EP3061516B1 - Co2 recovery apparatus and co2 recovery process - Google Patents
Co2 recovery apparatus and co2 recovery process Download PDFInfo
- Publication number
- EP3061516B1 EP3061516B1 EP15740962.4A EP15740962A EP3061516B1 EP 3061516 B1 EP3061516 B1 EP 3061516B1 EP 15740962 A EP15740962 A EP 15740962A EP 3061516 B1 EP3061516 B1 EP 3061516B1
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- flow rate
- absorbing liquid
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- supplied
- absorption tower
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- 238000011084 recovery Methods 0.000 title claims description 97
- 239000007788 liquid Substances 0.000 claims description 218
- 238000010521 absorption reaction Methods 0.000 claims description 107
- 230000008929 regeneration Effects 0.000 claims description 83
- 238000011069 regeneration method Methods 0.000 claims description 83
- 230000001172 regenerating effect Effects 0.000 claims description 10
- 238000010438 heat treatment Methods 0.000 claims description 4
- 238000005259 measurement Methods 0.000 claims description 2
- 239000007789 gas Substances 0.000 description 167
- 238000005406 washing Methods 0.000 description 32
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 27
- 238000001816 cooling Methods 0.000 description 16
- 229920006395 saturated elastomer Polymers 0.000 description 10
- 239000000498 cooling water Substances 0.000 description 7
- 238000000926 separation method Methods 0.000 description 7
- 230000007423 decrease Effects 0.000 description 5
- 239000003595 mist Substances 0.000 description 5
- 238000000034 method Methods 0.000 description 4
- 238000004140 cleaning Methods 0.000 description 3
- 238000000605 extraction Methods 0.000 description 3
- 239000002904 solvent Substances 0.000 description 3
- WRRSFOZOETZUPG-FFHNEAJVSA-N (4r,4ar,7s,7ar,12bs)-9-methoxy-3-methyl-2,4,4a,7,7a,13-hexahydro-1h-4,12-methanobenzofuro[3,2-e]isoquinoline-7-ol;hydrate Chemical compound O.C([C@H]1[C@H](N(CC[C@@]112)C)C3)=C[C@H](O)[C@@H]1OC1=C2C3=CC=C1OC WRRSFOZOETZUPG-FFHNEAJVSA-N 0.000 description 2
- 230000003247 decreasing effect Effects 0.000 description 2
- 238000004326 stimulated echo acquisition mode for imaging Methods 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
Images
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/14—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by absorption
- B01D53/1456—Removing acid components
- B01D53/1475—Removing carbon dioxide
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/14—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by absorption
- B01D53/1412—Controlling the absorption process
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/346—Controlling the process
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/46—Removing components of defined structure
- B01D53/62—Carbon oxides
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B32/00—Carbon; Compounds thereof
- C01B32/50—Carbon dioxide
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2252/00—Absorbents, i.e. solvents and liquid materials for gas absorption
- B01D2252/20—Organic absorbents
- B01D2252/204—Amines
- B01D2252/20478—Alkanolamines
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2258/00—Sources of waste gases
- B01D2258/02—Other waste gases
- B01D2258/0283—Flue gases
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02C—CAPTURE, STORAGE, SEQUESTRATION OR DISPOSAL OF GREENHOUSE GASES [GHG]
- Y02C20/00—Capture or disposal of greenhouse gases
- Y02C20/40—Capture or disposal of greenhouse gases of CO2
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/151—Reduction of greenhouse gas [GHG] emissions, e.g. CO2
Definitions
- the invention has been made in view of such actual circumstances, and an object thereof is to provide a CO 2 recovery apparatus and a CO 2 recovery process that can improve the total operational efficiency and stability of the apparatus even in a case where the treatment amount of a gas to be treated varies.
- the CO 2 recovery process can make the variations of the flow rate of the CO 2 absorbing liquid supplied to the CO 2 absorption tower and the flow rate of the steam supplied to the CO 2 absorbing liquid regeneration tower small even in a case where the flow rate of the gas to be treated vary at any time within classifications of the multiple flow rate ranges. Thus, it is possible to improve the total operational efficiency and stability of the apparatus.
- a CO 2 recovery process of the invention includes a CO 2 absorption step of bringing a gas to be treated containing CO 2 into contact with a CO 2 absorbing liquid in a CO 2 absorption tower and making the CO 2 absorbing liquid absorb CO 2 contained in the gas to be treated; a regeneration step of heating the CO 2 absorbing liquid, which has absorbed CO 2 , with steam in a CO 2 absorbing liquid regeneration tower, releasing CO 2 , and regenerating the CO 2 absorbing liquid; a step of measuring the flow rates of the gas to be treated, which is introduced into the CO 2 absorption tower, in a flow rate measuring unit, and measuring the CO 2 concentration of the gas to be treated, which is introduced into the CO 2 absorption tower, in a CO 2 concentration measuring unit; and a step of classifying CO 2 flow rates, which are obtained on the basis of the measured flow rates of the gas to be treated and the measurement value of the CO 2 concentration, into multiple flow rate ranges, and controlling the flow rate of the CO 2 absorbing liquid supplied to the CO 2 absorption tower and the flow rate
- the CO 2 recovery process of the invention it is required that the set load values are kept substantially constant within the multiple flow rate ranges and thereby the flow rate of the CO 2 absorbing liquid supplied to the CO 2 absorption tower and the flow rate of the steam supplied to the CO 2 absorbing liquid regeneration tower are controlled.
- the CO 2 recovery process can keep the flow rate of the CO 2 absorbing liquid supplied to the CO 2 absorption tower and the flow rate of the steam supplied to the CO 2 absorbing liquid regeneration tower substantially constant, even if the flow rate or the like of the gas to be treated may vary at any time within the multiple flow rate ranges.
- the set load values are kept at maximum values corresponding to the flow rate ranges within the multiple flow rate ranges and thereby the flow rate of the CO 2 absorbing liquid supplied to the CO 2 absorption tower and the flow rate of the steam supplied to the CO 2 absorbing liquid regeneration tower are controlled.
- the CO 2 recovery process can control the flow rate of the CO 2 absorbing liquid supplied to the CO 2 absorption tower and the flow rate of the steam supplied to the CO 2 absorbing liquid regeneration tower, according to the set maximum load values within the flow rate ranges.
- the CO 2 absorption tower 14 includes a CO 2 absorption section 141 that is provided on a lower part side of the CO 2 absorption tower 14 and has the exhaust gas 11A and the CO 2 absorbing liquid 13 (lean solution) cooled in the cooling tower 12 supplied thereto, a main washing section 142 that is provided on an upper part side of the CO 2 absorption tower 14, and a preliminary washing section 143 that is provided between and the CO 2 absorption section 141 and the main washing section 142.
- a liquid storage section 144 that stores washing water W 2 for cleaning an exhaust gas 11C from which CO 2 has been removed is provided at a bottom part of the main washing section 142.
- a circulation line L 2 through which the washing water W 2 , containing the CO 2 absorbing liquid 13 recovered in the liquid storage section 144, is supplied and circulated from a top part side of the main washing section 142, is provided between the liquid storage section 144 and an upper part of the main washing section 142.
- the circulation line L 2 is provided with a heat exchanger 21 that cools the washing water W 2 , and a circulation pump 22 that circulates the washing water W 2 , containing the CO 2 absorbing liquid 13 recovered in the liquid storage section 144, within the circulation line L 2 via the heat exchanger 21.
- the circulation line L 2 is provided with an extraction line L 3 through which a portion of the washing water W 2 (washing water W 3 ) is extracted and supplied to the preliminary washing section 143.
- the extraction line L 3 is provided with an adjusting valve 23 that adjusts the amount of supply of washing water W 3 supplied to the preliminary washing section 143, and a heat exchanger 24 that cools the washing water W 3 to a predetermined temperature.
- the exhaust gas 11B from which CO 2 has been removed is brought into gas-liquid contact with the washing water W 3 extracted from the main washing section 142, and is cleaned.
- the exhaust gas 11B from which CO 2 has been removed becomes the exhaust gas 11C in which the CO 2 absorbing liquid 13 entrained in the exhaust gas 11B has decreased.
- the exhaust gas 11C from which CO 2 that has passed through the preliminary washing section 143 has been removed rises via a chimney tray 145. Then, the exhaust gas 11C is brought into gas-liquid contact with the washing water W 2 supplied from the top part side of the main washing section 142, and becomes an exhaust gas 11D from which the CO 2 absorbing liquid 13 entrained in the exhaust gas 11C has been recovered by circulation cleaning. The exhaust gas 11D is exhausted to the outside from a tower top part 14a of the CO 2 absorption tower 14 after mist in the gas is trapped by a mist eliminator 146.
- a central part of the CO 2 absorbing liquid regeneration tower 15 is provided with a CO 2 absorbing liquid supply section 151 to which the CO 2 absorbing liquid 13 that has absorbed CO 2 is supplied.
- a tower bottom part 15b of the CO 2 absorbing liquid regeneration tower 15 is provided with a circulation line L 4 through which the CO 2 absorbing liquid 13 that has flowed down to the tower bottom part 15b circulates.
- a tower top part 15a of the CO 2 absorbing liquid regeneration tower 15 is provided with a gas exhaust line L 5 through which a CO 2 gas 41 accompanied by steam is exhausted.
- the gas exhaust line L 5 is provided with a condenser 42 that condenses moisture in the CO 2 gas 41, and a separation drum 43 that separates the CO 2 gas 41 from condensed water W 5 .
- a CO 2 gas 44 from which the condensed water W 5 has been separated is released to the outside from an upper part of the separation drum 43.
- a condensed water line L 6 through which the condensed water W 5 separated by the separation drum 43 is supplied to the upper part of the CO 2 absorbing liquid regeneration tower 15 is provided between a bottom part of the separation drum 43 and the upper part of the CO 2 absorbing liquid regeneration tower 15.
- the condensed water line L 6 is provided with a condensed water circulation pump 45 that supplies the condensed water W 5 separated by the separation drum 43 to the upper part of the CO 2 absorbing liquid regeneration tower 15.
- the tower bottom part 15b of the CO 2 absorbing liquid regeneration tower 15 and an upper part of the CO 2 absorption section 141 of the CO 2 absorption tower 14 are provided with a lean solution supply tube 53 through which a lean solution in the tower bottom part 15b of the CO 2 absorbing liquid regeneration tower 15 is supplied to the upper part of the CO 2 absorption section 141.
- the control unit 102 adjusts the flow rate of the lean solution pump 54 and the opening degree of the adjusting valve 32 in a range where the preset load values are 6 or more and 7 or less, and controls the flow rate of the CO 2 absorbing liquid 13 supplied to the CO 2 absorption tower 14 and the flow rate of steam supplied to the CO 2 absorbing liquid regeneration tower 15.
- the control unit 102 adjusts the flow rate of the lean solution pump 54 and the opening degree of the adjusting valve 32 in a range where the preset load values are 5 or more and 6 or less.
- the control unit 102 keeps the set load values at maximum values corresponding to the flow rate ranges R1 to R7 to control the flow rate of the CO 2 absorbing liquid 13 supplied to the CO 2 absorption tower 14 and the flow rate of the steam S supplied to the CO 2 absorbing liquid regeneration tower 15, within the multiple flow rate ranges R1 to R7.
- the set load value is kept at 7 that is a maximum value of 6 or more and 7 or less corresponding to the flow rate range R1.
- the control unit 102 classifies the flow rate ranges of the exhaust gas flow rates of the exhaust gas 11A to be set in advance into the seven stages. Accordingly, since the number of the flow rate ranges R1 to R7 to be set in advance is in a moderate range, it is possible to improve the total operational efficiency and stability of the CO 2 recovery apparatus 1.
- the flow rate ranges of the exhaust gas flow rates are not limited to the seven stages, and the exhaust gas flow rates may be classified into seven stages or more, or less than seven stages.
- FIG. 5 is a schematic view of a CO 2 recovery apparatus 2 related to a second embodiment of the invention.
- a CO 2 recovery apparatus 2 related to the present embodiment includes a CO 2 concentration meter (CO 2 concentration measuring unit) 103 that measures CO 2 concentration in the exhaust gas 11A, in the flue 16, in addition to the configuration of the CO 2 recovery apparatus 1 related to the above-described first embodiment.
- the control unit 102 obtains CO 2 flow rates in the exhaust gas 11A, on the basis of the exhaust gas flow rates of the exhaust gas 11A measured by the flowmeter 101 and the CO 2 concentration in the exhaust gas 11A measured by a CO 2 concentration meter 103.
- the CO 2 concentration meter 103 is not particularly limited if the CO 2 concentration in the exhaust gas 11A can be measured.
- control unit 102 adjusts the flow rate of the lean solution pump 54 and the opening degree of the adjusting valve 32 within a range of the set load values that are preset according to the flow rate ranges R11 to R17 classified into the seven stages, and controls the flow rate of the CO 2 absorbing liquid 13 supplied to the CO 2 absorption tower 14 and the flow rate of steam supplied to the CO 2 absorbing liquid regeneration tower 15.
- the set load values herein are, for example, the specific flow rates of the lean solution pump 54 and the specific opening degrees of the adjusting valve 32 that are preset according to the flow rate ranges R11 to R17.
- the control unit 102 adjusts the flow rate of the lean solution pump 54 and the opening degree of the adjusting valve 32 in a range where the preset load values are 6 or more and 7 or less, and controls the flow rate of the CO 2 absorbing liquid 13 supplied to the CO 2 absorption tower 14 and the flow rate of steam supplied to the CO 2 absorbing liquid regeneration tower 15.
- the control unit 102 adjusts the flow rate of the lean solution pump 54 and the opening degree of the adjusting valve 32 in a range where the preset load values are 5 or more and 6 or less.
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Analytical Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Chemistry (AREA)
- Biomedical Technology (AREA)
- Health & Medical Sciences (AREA)
- Environmental & Geological Engineering (AREA)
- Inorganic Chemistry (AREA)
- Gas Separation By Absorption (AREA)
- Treating Waste Gases (AREA)
- Carbon And Carbon Compounds (AREA)
Description
- The invention relates to a CO2 recovery apparatus and a CO2 recovery process, and particularly to a CO2 recovery apparatus and a CO2 recovery process that recover CO2 in a gas to be treated, using a CO2 absorbing liquid.
- In the related art, CO2 recovery apparatuses that recover CO2 exhausted from boilers or the like of thermoelectric power plants are suggested (for example, refer to PTL 1). In the CO2 recovery apparatuses, after an exhaust gas is introduced into a CO2 absorption tower and a CO2 absorbing liquid is brought into contact with CO2 contained in the exhaust gas to absorb CO2, the CO2 absorbing liquid that has absorbed CO2 is introduced into a regeneration tower and is decarboxylated, and a high-concentration CO2 gas is recovered therefrom.
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- [PTL 1] Japanese Patent No.
3212524 - [PTL 2]
US-4,106,916 - Meanwhile, in recent years, in boilers or the like of thermoelectric power plants, reduction of the amount of consumption of steam used for regeneration of the CO2 absorbing liquid for further saving of energy has been desired. In the related-art CO2 recovery apparatuses, the flow rate of an exhaust gas introduced into the CO2 absorption tower and CO2 concentration in the exhaust gas are measured, and the flow rate of the CO2 absorbing liquid and the amount of consumption of steam used for regeneration of the CO2 absorbing liquid is reduced on the basis of the measured exhaust gas flow rate and CO2 concentration.
- However, in the related-art CO2 recovery apparatuses, an efficient operation control may not necessarily be performed for variations of the CO2 flow rates in the exhaust gas caused by load variations of the boiler or the like, and further improvements in the efficiency and stability of the operation of the CO2 recovery apparatuses are desired.
- The invention has been made in view of such actual circumstances, and an object thereof is to provide a CO2 recovery apparatus and a CO2 recovery process that can improve the total operational efficiency and stability of the apparatus even in a case where the treatment amount of a gas to be treated varies.
- A CO2 recovery apparatus of the invention includes a CO2 absorption tower that brings a gas to be treated containing CO2 into contact with a CO2 absorbing liquid and makes the CO2 absorbing liquid absorb CO2 contained in the gas to be treated; a CO2 absorbing liquid regeneration tower that heats the CO2 absorbing liquid, which has absorbed CO2, with steam, releases CO2 from the CO2 absorbing liquid, and regenerates the CO2 absorbing liquid; a flow rate measuring unit that measures the flow rates of the gas to be treated that is introduced into the CO2 absorption tower; and a control unit that classifies the flow rates of the gas to be treated measured by the flow rate measuring unit into multiple flow rate ranges, and controls the flow rate of the CO2 absorbing liquid supplied to the CO2 absorption tower and the flow rate of steam supplied to the CO2 absorbing liquid regeneration tower, on the basis of set load values that are preset according to the multiple flow rate range ranges.
- According to this CO2 recovery apparatus, even in a case where the flow rate of the gas to be treated increases or decreases within classifications of the multiple flow rate ranges, it is possible to maintain operation conditions on the basis of the set load values corresponding to the flow rate ranges. Accordingly, the CO2 recovery apparatus is able to make the variations of the flow rate of the CO2 absorbing liquid supplied to the CO2 absorption tower and the flow rate of the steam supplied to the CO2 absorbing liquid regeneration tower small even in a case where the flow rate of the gas to be treated may vary at any time within classifications of the multiple flow rate ranges. Thus, it is possible to improve the total operational efficiency and stability of the apparatus.
- A CO2 recovery apparatus of the invention includes a CO2 absorption tower that brings a gas to be treated containing CO2 into contact with a CO2 absorbing liquid and makes the CO2 absorbing liquid absorb CO2 contained in the gas to be treated; a CO2 absorbing liquid regeneration tower that heats the CO2 absorbing liquid, which has absorbed CO2, with steam, releases CO2 from the CO2 absorbing liquid, and regenerates the CO2 absorbing liquid; a flow rate measuring unit that measures the flow rates of the gas to be treated that is introduced into the CO2 absorption tower; a CO2 concentration measuring unit that measures the CO2 concentration of the gas to be treated that is introduced into the CO2 absorption tower; and a control unit that classifies CO2 flow rates in the gas to be treated, which are obtained on the basis of the flow rates of the gas to be treated that are measured by the flow rate measuring unit and the CO2 concentration in the gas to be treated that is measured by the CO2 concentration measuring unit, into multiple flow rate ranges, and controls the flow rate of the CO2 absorbing liquid supplied to the CO2 absorption tower and the flow rate of steam supplied to the CO2 absorbing liquid regeneration tower, on the basis of set load values that are preset according to the multiple flow rate range classifications.
- According to this CO2 recovery apparatus, even in a case where the CO2 flow rates increase or decrease within classifications of the multiple flow rate ranges, it is possible to maintain the operation conditions on the basis of the set load values corresponding to the flow rate ranges. Accordingly, in the CO2 recovery apparatus, even in a case where the flow rate of the gas to be treated vary at any time within classifications of the multiple flow rate ranges, the variations of the flow rate of the CO2 absorbing liquid supplied to the CO2 absorption tower and the flow rate of the steam supplied to the CO2 absorbing liquid regeneration tower can be made small. Thus, it is possible to improve the total operational efficiency and stability of the apparatus. Moreover, since this CO2 recovery apparatus controls the operation conditions on the basis of the CO2 flow rates calculated on the basis of the CO2 concentration in the gas to be treated, it is possible to further improve the total operational efficiency and stability of the apparatus.
- In the CO2 recovery apparatus of the invention, it is required that the control unit keeps the set load values substantially constant within the multiple flow rate ranges and thereby controls the flow rate of the CO2 absorbing liquid supplied to the CO2 absorption tower and the flow rate of the steam supplied to the CO2 absorbing liquid regeneration tower. By virtue of this configuration, the CO2 recovery apparatus is able to keep the flow rate of the CO2 absorbing liquid supplied to the CO2 absorption tower and the flow rate of the steam supplied to the CO2 absorbing liquid regeneration tower substantially constant, even if the flow rate or the like of the gas to be treated may vary at any time within the multiple flow rate ranges. Accordingly, since the CO2 recovery apparatus can make the variations of the flow rate of the CO2 absorbing liquid supplied to the CO2 absorption tower and the flow rate of the steam supplied to the CO2 absorbing liquid regeneration tower small, it is possible to further improve the total operational efficiency and stability of the apparatus.
- In the CO2 recovery apparatus of the invention, it is preferable that the control unit keeps the set load values at maximum values corresponding to the flow rate ranges within the multiple flow rate ranges and thereby controls the flow rate of the CO2 absorbing liquid supplied to the CO2 absorption tower and the flow rate of the steam supplied to the CO2 absorbing liquid regeneration tower. By virtue of this configuration, the CO2 recovery apparatus can control the flow rate of the CO2 absorbing liquid supplied to the CO2 absorption tower and the flow rate of the steam supplied to the CO2 absorbing liquid regeneration tower, according to the maximum set load values within the multiple flow rate ranges. Thus, even in a case where the flow rate of the gas to be treated varies within the flow rate ranges, it is possible to appropriately control the flow rate of the CO2 absorbing liquid supplied to the CO2 absorption tower and the flow rate of the steam supplied to the CO2 absorbing liquid regeneration tower.
- In the CO2 recovery apparatus of the invention, it is preferable that there are 7 or less classifications in the multiple flow rate ranges. By virtue of this configuration, in the CO2 recovery apparatus, the number of the flow rate ranges is in a moderate range. Thus, it is possible to further improve the total operational efficiency and stability of the apparatus.
- A CO2 recovery process of the invention includes a CO2 absorption step of bringing a gas to be treated containing CO2 into contact with a CO2 absorbing liquid in a CO2 absorption tower and making the CO2 absorbing liquid absorb CO2 contained in the gas to be treated; a regeneration step of heating the CO2 absorbing liquid, which has absorbed CO2, with steam in a CO2 absorbing liquid regeneration tower, releasing CO2, and regenerating the CO2 absorbing liquid; a step of measuring the flow rates of the gas to be treated that is introduced into the CO2 absorption tower in a flow rate measuring unit; and a step of classifying the measured flow rates of the gas to be treated into multiple flow rate ranges, and controlling the flow rate of the CO2 absorbing liquid supplied to the CO2 absorption tower and the flow rate of steam supplied to the CO2 absorbing liquid regeneration tower, on the basis of set load values that are preset according to the multiple flow rate range classifications.
- According to this CO2 recovery process, even in a case where the flow rate of the gas to be treated increases or decreases within classifications of the multiple flow rate ranges, it is possible to maintain operation conditions on the basis of the set load values according to the flow rate ranges. Accordingly, the CO2 recovery process can make the variations of the flow rate of the CO2 absorbing liquid supplied to the CO2 absorption tower and the flow rate of the steam supplied to the CO2 absorbing liquid regeneration tower small even in a case where the flow rate of the gas to be treated vary at any time within classifications of the multiple flow rate ranges. Thus, it is possible to improve the total operational efficiency and stability of the apparatus.
- A CO2 recovery process of the invention includes a CO2 absorption step of bringing a gas to be treated containing CO2 into contact with a CO2 absorbing liquid in a CO2 absorption tower and making the CO2 absorbing liquid absorb CO2 contained in the gas to be treated; a regeneration step of heating the CO2 absorbing liquid, which has absorbed CO2, with steam in a CO2 absorbing liquid regeneration tower, releasing CO2, and regenerating the CO2 absorbing liquid; a step of measuring the flow rates of the gas to be treated, which is introduced into the CO2 absorption tower, in a flow rate measuring unit, and measuring the CO2 concentration of the gas to be treated, which is introduced into the CO2 absorption tower, in a CO2 concentration measuring unit; and a step of classifying CO2 flow rates, which are obtained on the basis of the measured flow rates of the gas to be treated and the measurement value of the CO2 concentration, into multiple flow rate ranges, and controlling the flow rate of the CO2 absorbing liquid supplied to the CO2 absorption tower and the flow rate of steam supplied to the CO2 absorbing liquid regeneration tower, on the basis of set load values that are preset according to the multiple flow rate range classifications.
- According to this CO2 recovery process, even in a case where the CO2 flow rates increase or decrease within classifications of the multiple flow rate ranges, it is possible to maintain operation conditions on the basis of the set load values according to the flow rate ranges. By virtue of this process, the CO2 recovery process can make the variations of the flow rate of the CO2 absorbing liquid supplied to the CO2 absorption tower and the flow rate of the steam supplied to the CO2 absorbing liquid regeneration tower even small in a case where the flow rate of the gas to be treated may vary at any time within classifications of the multiple flow rate ranges. Thus, it is possible to improve the total operational efficiency and stability of the apparatus. Moreover, since this CO2 recovery process controls the operation conditions on the basis of the CO2 flow rates calculated on the basis of the CO2 concentration in the gas to be treated, it is possible to further improve the total operational efficiency and stability of the apparatus.
- In the CO2 recovery process of the invention, it is required that the set load values are kept substantially constant within the multiple flow rate ranges and thereby the flow rate of the CO2 absorbing liquid supplied to the CO2 absorption tower and the flow rate of the steam supplied to the CO2 absorbing liquid regeneration tower are controlled. By virtue of this process, the CO2 recovery process can keep the flow rate of the CO2 absorbing liquid supplied to the CO2 absorption tower and the flow rate of the steam supplied to the CO2 absorbing liquid regeneration tower substantially constant, even if the flow rate or the like of the gas to be treated may vary at any time within the multiple flow rate ranges. Accordingly, since the CO2 recovery process can make the variations of the flow rate of the CO2 absorbing liquid supplied to the CO2 absorption tower and the flow rate of the steam supplied to the CO2 absorbing liquid regeneration tower small, it is possible to further improve the total operational efficiency and stability of the apparatus.
- In the CO2 recovery process of the invention, it is preferable that the set load values are kept at maximum values corresponding to the flow rate ranges within the multiple flow rate ranges and thereby the flow rate of the CO2 absorbing liquid supplied to the CO2 absorption tower and the flow rate of the steam supplied to the CO2 absorbing liquid regeneration tower are controlled. By virtue of this process, the CO2 recovery process can control the flow rate of the CO2 absorbing liquid supplied to the CO2 absorption tower and the flow rate of the steam supplied to the CO2 absorbing liquid regeneration tower, according to the set maximum load values within the flow rate ranges. Thus, even in a case where the flow rate of the gas to be treated varies within the flow rate ranges, it is possible to appropriately control the flow rate of the CO2 absorbing liquid supplied to the CO2 absorption tower and the flow rate of the steam supplied to the CO2 absorbing liquid regeneration tower.
- In the CO2 recovery process of the invention, it is preferable that there are 7 or less classifications in the multiple flow rate ranges. By virtue of this process, the number of the flow rate ranges is in a moderate range. Thus, it is possible to further improve the total operational efficiency and stability of the apparatus.
- According to the invention, it is possible to realize the CO2 recovery apparatus and the CO2 recovery process that can improve the total operational efficiency and stability of the apparatus even in a case where the treatment amount of a gas to be treated varies.
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Fig. 1 is a schematic view of a CO2 recovery apparatus related to a first embodiment. -
Fig. 2 is a view illustrating the relationship between the operation time of the CO2 recovery apparatus related to the first embodiment and changes in exhaust gas flow rate. -
Fig. 3 is a view illustrating the relationship between the operation time of the CO2 recovery apparatus related to the first embodiment and set load values of the CO2 recovery apparatus. -
Fig. 4 is a flowchart of the operation control of the CO2 recovery apparatus related to the first embodiment. -
Fig. 5 is a schematic view of a CO2 recovery apparatus related to a second embodiment. -
Fig. 6 is a view illustrating the relationship between the operation time of the CO2 recovery apparatus related to the second embodiment and changes in CO2 flow rate. -
Fig. 7 is a view illustrating the relationship between the operation time of the CO2 recovery apparatus related to the second embodiment and set load values of the CO2 recovery apparatus. -
Fig. 8 is a flowchart of the operation control of the CO2 recovery apparatus related to the second embodiment. - The present inventors have paid their attention to the fact that, in the related-art CO2 recovery apparatuses, operation conditions cannot be necessarily and sufficiently optimized with respect to load variations of a boiler or the like even if the flow rates or the like of an exhaust gas supplied to a CO2 absorption tower are measured and the operation control off the CO2 recovery apparatuses is performed. Also, the present inventors have found out that total operational efficiency and stability of the apparatuses are improved by classifying the treatment amounts of the exhaust gas into multiple ranges, setting set load values to the classified ranges in advance, and stepwisely performing operation control, even in cases where load variations of the boiler or the like have occurred, and have completed the invention.
- Hereinafter, embodiments of the invention will be described in detail with reference to the accompanying drawings. In addition, the invention is not limited to the following embodiments, can be appropriately changed and carried out. Additionally, the configurations of CO2 recovery apparatuses related to the following respective embodiments can be appropriately combined and carried out.
-
Fig. 1 is a schematic view of a CO2 recovery apparatus related to a first embodiment of the invention. As illustrated inFig. 1 , the CO2 recovery apparatus 1 is an apparatus that absorbs CO2 in an exhaust gas (a gas to be treated) 11A containing CO2 exhausted from industrial facilities, such as a boiler and a gas turbine, and recovers a high-concentration CO2 gas. The CO2 recovery apparatus 1 includes acooling tower 12 that cools theexhaust gas 11A containing CO2 exhausted from industrial facilities, such as a boiler and a gas turbine; a CO2 absorption tower 14 that is provided in a subsequent stage of thecooling tower 12, brings the cooledexhaust gas 11A into contact with a CO2 absorbing liquid 13, and makes the CO2 absorbing liquid 13 absorb and remove CO2 in theexhaust gas 11A; and a CO2 absorbingliquid regeneration tower 15 that is provided in the subsequent stage of the CO2 absorption tower 14, releases CO2 from the CO2 absorbing liquid 13 that has absorbed the CO2, and regenerates CO2 absorbing liquid 13 is provided. - Additionally, the CO2 recovery apparatus 1 includes a flowmeter (flow rate measuring unit) 101 that is provided in a
flue 16 between the coolingtower 12 and the CO2 absorption tower 14, and measures the flow rates of theexhaust gas 11A introduced into the CO2 absorption tower 14, and acontrol unit 102 that classifies the flow rates of theexhaust gas 11A measured by theflowmeter 101 into multiple flow rate ranges, and controls the flow rate of the CO2 absorbing liquid 13 supplied to the CO2 absorption tower 14 and the flow rate of steam supplied to the CO2 absorbingliquid regeneration tower 15, on the basis of set load values that are preset according to the multiple flow rate range classifications. Thecontrol unit 102 can be realized, for example, using a general-purpose computer or an exclusive computer, such as a central arithmetic unit (CPU), a read-only memory (ROM), or a random access memory (RAM), and programs that operate on this computer. - In the CO2 recovery apparatus 1, the CO2 absorbing liquid 13 circulates between the CO2 absorption tower 14 and the CO2 absorbing liquid regeneration towers 15. The CO2 absorbing liquid 13 (lean solution) is supplied to the CO2 absorbing
liquid regeneration tower 15 as the CO2 absorbing liquid 13 (rich solution) that has absorbed CO2 in the CO2 absorption tower 14. Additionally, the CO2 absorbing liquid 13 (rich solution) is supplied to the CO2 absorption tower 14 as the CO2 absorbing liquid 13 (lean solution) from which substantially all CO2 has been removed and regenerated in the CO2 absorbingliquid regeneration tower 15. - The
cooling tower 12 has acooling section 121 that cools theexhaust gas 11A. A circulation line L1 is provided between a bottom part of thecooling tower 12 and a top part of thecooling section 121. Aheat exchanger 122 that cools cooling water W1, and acirculation pump 123 circulate the cooling water W1 within the circulation line L1 are provided in the circulation line L1. - In the
cooling section 121, theexhaust gas 11A is cooled by bringing theexhaust gas 11A into countercurrent contact with the cooling water W1. Theheat exchanger 122 cools the cooling water W1 heated by the heat exchange with theexhaust gas 11A. Thecirculation pump 123 supplies the cooling water W1, which has flowed down the bottom part of thecooling tower 12, to the top part of thecooling section 121 via theheat exchanger 122. - The CO2 absorption tower 14 includes a CO2 absorption section 141 that is provided on a lower part side of the CO2 absorption tower 14 and has the
exhaust gas 11A and the CO2 absorbing liquid 13 (lean solution) cooled in thecooling tower 12 supplied thereto, amain washing section 142 that is provided on an upper part side of the CO2 absorption tower 14, and apreliminary washing section 143 that is provided between and the CO2 absorption section 141 and themain washing section 142. Aliquid storage section 144 that stores washing water W2 for cleaning anexhaust gas 11C from which CO2 has been removed is provided at a bottom part of themain washing section 142. A circulation line L2, through which the washing water W2, containing the CO2 absorbing liquid 13 recovered in theliquid storage section 144, is supplied and circulated from a top part side of themain washing section 142, is provided between theliquid storage section 144 and an upper part of themain washing section 142. The circulation line L2 is provided with aheat exchanger 21 that cools the washing water W2, and acirculation pump 22 that circulates the washing water W2, containing the CO2 absorbing liquid 13 recovered in theliquid storage section 144, within the circulation line L2 via theheat exchanger 21. Additionally, the circulation line L2 is provided with an extraction line L3 through which a portion of the washing water W2 (washing water W3) is extracted and supplied to thepreliminary washing section 143. The extraction line L3 is provided with an adjustingvalve 23 that adjusts the amount of supply of washing water W3 supplied to thepreliminary washing section 143, and aheat exchanger 24 that cools the washing water W3 to a predetermined temperature. - In the CO2 absorption section 141, the
exhaust gas 11A containing CO2 and the CO2 absorbing liquid 13 containing alkanolamine or the like come into countercurrent contact with each other. Accordingly, CO2 in theexhaust gas 11A is absorbed by the CO2 absorbing liquid 13 through a chemical reaction shown in the following Formula. As a result, theexhaust gas 11A containing CO2 becomes anexhaust gas 11B from which CO2 has been removed by passing through the CO2 absorption section 141.
R-NH2 + H2O + CO2 → R-NH3HCO3
- In the
preliminary washing section 143, theexhaust gas 11B from which CO2 has been removed is brought into gas-liquid contact with the washing water W3 extracted from themain washing section 142, and is cleaned. As a result, theexhaust gas 11B from which CO2 has been removed becomes theexhaust gas 11C in which the CO2 absorbing liquid 13 entrained in theexhaust gas 11B has decreased. - In the
main washing section 142, theexhaust gas 11C from which CO2 that has passed through thepreliminary washing section 143 has been removed rises via achimney tray 145. Then, theexhaust gas 11C is brought into gas-liquid contact with the washing water W2 supplied from the top part side of themain washing section 142, and becomes anexhaust gas 11D from which the CO2 absorbing liquid 13 entrained in theexhaust gas 11C has been recovered by circulation cleaning. Theexhaust gas 11D is exhausted to the outside from a towertop part 14a of the CO2 absorption tower 14 after mist in the gas is trapped by amist eliminator 146. - A rich
solution supply tube 50 through which the CO2 absorbing liquid 13 (rich solution), which has absorbed CO2 in the CO2 absorption tower 14, is supplied to an upper part side of the CO2 absorbingliquid regeneration tower 15 is provided between a towerbottom part 14b of the CO2 absorption tower 14 and an upper part of the CO2 absorbingliquid regeneration tower 15. The richsolution supply tube 50 is provided with a richsolvent pump 51 that supplies the CO2 absorbing liquid 13 (rich solution), which has absorbed CO2 in the CO2 absorption tower 14, toward the CO2 absorbingliquid regeneration tower 15, and a rich-leansolution heat exchanger 52 that heats the CO2 absorbing liquid 13 (rich solution) that has absorbed CO2, using the CO2 absorbing liquid 13 (lean solution) which has been heated with steam and from which CO2 has been removed. - A central part of the CO2 absorbing
liquid regeneration tower 15 is provided with a CO2 absorbingliquid supply section 151 to which the CO2 absorbing liquid 13 that has absorbed CO2 is supplied. Atower bottom part 15b of the CO2 absorbingliquid regeneration tower 15 is provided with a circulation line L4 through which the CO2 absorbing liquid 13 that has flowed down to the towerbottom part 15b circulates. The circulation line L4 is provided with aregenerative heater 31 that heats the CO2 absorbing liquid 13 with saturated steam S, an adjustingvalve 32 that adjusts the amount of saturated steam S supplied to theregenerative heater 31, and acirculation pump 33 that supplies the CO2 absorbing liquid 13 of the towerbottom part 15b of the CO2 absorbingliquid regeneration tower 15 to a lower part of the CO2 absorbingliquid supply section 151 of the CO2 absorbingliquid regeneration tower 15 via theregenerative heater 31. The adjustingvalve 32 is adjusted in opening degree by thecontrol unit 102, and adjusts the amount of the saturated steam S supplied to theregenerative heater 31. - A tower
top part 15a of the CO2 absorbingliquid regeneration tower 15 is provided with a gas exhaust line L5 through which a CO2 gas 41 accompanied by steam is exhausted. The gas exhaust line L5 is provided with acondenser 42 that condenses moisture in the CO2 gas 41, and aseparation drum 43 that separates the CO2 gas 41 from condensed water W5. A CO2 gas 44 from which the condensed water W5 has been separated is released to the outside from an upper part of theseparation drum 43. A condensed water line L6 through which the condensed water W5 separated by theseparation drum 43 is supplied to the upper part of the CO2 absorbingliquid regeneration tower 15 is provided between a bottom part of theseparation drum 43 and the upper part of the CO2 absorbingliquid regeneration tower 15. The condensed water line L6 is provided with a condensedwater circulation pump 45 that supplies the condensed water W5 separated by theseparation drum 43 to the upper part of the CO2 absorbingliquid regeneration tower 15. - Additionally, the tower
bottom part 15b of the CO2 absorbingliquid regeneration tower 15 and an upper part of the CO2 absorption section 141 of the CO2 absorption tower 14 are provided with a leansolution supply tube 53 through which a lean solution in the towerbottom part 15b of the CO2 absorbingliquid regeneration tower 15 is supplied to the upper part of the CO2 absorption section 141. The leansolution supply tube 53 is provided with the rich-leansolution heat exchanger 52 that heats the CO2 absorbing liquid 13 (rich solution), which has absorbed CO2, using the CO2 absorbing liquid 13 (lean solution) which has been heated with steam and from which CO2 has been removed, alean solution pump 54 that supplies the lean solution in the towerbottom part 15b of the CO2 absorbingliquid regeneration tower 15 to the upper part of the CO2 absorption section 141, and acooling section 55 that cools the CO2 absorbing liquid 13 (lean solution) to a predetermined temperature. In thelean solution pump 54, the amount of supply of the CO2 absorbing liquid 13 (lean solution) is controllable by thecontrol unit 102. - Next, the control of the operation conditions of the CO2 recovery apparatus 1 related to the present embodiment will be described below with reference to
Figs. 2 and 3. Fig. 2 is a view illustrating the relationship between the operation time of the CO2 recovery apparatus 1 related to the present embodiment and changes in exhaust gas flow rate, andFig. 3 is a view illustrating the relationship between the operation time of the CO2 recovery apparatus 1 related to the present embodiment and the set load values of the CO2 recovery apparatus 1. - As illustrated in
Fig. 2 , in the CO2 recovery apparatus 1 related to the present embodiment, for example, the flow rate of an exhaust gas exhausted from industrial facilities, such as a boiler and a gas turbine varies depending on variations or the like of generated electric power accompanied by changes in electric power demand. In the CO2 recovery apparatus 1 related to the present embodiment, for example, as illustrated inFig. 2 , the exhaust gas flow rate varies at any time within a range of 70 or more and 100 or less with the lapse of time. Here, for example, in a case where the exhaust gas flow rate greatly varies within a range of 70 to 100 like within a time range of 0 or more and 1 or less illustrated inFig. 2 , thecontrol unit 102 is able to increase the flow rate of the CO2 absorbing liquid 13 supplied to the CO2 absorption tower 14, and increase the flow rate of steam supplied to the CO2 absorbingliquid regeneration tower 15, thereby optimize the operation conditions. However, in a case where the exhaust gas flow rate varies on a small scale at any time within a range of 90 or more and 100 or less like within a time range of 3 or more and 4 or less illustrated inFig. 2 , even if the operation conditions are finely controlled, operation conditions after a change may not be reflected on variations of an actual exhaust gas flow rate, and sufficient operation control may not be able to be performed. - Therefore, in the present embodiment, the exhaust gas flow rates per unit time measured by the
flowmeter 101 are classified into multiple flow rate ranges R1 to R7 (R4 to R7 are not illustrated) that are set in advance. For example, in the example illustrated inFig. 2 , thecontrol unit 102 classifies the exhaust gas flow rates as seven stages having a range where the exhaust gas flow rates of theexhaust gas 11A measured by theflowmeter 101 are more than 90 and 100 or less as a flow rate range R1, a range where the exhaust gas flow rates are more than 80 and 90 or less as a flow rate range R2, a range where the exhaust gas flow rates are more than 70 and 80 or less as a flow rate range R3, a range where the exhaust gas flow rates are more than 60 and 70 or less as a flow rate range R4, a range where the exhaust gas flow rates are more than 50 and 60 or less as a flow rate range R5, a range where the exhaust gas flow rate are more than 40 and 50 or less as a flow rate range R6, and a range where the exhaust gas flow rates are more than zero and 40 or less as a flow rate range R7. - Also, the
control unit 102 adjusts the flow rate of thelean solution pump 54 and the opening degree of the adjustingvalve 32 on the basis of the set load values that are preset according to the flow rate ranges R1 to R7 classified into the seven stages, and controls the flow rate of the CO2 absorbing liquid 13 supplied to the CO2 absorption tower 14 and the flow rate of steam supplied to the CO2 absorbingliquid regeneration tower 15. In addition, the set load values herein are, for example, the specific flow rates of thelean solution pump 54 and the specific opening degrees of the adjustingvalve 32 that are preset according to the flow rate ranges R1 to R7. - In a case where the exhaust gas flow rate is the flow rate range R1, the
control unit 102 adjusts the flow rate of thelean solution pump 54 and the opening degree of the adjustingvalve 32 in a range where the preset load values are 6 or more and 7 or less, and controls the flow rate of the CO2 absorbing liquid 13 supplied to the CO2 absorption tower 14 and the flow rate of steam supplied to the CO2 absorbingliquid regeneration tower 15. Similarly, in a case where the exhaust gas flow rate is the flow rate range R2, thecontrol unit 102 adjusts the flow rate of thelean solution pump 54 and the opening degree of the adjustingvalve 32 in a range where the preset load values are 5 or more and 6 or less. - In a case where the exhaust gas flow rate is the flow rate range R3, the
control unit 102 adjusts the flow rate of thelean solution pump 54 and the opening degree of the adjustingvalve 32 in a range where the preset load values are 4 or more and 5 or less. In a case where the exhaust gas flow rate is the flow rate range R4, thecontrol unit 102 adjusts the flow rate of thelean solution pump 54 and the opening degree of the adjustingvalve 32 in a range where the preset load values are 3 or more and 4 or less. - In a case where the exhaust gas flow rate is the flow rate range R5, the
control unit 102 adjusts the flow rate of thelean solution pump 54 and the opening degree of the adjustingvalve 32 in a range where the preset load values are 2 or more and 3 or less. In a case where the exhaust gas flow rate is the flow rate range R6, thecontrol unit 102 adjusts the flow rate of thelean solution pump 54 and the opening degree of the adjustingvalve 32 in a range where the preset load values are 1 or more and 2 or less. - In a case where the exhaust gas flow rate is the flow rate range R7, the
control unit 102 adjusts the flow rate of thelean solution pump 54 and the opening degree of the adjustingvalve 32 in a range where the preset load values are more than 0 and 1 or less. As thecontrol unit 102 controls the operation condition of the CO2 recovery apparatus 1 in this way, it is possible to appropriately control the operation conditions over variations of the actual exhaust gas flow rate even in a case where the exhaust gas flow rate varies on a small scale at any time within a range of the flow rate ranges R1 to R7. In addition, thecontrol unit 102 may appropriately change the set load values to control operation according to elapsed time as long as it is within a range of the set load values corresponding to the range of the flow rate ranges R1 to R7. - Additionally, in the CO2 recovery apparatus 1 related to the present embodiment, it is preferable that the
control unit 102 keeps the set load values substantially constant to control the flow rate of the CO2 absorbing liquid 13 supplied to the CO2 absorption tower 14 and the flow rate of the saturated steam S supplied to the CO2 absorbingliquid regeneration tower 15, within the above-described multiple flow rate ranges R1 to R7. For example, as illustrated at thetimes 3 to 4 ofFigs. 2 and 3 , the set load value is kept at 7 in a case where the exhaust gas flow rate is in the flow rate range R1. Accordingly, even if the flow rate or the like of theexhaust gas 11A varies within the flow rate range R1, it is possible to keep the flow rate of the CO2 absorbing liquid 13 supplied to the CO2 absorption tower 14 and the flow rate of the saturated steam S supplied to the CO2 absorbingliquid regeneration tower 15 substantially constant. Accordingly, since the variations of the flow rate of the CO2 absorbing liquid 13 supplied to the CO2 absorption tower 14 and the flow rate of the steam S supplied to the CO2 absorbingliquid regeneration tower 15 can be made small, it is possible to improve the total operational efficiency and stability of the apparatus. - Moreover, in the CO2 recovery apparatus 1 related to the present embodiment, it is preferable that the
control unit 102 keeps the set load values at maximum values corresponding to the flow rate ranges R1 to R7 to control the flow rate of the CO2 absorbing liquid 13 supplied to the CO2 absorption tower 14 and the flow rate of the steam S supplied to the CO2 absorbingliquid regeneration tower 15, within the multiple flow rate ranges R1 to R7. For example, as illustrated at thetimes 3 to 4 ofFigs. 2 and 3 , in a case where the exhaust gas flow rate is in the flow rate range R1, the set load value is kept at 7 that is a maximum value of 6 or more and 7 or less corresponding to the flow rate range R1. Accordingly, the operation conditions of the flow rate of the CO2 absorbing liquid 13 supplied to the CO2 absorption tower 14 and the flow rate of the saturated steam S supplied to the CO2 absorbingliquid regeneration tower 15, according to the set maximum load values within the flow rate ranges R1 to R7, can be controlled. Thus, even in a case where the flow rate of theexhaust gas 11A varies within the flow rate ranges R1 to R7, it is possible to appropriately control the flow rate of the CO2 absorbing liquid 13 supplied to the CO2 absorption tower 14 and the flow rate of the steam S supplied to the CO2 absorbingliquid regeneration tower 15. - Additionally, in the CO2 recovery apparatus 1 related to the present embodiment, it is preferable that the
control unit 102 classifies the flow rate ranges of the exhaust gas flow rates of theexhaust gas 11A to be set in advance into the seven stages. Accordingly, since the number of the flow rate ranges R1 to R7 to be set in advance is in a moderate range, it is possible to improve the total operational efficiency and stability of the CO2 recovery apparatus 1. In addition, the flow rate ranges of the exhaust gas flow rates are not limited to the seven stages, and the exhaust gas flow rates may be classified into seven stages or more, or less than seven stages. - Next, the overall operation of the CO2 recovery apparatus 1 related to the present embodiment will be described with reference to
Fig. 4. Fig. 4 is a flowchart of the operation control of the CO2 recovery apparatus 1 related to the present embodiment. As illustrated inFig. 4 , in the CO2 recovery apparatus 1 related to the present embodiment, theflowmeter 101 measures the exhaust gas flow rates of theexhaust gas 11A introduced into the CO2 absorption tower 14 (Step S11), and thecontrol unit 102 classifies the exhaust gas flow rates detected by theflowmeter 101 into the preset flow rate ranges, and calculates the set load value according to the classified flow rate ranges (Step S12). Then, thecontrol unit 102 calculates the flow rate of the CO2 absorbing liquid 13 supplied to the CO2 absorption tower 14 and the flow rate of the steam S supplied to the CO2 absorbingliquid regeneration tower 15 according to the set load values (Step S13), and adjusts the flow rate of thelean solution pump 54 and the opening degree of the adjustingvalve 32 so that the calculated flow rates are obtained (Step S14). - The
exhaust gas 11A containing CO2 exhausted from industrial facilities, such as a boiler and a gas turbine, is introduced into thecooling tower 12, and is brought into countercurrent contact with and cooled by the cooling water W1. The cooledexhaust gas 11A is introduced into the CO2 absorption tower 14 via theflue 16, and the flow rates of theexhaust gas 11A introduced into the CO2 absorption tower 14 are measured. Theexhaust gas 11A introduced into the CO2 absorption tower 14 is brought into countercurrent contact with and cooled by the CO2 absorbing liquid 13 containing alkanolamine or the like in the CO2 absorption section 141, and becomes theexhaust gas 11B from which CO2 in theexhaust gas 11A has been absorbed by the CO2 absorbing liquid 13 and CO2 has been removed. - The
exhaust gas 11B from which CO2 has been removed is brought into gas-liquid contact with and cleaned by the washing water W3, which is a portion of the washing water W2 extracted from themain washing section 142, in thepreliminary washing section 143, and becomes theexhaust gas 11C in which the CO2 absorbing liquid 13 entrained in theexhaust gas 11B has decreased. Theexhaust gas 11C rises via thechimney tray 145, is brought into gas-liquid contact with the washing water W2 supplied from the top part side of themain washing section 142, and becomes theexhaust gas 11D from which the CO2 absorbing liquid 13 entrained in theexhaust gas 11C has been recovered by circulation cleaning. Theexhaust gas 11D is exhausted to the outside from the towertop part 14a of the CO2 absorption tower 14 after mist in the gas is trapped by amist eliminator 146. - The CO2 absorbing liquid 13 (rich solution) that has absorbed CO2 in the CO2 absorption tower 14 is supplied to the upper part of the CO2 absorbing
liquid regeneration tower 15 by the richsolvent pump 51 after being heat-exchanged with the CO2 absorbing liquid 13 (lean solution) in the rich-leansolution heat exchanger 52 via the richsolution supply tube 50. The CO2 absorbing liquid 13 supplied to the CO2 absorbingliquid regeneration tower 15 has CO2 removed therefrom and becomes a semi-lean solution, while flowing down to the towerbottom part 15b via the CO2 absorbingliquid supply section 151. This semi-lean solution while is circulates through the circulation line L4 by thecirculation pump 33, is heated by the saturated steam S in theregenerative heater 31, and becomes a lean solution. Here, thecontrol unit 102 controls the opening degree of the adjustingvalve 32 so that the amount of supply of the saturated steam S is obtained on the basis of set load values according to the flow rate ranges of the exhaust gas flow rates of theexhaust gas 11A measured by theflowmeter 101. The saturated steam S after being heated becomes the steam condensed water W4. The CO2 gas 41 removed from the CO2 absorbing liquid 13 is released to the outside as the CO2 gas 44 from which the condensed water W5 has been separated through the upper part of theseparation drum 43 after the moisture thereof is condensed by thecondenser 42. - The CO2 absorbing liquid 13 (lean solution) of the tower
bottom part 15b of the CO2 absorbingliquid regeneration tower 15 is supplied to the upper part of the CO2 absorption section 141 of the CO2 absorption tower 14 by thelean solution pump 54 after being heat-exchanged with the CO2 absorbing liquid 13 (rich solution) by the rich-leansolution heat exchanger 52 via the leansolution supply tube 53. Here, thecontrol unit 102 controls the flow rate of thelean solution pump 54 on the basis of the set load values according to the flow rate ranges R1 to R7 of the exhaust gas flow rates of theexhaust gas 11A measured by theflowmeter 101. - As described above, according to the present embodiment, even in a case where the flow rate of the
exhaust gas 11A increases or decreases within classifications of the multiple flow rate ranges R1 to R7, it is possible to maintain the operation conditions on the basis of the set load values corresponding to the flow rate ranges R1 to R7. Accordingly, in the CO2 recovery apparatus, even in a case where the flow rate of theexhaust gas 11A may vary at any time within classifications of the multiple flow rate ranges R1 to R7, the variations of the flow rate of the CO2 absorbing liquid 13 supplied to the CO2 absorption tower 14 and the flow rate of the steam S supplied to the CO2 absorbingliquid regeneration tower 15 can be made small. Thus, it is possible to improve the total operational efficiency and stability of the apparatus. - In addition, an example in which the
exhaust gas 11A containing CO2 exhausted from industrial facilities, such as a boiler and a gas turbine, is treated by the CO2 absorbing liquid 13 has been described in the above-described embodiment. However, as gases to be treated that is treated by the CO2 absorbing liquid 13, various gases can be applied if they are gases containing CO2. - Next, a second embodiment of the invention will be described. In addition, constituent elements common to those of the CO2 recovery apparatus 1 related to the above-described first embodiment will be designated by the same reference signs, and duplication of description thereof will be avoided.
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Fig. 5 is a schematic view of a CO2 recovery apparatus 2 related to a second embodiment of the invention. A CO2 recovery apparatus 2 related to the present embodiment includes a CO2 concentration meter (CO2 concentration measuring unit) 103 that measures CO2 concentration in theexhaust gas 11A, in theflue 16, in addition to the configuration of the CO2 recovery apparatus 1 related to the above-described first embodiment. Thecontrol unit 102 obtains CO2 flow rates in theexhaust gas 11A, on the basis of the exhaust gas flow rates of theexhaust gas 11A measured by theflowmeter 101 and the CO2 concentration in theexhaust gas 11A measured by a CO2 concentration meter 103. The CO2 concentration meter 103 is not particularly limited if the CO2 concentration in theexhaust gas 11A can be measured. - Next, the control of the operation conditions of the CO2 recovery apparatus 2 related to the present embodiment will be described below with reference to
Figs. 6 and 7. Fig. 6 is a view illustrating the relationship between the operation time of the CO2 recovery apparatus 2 related to the present embodiment and changes in CO2 flow rate, andFig. 7 is a view illustrating the relationship between the operation time of the CO2 recovery apparatus 2 related to the present embodiment and the set load values of the CO2 recovery apparatus 2. - As illustrated in
Fig. 6 , in the present embodiment, thecontrol unit 102 calculates CO2 flow rates on the basis of the exhaust gas flow rates of theexhaust gas 11A measured by theflowmeter 101 and the CO2 concentration of theexhaust gas 11A measured by the CO2 concentration meter 103, and classifies the calculated CO2 flow rates into multiple flow rate ranges R11 to R17 (R14 to R17 are not illustrated). For example, in the example illustrated inFig. 6 , thecontrol unit 102 classifies the CO2 flow rates as seven stages having a range where the CO2 flow rates of theexhaust gas 11A measured by theflowmeter 101 are more than 90 and 100 or less as a flow rate range R11, a range where the CO2 flow rates are more than 80 and 90 or less as a flow rate range R12, a range where the CO2 flow rates are more than 70 and 80 or less as a flow rate range R13, a range where the CO2 flow rates are more than 60 and 70 or less as a flow rate range R14, a range where the CO2 flow rates are more than 50 and 60 or less as a flow rate range R15, a range where the CO2 flow rates are more than 40 and 50 or less as a flow rate range R16, a range where the CO2 flow rates are more than zero and 40 or less as a flow rate range R17 in advance. - Also, the
control unit 102 adjusts the flow rate of thelean solution pump 54 and the opening degree of the adjustingvalve 32 within a range of the set load values that are preset according to the flow rate ranges R11 to R17 classified into the seven stages, and controls the flow rate of the CO2 absorbing liquid 13 supplied to the CO2 absorption tower 14 and the flow rate of steam supplied to the CO2 absorbingliquid regeneration tower 15. In addition, the set load values herein are, for example, the specific flow rates of thelean solution pump 54 and the specific opening degrees of the adjustingvalve 32 that are preset according to the flow rate ranges R11 to R17. - In a case where the CO2 flow rates are in the flow rate range R11, the
control unit 102 adjusts the flow rate of thelean solution pump 54 and the opening degree of the adjustingvalve 32 in a range where the preset load values are 6 or more and 7 or less, and controls the flow rate of the CO2 absorbing liquid 13 supplied to the CO2 absorption tower 14 and the flow rate of steam supplied to the CO2 absorbingliquid regeneration tower 15. Similarly, in a case where the CO2 flow rates are in the flow rate range R12, thecontrol unit 102 adjusts the flow rate of thelean solution pump 54 and the opening degree of the adjustingvalve 32 in a range where the preset load values are 5 or more and 6 or less. - Additionally, in a case where the CO2 flow rates are in the flow rate range R13, the
control unit 102 adjusts the flow rate of thelean solution pump 54 and the opening degree of the adjustingvalve 32 so that the preset load value of the CO2 recovery apparatus 2 is within a range of 4 or more and 5 or less. In a case where the CO2 flow rates are in the flow rate range R14, thecontrol unit 102 adjusts the flow rate of thelean solution pump 54 and the opening degree of the adjustingvalve 32 in a range where the preset load values are 3 or more and 4 or less. - Moreover, in a case where the CO2 flow rates are in the flow rate range R15, the
control unit 102 adjusts the flow rate of thelean solution pump 54 and the opening degree of the adjustingvalve 32 in a range where the preset load values are 2 or more and 3 or less. In a case where the CO2 flow rates are in the flow rate range R16, thecontrol unit 102 adjusts the flow rate of thelean solution pump 54 and the opening degree of the adjustingvalve 32 in a range where the preset load values are 1 or more and 2 or less. - Additionally, in a case where the CO2 flow rates are in the flow rate range R17, the
control unit 102 adjusts the flow rate of thelean solution pump 54 and the opening degree of the adjustingvalve 32 in a range where the preset load values are 0 or more and 1 or less. As thecontrol unit 102 controls the operation condition of the CO2 recovery apparatus 2 in this way, it is possible to appropriately control the operation conditions over variations of the actual CO2 flow rates even in a case where the CO2 flow rates vary on a small scale at any time within a range of the flow rate ranges R11 to R17. In addition, thecontrol unit 102 may appropriately change the set load values to control operation according to elapsed time as long as the exhaust gas flow rate is within a range of the set load values corresponding to the range of the flow rate ranges R11 to R17. - Next, the overall operation of the CO2 recovery apparatus 2 related to the present embodiment will be described with reference to
Fig. 8. Fig. 8 is a flowchart of the operation control of the CO2 recovery apparatus 2 related to the present embodiment. As illustrated inFig. 8 , in the CO2 recovery apparatus 2 related to the present embodiment, theflowmeter 101 measures the exhaust gas flow rates of theexhaust gas 11A introduced into the CO2 absorption tower 14, and the CO2 concentration meter 103 measures CO2 concentration in theexhaust gas 11A (Step S21). Next, thecontrol unit 102 obtains CO2 flow rates per unit time, on the basis of the measured exhaust gas flow rates and CO2 concentration of theexhaust gas 11A (Step S22). Next, thecontrol unit 102 classifies the obtained CO2 flow rates into preset flow rate ranges, and calculates set load values according to the classified flow rate ranges (Step S23). Then, thecontrol unit 102 calculates the flow rate of the CO2 absorbing liquid 13 supplied to the CO2 absorption tower 14 and the flow rate of the steam S supplied to the CO2 absorbingliquid regeneration tower 15 according to the set load values (Step S24), and adjusts the flow rate of thelean solution pump 54 and the opening degree of the adjustingvalve 32 so that the calculated flow rates are obtained (Step S25). - As described above, according to the present embodiment, the
control unit 102 performs operation control, on the basis of the CO2 flow rates obtained by measuring the flow rates of theexhaust gas 11A and the CO2 concentration in theexhaust gas 11A. Thus, the flow rate of the CO2 absorbing liquid 13 supplied to the CO2 absorption tower 14 and the flow rate of the steam S supplied to the CO2 absorbingliquid regeneration tower 15 can be more precisely controlled. -
- 1, 2: CO2
- RECOVERY APPARATUS
- 11A, 11B, 11C, 11D:
- EXHAUST GAS
- 12:
- COOLING TOWER
- 121:
- COOLING SECTION
- 122:
- HEAT EXCHANGER
- 123:
- CIRCULATION PUMP
- 13:
- CO2 ABSORBING LIQUID
- 14:
- CO2 ABSORPTION TOWER
- 14a:
- TOWER TOP PART
- 14b:
- TOWER BOTTOM PART
- 141:
- CO2 ABSORPTION SECTION
- 142:
- MAIN WASHING SECTION
- 143:
- PRELIMINARY WASHING SECTION
- 144:
- LIQUID STORAGE SECTION
- 145:
- CHIMNEY TRAY
- 146:
- MIST ELIMINATOR
- 15:
- CO2 ABSORBING LIQUID REGENERATION TOWER
- 15a:
- TOWER TOP PART
- 151:
- CO2 ABSORBING LIQUID SUPPLY SECTION
- 16:
- FLUE
- 21:
- HEAT EXCHANGER
- 22:
- CIRCULATION PUMP
- 23:
- ADJUSTING VALVE
- 24:
- HEAT EXCHANGER
- 31:
- REGENERATIVE HEATER
- 32:
- ADJUSTING VALVE
- 33:
- CIRCULATION PUMP
- 41, 44:
- CO2 GAS
- 42:
- CONDENSER
- 43:
- SEPARATION DRUM
- 45:
- CONDENSED WATER CIRCULATION PUMP
- 50:
- RICH SOLUTION SUPPLY TUBE
- 51:
- RICH SOLVENT PUMP
- 52:
- RICH-LEAN SOLUTION HEAT EXCHANGER
- 53:
- LEAN SOLUTION SUPPLY TUBE
- 54:
- LEAN SOLUTION PUMP
- 55:
- COOLING SECTION
- 101:
- FLOWMETER
- 102:
- CONTROL UNIT
- 103:
- CO2 CONCENTRATION METER
- L1, L2, L4:
- CIRCULATION LINE
- L3:
- EXTRACTION LINE
- L5:
- GAS EXHAUST LINE
- L6:
- CONDENSED WATER LINE
- S:
- SATURATED STEAM
- W1:
- COOLING WATER
- W2, W3:
- WASHING WATER
- W4:
- STEAM CONDENSED WATER
- W5:
- CONDENSED WATER
Claims (8)
- A CO2 recovery apparatus (1) comprising:a CO2 absorption tower (14) that brings a gas to be treated containing CO2 into contact with a CO2 absorbing liquid and makes the CO2 absorbing liquid absorb CO2 contained in the gas to be treated;a CO2 absorbing liquid regeneration tower (15) that heats the CO2 absorbing liquid, which has absorbed CO2, with steam, releases CO2 from the CO2 absorbing liquid, and regenerates the CO2 absorbing liquid;a flow rate measuring unit (101) that measures the flow rates of the gas to be treated that is introduced into the CO2 absorption tower (14); anda control unit (102) that classifies the flow rates of the gas to be treated measured by the flow rate measuring unit (101) into multiple flow rate ranges, and controls the flow rate of the CO2 absorbing liquid supplied to the CO2 absorption tower (14) and the flow rate of steam supplied to the CO2 absorbing liquid regeneration tower (15), on the basis of set load values that are preset according to the multiple flow rate range classifications,characterized in that the control unit (102) keeps the set load values constant within the multiple flow rate ranges and thereby controls the flow rate of the CO2 absorbing liquid supplied to the CO2 absorption tower (14) and the flow rate of the steam supplied to the CO2 absorbing liquid regeneration tower (15).
- A CO2 recovery apparatus (2) comprising:a CO2 absorption tower that brings a gas to be treated containing CO2 into contact with a CO2 absorbing liquid and makes the CO2 absorbing liquid absorb CO2 contained in the gas to be treated;a CO2 absorbing liquid regeneration tower that heats the CO2 absorbing liquid, which has absorbed CO2, with steam, releases CO2 from the CO2 absorbing liquid, and regenerates the CO2 absorbing liquid;a flow rate measuring unit that measures the flow rates of the gas to be treated that is introduced into the CO2 absorption tower;a CO2 concentration measuring unit (103) that measures the CO2 concentration of the gas to be treated that is introduced into the CO2 absorption tower (14); anda control unit (102) that classifies CO2 flow rates in the gas to be treated, which are obtained on the basis of the flow rates of the gas to be treated that are measured by the flow rate measuring unit (101) and the CO2 concentration in the gas to be treated that is measured by the CO2 concentration measuring unit (103), into multiple flow rate ranges, and controls the flow rate of the CO2 absorbing liquid supplied to the CO2 absorption tower and the flow rate of steam supplied to the CO2 absorbing liquid regeneration tower, on the basis of set load values that are preset according to the multiple flow rate range classifications,characterized in that the set load values are kept constant within the multiple flow rate ranges and the flow rate of the CO2 absorbing liquid supplied to the CO2 absorption tower (14) and thereby the flow rate of the steam supplied to the CO2 absorbing liquid regeneration tower (15) are controlled.
- The CO2 recovery apparatus (1, 2) according to Claim 1 or 2,
wherein the control unit (102) keeps the set load values constant at maximum values corresponding to the flow rate ranges within the multiple flow rate ranges and thereby controls the flow rate of the CO2 absorbing liquid supplied to the CO2 absorption tower (14) and the flow rate of the steam supplied to the CO2 absorbing liquid regeneration tower (15). - The CO2 recovery apparatus (1, 2) according to any one of Claims 1 to 3,
wherein there are 7 or less classifications in the multiple flow rate ranges. - A CO2 recovery process comprising:a CO2 absorption step of bringing a gas to be treated containing CO2 into contact with a CO2 absorbing liquid in a CO2 absorption tower (14) and making the CO2 absorbing liquid absorb CO2 contained in the gas to be treated;a regeneration step of heating the CO2 absorbing liquid, which has absorbed CO2, with steam in a CO2 absorbing liquid regeneration tower (15), releasing CO2, and regenerating the CO2 absorbing liquid;a step of measuring the flow rates of the gas to be treated that is introduced into the CO2 absorption tower (14) in a flow rate measuring unit (101); anda step of classifying the measured flow rates of the gas to be treated into multiple flow rate ranges, and controlling the flow rate of the CO2 absorbing liquid supplied to the CO2 absorption tower (14) and the flow rate of steam supplied to the CO2 absorbing liquid regeneration tower (15), on the basis of set load values that are preset according to the multiple flow rate range classifications,characterized in that the set load values are kept constant within the multiple flow rate ranges and the flow rate of the CO2 absorbing liquid supplied to the CO2 absorption tower (14) and thereby the flow rate of the steam supplied to the CO2 absorbing liquid regeneration tower (15) are controlled.
- A CO2 recovery process, comprising:a CO2 absorption step of bringing a gas to be treated containing CO2 into contact with a CO2 absorbing liquid in a CO2 absorption tower and making the CO2 absorbing liquid absorb CO2 contained in the gas to be treated;a regeneration step of heating the CO2 absorbing liquid, which has absorbed CO2, with steam in a CO2 absorbing liquid regeneration tower, releasing CO2, and regenerating the CO2 absorbing liquid;a step of measuring the flow rates of the gas to be treated, which is introduced into the CO2 absorption tower, in a flow rate measuring unit, and measuring the CO2 concentration of the gas to be treated, which is introduced into the CO2 absorption tower (14), in a CO2 concentration measuring unit (103); anda step of classifying CO2 flow rates, which are obtained on the basis of the measured flow rates of the gas to be treated and the measurement value of the CO2 concentration, into multiple flow rate ranges, and controlling the flow rate of the CO2 absorbing liquid supplied to the CO2 absorption tower (14) and the flow rate of steam supplied to the CO2 absorbing liquid regeneration tower (15), on the basis of set load values that are preset according to the multiple flow rate range classifications,characterized in that the set load values are kept constant within the multiple flow rate ranges and the flow rate of the CO2 absorbing liquid supplied to the CO2 absorption tower (14) and thereby the flow rate of the steam supplied to the CO2 absorbing liquid regeneration tower (15) are controlled.
- The CO2 recovery process according to Claim 5 or 6,
wherein the set load values are kept constant at maximum values corresponding to the flow rate ranges within the multiple flow rate ranges and thereby the flow rate of the CO2 absorbing liquid supplied to the CO2 absorption tower (14) and the flow rate of the steam supplied to the CO2 absorbing liquid regeneration tower (15) are controlled. - The CO2 recovery process according to any one of Claims 5 to 7,
wherein there are 7 or less classifications in the multiple flow rate ranges.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2014011562A JP6200338B2 (en) | 2014-01-24 | 2014-01-24 | CO2 recovery device and CO2 recovery method |
PCT/JP2015/050550 WO2015111454A1 (en) | 2014-01-24 | 2015-01-09 | Co2 recovery apparatus and co2 recovery process |
Publications (3)
Publication Number | Publication Date |
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EP3061516A1 EP3061516A1 (en) | 2016-08-31 |
EP3061516A4 EP3061516A4 (en) | 2016-11-23 |
EP3061516B1 true EP3061516B1 (en) | 2017-11-29 |
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EP15740962.4A Active EP3061516B1 (en) | 2014-01-24 | 2015-01-09 | Co2 recovery apparatus and co2 recovery process |
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US (1) | US10427093B2 (en) |
EP (1) | EP3061516B1 (en) |
JP (1) | JP6200338B2 (en) |
AU (1) | AU2015210213B2 (en) |
CA (1) | CA2931871C (en) |
NO (1) | NO3061516T3 (en) |
WO (1) | WO2015111454A1 (en) |
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JP6796140B2 (en) | 2016-10-19 | 2020-12-02 | 三菱重工業株式会社 | Carbon dioxide capture system, thermal power generation equipment, and carbon dioxide capture method |
JP6953777B2 (en) * | 2017-04-28 | 2021-10-27 | 株式会社Ihi | Carbon dioxide recovery system and recovery method |
JP6990103B2 (en) * | 2017-12-20 | 2022-01-12 | 株式会社東芝 | How to maintain carbon dioxide capture equipment and carbon dioxide capture equipment |
US11801472B2 (en) * | 2019-01-28 | 2023-10-31 | Saudi Arabian Oil Company | Amine sweetening in flash gas |
JP7332404B2 (en) * | 2019-09-12 | 2023-08-23 | 株式会社東芝 | CO2 RECOVERY SYSTEM AND METHOD OF OPERATION THEREOF |
CN113797715A (en) * | 2021-10-19 | 2021-12-17 | 新疆大全新能源股份有限公司 | Step control process and system for polycrystalline silicon tail gas recovery absorption liquid |
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US2549952A (en) | 1947-07-10 | 1951-04-24 | Carlton M Wheelock | Heating device and automatic control means therefor |
US4106916A (en) * | 1977-08-10 | 1978-08-15 | Phillips Petroleum Company | Automatic control of an absorption/stripping process |
US4198388A (en) | 1978-02-14 | 1980-04-15 | Bethlehem Steel Corporation | Selective removal of H2 S from an H2 S and CO2 containing gas stream |
US4772298A (en) | 1982-11-24 | 1988-09-20 | Phillips Petroleum Company | Control of a H2 S absorber |
JP3212524B2 (en) | 1996-12-16 | 2001-09-25 | 関西電力株式会社 | Control method of flue gas decarbonation equipment |
CA2779625C (en) * | 2009-06-17 | 2014-11-18 | Mitsubishi Heavy Industries, Ltd. | Co2 recovering apparatus and method |
JP2011000528A (en) * | 2009-06-17 | 2011-01-06 | Mitsubishi Heavy Ind Ltd | Co2 recovering device and co2 recovering method |
JP2011177684A (en) * | 2010-03-03 | 2011-09-15 | Toshiba Corp | Carbon dioxide separation and recovery system |
JP6216490B2 (en) * | 2012-02-03 | 2017-10-18 | 三菱重工業株式会社 | CO2 recovery device |
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2014
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US10427093B2 (en) | 2019-10-01 |
AU2015210213A1 (en) | 2016-06-16 |
EP3061516A4 (en) | 2016-11-23 |
EP3061516A1 (en) | 2016-08-31 |
CA2931871A1 (en) | 2015-07-30 |
WO2015111454A1 (en) | 2015-07-30 |
NO3061516T3 (en) | 2018-04-28 |
JP2015136687A (en) | 2015-07-30 |
AU2015210213B2 (en) | 2017-12-14 |
US20170106332A1 (en) | 2017-04-20 |
JP6200338B2 (en) | 2017-09-20 |
CA2931871C (en) | 2018-05-01 |
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