EP2981633A2 - Constructions superdures et ses procédés de fabrication - Google Patents
Constructions superdures et ses procédés de fabricationInfo
- Publication number
- EP2981633A2 EP2981633A2 EP14713509.9A EP14713509A EP2981633A2 EP 2981633 A2 EP2981633 A2 EP 2981633A2 EP 14713509 A EP14713509 A EP 14713509A EP 2981633 A2 EP2981633 A2 EP 2981633A2
- Authority
- EP
- European Patent Office
- Prior art keywords
- superhard
- grains
- polycrystalline
- particles
- fraction
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
- 238000000034 method Methods 0.000 title claims abstract description 55
- 238000010276 construction Methods 0.000 title claims abstract description 43
- 239000000463 material Substances 0.000 claims abstract description 182
- 239000002245 particle Substances 0.000 claims abstract description 70
- 229910003460 diamond Inorganic materials 0.000 claims description 124
- 239000010432 diamond Substances 0.000 claims description 124
- 239000000758 substrate Substances 0.000 claims description 50
- 239000003054 catalyst Substances 0.000 claims description 48
- 239000011230 binding agent Substances 0.000 claims description 36
- MCMNRKCIXSYSNV-UHFFFAOYSA-N Zirconium dioxide Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 claims description 32
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims description 23
- 229910017052 cobalt Inorganic materials 0.000 claims description 22
- 239000010941 cobalt Substances 0.000 claims description 22
- 239000000203 mixture Substances 0.000 claims description 20
- 238000005520 cutting process Methods 0.000 claims description 19
- 239000002904 solvent Substances 0.000 claims description 19
- 238000003801 milling Methods 0.000 claims description 17
- 238000005553 drilling Methods 0.000 claims description 12
- 229910052751 metal Inorganic materials 0.000 claims description 11
- 239000002184 metal Substances 0.000 claims description 11
- UONOETXJSWQNOL-UHFFFAOYSA-N tungsten carbide Chemical compound [W+]#[C-] UONOETXJSWQNOL-UHFFFAOYSA-N 0.000 claims description 11
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 9
- 239000011435 rock Substances 0.000 claims description 9
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical group [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 8
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 7
- 238000009826 distribution Methods 0.000 claims description 6
- 229910052759 nickel Inorganic materials 0.000 claims description 6
- 229910045601 alloy Inorganic materials 0.000 claims description 5
- 239000000956 alloy Substances 0.000 claims description 5
- 239000010439 graphite Substances 0.000 claims description 5
- 229910002804 graphite Inorganic materials 0.000 claims description 5
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 3
- 229910052804 chromium Inorganic materials 0.000 claims description 3
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- 230000001747 exhibiting effect Effects 0.000 claims description 3
- 238000011049 filling Methods 0.000 claims description 3
- 238000000227 grinding Methods 0.000 claims description 3
- 229910052742 iron Inorganic materials 0.000 claims description 3
- BPUBBGLMJRNUCC-UHFFFAOYSA-N oxygen(2-);tantalum(5+) Chemical compound [O-2].[O-2].[O-2].[O-2].[O-2].[Ta+5].[Ta+5] BPUBBGLMJRNUCC-UHFFFAOYSA-N 0.000 claims description 3
- 229910001936 tantalum oxide Inorganic materials 0.000 claims description 3
- RUDFQVOCFDJEEF-UHFFFAOYSA-N yttrium(III) oxide Inorganic materials [O-2].[O-2].[O-2].[Y+3].[Y+3] RUDFQVOCFDJEEF-UHFFFAOYSA-N 0.000 claims description 3
- 239000011248 coating agent Substances 0.000 claims description 2
- 150000001247 metal acetylides Chemical class 0.000 claims description 2
- 150000002739 metals Chemical class 0.000 claims description 2
- 150000004767 nitrides Chemical class 0.000 claims description 2
- 238000009527 percussion Methods 0.000 claims description 2
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- 238000005096 rolling process Methods 0.000 claims description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims 2
- 238000004519 manufacturing process Methods 0.000 claims 1
- 239000000377 silicon dioxide Substances 0.000 claims 1
- 238000005245 sintering Methods 0.000 description 31
- 239000000843 powder Substances 0.000 description 23
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 15
- 230000008569 process Effects 0.000 description 14
- 238000012360 testing method Methods 0.000 description 14
- 239000002131 composite material Substances 0.000 description 10
- 231100000241 scar Toxicity 0.000 description 10
- 208000010392 Bone Fractures Diseases 0.000 description 9
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- 238000006243 chemical reaction Methods 0.000 description 6
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- 230000000694 effects Effects 0.000 description 4
- 230000001737 promoting effect Effects 0.000 description 4
- 229910052582 BN Inorganic materials 0.000 description 3
- PZNSFCLAULLKQX-UHFFFAOYSA-N Boron nitride Chemical compound N#B PZNSFCLAULLKQX-UHFFFAOYSA-N 0.000 description 3
- 239000002775 capsule Substances 0.000 description 3
- 239000000919 ceramic Substances 0.000 description 3
- 229910021446 cobalt carbonate Inorganic materials 0.000 description 3
- ZOTKGJBKKKVBJZ-UHFFFAOYSA-L cobalt(2+);carbonate Chemical compound [Co+2].[O-]C([O-])=O ZOTKGJBKKKVBJZ-UHFFFAOYSA-L 0.000 description 3
- 238000005056 compaction Methods 0.000 description 3
- 230000006872 improvement Effects 0.000 description 3
- 238000011068 loading method Methods 0.000 description 3
- 238000004901 spalling Methods 0.000 description 3
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 2
- -1 VIB metals Chemical class 0.000 description 2
- 238000000231 atomic layer deposition Methods 0.000 description 2
- 229910052799 carbon Inorganic materials 0.000 description 2
- 238000005229 chemical vapour deposition Methods 0.000 description 2
- UFMZWBIQTDUYBN-UHFFFAOYSA-N cobalt dinitrate Chemical compound [Co+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O UFMZWBIQTDUYBN-UHFFFAOYSA-N 0.000 description 2
- 230000008021 deposition Effects 0.000 description 2
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- 239000000523 sample Substances 0.000 description 2
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 1
- 208000032544 Cicatrix Diseases 0.000 description 1
- 229910000531 Co alloy Inorganic materials 0.000 description 1
- 208000013201 Stress fracture Diseases 0.000 description 1
- 239000003082 abrasive agent Substances 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 238000010306 acid treatment Methods 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
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- 238000000498 ball milling Methods 0.000 description 1
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- 238000009694 cold isostatic pressing Methods 0.000 description 1
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- 238000001035 drying Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000001125 extrusion Methods 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 239000010438 granite Substances 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 238000002347 injection Methods 0.000 description 1
- 239000007924 injection Substances 0.000 description 1
- 238000010902 jet-milling Methods 0.000 description 1
- 238000005304 joining Methods 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- 238000005065 mining Methods 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- 229910052758 niobium Inorganic materials 0.000 description 1
- 239000010955 niobium Substances 0.000 description 1
- GUCVJGMIXFAOAE-UHFFFAOYSA-N niobium atom Chemical compound [Nb] GUCVJGMIXFAOAE-UHFFFAOYSA-N 0.000 description 1
- 230000021715 photosynthesis, light harvesting Effects 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 238000000197 pyrolysis Methods 0.000 description 1
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- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 description 1
- 229910052721 tungsten Inorganic materials 0.000 description 1
- 239000010937 tungsten Substances 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 239000002023 wood Substances 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B24—GRINDING; POLISHING
- B24D—TOOLS FOR GRINDING, BUFFING OR SHARPENING
- B24D18/00—Manufacture of grinding tools or other grinding devices, e.g. wheels, not otherwise provided for
- B24D18/0009—Manufacture of grinding tools or other grinding devices, e.g. wheels, not otherwise provided for using moulds or presses
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C26/00—Alloys containing diamond or cubic or wurtzitic boron nitride, fullerenes or carbon nanotubes
-
- E—FIXED CONSTRUCTIONS
- E21—EARTH OR ROCK DRILLING; MINING
- E21B—EARTH OR ROCK DRILLING; OBTAINING OIL, GAS, WATER, SOLUBLE OR MELTABLE MATERIALS OR A SLURRY OF MINERALS FROM WELLS
- E21B10/00—Drill bits
- E21B10/46—Drill bits characterised by wear resisting parts, e.g. diamond inserts
-
- E—FIXED CONSTRUCTIONS
- E21—EARTH OR ROCK DRILLING; MINING
- E21B—EARTH OR ROCK DRILLING; OBTAINING OIL, GAS, WATER, SOLUBLE OR MELTABLE MATERIALS OR A SLURRY OF MINERALS FROM WELLS
- E21B10/00—Drill bits
- E21B10/46—Drill bits characterised by wear resisting parts, e.g. diamond inserts
- E21B10/56—Button-type inserts
-
- E—FIXED CONSTRUCTIONS
- E21—EARTH OR ROCK DRILLING; MINING
- E21B—EARTH OR ROCK DRILLING; OBTAINING OIL, GAS, WATER, SOLUBLE OR MELTABLE MATERIALS OR A SLURRY OF MINERALS FROM WELLS
- E21B10/00—Drill bits
- E21B10/46—Drill bits characterised by wear resisting parts, e.g. diamond inserts
- E21B10/56—Button-type inserts
- E21B10/567—Button-type inserts with preformed cutting elements mounted on a distinct support, e.g. polycrystalline inserts
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
- B22F5/00—Manufacture of workpieces or articles from metallic powder characterised by the special shape of the product
- B22F2005/001—Cutting tools, earth boring or grinding tool other than table ware
Definitions
- This disclosure relates to superhard constructions and methods of making such constructions, particularly but not exclusively to constructions comprising polycrystalline diamond (PCD) structures attached to a substrate, and tools comprising the same, particularly but not exclusively for use in rock degradation or drilling, or for boring into the earth.
- PCD polycrystalline diamond
- Polycrystalline superhard materials such as polycrystalline diamond (PCD) and polycrystalline cubic boron nitride (PCBN) may be used in a wide variety of tools for cutting, machining, drilling or degrading hard or abrasive materials such as rock, metal, ceramics, composites and wood-containing materials.
- tool inserts in the form of cutting elements comprising PCD material are widely used in drill bits for boring into the earth to extract oil or gas.
- the working life of super hard tool inserts may be limited by fracture of the super hard material, including by spalling and chipping, or by wear of the tool insert.
- Cutting elements such as those for use in rock drill bits or other cutting tools typically have a body in the form of a substrate which has an interface end/surface and a super hard material which forms a cutting layer bonded to the interface surface of the substrate by, for example, a sintering process.
- the substrate is generally formed of a tungsten carbide-cobalt alloy, sometimes referred to as cemented tungsten carbide and the super hard material layer is typically polycrystalline diamond (PCD), polycrystalline cubic boron nitride (PCBN) or a thermally stable product TSP material such as thermally stable polycrystalline diamond.
- PCD polycrystalline diamond
- PCBN polycrystalline cubic boron nitride
- TSP material thermally stable product
- PCD Polycrystalline diamond
- PCD material is an example of a superhard material (also called a superabrasive material or ultra hard material) comprising a mass of substantially inter-grown diamond grains, forming a skeletal mass defining interstices between the diamond grains.
- PCD material typically comprises at least about 80 volume % of diamond and is conventionally made by subjecting an aggregated mass of diamond grains to an ultra-high pressure of greater than about 5 GPa, and temperature of at least about 1 ,200°C, for example.
- a material wholly or partly filling the interstices may be referred to as filler or binder material.
- PCD is typically formed in the presence of a sintering aid such as cobalt, which promotes the inter-growth of diamond grains.
- a sintering aid such as cobalt
- Suitable sintering aids for PCD are also commonly referred to as a solvent-catalyst material for diamond, owing to their function of dissolving, to some extent, the diamond and catalysing its re-precipitation.
- a solvent-catalyst for diamond is understood be a material that is capable of promoting the growth of diamond or the direct diamond-to-diamond inter-growth between diamond grains at a pressure and temperature condition at which diamond is thermodynamically stable. Consequently the interstices within the sintered PCD product may be wholly or partially filled with residual solvent-catalyst material.
- PCD is often formed on a cobalt-cemented tungsten carbide substrate, which provides a source of cobalt solvent-catalyst for the PCD.
- Materials that do not promote substantial coherent intergrowth between the diamond grains may themselves form strong bonds with diamond grains, but are not suitable solvent -catalysts for PCD sintering.
- Cemented tungsten carbide which may be used to form a suitable substrate is formed from carbide particles being dispersed in a cobalt matrix by mixing tungsten carbide particles/grains and cobalt together then heating to solidify.
- a superhard material layer such as PCD or PCBN
- diamond particles or grains or CBN grains are placed adjacent the cemented tungsten carbide body in a refractory metal enclosure such as a niobium enclosure and are subjected to high pressure and high temperature so that inter-grain bonding between the diamond grains or CBN grains occurs, forming a polycrystalline superhard diamond or polycrystalline CBN layer.
- the substrate may be fully cured prior to attachment to the superhard material layer whereas in other cases, the substrate may be green, that is, not fully cured. In the latter case, the substrate may fully cure during the HTHP sintering process.
- the substrate may be in powder form and may solidify during the sintering process used to sinter the superhard material layer.
- Cutting elements or tool inserts comprising PCD material are widely used in drill bits for boring into the earth in the oil and gas drilling industry.
- Rock drilling and other operations require high abrasion resistance and impact resistance.
- One of the factors limiting the success of the polycrystalline diamond (PCD) abrasive cutters is the generation of heat due to friction between the PCD and the work material. This heat causes the thermal degradation of the diamond layer. The thermal degradation increases the wear rate of the cutter through increased cracking and spalling of the PCD layer as well as back conversion of the diamond to graphite causing increased abrasive wear.
- Methods used to improve the abrasion resistance of a PCD composite often result in a decrease in impact resistance of the composite.
- PCD polycrystalline diamond
- a superhard polycrystalline construction comprising:
- a body of polycrystalline superhard material comprising:
- the superhard phase comprising a plurality of inter- bonded superhard grains; wherein the non-superhard phase comprises particles or grains that do not chemically react with the superhard grains and form less than around 10 volume % of the body of polycrystalline superhard material.
- a method of forming a superhard polycrystalline construction comprising:
- a tool comprising the superhard polycrystalline construction defined above, the tool being for cutting, milling, grinding, drilling, earth boring, rock drilling or other abrasive applications.
- the tool may comprise, for example, a drill bit for earth boring or rock drilling, a rotary fixed-cutter bit for use in the oil and gas drilling industry, or a rolling cone drill bit, a hole opening tool, an expandable tool, a reamer or other earth boring tools.
- a drill bit or a cutter or a component therefor comprising the superhard polycrystalline construction defined above.
- Figure 1 is a perspective view of an example PCD cutter element for a drill bit for boring into the earth;
- Figure 2a is a schematic cross-section of an example portion of a PCD micro-structure with a second dispersed non-reactive phase in the material;
- Figure 2b is an expanded view of a section of the schematic cross-section of the example PCD micro-structure of Figure 2a;
- Figure 3 is a plot showing the results of a wear resistance test comparing the wear resistance of an embodiment with that of a conventional PCD material
- Figure 4 is a plot showing the results of a vertical borer test comparing a conventional unleached PCD material, a conventional PCD material leached using an acid treatment, and an embodiment of PCD material prepared according to the described method;
- Figure 5 is a plot showing the results of a vertical borer test comparing a conventional unleached PCD material, and a further embodiment of PCD material.
- a "superhard material” is a material having a Vickers hardness of at least about 28 GPa.
- Diamond and cubic boron nitride (cBN) material are examples of superhard materials.
- a "superhard construction” means a construction comprising a body of polycrystalline superhard material.
- a substrate may be attached thereto or alternatively the body of polycrystalline material may be free-standing and unbacked.
- polycrystalline diamond is a type of polycrystalline superhard (PCS) material comprising a mass of diamond grains, a substantial portion of which are directly inter-bonded with each other and in which the content of diamond is at least about 80 volume percent of the material.
- interstices between the diamond grains may be at least partly filled with a binder material comprising a catalyst for diamond.
- interstices or "interstitial regions” are regions between the diamond grains of PCD material.
- interstices or interstitial regions may be substantially or partially filled with a material other than diamond, or they may be substantially empty.
- PCD material may comprise at least a region from which catalyst material has been removed from the interstices, leaving interstitial voids between the diamond grains.
- a "catalyst material" for a superhard material is capable of promoting the growth or sintering of the superhard material.
- substrate as used herein means any substrate over which the superhard material layer is formed.
- a “substrate” as used herein may be a transition layer formed over another substrate.
- integrally formed regions or parts are produced contiguous with each other and are not separated by a different kind of material.
- a cutting element 1 includes a substrate 10 with a layer of superhard material 12 formed on the substrate 10.
- the substrate 10 may be formed of a hard material such as cemented tungsten carbide.
- the superhard material 12 may be, for example, polycrystalline diamond (PCD), or a thermally stable product such as thermally stable PCD (TSP).
- the cutting element 1 may be mounted into a bit body such as a drag bit body (not shown) and may be suitable, for example, for use as a cutter insert for a drill bit for boring into the earth.
- the exposed top surface of the superhard material opposite the substrate forms the cutting face 14, which is the surface which, along with its edge 16, performs the cutting in use.
- a PCD grade is a PCD material characterised in terms of the volume content and size of diamond grains, the volume content of interstitial regions between the diamond grains and composition of material that may be present within the interstitial regions.
- a grade of PCD material may be made by a process including providing an aggregate mass of diamond grains having a size distribution suitable for the grade, optionally introducing catalyst material or additive material into the aggregate mass, and subjecting the aggregated mass in the presence of a source of catalyst material for diamond to a pressure and temperature at which diamond is more thermodynamically stable than graphite and at which the catalyst material is molten. Under these conditions, molten catalyst material may infiltrate from the source into the aggregated mass and is likely to promote direct intergrowth between the diamond grains in a process of sintering, to form a PCD structure.
- the aggregate mass may comprise loose diamond grains or diamond grains held together by a binder material and said diamond grains may be natural or synthesised diamond grains.
- Different PCD grades may have different microstructures and different mechanical properties, such as elastic (or Young's) modulus E, modulus of elasticity, transverse rupture strength (TRS), toughness (such as so-called KiC toughness), hardness, density and coefficient of thermal expansion (CTE).
- Different PCD grades may also perform differently in use. For example, the wear rate and fracture resistance of different PCD grades may be different.
- All of the PCD grades may comprise interstitial regions filled with material comprising cobalt metal, which is an example of catalyst material for diamond.
- the PCD structure 12 may comprise one or more PCD grades.
- Figures 2a and 2b are cross-sections through an embodiment of PCD material forming the superhard layer 12 of Figure 1 showing, schematically, the PCD microstructure.
- a non-reactive phase comprising particles 30 formed of, for example, ceramic oxides are dispersed in the diamond phase matrix 32 to act as localised stress raisers and/or micro-defects.
- the diamond phase matrix 32 here refers to conventional PCD formed of diamond grains and a catalyst binder phase 33 dispersed therein.
- the non- reactive phase 30 may comprise an oxide, formed for example,of one or more oxides of alumina, zirconia, tantalum oxide and yttria.
- the grain size of the dispersed non-reactive phase particles 30 may, in some embodiments, not be greater than 30% of the size of diamond grains.
- the non-reactive phase particles 30 may be admixed with diamond powder and then the composite is sintered in the traditional way with, for example, cobalt infiltration at HPHT to provide the catalyst binder to form the intergranular bonds between the diamond grains.
- the non-reactive particles are non- reactive with respect to the superhard phase, for example, diamond, and may also be non-reactive with the binder phase such that they are not soluble in the binder phase and do not adhere to the superhard (eg diamond) particles, that is, there is substantially no interfacial bonding between the superhard particles and the non-reactive particles which may be located, as shown in Figure 2b between interbonded diamond grains and in a number of interstitial spaces between interbonded diamond grains, some of which spaces may be at least partially filled with residual binder phase.
- the superhard eg diamond
- the non-reactive phase particles 30 comprise less than 5 volume % of the sintered PCD material. In other embodiments, the non-reactive phase particles 30 comprise less than 3 volume % of the sintered PCD material, or even, in some cases, less than 1 volume % of the sintered PCD material.
- These disperse non-reactive phase particles 30 may be localized inside the binder pools or in between diamond grains, depending on the sizes.
- the grains of superhard material may be, for example, diamond grains or particles.
- the feed comprises a mixture of a coarse fraction of diamond grains and a fine fraction of diamond grains.
- the coarse fraction may have, for example, an average particle/grain size ranging from about 10 to 60 microns.
- average particle or grain size it is meant that the individual particles/grains have a range of sizes with the mean particle/grain size representing the "average”.
- the average particle/grain size of the fine fraction is less than the size of the coarse fraction, for example between around 1/10 to 6/10 of the size of the coarse fraction, and may, in some embodiments, range for example between about 0.1 to 20 microns.
- the weight ratio of the coarse diamond fraction to the fine diamond fraction ranges from about 50% to about 97% coarse diamond and the weight ratio of the fine diamond fraction may be from about 3% to about 50%. In other embodiments, the weight ratio of the coarse fraction to the fine fraction will range from about 70:30 to about 90:10.
- the weight ratio of the coarse fraction to the fine fraction may range for example from about 60:40 to about 80:20.
- the particle size distributions of the coarse and fine fractions do not overlap and in some embodiments the different size components of the compact are separated by an order of magnitude between the separate size fractions making up the multimodal distribution.
- Some embodiments consist of a wide bi-modal size distribution between the coarse and fine fractions of superhard material, but some embodiments may include three or even four or more size modes which may, for example, be separated in size by an order of magnitude, for example, a blend of particle sizes whose average particle size is 20 microns, 2 microns, 200nm and 20nm.
- Sizing of diamond particles/grains into fine fraction, coarse fraction, or other sizes in between, may be through known processes such as jet-milling of larger diamond grains and the like.
- the diamond grains used to form the polycrystalline diamond material may be natural or synthetic.
- the binder catalyst/solvent may comprise cobalt or some other iron group elements, such as iron or nickel, or an alloy thereof.
- Carbides, nitrides, borides, and oxides of the metals of Groups IV-VI in the periodic table are other examples of non-diamond material that might be added to the sinter mix.
- the binder/catalyst/sintering aid may be Co.
- the cemented metal carbide substrate may be conventional in composition and, thus, may be include any of the Group IVB, VB, or VIB metals, which are pressed and sintered in the presence of a binder of cobalt, nickel or iron, or alloys thereof.
- the metal carbide is tungsten carbide.
- the cutter of Figure 1 having the microstructure of Figures 2a and 2b may be fabricated, for example, as follows.
- a "green body” is a body comprising grains to be sintered and a means of holding the grains together, such as a binder, for example an organic binder, together with the additional non-reactive phase 30.
- Embodiments of superhard constructions may be made by a method of preparing a green body comprising grains or particles of superhard material, non-reactive phase and a binder, such as an organic binder.
- the green body may also comprise catalyst material for promoting the sintering of the superhard grains.
- the green body may be made by combining the grains or particles with the binder/catalyst and forming them into a body having substantially the same general shape as that of the intended sintered body, and drying the binder. At least some of the binder material may be removed by, for example, burning it off.
- the green body may be formed by a method including a compaction process, an injection process or other methods such as molding, extrusion, deposition modelling methods.
- a green body for the superhard construction may be placed onto a substrate, such as a pre-formed cemented carbide substrate to form a pre- sinter assembly, which may be encapsulated in a capsule for an ultra-high pressure furnace, as is known in the art.
- the substrate may provide a source of catalyst material for promoting the sintering of the superhard grains.
- the superhard grains may be diamond grains and the substrate may be cobalt-cemented tungsten carbide, the cobalt in the substrate being a source of catalyst for sintering the diamond grains.
- the pre-sinter assembly may comprise an additional source of catalyst material.
- the method may include loading the capsule comprising a pre-sinter assembly into a press and subjecting the green body to an ultrahigh pressure and a temperature at which the superhard material is thermodynamically stable to sinter the superhard grains.
- the green body may comprise diamond grains and the pressure to which the assembly is subjected is at least about 5 GPa and the temperature is at least about 1 ,300 degrees centigrade.
- a version of the method may include making a diamond composite structure by means of a method disclosed, for example, in PCT application publication number WO2009/128034 with the additional step of admixing with the diamond grains, prior to sintering, the grains/particles of non- reactive phase.
- a powder blend comprising diamond particles, non- reactive phase particles and a metal binder material, such as cobalt may be prepared by combining these particles and blending them together.
- An effective powder preparation technology may be used to blend the powders, such as wet or dry multi-directional mixing, planetary ball milling and high shear mixing with a homogenizer.
- the mean size of the diamond particles may be at least about 50 microns and they may be combined with other particles by mixing the powders or, in some cases, stirring the powders together by hand.
- precursor materials suitable for subsequent conversion into binder material may be included in the powder blend, and in one version of the method, metal binder material may be introduced in a form suitable for infiltration into a green body.
- the powder blend may be deposited in a die or mold and compacted to form a green body, for example by uni-axial compaction or other compaction method, such as cold isostatic pressing (CIP).
- CIP cold isostatic pressing
- the green body may be subjected to a sintering process known in the art to form a sintered article.
- the method may include loading the capsule comprising a pre-sinter assembly into a press and subjecting the green body to an ultra-high pressure and a temperature at which the superhard material is thermodynamically stable to sinter the superhard grains.
- the polycrystalline super hard constructions may be ground to size and may include, if desired, a 45° chamfer of approximately 0.4mm height on the body of polycrystalline super hard material so produced.
- the sintered article may be subjected to a subsequent treatment at a pressure and temperature at which diamond is thermally stable to convert some or all of the non-diamond carbon back into diamond and produce a diamond composite structure.
- An ultra-high pressure furnace well known in the art of diamond synthesis may be used and the pressure may be at least about 5.5 GPa and the temperature may be at least about 1 ,250 degrees centigrade for the second sintering process.
- a further embodiment of a superhard construction may be made by a method including providing a PCD structure and a precursor structure for a diamond composite structure, forming each structure into the respective complementary shapes, assembling the PCD structure and the diamond composite structure onto a cemented carbide substrate to form an unjoined assembly, and subjecting the unjoined assembly to a pressure of at least about 5.5 GPa and a temperature of at least about 1 ,250 degrees centigrade to form a PCD construction.
- the precursor structure may comprise carbide particles and diamond or non-diamond carbon material, such as graphite, non-reactive phase particles, and a binder material comprising a metal, such as cobalt.
- the precursor structure may be a green body formed by compacting a powder blend comprising particles of diamond or non-diamond carbon and particles of carbide material and compacting the powder blend.
- both the bodies of, for example, diamond and carbide material plus the non-reactive phase and sintering aid/binder/catalyst are applied as powders and sintered simultaneously in a single UHP/HT process.
- the mixture of diamond grains, non-reactive phase particles and mass of carbide are placed in an HP/HT reaction cell assembly and subjected to HP/HT processing.
- the HP/HT processing conditions selected are sufficient to effect intercrystalline bonding between adjacent grains of abrasive particles and, optionally, the joining of sintered particles to the cemented metal carbide support.
- the processing conditions generally involve the imposition for about 3 to 120 minutes of a temperature of at least about 1200 degrees C and an ultra-high pressure of greater than about 5 GPa.
- the substrate may be pre-sintered in a separate process before being bonded together in the HP/HT press during sintering of the ultrahard polycrystalline material.
- both the substrate and a body of polycrystalline superhard material are pre-formed.
- the bimodal feed of ultrahard grains/particles with non-reactive phase particles and optional carbonate binder-catalyst also in powdered form are mixed together, and the mixture is packed into an appropriately shaped canister and is then subjected to extremely high pressure and temperature in a press.
- the pressure is at least 5 GPa and the temperature is at least around 1200 degrees C.
- the preformed body of polycrystalline superhard material is then placed in the appropriate position on the upper surface of the preform carbide substrate (incorporating a binder catalyst), and the assembly is located in a suitably shaped canister.
- the assembly is then subjected to high temperature and pressure in a press, the order of temperature and pressure being again, at least around 1200 degrees C and 5 GPa respectively.
- the solvent/catalyst migrates from the substrate into the body of superhard material and acts as a binder-catalyst to effect intergrowth in the layer and also serves to bond the layer of polycrystalline superhard material to the substrate.
- the sintering process also serves to bond the body of superhard polycrystalline material to the substrate.
- solvent / catalyst material may be included or introduced into the aggregated mass of diamond grains from a source of the material other than the cemented carbide substrate.
- the solvent / catalyst material may comprise cobalt that infiltrates from the substrate in to the aggregated mass of diamond grains just prior to and during the sintering step at an ultra-high pressure.
- an alternative source may need to be provided in order to ensure good sintering of the aggregated mass to form PCD.
- Solvent / catalyst for diamond may be introduced into the aggregated mass of diamond grains by various methods, including blending solvent / catalyst material in powder form with the diamond grains, depositing solvent / catalyst material onto surfaces of the diamond grains, or infiltrating solvent / catalyst material into the aggregated mass from a source of the material other than the substrate, either prior to the sintering step or as part of the sintering step.
- Methods of depositing solvent / catalyst for diamond, such as cobalt, onto surfaces of diamond grains are well known in the art, and include chemical vapour deposition (CVD), physical vapour deposition (PVD), sputter coating, electrochemical methods, electroless coating methods and atomic layer deposition (ALD). It will be appreciated that the advantages and disadvantages of each depend on the nature of the sintering aid material and coating structure to be deposited, and on characteristics of the grain.
- non-reactive phase particles may be introduced by various means, for example, the diamond grains or particles could be coated with a non-reacting material prior to sintering.
- the binder/catalyst such as cobalt may be deposited onto surfaces of the diamond grains by first depositing a pre-cursor material and then converting the precursor material to a material that comprises elemental metallic cobalt.
- cobalt carbonate may be deposited on the diamond grain surfaces using the following reaction:
- the deposition of the carbonate or other precursor for cobalt or other solvent / catalyst for diamond may be achieved by means of a method described in PCT patent publication number WO/2006/032982.
- the cobalt carbonate may then be converted into cobalt and water, for example, by means of pyrolysis reactions such as the following:
- cobalt powder or precursor to cobalt such as cobalt carbonate
- cobalt carbonate may be blended with the diamond grains.
- a precursor to a solvent / catalyst such as cobalt
- the cemented carbide substrate may be formed of tungsten carbide particles bonded together by the binder material, the binder material comprising an alloy of Co, Ni and Cr.
- the tungsten carbide particles may form at least 70 weight percent and at most 95 weight percent of the substrate.
- the binder material may comprise between about 10 to 50 wt.% Ni, between about 0.1 to 10 wt.% Cr, and the remainder weight percent comprises Co.
- Example 4 0.25g of Zirconia with an average grain size of 1 micron was added to 50g of a unimodal diamond powder with an average grain size of 3 microns.
- the aggregated mass was ball milled in 60ml of methanol with co-WC milling balls.
- the ratio of milling balls : powder was 5:1 and milling was carried out for 1 hour at 90rpm.
- 2.1 g of the mixture was placed on top of a pre-formed WC-Co substrate and sintered under high pressure high temperature HPHT conditions at 6.8GPa and 1450°C.
- the PCD cutter was recovered, processed and analysed. The results are discussed below with reference to Figures 3 to 5.
- Example 4 Example 4:
- 0.5g of Zirconia with an average grain size of 1 micron was added to 50g of a unimodal diamond powder with an average grain size of 3 microns.
- the aggregated mass was ball milled in 60ml of methanol with Co-WC milling balls.
- the ratio of milling balls : powder was 5:1 and milling was carried out for 1 hour at 90rpm.
- 2.1 g of the mixture was placed on top of a pre-formed WC-Co substrate and sintered under high pressure high temperature HPHT conditions at 6.8GPa and 1450°C. The PCD cutter was recovered, processed and analysed.
- the PCD compact formed according to Example 1 was compared in a vertical boring mill test with both leached (Ref Z) and unleached (Ref NZ) commercially available polycrystalline diamond cutter elements.
- the wear flat area was measured as a function of the number of passes of the cutter element boring into the workpiece.
- the results obtained are illustrated graphically in Figure 4. The results provide an indication of the total wear scar area plotted against cutting length. It will be seen that the PCD compact formed according to example 1 was able to achieve a greater cutting length and smaller wear scar area than that occurring in both leached and unleached conventional PCD compacts which were subjected to the same test for comparison.
- the conventional PCD compacts in this test comprised Ref 2 which was a bimodal mixture having an average diamond grain size of around 4 microns. Indeed, Figure 4 shows a 96% improvement in cutting length was achieved in the embodiment of PCD compared to a conventional PCD without zirconia addition.
- the fracture performance of PCD may be improved through the introduction of the micro-defects and/or stress raisers in a PCD matrix according to some embodiments described herein.
- the micro-defects and/or stress raisers are believed to promote crack bifurcation or multiple crack fronts in the PCD material in use, resulting in a redistribution of available strain energy or energy release rate (G) amongst the various crack tips.
- G strain energy or energy release rate
- the end result in application of the PCD material including such micro-defects is that, in use, the number of cracks initiated on the wear scar may be increased as compared to conventional PCD, thus reducing the strain energy available for each individual crack, hence slowing the growth rate, and the generation of shorter cracks.
- the ideal case is where the wear rate is comparable to the crack growth rate, in which case no cracks will be visible behind the wear scar thereby forming a smooth wear scar appearance with no chips or grains pulled out of the sintered PCD.
- the addition of a ceramic non-reactive phase may also have the effect of increasing the thermal stability of the PCD through the resultant lower cobalt content in the material of the invention compared to conventional PCD.
- micro-defects may be tailored to the final application of the PCD material. It is believed possible to improve fracture resistance without significantly compromising the overall abrasion resistance of the material, which is desirable for PCD cutting tools.
- embodiments may provide a means of toughening PCD material without compromising its high abrasion resistance. This may be achieved by engineering micro-defects into the PCD matrix.
- the concept works by enabling the creation of multiple crack-fronts or defects which help to redistribute or dissipate the available fracture energy. These defects may also promote crack bifurcations, which is another energy dissipation mechanism. The end result is that there is insufficient energy available to each individual crack to enable it to propagate quickly and hence this may significantly slow down the rate of crack growth.
- embodiments of a PCD material may be formed having that a combination of high abrasion and fracture performance.
- the PCD element 10 described with reference to Figure 1 may be further processed after sintering.
- catalyst material may be removed from a region of the PCD structure adjacent the working surface or the side surface or both the working surface and the side surface. This may be done by treating the PCD structure with acid to leach out catalyst material from between the diamond grains, or by other methods such as electrochemical methods.
- a thermally stable region which may be substantially porous, extending a depth of at least about 50 microns or at least about 100 microns from a surface of the PCD structure, may thus be provided which may further enhance the thermal stability of the PCD element.
- the PCD body in the structure of Figure 1 comprising a PCD structure bonded to a cemented carbide support body may be created or finished by, for example, grinding, to provide a PCD element which is substantially cylindrical and having a substantially planar working surface, or a generally domed, pointed, rounded conical or frusto-conical working surface.
- the PCD element may be suitable for use in, for example, a rotary shear (or drag) bit for boring into the earth, for a percussion drill bit or for a pick for mining or asphalt degradation.
- the micro-defects in the form of the non-reactive phase particles may be introduced into the PCD in various ways and, in some embodiments, they may be introduced by modifying the HPHT sintering conditions such that micro-defects are introduced along diamond grain boundaries through partial sintering of the PCD.
- These dispersed non-reactive phase particles may be localized inside the binder pools or in between diamond grains, depending on the sizes.
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- Geology (AREA)
- Mechanical Engineering (AREA)
- Materials Engineering (AREA)
- Geochemistry & Mineralogy (AREA)
- General Life Sciences & Earth Sciences (AREA)
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- Fluid Mechanics (AREA)
- Organic Chemistry (AREA)
- Metallurgy (AREA)
- Crystallography & Structural Chemistry (AREA)
- Manufacturing & Machinery (AREA)
- Earth Drilling (AREA)
- Cutting Tools, Boring Holders, And Turrets (AREA)
- Polishing Bodies And Polishing Tools (AREA)
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Abstract
L'invention concerne une construction polycristalline superdure comprenant un corps de matériau superdur polycristallin comprenant une phase superdure, et une phase non superdure dispersée dans la phase superdure, la phase superdure comprenant une pluralité de grains superdurs interliés. La phase non superdure comprend des particules ou grains qui ne réagissent pas chimiquement avec les grains superdurs et forment moins d'environ 10 % en volume du corps de matériau superdur polycristallin. Un procédé de formation de telles constructions polycristallines superdures est également décrit.
Applications Claiming Priority (2)
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GBGB1305871.4A GB201305871D0 (en) | 2013-03-31 | 2013-03-31 | Superhard constructions & methods of making same |
PCT/EP2014/056463 WO2014161818A2 (fr) | 2013-03-31 | 2014-03-31 | Constructions superdures et ses procédés de fabrication |
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EP2981633A2 true EP2981633A2 (fr) | 2016-02-10 |
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EP14713509.9A Withdrawn EP2981633A2 (fr) | 2013-03-31 | 2014-03-31 | Constructions superdures et ses procédés de fabrication |
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US (3) | US20160251741A1 (fr) |
EP (1) | EP2981633A2 (fr) |
JP (1) | JP6316936B2 (fr) |
CN (2) | CN110157967A (fr) |
GB (2) | GB201305871D0 (fr) |
WO (1) | WO2014161818A2 (fr) |
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GB201318640D0 (en) * | 2013-10-22 | 2013-12-04 | Element Six Abrasives Sa | Superhard constructions & methods of making same |
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US11434136B2 (en) | 2015-03-30 | 2022-09-06 | Diamond Innovations, Inc. | Polycrystalline diamond bodies incorporating fractionated distribution of diamond particles of different morphologies |
CN104962793B (zh) * | 2015-06-23 | 2017-04-26 | 中南钻石有限公司 | 一种具有良好导电性能的金刚石聚晶复合片及其制备方法 |
GB201523182D0 (en) * | 2015-12-31 | 2016-02-17 | Element Six Uk Ltd | Super hard constructions & methods of making same |
CN105525345B (zh) * | 2016-02-18 | 2018-06-26 | 长春阿尔玛斯科技有限公司 | 金刚石多晶体合成超硬材料及其生产工艺 |
DE102016207028A1 (de) * | 2016-04-26 | 2017-10-26 | H.C. Starck Gmbh | Hartmetall mit zähigkeitssteigerndem Gefüge |
GB201622472D0 (en) * | 2016-12-31 | 2017-02-15 | Element Six (Uk) Ltd | Superhard constructions & methods of making same |
US10603719B2 (en) * | 2017-08-31 | 2020-03-31 | Baker Hughes, A Ge Company, Llc | Cutting elements and methods for fabricating diamond compacts and cutting elements with functionalized nanoparticles |
CN107904471B (zh) * | 2017-11-14 | 2019-05-24 | 陕西理工大学 | 低密度耐磨蚀硬质合金材料及其制备方法 |
CN108585855B (zh) * | 2018-01-26 | 2020-07-28 | 西南交通大学 | 一种硒触媒的多晶金刚石烧结体及其制备方法 |
GB201918378D0 (en) * | 2019-12-13 | 2020-01-29 | Element Six Uk Ltd | Polycrystalline diamond with iron-containing binder |
CN111850335B (zh) * | 2020-07-27 | 2022-04-29 | 深圳市海明润超硬材料股份有限公司 | 一种易脱钴金刚石复合片及其制备方法 |
CN113968736B (zh) * | 2021-12-01 | 2022-12-30 | 西南交通大学 | 一种碲触媒的多晶金刚石烧结体及其制备方法 |
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Also Published As
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GB201405736D0 (en) | 2014-05-14 |
WO2014161818A3 (fr) | 2014-12-24 |
JP2016520504A (ja) | 2016-07-14 |
US20160251741A1 (en) | 2016-09-01 |
JP6316936B2 (ja) | 2018-04-25 |
WO2014161818A2 (fr) | 2014-10-09 |
CN105209649A (zh) | 2015-12-30 |
GB201305871D0 (en) | 2013-05-15 |
GB2512500A (en) | 2014-10-01 |
US20190017153A1 (en) | 2019-01-17 |
GB2512500B (en) | 2015-10-07 |
CN110157967A (zh) | 2019-08-23 |
US20220411900A1 (en) | 2022-12-29 |
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