EP2996967B1 - Behälter zur lagerung und zum transport organischer peroxyde - Google Patents

Behälter zur lagerung und zum transport organischer peroxyde Download PDF

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Publication number
EP2996967B1
EP2996967B1 EP14729952.3A EP14729952A EP2996967B1 EP 2996967 B1 EP2996967 B1 EP 2996967B1 EP 14729952 A EP14729952 A EP 14729952A EP 2996967 B1 EP2996967 B1 EP 2996967B1
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EP
European Patent Office
Prior art keywords
container
thermal insulation
insulation means
reservoir
partition
Prior art date
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Active
Application number
EP14729952.3A
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English (en)
French (fr)
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EP2996967A1 (de
Inventor
Olaf Tietze
Philippe Maj
Ralf WITTLINGER
Martin Moellers
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Arkema France SA
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Arkema France SA
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Filing date
Publication date
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Application filed by Arkema France SA filed Critical Arkema France SA
Priority to PL14729952T priority Critical patent/PL2996967T3/pl
Priority to EP18198929.4A priority patent/EP3441325A1/de
Publication of EP2996967A1 publication Critical patent/EP2996967A1/de
Application granted granted Critical
Publication of EP2996967B1 publication Critical patent/EP2996967B1/de
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Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65D—CONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
    • B65D88/00—Large containers
    • B65D88/74—Large containers having means for heating, cooling, aerating or other conditioning of contents
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65D—CONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
    • B65D85/00—Containers, packaging elements or packages, specially adapted for particular articles or materials
    • B65D85/50—Containers, packaging elements or packages, specially adapted for particular articles or materials for living organisms, articles or materials sensitive to changes of environment or atmospheric conditions, e.g. land animals, birds, fish, water plants, non-aquatic plants, flower bulbs, cut flowers or foliage
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65D—CONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
    • B65D90/00—Component parts, details or accessories for large containers
    • B65D90/02—Wall construction
    • B65D90/022—Laminated structures
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65D—CONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
    • B65D90/00—Component parts, details or accessories for large containers
    • B65D90/02—Wall construction
    • B65D90/027—Corrugated or zig-zag structures; Folded plate
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65D—CONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
    • B65D90/00—Component parts, details or accessories for large containers
    • B65D90/02—Wall construction
    • B65D90/06—Coverings, e.g. for insulating purposes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65D—CONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
    • B65D88/00—Large containers
    • B65D88/02—Large containers rigid
    • B65D88/10—Large containers rigid parallelepipedic

Definitions

  • the invention relates to a means for transporting, without danger and without degradation, thermosensitive products, particularly in regions where exposure to very high temperatures is inevitable.
  • the invention relates more particularly to a metal container for the storage and transport of organic peroxides.
  • thermosensitive products organic peroxides (or, more generally, chemical compounds capable of starting and / or promoting the polymerization / crosslinking of polymers) for which the present invention is particularly intended to provide solution.
  • organic peroxides or, more generally, chemical compounds capable of starting and / or promoting the polymerization / crosslinking of polymers
  • the present invention is particularly intended to provide solution.
  • special considerations in terms of safety must be taken during the storage and transport of organic peroxides, especially in connection with the temperature of said peroxides (often present in liquid form, or pasty).
  • Organic peroxides having particularly low decomposition temperatures are advantageously packaged in the form of an aqueous emulsion, comprising an antifreeze, said antifreeze allowing a maintenance in liquid form of the emulsion, at temperatures below -10 ° C., preferably below at -20 ° C. These negative temperatures make it possible to prevent the uncontrolled decomposition of said peroxides during storage and transport operations.
  • the presence of water, as a heat transfer fluid absorbs and dissipates the energy generated in case of possible decompositions of said peroxides.
  • Such refrigerant systems or complex thermal insulation are for example disclosed in the following documents: FR 1272944 , FR 1273907 , FR 1515058 , FR 2407434 and FR 2822880 .
  • WO2008 / 014572 A1 discloses a container for transporting thermally sensitive goods, such as wine bottles, but not requiring special safety precautions.
  • the container is dressed along its inner walls with double-sided reflective insulating layers.
  • the Applicant has discovered an insulation system particularly well suited to the transport and storage of peroxides in conventionally used containers.
  • This thermal insulation system removable and requiring no energy source, keeps the temperature of these products below their operating temperature limit, from which the risk of degradation or explosion, said products becomes significant.
  • the present invention thus relates to a container for storing and transporting organic peroxides as defined in claim 1.
  • the invention also relates to the use of thermal insulation means of a reservoir disposed in a container for storing and transporting organic peroxides, such as, in particular, polymerization and / or crosslinking initiators, the container, metallic preference, having two parallel longitudinal sides and two parallel lateral sides and two upper / lower faces, the container comprising at least one reservoir, preferably thermoplastic, for accommodating organic peroxides, said container comprising at least one opening for allowing the insertion and removal of the reservoir, preferably thermoplastic, containing said thermosensitive products, and thermal insulation means, wherein the thermal insulation means consist or are arranged according to any one of claims 1-10.
  • organic peroxides such as, in particular, polymerization and / or crosslinking initiators
  • the thermal insulation means can indeed be used in a particularly suitable manner with all types of containers, more particularly those metal currently used at present for the transport and storage of all types of products.
  • the container 1 is a conventional metal container.
  • This container 1 has two parallel longitudinal sides 2, 2 'and two lateral sides 3, perpendicular to said longitudinal sides, the longitudinal sides 2, 2' having larger dimensions than the lateral sides 3. It also comprises two faces, upper 4 and 4 'lower, so that obviously, this type of container 1 is closed especially during a transport of goods or products.
  • the container 1 Since the container 1 is intended to directly receive products / goods and / or one or more tanks or the like containing such products, it conventionally has an opening 6.
  • This opening 6 is here visible on the figure 4 and consists of two leaves 7, 7 'of the container 1 opening and closing one of the two lateral sides 3.
  • the container 1 also conventionally has walls whose section has a substantially crenellated shape so as to allow in particular a better mechanical resistance to shocks.
  • the present invention advantageously uses this conventional structure of metallic containers 1 in that it makes it possible to create an air chamber between the walls of the container 1 and the thermal insulation means 8.
  • the container 1 conventionally comprises at least one vent, generally located on its upper face 4, allowing a certain air exchange between the interior of the container 1 and the external environment.
  • the opening of this vent is often adjustable and can even be completely closed.
  • This type of container 1 conventionally comprises gripping means 9, such as those visible on the figure 3 .
  • Fastening means 10, present on the thermal insulation means 8, consisting of curved hooks, allow the removable mechanical attachment of the thermal insulation means 8 to the container 1 via its gripping means 9, spaced from each other and conventionally present near the junction of the upper face 4 and the sides 2, 2 'or 3.
  • the attachment means 10 being present ideally in number equivalent to the setting means 9 present in the container 1.
  • thermal insulation means 8 do not necessarily have fixing means in the lower part, the thermal insulation panels, consisting of the multilayer structure partition, extending vertically to touch the underside 4 'of the container 1.
  • gripping means 9 and catch 10 optionally having elastic portions (or spring), can also be envisaged respectively on the walls of the container 1 and the thermal insulation means 8 .
  • the insulation means 8 also have at each attachment means 10 a protruding portion 11 fixing said means, this protruding portion 11 being advantageously made of a thermal insulating material. It has been found that it is particularly important to avoid any physical contact with the walls 2, 2 ', 3 (metal) of the container 1 because the latter, by their very nature, heat very quickly when the containers are placed in an environment with a (very) high temperature.
  • the thermal insulation means 8 according to the invention advantageously make it possible, by their fixing and their arrangement in the container 1, to avoid any heat conduction of heat between the walls 2, 2 ', 3 and 4 of the container 1 and the tank 5 of products.
  • the thermal insulation means 8 may be installed so as to (re) cover at least the two longitudinal sides 2, 2 'as well as the upper face 4. Nevertheless, advantageously, the thermal insulation means 8 will extend between the reservoir 5 and the four sides 2, 2 'and 3. In this case, on the side face 3 having the opening of the container 1, the thermal insulation means 8 can easily be divided like the flaps 7 , 7 'of the opening of the container 1, for example by means of a zipper / opening 12 allowing an operator to open the thermal insulation means 8 on this side 3, without requiring the integral withdrawal of the latter 8.
  • the figure 4 schematically illustrates the lateral side 3 of the container 1 where the opening is located and the thermal insulation means 8 are visible with the opening / closing zipper 12 extending vertically over the entire height to allow the opening of said means 8 , identical to the two wings 7, 7 'of the opening of the container 1.
  • a good thermal insulating material by conduction, has at least one thermal conductivity, expressed in Wm -1 .K -1 (Watt per meter per Kelvin) at 20 ° C., less than 0.1 Wm . 1 .K -1 , preferably less than 0.05 Wm -1 .K -1 .
  • the thermal insulation wall 8 consists of a fabric or fabric with a multi-structure, that is to say constituted by a plurality of layers or films fixed to one another.
  • the thermal insulation means 8 are ideally formed of a plurality of adjacent layers or films each having heat-barrier properties, whether by radiation, convection or, of course, conduction, but also having an insulating effect. synergistic thermal by the association, in a specific order, of these different layers or films.
  • thermal insulation means 8 are light and relatively flexible so that a single operator can, without difficulty, adjust, arrange and fix said means 8 in the container 1.
  • thermal insulation means such as hooks or the like
  • mechanical means may be present on the entire inner surface of the container 1 and cooperate with anchoring means located on the thermal insulation means 8 so as to tighten this multilayer structure and effectively provide two thermal insulation chambers 14, 15 having a substantially constant volume.
  • one of the main aims of the present invention is to provide two thermal insulation chambers, each filled with air (which forms per se a good means of thermal insulation), separated by an excellent means of insulation thermal, in this case the multilayer structure according to the invention.
  • the air chamber 15 may be filled with a refrigerant gas capable of cooling this section and in particular the tank 5 containing the heat-sensitive materials. This solution is conceivable because of the impermeability of the multilayer structure 8.
  • thermosensitive material that it contains will not rise in temperature, or at all not beyond a critical threshold.
  • the outer wall of the thermal insulation means 8 is advantageously made of an excellent radiation reflective heat-reflecting metal material.
  • Such material can be aluminum.
  • this metallic material may be at the two ends of the sandwich formed by the multilayer structure of the thermal insulation means 8 or at least present on the outer side (forming the layer or film closest to the walls 2, 2 ', 3 or 4 of the container 1).
  • all the other layers or films are excellent thermal insulator (zero or very low thermal conduction) with respect to the definition given above.
  • one of the layers of the thermal insulation means 8 is advantageously made of polyethylene and another layer of polyester.
  • these elements can be replaced by other polymeric materials having excellent thermal insulation properties, such as for example polyurethane foam or expanded polystyrene.
  • the thermal insulation means may advantageously comprise an air bubble layer, conventionally made of polyethylene, because such a layer forms a very good thermal insulation.
  • an advantageous aspect of the invention lies in the formation of two air chambers 14, 15 (excellent thermal insulation) obtained by virtue of the particular placement of the thermal insulation means 8 according to the invention.
  • an air chamber 14 between the walls of the container 1 and the thermal insulation means 8 and between the insulation means 8 and the tank or tanks 5. This provision also avoids creating heat conduction points in other words, points of contact between the tank (s) 5 and the walls 2, 2 ', 3 or 4 of the container 1, the latter having the most important temperatures.
  • thermal insulation means 8 have been arranged and fixed inside the container 1 according to the use prescribed for said means 8.

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  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Evolutionary Biology (AREA)
  • General Health & Medical Sciences (AREA)
  • Marine Sciences & Fisheries (AREA)
  • Toxicology (AREA)
  • Zoology (AREA)
  • Packages (AREA)

Claims (11)

  1. Behälter zur Lagerung und zum Transport von organischen Peroxiden, wobei der Behälter (1) zwei parallele Längsseiten (2, 2') und zwei parallele Seitenflächen (3) und zwei obere/untere Seiten (4, 4') aufweist, wobei der vorzugsweise metallische Behälter (1) mindestens einen vorzugsweise thermoplastischen Tank (5) umfasst, der dazu bestimmt ist, organische Peroxide, wie insbesondere Polymerisations- und/oder Vernetzungsinitiatoren, zu enthalten, wobei der Behälter (1) mindestens eine Öffnung, die dazu bestimmt ist, das Einsetzen und Entnehmen des Tanks (5), der die organischen Peroxide enthält, zu gestatten, und Wärmeisoliermittel (8) umfasst, wobei in dem Behälter die Wärmeisoliermittel (8) abnehmbar sind und in einer Trennwand mit mehrschichtiger Struktur oder Folien bestehen, die zwischen der Wand des Tanks (5) und mindestens den Wänden von zwei der oben genannten Seiten (2, 2' oder 3) sowie der Oberseite (4) des Behälters (1) angeordnet ist, und wobei die Trennwand (8) in einem Abstand zu jeder der Wände (2, 2', 3, 4) angeordnet ist, um zwei Kammern (14, 15) zwischen den Wänden (2, 2', 3, 4) des Behälters (1) und der Trennwand (8) bzw. zwischen der Trennwand und der Wand des Tanks (5) zu bilden, wobei der Abstand zwischen der Trennwand (8) und den Wänden (2, 2', 3) zu der Seite oder der Fläche (4) des Behälters (1) mindestens einen Zentimeter, vorzugsweise mindestens drei Zentimeter, beträgt, und wobei die Trennwand mit mehrschichtiger Struktur (8) mindestens drei thermoplastische und/oder duroplastische Folien aufweist.
  2. Behälter nach Anspruch 1, dadurch gekennzeichnet, dass die Wärmeisoliermittel (8) zwischen den vier oben genannten Seiten (2, 2' und 3) des Behälters (1) und dem Tank (5) angeordnet sind.
  3. Behälter nach Anspruch 1 oder 2, dadurch gekennzeichnet, dass der Abstand zwischen der Wand des Tanks (5) und der Trennwand (8) mindestens zwei Zentimeter, vorzugsweise mindestens fünf Zentimeter, beträgt.
  4. Behälter nach einem der vorhergehenden Ansprüche, dadurch gekennzeichnet, dass die Wärmeisoliermittel (8) mechanisch auf dem Behälter (1) durch eine Vielzahl von Befestigungs- (10) und Eingriffspunkten (9), die auf den Wärmeisoliermitteln (8) bzw. auf dem Behälter (1) vorhanden sind, befestigt sind.
  5. Behälter nach Anspruch 4, dadurch gekennzeichnet, dass die Befestigungspunkte (10) in Haken bestehen, die dazu bestimmt sind, in einer Vielzahl von entsprechenden Eingriffspunkten (9), die an den Wänden (2, 2', 3) des Behälters (1) angeordnet sind, in Eingriff zu gelangen.
  6. Behälter nach Anspruch 4 oder 5, dadurch gekennzeichnet, dass die Befestigungspunkte (10) der Wärmeisoliermittel (8) vorstehend und zumindest teilweise von einem Wärmeisoliermaterial umgeben sind.
  7. Behälter nach einem der vorhergehenden Ansprüche, dadurch gekennzeichnet, dass eine der Folien der Trennwand mit mehrschichtiger Struktur (8) in einer metallischen Folie, vorzugsweise aus Aluminium, besteht, wobei die metallische Folie vorzugsweise eine äußere Schicht der mehrschichtigen Struktur bildet.
  8. Behälter nach Anspruch 8, dadurch gekennzeichnet, dass eine der Folien aus Polyethylen und eine weitere Folie aus Polyester ist.
  9. Behälter nach einem der vorhergehenden Ansprüche, dadurch gekennzeichnet, dass mindestens eine der Folien der Trennwand mit mehrschichtiger Struktur (8) eine Struktur mit Luftblasen aufweist.
  10. Behälter nach einem der vorhergehenden Ansprüche, dadurch gekennzeichnet, dass die Wärmeisoliermittel geeignet sind, die organischen Peroxide, die in dem Tank enthalten sind, auf einer Temperatur unter 60 °C, vorzugsweise unter 50 °C, noch bevorzugter unter 45 °C, zu halten.
  11. Verwendung von Wärmeisoliermitteln eines Tanks, der in einem Behälter zur Lagerung und zum Transport von organischen Peroxiden, wie insbesondere Polymerisations- und/oder Vernetzungsinitiatoren, wobei der vorzugsweise metallische Behälter (1) zwei parallele Längsseiten (2, 2') und zwei parallele Seitenflächen (3) und zwei obere/untere Seiten (4, 4') aufweist, wobei der Behälter (1) mindestens einen vorzugsweise thermoplastischen Tank (5) umfasst, der dazu bestimmt ist, organische Peroxide aufzunehmen,
    wobei der Behälter (1) mindestens eine Öffnung, die dazu bestimmt ist, das Einsetzen und Entnehmen des Tanks (5) zu gestatten, und Wärmeisoliermittel (8) umfasst,
    wobei bei der Verwendung die Wärmeisoliermittel (8) nach einem der vorhergehenden Ansprüche vorhanden oder angeordnet sind.
EP14729952.3A 2013-05-14 2014-05-14 Behälter zur lagerung und zum transport organischer peroxyde Active EP2996967B1 (de)

Priority Applications (2)

Application Number Priority Date Filing Date Title
PL14729952T PL2996967T3 (pl) 2013-05-14 2014-05-14 Pojemnik do przechowywania i transportu nadtlenków organicznych
EP18198929.4A EP3441325A1 (de) 2013-05-14 2014-05-14 Behälter zur lagerung und zum transport organischer peroxyde

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FR1354304A FR3005642B1 (fr) 2013-05-14 2013-05-14 Conteneur pour le stockage et le transport de produits thermosensibles
PCT/FR2014/051117 WO2014184491A1 (fr) 2013-05-14 2014-05-14 Conteneur pour le stockage et le transport de produits thermosensibles

Related Child Applications (2)

Application Number Title Priority Date Filing Date
EP18198929.4A Division-Into EP3441325A1 (de) 2013-05-14 2014-05-14 Behälter zur lagerung und zum transport organischer peroxyde
EP18198929.4A Division EP3441325A1 (de) 2013-05-14 2014-05-14 Behälter zur lagerung und zum transport organischer peroxyde

Publications (2)

Publication Number Publication Date
EP2996967A1 EP2996967A1 (de) 2016-03-23
EP2996967B1 true EP2996967B1 (de) 2018-11-14

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EP18198929.4A Pending EP3441325A1 (de) 2013-05-14 2014-05-14 Behälter zur lagerung und zum transport organischer peroxyde
EP14729952.3A Active EP2996967B1 (de) 2013-05-14 2014-05-14 Behälter zur lagerung und zum transport organischer peroxyde

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EP18198929.4A Pending EP3441325A1 (de) 2013-05-14 2014-05-14 Behälter zur lagerung und zum transport organischer peroxyde

Country Status (7)

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US (1) US11279553B2 (de)
EP (2) EP3441325A1 (de)
KR (1) KR102332259B1 (de)
ES (1) ES2702176T3 (de)
FR (1) FR3005642B1 (de)
PL (1) PL2996967T3 (de)
WO (1) WO2014184491A1 (de)

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR3005642B1 (fr) 2013-05-14 2016-01-01 Arkema France Conteneur pour le stockage et le transport de produits thermosensibles
FR3106661B1 (fr) * 2020-01-28 2022-01-21 Ateq Dispositif de détection de fuites
DK202200777A1 (en) * 2022-08-19 2024-02-21 Maersk As Container assembly

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WO2008014572A1 (en) 2006-08-04 2008-02-07 Kenneth Norman Osborne Container liner reflective on both sides and spaced from container wall
US20080197649A1 (en) 2007-02-15 2008-08-21 Blue Planet Logistics Method and apparatus for transporting cargo that is temperature or moisture sensitive
WO2010046790A1 (en) 2008-10-23 2010-04-29 Trans Ocean Liquid Technologies (Pty) Ltd Thermal insulation of shipping containers
US20110291045A1 (en) 2009-02-03 2011-12-01 Arkema Inc. Thixotropic anhydrous shear thinning peroxide dispersions
WO2014184491A1 (fr) 2013-05-14 2014-11-20 Arkema France Conteneur pour le stockage et le transport de produits thermosensibles

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US20050023278A1 (en) 2003-04-07 2005-02-03 Yong Lawrence Joon Leong Thermal insulation liner
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US20080197649A1 (en) 2007-02-15 2008-08-21 Blue Planet Logistics Method and apparatus for transporting cargo that is temperature or moisture sensitive
WO2010046790A1 (en) 2008-10-23 2010-04-29 Trans Ocean Liquid Technologies (Pty) Ltd Thermal insulation of shipping containers
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Also Published As

Publication number Publication date
WO2014184491A1 (fr) 2014-11-20
KR102332259B1 (ko) 2021-11-26
EP2996967A1 (de) 2016-03-23
FR3005642A1 (fr) 2014-11-21
US11279553B2 (en) 2022-03-22
PL2996967T3 (pl) 2019-02-28
ES2702176T3 (es) 2019-02-27
FR3005642B1 (fr) 2016-01-01
KR20160008622A (ko) 2016-01-22
US20160251154A1 (en) 2016-09-01
EP3441325A1 (de) 2019-02-13

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