EP3068524A1 - Method for preparing an ethanol fuel composition - Google Patents
Method for preparing an ethanol fuel compositionInfo
- Publication number
- EP3068524A1 EP3068524A1 EP14862717.7A EP14862717A EP3068524A1 EP 3068524 A1 EP3068524 A1 EP 3068524A1 EP 14862717 A EP14862717 A EP 14862717A EP 3068524 A1 EP3068524 A1 EP 3068524A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- ethanol
- mixture
- vessel
- amount
- blending
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
Classifications
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/02—Liquid carbonaceous fuels essentially based on components consisting of carbon, hydrogen, and oxygen only
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01F—MIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
- B01F23/00—Mixing according to the phases to be mixed, e.g. dispersing or emulsifying
- B01F23/40—Mixing liquids with liquids; Emulsifying
- B01F23/405—Methods of mixing liquids with liquids
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/02—Liquid carbonaceous fuels essentially based on components consisting of carbon, hydrogen, and oxygen only
- C10L1/023—Liquid carbonaceous fuels essentially based on components consisting of carbon, hydrogen, and oxygen only for spark ignition
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/02—Liquid carbonaceous fuels essentially based on components consisting of carbon, hydrogen, and oxygen only
- C10L1/026—Liquid carbonaceous fuels essentially based on components consisting of carbon, hydrogen, and oxygen only for compression ignition
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/10—Liquid carbonaceous fuels containing additives
- C10L1/14—Organic compounds
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/10—Liquid carbonaceous fuels containing additives
- C10L1/14—Organic compounds
- C10L1/143—Organic compounds mixtures of organic macromolecular compounds with organic non-macromolecular compounds
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/10—Liquid carbonaceous fuels containing additives
- C10L1/14—Organic compounds
- C10L1/18—Organic compounds containing oxygen
- C10L1/182—Organic compounds containing oxygen containing hydroxy groups; Salts thereof
- C10L1/1822—Organic compounds containing oxygen containing hydroxy groups; Salts thereof hydroxy group directly attached to (cyclo)aliphatic carbon atoms
- C10L1/1824—Organic compounds containing oxygen containing hydroxy groups; Salts thereof hydroxy group directly attached to (cyclo)aliphatic carbon atoms mono-hydroxy
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/10—Liquid carbonaceous fuels containing additives
- C10L1/14—Organic compounds
- C10L1/18—Organic compounds containing oxygen
- C10L1/185—Ethers; Acetals; Ketals; Aldehydes; Ketones
- C10L1/1852—Ethers; Acetals; Ketals; Orthoesters
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/10—Liquid carbonaceous fuels containing additives
- C10L1/14—Organic compounds
- C10L1/22—Organic compounds containing nitrogen
- C10L1/222—Organic compounds containing nitrogen containing at least one carbon-to-nitrogen single bond
- C10L1/2222—(cyclo)aliphatic amines; polyamines (no macromolecular substituent 30C); quaternair ammonium compounds; carbamates
- C10L1/2225—(cyclo)aliphatic amines; polyamines (no macromolecular substituent 30C); quaternair ammonium compounds; carbamates hydroxy containing
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/10—Liquid carbonaceous fuels containing additives
- C10L1/14—Organic compounds
- C10L1/22—Organic compounds containing nitrogen
- C10L1/234—Macromolecular compounds
- C10L1/238—Macromolecular compounds obtained otherwise than by reactions involving only carbon-to-carbon unsaturated bonds
- C10L1/2383—Polyamines or polyimines, or derivatives thereof (poly)amines and imines; derivatives thereof (substituted by a macromolecular group containing 30C)
- C10L1/2387—Polyoxyalkyleneamines (poly)oxyalkylene amines and derivatives thereof (substituted by a macromolecular group containing 30C)
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L10/00—Use of additives to fuels or fires for particular purposes
- C10L10/18—Use of additives to fuels or fires for particular purposes use of detergents or dispersants for purposes not provided for in groups C10L10/02 - C10L10/16
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L2200/00—Components of fuel compositions
- C10L2200/04—Organic compounds
- C10L2200/0461—Fractions defined by their origin
- C10L2200/0469—Renewables or materials of biological origin
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L2270/00—Specifically adapted fuels
- C10L2270/02—Specifically adapted fuels for internal combustion engines
- C10L2270/026—Specifically adapted fuels for internal combustion engines for diesel engines, e.g. automobiles, stationary, marine
Definitions
- the present invention relates to the field of preparation of ethanol fuel compositions.
- the invention relates to methods which reduces or avoids precipitation of components of the ethanol fuel compositions during the preparation.
- Ethanol is currently the most commonly used renewable automobile fuel. It is largely produced by fermentation of sugar- or starch-containing feedstocks, such as cane sugar, corn and wheat. Also, it may be produced from lignocellulose, which is a less expensive raw material. Other benefits of lignocellulose are that it is not considered a human food resource and that ethanol may be produced from it with a relatively high net energy gain and a high renewable CO 2 -efficiency, i.e. the amount of fossil CO 2 generated throughout the production chain when producing ethanol from lignocellulose is comparatively low.
- ethanol fuel compositions that are adapted for such use have been developed over the past years. Many of these fuel compositions comprise various additives, and it may be problematic to achieve a sufficient mixing of the ethanol and such additives, especially in large scale production of the fuel compositions.
- ED95 is an ethanol based fuel comprising an ignition improver consisting of an adduct of a polyol having 3-10 hydroxyl groups and ethylene oxide and/or propylene oxide; a surface active agent consisting of ethoxylated oleyl amine, a corrosion inhibitor, denaturants and a colorant.
- an ignition improver consisting of an adduct of a polyol having 3-10 hydroxyl groups and ethylene oxide and/or propylene oxide
- a surface active agent consisting of ethoxylated oleyl amine, a corrosion inhibitor, denaturants and a colorant.
- the present inventors have developed a method of preparing such ethanol fuels which surprisingly overcomes the problem described above by reducing or even eliminating precipitation of the ignition improver and the surface active agent in the preparation of the fuel.
- a first aspect of the present invention relates to a method for preparing an ethanol fuel composition, comprising the following steps:
- the concentration of ethanol in the first mixture is 35-55 % (w/w);
- the ratio (w/w) of ethoxylated oleyl amine to ethanol in the first mixture is in the range 1 :4 - 1 :15, preferably in the range 1 :6 - 1 :10 , and
- the ratio (w/w) of ignition improver to ethanol in the first mixture is in the range 1 :1 - 1 :3, preferably in the range 1 :1 .2 - 1 :2
- step d) combining the blended first mixture obtained in step c) with a second amount of ethanol such that a second mixture is obtained;
- step d) blending of the second mixture obtained in step d) to obtain the ethanol fuel
- ethanol fuel obtained in step e) comprises: 80-90 % (w/w), preferably 84-88 % (w/w) ethanol
- the ignition improver added in step b) is a water soluble adduct of polyol having 3-10 hydroxyl groups and ethylene oxide and/or propylene oxide and wherein the molecular weight of the aduct is 350 to 2000 Da , preferably 600-1000 Da; Detailed description
- Ethanol based fuels comprising 80-90 % (w/w) ethanol, a surface active agent, consisting of ethoxylated oleyl amine, and of an ignition improver, consisting of an adduct of a polyol having 3-10 hydroxyl groups and ethylene oxide and/or propylene oxide, are presently used as fuel for busses and lorries.
- a drawback with these kinds of fuels is that it is hard to mix the fuel in an efficient way since the ignition improver and the surface active agent easily precipitates. This is problematic since the precipitates are hard to dissolve and non-dissolved precipitates will affect the concentration of ignition improver and surface active agent in the final fuel.
- the present inventors have realized that there is a need for improved methods of blending ethanol based fuels comprising such surface active agent and such ignition improvers.
- the present inventors have found that it is possible to vastly reduce or even prevent the precipitation of ignition improver and surface active agent by making an initial premix of ethanol, ignition improver and surface active agent in a premixing step.
- the present inventors have further found that the concentration of ethanol, the ratio of ethanol to ignition improver and the ratio of ethanol to surface active agent, in the premixing step, are critical for the level of precipitation. In particularly, if the ethanol concentration in the premixing step is 35-55 % (w/w); the present inventors have discovered that precipitation of the ignition improver is surprisingly low if the ratio of ethanol to ignition improver is in the range 1 :1 - 1 :3.
- the ratio of ethanol to ignition improver is in the range 1 :1 .2 - 1 :2.
- the present inventors have further discovered that the precipitation of the surface active agent can be vastly reduced if the ratio of ethanol to surface active agent is in the range 1 :4— 1 :15. Even better results are achieved if the ratio of ethanol to surface active agent is in the range 1 :6— 1 :10.
- the ignition improver and the surface active agent preferably should be added to the ethanol and not the other way around. If the ethanol is added to a vessel comprising the ignition improver and/or the surface active agent, the present inventors have discovered that the levels of precipitated ignition improver and/or the surface active agent will be higher.
- the present inventors have discovered that vertical circulation and/or stirring of such a premix is a suitable way of blending the premix.
- One advantage with vertical circulation is that less costly equipment can be used compared to if for example a stirred tank reactor is used for the blending of the premix.
- the final fuel can be prepared from the premix by addition of ethanol up to the desired concentration, i.e 80-90 % (w/w), followed by blending of the obtained mixture by stirring, preferably in a stirred tank reactor.
- "blending" refers to mixing at least two constituents such that these become less separated from eachother.
- vertical circulation shall be interpreted as that liquid in a container is pumped from a first position in the container to a second position in the container which is located higher than the first.
- liquid is pumped from the bottom of the container to a position near the liquid surface
- the concentration of ethanol in the first mixture is 35-55 % (w/w); the ratio (w/w) of ethoxylated oleyl amine to ethanol in the first mixture is in the range 1 :4 - 1 :15, preferably in the range 1 :6 - 1 :10 , and
- the ratio (w/w) of ignition improver to ethanol in the first mixture is in the range 1 :1 - 1 :3, preferably in the range 1 :1 .2 - 1 :2
- step d) combining the blended first mixture obtained in step c) with a second amount of ethanol such that a second mixture is obtained;
- step d) blending of the second mixture obtained in step d) to obtain the ethanol fuel
- step e) wherein the ethanol fuel obtained in step e) comprises:
- the ignition improver added in step b) is a water soluble adduct of polyol having 3-10 hydroxyl groups and ethylene oxide and/or propylene oxide and wherein the molecular weight of the aduct is 350 to 2000 Da , preferably 600-1000 Da
- ignition improver refers to an agent which improves the ignition properties of a fuel into which it has been blended.
- suitable ignition improvers for the fuels prepared according to the present invention have been described previously, see WO9505437, and are also commercially available and sold under the trade name Beraid (Akzo Nobel).
- Suitable ethoxylated oleyl amine includes tertiary amine ethoxylate, based on a primary oleyl amine.
- a preferred ethoxylated oleyl amine is bis-(2-hydroxyethyl)-oleyl amine.
- One example of a suitable ethoxylated oleyl amine is Ethomeen ⁇ /12 (Akzo Nobel).
- the temperature of the ignition improver added in step b) is at least 15 °C such as at least 20 °C .
- denaturing agents are added to ethanol fuel compositions, to prevent consumption of the fuel composition.
- denaturing agents should preferably have one or more, preferably all, of the following properties:
- the denaturing agent(s) is/are not harmful to fuel systems and engines and is/are not easily separated from the fuel composition by distillation or other methods.
- suitable denaturating agents includes butanol and C1 -3 alkyl-tert-butyleter, such as metyl-tert-butyleter (MTBE) and etyl-tert-butyleter (ETBE).
- MTBE metyl-tert-butyleter
- ETBE etyl-tert-butyleter
- the commercially available fuel ED95 comprises Iso-butanol and MTBE.
- the denaturing agents (at least in the case of iso-butanol, MTBE and ETBE) can be added at any of the steps a)-e).
- the present inventors have discovered that the blending is more efficient if the denaturating components are added to the ethanol provided in step a) together with the ethoxylated oleyl amine and the ignition improver.
- the method further comprises a step of adding butanol prior to and/or during any of the steps a)-e) such that the ethanol fuel obtained in step e) comprises 0.2-1 .5 % (w/w) butanol.
- the butanol is n-butanol and/or iso-butanol.
- the butanol is iso-butanol.
- the method further comprises a step of adding MTBE and/or ETBE prior to and/or during any of the steps a)-e) such that the ethanol fuel obtained in step e) comprises 1 -3 % (w/w) MTBE and/or ETBE.
- the ethanol fuel composition is ED95.
- the method further comprises addition of a colourant prior to and/or during any of the steps a)-e).
- a corrosion inhibitor may be added to the fuel composition.
- the inventors have found that morpholin is a particularly suitable corrosion inhibitor for this purpose. Consequently, in one
- the corrosion inhibitor may be morpholin or derivatives thereof. Furthermore, in one embodiments of the invention, the corrosion inhibitor is added in an amount corresponding to 5-500 ppm, preferably 30-300 ppm, more preferably 50-150 ppm of the total weight of the ethanol fuel composition, i.e. the ethanol fuel composition obtained in step e). The ranges are particularly relevant if the corrosion inhibitor is morpholin.
- the corrosion inhibitor is added together with the ignition improver in step b). For example, the corrosion inhibitor may be pre-mixed with the ignition improver added in step b).
- step e) the blending of the first mixture in step c) is performed at least partly by using vertical circulation and/or stirring.
- vertical circulation is less suitable since the volume in step e) is much larger than in step c).
- Vertical circulation is less practical and demands more energy and expensive equipment when the volumes are larger.
- the blending in step e) is at least partly mediated by stirring of the second mixture obtained in step d).
- the total weight of the first mixture obtained in step b) is between 100 and 1000 tons preferably 200-600 tons such as 300-500 tons.
- the total weight of the second mixture obtained in step d) is between 540 and 5400 tons preferably 1 100-3200 tons such as 1600-2700 tons.
- Step d) can preferably be performed by transferring the blended first mixture obtained in step c) to a second vessel comprising the second amount of ethanol.
- the present inventors have realized that this is benificial for the blending in step e).
- the blending of the first mixture in step c) is performed in a first vessel comprising means for vertical circulation and step d) comprises transferring the blended first mixture obtained in step c) to a second vessel.
- the second vessel is comprising the second amount of ethanol and the blending of the second mixture in step e) is performed in the second vessel.
- the second vessel is a stirred tank reactor.
- the second vessel is a tank on a motor vehicle designed to carry liquefied loads.
- motor vehicles are well known to the skilled person and are commonly referred to as tank trucks, tanker trucks or petrol tankers.
- One advantage with this solution is that the second mixture is, at least to som extent, blended by the movement of the second mixture within the tank, mediated by the movement generated when the motor vehicle is driving.
- Another advantage is that it eliminates the needs for a large stirred tank reactor for the blending of the second mixture.
- a third advantage is that the fuel can be produced on demand from a premixed solution, directly in a vehicle for transportation of the fuel.
- blended first mixture can be withdrawn from the first vessel via a first pipe and the second amount of ethanol can be withdrawn from a container containing ethanol via a second pipe.
- Both the first pipe and the second pipe can lead to a third pipe such that the first blended mixture is mixed with the second amount of ethanol in the said third pipe to obtain the second mixture within the third pipe.
- the third pipe can lead to the tank on the motor vehicle, such that the second mixture is transferred to the said tank via the third pipe.
- the inline mixing can be mediated by an inline mixing device which can be present in the third pipe.
- the inline mixing device can be a static mixer.
- static mixers can comprise geometric mixing elements fixed within a pipe, and which use the energy of a flow stream to create mixing between two or more fluids.
- a static mixer can be arranged in the third pipe to facilitate blending of the first mixture obtained in step c) with the second amount of ethanol prior to introduction of the second mixture in the tank on the motor vehicle designed to carry liquefied loads.
- the second vessel is a tank on a motor vehicle designed to carry liquefied loads.
- the blending of the second mixture in step e) is at least partly achieved by the motion created when the motor vehicle is driving.
- the blended first mixture obtained in step c) is inline mixed with the second amount of ethanol such that the second mixture is formed inline prior to introduction of the second mixture in the tank on the motor vehicle designed to carry liquefied loads.
- the inline mixing is at least partly mediated by an inline mixing device.
- the inline mixing device is a static mixer
- the second amount of ethanol can be added to the blended first mixture obtained in step c).
- An advantage with this is that only one vessel is needed for the preparation of the fuel but a draw back is that the blending in step e) is less effective.
- the blending of the first mixture in step c) is performed in a first vessel, preferably comprising means for vertical circulation, and step d) comprises adding the second amount of ethanol to the first vessel and the blending of the second mixture in step e) is performed in the first vessel.
- the first vessel is a stirred tank reactor, preferably comprising means for vertical circulation.
- step e) preferably shall be performed until the density difference between the liquid by the liquid surface and the liquid by the bottom of the vessel is 2 % or less, such as 1 % or less.
- the density difference is 0.5 % or less, more preferably 0.2 % or less.
- the density difference between the liquid by the liquid surface and the liquid by the bottom of the vessel is low.
- the density difference between the liquid by the liquid surface and the liquid by the bottom of a vessel of the first mixture obtained in step c) is 5 % or less, such as 2 % or less, such as 1 % or less.
- the density difference is 0.5 % or less, more preferably 0.2 % or less.
- Such a low density difference may preferably be achieved by means of vertical circulation of the total volume of the first mixture obtained in step b) at least 1 time, such as at least 1 .15 times, such as at least 1 .5 times, such as at least 2 times.
- ethanol liquid comprising about 93 % ethanol (w/w) and 7 % water (w/w) is pumped to a tank comprising means for vertical circulation.
- Basonylbasic Red (BASF) is pumped to the tank during vertical circulation of the liquid in the tank. This circulation is performed at a rate of 60 m 3 /h. After all the components have been added, the liquid in the tank is vertically circulated for 10 h at a rate of 60 m 3 /h to obtain a first mixture. Thereafter the first mixture is pumped into a stirred tank reactor comprising 800 tonnes of ethanol ( 93% w/w) during stirring of the stirred tank reactor. Thereafter 1 190 tonnes of ethanol (93 % w/w) is added during stirring, followed by stirring of the solution for about 1 -5 days to obtain the ethanol fuel.
- BASF Basonylbasic Red
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- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Emergency Medicine (AREA)
- Combustion & Propulsion (AREA)
- Liquid Carbonaceous Fuels (AREA)
Abstract
Description
Claims
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
SE1351329A SE538634C2 (en) | 2013-11-12 | 2013-11-12 | Method for preparing an ethanol fuel composition |
PCT/SE2014/051317 WO2015072911A1 (en) | 2013-11-12 | 2014-11-06 | Method for preparing an ethanol fuel composition |
Publications (2)
Publication Number | Publication Date |
---|---|
EP3068524A1 true EP3068524A1 (en) | 2016-09-21 |
EP3068524A4 EP3068524A4 (en) | 2017-06-28 |
Family
ID=53057734
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP14862717.7A Withdrawn EP3068524A4 (en) | 2013-11-12 | 2014-11-06 | Method for preparing an ethanol fuel composition |
Country Status (3)
Country | Link |
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EP (1) | EP3068524A4 (en) |
SE (1) | SE538634C2 (en) |
WO (1) | WO2015072911A1 (en) |
Families Citing this family (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN105080379A (en) * | 2015-08-04 | 2015-11-25 | 周荣国 | Device for blending fuel oil for ship and processing technology thereof |
RU2723546C1 (en) * | 2019-10-08 | 2020-06-16 | Дмитрий Владимирович Цыганков | Alternative automotive fuel and method of its production |
Family Cites Families (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
SE510104C2 (en) * | 1993-08-19 | 1999-04-19 | Berol Nobel Ab | Ethanol fuel and use of an ignition enhancer |
SE523228C2 (en) * | 2000-12-15 | 2004-04-06 | Akzo Nobel Nv | Fuel composition containing a hydrocarbon fraction, ethanol and an additive with water solubilizing capacity |
EP2128232A1 (en) * | 2008-05-20 | 2009-12-02 | Castrol Limited | Lubricating composition for ethanol fueled engines |
EP2204433A1 (en) * | 2008-12-30 | 2010-07-07 | SEKAB BioFuels & Chemicals AB | Ethanol-based fuel for compression engines |
SE535227C2 (en) * | 2010-10-06 | 2012-05-29 | Scania Cv Ab | Use of rapeseed methyl ester as a precipitant inhibiting fuel additive in ethanol-based fuels |
-
2013
- 2013-11-12 SE SE1351329A patent/SE538634C2/en not_active IP Right Cessation
-
2014
- 2014-11-06 WO PCT/SE2014/051317 patent/WO2015072911A1/en active Application Filing
- 2014-11-06 EP EP14862717.7A patent/EP3068524A4/en not_active Withdrawn
Also Published As
Publication number | Publication date |
---|---|
SE538634C2 (en) | 2016-10-04 |
EP3068524A4 (en) | 2017-06-28 |
WO2015072911A1 (en) | 2015-05-21 |
SE1351329A1 (en) | 2015-05-13 |
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