deutlich, dass der Platzbedarf der Kartusche 1 bzw. der Aufnahmekammern 2, 3 im kollabierten Zustand nur ca. 20% des Platzbedarfs im expandierten Zustand beträgt. Das Zusammenschieben der Kartuschenwände 4, 5 kann dabei, insbesondere bei abgeschraubter Schraubkappe 15 durch eine im Folgenden noch näher beschriebene Austragvorrichtung erfolgen.According to the invention, the cartridge walls 4, 5 are pushed together before being filled with the medium to be discharged in the longitudinal direction of the receiving chambers 2, 3 until the cartridge is in its collapsed state in which the receiving chambers 2, 3 each have their minimum volume occupies. This collapsed state is in Fig. 2 shown. From the comparison of Fig. 1 and 2 becomes immediately clear that the space requirement of the cartridge 1 and the receiving chambers 2, 3 in the collapsed state is only about 20% of the space required in the expanded state. The pushing together of the cartridge walls 4, 5 can, in particular when screw cap 15 is unscrewed by a discharge device described in more detail below.

Fig. 3 zeigt eine gegenüber den Fig. 1 und 2 geringfügig abgewandelte Kartusche 1. Der einzige Unterschied besteht darin, dass im Bereich der Auslässe 13, 14 keine Schraubverbindung zum Befestigen der Schraubkappe 15, sondern eine Bajonettverbindung zum Befestigen einer Verschlusskappe mit Bajonettverschluss vorgesehen ist. Die Ausgestaltung der Befestigungsart durch Verschraubung oder durch eine Bajonettverbindung ist für die vorliegende Erfindung nicht relevant. Darüber hinaus umfasst auch eine Bajonettbefestigung neben einer Steckbewegung eine sich daran anschließende Dreh- bzw. Schraubbewegung, so dass im Folgenden zur Vereinfachung einheitlich die Begriffe "Schraubkappe" bzw. "Schraubansatz" verwendet werden, auch wenn eine Bajonettbefestigung der Verschlusskappe gezeigt ist. In Fig. 3 ist aufgrund der abgenommenen Schraubkappe 15 zu erkennen, dass sich die Auslässe 13, 14 bis zu einem stirnseitigen freien Ende eines Schraubansatzes 16 erstrecken, auf den die Schraubkappe 15 aufschraubbar ist. Über die Auslässe 13, 14 ist eine Frontbefüllung der sich in ihrem kollabierten Zustand befindenden Kartusche 1 möglich, wobei durch das eingefüllte Medium die Kartusche 1 automatisch in ihren in Fig. 3 dargestellten expandierten Zustand überführt wird. Fig. 3 shows one opposite the Fig. 1 and 2 slightly modified cartridge 1. The only difference is that in the region of the outlets 13, 14 no screw connection for fastening the screw cap 15, but a bayonet connection for attaching a cap with bayonet closure is provided. The design of the fastening by screwing or by a bayonet connection is not relevant to the present invention. In addition, a bayonet attachment in addition to a plugging movement includes an adjoining rotational or screwing, so that in the following for simplicity uniformly the terms "screw" or "Schraubansatz" are used, even if a bayonet attachment of the cap is shown. In Fig. 3 can be seen due to the removed screw cap 15 that the outlets 13, 14 extend to a frontal free end of a screw 16, to which the screw cap 15 can be screwed. About the outlets 13, 14 is a front filling of the cartridge located in its collapsed state 1 is possible, with the cartridge filled by 1 automatically in their in Fig. 3 shown expanded state is transferred.

Fig. 4 zeigt eine Austragvorrichtung 17, in die die erfindungsgemässe Kartusche 1 einsetzbar ist. Die Austragvorrichtung 17 umfasst eine Zweikomponenten-Stützkartusche 18, an deren Stirnseite zwei Aufnahmeöffnungen 19, 20 für die Kartusche 1 ausgebildet sind. Wie in Fig. 5 dargestellt kann die Kartusche 1 mit ihren Kartuschenwänden 4, 5 soweit in die Aufnahmeöffnungen eingeschoben werden, bis das Kopfteil 6 an der Stirnseite der Stützkartusche 18 anliegt. Fig. 4 shows a discharge device 17, in which the cartridge 1 according to the invention can be used. The discharge device 17 comprises a two-component support cartridge 18, on whose front side two receiving openings 19, 20 are formed for the cartridge 1. As in Fig. 5 the cartridge 1 with its cartridge walls 4, 5 can be pushed into the receiving openings until the head part 6 bears against the end face of the support cartridge 18.

Anschliessend kann die Stützkartusche 18 zusammen mit der eingeschobenen Kartusche 1 um eine Schwenkachse 21 verschwenkt werden, so dass sie im Inneren eines Gehäuseabschnitts 22 der Austragvorrichtung 17 zu liegen kommt, wie es in Fig. 6 dargestellt ist. Der Schraubansatz 16 ragt dabei durch eine stirnseitige Öffnung 23 in dem Gehäuseabschnitt 22 hindurch, sodass zum Austragen des in den Aufnahmekammern 2, 3 vorhandenen Medium eine nicht dargestellte Mischerspitze auf den Schraubansatz 16 aufgeschraubt werden kann. Anschliessend kann in an sich bekannter Weise durch wiederholtes Betätigen eines Betätigungshebels 24 ein Ratschenschieber 25, an dessen vorderen Ende zwei plattenförmige Vorschubkolben 26, 27 vorgesehen sind, in Richtung zu dem vorderen Ende der Austragvorrichtung 17 verschoben werden, wodurch die in den Aufnahmekammern 2, 3 vorhandene Füllmasse durch die Auslässe 13, 14 ausgetragen und anschliessend durch die Mischerspitze vermischt werden.Subsequently, the support cartridge 18 can be pivoted together with the inserted cartridge 1 about a pivot axis 21, so that they are inside a housing portion 22 of the discharge 17 comes to rest, as it is in Fig. 6 is shown. The screw lug 16 protrudes through an end opening 23 in the housing portion 22, so that for discharging the present in the receiving chambers 2, 3 medium, a mixer tip, not shown, can be screwed onto the screw boss 16. Subsequently, in a conventional manner by repeated actuation of an actuating lever 24, a ratchet slide 25, at the front end of two plate-shaped feed piston 26, 27 are provided, are displaced in the direction of the front end of the discharge 17, whereby in the receiving chambers 2, 3rd existing filling material discharged through the outlets 13, 14 and then mixed by the mixer tip.

Aus Fig. 7 ist in einem Schritt 1 "Herstellung" angedeutet, dass durch die Ausgestaltung der Kartuschenwand als Folie Herstellungskosten gegenüber einer Kartusche mit formstabiler Kartuschenwand deutlich eingespart werden können. Durch die Überführung der leeren Kartusche direkt nach ihrer Herstellung in ihren kollabierten Zustand wird der Platzbedarf gemäss Schritt 2 "Lagerung (leer)" um ca. 80% verringert, wodurch die Lagerkosten entsprechend reduziert werden. In entsprechender Weise werden beim Transport der leeren, kollabierten Kartuschen zu den Medienherstellern ca. 80% an Volumen und Gewicht eingespart, wie es in Schritt 3 "Transport (leer)" angedeutet ist. Erst beim anschliessenden Befüllen der Kartuschen (Schritt 4 "Befüllung") werden die Kartuschen wieder expandiert, so dass beim nachfolgenden Transport (Schritt 5 "Transport (befüllt)") lediglich eine 15%ige Gewichtsreduktion aufgrund der verwendeten Folie gegeben ist. Die nachfolgenden Schritte 6 "Lagerung (befüllt)" und 7 "Anwendung" erfolgen dann in bekannter Weise, während im Schritt 8 "Abfallentsorgung" wiederum eine ca. 80%ige Volumenreduktion gegenüber Kartuschen mit formstabiler Kartuschenwand besteht.Out Fig. 7 is indicated in a step 1 "production" that can be significantly saved by the design of the cartridge wall as a film manufacturing costs compared to a cartridge with dimensionally stable cartridge wall. By transferring the empty cartridge directly after its production in its collapsed state, the space required in step 2 "storage (empty)" is reduced by about 80%, whereby the storage costs are reduced accordingly. Similarly, when transporting the empty, collapsed cartridges to the media manufacturers about 80% in volume and weight saved, as it is indicated in step 3 "Transport (empty)". Only during the subsequent filling of the cartridges (step 4 "filling") the cartridges are expanded again, so that in the subsequent transport (step 5 "transport (filled)") only a 15% weight reduction due to the film used is given. The subsequent steps 6 "storage (filled)" and 7 "application" then take place in a known manner, while in step 8 "waste disposal" again there is an approximately 80% volume reduction compared to cartridges with dimensionally stable cartridge wall.

BezugszeichenlisteLIST OF REFERENCE NUMBERS

11
Kartuschecartridge
22
Aufnahmekammerreceiving chamber
33
Aufnahmekammerreceiving chamber
44
Kartuschenwandcartridge wall
55
Kartuschenwandcartridge wall
66
Kopfteilheadboard
77
EndeThe End
88th
EndeThe End
99
Klemmringclamping ring
1010
Klemmringclamping ring
1111
EndeThe End
1212
EndeThe End
1313
Auslassoutlet
1414
Auslassoutlet
1515
Schraubkappescrew cap
1616
Schraubansatzscrew attachment
1717
Austragvorrichtungdischarge
1818
Zweikomponenten-StützkartuscheTwo-component cartridge support
1919
Aufnahmeöffnungreceiving opening
2020
Aufnahmeöffnungreceiving opening
2121
Schwenkachseswivel axis
2222
Gehäuseabschnitthousing section
2323
Öffnungopening
2424
Betätigungshebelactuating lever
2525
Ratschenschieberratchet slide
2626
Vorschubkolbenfeed piston
2727
Vorschubkolbenfeed piston

Claims (15)

  1. A cartridge (1) having a reception chamber (2, 3) extending in a longitudinal direction for a medium to be dispensed having a head part (6) and a cartridge wall (4, 5) which bound the reception chamber (2, 3), wherein the head part (6) has an outlet (13, 14) for the medium, the cartridge wall (4, 5) is configured at least regionally as a film and the head part (6) is configured as a stable-shape part and the head part (6) is sealingly and in particular unreleasably connected to the cartridge wall (4, 5), with the cartridge (1) being configured as a collapsible cartridge (1), i.e. with it being able to be converted from an expanded state in which the reception chamber (2, 3) has a maximum volume into a collapsed state in which the reception chamber (3, 4) has a minimal volume;
    and wherein the cartridge (1) not yet filled with medium is in its collapsed state,
    characterized in that
    the space requirements of the not yet filled reception chamber (2, 3) in the collapsed state only amounts to 30% or less, in particular only 25% or less, preferably only 20% or less, of the space requirements of the reception chamber (2, 3) in the expanded state.
  2. A cartridge (1) having a reception chamber (2, 3) extending in the longitudinal direction for a medium to be dispensed having a head part (6) and a cartridge wall (4, 5) which bound the reception chamber (2, 3), wherein the head part (6) has an outlet (13, 14) for the medium, the cartridge wall (4, 5) is configured at least regionally as a film and the head part (6) is configured as a stable-shape part and the head part (6) is sealingly and in particular unreleasably connected to the cartridge wall (4, 5), with the cartridge (1) being configured as a collapsible cartridge (1), i.e. with it being able to be converted from an expanded state in which the reception chamber (2, 3) has a maximum volume into a collapsed state in which the reception chamber (3, 4) has a minimal volume;
    and wherein the cartridge (1) not yet filled with medium is in its collapsed state,
    characterized in that
    the space requirements of the not yet filled cartridge (1) in the collapsed state only amounts to 30% or less, in particular only 25% or less, preferably only 20% or less, of the space requirements of the cartridge (1) in the expanded state.
  3. A cartridge in accordance with claim 1 or claim 2,
    characterized in that
    the cartridge wall (4, 5) is pushed together, in particular like a concertina, in the longitudinal direction of the reception chamber (2, 3) in the collapsed state of the cartridge (1).
  4. A cartridge in accordance with at least one of the preceding claims,
    characterized in that
    the cartridge (1) is configured as a single-component cartridge having a reception chamber or as a multicomponent cartridge having a plurality of reception chambers (2, 3), in particular as a two-component cartridge having two reception chambers (2, 3).
  5. A cartridge in accordance with claim 4,
    characterized in that,
    in the case of a multicomponent cartridge, a separate head part is associated with each reception chamber and its outlet is respectively in fluid communication with the reception chamber associated with it;
    or
    in that, in the case of a multicomponent cartridge, a uniform common head part (6) is associated with the reception chambers (2, 3), with the head part (6) having a plurality of outlets (13, 14) of which a respective one is in fluid communication with a respective one reception chamber (2, 3).
  6. A cartridge in accordance with at least one of the preceding claims,
    characterized in that
    the head part (6) is injection molded to the cartridge wall (4, 5); and in that the end (7, 8) of the hose-shaped cartridge wall (4, 5) disposed remote from the head part (6) is sealingly closed by a crimp connection or by a clamp connection.
  7. A method for manufacturing a cartridge in accordance with at least one of the preceding claims,
    wherein
    the cartridge wall (4, 5) is sealingly and unreleasably connected to the head part (6) for producing the cartridge (1) in its expanded state; and wherein the wall (4, 5) of the not yet filled cartridge is pushed together after the production of the cartridge (1) in its expanded state such that the cartridge (1) is converted into its collapsed state in which the reception chamber (2, 3) has its minimal volume.
  8. A method in accordance with claim 7,
    characterized in that
    the cartridge (1) not yet filled with medium is stored and/or is transported to a filling apparatus in its collapsed state.
  9. A method in accordance with claim 7 or claim 8,
    characterized in that
    the end (7, 8) of the cartridge wall (4, 5) disposed remote from the head part (6) is sealingly closed before the pushing together.
  10. A method in accordance with claim 7, claim 8 or claim 9,
    characterized in that
    the cartridge wall (4, 5) is pushed together in the longitudinal direction of the reception chamber (2, 3).
  11. A method in accordance with at least one of the claims 7 to 10, characterized in that
    a predefined pressure is generated in the reception chamber (2, 3) and the pushing together of the cartridge wall (4, 5) takes place against the pressure.
  12. A method in accordance with claim 11,
    characterized in that
    the pressure is gradually reduced on the pushing together; and in particular in that the pressure is selected as so high that the cartridge wall (4, 5) is substantially folded together like a concertina on the pushing together.
  13. A method in accordance with at least one of the claims 7 to 12,
    characterized in that
    the medium is filled into the reception chamber (2, 3) through the outlet (13, 14) in the head part (6) for filling the cartridge (1); and in particular in that the cartridge wall (4, 5) is pushed apart again by the filling of the cartridge (1) so that the cartridge (1) is converted from its collapsed state into a partly expanded state or into its expanded state.
  14. A method for manufacturing a cartridge (1) having a reception chamber (2, 3) extending in the longitudinal direction for a medium to be dispensed having a head part (6) and a cartridge wall (4, 5) which bound the reception chamber (2, 3), wherein the head part (6) has an outlet (13, 14) for the medium, the cartridge wall (4, 5) is configured at least regionally as a film and the head part (6) is configured as a stable-shape part and the head part (6) is sealingly and in particular unreleasably connected to the cartridge wall (4, 5), with the cartridge (1) being configured as a collapsible cartridge (1), i.e. with it being able to be converted from an expanded state in which the reception chamber (2, 3) has a maximum volume into a collapsed state in which the reception chamber (3, 4) has a minimal volume; and wherein the cartridge (1) not yet filled with medium is in its collapsed state, said method in particular for manufacturing a cartridge in accordance with at least one of the claims 1 to 6,
    wherein the cartridge wall (4, 5) is sealingly and unreleasably connected to the head part (6) for producing the cartridge (1) in its expanded state; and wherein the cartridge wall (4, 5) is pushed together after the production of the cartridge (1) in its expanded state such that the cartridge (1) is converted into its collapsed state in which the reception chamber (2, 3) has its minimal volume,
    characterized in that
    the cartridge (1) not yet filled with medium is stored and/or is transported to a filling apparatus in its collapsed state.
  15. A method for manufacturing a cartridge (1) having a reception chamber (2, 3) extending in the longitudinal direction for a medium to be dispensed having a head part (6) and a cartridge wall (4, 5) which bound the reception chamber (2, 3), wherein the head part (6) has an outlet (13, 14) for the medium, the cartridge wall (4, 5) is configured at least regionally as a film and the head part (6) is configured as a stable-shape part and the head part (6) is sealingly and in particular unreleasably connected to the cartridge wall (4, 5), with the cartridge (1) being configured as a collapsible cartridge (1), i.e. with it being able to be converted from an expanded state in which the reception chamber (2, 3) has a maximum volume into a collapsed state in which the reception chamber (3, 4) has a minimal volume; and wherein the cartridge (1) not yet filled with medium is in its collapsed state, said method in particular for manufacturing a cartridge in accordance with at least one of the claims 1 to 6,
    wherein the cartridge wall (4, 5) is sealingly and unreleasably connected to the head part (6) for producing the cartridge (1) in its expanded state; and wherein the cartridge wall (4, 5) is pushed together after the production of the cartridge (1) in its expanded state such that the cartridge (1) is converted into its collapsed state in which the reception chamber (2, 3) has its minimal volume,
    wherein a predefined pressure is generated in the reception chamber (2, 3) and the pushing together of the cartridge wall (4, 5) takes place against the pressure,
    characterized in that
    the pressure is gradually reduced on the pushing together.
EP15712136.9A 2014-03-31 2015-03-25 Cartridge and method for producing a cartridge Active EP3102503B1 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
PL15712136T PL3102503T3 (en) 2014-03-31 2015-03-25 Cartridge and method for producing a cartridge

Applications Claiming Priority (2)

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EP14162975.8A EP2927156A1 (en) 2014-03-31 2014-03-31 Cartridge and method for producing a cartridge
PCT/EP2015/056459 WO2015150196A1 (en) 2014-03-31 2015-03-25 Cartridge and method for producing a cartridge

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EP3102503B1 true EP3102503B1 (en) 2017-07-19

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US (1) US9975139B2 (en)
EP (2) EP2927156A1 (en)
JP (1) JP6178021B2 (en)
KR (1) KR101767429B1 (en)
CN (1) CN106458424B (en)
BR (1) BR112016022823B8 (en)
CA (1) CA2942622C (en)
ES (1) ES2644046T3 (en)
NO (1) NO3102503T3 (en)
PL (1) PL3102503T3 (en)
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WO (1) WO2015150196A1 (en)

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ES2698549T3 (en) * 2016-07-01 2019-02-05 Sulzer Mixpac Ag Cartridge, core, mold and method of manufacturing a cartridge
EP3263483A1 (en) * 2016-07-01 2018-01-03 Sulzer Mixpac AG Cartridge, core, mold and method of manufacturing a cartridge
US10968031B2 (en) * 2017-12-27 2021-04-06 Sulzer Mixpac Ag Piston for a collapsible cartridge
EP3632575A1 (en) * 2018-10-02 2020-04-08 Sulzer Mixpac AG Reusable cartridge piston
BR112021005499A2 (en) * 2018-10-02 2021-06-15 Sulzer Mixpac Ag cartridge, dispensing assembly and method of manufacturing a cartridge
US10870127B2 (en) * 2018-10-02 2020-12-22 Sulzer Mixpac Ag Cartridge for a mixing and dispensing system
WO2020069806A1 (en) * 2018-10-02 2020-04-09 Sulzer Mixpac Ag Cartridge for a one or two-component mixing and dispensing system
EP3833614A1 (en) * 2018-10-02 2021-06-16 Sulzer Mixpac AG Cartridge, method of manufacturing a cartridge, dispensing assembly and method of assembling a dispensing assembly
EP3714994A1 (en) * 2019-03-26 2020-09-30 Sulzer Mixpac AG Piston, cartridge, dispenser
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EP3835232A1 (en) * 2019-12-13 2021-06-16 Hilti Aktiengesellschaft Cartridge and method for producing a cartridge
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Publication number Publication date
CN106458424B (en) 2019-11-19
PL3102503T3 (en) 2017-12-29
ES2644046T3 (en) 2017-11-27
KR20160134852A (en) 2016-11-23
CN106458424A (en) 2017-02-22
TWI722982B (en) 2021-04-01
KR101767429B1 (en) 2017-08-11
BR112016022823B8 (en) 2023-03-21
BR112016022823A2 (en) 2017-08-15
WO2015150196A1 (en) 2015-10-08
TW201600413A (en) 2016-01-01
JP6178021B2 (en) 2017-08-09
US9975139B2 (en) 2018-05-22
BR112016022823B1 (en) 2021-08-29
US20170216874A1 (en) 2017-08-03
NO3102503T3 (en) 2017-12-16
CA2942622C (en) 2018-01-16
JP2017512727A (en) 2017-05-25
EP3102503A1 (en) 2016-12-14
CA2942622A1 (en) 2015-10-08
EP2927156A1 (en) 2015-10-07

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