Classifications

• • D—TEXTILES; PAPER
  • D07—ROPES; CABLES OTHER THAN ELECTRIC
  • D07B—ROPES OR CABLES IN GENERAL
  • D07B1/00—Constructional features of ropes or cables
  • D07B1/06—Ropes or cables built-up from metal wires, e.g. of section wires around a hemp core
  • D07B1/0606—Reinforcing cords for rubber or plastic articles
  • D07B1/066—Reinforcing cords for rubber or plastic articles the wires being made from special alloy or special steel composition
• • B—PERFORMING OPERATIONS; TRANSPORTING
  • B32—LAYERED PRODUCTS
  • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
  • B32B15/00—Layered products comprising a layer of metal
  • B32B15/01—Layered products comprising a layer of metal all layers being exclusively metallic
  • B32B15/013—Layered products comprising a layer of metal all layers being exclusively metallic one layer being formed of an iron alloy or steel, another layer being formed of a metal other than iron or aluminium
• • B—PERFORMING OPERATIONS; TRANSPORTING
  • B32—LAYERED PRODUCTS
  • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
  • B32B15/00—Layered products comprising a layer of metal
  • B32B15/01—Layered products comprising a layer of metal all layers being exclusively metallic
  • B32B15/013—Layered products comprising a layer of metal all layers being exclusively metallic one layer being formed of an iron alloy or steel, another layer being formed of a metal other than iron or aluminium
  • B32B15/015—Layered products comprising a layer of metal all layers being exclusively metallic one layer being formed of an iron alloy or steel, another layer being formed of a metal other than iron or aluminium the said other metal being copper or nickel or an alloy thereof
• • C—CHEMISTRY; METALLURGY
  • C21—METALLURGY OF IRON
  • C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
  • C21D8/00—Modifying the physical properties by deformation combined with, or followed by, heat treatment
  • C21D8/06—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of rods or wires
  • C21D8/065—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of rods or wires of ferrous alloys
• • C—CHEMISTRY; METALLURGY
  • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
  • C22C—ALLOYS
  • C22C38/00—Ferrous alloys, e.g. steel alloys
  • C22C38/001—Ferrous alloys, e.g. steel alloys containing N
• • C—CHEMISTRY; METALLURGY
  • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
  • C22C—ALLOYS
  • C22C38/00—Ferrous alloys, e.g. steel alloys
  • C22C38/02—Ferrous alloys, e.g. steel alloys containing silicon
• • C—CHEMISTRY; METALLURGY
  • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
  • C22C—ALLOYS
  • C22C38/00—Ferrous alloys, e.g. steel alloys
  • C22C38/04—Ferrous alloys, e.g. steel alloys containing manganese
• • C—CHEMISTRY; METALLURGY
  • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
  • C22C—ALLOYS
  • C22C38/00—Ferrous alloys, e.g. steel alloys
  • C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
  • C22C38/40—Ferrous alloys, e.g. steel alloys containing chromium with nickel
  • C22C38/44—Ferrous alloys, e.g. steel alloys containing chromium with nickel with molybdenum or tungsten
• • C—CHEMISTRY; METALLURGY
  • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
  • C22C—ALLOYS
  • C22C38/00—Ferrous alloys, e.g. steel alloys
  • C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
  • C22C38/40—Ferrous alloys, e.g. steel alloys containing chromium with nickel
  • C22C38/54—Ferrous alloys, e.g. steel alloys containing chromium with nickel with boron
• • B—PERFORMING OPERATIONS; TRANSPORTING
  • B60—VEHICLES IN GENERAL
  • B60C—VEHICLE TYRES; TYRE INFLATION; TYRE CHANGING; CONNECTING VALVES TO INFLATABLE ELASTIC BODIES IN GENERAL; DEVICES OR ARRANGEMENTS RELATED TO TYRES
  • B60C9/00—Reinforcements or ply arrangement of pneumatic tyres
  • B60C9/0007—Reinforcements made of metallic elements, e.g. cords, yarns, filaments or fibres made from metal
• • C—CHEMISTRY; METALLURGY
  • C21—METALLURGY OF IRON
  • C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
  • C21D2211/00—Microstructure comprising significant phases
  • C21D2211/005—Ferrite
• • C—CHEMISTRY; METALLURGY
  • C21—METALLURGY OF IRON
  • C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
  • C21D2211/00—Microstructure comprising significant phases
  • C21D2211/009—Pearlite
• • D—TEXTILES; PAPER
  • D07—ROPES; CABLES OTHER THAN ELECTRIC
  • D07B—ROPES OR CABLES IN GENERAL
  • D07B2205/00—Rope or cable materials
  • D07B2205/30—Inorganic materials
  • D07B2205/3021—Metals
  • D07B2205/3025—Steel
  • D07B2205/3035—Pearlite
• • D—TEXTILES; PAPER
  • D07—ROPES; CABLES OTHER THAN ELECTRIC
  • D07B—ROPES OR CABLES IN GENERAL
  • D07B2205/00—Rope or cable materials
  • D07B2205/30—Inorganic materials
  • D07B2205/3021—Metals
  • D07B2205/3025—Steel
  • D07B2205/3042—Ferrite
• • D—TEXTILES; PAPER
  • D07—ROPES; CABLES OTHER THAN ELECTRIC
  • D07B—ROPES OR CABLES IN GENERAL
  • D07B2205/00—Rope or cable materials
  • D07B2205/30—Inorganic materials
  • D07B2205/3021—Metals
  • D07B2205/3025—Steel
  • D07B2205/3046—Steel characterised by the carbon content
  • D07B2205/305—Steel characterised by the carbon content having a low carbon content, e.g. below 0,5 percent respectively NT wires

Definitions

• a process for drawing a steel wire comprising a carbon content by weight of between 0.05% inclusive and 0.4% excluded
• the invention relates to a wire drawing process of a steel wire, in particular for a tire.
• a carcass reinforcement tire for example radial, comprises a tread, two inextensible beads, two flanks connecting the beads to the tread and a crown reinforcement disposed circumferentially between the carcass reinforcement and the body. tread.
• the crown and / or carcass reinforcement comprises one or more rubber plies, possibly reinforced by reinforcement elements or reinforcements such as single metal wires or metal cables coming from the assembly of several single metal wires.
• the metal reinforcements are made of steel.
• the crown reinforcement generally consists of at least two superimposed vertex plies, sometimes called “working” or “crossed” plies, whose reinforcement cables, generally metallic, are arranged substantially parallel to each other. to others within a web, but crossed from one web to another, that is to say inclined, symmetrically or otherwise, with respect to the median circumferential plane, of an angle which is generally understood between 10 ° and 45 ° depending on the type of tire.
• the crossed plies may be supplemented by various other plies or layers of auxiliary rubber, of varying widths depending on the case, with or without reinforcements.
• protection plies responsible for protecting the rest of the crown reinforcement from external aggressions, perforations, or so-called “hooping” plies comprising reinforcements oriented substantially in the circumferential direction (so-called “zero degree” plies), whether radially external or internal to the crossed plies.
• the invention aims to provide a metal reinforcement less sensitive to fatigue and corrosion.
• the wire used has a relatively low mass C of carbon.
• wire drawability is improved, i.e. the possibility of obtaining a relatively small diameter d from a relatively large diameter.
• the relatively low mass C of carbon mass allows a rational deformation ⁇ 'high which allows to sufficiently wet the wire to impart sufficient or even high mechanical strength properties, including a maximum stress before breaking sufficiently high.
• the yarn obtained by the process according to the invention is much less sensitive to fatigue and corrosion which improves the endurance of the tire and offsets its initial deficit in maximum stress before rupture.
• the maximum breaking stress or breaking strength is the force required to break the wire.
• the measurements of maximum stress before rupture denoted R (in MPa) are carried out according to the ISO 6892 standard of 1984.
• uninterrupted series of drawing steps it is meant that the wire performs a series of successive passages in several drawing dies, each passage in each drawing die corresponding to a drawing step. Apart from the last passage, each passage in a sector is followed directly by a passage in the chain that follows.
• the wire undergoes no steps, in particular heat treatment or coating, other than a drawing step between two drawing steps of the series. In other words, the wire undergoes no steps, in particular heat treatment or coating, between two directly successive drawing steps of the series.
• the micro-structure of the steel is integrally ferrite, pearlite or a mixture of these microstructures. This microstructure is preferably observed on the diameter wire.
• the micro-structure of the steel is devoid of martensite and / or bainite.
• a ferritic-martensitic microstructure causes decohesion between the ferritic and martensitic phases, which is undesirable.
• a martensitic microstructure is not sufficiently ductile to allow wire drawing which would break too frequently.
• a ferritic, pearlitic or ferrito-pearlitic micro-structure can be distinguished from another micro-structure, in particular martensitic or bainitic, by metallographic observation, preferably on the diameter wire.
• the ferritol pearlitic microstructure has ferrite grains as well as lamellar pearlitic zones.
• the martensitic micro-structure comprises slats and / or needles which those skilled in the art will be able to distinguish between ferrite-pearlitic and pearlitic micro-structures from grains and lamellae.
• the microstructure of the steel is entirely ferrito- pearlitic.
• the wire is made of steel, that is to say that it consists mainly (that is to say for more than 50% by weight) or completely (for 100% by weight) of steel such as defined in standard NF EN10020.
• a steel is a material containing more iron than any other element and with a carbon content of less than 2% and contains other alloying elements.
• the steel optionally includes other alloying elements.
• the steel is a non-alloy steel as defined in the NF EN10020 standard.
• the steel comprises, in addition to carbon and iron, other known alloying elements in quantities in accordance with the NF EN10020 standard.
• the steel is an alloy steel as defined in the NF EN10020 standard.
• the steel comprises, in addition to carbon and iron, other known alloying elements.
• the steel is a stainless steel as defined in the NF EN 10020 standard.
• the steel comprises at least 10.5% by weight of chromium and at most 1, 2% by mass of carbon.
• ⁇ ' ⁇ 4.3 preferably ⁇ ' ⁇ 4.5 and more preferably ⁇ ' ⁇ 5.
• the yarn has a carbon content in mass C such that 0.07% ⁇ C ⁇ 0.3%, preferably 0.1% ⁇ C ⁇ 0.3% and more preferably 0 , 15% ⁇ C ⁇ 0.25%.
• - d ' is greater than or equal to 1 mm and preferably to 1, 3 mm.
• the diameter of is large enough to obtain high mechanical properties by hardening the wire.
• d is less than or equal to 2.5 mm, preferably 2.2 mm and more preferably less than 2 mm.
• the diameter of is small enough to allow the work hardening to the final diameter of the wire.
• d is greater than or equal to 0.10 mm and preferably 0.12 mm.
• d is less than or equal to 0.40 mm, preferably 0.25 mm, more preferably 0.23 mm and even more preferentially 0.20 mm.
• the uninterrupted series of wire drawing steps is carried out from the diameter of the diameter to the wet diameter.
• the wire By drawing in a humid medium, it is understood that the wire circulates in a liquid medium, for example an aqueous solution.
• a liquid medium for example an aqueous solution.
• the drawing lubricant in a wet drawing is in liquid form.
• the traction means for example capstans, are exposed to the liquid medium, for example the aqueous solution.
• the method comprises, before the series of wire drawing steps of the diameter diameter diameter, an uninterrupted series of wire drawing steps of a diameter D to the diameter of.
• the wire undergoes no steps, in particular heat treatment or coating, other than a drawing step between two drawing steps of the series.
• the wire undergoes no steps, in particular heat treatment or coating, between two directly successive drawing steps of the series.
• one carries out the series of steps of wire drawing of the diameter of the wire towards the diameter of in dry medium.
• the wire circulates in a gaseous medium, for example ambient air.
• a gaseous medium for example ambient air.
• the drawing lubricant during drawing in a dry medium is in pulverulent form.
• the means of traction for example capstans, are exposed to the ambient air.
• the rational strain ⁇ 2. ⁇ (D / d) is such that ⁇ 6.5, preferably ⁇ ⁇ 6.75 and more preferably ⁇ ⁇ 7.2 and even more preferably ⁇ 7 5.
• D is greater than or equal to 4 mm, preferably 5 mm.
• the wire of diameter is advantageously heat treated.
• the wire of diameter is coated with at least one metal layer.
• the invention also relates to a wire that can be obtained from the method according to the invention.
• the son or strands undergo both a collective twist and an individual twist around their own axis, which generates a torque of untwisting each of the son or strands.
• One can also obtain a semi-finished element comprising a rubber matrix in which is embedded at least one wire obtained by the method according to the invention.
• the rubber matrix comprises at least one diene elastomer, a reinforcing filler, a vulcanization system and various additives.
• diene elastomer of the rubber matrix is generally meant an elastomer derived at least in part (ie a homopolymer or a copolymer) of monomers dienes (monomers bearing two carbon-carbon double bonds, conjugated or not) .
• the diene elastomers in known manner, can be classified into two categories: those called “essentially unsaturated” and those said “essentially saturated”.
• the diene elastomer of the rubber matrix is chosen from the group of diene elastomers (essentially unsaturated) consisting of polybutadienes (BR), synthetic polyisoprenes (IR), natural rubber (NR), copolymers of butadiene, isoprene copolymers and mixtures of these elastomers.
• Such copolymers are more preferably selected from the group consisting of butadiene-styrene copolymers (SBR), isoprene-butadiene copolymers (BIR), isoprene-styrene copolymers (SIR), isoprene-copolymers of butadiene-styrene (SBIR) and mixtures of such copolymers.
• SBR butadiene-styrene copolymers
• BIR isoprene-butadiene copolymers
• SIR isoprene-styrene copolymers
• SBIR isoprene-copolymers of butadiene-styrene
• the rubber matrix may contain a single diene elastomer or a mixture of several diene elastomers, or the diene elastomers may be used in combination with any type of synthetic elastomer other than diene, or even with polymers other than elastomers for example thermoplastic polymers.
• carbon black or an inorganic filler preference is given to carbon black or an inorganic filler. More particularly, carbon blacks are suitable for all carbon blacks, especially blacks of the HAF, ISAF, SAF type conventionally used in tires. By way of nonlimiting examples of such blacks, mention may be made of N115, N134, N234, N330, N339, N347 and N375 blacks. However, the carbon black can of course be used in cutting with reinforcing fillers and in particular other inorganic fillers. Such inorganic fillers include silica, especially highly dispersible silicas.
• inert fillers such as clay particles, bentonite, talc, chalk, kaolin, usable for example in flanks or strips of colored tire bearing.
• the rubber matrix may also comprise all or part of the usual additives usually used in elastomer compositions intended for the manufacture of tires, for example plasticizers or extension oils, which are of aromatic nature. or non-aromatic, pigments, protective agents such as anti-ozone waxes, chemical antiozonants, anti-oxidants, anti-fatigue agents, reinforcing resins, acceptors (eg novalaque phenolic resin) or donors methylene (eg HMT or H3M).
• plasticizers or extension oils which are of aromatic nature. or non-aromatic, pigments, protective agents such as anti-ozone waxes, chemical antiozonants, anti-oxidants, anti-fatigue agents, reinforcing resins, acceptors (eg novalaque phenolic resin) or donors methylene (eg HMT or H3M).
• the rubber matrix also comprises a vulcanization system based on either sulfur, or sulfur and / or peroxide donors and / or bismaleimides, vulcanization accelerators, vulcanization activators.
• the vulcanization system itself is preferably based on sulfur and a primary vulcanization accelerator, in particular a sulfenamide type accelerator, as selected from the group consisting of 2-mercaptobenzothiazyl disulfide (MBTS).
• a primary vulcanization accelerator in particular a sulfenamide type accelerator, as selected from the group consisting of 2-mercaptobenzothiazyl disulfide (MBTS).
• MBTS 2-mercaptobenzothiazyl disulfide
• CBS N-cyclohexyl-2-benzothiazyl sulfenamide
• DCBS N, N-dicyclohexyl-2-benzothiazyl sulfenamide
• TBBS N-tert-butyl-2-benzothiazyl sulfenamide
• TBSI N-tert-butyl-2-benzothiazyl sulfenimide
• the invention also relates to a tire comprising a wire that can be obtained by the method according to the invention.
• the tire is intended for passenger vehicles, industrial vehicles chosen from light trucks, heavy vehicles such as "heavy goods vehicles” - ie, metro, buses, road transport vehicles (trucks, tractors, trailers). , off-the-road vehicles -, agricultural or engineering machinery, aircraft, other transport or handling vehicles. More preferably, the tire is intended for heavy vehicles, agricultural or civil engineering machinery, aircraft, other transport vehicles or handling.
• the wire is intended to reinforce a crown reinforcement and / or tire carcass. More preferably, the wire is intended to reinforce a tire carcass reinforcement.
• the tire is for heavy-vehicle type vehicle comprising a carcass reinforcement comprising at least one wire obtained by the method according to the invention.
• Figure 1 a sectional view perpendicular to the circumferential direction of a tire comprising a wire obtainable by the method according to the invention
• FIG. 2 is a diagram illustrating steps of a drawing process according to the invention.
• Fig. 3 is an optical microscope view of a ferritol pearlitic microstructure
• Figure 4 is a scanning electron microscope view of a ferrito-pearlitic microstructure
• Figure 5 is an optical microscope view of an acicular ferritic micro-structure (so-called Windmanstatten).
• the tire 10 has a vertex 12 reinforced by a crown reinforcement 14, two sidewalls 16 and two beads 18, each of these beads 18 being reinforced with a rod 20.
• the top 12 is surmounted by a tread not represented in this schematic figure.
• a carcass reinforcement 22 is wound around the two rods 20 in each bead 18 and comprises an upturn 24 disposed towards the outside of the tire 10 which is shown here mounted on a rim 26.
• the carcass reinforcement 22 is in known manner constituted by at least one sheet reinforced by son or cables. These wires or cables of the carcass reinforcement are said to be “radial”, that is to say that these wires or cables are arranged practically parallel to each other and extend from one bead to the other to form an angle between 80 ° and 90 ° with the median circumferential plane (plane perpendicular to the axis of rotation of the tire which is located halfway between the two beads 18 and passes through the middle of the crown reinforcement 14 ).
• the crown reinforcement 14 comprises at least one ply reinforced by son or cables according to the invention. In this crown reinforcement 14 schematized in a very simple manner in FIG.
• the son or cables of the invention may, for example, reinforce all or part of the working crown plies, or the plies (or half-plies) vertex triangulation and / or protection top plies, when such triangulation top or protection plies are used.
• the crown reinforcement 14 of the tire of the invention may of course comprise other crown plies, for example one or more crown plies.
• the tire 10 also comprises, in a known manner, a layer of rubber or inner elastomer (commonly called “inner rubber”) which defines the radially inner face of the tire and which is intended to protect the carcass reinforcement of air diffusion from the interior space to the tire.
• inner rubber commonly called “inner rubber”
• it may further comprise an intermediate reinforcing elastomer layer which is located between the carcass reinforcement and the inner layer, intended to reinforce the inner layer and, therefore, the carcass reinforcement, also intended to partially relocate the forces suffered by the carcass reinforcement.
• the tire is manufactured by assembling the various elements described above in the form of semi-finished elements comprising a rubber matrix in which are embedded the son or cables. [070] EXAMPLES OF CABLES COMPRISING WIRES OBTAINED BY THE PROCESS ACCORDING TO THE INVENTION
• crown reinforcement and / or carcass are reinforced by cables, they are manufactured by assembling several son of steel according to the invention, either by wiring or by twisting.
• the crown reinforcement and / or carcass is reinforced by cables according to the invention, chosen in particular from the layered cables of structure 1 + 3 + 8, 1 + 6 + 11, 1 + 6 + 12, 2 + 7, 3 + 8, 3 + 9, 3 + 9 + 15 and strand cables with structure 3 x (1 +5) , (1 +6) x (3 + 8), (1 + 6) x (3 + 9 + 15), (1 + 6) x (4 + 10 + 16).
• cables that can reinforce the crown and / or carcass reinforcement are also described in document WO 2010/139583.
• the crown and / or carcass reinforcement is reinforced by cables according to the invention and in particular chosen from the 2 + 1, 2+ structural cables. 2, 2 + 4 and 4x3.
• the cables according to the invention can be gummed in situ, as described, inter alia, in WO 2010/139583.
• crown and / or carcass reinforcement may also be reinforced by one or more unitary son in accordance with the invention but not assembled.
• the wire is made of steel.
• the steel is a non-alloy steel as defined in the NF EN 10020 standard. Alloy or stainless steel wires as defined in the NF EN10020 standard are also conceivable.
• the steel used can therefore preferably comprise elements of known alloys such as for example Mn, Si, P, S, N, V, Cr, Mo, Ni, B and Co (see for example Research Disclosure 34984 - "Micro-alloyed steel cord constructions for tires” - May 1993, Research Disclosure 34054 - "High tensile strength steel cord constructions for tires” (August 1992) for adapting steel.
• the preferred unalloyed steel according to the NF EN10020 standard comprises at most 1.65% by weight and more preferably between 0.3 and 0.7% by weight of manganese, here 0.583%.
• the preferential unalloyed steel according to the NF EN10020 standard comprises at most 0.60% by weight and more preferably between 0.1 and 0.3% by weight of silicon, in this case 0.161%.
• the preferential unalloyed steel according to the NF EN10020 standard comprises at most 0.10% by weight and more preferably at most 0.045% by weight of phosphorus, here 0.0085%.
• the preferential unalloyed steel conforming to the NF EN10020 standard comprises at most 0.10% by weight and more preferably at most 0.045% by weight of sulfur, here 0.0151%.
• the preferential unalloyed steel according to the NF EN10020 standard comprises at most 0.10% by weight and more preferably at most 0.008% by mass of nitrogen, in this case 0.0029%.
• the preferential unalloyed steel conforming to the NF EN10020 standard comprises at most 0.10% by weight and more preferably at most 0.05% by weight and even more preferably 0.02% of vanadium, in this case 0%.
• the preferential unalloyed steel conforming to the NF EN10020 standard comprises at most 0.30% by weight of chromium.
• the steel used comprises a chromium content in Cr mass such that Cr ⁇ 10.5%, preferably such that Cr ⁇ 5%, more preferably such as Cr ⁇ 1%, and even more preferentially such as Cr ⁇ 0.2%. and here 0.039%.
• the preferential unalloyed steel conforming to the NF EN10020 standard comprises at most 0.08% inclusive, more preferably at most 0.05% included, and even more preferably at most 0.02% inclusive massed terminal of molybdenum, here 0.009%.
• the preferential unalloyed steel conforming to the NF EN10020 standard comprises at most 0.3% inclusive of nickel, in this case 0.026%.
• the preferential unalloyed steel conforming to the NF EN10020 standard comprises at most 0.0008% inclusive of boron by weight, here 0.0002%.
• the preferential unalloyed steel conforming to the NF EN10020 standard comprises at most 0.3% inclusive, preferably at most 0.01% inclusive, and more preferably at most 0.001% inclusive cobalt, here 0%.
• the microstructure of the steel is selected from ferrite, perlite and mixtures of these microstructures.
• the wire is preferably made of ferritobalititic steel, illustrated in FIGS. 3 and 4.
• the steel used comprises a carbon content C, expressed in%, by mass of steel such that 0.05% ⁇ C ⁇ 0.4 %.
• the wire may be coated with a metallic layer, for example improving the properties of use of the wire, or the properties of use of the wire, the cable and / or the tire themselves, such as the properties of the wire. adhesion, resistance to corrosion or resistance to aging.
• the wire is coated with a layer of brass (Cu-Zn alloy) or zinc.
• the wire may be free of metal coating.
• the son of the examples of Table 1 have a diameter d greater than or equal to 0.10 mm and preferably 0.12 mm.
• the son of the examples of Table 1 have a diameter d less than or equal to 0.40 mm, preferably 0.25 mm, more preferably 0.23 mm and even more preferably 0.20 mm.
• the F1 to F4 son are such that R ⁇ 1500 MPa.
• the F1 and F2 wires are such that R ⁇ 1800 MPa and preferably R ⁇ 1900 MPa.
• the son F3 and F4 are such that R ⁇ 2000 MPa and preferably R ⁇ 2100 MPa.
• FIG. 2 is a diagram of a method for drawing wire as described above.
• a steel wire with an initial diameter D ⁇ 4, preferably D ⁇ 5, in this case equal to 5.5 mm and having a maximum breaking stress of between 300 MPa and 700 MPa, in this case R 525 MPa.
• the yarn, called machine wire is stored as a boot on a reel from which it is unrolled by automated unwinding means, for example a unwinder.
• the micro-structure of the steel is ferrito-pearlitic.
• a descaling step 200 of the machine wire the wire rod is passed through several successive pulleys and in two trainers each formed by several pulleys, the pulleys of each blocker being mounted in rotation along an axis perpendicular to the axis. rotation of the pulleys of the other trainer. This removes a layer of iron oxides, called calamine, present on the surface of the wire rod.
• the wire rod is coated with a layer of an adhesion promoter of a drawing lubricant.
• the steps 400i to 400 n are intended to reduce the wire diameter of the initial diameter D to an intermediate diameter of, for example greater or equal to 1 mm and preferably at 1, 3 mm and for example less than or equal to 2.5 mm and preferably to 2.2 mm and more preferably to 2 mm.
• the steps 400i to 400 n form an uninterrupted series of dry medium in steps of drawing of the wire diameter D of the initial to the intermediate diameter.
• Each step 400i to 400 n is in dry wire drawing step in which the wire is passed into a lower diameter die to the diameter of the wire upstream of the die.
• the wire has a diameter downstream of the die less than the diameter upstream of the die.
• the diameter of each die is less than the diameter of the die upstream.
• a drawing lubricant is used in pulverulent form.
• a heat treatment step 500 the metallographic structure of the intermediate diameter wire d is modified to regenerate the structure of the wire rod.
• the skilled person knows how to find the various parameters of this step, for example in "The basic principles of the heat treatment of steels", André Constant and Guy Henry, ISBN 2-85330-083-8.
• the wire of intermediate diameter is heated to a temperature greater than or equal to the austenization temperature of the steel, here greater than or equal to 850 ° C.
• the austenization temperature of the steel here greater than or equal to 850 ° C.
• the austenization temperature it must reach.
• the micro-structure obtained during subsequent cooling is an acicular ferrite (known as Windmanstatten), illustrated in FIG. 5, and not a ferrito-pearlitic structure.
• the wire of intermediate diameter is cooled to give the steel a ferrito-pearlitic micro-structure.
• the wire is cooled to avoid the formation of microstructure other than a structure pearlitic, ferritic or ferrito-pearlitic.
• a too fast cooling rate would lead to a ferritic acicular, bainitic or martensitic micro-structure.
• the person skilled in the art knows how to determine the cooling rate as a function of the chemical composition of the steel, of the austenitization temperature by means of abacuses available in particular in the document "Atlas of the curves for converting French-made steels". , IRDIS, 1974.
• the intermediate diameter wire is coated with at least one metal layer, here a brass layer.
• Steps 700i to 700 m are intended to reduce the diameter of the wire of the intermediate diameter to the final diameter d and increase the maximum breaking stress of the wire.
• the steps 700i to 700m form an uninterrupted series of wet wire drawing steps of the yarn of the intermediate diameter d 'to the final diameter d.
• Each step 700i to 700 m is a wet drawing step in which the wire is passed through a die of diameter less than the diameter of the wire upstream of the die.
• the wire has a diameter downstream of the die less than the diameter upstream of the die.
• the diameter of each die is less than the diameter of the die upstream.
• the steps 700i to 700 m will be carried out in a dry medium.
• Thread pulling means positioned downstream of each die allow to exert sufficient traction force to pull the wire through each die.
• the traction means and the dies are immersed in a liquid bath of drawing lubricant, for example as described in WO 2008/113481.
• the drawing process thus comprises N uninterrupted series of drawing steps, for example one in a dry environment and one in a wet environment.
• N 2.
• eT 2.In (D / d).
• the drawing process comprises M heat treatment step (s) aimed at regenerating the structure of the wire rod.
• M 1 which reduces the industrial cost of wire diameter d.
• the yarn is obtainable by the method according to the invention.
• Table 2 shows different values of the characteristics of the yarns obtained by the process according to the invention and from the state of the art.
• wires F1 to F4 ⁇ ⁇ 3, preferably ⁇ ⁇ 2.75. It will be noted that, for the wires F1 to F3, more preferentially ⁇ ⁇ 2.5. It will also be noted that, for the wires F1 to F4, ⁇ 6.5 and preferably ⁇ 6.75. For the wire F3, more preferably ⁇ 7.2. For the wire F4, it is even more preferentially ⁇ 7.5. In addition, it will be noted that, unlike the son EDT1 and EDT2, we have ⁇ '> 4. For the wire F1, we have ⁇ ' ⁇ 4.3. For the son F2 to F4, it is preferably ⁇ ' ⁇ 4.5. More preferentially, for the wire F4, one has ⁇ ' ⁇ 5. [0121] TESTS AND COMPARATIVE TESTS
• the F1, F2 son obtained by the process according to the invention break at significantly higher stresses than those of the state of the art, and this in a humid environment, thus illustrating one of the advantages of the invention.
• the initial breaking stress of F1, F2 son is significantly lower than that of son EDT1 and EDT2
• the fatigue-corrosion endurance of son F1, F2 is significantly higher than son EDT1 and EDT2.
• a first type of cable (C1 and C1 I) having a structure (1 + 6 + 12) ⁇ 0.18 was tested during a wavy tensile test.
• This test measures the endurance limit of each cable tested.
• each cable is subjected to a voltage variation between two extremes defining an amplitude, and this for a predetermined number of cycles, in this case 5 cycles. If the cable breaks, we repeat the test with a lower amplitude and if the wire does not break, we start the test with a higher amplitude.
• the value of the endurance limit is thus determined step by step, for example by the so-called staircase method. This test was carried out under two different conditions: under a dry atmosphere (less than 8% relative humidity) and under a humid atmosphere (more than 60% relative humidity).
• the CM cable using the F2 son obtained by the method according to the invention has a significantly lower degradation to the cable C1 of the state of the art using EDT2 son in both dry and wet environment illustrating thus one of the advantages of the invention.
• the breaking stress and the breaking force of the cable CM are smaller than those of the cable C1, the fatigue-corrosion endurance of the cable CM is much greater than that of the cable C1.
• a second type of cable (C2 using son EDT1, CI2A using F1 son, CI2B using F2 son) having a structure 3x0,18 mm during a test of rotating bending similar to that used was tested. for the previous thread test.
• the descaling step 200 may be carried out by the action of a chemical agent, for example acid.
• step 600 it is possible to coat the intermediate diameter wire only with a layer of zinc.
• the wire could be covered with a metal layer other than brass or zinc, whose function, for example, is to improve the resistance to corrosion of the wire and / or their adhesion to the rubber, for example a thin layer Co, Ni, Al, an alloy of two or more of Cu, Zn, Al, Ni, Co, Sn.

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  • 2014-11-21 WO PCT/EP2014/075223 patent/WO2015075163A1/fr active Application Filing
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